JPH0251905B2 - - Google Patents
Info
- Publication number
- JPH0251905B2 JPH0251905B2 JP57173378A JP17337882A JPH0251905B2 JP H0251905 B2 JPH0251905 B2 JP H0251905B2 JP 57173378 A JP57173378 A JP 57173378A JP 17337882 A JP17337882 A JP 17337882A JP H0251905 B2 JPH0251905 B2 JP H0251905B2
- Authority
- JP
- Japan
- Prior art keywords
- zone
- reaction
- isobutane
- mixture
- series
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 136
- 238000006243 chemical reaction Methods 0.000 claims description 71
- 239000001282 iso-butane Substances 0.000 claims description 68
- 239000011541 reaction mixture Substances 0.000 claims description 50
- 238000000034 method Methods 0.000 claims description 44
- 239000000203 mixture Substances 0.000 claims description 33
- 230000008569 process Effects 0.000 claims description 31
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 31
- 238000007254 oxidation reaction Methods 0.000 claims description 30
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 25
- 239000001301 oxygen Substances 0.000 claims description 25
- 229910052760 oxygen Inorganic materials 0.000 claims description 25
- 230000003647 oxidation Effects 0.000 claims description 20
- 238000004519 manufacturing process Methods 0.000 claims description 13
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 3
- 229910001882 dioxygen Inorganic materials 0.000 claims description 2
- 239000012071 phase Substances 0.000 description 23
- 239000000376 reactant Substances 0.000 description 16
- 239000000047 product Substances 0.000 description 10
- 238000002156 mixing Methods 0.000 description 7
- 230000008901 benefit Effects 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 239000012808 vapor phase Substances 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 3
- 238000005086 pumping Methods 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910000042 hydrogen bromide Inorganic materials 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
- B01J3/008—Processes carried out under supercritical conditions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/0004—Processes in series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00761—Details of the reactor
- B01J2219/00763—Baffles
- B01J2219/00765—Baffles attached to the reactor wall
- B01J2219/00777—Baffles attached to the reactor wall horizontal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/182—Details relating to the spatial orientation of the reactor horizontal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/308,629 US4408081A (en) | 1981-10-05 | 1981-10-05 | Process for oxidation of isobutane |
| US308629 | 1981-10-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5872557A JPS5872557A (ja) | 1983-04-30 |
| JPH0251905B2 true JPH0251905B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1990-11-08 |
Family
ID=23194740
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57173378A Granted JPS5872557A (ja) | 1981-10-05 | 1982-10-04 | 第３級ブチルハイドロパ−オキサイドの製造法 |
Country Status (5)
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5104493B1 (en) * | 1991-01-24 | 1995-08-15 | Arco Chem Tech | Tertiary butyl hydroperoxide concentration |
| US5149885A (en) * | 1992-02-20 | 1992-09-22 | Arco Chemical Technology, L.P. | Oxidation of isobutane to tertiary butyl hydroperoxide |
| US5243084A (en) * | 1992-04-22 | 1993-09-07 | Arco Chemical Technology, L.P. | Oxidation of isobutane to tertiary butyl hydroperoxide |
| US5196597A (en) * | 1992-04-22 | 1993-03-23 | Arco Chemical Technology, L.P. | Oxidation of isobutane to tertiary butyl hydroperoxide |
| US5243083A (en) * | 1992-07-24 | 1993-09-07 | Texaco Chemical Company | Thermosyphonic reaction of oxygen with isobutane and reactor |
| US5288919A (en) * | 1993-05-13 | 1994-02-22 | Arco Chemical Technology, L.P. | Preparation of dialkyl peroxides |
| US5430198A (en) * | 1993-11-08 | 1995-07-04 | Texaco Chemical Inc. | Diisopropyl ehter/MTBE cogeneration from crude by-product acetone |
| US5371298A (en) * | 1993-12-22 | 1994-12-06 | Arco Chemical Technology, L.P. | Preparation of dialkyl peroxides |
| US5475147A (en) * | 1994-10-19 | 1995-12-12 | Arco Chemical Technology, L.P. | Production of tertiary butyl hydroperoxide |
| CA2253215A1 (en) * | 1997-11-13 | 1999-05-13 | Shell Internationale Research Maatschappij B.V. | Process for preparing organic hydroperoxides |
| US6710192B2 (en) | 2001-10-16 | 2004-03-23 | Arco Chemical Technology, L.P. | Dense phase epoxidation |
| RU2209812C2 (ru) * | 2001-11-02 | 2003-08-10 | Открытое акционерное общество Научно-исследовательский институт "Ярсинтез" | Способ жидкофазного окисления углеводородов |
| US6936740B1 (en) | 2004-08-19 | 2005-08-30 | Arco Chemical Technology, L.P. | Dense phase oxidation of benzene |
| US9637424B1 (en) | 2014-12-16 | 2017-05-02 | Exxonmobil Research And Engineering Company | High octane gasoline and process for making same |
| WO2016099883A1 (en) | 2014-12-16 | 2016-06-23 | Exxonmobil Research And Engineering Company | Upgrading paraffins to distillates and lubricant basestocks |
| US10023533B2 (en) | 2014-12-16 | 2018-07-17 | Exxonmobil Research And Engineering Company | Process to produce paraffinic hydrocarbon fluids from light paraffins |
| US9637423B1 (en) | 2014-12-16 | 2017-05-02 | Exxonmobil Research And Engineering Company | Integrated process for making high-octane gasoline |
| EP3507273B1 (en) | 2016-10-12 | 2021-11-24 | Lyondell Chemical Technology, L.P. | Production of tert- butyl hydroperoxide solution and process to form products therefrom |
| WO2018118347A1 (en) | 2016-12-22 | 2018-06-28 | Exxonmobil Research And Engineering Company | Integrated process for making high-octane gasoline and high-cetane diesel |
| CA3045631A1 (en) | 2016-12-22 | 2018-06-28 | Exxonmobil Research And Engineering Company | A process for making high octane gasoline |
| WO2018203179A1 (en) | 2017-05-03 | 2018-11-08 | Sabic Global Technologies B.V. | Efficient production of mtbe, ethyl oxide, and ethylene glycol from isobutane, ethylene and oxygen feedstocks |
| WO2023059552A1 (en) | 2021-10-04 | 2023-04-13 | Lyondell Chemical Technology, L.P. | Systems and methods for removing or reducing water in mixtures that include t-butyl hydroperoxide |
| CN119707768B (zh) * | 2024-12-30 | 2025-07-01 | 常州瑞华化工工程技术股份有限公司 | 一种异丁烷氧化方法及系统 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2845461A (en) * | 1956-04-12 | 1958-07-29 | Shell Dev | Non-catalytic liquid phase isobutane oxidation |
| US3478108A (en) * | 1966-02-21 | 1969-11-11 | Atlantic Richfield Co | Isobutane oxidation |
| US3907902A (en) * | 1966-10-10 | 1975-09-23 | Atlantic Richfield Co | Method for the production of tertiary-butyl hydroperoxide |
| US3502740A (en) * | 1968-06-25 | 1970-03-24 | Atlantic Richfield Co | Production of isoprene |
| FR2082823A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1970-03-27 | 1971-12-10 | Raffinage Cie Francaise | |
| US3974228A (en) * | 1970-04-17 | 1976-08-10 | Petro-Tex Chemical Corporation | Preparation of hydroperoxides by autoxidation |
| US3816540A (en) * | 1971-05-24 | 1974-06-11 | Petro Tex Chem Corp | Preparation of hydro-peroxides by autoxidation |
| US4066706A (en) * | 1975-04-21 | 1978-01-03 | Halcon International, Inc. | Preparation of ethylbenzene hydroperoxide |
| US4128587A (en) * | 1976-11-26 | 1978-12-05 | Atlantic Richfield Company | Manufacture of tertiary butyl hydroperoxide |
-
1981
- 1981-10-05 US US06/308,629 patent/US4408081A/en not_active Expired - Lifetime
-
1982
- 1982-09-14 DE DE8282201135T patent/DE3273583D1/de not_active Expired
- 1982-09-14 EP EP82201135A patent/EP0076532B1/en not_active Expired
- 1982-09-22 CA CA000411968A patent/CA1248973A/en not_active Expired
- 1982-10-04 JP JP57173378A patent/JPS5872557A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| CA1248973A (en) | 1989-01-17 |
| EP0076532A1 (en) | 1983-04-13 |
| EP0076532B1 (en) | 1986-10-01 |
| DE3273583D1 (en) | 1986-11-06 |
| US4408081A (en) | 1983-10-04 |
| JPS5872557A (ja) | 1983-04-30 |
| US4408081B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1986-05-13 |
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