JPH0491010A - Transparent solid cosmetic - Google Patents
Transparent solid cosmeticInfo
- Publication number
- JPH0491010A JPH0491010A JP20954390A JP20954390A JPH0491010A JP H0491010 A JPH0491010 A JP H0491010A JP 20954390 A JP20954390 A JP 20954390A JP 20954390 A JP20954390 A JP 20954390A JP H0491010 A JPH0491010 A JP H0491010A
- Authority
- JP
- Japan
- Prior art keywords
- transparency
- hydroxystearic acid
- transparent
- solid cosmetic
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 18
- 239000007787 solid Substances 0.000 title claims abstract description 15
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229940114072 12-hydroxystearic acid Drugs 0.000 claims abstract description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 7
- -1 coloring matters Substances 0.000 abstract description 5
- 239000004615 ingredient Substances 0.000 abstract description 5
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003963 antioxidant agent Substances 0.000 abstract description 3
- 238000004040 coloring Methods 0.000 abstract description 2
- 238000001816 cooling Methods 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 238000000465 moulding Methods 0.000 abstract description 2
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000049 pigment Substances 0.000 abstract description 2
- 239000003755 preservative agent Substances 0.000 abstract description 2
- 229940032094 squalane Drugs 0.000 abstract description 2
- 239000002304 perfume Substances 0.000 abstract 2
- 238000005266 casting Methods 0.000 abstract 1
- 239000006071 cream Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229940124543 ultraviolet light absorber Drugs 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 7
- 239000003921 oil Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 230000001953 sensory effect Effects 0.000 description 4
- 238000007872 degassing Methods 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 description 3
- 239000007934 lip balm Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 235000010654 Melissa officinalis Nutrition 0.000 description 1
- 244000062730 Melissa officinalis Species 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- AZPFEYANVWPOHJ-CLFAGFIQSA-N [2-hydroxy-3-[2-hydroxy-3-[(Z)-octadec-9-enoyl]oxypropoxy]propyl] (Z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)COCC(O)COC(=O)CCCCCCC\C=C/CCCCCCCC AZPFEYANVWPOHJ-CLFAGFIQSA-N 0.000 description 1
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 description 1
- HGKOWIQVWAQWDS-UHFFFAOYSA-N bis(16-methylheptadecyl) 2-hydroxybutanedioate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CC(O)C(=O)OCCCCCCCCCCCCCCCC(C)C HGKOWIQVWAQWDS-UHFFFAOYSA-N 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 239000000865 liniment Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000008164 mustard oil Substances 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、保存安定性に優れ、肌への付着性伸展性、持
続性等の官能特性が良好で、かつ透明性の改善された透
明固形化粧料に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention provides a transparent material that has excellent storage stability, good organoleptic properties such as adhesion to the skin, extensibility, and durability, and improved transparency. Regarding solid cosmetics.
従来、透明化粧料の固形化剤としては、ポリアミド樹脂
１エステルガム等（特公昭４５４１３１８、特公昭５２
−７０６７）が知られている。しかしこれらを用いた化
粧料は、透明性。Conventionally, as a solidifying agent for transparent cosmetics, polyamide resin 1 ester gum, etc.
-7067) is known. However, cosmetics using these materials are transparent.
保存安定性、官能特性、（特に透明性）に劣るものであ
った。It was poor in storage stability, sensory properties, and especially transparency.
そこで、１２−ヒドロキシステアリン酸を固形化剤とし
て用いた透明固形化粧料が開発されている。１２−ヒド
ロキシステアリン酸のゲルは粘着感が少なく、伸展性が
良好で、肌等への付着性にも優れ、広い温度変化にわた
って硬度変化が少なく、透明性も良好である。Therefore, transparent solid cosmetics using 12-hydroxystearic acid as a solidifying agent have been developed. The gel of 12-hydroxystearic acid has less sticky feeling, good extensibility, excellent adhesion to skin, etc., little change in hardness over a wide range of temperature changes, and good transparency.
特開昭６３−１１９４０５号公報では、１２−ヒドロキ
システアリン酸を、ロジンエステル、多価アルコール飽
和（ｏｒ不飽和）脂肪酸エステルを含む透明固形化粧料
に配合することが捷案されている。しかし、透明性、保
存安定性、官能特性の全てにおいて満足な結果が得られ
るものではなかった。JP-A-63-119405 proposes incorporating 12-hydroxystearic acid into a transparent solid cosmetic containing a rosin ester and a polyhydric alcohol saturated (or unsaturated) fatty acid ester. However, satisfactory results were not obtained in all aspects of transparency, storage stability, and sensory characteristics.
従って本発明の目的は、１２−ヒドロキシステアリン酸
を固形化剤として含む固形化粧料の、透明性、保存安定
性、官能特性を改善することにある。Therefore, an object of the present invention is to improve the transparency, storage stability, and organoleptic properties of solid cosmetics containing 12-hydroxystearic acid as a solidifying agent.
本発明は下記（＾）〜（Ｃ）の３成分を含有することを
特徴とする透明固形化粧料である。The present invention is a transparent solid cosmetic containing the following three components (^) to (C).
（＾）１２−ヒドロキシステアリン酸
（Ｂ）水酸基価１２０以下の透明液状油性成分（Ｃ）メ
チルフェニルポリシロキサン
本発明において用いられる１２−ヒドロキシステアリン
酸は、白色あるいは淡黄色のロウ状固体であり、一般に
、とマシ油等から得られるリシノール酸を還元すること
により得られる。(^) 12-Hydroxystearic acid (B) Transparent liquid oil component with a hydroxyl value of 120 or less (C) Methylphenylpolysiloxane The 12-hydroxystearic acid used in the present invention is a white or pale yellow waxy solid, Generally, it is obtained by reducing ricinoleic acid obtained from mustard oil or the like.
本発明における１２−ヒドロキシステアリン酸の含有量
は２．０〜１０．０重量％（以下ｗｔ％と略記する）が
好ましい、少ないと固形化しにくく、多いと透明性が低
下する。The content of 12-hydroxystearic acid in the present invention is preferably 2.0 to 10.0% by weight (hereinafter abbreviated as wt%); if it is too low, it will be difficult to solidify, and if it is too high, the transparency will decrease.
ここで言う「透明」とは、分光光度針にて測定した４０
０〜７００ｎｍの光の平均透過率が、７０％以上である
ことを意味する。"Transparent" here means 40% as measured with a spectrophotometer needle.
This means that the average transmittance of light in the range of 0 to 700 nm is 70% or more.
本発明において用いられる透明液状油性成分は、通常化
粧料等に使用されているもののうち、水酸基価が１２０
以下好ましくは９０以下のものである。水酸基価が高い
と固形化しにくり、透明性も劣る傾向にある。The transparent liquid oil component used in the present invention has a hydroxyl value of 120 among those commonly used in cosmetics, etc.
It is preferably 90 or less. If the hydroxyl value is high, it will be difficult to solidify and the transparency will tend to be poor.
水酸基価１２０以下の透明液状油性成分としては、スク
ワラン、流動パラフィン、ホホバ油、ミリスチン酸オク
チルドデシル、リンゴ酸ジイソステアリル、グリセリン
脂肪酸エステル、プロピレングリコール脂肪酸エステル
等が挙げられるが、これらに限定されるものではない。Transparent liquid oily components with a hydroxyl value of 120 or less include, but are not limited to, squalane, liquid paraffin, jojoba oil, octyldodecyl myristate, diisostearyl malate, glycerin fatty acid ester, propylene glycol fatty acid ester, etc. It's not a thing.
本発明における上記透明液状油性成分の含有量は、２０
．０〜６０． ＯＷ ｔ％が好ましい、２０．０ｗｔ％
より少ないと付着性、持続性に劣り、６０、 Ｏｗ ｔ
％を超えると固形化しに＜＜、透明性にも劣る。The content of the transparent liquid oil component in the present invention is 20
．． 0-60. OW t% is preferred, 20.0wt%
If it is less than 60, the adhesion and durability will be poor.
If it exceeds %, solidification will occur and transparency will be poor.
本発明において用いられるメチルフェニルポリシロキサ
ンは、粘度が５０〜１０００ｃｓのものが好ましい。粘
度が低い場合には、硬度が低く、透明性、保存安定性、
肌への付着性に劣る。粘度が高い場合には、肌への伸展
性が劣る。The methylphenylpolysiloxane used in the present invention preferably has a viscosity of 50 to 1000 cs. Low viscosity means low hardness, transparency, storage stability,
Poor adhesion to skin. When the viscosity is high, the spreadability to the skin is poor.
本発明におけるメチルフェニルポリシロキサンの含有量
は、２５．０〜６５． ＯＷ １％が好ましい。The content of methylphenylpolysiloxane in the present invention is 25.0 to 65. OW 1% is preferred.
含有量が少ないと透明性に劣り、多いと肌への付着性、
持続性の点で劣る。If the content is low, the transparency will be poor, and if the content is high, it will be difficult to adhere to the skin.
Inferior in terms of sustainability.
本発明の透明固形化粧料には、上記した成分の他に、着
色顔料１色素、抗酸化剤、紫外線吸収剤。In addition to the above-mentioned ingredients, the transparent solid cosmetic of the present invention also contains one coloring pigment, an antioxidant, and an ultraviolet absorber.
防腐剤、香料等を、本発明の目的を達成する範囲内で適
宜配合することができる。Preservatives, fragrances, etc. may be added as appropriate within the range that achieves the purpose of the present invention.
本発明の透明固形化粧料の使用形態は、固形状の化粧料
であれば良く、例えば口紅、リップクリーム、へ７−ス
ティック、サンスティック、 ＆！香等に利用すること
ができる。The transparent solid cosmetic of the present invention may be used as long as it is a solid cosmetic, such as lipstick, lip balm, He7-stick, sunstick, &! It can be used for incense, etc.
本発明の透明固形化粧料は、全成分を約９０℃で均一に
加熱溶解し、脱気後、８０〜８５℃にて型に流し込み、
冷却成型することにより、調製することができる。The transparent solid cosmetic of the present invention is produced by uniformly heating and dissolving all the ingredients at about 90°C, degassing, and then pouring into a mold at 80 to 85°C.
It can be prepared by cooling and molding.
以下実施例により、本発明を更に詳細に説明する。 The present invention will be explained in more detail with reference to Examples below.
尚、実施例に用いた透明性、保存安定性、官能特性の評
価方法は次の通りである。The evaluation methods for transparency, storage stability, and sensory characteristics used in the Examples are as follows.
（１１ｉ３明性試験
光路長１０ｍｍｘ光路巾１０ｍｍのガラスセルに試料を
流し込み、冷却固化させたものを、分光光度計にかけ、
可視部（４００〜７００ｎｍ）の退化率を測定し、チャ
ート面積にて透過率の平均を算出し、下記の判断基準に
より評価した。(11i3 brightness test Pour the sample into a glass cell with an optical path length of 10 mm x optical path width of 10 mm, cool and solidify it, apply it to a spectrophotometer,
The deterioration rate in the visible region (400 to 700 nm) was measured, the average transmittance was calculated based on the chart area, and evaluation was made according to the following criteria.
１２） 保存安定性試験
同一試料を２つの容器に入れ、一方を５℃他方を４５℃
で３ケ月間保存する。５℃の保存品と比べた時の、４５
℃の保存品の油のにじみの度合を、酸化防止剤および１
．３−ブチレングリコールを加えて均一に熔解し、脱気
後６０℃にて型に流し込（３） 官能特性試験
２０名の女子被験者の唇に、実施例（又は比較例）の試
料と対照例１の試料を交互に塗布する。12) Storage stability test The same sample was placed in two containers, one at 5°C and the other at 45°C.
Save it for 3 months. 45 when compared with products stored at 5℃
The degree of oil oozing of products stored at ℃ was determined by adding antioxidant and
．． Add 3-butylene glycol, melt it uniformly, and pour it into a mold at 60℃ after degassing (3) Sensory properties test Samples of the example (or comparative example) and the control example were placed on the lips of 20 female subjects. Apply samples of 1 alternately.
被験者本人に、「付着性」、「伸展性」、「持続性」の
各項目について、実施例（又は比較例）の各々と対照例
とを比較評価させた。The test subjects themselves were asked to compare and evaluate each of the examples (or comparative examples) and the control example with respect to each item of "adhesion,""extensibility," and "persistence."
実施例１〜２．比較例１〜３
第１表に示した成分を９０℃で均一に溶解し、脱気後８
０〜８５℃にて型に流し込み、冷却成型してリップクリ
ームを得た。Examples 1-2. Comparative Examples 1 to 3 The components shown in Table 1 were uniformly dissolved at 90°C, and after degassing,
It was poured into a mold at 0 to 85°C and cooled and molded to obtain a lip balm.
対照例１
１２−ヒドロキシステアリン酸、ジグリセリルジオレエ
ート、エステルガムを、約１１０℃において加熱溶解し
、６０℃まで冷却し、更に香料。Control Example 1 12-hydroxystearic acid, diglyceryl dioleate, and ester gum were heated and dissolved at about 110°C, cooled to 60°C, and then perfumed.
実施例。Example.
比較例及び対照例のリップクリームに
第２表から明らかな通り、実施例１．２のリップクリー
ムは、透明性に優れ、保存による油にしみがほとんどな
く、実用試験の結果も良好であった。As is clear from Table 2 of the lip balms of Comparative and Control Examples, the lip balm of Example 1.2 had excellent transparency, had almost no oil stains due to storage, and had good results in practical tests. .
それに比べて、水酸基価１２０以上の透明液状油性成分
であるヒマシ油を配合した比較例１は固化しに＜（、透
明固形化粧料が得られなかった。In comparison, Comparative Example 1, in which castor oil, which is a transparent liquid oil component with a hydroxyl value of 120 or more, was blended did not solidify and a transparent solid cosmetic could not be obtained.
メチルフェニルポリシロキサンの代わりにメチルポリシ
ロキサンを配合した比較例２１本発明の必須成分である
（Ｃ）成分を配合しない比較例３は、いずれも透明性、
保存安定性に劣り、実用試験の結果も良くなかった。Comparative Example 21 in which methylpolysiloxane was blended instead of methylphenylpolysiloxane; Comparative Example 3 in which component (C), which is an essential component of the present invention, was not blended, both had transparency,
The storage stability was poor, and the results of practical tests were also poor.
また、エステルガムを配合した対照例１は、透明性、安
定性に劣るものであった。Furthermore, Control Example 1 containing ester gum was inferior in transparency and stability.
上述した様に、本発明の透明固形化粧料は、透明性、保
存安定性に優れ、しかも肌への付着性伸展性、持続性等
の官能特性も良好である。As mentioned above, the transparent solid cosmetic of the present invention has excellent transparency and storage stability, and also has good organoleptic properties such as adhesion to the skin, extensibility, and persistence.
Claims (1)
る透明固形化粧料。 （Ａ）１２−ヒドロキシステアリン酸 （Ｂ）水酸基価１２０以下の透明液状油性成分（Ｃ）メ
チルフェニルポリシロキサン[Scope of Claims] A transparent solid cosmetic comprising the following three components (A) to (C). (A) 12-hydroxystearic acid (B) Transparent liquid oil component with a hydroxyl value of 120 or less (C) Methylphenylpolysiloxane
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20954390A JPH0491010A (en) | 1990-08-07 | 1990-08-07 | Transparent solid cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20954390A JPH0491010A (en) | 1990-08-07 | 1990-08-07 | Transparent solid cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0491010A true JPH0491010A (en) | 1992-03-24 |
Family
ID=16574549
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20954390A Pending JPH0491010A (en) | 1990-08-07 | 1990-08-07 | Transparent solid cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0491010A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5455026A (en) * | 1994-01-31 | 1995-10-03 | Dow Corning Corporation | Method of making clear antiperspirant gels |
| EP0707845A3 (en) * | 1994-10-17 | 1997-06-18 | Dow Corning | Alkylmethylsiloxane-containing gels |
| EP0704204A3 (en) * | 1994-09-23 | 1997-06-18 | Dow Corning | Siloxane gels |
| EP2566439A4 (en) * | 2010-05-07 | 2013-09-25 | Unilever Plc | Skin conditioning compositions containing 12-hydrocystearic acid |
| WO2018030326A1 (en) | 2016-08-08 | 2018-02-15 | 株式会社 資生堂 | Transparent solid composition |
| WO2018084097A1 (en) | 2016-11-01 | 2018-05-11 | L'oreal | A solid cosmetic composition comprising a fatty acid-based gelling agent and a polyamide |
| WO2018084005A1 (en) | 2016-11-01 | 2018-05-11 | L'oreal | A solid cosmetic composition comprising a fatty acid-based gelling agent and a co-gelling agent |
| WO2018198800A1 (en) | 2017-04-26 | 2018-11-01 | 株式会社 資生堂 | Transparent composition and transparent cosmetic |
-
1990
- 1990-08-07 JP JP20954390A patent/JPH0491010A/en active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5455026A (en) * | 1994-01-31 | 1995-10-03 | Dow Corning Corporation | Method of making clear antiperspirant gels |
| EP0704204A3 (en) * | 1994-09-23 | 1997-06-18 | Dow Corning | Siloxane gels |
| EP0707845A3 (en) * | 1994-10-17 | 1997-06-18 | Dow Corning | Alkylmethylsiloxane-containing gels |
| EP2566439A4 (en) * | 2010-05-07 | 2013-09-25 | Unilever Plc | Skin conditioning compositions containing 12-hydrocystearic acid |
| KR20190035698A (en) | 2016-08-08 | 2019-04-03 | 가부시키가이샤 시세이도 | Transparent solid composition |
| CN109562035A (en) * | 2016-08-08 | 2019-04-02 | 株式会社资生堂 | Transparent solid composition |
| WO2018030326A1 (en) | 2016-08-08 | 2018-02-15 | 株式会社 資生堂 | Transparent solid composition |
| US11123269B2 (en) | 2016-08-08 | 2021-09-21 | Shiseido Company, Ltd. | Transparent solid composition |
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| WO2018084005A1 (en) | 2016-11-01 | 2018-05-11 | L'oreal | A solid cosmetic composition comprising a fatty acid-based gelling agent and a co-gelling agent |
| US11197806B2 (en) | 2016-11-01 | 2021-12-14 | L'oreal | Solid cosmetic composition comprising a fatty acid-based gelling agent and a co-gelling agent |
| WO2018198800A1 (en) | 2017-04-26 | 2018-11-01 | 株式会社 資生堂 | Transparent composition and transparent cosmetic |
| KR20190136046A (en) | 2017-04-26 | 2019-12-09 | 가부시키가이샤 시세이도 | Transparent composition and transparent cosmetic |
| US11413234B2 (en) | 2017-04-26 | 2022-08-16 | Shiseido Company, Ltd. | Transparent composition and transparent cosmetic |
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