JPH01319244A - Manufacture of electric bulb - Google Patents

Manufacture of electric bulb

Info

Publication number
JPH01319244A
JPH01319244A JP15124288A JP15124288A JPH01319244A JP H01319244 A JPH01319244 A JP H01319244A JP 15124288 A JP15124288 A JP 15124288A JP 15124288 A JP15124288 A JP 15124288A JP H01319244 A JPH01319244 A JP H01319244A
Authority
JP
Japan
Prior art keywords
light
thin film
film
diffusing
light scattering
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP15124288A
Other languages
Japanese (ja)
Other versions
JP2902404B2 (en
Inventor
Osamu Mizuno
修 水野
Yoshio Sakurai
美穂 櫻井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ushio Denki KK
Ushio Inc
Original Assignee
Ushio Denki KK
Ushio Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ushio Denki KK, Ushio Inc filed Critical Ushio Denki KK
Priority to JP63151242A priority Critical patent/JP2902404B2/en
Publication of JPH01319244A publication Critical patent/JPH01319244A/en
Application granted granted Critical
Publication of JP2902404B2 publication Critical patent/JP2902404B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PURPOSE:To stably exert the desired performance of a light interfering film and obtain the radiation light with high homogeneity of illuminance by providing a specific light scattering thin film on the surface of the light interfering film of a sealed tube made of glass. CONSTITUTION:A multi-layer light interfering film 20 is provided on the outer surface of a sealed tube 10 made of glass, a light scattering thin film 30 is provided on the surface of the light interfering film 20. The light scattering thin film 30 is formed by the dipping method by using a coating liquid dispersed with the fine powder of a ceramic material in a silicon compound solution. The light scattering thin film 30 with a sufficient light scattering property is thereby formed without damaging the light interfering film 20 at all. When a reinforcing thin film is formed on the surface of the light scattering thin film 30, the sticking strength of the light scattering thin film is improved.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、電球の製造方法に関し、特に放射光に特徴の
ある電球の製造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a method of manufacturing a light bulb, and particularly to a method of manufacturing a light bulb characterized by emitted light.

〔技術の背景〕[Technology background]

電球は、一般に種々の分野で用いられているが、例えば
複写機の露光用光源、その他の光学装置等に用いられる
電球においては、■放射効率の高い良好な分光特性が得
られること、■リップルが小さ(て照度の均一性が高い
こと、が要求されている。
Light bulbs are generally used in a variety of fields, but for example, light bulbs used for exposure light sources in copying machines and other optical devices have two characteristics: ■ Good spectral characteristics with high radiation efficiency; ■ Ripple It is required that the illuminance be small (and that the uniformity of illuminance be high).

従来、放射効率の高い良好な分光特性を得るための手段
としては、ガラス製発光管の外表面に多層構成の光干渉
膜を設ける手段が知られている。
BACKGROUND ART Conventionally, as a means for obtaining good spectral characteristics with high radiation efficiency, there has been known a method of providing a multilayer optical interference film on the outer surface of a glass arc tube.

また、リップルが小さくて照度の均一性が高い放射光を
得る手段としては、ガラス製発光管の外表面を例えばサ
ンドブラスト等によりフロスト加工して散光面とする手
段が知られている。
Furthermore, as a means for obtaining synchronized light with small ripples and high uniformity of illuminance, it is known to frost the outer surface of a glass arc tube by sandblasting or the like to form a light diffusing surface.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

しかし、ガラス製封体管の外表面に光干渉膜を設けたう
え、さらにサンドブラスト等によりフロスト加工して散
光面とする場合には、当該光干渉膜が損傷し、光干渉膜
の所期の性能が発揮されない問題がある。
However, if an optical interference film is provided on the outer surface of the glass envelope tube and then frosted by sandblasting etc. to create a light diffusing surface, the optical interference film will be damaged and the intended purpose of the optical interference film may be damaged. There is a problem with performance not being achieved.

本発明は以上の如き事情に基づいてなされたものであっ
て、その目的は、光干渉膜の所期の性能が安定に発揮さ
れ、しかもリップルが小さくて照度の均一性が高い放射
光が得られる電球の製造方法を提供することにある。
The present invention has been made based on the above circumstances, and its purpose is to stably exhibit the desired performance of an optical interference film, and to obtain synchrotron radiation with small ripples and high uniformity of illuminance. The purpose of the present invention is to provide a method for manufacturing a light bulb that can

〔課題を解決するための手段〕[Means to solve the problem]

上記目的を達成するため、本発明は、ガラス製封体管の
外表面に多層構成の光干渉膜を設け、当該光干渉膜の表
面にさらに散光性薄膜を設けてなる電球の製造方法であ
って、前記散光性薄膜を、シリコン化合物の溶液にセラ
ミック材料の微粉末を分散してなる被覆液を用いてディ
ッピング法により形成することを特徴とする。
In order to achieve the above object, the present invention provides a method for manufacturing a light bulb, which comprises providing a multi-layered optical interference film on the outer surface of a glass envelope tube, and further providing a light-diffusing thin film on the surface of the optical interference film. The light-diffusing thin film is formed by a dipping method using a coating liquid in which fine powder of a ceramic material is dispersed in a solution of a silicon compound.

また、散光性薄膜の表面にさらに補強用薄膜を形成する
ことを特徴とする。
Moreover, a reinforcing thin film is further formed on the surface of the light-diffusing thin film.

〔作用〕[Effect]

ガラス製封体管の外表面に多層構成の光干渉膜を設け、
この光干渉膜の外面に、特定の被覆液を用いてディッピ
ング法により散光性薄膜を形成すると、光干渉膜をなん
ら損傷することなく十分な散光性を有する散光性薄膜が
形成される。
A multilayer optical interference film is provided on the outer surface of the glass envelope tube,
When a light-diffusing thin film is formed on the outer surface of this light interference film by a dipping method using a specific coating liquid, a light-diffusing thin film having sufficient light-diffusing properties is formed without damaging the light interference film in any way.

また、散光性薄膜の表面にさらに補強用薄膜を形成する
と、散光性薄膜の付着強度が高まる。
Furthermore, if a reinforcing thin film is further formed on the surface of the light-diffusing thin film, the adhesion strength of the light-diffusing thin film is increased.

〔発明の具体的構成〕[Specific structure of the invention]

以下、本発明の構成を具体的に説明する。 Hereinafter, the configuration of the present invention will be specifically explained.

第1図は、本発明に係る電球の製造方法によって製造さ
れた電球の一例を示す説明図である。同図において、1
0はガラス製発光管、11はフィラメント、20!−!
多層構成の光干渉膜、30は散光性薄膜、40は口金で
ある。ガラス製発光管10は例ズば石英ガラス製であり
、その内部には例えばハロゲンが封入されている。
FIG. 1 is an explanatory diagram showing an example of a light bulb manufactured by the light bulb manufacturing method according to the present invention. In the same figure, 1
0 is a glass arc tube, 11 is a filament, 20! -!
The optical interference film has a multilayer structure, 30 is a light-diffusing thin film, and 40 is a base. The glass arc tube 10 is made of, for example, quartz glass, and has, for example, halogen sealed therein.

本発明においては、以下のようにして電球を製造する。In the present invention, a light bulb is manufactured as follows.

(1)ガラス製封体管10の外表面に多層構成の光干渉
膜20を設ける。この光干渉膜20は、特定波長域の光
の透過率または反射率を制御17、て所望の分光特性を
得るためのものである。具体的には、高屈折率層と、低
屈折率層どを交互に積層して構成することができる。
(1) A multilayer optical interference film 20 is provided on the outer surface of the glass enclosure tube 10. This optical interference film 20 is for controlling 17 the transmittance or reflectance of light in a specific wavelength range to obtain desired spectral characteristics. Specifically, it can be constructed by alternately stacking high refractive index layers and low refractive index layers.

例えば赤外域の光を主として反射する赤外線反射膜とし
、ての機能を有する光干渉膜20は、酸化チタン(T1
02)、二酸化ケイ素(Sin2)等よりなる2種以上
の層を交互に積層して形成することができる。
For example, the optical interference film 20, which has the function of an infrared reflective film that mainly reflects light in the infrared region, is made of titanium oxide (T1
02), silicon dioxide (Sin2), etc., can be formed by alternately stacking two or more layers.

光干渉@2Qは、例えば蒸着法、ディッピング法等の薄
膜形成手段により形成することができ、その形成手段は
特に限定されない。
The optical interference @2Q can be formed by a thin film forming method such as a vapor deposition method or a dipping method, and the forming method is not particularly limited.

(2)以上のようにしてガラス製封体管10の外表面に
光干渉膜20を形成した後、シリコン化合物の溶液にセ
ラミック材料の微粉末を分散してなる被覆液を用いてデ
ィッピング法により、上記光干渉膜20の表面にさらに
散光性薄119!30を形成する。
(2) After forming the optical interference film 20 on the outer surface of the glass enclosure tube 10 as described above, a dipping method is performed using a coating liquid made by dispersing fine powder of a ceramic material in a solution of a silicon compound. , a light-diffusing thin layer 119!30 is further formed on the surface of the optical interference film 20.

シリコン化合物の溶液としては、例えばシリコンアルコ
レートに、エタノーノベ酢酸、塩酸等を加え、これらを
反応させて得られる溶液を好ましく用いることができる
As the solution of the silicon compound, for example, a solution obtained by adding ethanolanobeacetic acid, hydrochloric acid, etc. to silicon alcoholate and reacting them can be preferably used.

特に、シリコンアルコレートを用いて調製すると、散光
性薄膜30の光干渉膜20に対する付着性が向上する。
In particular, when prepared using silicon alcoholate, the adhesion of the light-diffusing thin film 30 to the light interference film 20 is improved.

また、シリコン化合物の溶液には、さらに必要に応じて
五酸化リン等の特性改良剤を添加してもよい。この五酸
化リンは、散光性薄膜30の膜強度を高めるうえで好ま
しいものである、。
Further, a property improving agent such as phosphorus pentoxide may be further added to the silicon compound solution as necessary. This phosphorus pentoxide is preferable for increasing the film strength of the light-diffusing thin film 30.

セラミック材料の微粉末としては、例えば二酸化ケイ素
(S i 02)の微粉末を主成分とし、これに必要に
応じて例えば酸化アルミニウム(Δ120.)、酸化チ
タン(Ti02)S酸化ジルコニウム(Zr02)等の
@粉末を加えたものを好ま17<用いることができる。
As the fine powder of the ceramic material, for example, the main component is fine powder of silicon dioxide (S i 02), and if necessary, for example, aluminum oxide (Δ120.), titanium oxide (Ti02), S zirconium oxide (Zr02), etc. are added. It is preferable to use a powder to which 17< powder is added.

斯かる微粉末の粒子径はO,]、um〜数JJ肩程度が
よい。
The particle diameter of such fine powder is preferably about 0,], um to several JJ.

散光性薄膜30は、上記被覆液を用いてディッピング法
で形成する。すなわち、第2図〜第4図(こ示すように
、被覆液50中に、外表面に光干渉膜20が形成された
ガラス製封体管10をほぼ垂直に下降させて浸漬した後
、当該ガラス製封体管lOを上方にほぼ垂直に引上げる
。次いで、このガラス製封体管10を加熱して表面のデ
ィッピング膜を乾燥(,5、さらに乾燥した膜を例えば
電気炉等により加熱1−で焼成し、もって第5図に示す
ように、セラミック材料の微粉末が分散含有されてなる
散光性薄膜30を得る。この散光性薄膜30の厚さは例
えば0.5〜Ion程度である。
The light-diffusing thin film 30 is formed by a dipping method using the above coating liquid. That is, as shown in FIGS. 2 to 4, after lowering and immersing the glass enclosure tube 10 with the optical interference film 20 formed on the outer surface in the coating liquid 50 almost vertically, The glass envelope tube 10 is pulled up almost perpendicularly. Next, the glass envelope tube 10 is heated to dry the dipping film on the surface (5), and the dried film is heated in an electric furnace, etc. As shown in FIG. 5, a light-diffusing thin film 30 in which fine powder of a ceramic material is dispersed is obtained.The thickness of this light-diffusing thin film 30 is, for example, about 0.5 to ion. .

散光性薄膜30は、上記の薄膜形成工程を1回だけ遂行
して単層構成としてもよいし、さらには必要に応じて上
記の薄膜形成工程を複数回繰返して遂行して2層以上の
積層構成としてもよい。2層以上の積層構成とする場合
には、散光性薄膜30の厚さを相当大きな自由度で調整
することができる。
The light-diffusing thin film 30 may be formed into a single layer structure by performing the above thin film forming process only once, or may be formed into a laminate of two or more layers by repeating the above thin film forming process multiple times as necessary. It may also be a configuration. In the case of a laminated structure of two or more layers, the thickness of the light-diffusing thin film 30 can be adjusted with a considerably large degree of freedom.

また、箪6図に示すように、上記の散光性薄膜300表
面にさらに例えば二酸化ケイ素等よりなる補強用薄膜6
0を設けることにより、散光性薄膜30の付着強度を高
めることができる。この補強用薄膜60は、例えば散光
性薄膜の形成に用いる上記シリコン化合物の溶液と同様
の溶液を被覆液として用いて、ディッピング法により形
成することができる。
Further, as shown in Figure 6, a reinforcing thin film 6 made of silicon dioxide or the like is further added to the surface of the light-diffusing thin film 300.
By providing 0, the adhesion strength of the light-diffusing thin film 30 can be increased. This reinforcing thin film 60 can be formed, for example, by a dipping method using a solution similar to the above silicon compound solution used for forming the light-diffusing thin film as a coating liquid.

〔実施例〕〔Example〕

以下、本発明の実施例を具体的に説明するが、本発明が
これらの実施例に限定されるものではない。
Examples of the present invention will be specifically described below, but the present invention is not limited to these Examples.

(光干渉膜の形成) 長さ3Qcm、外径Q、 5cmの石英ガラス製封体管
の外表面に、蒸着法により、酸化チタン層と二酸化ケイ
素層とを交互に積層してなる多層構成の赤外線反射特性
を有する光干渉膜を形成した。
(Formation of an optical interference film) A multilayer structure consisting of titanium oxide layers and silicon dioxide layers alternately laminated by vapor deposition on the outer surface of a quartz glass enclosure tube with a length of 3Qcm and an outer diameter of Q of 5cm. An optical interference film with infrared reflective properties was formed.

(散光性薄膜の形成) シリコンアルコレート(Si(OC28s)4)と、エ
タノール(C2HaOH)と、酢酸(CH,C00H)
と、塩酸(MCI)  とを、1 :13 : 3 :
0.007 (モル比)となる割合で混合し、これを還
流下で24時間反応させた後、さらに五酸化リン(P、
O,)を3i02換算濃度で15重量%となる割合で添
加し、もって被覆液用の溶液を得た。
(Formation of light-diffusing thin film) Silicon alcoholate (Si(OC28s)4), ethanol (C2HaOH), and acetic acid (CH,C00H)
and hydrochloric acid (MCI), 1:13:3:
After mixing at a ratio of 0.007 (molar ratio) and reacting under reflux for 24 hours, phosphorus pentoxide (P,
O,) was added at a ratio of 15% by weight in terms of 3i02 concentration to obtain a coating solution.

この被覆液用の溶液500m1に、それぞれ後記第1表
に示すセラミック材料の微粉末を添加し、これを分散し
て各被覆液を得た。
Fine powders of ceramic materials shown in Table 1 below were added to 500 ml of this coating liquid solution, and the powder was dispersed to obtain each coating liquid.

これらの被覆液を用いてディッピング法による薄膜形成
工程を後記第1表に示す回数遂行して、上記光干渉膜の
表面に単層構成または積層構成の散光性薄膜を形成した
Using these coating solutions, a thin film forming process by dipping was performed the number of times shown in Table 1 below to form a light-diffusing thin film with a single layer or a laminated structure on the surface of the optical interference film.

なあ、ディッピング条件および焼成条件は次の通りであ
る。
The dipping conditions and baking conditions are as follows.

〈1)ディッピング条件 引上げ雰囲気を温度10℃、相対湿度30%とし、引上
げ速度を11mm/secとした。
<1) Dipping conditions The temperature of the pulling atmosphere was 10° C., the relative humidity was 30%, and the pulling speed was 11 mm/sec.

(2)焼成条件 ドライオーブンにより120℃で5分間乾燥した後、電
気炉により600℃で10分間焼成した。
(2) Firing Conditions After drying at 120°C for 5 minutes in a dry oven, it was fired at 600°C for 10 minutes in an electric furnace.

また、一部の実施例においては、さらに、上記散光性薄
膜の形成に用いた被覆液用の溶液と同様の組成の溶液を
被覆液として用い、引上げ速度を8.9 mm/sec
としたほかは上記散光性薄膜の形成と同様の条件で薄膜
形成工程を後記第1表に示す回数遂行し、もって上記散
光性薄膜の表面に二酸化ケイ素よりなる補強用薄膜を形
成した。
In some examples, a solution having the same composition as the coating solution used to form the light-diffusing thin film was used as the coating solution, and the pulling rate was set at 8.9 mm/sec.
The thin film forming process was performed the number of times shown in Table 1 below under the same conditions as for the formation of the light-diffusing thin film, except that a reinforcing thin film made of silicon dioxide was formed on the surface of the light-diffusing thin film.

以上のようにして製造された各電球について、散光性薄
膜の性能右よび付着強度を評価した。結果を後記第1表
に併せて示す。
For each light bulb manufactured as described above, the performance and adhesion strength of the light-diffusing thin film were evaluated. The results are also shown in Table 1 below.

なお、散光性薄膜の付着強度は、次のようにして評価し
た。すなわち、粘着テープを散光性薄膜または補強用薄
膜の上から貼付した後、当該粘着テープをゆっくりと引
き剥がす試験を行い、散光性薄膜の剥離が生ずるか否か
を目視により副べた。
The adhesion strength of the light-diffusing thin film was evaluated as follows. That is, a test was conducted in which an adhesive tape was pasted onto a light-diffusing thin film or a reinforcing thin film, and then the adhesive tape was slowly peeled off, and whether or not the light-diffusing thin film peeled off was visually observed.

評価は、散光性薄膜の剥離が生ぜず十分な付着強度を有
していた場合を「○」、「O」より若干劣るが実用上問
題のない場合を「Δ」、「△」より若干劣るが実用上問
題のない場合を「△△」、実用的には問題のある場合を
rx、とした。
The evaluation is "○" when the light-diffusing thin film does not peel off and has sufficient adhesion strength, "Δ" when it is slightly inferior to "O" but has no practical problems, and slightly inferior to "△". The case where there is no practical problem is marked as "Δ△", and the case where there is a practical problem is marked as rx.

〔発明の効果〕〔Effect of the invention〕

以上説明したように、本発明によれば、ガラス製封体管
の外表面に多層構成の光干渉膜を設け、この光干渉膜の
外面に、特定の被覆液を用いてディッピング法により吸
光性薄膜を形成するので、光干渉膜の所期の性能を確実
に発揮させることができるうえ散光性薄膜により優れた
散光特性が発揮される電球を製造することができる。
As explained above, according to the present invention, a multilayered optical interference film is provided on the outer surface of a glass envelope tube, and the outer surface of this optical interference film is made to absorb light by dipping with a specific coating liquid. Since a thin film is formed, the desired performance of the light interference film can be reliably exhibited, and a light bulb can be manufactured that exhibits excellent light scattering properties due to the light scattering thin film.

そして、被覆液がシリコン化合物の溶液にセラミック材
料の微粉末を分散してなるので、散光性薄膜の光干渉膜
に対する付着性を高めることができる。
Since the coating liquid is made by dispersing fine powder of a ceramic material in a solution of a silicon compound, it is possible to improve the adhesion of the light-diffusing thin film to the light interference film.

また、散光性薄膜の表面にさらに補強用薄膜を形成する
ことにより、散光性薄膜の付着強度を高めることができ
て耐久性の優れた電球を製造することができる。
Further, by further forming a reinforcing thin film on the surface of the light-diffusing thin film, the adhesion strength of the light-diffusing thin film can be increased, and a light bulb with excellent durability can be manufactured.

なお、本発明の方法により製造された電球は、光源とし
て各種の分野に利用することができ、その用途は特に限
定されない。
Note that the light bulb manufactured by the method of the present invention can be used as a light source in various fields, and its uses are not particularly limited.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の方法により製造された電球の一例の概
略を示す説明用断面図、第2図〜第4図はディッピング
法の説明図、第5図は散光性薄膜の説明用断面図、第6
図は補強用薄膜の説明用断面図である。 10・・・ガラス製発光管  11・・・フィラメント
20・・・光干渉膜     30・・・散光性薄膜4
0・・・口金       50・・・被覆液60・・
・補強用薄膜
Fig. 1 is an explanatory cross-sectional view showing an outline of an example of a light bulb manufactured by the method of the present invention, Figs. 2 to 4 are explanatory views of the dipping method, and Fig. 5 is an explanatory cross-sectional view of a light-diffusing thin film. , 6th
The figure is an explanatory cross-sectional view of the reinforcing thin film. 10...Glass arc tube 11...Filament 20...Light interference film 30...Diffusing thin film 4
0... Mouthpiece 50... Coating liquid 60...
・Thin reinforcement film

Claims (2)

【特許請求の範囲】[Claims] (1)ガラス製封体管の外表面に多層構成の光干渉膜を
設け、当該光干渉膜の表面にさらに散光性薄膜を設けて
なる電球の製造方法であって、前記散光性薄膜を、シリ
コン化合物の溶液にセラミック材料の微粉末を分散して
なる被覆液を用いてディッピング法により形成すること
を特徴とする電球の製造方法。
(1) A method for manufacturing a light bulb, which comprises providing a multilayered light interference film on the outer surface of a glass envelope tube, and further providing a light-diffusing thin film on the surface of the light-diffusing film, the method comprising: 1. A method of manufacturing a light bulb, characterized in that the light bulb is formed by a dipping method using a coating liquid made by dispersing fine powder of a ceramic material in a solution of a silicon compound.
(2)散光性薄膜の表面にさらに補強用薄膜を形成する
ことを特徴とする請求項1に記載の電球の製造方法。
(2) The method for manufacturing a light bulb according to claim 1, further comprising forming a reinforcing thin film on the surface of the light-diffusing thin film.
JP63151242A 1988-06-21 1988-06-21 How to make a light bulb Expired - Fee Related JP2902404B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63151242A JP2902404B2 (en) 1988-06-21 1988-06-21 How to make a light bulb

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63151242A JP2902404B2 (en) 1988-06-21 1988-06-21 How to make a light bulb

Publications (2)

Publication Number Publication Date
JPH01319244A true JPH01319244A (en) 1989-12-25
JP2902404B2 JP2902404B2 (en) 1999-06-07

Family

ID=15514366

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63151242A Expired - Fee Related JP2902404B2 (en) 1988-06-21 1988-06-21 How to make a light bulb

Country Status (1)

Country Link
JP (1) JP2902404B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005032215A1 (en) * 2003-09-30 2005-04-07 Harison Toshiba Lighting Corp. Tube and ball

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59221968A (en) * 1983-05-31 1984-12-13 東芝ライテック株式会社 Method of forming scattering membrane
JPS6188449A (en) * 1984-10-08 1986-05-06 東芝硝子株式会社 Protective film for reflector

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59221968A (en) * 1983-05-31 1984-12-13 東芝ライテック株式会社 Method of forming scattering membrane
JPS6188449A (en) * 1984-10-08 1986-05-06 東芝硝子株式会社 Protective film for reflector

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005032215A1 (en) * 2003-09-30 2005-04-07 Harison Toshiba Lighting Corp. Tube and ball

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