JPH02147059A - Deodorizing antimicrobial film - Google Patents
Deodorizing antimicrobial filmInfo
- Publication number
- JPH02147059A JPH02147059A JP63301510A JP30151088A JPH02147059A JP H02147059 A JPH02147059 A JP H02147059A JP 63301510 A JP63301510 A JP 63301510A JP 30151088 A JP30151088 A JP 30151088A JP H02147059 A JPH02147059 A JP H02147059A
- Authority
- JP
- Japan
- Prior art keywords
- film
- aluminum sulfate
- synthetic resin
- deodorizing
- compd
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 15
- 230000000845 anti-microbial effect Effects 0.000 title abstract 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims abstract description 21
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 18
- 239000000057 synthetic resin Substances 0.000 claims abstract description 18
- 230000000844 anti-bacterial effect Effects 0.000 claims description 12
- -1 aluminum ions Chemical class 0.000 abstract description 6
- 229920001684 low density polyethylene Polymers 0.000 abstract description 4
- 239000004702 low-density polyethylene Substances 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000002216 antistatic agent Substances 0.000 abstract description 3
- 238000001125 extrusion Methods 0.000 abstract description 3
- 244000005700 microbiome Species 0.000 abstract description 3
- 239000004014 plasticizer Substances 0.000 abstract description 3
- 239000004952 Polyamide Substances 0.000 abstract description 2
- 229910052782 aluminium Inorganic materials 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 239000000155 melt Substances 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- 229920002647 polyamide Polymers 0.000 abstract description 2
- 229920000728 polyester Polymers 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- 238000004332 deodorization Methods 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 229920005992 thermoplastic resin Polymers 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 4
- 238000011056 performance test Methods 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 230000001580 bacterial effect Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- FKTXTEOQZYEBRF-UHFFFAOYSA-N 4-[dichloro(fluoro)methyl]sulfanylisoindole-1,3-dione Chemical compound FC(Cl)(Cl)SC1=CC=CC2=C1C(=O)NC2=O FKTXTEOQZYEBRF-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 241000194017 Streptococcus Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 210000001072 colon Anatomy 0.000 description 1
- 238000012136 culture method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 229920006262 high density polyethylene film Polymers 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
Description
【発明の詳細な説明】
し産業上の利用分野］
本発明は脱臭性能と抗菌性能を併せ有することによりゴ
ミ９１紙オムツや食器棚用シートなど多目的に使用する
ことができる脱臭抗菌性フィルムに関するものである。[Detailed Description of the Invention] Industrial Field of Application] The present invention relates to a deodorizing antibacterial film that has both deodorizing and antibacterial properties and can be used for multiple purposes such as garbage 91 disposable diapers and sheets for cupboards. It is.
［従来の技術および解決課題］
従来、脱臭抗菌性フィルムとして、二価の鉄塩とＮ（フ
ルオロジクロロメチルチオ）フタルイミドのような抗菌
剤を熱可塑性合成樹脂フィルムに分散含有させたものが
知られている。しかし、このフィルムは鉄を含有するた
め水との接触する状態で使用すると、鉄が酸化されて茶
色く着色して外観が劣化する。[Prior art and problems to be solved] Conventionally, as a deodorizing antibacterial film, a thermoplastic synthetic resin film containing a divalent iron salt and an antibacterial agent such as N (fluorodichloromethylthio)phthalimide dispersed therein has been known. There is. However, since this film contains iron, if it is used in contact with water, the iron will be oxidized, turning it brown and deteriorating its appearance.
また、食器や食品との接触する状態で使用した場合、抗
菌剤が人体にとりこまれる可能性があり、安全性の点で
問題があった。Furthermore, when used in contact with tableware or food, there is a possibility that the antibacterial agent may be absorbed into the human body, which poses a safety problem.
［課題を解決するための手段］
本発明者は、前記問題点を解決するために種々検討の結
果、微粒子状の硫酸アルミニウムを合成樹脂中に分散さ
せて、フィルム化することにより、脱臭性能と抗菌性能
を有する合成樹脂フィルムを得られることを見出し、本
発明を完成した。[Means for Solving the Problems] As a result of various studies to solve the above-mentioned problems, the inventors of the present invention have improved the deodorizing performance by dispersing fine particulate aluminum sulfate in a synthetic resin and forming it into a film. The present invention was completed based on the discovery that a synthetic resin film having antibacterial properties can be obtained.
即ち、本発明は微粒子状の硫酸アルミニウムが合成樹脂
フィルムに含有されていることを特徴とする。That is, the present invention is characterized in that fine particulate aluminum sulfate is contained in the synthetic resin film.
本発明に使用する硫酸アルミニウムは、粒径が５０μｍ
より以下のものが適しており、望ましくは３０μｍ以下
がよい０粒径が５０μｍより大きいものを使用すると、
フィルム化した時、硫酸アルミニウムの粒子が目立つた
め、ざらつくと共に外観上好ましくない、使用する合成
樹脂フィルムの基材としては、硫酸アルミニウムを安定
して分敗できる熱可塑性合成樹脂であればどのようなも
のでも使用でき、例えば高密度ポリエステル、低密度ポ
リエチレン、ポリプロピレン、ポリ塩化ビニリデン、ポ
リビニルアセテート、ポリアミドなどを選択することが
できる。The aluminum sulfate used in the present invention has a particle size of 50 μm.
If you use one with a zero particle size larger than 50 μm, preferably 30 μm or less,
When formed into a film, the particles of aluminum sulfate stand out, giving it a rough and undesirable appearance.As a base material for the synthetic resin film, any thermoplastic synthetic resin that can stably decompose aluminum sulfate can be used. For example, high density polyester, low density polyethylene, polypropylene, polyvinylidene chloride, polyvinyl acetate, polyamide, etc. can be selected.
硫酸アルミニウムの添加量は有効な脱臭性と抗菌性を有
するように決定され、合成樹脂に対し０．０５〜１０！
１ｆｆｔ％の範囲内が適当であり、好ましくは０．１〜
３重量％である。また合成樹脂フィルムの性状を改善す
るため可塑剤、帯電防止剤等を添加することも可能であ
る。The amount of aluminum sulfate added is determined to have effective deodorizing and antibacterial properties, and is 0.05 to 10!
Appropriately, it is within the range of 1 fft%, preferably from 0.1 to
It is 3% by weight. It is also possible to add plasticizers, antistatic agents, etc. to improve the properties of the synthetic resin film.
本発明の脱臭性能、抗菌性能を有する合成樹脂フィルム
は、例えば硫酸アルミニウム、可塑剤。The synthetic resin film having deodorizing performance and antibacterial performance of the present invention includes, for example, aluminum sulfate and a plasticizer.
帯電防止剤等を添加し合成樹脂の融点以上に加熱し、充
分に混合した後、Ｔ−ダイ法及びインフレーション法に
よる溶融押出方式にしたがってフィルム化することによ
り得ることができる。It can be obtained by adding an antistatic agent and the like, heating to a temperature higher than the melting point of the synthetic resin, thoroughly mixing the mixture, and then forming it into a film according to a melt extrusion method using a T-die method or an inflation method.
［作 用］
合成樹脂シートに添加した硫酸アルミニウムは、アルミ
ニウムイオンの収れん作用により微生物を死滅させるこ
とができる。一方、硫酸アルミニウムの硫酸イオンはＮ
系化合物と反応して塩を生成するためＮ系化合物の脱臭
が可能である。また、微生物分解が原因で発生する臭気
も原因となる微生物を硫酸アルミニウムで死滅させるた
め、その発生を防止できる。[Function] Aluminum sulfate added to the synthetic resin sheet can kill microorganisms due to the astringent action of aluminum ions. On the other hand, the sulfate ion of aluminum sulfate is N
Since it reacts with N-based compounds to produce salts, it is possible to deodorize N-based compounds. In addition, aluminum sulfate kills the microorganisms that cause odors caused by microbial decomposition, thereby preventing their occurrence.
本発明の脱臭抗菌性能を有する合成樹脂フィルムは水に
ぬれても着色することがない。また、仮に食器や食品と
接触する状態で使用し、硫酸アルミニウムが人体にとり
こまれても硫酸アルミニウムは人体に対する安全性が高
く安全面で問題はない。The synthetic resin film of the present invention having deodorizing and antibacterial properties does not become colored even when wet with water. Further, even if aluminum sulfate is taken into the human body when used in contact with tableware or food, aluminum sulfate is highly safe for the human body and there will be no safety problems.
［実施例］
以下、実施例に基づいて本発明を具体的に説明するが、
本発明はこれらの実施例において同等限定されるもので
はない。[Examples] Hereinafter, the present invention will be specifically explained based on Examples.
The invention is not equally limited to these examples.
製造例１
平均粒径１２μｍの硫酸アルミニウム２．０重量部を少
量の界面活性剤と共に１００重量部の低密度ポリエチレ
ンに加え、常温でミキサーにより充分混合した。ついで
混合物をＴ−ダイ押出機に供給し、押出温度２００℃で
フィルム状に押し出して厚さ３０μｍのフィルムを得た
。Production Example 1 2.0 parts by weight of aluminum sulfate having an average particle size of 12 μm was added to 100 parts by weight of low-density polyethylene together with a small amount of surfactant, and the mixture was thoroughly mixed with a mixer at room temperature. The mixture was then fed into a T-die extruder and extruded into a film at an extrusion temperature of 200°C to obtain a film with a thickness of 30 μm.
製造例２
平均粒径１２μｍの硫酸アルミニウム０．２重量部を少
量の界面活性剤と共に１００重量部の高密度ポリエチレ
ンに加え、実施例１と同様にして厚さ３０ｕｍのフィル
ムを得た。Production Example 2 A film having a thickness of 30 um was obtained in the same manner as in Example 1 by adding 0.2 parts by weight of aluminum sulfate having an average particle size of 12 μm to 100 parts by weight of high-density polyethylene together with a small amount of surfactant.
製造例３
実施例２の高密度ポリエチレンの代りにポリプロピレン
樹脂を使用した以外は実施例２と同様にして厚さ３０μ
ｍのポリプロピレン樹脂フィルムを得た。Production Example 3 The same procedure as in Example 2 except that polypropylene resin was used instead of the high-density polyethylene in Example 2, with a thickness of 30 μm.
A polypropylene resin film of m was obtained.
次に、以上のようにして得られたフィルムを脱臭性能試
験および抗菌性能試験に供した。Next, the film obtained as described above was subjected to a deodorizing performance test and an antibacterial performance test.
脱臭性能試験
製造例１で得られたフィルムＡと、厚さ３０μｍの低密
度ポリエチレンフィルムＢを試料とした。Deodorizing performance test Film A obtained in Production Example 1 and low density polyethylene film B having a thickness of 30 μm were used as samples.
アンモニア初期濃度（Ｃｏ）１５０ｐｐｍ、１７０ｐｐ
ｍに調整した６、３℃のデシケータ−内に３５ｃｍｘ
４０ｃｍに裁断した上記試料を投入し、経時的にアンモ
ニアガス濃度（Ｃ）を測定し、アンモニア残存率Ｃ／
Ｃｏを求めた。結果を第１表に示す。Ammonia initial concentration (Co) 150ppm, 170ppm
35cmx in a desiccator at 6.3℃ adjusted to
The above sample cut to 40 cm was put in, and the ammonia gas concentration (C) was measured over time, and the ammonia residual rate C/
I asked for Co. The results are shown in Table 1.
第 １ 表
抗菌性能試験
製造例２で得られたフィルムＩ、製造例３で得られたフ
ィルムＩＩ、厚さ３０μｍの高密度ポリエチレンフィル
ム■、厚さ３０ＬＬｍのポリプロピレンフィルム■を試
料とし、試験菌株として、５ｔｒｅｐｔｏｃｏｃｃｕｓ
ｐｙｏｇｅｎｅｓ ！１０７１２ （溶連菌） 、５
ｔａｐｈｙｌｏｃｏｃｃｕｓ ａｕｒｅｕｓ ＩＦＯ１
２７３２（黄色ブドウ球菌） 、 Ｅｓｃｈｅｒｉｃｈ
ｉａ ｃｏｌｉ ＩＦＯ３３０１（大腸試験方法
菌）を使用した。Table 1 Antibacterial Performance Test Film I obtained in Production Example 2, Film II obtained in Production Example 3, 30 μm thick high-density polyethylene film ■, and 30 LLm thick polypropylene film ■ were used as samples, and as test bacterial strains. , 5treptococcus
pyogenes! 10712 (Streptococcus), 5
taphylococcus aureus IFO1
2732 (Staphylococcus aureus), Escherich
Ia coli IFO3301 (colon test method bacterium) was used.
試験方法
各試験菌液の入った三角フラスコに細切りした試料１．
５ｇを入れ２５℃、回転数１４０ｒｐｍで振とうした。Test method Samples 1. Cut into small pieces into Erlenmeyer flasks containing each test bacterial solution.
5 g was added and shaken at 25° C. and 140 rpm.
振とう開始時及び５時間後に試験菌液の一部を取り出し
、トリプトソーヤ寒天借地（栄研）を用いる混釈培養法
によりその生菌数を測定した０次式により生菌の減少率
を算出し結果を第２表に示す。At the start of shaking and after 5 hours, a portion of the test bacterial solution was taken out, and the number of viable bacteria was measured by the pour culture method using trypto soya agar (Eiken).The reduction rate of viable bacteria was calculated using a zero-order equation. The results are shown in Table 2.
′−２−気Ｏ
減少率（％）＝ Ｘ１００
１℃
ｎ：振とう前の三角フラスコ内の１ｍｌ当りの生菌数
ｎｏ：振とう後の三角フラスコ内の１ｍｌ当りの生菌数
（以下余白）
［発明の効果］
以上説明したように本発明は、微粒子状の硫酸アルミニ
ウムを合成樹脂フィルムに分散させたため、経時的に変
色がなく、安全性の高い脱臭抗菌性フィルムとすること
ができる。'-2-Air O Reduction rate (%) = X100 1℃ n: Number of viable bacteria per ml in the Erlenmeyer flask before shaking no: Number of viable bacteria per ml in the Erlenmeyer flask after shaking (margin below) ) [Effects of the Invention] As explained above, in the present invention, since fine particulate aluminum sulfate is dispersed in a synthetic resin film, a highly safe deodorizing and antibacterial film that does not discolor over time can be obtained.
このため本発明の脱臭抗菌性フィルムは広範囲に適用が
可能である６例えば、合成樹脂フィルム単体を生ゴミ処
理用袋、畜尿袋等に使用可能である。また、他の適当な
材質と併せて加工することにより食器棚用シート、紙オ
ムツ等にも適用が可能である。Therefore, the deodorizing antibacterial film of the present invention can be widely applied.6 For example, the synthetic resin film alone can be used for garbage disposal bags, livestock urine bags, etc. Furthermore, by processing it in combination with other suitable materials, it can be applied to sheets for cupboards, disposable diapers, etc.
Claims (1)
されていることを特徴とする脱臭抗菌性フィルム。A deodorizing antibacterial film characterized by containing fine particulate aluminum sulfate in a synthetic resin film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63301510A JPH02147059A (en) | 1988-11-29 | 1988-11-29 | Deodorizing antimicrobial film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63301510A JPH02147059A (en) | 1988-11-29 | 1988-11-29 | Deodorizing antimicrobial film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02147059A true JPH02147059A (en) | 1990-06-06 |
Family
ID=17897790
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63301510A Pending JPH02147059A (en) | 1988-11-29 | 1988-11-29 | Deodorizing antimicrobial film |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02147059A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62207463A (en) * | 1986-03-07 | 1987-09-11 | 包国 祐雄 | Deodorizing material |
| JPS62235363A (en) * | 1986-04-07 | 1987-10-15 | Dainichi Color & Chem Mfg Co Ltd | Deodorizing resin composition and deodorizing molded article |
| JPS62250057A (en) * | 1986-04-23 | 1987-10-30 | Daicel Chem Ind Ltd | Thermoplastic resin composition |
-
1988
- 1988-11-29 JP JP63301510A patent/JPH02147059A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62207463A (en) * | 1986-03-07 | 1987-09-11 | 包国 祐雄 | Deodorizing material |
| JPS62235363A (en) * | 1986-04-07 | 1987-10-15 | Dainichi Color & Chem Mfg Co Ltd | Deodorizing resin composition and deodorizing molded article |
| JPS62250057A (en) * | 1986-04-23 | 1987-10-30 | Daicel Chem Ind Ltd | Thermoplastic resin composition |
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