JPH0227295B2 - - Google Patents
Info
- Publication number
- JPH0227295B2 JPH0227295B2 JP63003656A JP365688A JPH0227295B2 JP H0227295 B2 JPH0227295 B2 JP H0227295B2 JP 63003656 A JP63003656 A JP 63003656A JP 365688 A JP365688 A JP 365688A JP H0227295 B2 JPH0227295 B2 JP H0227295B2
- Authority
- JP
- Japan
- Prior art keywords
- glass
- microbubbles
- metal oxide
- ratio
- examples
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011521 glass Substances 0.000 claims description 70
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 27
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 23
- 239000002245 particle Substances 0.000 claims description 22
- 239000000377 silicon dioxide Substances 0.000 claims description 13
- 229910018068 Li 2 O Inorganic materials 0.000 claims description 10
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims description 10
- 229910052681 coesite Inorganic materials 0.000 claims description 9
- 229910052906 cristobalite Inorganic materials 0.000 claims description 9
- 235000012239 silicon dioxide Nutrition 0.000 claims description 9
- 229910052682 stishovite Inorganic materials 0.000 claims description 9
- 229910052905 tridymite Inorganic materials 0.000 claims description 9
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 8
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 7
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 239000000203 mixture Substances 0.000 description 34
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 14
- 239000011734 sodium Substances 0.000 description 14
- 239000004604 Blowing Agent Substances 0.000 description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 7
- 238000007496 glass forming Methods 0.000 description 7
- 239000000395 magnesium oxide Substances 0.000 description 7
- 229910052717 sulfur Inorganic materials 0.000 description 7
- 239000011593 sulfur Substances 0.000 description 7
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000013049 sediment Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 238000005119 centrifugation Methods 0.000 description 4
- 238000004031 devitrification Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 239000011324 bead Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000010433 feldspar Substances 0.000 description 3
- 239000003345 natural gas Substances 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 235000019738 Limestone Nutrition 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 239000005388 borosilicate glass Substances 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 235000010216 calcium carbonate Nutrition 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 2
- 229910052808 lithium carbonate Inorganic materials 0.000 description 2
- 229910001947 lithium oxide Inorganic materials 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000006060 molten glass Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 229910052642 spodumene Inorganic materials 0.000 description 2
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- 229910004261 CaF 2 Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000007832 Na2SO4 Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 1
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 239000005350 fused silica glass Substances 0.000 description 1
- 239000006066 glass batch Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229910052611 pyroxene Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C11/00—Multi-cellular glass ; Porous or hollow glass or glass particles
- C03C11/002—Hollow glass particles
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US2637 | 1987-01-12 | ||
US07/002,637 US4767726A (en) | 1987-01-12 | 1987-01-12 | Glass microbubbles |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS63176338A JPS63176338A (ja) | 1988-07-20 |
JPH0227295B2 true JPH0227295B2 (US20100268047A1-20101021-C00003.png) | 1990-06-15 |
Family
ID=21701728
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP63003656A Granted JPS63176338A (ja) | 1987-01-12 | 1988-01-11 | マイクロバブル |
Country Status (8)
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007503997A (ja) * | 2003-05-16 | 2007-03-01 | ジェームズ ハーディー インターナショナル ファイナンス ベスローテン フェンノートシャップ | 低密度製品の製造方法 |
Families Citing this family (98)
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JP2927431B2 (ja) * | 1988-05-20 | 1999-07-28 | 富士通株式会社 | 加入者回路における遅延調整回路 |
US5002696A (en) * | 1988-08-01 | 1991-03-26 | Grefco, Inc. | Expanded mineral particles and apparatus and method of production |
US4983550A (en) * | 1988-08-24 | 1991-01-08 | Potters Industries, Inc. | Hollow glass spheres |
US5217928A (en) * | 1988-08-24 | 1993-06-08 | Potters Industries, Inc. | Hollow glass spheres |
US5064784A (en) * | 1989-04-18 | 1991-11-12 | Tokai Kogyo Co., Ltd. | Glass frit useful for the preparation of glass bubbles, and glass bubbles prepared by using it |
EP0500590B1 (en) * | 1989-11-17 | 1995-07-12 | Minnesota Mining And Manufacturing Company | Elastomeric laminates with microtextured skin layers |
US5354597A (en) * | 1990-03-30 | 1994-10-11 | Minnesota Mining And Manufacturing Company | Elastomeric tapes with microtextured skin layers |
US5344691A (en) * | 1990-03-30 | 1994-09-06 | Minnesota Mining And Manufacturing Company | Spatially modified elastic laminates |
US5429856A (en) * | 1990-03-30 | 1995-07-04 | Minnesota Mining And Manufacturing Company | Composite materials and process |
JP3021586B2 (ja) * | 1990-09-17 | 2000-03-15 | 富士通株式会社 | 低誘電率セラミック基板とグリーンシートの製造方法 |
US5069702A (en) * | 1990-12-20 | 1991-12-03 | W. R. Grace & Co.-Conn. | Method of making small hollow glass spheres |
AU701603B2 (en) * | 1994-04-25 | 1999-02-04 | Minnesota Mining And Manufacturing Company | Compositions comprising fused particulates and methods of making them |
US5773374A (en) * | 1995-04-24 | 1998-06-30 | Wood; Leigh E. | Composite materials and process |
US6045913A (en) * | 1995-11-01 | 2000-04-04 | Minnesota Mining And Manufacturing Company | At least partly fused particulates and methods of making them by flame fusion |
US6254981B1 (en) | 1995-11-02 | 2001-07-03 | Minnesota Mining & Manufacturing Company | Fused glassy particulates obtained by flame fusion |
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US2582852A (en) * | 1948-06-16 | 1952-01-15 | Pittsburgh Corning Corp | Method of making cellular glass of light color |
NL232500A (US20100268047A1-20101021-C00003.png) * | 1957-10-22 | |||
US3230064A (en) * | 1960-10-21 | 1966-01-18 | Standard Oil Co | Apparatus for spherulization of fusible particles |
DE1421921B2 (de) * | 1962-09-04 | 1972-05-10 | Ploche sklo n.p., Teplitz (Tschechoslowakei) | Verfahren zur unterdrueckung der nachteiligen rekristallisation von glaspulvern waehrend ihrer erhitzung |
US3365315A (en) * | 1963-08-23 | 1968-01-23 | Minnesota Mining & Mfg | Glass bubbles prepared by reheating solid glass partiles |
JPS4937565A (US20100268047A1-20101021-C00003.png) * | 1972-08-09 | 1974-04-08 | ||
US4391646A (en) * | 1982-02-25 | 1983-07-05 | Minnesota Mining And Manufacturing Company | Glass bubbles of increased collapse strength |
FR2566384B1 (fr) * | 1984-06-21 | 1986-09-05 | Saint Gobain Vitrage | Perfectionnements aux techniques de production de microspheres en verre |
-
1987
- 1987-01-12 US US07/002,637 patent/US4767726A/en not_active Expired - Lifetime
- 1987-11-09 CA CA000551376A patent/CA1270497A/en not_active Expired - Fee Related
- 1987-11-10 AU AU80965/87A patent/AU589819B2/en not_active Ceased
-
1988
- 1988-01-11 ZA ZA88159A patent/ZA88159B/xx unknown
- 1988-01-11 JP JP63003656A patent/JPS63176338A/ja active Granted
- 1988-01-12 EP EP88300228A patent/EP0276921B2/en not_active Expired - Lifetime
- 1988-01-12 ES ES88300228T patent/ES2032213T5/es not_active Expired - Lifetime
- 1988-01-12 DE DE8888300228T patent/DE3870266D1/de not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007503997A (ja) * | 2003-05-16 | 2007-03-01 | ジェームズ ハーディー インターナショナル ファイナンス ベスローテン フェンノートシャップ | 低密度製品の製造方法 |
Also Published As
Publication number | Publication date |
---|---|
ZA88159B (en) | 1989-09-27 |
EP0276921B2 (en) | 2000-10-04 |
ES2032213T5 (es) | 2000-12-01 |
AU589819B2 (en) | 1989-10-19 |
AU8096587A (en) | 1988-07-14 |
US4767726A (en) | 1988-08-30 |
ES2032213T3 (es) | 1993-01-16 |
JPS63176338A (ja) | 1988-07-20 |
DE3870266D1 (de) | 1992-05-27 |
EP0276921B1 (en) | 1992-04-22 |
EP0276921A1 (en) | 1988-08-03 |
CA1270497A (en) | 1990-06-19 |
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