JPH02264707A - Solid cosmetic - Google Patents
Solid cosmeticInfo
- Publication number
- JPH02264707A JPH02264707A JP8507889A JP8507889A JPH02264707A JP H02264707 A JPH02264707 A JP H02264707A JP 8507889 A JP8507889 A JP 8507889A JP 8507889 A JP8507889 A JP 8507889A JP H02264707 A JPH02264707 A JP H02264707A
- Authority
- JP
- Japan
- Prior art keywords
- storage stability
- transparency
- solid cosmetic
- liquid
- examples
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 18
- 239000007787 solid Substances 0.000 title claims abstract description 17
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 229940114072 12-hydroxystearic acid Drugs 0.000 claims abstract description 5
- 239000012530 fluid Substances 0.000 claims description 3
- 239000003921 oil Substances 0.000 abstract description 8
- 235000019198 oils Nutrition 0.000 abstract description 8
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 abstract description 4
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 229940057995 liquid paraffin Drugs 0.000 abstract description 3
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004006 olive oil Substances 0.000 abstract description 2
- 235000008390 olive oil Nutrition 0.000 abstract description 2
- 229940032094 squalane Drugs 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 8
- 238000002156 mixing Methods 0.000 description 5
- 230000001953 sensory effect Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- 239000007934 lip balm Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 244000062730 Melissa officinalis Species 0.000 description 1
- 235000010654 Melissa officinalis Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- HGKOWIQVWAQWDS-UHFFFAOYSA-N bis(16-methylheptadecyl) 2-hydroxybutanedioate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CC(O)C(=O)OCCCCCCCCCCCCCCCC(C)C HGKOWIQVWAQWDS-UHFFFAOYSA-N 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 239000008395 clarifying agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 239000000865 liniment Substances 0.000 description 1
- -1 lipstick Substances 0.000 description 1
- 229940105132 myristate Drugs 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、透明窓に優れ、しかも保存安定性。[Detailed description of the invention] [Industrial application field] The present invention has excellent transparent windows and storage stability.
官能特性（付着性、伸展性、持続性）が良好な固形化粧
料に関する。It relates to solid cosmetics with good organoleptic properties (adhesiveness, spreadability, persistence).
〔従来の技術及び発明が解決しようとする課題〕従来、
透明な化粧料といえばペースト状や液状のものが広く知
られており、固形のものとしては、固形化剤としてポリ
アミド樹脂、エステルガム等の樹脂類（高分子物質）を
配合したものがわずかにあるだけであった。（特公昭４
５−４１３１８号公報、特公昭５２−７０６７号公報、
特開昭６３−１１９４０５号公報参照）。しかし、これ
らの化粧料は、透明性、保存安定性５官能特性の点、特
に透明性の点で必ずしも満足のいくものではなかった。[Problems to be solved by conventional techniques and inventions] Conventionally,
When it comes to transparent cosmetics, paste and liquid types are widely known, and there are only a few solid ones that contain resins (polymer substances) such as polyamide resin and ester gum as solidifying agents. There was only that. (Tokuko Showa 4
Publication No. 5-41318, Japanese Patent Publication No. 52-7067,
(See Japanese Patent Application Laid-open No. 119405/1983). However, these cosmetics were not always satisfactory in terms of transparency, storage stability, and pentafunctional properties, especially in terms of transparency.
従って、保存安定性、官能特性に優れ、透明性の改善さ
れた固形化粧料が待ち望まれていた。Therefore, solid cosmetics with excellent storage stability, sensory properties, and improved transparency have been awaited.
本発明は、透明性、保存安定性、官能特性に優れた固形
化粧料を提供することを目的としている。An object of the present invention is to provide a solid cosmetic with excellent transparency, storage stability, and sensory characteristics.
本発明は、１２−ヒドロキシステアリン酸と重質流動イ
ソパラフィンと液状油性成分とを含有してなる固形化粧
料である。The present invention is a solid cosmetic containing 12-hydroxystearic acid, heavy fluid isoparaffin, and a liquid oily component.
本発明に使用する１２−ヒドロキシステアリン酸は、ヒ
マシ油に８０〜８５％含まれるリシノール酸を水素ガス
にて接触還元して得られる脂肪酸であって、白色の固く
て脆いロウ状の固体であり、市販品が使用できる。１２
〜ヒドロキシステアリン酸は透明固形化粧料の固形化剤
であって、そのゲルは粘着感（べたつき）が少なく、伸
展性が良好で、肌等への付着性に優れ、広い温度範囲に
わたって硬度変化が少なく、また透明性も良好である。12-Hydroxystearic acid used in the present invention is a fatty acid obtained by catalytic reduction of ricinoleic acid, which is contained in castor oil in an amount of 80 to 85%, with hydrogen gas, and is a white, hard and brittle waxy solid. , commercially available products can be used. 12
~Hydroxystearic acid is a solidifying agent for transparent solid cosmetics, and its gel has low stickiness, good extensibility, and excellent adhesion to the skin, and its hardness does not change over a wide temperature range. It also has good transparency.
その配合量は３．０〜１０．０重量％（以下、ｗｔ％と
略記する。）が好ましく、配合量が３ｗ ｔ％より少な
いと固形化しにくく、１０ｗｔ％より多いと透明性が低
下する。The blending amount is preferably 3.0 to 10.0% by weight (hereinafter abbreviated as wt%); if the blending amount is less than 3wt%, it will be difficult to solidify, and if it is more than 10wt%, the transparency will decrease.
本発明に使用する重質流動イソパラフィンは通常の流動
パラフィンとは異なり、イソブチンとｎブテンを共重合
して得られる側鎖を有する炭化水素の混合物である。そ
の重合度はｎ＝１０〜４６のものが好ましい。゛重質流
動イソパラフィンは透明化剤であって、その配合量は２
０．０〜６０、 Ｏｗ ｔ％が好ましく、配合量がこの
範囲外では強度、官能特性、透明性に劣るため好ましく
ない。The heavy liquid isoparaffin used in the present invention differs from ordinary liquid paraffin in that it is a mixture of hydrocarbons having side chains obtained by copolymerizing isobutene and n-butene. The degree of polymerization is preferably n=10 to 46.゛Heavy liquid isoparaffin is a clarifying agent, and its blending amount is 2
0.0 to 60 Owt% is preferable, and if the blending amount is outside this range, the strength, sensory properties, and transparency will be poor, so it is not preferable.
本発明に使用する液状油性成分は通常化粧料に配合され
る液状油性成分から選ばれた少なくとも１種以上が適用
される１例えば、オリーブ油、ホホバ油、スクワラン、
流動パラフィン、リシルイン酸オクチルドデシル、ミリ
スチン酸オクチルドデンル、リンゴ酸ジイソステアリル
、メチルフェニルポリシロキサン等のシリコン油等を挙
げることができる。その配合量は３０．０〜７０． Ｏ
ｗ ｔ％が好ましく、配合量がこの範囲外では強度、官
能特性、透明性、保存安定性に劣るため好ましくない。The liquid oily component used in the present invention is at least one selected from liquid oily components that are usually blended into cosmetics. For example, olive oil, jojoba oil, squalane,
Examples include silicone oils such as liquid paraffin, octyldodecyl lysylinate, octyldodenyl myristate, diisostearyl malate, and methylphenylpolysiloxane. Its blending amount is 30.0 to 70. O
Wt% is preferable, and if the amount is outside this range, strength, organoleptic properties, transparency, and storage stability will be poor, so it is not preferable.
本発明の固形化粧料には上記成分の他に、固形パラフィ
ンワックス、着色顔料１色素、抗酸化剤。In addition to the above ingredients, the solid cosmetic of the present invention contains solid paraffin wax, one coloring pigment, and an antioxidant.
防腐剤、香料等を本発明の目的を達成する範囲で適宜配
合することが可能である。Preservatives, fragrances, etc. can be added as appropriate within the range that achieves the purpose of the present invention.
本発明の固形化粧料の形態は固形状であれば特定するこ
となく広く各種化粧品基剤として利用でき、例えば口紅
、リップクリーム、ヘアースティック、サンスティック
、線香等が挙げられる。As long as the solid cosmetic of the present invention is in solid form, it can be widely used as a base for various cosmetics, such as lipstick, lip balm, hair stick, sun stick, incense stick, etc.
以下実施例及び比較例によって本発明を更に詳細に説明
する。尚、透明性、保存安定性、官能特性の評価方法に
ついては後記の通りである。The present invention will be explained in more detail below with reference to Examples and Comparative Examples. The methods for evaluating transparency, storage stability, and sensory characteristics are as described below.
（透明性試験）
光路長１０ｍｍｘ光路幅１０ｍｍのガラスセルに試料を
流し込み冷却固化させたものを分光光度針で可視部（４
００〜７００ｍｍ）の透過率を測定し、チャート面積に
て通過率の平均を算出し、下記の判断基準により評価し
た。(Transparency test) A sample was poured into a glass cell with an optical path length of 10 mm x an optical path width of 10 mm, and the sample was cooled and solidified.
00 to 700 mm) was measured, the average of the transmittance was calculated based on the chart area, and the evaluation was made according to the following criteria.
評 価 記号
透過率 ７０％以上 ０５０％以上
７０％未満 ０
３０％以上５０％未満 ６
３０％未満 ×
（保存安定性試験）
同一試料を５℃、４５℃の恒温槽に３ケ月間保存した後
、両者の経口に於ける匂い、外観く色）油のにじみの変
化を比較した。Evaluation Symbol transmittance 70% or more 0 50% or more and less than 70% 0 30% or more and less than 50% 6 Less than 30% × (Storage stability test) After storing the same sample in a thermostat at 5℃ and 45℃ for 3 months The changes in odor, appearance, color, and oil ooze during oral administration of the two were compared.
匂 い
評 価
記号全（同じ ◎ごくわ
ずかに酸敗臭を有する Ｏやや酸敗臭を有す
る Δ強く酸敗臭を有する
×外観（色）
評 価
記号全く同じ ◎ご（わ
ずかに着色
やや着色
強 （才１色
○
△
油のにじみ
評 価
記号全く同じ ＠ごくわ
ずかに油のにじみ Ｏやや油のにじみ
△強く油のにじみ
×判定結果は５℃の保存品と比較したとき
の４５℃の保存品の匂い５色、油のにじみの差を上記判
定基準により◎、○、Δ、×で示した。Odor evaluation
All symbols (same) ◎ Slightly rancid odor O Slightly rancid odor Δ Strongly rancid odor
×Appearance (color) Evaluation
Exactly the same symbol ◎ (Slightly colored, slightly colored) (1 color) △ Oil bleed evaluation
Exactly the same symbol ＠Very slight oil bleed O Slight oil bleed
△ Strong oil smear
The results of the × judgment were expressed as ◎, ◯, ∆, and × based on the above-mentioned criteria for the differences in the five odor colors and oil bleed of the product stored at 45°C when compared to the product stored at 5°C.
（官能特性試験）
２０名の女子被験者に比較例と実施例の試料を交互に２
回ずつ唇に塗布し、その直後のＵ付着性Ｊ「伸展性」「
持続性Ｊの評価項目を被験者本人が一対比較法で評価し
た。評価結果は上記の各評価項目に関して比較例より実
施例の方が良いと回答した者の数で示した。(Sensory property test) Samples of comparative example and example were alternately given to 20 female subjects.
Apply it to your lips once and immediately after that, apply it to your lips.
The evaluation items for persistence J were evaluated by the subjects themselves using the paired comparison method. The evaluation results are shown by the number of people who answered that the example was better than the comparative example regarding each of the above evaluation items.
実施例１〜６．比較例１〜２ 下記の処方の如〈実施例及び比較例のりラブダ リーム及び口紅を調製し、 前記諸試験を実施した。Examples 1-6. Comparative examples 1-2 As per the following formulation (Example and Comparative Example Nori Labda) Prepare cream and lipstick, The various tests mentioned above were conducted.
（調製法）
■ 実施例１〜６．比較例１
処方の全成分を９０℃で均一に溶解し、脱泡後８０〜８
５℃にて樹脂型に流し込み、冷却成型してリップクリー
ムを得た。(Preparation method) ■ Examples 1 to 6. Comparative Example 1 All components of the formulation were uniformly dissolved at 90°C, and after defoaming, the temperature was 80~8°C.
It was poured into a resin mold at 5° C., and cooled and molded to obtain a lip balm.
■ 比較例２
成分（１１，（２）、 １８）を１１０℃にて加熱溶解
した後、６０℃まで冷却し、これに成分＋３１ ％ （
７１を加え均一に溶解し、脱泡後６０℃にて樹脂型に沃
し込み、冷却成型して口紅を得た。■ Comparative Example 2 Components (11, (2), 18) were heated and dissolved at 110°C, then cooled to 60°C, and the components +31% (
71 was added and uniformly dissolved, and after defoaming, it was injected into a resin mold at 60°C, and cooled and molded to obtain a lipstick.
（特性） 諸試験の結果を第１表に示した。(Characteristic) The results of various tests are shown in Table 1.
第１表から明らかな如く、実施例１〜６のリップクリー
ムは諸試験に於いて優れた結果を示した。As is clear from Table 1, the lip balms of Examples 1 to 6 showed excellent results in various tests.
一方、本発明の必須成分である重質流動イソパラフィン
を欠いた比較例１や特開昭６３＝１１９４０５号公報の
実施例に記載の処方により調製した比較例２は、透明性
も保存安定性も悪く、官能特性に於いても本発明実施例
の方が優れてぃ（発明の効果〕
以上記載のごとく、本発明は透明性に優れ、しかも保存
安定性、官能特性−が良好な固形化粧料を提供すること
は明らかである。On the other hand, Comparative Example 1 lacking heavy fluid isoparaffin, which is an essential component of the present invention, and Comparative Example 2 prepared using the formulation described in the example of JP-A-63-119405 had neither transparency nor storage stability. However, the examples of the present invention are superior in terms of organoleptic properties (effects of the invention) As described above, the present invention provides solid cosmetics with excellent transparency, storage stability, and organoleptic properties. It is clear that the
手続補正書
１．事件の表示
平成 １年特許願第８５０７８号
２、発明の名称
固形化粧料
３、補正をする者
事件との関係 特許出願人
住所 東京都墨田区墨田五丁目１７番４号〒５３４ 大
阪市部島区友淵町−丁目５番９０号鐘紡株式会社特許部
電話 （０６）９２１−１２５１
５、補正の対象
明細書
６、補正の内容
（１）明細書第６頁第２０行目にｒ実施例１〜６Ｊとあ
るを、ｒ実施例１〜８ｊと訂正する。Procedural amendment 1. Display of the case 1999 Patent Application No. 85078 2, Name of the invention Solid cosmetics 3, Person making the amendment Relationship to the case Patent applicant address 5-17-4 Sumida, Sumida-ku, Tokyo 534 Bejima, Osaka City 5-90 Tomobuchi-cho-ku Kanebo Co., Ltd. Patent Department Telephone (06) 921-1251 5. Specification subject to amendment 6, Contents of amendment (1) Example r on page 6, line 20 of the specification 1 to 6J is corrected to r Examples 1 to 8j.
（２）明細書第８頁の処方を別紙の通り訂正する。(2) The prescription on page 8 of the specification is corrected as shown in the attached sheet.
（３）明細書第９頁第１３行目にｒ実施例１〜６」とあ
るを、ｒ実施例１〜８１と訂正する。(3) On page 9, line 13 of the specification, the text "r Examples 1 to 6" is corrected to r Examples 1 to 81.
（４）明細書第１０頁第４行目にｒ実施例１〜６Ｊとあ
るを、ｒ実施例１〜８」と訂正する。(4) In the fourth line of page 10 of the specification, the text "r Examples 1 to 6J" is corrected to "r Examples 1 to 8."
（５）明細書第１１頁の第１表を別紙の通り訂正する。(5) Table 1 on page 11 of the specification is corrected as shown in the attached sheet.
７、添付書類の目録 （１）別紙（明細書第８頁及び第１１頁） 各１通以上7. List of attached documents (1) Attachment (page 8 and page 11 of specification) At least one copy each
Claims (1)
ンと液状油性成分とを含有してなる固形化粧料A solid cosmetic containing 12-hydroxystearic acid, heavy fluid isoparaffin, and a liquid oily component.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8507889A JP2791093B2 (en) | 1989-04-03 | 1989-04-03 | Solid cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8507889A JP2791093B2 (en) | 1989-04-03 | 1989-04-03 | Solid cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02264707A true JPH02264707A (en) | 1990-10-29 |
| JP2791093B2 JP2791093B2 (en) | 1998-08-27 |
Family
ID=13848586
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8507889A Expired - Lifetime JP2791093B2 (en) | 1989-04-03 | 1989-04-03 | Solid cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2791093B2 (en) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5429816A (en) * | 1992-05-12 | 1995-07-04 | Procter & Gamble | Antiperspirant gel stick compositions |
| US5607972A (en) * | 1994-08-08 | 1997-03-04 | The Procter & Gamble Company | Gelling compositions comprising optically enriched gellants |
| US5733534A (en) * | 1993-04-27 | 1998-03-31 | The Procter & Gamble Company | Antiperspirant stick compositions exhibiting improved wash-off performance |
| US5744130A (en) * | 1996-12-20 | 1998-04-28 | The Procter & Gamble Company | Antiperspirant gel-solid stick compositions substantially free of select polar solvents |
| US5750096A (en) * | 1996-12-20 | 1998-05-12 | The Procter & Gamble Company | Low residue antiperspirant gel-solid stick compositions containing select gellants |
| US5776494A (en) * | 1996-12-20 | 1998-07-07 | The Procter & Gamble Company | Pharmaceuticals compositions containing gellants in the form of alkyl amides of di-and tri-carboxylic acids |
| US5840286A (en) * | 1996-12-20 | 1998-11-24 | Procter & Gamble Company | Methods of making low residue antiperspirant gel-solid stick compositions |
| US5840287A (en) * | 1996-12-20 | 1998-11-24 | Procter & Gamble Company | Antiperspirant compositions containing gellants in the form of alkyl amides of di- and tri-carboxylic acids |
| US5840288A (en) * | 1996-12-20 | 1998-11-24 | Procter & Gamble Company | Antiperspirant gel-solid stick composition containing a modified silicone carrier |
| US5846520A (en) * | 1996-12-20 | 1998-12-08 | Procter & Gamble Company | Antiperspirant gel-solid stick compositions containing select fatty acid gellants |
| US5849276A (en) * | 1996-12-20 | 1998-12-15 | Procter & Gamble | Antiperspirant gel-solid stick compositions containing select nucleating agents |
| EP1044674A2 (en) * | 1999-04-14 | 2000-10-18 | Shiseido Company Limited | Composition for lip rouge |
| US6171601B1 (en) | 1996-12-20 | 2001-01-09 | The Procter & Gamble Company | Low residue antiperspirant gel-solid stick compositions |
| US6190673B1 (en) | 1996-12-20 | 2001-02-20 | The Procter & Gamble Company | Gel compositions containing gellants in the form of alkyl amides of tri-carboxylic acids |
| JP2007320871A (en) * | 2006-05-31 | 2007-12-13 | Mandom Corp | Composition for hair-care |
| JP2010260795A (en) * | 2009-04-30 | 2010-11-18 | Pola Chem Ind Inc | Oil gel cosmetic |
| JP2016164140A (en) * | 2015-02-26 | 2016-09-08 | 株式会社コーセー | Oily solid cosmetics |
| WO2018030326A1 (en) | 2016-08-08 | 2018-02-15 | 株式会社 資生堂 | Transparent solid composition |
| WO2018198800A1 (en) | 2017-04-26 | 2018-11-01 | 株式会社 資生堂 | Transparent composition and transparent cosmetic |
-
1989
- 1989-04-03 JP JP8507889A patent/JP2791093B2/en not_active Expired - Lifetime
Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5429816A (en) * | 1992-05-12 | 1995-07-04 | Procter & Gamble | Antiperspirant gel stick compositions |
| US5733534A (en) * | 1993-04-27 | 1998-03-31 | The Procter & Gamble Company | Antiperspirant stick compositions exhibiting improved wash-off performance |
| US5607972A (en) * | 1994-08-08 | 1997-03-04 | The Procter & Gamble Company | Gelling compositions comprising optically enriched gellants |
| US5641476A (en) * | 1994-08-08 | 1997-06-24 | The Procter & Gamble Company | Gelling compositions comprising optically enriched gellants |
| US5776494A (en) * | 1996-12-20 | 1998-07-07 | The Procter & Gamble Company | Pharmaceuticals compositions containing gellants in the form of alkyl amides of di-and tri-carboxylic acids |
| US5750096A (en) * | 1996-12-20 | 1998-05-12 | The Procter & Gamble Company | Low residue antiperspirant gel-solid stick compositions containing select gellants |
| US6190673B1 (en) | 1996-12-20 | 2001-02-20 | The Procter & Gamble Company | Gel compositions containing gellants in the form of alkyl amides of tri-carboxylic acids |
| US5840286A (en) * | 1996-12-20 | 1998-11-24 | Procter & Gamble Company | Methods of making low residue antiperspirant gel-solid stick compositions |
| US5840287A (en) * | 1996-12-20 | 1998-11-24 | Procter & Gamble Company | Antiperspirant compositions containing gellants in the form of alkyl amides of di- and tri-carboxylic acids |
| US5840288A (en) * | 1996-12-20 | 1998-11-24 | Procter & Gamble Company | Antiperspirant gel-solid stick composition containing a modified silicone carrier |
| US5846520A (en) * | 1996-12-20 | 1998-12-08 | Procter & Gamble Company | Antiperspirant gel-solid stick compositions containing select fatty acid gellants |
| US5849276A (en) * | 1996-12-20 | 1998-12-15 | Procter & Gamble | Antiperspirant gel-solid stick compositions containing select nucleating agents |
| US5744130A (en) * | 1996-12-20 | 1998-04-28 | The Procter & Gamble Company | Antiperspirant gel-solid stick compositions substantially free of select polar solvents |
| US6171601B1 (en) | 1996-12-20 | 2001-01-09 | The Procter & Gamble Company | Low residue antiperspirant gel-solid stick compositions |
| EP1044674A2 (en) * | 1999-04-14 | 2000-10-18 | Shiseido Company Limited | Composition for lip rouge |
| EP1044674A3 (en) * | 1999-04-14 | 2002-10-23 | Shiseido Company Limited | Composition for lip rouge |
| JP2007320871A (en) * | 2006-05-31 | 2007-12-13 | Mandom Corp | Composition for hair-care |
| JP2010260795A (en) * | 2009-04-30 | 2010-11-18 | Pola Chem Ind Inc | Oil gel cosmetic |
| JP2016164140A (en) * | 2015-02-26 | 2016-09-08 | 株式会社コーセー | Oily solid cosmetics |
| WO2018030326A1 (en) | 2016-08-08 | 2018-02-15 | 株式会社 資生堂 | Transparent solid composition |
| CN109562035A (en) * | 2016-08-08 | 2019-04-02 | 株式会社资生堂 | Transparent solid composition |
| KR20190035698A (en) | 2016-08-08 | 2019-04-03 | 가부시키가이샤 시세이도 | Transparent solid composition |
| US11123269B2 (en) | 2016-08-08 | 2021-09-21 | Shiseido Company, Ltd. | Transparent solid composition |
| WO2018198800A1 (en) | 2017-04-26 | 2018-11-01 | 株式会社 資生堂 | Transparent composition and transparent cosmetic |
| KR20190136046A (en) | 2017-04-26 | 2019-12-09 | 가부시키가이샤 시세이도 | Transparent composition and transparent cosmetic |
| US11413234B2 (en) | 2017-04-26 | 2022-08-16 | Shiseido Company, Ltd. | Transparent composition and transparent cosmetic |
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|---|---|
| JP2791093B2 (en) | 1998-08-27 |
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