JP2791093B2 - Solid cosmetics - Google Patents
Solid cosmeticsInfo
- Publication number
- JP2791093B2 JP2791093B2 JP8507889A JP8507889A JP2791093B2 JP 2791093 B2 JP2791093 B2 JP 2791093B2 JP 8507889 A JP8507889 A JP 8507889A JP 8507889 A JP8507889 A JP 8507889A JP 2791093 B2 JP2791093 B2 JP 2791093B2
- Authority
- JP
- Japan
- Prior art keywords
- transparency
- present
- examples
- oil
- solid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- Cosmetics (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、透明感に優れ、しかも保存安定性,官能特
性(付着性,伸展性,持続性)が良好な固形化粧料に関
する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a solid cosmetic having excellent transparency and excellent storage stability and organoleptic properties (adhesiveness, extensibility, and sustainability).
従来、透明な化粧料といえばペースト状や液状のもの
が広く知られており、固形のものとしては、固形化剤と
してポリアミド樹脂、エステルガム等の樹脂類(高分子
物質)を配合したものがわずかにあるだけであった。
(特公昭45−41318号公報,特公昭52−7067号公報,特
開昭63−119405号公報参照)。しかし、これらの化粧料
は、透明性,保存安定性,官能特性の点、特に透明性の
点で必ずしも満足のいくものではなかった。Conventionally, transparent cosmetics are widely known in the form of pastes or liquids. Solid products include those containing resins (polymeric substances) such as polyamide resins and ester gums as solidifying agents. There were only a few.
(See JP-B-45-41318, JP-B-52-7067, and JP-A-63-119405). However, these cosmetics are not always satisfactory in terms of transparency, storage stability, and organoleptic properties, particularly transparency.
従って、保存安定性,官能特性に優れ、透明性の改善
された固形化粧料が待ち望まれていた。Therefore, there has been a long-awaited need for a solid cosmetic having excellent storage stability and organoleptic properties and improved transparency.
本発明は、透明性,保存安定性,官能特性に優れた固
形化粧料を提供することを目的としている。An object of the present invention is to provide a solid cosmetic having excellent transparency, storage stability, and organoleptic properties.
本発明は、12−ヒドロキシステアリン酸と重質流動イ
ソパラフィンと液状油性成分とを含有してなる固形化粧
料である。The present invention is a solid cosmetic comprising 12-hydroxystearic acid, heavy liquid isoparaffin, and a liquid oil component.
本発明に使用する12−ヒドロキシステアリン酸は、ヒ
マシ油に80〜85%含まれるリシノール酸を水素ガスにて
接触還元して得られる脂肪酸であって、白色の固くて脆
いロウ状の固体であり、市販品が使用できる。12−ヒド
ロキシステアリン酸は透明固形化粧料の固形化剤であっ
て、そのゲルは粘着感(べたつき)が少なく、伸展性が
良好で、肌等への付着性に優れ、広い温度範囲にわたっ
て硬度変化が少なく、また透明性も良好である。その配
合量は3.0〜10.0重量%(以下、wt%と略記する。)が
好ましく、配合量が3wt%より少ないと固形化しにく
く、10wt%より多いと透明性が低下する。12-Hydroxystearic acid used in the present invention is a fatty acid obtained by catalytic reduction of ricinoleic acid contained in castor oil by 80 to 85% with hydrogen gas, and is a white hard and brittle waxy solid. And commercial products can be used. 12-Hydroxystearic acid is a solidifying agent for transparent solid cosmetics, and its gel has low stickiness (stickiness), good extensibility, excellent adhesion to skin, etc., and changes in hardness over a wide temperature range. And the transparency is good. The compounding amount is preferably 3.0 to 10.0% by weight (hereinafter abbreviated as wt%). If the compounding amount is less than 3% by weight, it is difficult to solidify, and if it is more than 10% by weight, the transparency is reduced.
本発明に使用する重質流動イソパラフィンは通常の流
動パラフィンとは異なり、イソブテンとn−ブテンを共
重合して得られる側鎖を有する炭化水素の混合物であ
る。その重合度はn=10〜46のものが好ましい。重質流
動イソパラフィンは透明化剤であって、その配合量は2
0.0〜60.0wt%が好ましく、配合量がこの範囲外では強
度,官能特性,透明性に劣るため好ましくない。The heavy liquid isoparaffin used in the present invention is different from ordinary liquid paraffin and is a mixture of hydrocarbons having a side chain obtained by copolymerizing isobutene and n-butene. The polymerization degree is preferably n = 10 to 46. Heavy liquid isoparaffin is a clarifying agent, and its compounding amount is 2
The content is preferably 0.0 to 60.0% by weight, and if the amount is out of this range, strength, sensory characteristics, and transparency are unfavorably poor.
本発明に使用する液状油性成分は通常化粧料に配合さ
れる液状油性成分から選ばれた少なくとも1種以上が適
用される、例えば、オリーブ油,ホホバ油,スクワラ
ン,流動パラフィン,リシノレイン酸オクチルドデシ
ル,ミリスチン酸オクチルドデシル,リンゴ酸ジイソス
テアリル,メチルフェニルポリシロキサン等のシリコン
油等を挙げることができる。その配合量は30.0〜70.0wt
%が好ましく、配合量がこの範囲外では強度,官能特
性,透明性,保存安定性に劣るため好ましくない。As the liquid oily component used in the present invention, at least one selected from liquid oily components usually added to cosmetics is applied. For example, olive oil, jojoba oil, squalane, liquid paraffin, octyldodecyl ricinoleate, myristin Silicon oils such as octyldodecyl acid, diisostearyl malate, methylphenylpolysiloxane and the like can be mentioned. The compounding amount is 30.0 ~ 70.0wt
% Is preferable, and when the amount is outside this range, strength, sensory characteristics, transparency, and storage stability are inferior.
本発明の固形化粧料には上記成分の他に、固形パラフ
ィンワックス,着色顔料,色素,抗酸化剤,防腐剤,香
料等を本発明の目的を達成する範囲で適宜配合すること
が可能である。In addition to the above-mentioned components, the solid cosmetic of the present invention can appropriately contain a solid paraffin wax, a coloring pigment, a coloring matter, an antioxidant, a preservative, a fragrance, and the like as long as the object of the present invention is achieved. .
本発明の固形化粧料の形態は固形状であれば特定する
ことなく広く各種化粧品基剤として利用でき、例えば口
紅,リップクリーム,ヘアースティック,サンスティッ
ク,練香等が挙げられる。The form of the solid cosmetic of the present invention can be widely used as various cosmetic bases without any particular limitation as long as it is solid, and examples thereof include lipstick, lip balm, hair stick, sun stick, and condensate.
以下実施例及び比較例によって本発明を更に詳細に説
明する。尚、透明性,保存安定性,官能特性の評価方法
については後記の通りである。Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples. The methods for evaluating the transparency, storage stability, and sensory characteristics are as described below.
(透明性試験) 光路長10mm×光路幅10mmのガラスセルに試料を流し込
み冷却固化させたものを分光光度計で可視部(400〜700
mm)の透過率を測定し、チャート面積にて透過率の平均
を算出し、下記の判断基準により評価した。(Transparency test) A sample was poured into a glass cell with an optical path length of 10 mm and an optical path width of 10 mm, and was cooled and solidified.
mm), the average of the transmittances was calculated based on the chart area, and evaluated according to the following criteria.
評 価 記号 透過率 70%以上 ◎ 〃 50%以上70%未満 ○ 〃 30%以上50%未満 △ 〃 30%未満 × (保存安定性試験) 同一試料を5℃,45℃の恒温槽に3ヶ月間保存した
後、両者の経日に於ける匂い,外観(色),油のにじみ
の変化を比較した。Evaluation symbol Transmittance 70% or more ◎ 〃 50% or more and less than 70% ○ 〃 30% or more and less than 50% △ 未 満 Less than 30% × (Storage stability test) The same sample is stored in a thermostat at 5 ℃ and 45 ℃ for 3 months After storage for a while, the changes in odor, appearance (color), and oil bleeding over time were compared.
匂い 評 価 記号 全く同じ ◎ ごくわずかに酸敗臭を有する ○ やや酸敗臭を有する △ 強く酸敗臭を有する × 外観(色) 評 価 記号 全く同じ ◎ ごくわずかに着色 ○ やや着色 △ 強く着色 × 油のにじみ 評 価 記号 全く同じ ◎ ごくわずかに油のにじみ ○ やや油のにじみ △ 強く油のにじみ × 判定結果は5℃の保存品と比較したときの45℃の保存
品の匂い,色,油のにじみの差を上記判定基準により
◎,○,△,×で示した。Odor evaluation symbol Exactly the same ◎ Very slight rancidity ○ Slightly rancidity △ Strong rancidity × Appearance (color) Evaluation symbol Exactly the same ◎ Very slightly colored ○ Slightly colored △ Strongly colored × Oil Bleeding evaluation symbol Exactly the same ◎ Very slightly bleeding of oil ○ Slightly bleeding of oil △ Strongly bleeding of oil × Judgment result is smell, color, and bleeding of oil at 45 ° C when compared with stored at 5 ° C Are indicated by ◎, △, Δ, and × according to the above criteria.
(官能特性試験) 20名の女子被験者に比較例と実施例の試料を交互に2
回ずつ唇に塗布し、その直後の「付着性」「伸展性」
「持続性」の評価項目を被験者本人が一対比較法で評価
した。評価結果は上記の各評価項目に関して比較例より
実施例の方が良いと回答した者の数で示した。(Sensory Characteristic Test) Samples of Comparative Example and Example were alternately applied to 20 female subjects.
Apply to the lips each time, immediately afterwards "adhesiveness""extensibility"
The subject of the evaluation of "sustainability" was evaluated by the paired comparison method. The evaluation results are shown in terms of the number of those who answered that the examples were better than the comparative examples for each of the above evaluation items.
実施例1〜8,比較例1〜2 下記の処方の如く実施例及び比較例のリップクリーム
及び口紅を調製し、前記諸試験を実施した。その結果を
第1表に示した。Examples 1 to 8 and Comparative Examples 1 and 2 Lip lip balms and lipsticks of Examples and Comparative Examples were prepared according to the following formulations, and the above-mentioned tests were carried out. The results are shown in Table 1.
(調製法) 実施例1〜8,比較例1 処方の全成分を90℃で均一に溶解し、脱泡後80〜85℃
にて樹脂型に流し込み、冷却成型してリップクリームを
得た。 (Preparation method) Examples 1 to 8, Comparative Example 1 All components of the formulation were uniformly dissolved at 90 ° C, and after defoaming, 80 to 85 ° C
The mixture was poured into a resin mold and cooled and molded to obtain a lip balm.
比較例2 成分(1),(2),(8)を110℃にて加熱溶解し
た後、60℃まで冷却し、これに成分(3)〜(7)を加
え均一に溶解し、脱泡後60℃にて樹脂型に流し込み、冷
却成型して口紅を得た。Comparative Example 2 Components (1), (2), and (8) were heated and dissolved at 110 ° C., then cooled to 60 ° C., and components (3) to (7) were added thereto, uniformly dissolved, and defoamed. Thereafter, the mixture was poured into a resin mold at 60 ° C. and cooled and molded to obtain a lipstick.
(特性) 諸試験の結果を第1表に示した。(Characteristics) The results of various tests are shown in Table 1.
第1表から明らかな如く、実施例1〜8のリップクリ
ームは諸試験に於いて優れた結果を示した。As is clear from Table 1, the lip balms of Examples 1 to 8 showed excellent results in various tests.
一方、本発明の必須成分である重質流動イソパラフィ
ンを欠いた比較例1や特開昭63−119405号公報の実施例
に記載の処方により調製した比較例2は、透明性も保存
安定性も悪く、官能特性に於いても本発明実施例の方が
優れていた。On the other hand, Comparative Example 1 lacking the heavy liquid isoparaffin, which is an essential component of the present invention, and Comparative Example 2 prepared by the formulation described in Examples of JP-A-63-119405 have both transparency and storage stability. The examples of the present invention were also poor in sensory characteristics.
〔発明の効果〕 以上記載のごとく、本発明は透明性に優れ、しかも保
存安定性,官能特性が良好な固形化粧料を提供すること
は明らかである。 [Effects of the Invention] As described above, it is apparent that the present invention provides a solid cosmetic having excellent transparency, storage stability and organoleptic properties.
Claims (1)
ソパラフィンと液状油性成分とを含有してなる固形化粧
料1. A solid cosmetic comprising 12-hydroxystearic acid, heavy liquid isoparaffin, and a liquid oil component.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8507889A JP2791093B2 (en) | 1989-04-03 | 1989-04-03 | Solid cosmetics |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8507889A JP2791093B2 (en) | 1989-04-03 | 1989-04-03 | Solid cosmetics |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH02264707A JPH02264707A (en) | 1990-10-29 |
JP2791093B2 true JP2791093B2 (en) | 1998-08-27 |
Family
ID=13848586
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8507889A Expired - Lifetime JP2791093B2 (en) | 1989-04-03 | 1989-04-03 | Solid cosmetics |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2791093B2 (en) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993023008A1 (en) * | 1992-05-12 | 1993-11-25 | The Procter & Gamble Company | Antiperspirant gel stick composition |
ES2105704T3 (en) * | 1993-04-27 | 1997-10-16 | Procter & Gamble | ANTI-TRANSPIRATIONAL COMPOSITIONS IN BAR THAT PRESENT IMPROVED PROPERTIES OF ELIMINATION BY WASHING. |
US5607972A (en) * | 1994-08-08 | 1997-03-04 | The Procter & Gamble Company | Gelling compositions comprising optically enriched gellants |
US5849276A (en) * | 1996-12-20 | 1998-12-15 | Procter & Gamble | Antiperspirant gel-solid stick compositions containing select nucleating agents |
US5846520A (en) * | 1996-12-20 | 1998-12-08 | Procter & Gamble Company | Antiperspirant gel-solid stick compositions containing select fatty acid gellants |
US5840288A (en) * | 1996-12-20 | 1998-11-24 | Procter & Gamble Company | Antiperspirant gel-solid stick composition containing a modified silicone carrier |
US5744130A (en) * | 1996-12-20 | 1998-04-28 | The Procter & Gamble Company | Antiperspirant gel-solid stick compositions substantially free of select polar solvents |
US5776494A (en) * | 1996-12-20 | 1998-07-07 | The Procter & Gamble Company | Pharmaceuticals compositions containing gellants in the form of alkyl amides of di-and tri-carboxylic acids |
US5840287A (en) * | 1996-12-20 | 1998-11-24 | Procter & Gamble Company | Antiperspirant compositions containing gellants in the form of alkyl amides of di- and tri-carboxylic acids |
US5840286A (en) * | 1996-12-20 | 1998-11-24 | Procter & Gamble Company | Methods of making low residue antiperspirant gel-solid stick compositions |
US6190673B1 (en) | 1996-12-20 | 2001-02-20 | The Procter & Gamble Company | Gel compositions containing gellants in the form of alkyl amides of tri-carboxylic acids |
US5750096A (en) * | 1996-12-20 | 1998-05-12 | The Procter & Gamble Company | Low residue antiperspirant gel-solid stick compositions containing select gellants |
US6171601B1 (en) | 1996-12-20 | 2001-01-09 | The Procter & Gamble Company | Low residue antiperspirant gel-solid stick compositions |
US6325996B1 (en) * | 1999-04-14 | 2001-12-04 | Shiseido Co., Ltd. | Composition for lip rouge |
JP4987356B2 (en) * | 2006-05-31 | 2012-07-25 | 株式会社マンダム | Hair care composition |
JP5855330B2 (en) * | 2009-04-30 | 2016-02-09 | ポーラ化成工業株式会社 | Oil gel cosmetics |
JP6683486B2 (en) * | 2015-02-26 | 2020-04-22 | 株式会社コーセー | Oily solid cosmetics |
CN109562035A (en) * | 2016-08-08 | 2019-04-02 | 株式会社资生堂 | Transparent solid composition |
JP7320914B2 (en) | 2017-04-26 | 2023-08-04 | 株式会社 資生堂 | Transparent composition and transparent cosmetic |
-
1989
- 1989-04-03 JP JP8507889A patent/JP2791093B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPH02264707A (en) | 1990-10-29 |
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