JPH0297093A - Treatment of inner layer material - Google Patents
Treatment of inner layer materialInfo
- Publication number
- JPH0297093A JPH0297093A JP24930888A JP24930888A JPH0297093A JP H0297093 A JPH0297093 A JP H0297093A JP 24930888 A JP24930888 A JP 24930888A JP 24930888 A JP24930888 A JP 24930888A JP H0297093 A JPH0297093 A JP H0297093A
- Authority
- JP
- Japan
- Prior art keywords
- treatment
- rinse
- inner layer
- layer material
- rinsing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 23
- 238000005238 degreasing Methods 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 10
- 238000005554 pickling Methods 0.000 claims abstract description 10
- 239000002253 acid Substances 0.000 claims abstract description 8
- 238000005530 etching Methods 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims description 7
- 230000000694 effects Effects 0.000 abstract description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- -1 etc. Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000012487 rinsing solution Substances 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Production Of Multi-Layered Print Wiring Board (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は″ftft型、計算機器、通信機器等に用いら
れる多層配線基板の内層材の処理方法に関するものであ
る。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a method for treating inner layer materials of multilayer wiring boards used in ``ftft'' type, computing equipment, communication equipment, etc.
従来、a9Cm器等に用いられる多層配線基板の内層材
は、脱脂処理後のリンス処理は水で行なっているが、リ
ンス効果が劣り1色ムラが発生するという問題があった
。Conventionally, the inner layer material of a multilayer wiring board used in A9Cm devices and the like has been rinsed with water after degreasing, but there was a problem that the rinsing effect was poor and one color unevenness occurred.
従来の技術で述べたように脱脂処理後のリンス処理を水
で行なうとリンス効果が劣り、色ムラが発生するという
問題がある。本発明は従来の技術における上述の問題点
に鑑みてなされたもので、その目的とするところは、脱
脂処理後のリンス効果を向上せしめる内層材の処理方法
を提供することにある。As described in the related art section, if the rinsing treatment after degreasing treatment is performed with water, the rinsing effect will be poor and color unevenness will occur. The present invention has been made in view of the above-mentioned problems in the prior art, and its object is to provide a method for treating an inner layer material that improves the rinsing effect after degreasing.
本発明は内層材を脱脂処理後、含酸リンス液でリンス処
理し、次いでソフトエツチング処理、リンス処理、酸洗
い処理、リンス処理することを特徴とする内層材の処理
方法のため、リンス効果が向上し色ムラ発生がなくなっ
たもので、以下本発明の詳細な説明する。The present invention is an inner layer material treatment method characterized by degreasing the inner layer material, rinsing it with an acid-containing rinsing liquid, and then performing soft etching treatment, rinsing treatment, pickling treatment, and rinsing treatment, so that the rinsing effect is improved. The present invention will be described in detail below.
本発明に用いる内層材はフェノール樹脂、クレゾール樹
脂、エポキシ樹脂、不飽和ポリエステル樹脂、メラミン
樹脂、ポリイミド樹脂、ボリフエニVンオキサイド樹脂
、弗化樹脂等の合成樹脂をガラス、アスベスト等の無!
I繊雌やポリエステル、ポリアミド、ポリビニルアルコ
ール、ポリウレタン、ポリイミド等の有機合成aIaや
、木綿等の天然繊維の織布、不織布、マット、ネット、
寒冷紗、紙等の基材に乾燥後の樹脂量が船〜ω重量%(
以下単に%と記す)Kなるように含浸、乾慢してなる厚
み0.O1〜IHの樹脂含浸基材の所要枚数を重ねた上
面及び又は下面に鋼、アルミニウム、ニッケル、亜鉛等
の単独、合金、複合からなる金属箔を配役一体化してな
るもので、いわゆる片面金属張積層板、両面金属張積層
板と称するものである。内層材の脱脂処理は特に限定す
るものではないが、塩酸等の無機酸、イソプロピルアル
コール等の溶剤、界面活性剤等の添加剤等からなるもの
が好ましい。含酸リンス液は塩酸等を含有する水溶液等
が用いられるが好ましくは酸洗い処理後の一次リンス液
であることが処理液の有効利用にもなシ望ましいことで
ある。ソフトエツチング処理、リンス処理、酸洗い処理
、リンス処理については通常用いられる処理方法をその
ft用いることができるものである。The inner layer material used in the present invention is made of synthetic resins such as phenol resin, cresol resin, epoxy resin, unsaturated polyester resin, melamine resin, polyimide resin, polyurethane oxide resin, and fluorinated resin, and is free of glass, asbestos, etc.
Organic synthetic materials such as I fibers, polyester, polyamide, polyvinyl alcohol, polyurethane, polyimide, etc., woven fabrics, non-woven fabrics, mats, nets, etc. made of natural fibers such as cotton, etc.
The amount of resin after drying on base materials such as cheesecloth and paper is approximately ω% by weight (
(Hereinafter simply written as %) K is impregnated and dried to a thickness of 0. It is made by integrating a metal foil made of steel, aluminum, nickel, zinc, etc. alone, alloy, or composite on the upper and/or lower surfaces of the required number of O1 to IH resin-impregnated base materials, so-called single-sided metal cladding. This is called a laminate or double-sided metal-clad laminate. The degreasing treatment of the inner layer material is not particularly limited, but it is preferable to use an inorganic acid such as hydrochloric acid, a solvent such as isopropyl alcohol, and an additive such as a surfactant. As the acid-containing rinsing liquid, an aqueous solution containing hydrochloric acid or the like is used, but it is preferable to use a primary rinsing liquid after pickling treatment, since this is also effective in utilizing the treatment liquid. For the soft etching treatment, rinsing treatment, pickling treatment, and rinsing treatment, commonly used treatment methods can be used.
以下本発明を実施例にもとづいて説明する。The present invention will be explained below based on examples.
実施例
厚み0.8ffの両面銅張エポキシ樹脂がフス布漬層板
を、脱脂液(メック株式会社製、商品名メックプフイト
)で90秒間脱脂処理後、塩酸を10〜I4含有する酸
洗い処理後の一次リンス液でリンス処理し、次いで通常
行なわれる方法でソフトエツチング処理、リンス処理、
酸洗い処理、リンス処理を行ない内層材を処理した。こ
の際酸洗い処理後の一次リンス液の含酸リンス槽へのフ
ィード創ま1■でちった。Example A double-sided copper-clad epoxy resin-clad laminate with a thickness of 0.8 ff was degreased for 90 seconds with a degreasing solution (manufactured by MEC Co., Ltd., trade name: MEC PUFIT), and then pickled with hydrochloric acid containing 10 to 14 Rinsing with a primary rinsing solution, followed by soft etching, rinsing, and
The inner layer material was treated by pickling and rinsing. At this time, the primary rinsing solution after the pickling treatment was fed into the acid-containing rinsing tank in 1 part.
比較例
脱脂処理後のリンス処理を水のみで行なった以外は実施
例と同様に処理して内層材の処理を行なった。Comparative Example The inner layer material was treated in the same manner as in the example except that the rinsing treatment after the degreasing treatment was performed using only water.
実施例及び比較例の内層材の表面状態は第1表のようで
ある。The surface conditions of the inner layer materials of Examples and Comparative Examples are as shown in Table 1.
第1表
〔発明の効果〕
本発明は上述したクロ〈構成されている。特許請求の範
囲に記載した構成′f:存する内層材の処理方法におい
ては内層材表面に色ムフを発生することがなく、脱脂処
理後のリンス処理を向上させる効果を有している。Table 1 [Effects of the Invention] The present invention is constructed as described above. Configuration 'f' described in the claims: The existing inner layer material treatment method does not cause discoloration on the surface of the inner layer material, and has the effect of improving rinsing treatment after degreasing treatment.
Claims (2)
理し、次いでソフトエッチング処理、リンス処理、酸洗
い処理、リンス処理することを特徴とする内層材の処理
方法。(1) A method for treating an inner layer material, which comprises degreasing the inner layer material, rinsing it with an acid-containing rinsing liquid, and then subjecting it to soft etching treatment, rinsing treatment, pickling treatment, and rinsing treatment.
あることを特徴とする特許請求の範囲第1項記載の内層
材の処理方法。(2) The method for treating an inner layer material according to claim 1, wherein the acid-containing rinsing liquid is a primary rinsing liquid after pickling treatment.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP24930888A JPH0297093A (en) | 1988-10-03 | 1988-10-03 | Treatment of inner layer material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP24930888A JPH0297093A (en) | 1988-10-03 | 1988-10-03 | Treatment of inner layer material |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0297093A true JPH0297093A (en) | 1990-04-09 |
Family
ID=17191055
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP24930888A Pending JPH0297093A (en) | 1988-10-03 | 1988-10-03 | Treatment of inner layer material |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0297093A (en) |
-
1988
- 1988-10-03 JP JP24930888A patent/JPH0297093A/en active Pending
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