JPH025724B2 - - Google Patents
Info
- Publication number
- JPH025724B2 JPH025724B2 JP57137073A JP13707382A JPH025724B2 JP H025724 B2 JPH025724 B2 JP H025724B2 JP 57137073 A JP57137073 A JP 57137073A JP 13707382 A JP13707382 A JP 13707382A JP H025724 B2 JPH025724 B2 JP H025724B2
- Authority
- JP
- Japan
- Prior art keywords
- oil
- lipstick
- hydroxystearate
- cholesteryl
- solid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 235000018330 Macadamia integrifolia Nutrition 0.000 claims description 13
- 240000000912 Macadamia tetraphylla Species 0.000 claims description 13
- 235000003800 Macadamia tetraphylla Nutrition 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 239000010466 nut oil Substances 0.000 claims description 13
- SHBUUTHKGIVMJT-UHFFFAOYSA-N Hydroxystearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OO SHBUUTHKGIVMJT-UHFFFAOYSA-N 0.000 claims description 2
- 229940072106 hydroxystearate Drugs 0.000 claims description 2
- 239000003921 oil Substances 0.000 description 25
- 235000019198 oils Nutrition 0.000 description 25
- 239000007787 solid Substances 0.000 description 14
- 239000007788 liquid Substances 0.000 description 11
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 8
- XKMYWNHZAQUEPY-YZGJEOKZSA-N [(3s,8s,9s,10r,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1h-cyclopenta[a]phenanthren-3-yl] 12-hydroxyoctadecanoate Chemical compound C([C@@H]12)C[C@]3(C)[C@@H]([C@H](C)CCCC(C)C)CC[C@H]3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)CCCCCCCCCCC(O)CCCCCC)C1 XKMYWNHZAQUEPY-YZGJEOKZSA-N 0.000 description 7
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 6
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 5
- 239000001993 wax Substances 0.000 description 5
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 4
- 229940114069 12-hydroxystearate Drugs 0.000 description 4
- 239000004204 candelilla wax Substances 0.000 description 4
- 235000013868 candelilla wax Nutrition 0.000 description 4
- 229940073532 candelilla wax Drugs 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- HVYWMOMLDIMFJA-UHFFFAOYSA-N 3-cholesterol Natural products C1C=C2CC(O)CCC2(C)C2C1C1CCC(C(C)CCCC(C)C)C1(C)CC2 HVYWMOMLDIMFJA-UHFFFAOYSA-N 0.000 description 3
- 206010049047 Chapped lips Diseases 0.000 description 3
- 239000004166 Lanolin Substances 0.000 description 3
- 235000021319 Palmitoleic acid Nutrition 0.000 description 3
- 239000004203 carnauba wax Substances 0.000 description 3
- 235000013869 carnauba wax Nutrition 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 235000019388 lanolin Nutrition 0.000 description 3
- 229940039717 lanolin Drugs 0.000 description 3
- 229940057995 liquid paraffin Drugs 0.000 description 3
- 239000004200 microcrystalline wax Substances 0.000 description 3
- 235000019808 microcrystalline wax Nutrition 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 241000208467 Macadamia Species 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 230000035900 sweating Effects 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BITHHVVYSMSWAG-KTKRTIGZSA-N (11Z)-icos-11-enoic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCC(O)=O BITHHVVYSMSWAG-KTKRTIGZSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- POJOORKDYOPQLS-UHFFFAOYSA-L barium(2+) 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonate Chemical compound [Ba+2].C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O.C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O POJOORKDYOPQLS-UHFFFAOYSA-L 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 239000012185 ceresin wax Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 229940108623 eicosenoic acid Drugs 0.000 description 1
- BITHHVVYSMSWAG-UHFFFAOYSA-N eicosenoic acid Natural products CCCCCCCCC=CCCCCCCCCCC(O)=O BITHHVVYSMSWAG-UHFFFAOYSA-N 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- LDHBWEYLDHLIBQ-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide;hydrate Chemical compound O.[OH-].[O-2].[Fe+3] LDHBWEYLDHLIBQ-UHFFFAOYSA-M 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- -1 red No. 202 Chemical compound 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- 239000010913 used oil Substances 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Description
本発明は新規な棒状口紅用組成物に係るもので
あり、ソフトで滑らかな使用感を有し、かつ唇へ
のフイツト感、持ちが良く、唇の荒れを防ぎ潤い
と艶を与える口紅用組成物を提供することを目的
とするものである。
一般に口紅は、固形及び半固形油分10〜40重量
％（以下％は全て重量％）、液状油分50〜90％、
着色剤１〜20％からなり、この処方範囲内で適宜
配合量を変えることにより目的の口紅を得るもの
である。たとえばソフトな感触の口紅を得ようと
する場合は、固形油分量を減らし、半固形油分、
液体油分量を多くすることになる。
ところで従来口紅に用いられてきた固形油分と
しては、カルナバワツクス、キヤンデリラワツク
ス、ビースワツクス等の動食物系ワツクス、固形
パラフイン、セレシン、ミクロクリスタリンワツ
クス等の炭化水素系ワツクスが知られており、ま
た半固形油分としてはワセリン、ラノリン等が、
液状油分としてはヒマシ油、オリーブ油、液状ラ
ノリン等の動植物系油分、流動パラフインに代表
される鉱物系油分、グリセリル−ジ−２−ヘプチ
ルウンデカノエート、トリメチロールプロパン−
トリ−２−ヘプチルウンデカノエート等の合成エ
ステル油分等が知られている。
これら従来用いられてきた油分を組合せて前述
のようにソフトな感触の口紅を得ようとすると単
純に固形油分を減らし、液状油分を増やすだけで
はできない種々の問題があつた。たとえば、ヒマ
シ油と各種ワツクスの組合せでは変臭、発汗等経
日安定性が悪くなり、流動パラフインと各種ワツ
クスの系では系全体の相溶性が悪く色縞を生じ易
くなつたり、唇へのあたりが硬くもろい感じでソ
フトで滑らかな感触とはなりにくかつた。また合
成エステル油と各種ワツクスとの系では一般に着
色剤、顔料とのなじみが悪く粉つぽい感触のもの
となつてしまう等である。また特定の系でソフト
なものが得られる場合があつてもさつぱりしすぎ
てフイツト感、もちに欠ける、唇のひだに入りこ
み輪郭がにじんで仕上り感が悪い。唇の荒れ防止
効果、リツチ感に欠ける等の欠点があつた。
本発明者らは上記従来技術の欠点を改良し、ソ
フトで滑らかな感触を有し、かつ唇へのフイツト
感、持ちが良く、唇の荒れを防ぎ潤いと艶を与
え、長期保存しても変臭、発汗等せず安定な口紅
を得るべく鋭意研究を重ねた結果、マカデミアナ
ツツ油を液状油分として使用する他成分との相溶
性も良くソフトな感触の口紅が得られることを見
い出し、さらにコレステリル−12−ヒドロキシス
テアレートを組み合せることにより唇へのフイツ
ト感に優れ、もちが良く、潤いと艶を与える等、
前述の目的が達成できることを見い出し本発明を
完成するに至つた。
すなわち本発明は、マカデミアナツツ油と、コ
レステリル−12−ヒドロキシステアレートとを配
合してなる口紅用組成物である。
次に本発明の構成について述べる。
マカデミアナツツ油はオーストラリア、ハワ
イ、アフリカ等で産するマカデミアナツツから圧
搾、溶媒抽出等の処理により得られる液状油であ
りその構成脂肪酸組成は、ミリスチン酸0.2〜１
％、パルミチン酸７〜10％、パルミトオレイン酸
20〜26.5％、ステアリン酸2.5〜3.8％、オレイン
酸54〜58％、リノール酸1.5〜2.8％、アラキジン
酸２〜３％、エイコセン酸２〜３％とからなり、
植物油としてはパルミトオレイン酸を特異的に多
く含んでいる酸化安定性に優れた低粘度油分であ
る。
本発明で配合されるマカデミアナツツ油は抽出
粗油でもよいが、常法により脱臭、脱色した精製
油が好ましく、またトコフエロール、BHT等の
酸化防止剤を0.002〜0.2％程度含有するものであ
つても良い。
本発明の実施にあたつて、マカデミアナツツ油
は組成物中10〜80％程度、好ましくは、25〜70％
程度配合される。10％以下では本発明の目的を達
成しにくく、80％以上では棒状口紅とはなりにく
い。
本発明に用いられるコレステリル−12−ヒドロ
キシステアレートは下記一般式で表わされるコレ
ステリンと12−ヒドロキシステアレートとのエス
テルで、モノ、ジ、トリ−12−ヒドロキシステア
〔式中ｎは１〜３の整数〕レートとのエステル混
合物として得られる。
本発明の実施にあたつては、エステル混合物の
まま配合して良く、あえて分離し単独配合する必
要はない。配合量は組成物中0.3〜15％程度であ
る。0.3％以下ではフイツト感、持ち等が劣り、
15％以上ではソフトで延びの良い口紅は得にく
く、べたついたものとなり、本発明の目的を達成
しにくくなる。
本発明の口紅用組成物には上記した必須成分の
他に、前述の固形油分、半固形油分、液状油分、
着色剤、保湿剤、香料、酸化防止剤、紫外線吸収
剤、水等通常用いられる原料が、本発明の効果を
損わない範囲で配合できる。
次にマカデミアナツツ油とコレステリル−12−
ヒドロキシステアレートの調製例について説明す
る。％は重量％である。
調製例１ マカデミアナツツ油
マカデミアナツツを圧搾抽出して得た油を24時
間静置し、水分とオリをデカンターにより除去し
た後過し清澄な油を得る。この油を真空下105
℃に加熱活性白土１％を添加し５分間脱色処理
し、更に温度を190℃に上げ水蒸気脱臭を２時間
行い無色、無臭の精製マカデミアナツツ油を得
た。このものの構成脂肪酸中パルミトオレイン酸
含量は23.8％であつた。
調製例２ コレステリル−12−ヒドロキシステア
レート
コレステリンと12−ヒドロキシステアリン酸の
モル比が１：12になるよう調製した試料を常法に
より触媒存在下でエステル化反応させた後触媒除
去、活性白土処理、水蒸気脱臭処理し過して微
黄色ペースト状のコレステリル−12−ヒドロキシ
ステアレートを得た。
得られたものの成分定量値は、コレステリル−
モノ−12−ヒドロキシステアレート40〜45％、コ
レステリル−ジ−12−ヒドロキシステアレート20
〜25％、コレステリル−トリ−12−ヒドロキシス
テアレート10〜15％、コレステリン10〜15％、ポ
リ−12−ヒドロキシステアレート５〜10％であつ
た。
次に実施例をあげて本発明の効果について述べ
る。
表１に示す処方、配合量にて口紅を製造した。
表中のマカデミアナツツ油およびコレステリル−
12−ヒドロキシステアレートは夫々調製例１およ
び２で得られたものを使用した。表中の数字は重
量％を表わす。
実施例１〜８、比較例１〜５
The present invention relates to a novel stick-shaped lipstick composition, which has a soft and smooth feeling when used, has a good fit on the lips, has good durability, and prevents chapped lips and provides moisture and shine. The purpose is to provide something. Generally, lipstick contains 10 to 40% by weight of solid and semi-solid oil (all percentages below are by weight), 50 to 90% of liquid oil,
It consists of a coloring agent of 1 to 20%, and the desired lipstick can be obtained by appropriately changing the blending amount within this prescription range. For example, if you are trying to obtain a lipstick with a soft feel, reduce the amount of solid oil, add semi-solid oil,
This will increase the amount of liquid oil. By the way, solid oils conventionally used in lipsticks include animal food waxes such as carnauba wax, candelilla wax, and beeswax, and hydrocarbon waxes such as solid paraffin, ceresin, and microcrystalline wax. , and semi-solid oils such as vaseline and lanolin,
Liquid oils include animal and vegetable oils such as castor oil, olive oil, and liquid lanolin, mineral oils such as liquid paraffin, glyceryl di-2-heptyl undecanoate, and trimethylolpropane.
Synthetic ester oils such as tri-2-heptyl undecanoate are known. When attempting to obtain a lipstick with a soft feel as described above by combining these conventionally used oils, various problems arose which could not be achieved by simply reducing the solid oil and increasing the liquid oil. For example, a combination of castor oil and various waxes will cause bad odor and sweating, resulting in poor stability over time, while a system of liquid paraffin and various waxes will have poor compatibility as a whole, resulting in color streaks, and may be difficult to touch on the lips. It felt hard and brittle, making it difficult to feel soft and smooth. Furthermore, systems containing synthetic ester oils and various waxes generally have poor compatibility with colorants and pigments, resulting in a powdery feel. Also, even if you can get a soft product with a certain type, it is too crisp and lacks a sense of fit and elasticity, and it gets into the folds of the lips and blurs the contours, giving a poor finish. It had drawbacks such as lack of effect on preventing chapped lips and lack of richness. The present inventors have improved the above-mentioned drawbacks of the prior art, and have created a product that has a soft and smooth feel, has a good fit on the lips, has good durability, prevents chapped lips, provides moisture and gloss, and can be stored for a long time. As a result of extensive research in order to obtain a stable lipstick that does not cause odor or sweating, we discovered that macadamia nut oil can be used as a liquid oil to create a lipstick that has good compatibility with other ingredients and has a soft feel. By combining cholesteryl-12-hydroxystearate, it provides an excellent fit to the lips, lasts well, and provides moisture and shine.
The present invention has been completed by discovering that the above object can be achieved. That is, the present invention is a lipstick composition comprising macadamia nut oil and cholesteryl-12-hydroxystearate. Next, the configuration of the present invention will be described. Macadamia nut oil is a liquid oil obtained from macadamia nuts grown in Australia, Hawaii, Africa, etc. through processes such as pressing and solvent extraction.The fatty acid composition is 0.2 to 1 of myristic acid.
%, palmitic acid 7-10%, palmitoleic acid
20-26.5%, stearic acid 2.5-3.8%, oleic acid 54-58%, linoleic acid 1.5-2.8%, arachidic acid 2-3%, eicosenoic acid 2-3%,
As a vegetable oil, it is a low-viscosity oil with excellent oxidation stability and specifically contains a large amount of palmitoleic acid. The macadamia nut oil blended in the present invention may be extracted crude oil, but it is preferably a refined oil that has been deodorized and decolored by conventional methods, and contains about 0.002 to 0.2% of antioxidants such as tocopherols and BHT. Also good. In carrying out the present invention, macadamia nut oil accounts for about 10 to 80% of the composition, preferably 25 to 70%.
It is mixed to some extent. If it is less than 10%, it is difficult to achieve the object of the present invention, and if it is more than 80%, it is difficult to obtain a stick-shaped lipstick. Cholesteryl-12-hydroxystearate used in the present invention is an ester of cholesterin and 12-hydroxystearate represented by the following general formula. [In the formula, n is an integer of 1 to 3] It is obtained as an ester mixture. In carrying out the present invention, the ester mixture may be blended as is, and there is no need to separate the esters and blend them individually. The blending amount is about 0.3 to 15% in the composition. If it is less than 0.3%, the fit and durability will be poor.
If it exceeds 15%, it is difficult to obtain a soft and spreadable lipstick, and the lipstick becomes sticky, making it difficult to achieve the object of the present invention. In addition to the above-mentioned essential ingredients, the lipstick composition of the present invention includes the above-mentioned solid oil, semi-solid oil, liquid oil,
Commonly used raw materials such as colorants, humectants, fragrances, antioxidants, ultraviolet absorbers, and water can be incorporated within the range that does not impair the effects of the present invention. Next, macadamia nut oil and cholesteryl-12-
An example of preparing hydroxystearate will be explained. % is by weight. Preparation Example 1 Macadamia nut oil The oil obtained by compressing and extracting macadamia nuts is allowed to stand for 24 hours, water and sludge are removed using a decanter, and then filtered to obtain a clear oil. This oil under vacuum 105
1% heat-activated clay was added to decolorize the mixture for 5 minutes, and the temperature was further raised to 190°C and steam deodorization was performed for 2 hours to obtain colorless and odorless refined macadamia nut oil. The palmitoleic acid content of this product among the constituent fatty acids was 23.8%. Preparation Example 2 Cholesteryl-12-hydroxystearate A sample prepared so that the molar ratio of cholesterin and 12-hydroxystearic acid was 1:12 was subjected to an esterification reaction in the presence of a catalyst by a conventional method, and then the catalyst was removed and activated clay After treatment and steam deodorization, cholesteryl-12-hydroxystearate in the form of a pale yellow paste was obtained. The quantitative values of the components obtained are cholesteryl-
Mono-12-hydroxystearate 40-45%, cholesteryl-di-12-hydroxystearate 20%
~25%, cholesteryl tri-12-hydroxystearate 10-15%, cholesterin 10-15%, and poly-12-hydroxystearate 5-10%. Next, the effects of the present invention will be described with reference to Examples. Lipsticks were manufactured using the formulations and amounts shown in Table 1.
Macadamia nut oil and cholesteryl in the table
The 12-hydroxystearates obtained in Preparation Examples 1 and 2 were used, respectively. The numbers in the table represent weight %. Examples 1-8, Comparative Examples 1-5
【表】 実施例１〜８、比較例１〜５【table】 Examples 1-8, Comparative Examples 1-5
【表】
（製造法）
実施例１は液状油分（液状ラノリン、マカデミ
アナツツ油、グリセリル−ジ−２−ヘプチルウン
デカノエート）中に固形油分（セレシン、カルナ
ウバロウ、キヤンデリラロウ）及びコレステリル
−12−ヒドロキシステアレートを加え90〜100℃
にて加熱溶解した後、あらかじめ液状油分の一部
で練つた顔料（雲母チタン、二酸化チタン、赤色
酸化鉄、黄色酸化鉄、黒色酸化鉄、赤色202号、
赤色204号）を加えてよく撹拌分散した後、脱気
し口紅成型器に流し込み冷却後、型からとり出し
て棒状口紅を得た。
実施例２〜８および比較例１〜５も実施例１と
同様にして製造した。
（試験法）
使用性：専門パネル10名により官能評価を行つ
た。評価項目は、なめらかなのび、適度な
フイツト感、しつとり感、油つぽさのな
さ、粉つぽさのなさ、の５項目である。
評価結果は下記の表示で表わすことにし
た。
◎：10名中８名以上が良好と回答した。
〇： 〃 ６名 〃 〃
△： 〃 ４名 〃 〃
×： 〃 ４名未満が 〃
酸化安定性：各試料を50℃に３ケ月間放置し、臭
いの変化を専門パネルが官能評価した。
〇：ほとんど変化なし。
×：油の焼けたような変臭があつた。
以上の項目についての評価結果を表２に示す。[Table] (Production method) Example 1 contains solid oils (ceresin, carnauba wax, candelilla wax) and cholesteryl-12-hydroxystear in liquid oils (liquid lanolin, macadamia nut oil, glyceryl-di-2-heptyl undecanoate). Add rate 90~100℃
Pigments (mica titanium, titanium dioxide, red iron oxide, yellow iron oxide, black iron oxide, red No. 202,
Red No. 204) was added and thoroughly stirred and dispersed, then degassed, poured into a lipstick molder, cooled, and taken out from the mold to obtain a stick-shaped lipstick. Examples 2 to 8 and Comparative Examples 1 to 5 were also produced in the same manner as Example 1. (Test method) Usability: Sensory evaluation was conducted by a panel of 10 experts. The evaluation items are 5 items: smooth spread, appropriate fit, moisturizing feeling, non-oily feeling, and non-powdering feeling. The evaluation results will be expressed as shown below. ◎: More than 8 out of 10 people answered that it was good. 〃: 〃 6 people 〃 〃 △: 〃 4 people 〃 〃 ×: 〃 Less than 4 people 〃 Oxidation stability: Each sample was left at 50°C for 3 months, and a specialized panel sensory-evaluated the change in odor. ○: Almost no change. ×: There was a strange odor like burnt oil. Table 2 shows the evaluation results for the above items.
【表】
表２からも明らかなように本発明に係る口紅用
組成物が使用性、酸化安定性共に良好であること
が確認された。
実施例 ９ （重量％）
固形パラフイン 2.0
ミクロクリスタリンワツクス 6.0
セレシン 3.0
キヤンデリラロウ 4.0
コレステリル−12−ヒドロキシステアレート
5.0
流動パラフイン 10.0
マカデミアナツツ油 61.98
顔 料 8.0
香 料 0.02
，の液状油分中に〜の固形、半固形油
分を加え、90〜100℃にて加熱溶解した後、を
加えて良く撹拌分散し、脱気した後これにを加
えて口紅成型器に流し込み、25〜20℃に冷却後、
型より取り出して棒状口紅を得た。
実施例 10 （重量％）
セレシン 7.0
ミクロクリスタリンワツクス 2.0
カルナウバロウ 1.0
キヤンデリラロウ 4.0
コレステリル−12−ヒドロキシステアレート
1.0
マカデミアナツツ油 78.0
ヒマシ油 2.0
顔 料 4.98
香 料 0.02
実施例９と同様の製法で棒状口紅を得た。[Table] As is clear from Table 2, it was confirmed that the lipstick composition according to the present invention has good usability and oxidation stability. Example 9 (% by weight) Solid paraffin 2.0 Microcrystalline wax 6.0 Ceresin 3.0 Candelilla wax 4.0 Cholesteryl-12-hydroxystearate
5.0 Liquid paraffin 10.0 Macadamia nut oil 61.98 Pigment 8.0 Fragrance 0.02 Add the solid or semi-solid oil from ~ to the liquid oil, heat and dissolve at 90~100°C, then add and stir well to disperse and desorb. After cooling, add this and pour into a lipstick molder, cool to 25-20℃,
It was removed from the mold to obtain a lipstick stick. Example 10 (% by weight) Ceresin 7.0 Microcrystalline wax 2.0 Carnauba wax 1.0 Candelilla wax 4.0 Cholesteryl-12-hydroxystearate
1.0 Macadamia nut oil 78.0 Castor oil 2.0 Pigment 4.98 Fragrance 0.02 A rod-shaped lipstick was obtained in the same manner as in Example 9.
Claims (1)
ヒドロキシステアレートとを配合してなる口紅用
組成物。1 Macadamia nut oil and cholesteryl-12-
A lipstick composition containing hydroxystearate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57137073A JPS5927808A (en) | 1982-08-06 | 1982-08-06 | Composition for lipstick |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57137073A JPS5927808A (en) | 1982-08-06 | 1982-08-06 | Composition for lipstick |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5927808A JPS5927808A (en) | 1984-02-14 |
| JPH025724B2 true JPH025724B2 (en) | 1990-02-05 |
Family
ID=15190265
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57137073A Granted JPS5927808A (en) | 1982-08-06 | 1982-08-06 | Composition for lipstick |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5927808A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59225105A (en) * | 1983-06-02 | 1984-12-18 | Shiseido Co Ltd | Emulsified composition |
| ES8800125A1 (en) * | 1985-03-13 | 1987-11-01 | Kao Corp | Solid cosmetic preparation. |
| JPS62129432A (en) * | 1985-11-29 | 1987-06-11 | 倉真木材株式会社 | Building method and laminated member for wall |
| JPH04108718A (en) * | 1990-08-28 | 1992-04-09 | Mikimoto Pharmaceut Co Ltd | Lipstick or lip-gloss |
| JPH071113U (en) * | 1993-12-28 | 1995-01-10 | 倉真木材株式会社 | Wall assembly |
-
1982
- 1982-08-06 JP JP57137073A patent/JPS5927808A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5927808A (en) | 1984-02-14 |
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