JPH01294871A - Method for controlling copper foil blackening solution - Google Patents
Method for controlling copper foil blackening solutionInfo
- Publication number
- JPH01294871A JPH01294871A JP12645588A JP12645588A JPH01294871A JP H01294871 A JPH01294871 A JP H01294871A JP 12645588 A JP12645588 A JP 12645588A JP 12645588 A JP12645588 A JP 12645588A JP H01294871 A JPH01294871 A JP H01294871A
- Authority
- JP
- Japan
- Prior art keywords
- copper foil
- potassium persulfate
- soln
- blackening
- sodium hydroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 239000011889 copper foil Substances 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 33
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims abstract description 14
- 239000007800 oxidant agent Substances 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims description 15
- 238000007726 management method Methods 0.000 claims description 3
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 239000011888 foil Substances 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/60—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using alkaline aqueous solutions with pH greater than 8
- C23C22/63—Treatment of copper or alloys based thereon
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Production Of Multi-Layered Print Wiring Board (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分計）
本発明は′醒気機器、計算機器、通信機器等に川すられ
るプリント配線板の夷造工程中のｍ箔黒化処理液の９ｒ
理方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Utilization) The present invention is directed to the use of 9R of m-foil blackening treatment liquid during the fabrication process of printed wiring boards used in ventilation equipment, computing equipment, communication equipment, etc.
It is related to the process method.
従来、プリイト配線板のシ造工程における、内Ｉ−鋼箔
の黒化処理液におりで、酸化剤として過硫酸カリウムを
用いる場合は、液中の酸化剤の自己分解により液組成を
安定管理することが困難で、液をパ噌チ処理毎に廃棄し
たり、一定処理時間毎に液蓋の１／３〜１／２を廃棄し
、廃棄分を新規追加したり、手分析により酸化剤減少値
を解明し遂次新規追加して安定管理を狙ってｂた。Conventionally, when potassium persulfate is used as an oxidizing agent in the blackening treatment solution for steel foil in the manufacturing process of printed circuit boards, the composition of the solution can be stably controlled by self-decomposition of the oxidizing agent in the solution. It is difficult to remove the oxidizing agent by discarding the liquid after each patch treatment, or by discarding 1/3 to 1/2 of the liquid cap at a certain processing time and adding the discarded portion, or by manual analysis. We clarified the decreased value and added new ones one after another, aiming for stable management.
従来の技術で述べたように、バ咋チ処理或は液の一部を
廃棄、新規追加、遂次新規追加する方法は液の安定性、
長寿命性に欠けるとＡう問題があまた０本発明は従来の
技術における上述の問題点に鑑みてなされたもので、そ
の目的とするところは、銅箔黒化処理液の安定性、長寿
命化により液の連続使用を可能にする銅箔黒化処理液の
管理方法を提供することにある。As mentioned in the conventional technology, the method of removing liquid, discarding a part of the liquid, adding new one, and adding new one in succession depends on the stability of the liquid,
The present invention has been made in view of the above-mentioned problems in the conventional technology, and its purpose is to improve the stability and long life of the copper foil blackening treatment solution. An object of the present invention is to provide a method for managing a copper foil blackening treatment solution that enables continuous use of the solution by oxidation.
本発明は酸化剤として過硫酸力１１ウムを用いる銅箔黒
化処理液において、鋼箔処理面積に対応して過硫酸カリ
ウムと水酸化ナトリウムとを補給することを特徴とする
鋼箔黒化処理液の管理方法のため、上記目的を達成する
ことができたもので、以下本発明の詳細な説明する。The present invention is a steel foil blackening treatment characterized in that potassium persulfate and sodium hydroxide are replenished in accordance with the steel foil treatment area in a copper foil blackening treatment solution using 11 um persulfate as an oxidizing agent. Due to the liquid management method, the above object can be achieved, and the present invention will be described in detail below.
本発明は酸化剤として過硫酸カリウムを用する銅箔黒化
処理銭金てに適用することができるもので、銅箔処理面
積に対応して過硫酸カリウムと水酸化ナト１１ウムとを
補給するもので、銅箔処理面積は液量の大きさ等に応じ
て選択することができ、それに対応して補給しも変化す
るが、好ましくは銅箔処理面積５０ゴ毎に、過硫酸カリ
ウム７５０〜１２５０ ｇ、水酸化ナトリウム４００〜
６００ ｆを補給することが望ましＡ、過硫酸力１１ウ
ム、水酸化ナトリウムの童がこの範囲を外れると処理時
間の延長化や銅箔の表面状態が粗大になる傾向にあり好
ましくなり０なお本発明の黒化処理液には電解餉ｆ６、
圧ｉｌ＃、１Ｍ箔の如何を問わす銅箔全般を用すること
ができる。The present invention can be applied to copper foil blackening treatment coins using potassium persulfate as an oxidizing agent, and potassium persulfate and 11 um of sodium hydroxide are replenished in accordance with the area of copper foil treatment. The area to be treated with copper foil can be selected depending on the amount of liquid, etc., and the amount of replenishment will also change accordingly, but preferably 750~750~ 1250 g, sodium hydroxide 400~
It is desirable to replenish 600 f of A, persulfate power of 11 um, and sodium hydroxide. The blackening treatment solution of the present invention includes electrolyte f6,
Any copper foil can be used, whether it is il# or 1M foil.
以下本発明を実施例にもとづｂて説明する。The present invention will be explained below based on examples.
実施例
厚さ３５ミクロンの銅回路層を有する両面回路内層材を
、過硫酸力１１ウム、水酸化ナトＩＩウムを含有する黒
化処理液で黒化処理したが、ψ苗処理面積５０ゴ毎に過
硫酸カリウム１００Ｈ’ 、水酸化ナトＩＩウムｓｏｏ
ｆを黒化処理液に補給した。Example A double-sided circuit inner layer material having a copper circuit layer with a thickness of 35 microns was blackened with a blackening treatment solution containing 11 um persulfate and sodium II hydroxide. potassium persulfate 100H', sodium hydroxide soo
f was replenished into the blackening treatment solution.
比較例
過硫酸カリウム、水酸化ナトリウムを含有する黒化処理
液で厚さ３５ミクロンの銅回路Ｉ−を有する両面回路内
Ｊ−材を処理し、銅回路Ｉ―の黒色が鮮明でなくなった
時期で処理を中止し、液を廃莱し新規液と入れ替えた。Comparative Example: A double-sided circuit J- material with a 35-micron-thick copper circuit I- was treated with a blackening treatment solution containing potassium persulfate and sodium hydroxide, and the time when the black color of the copper circuit I- was no longer clear. The process was stopped, the liquid was discarded, and it was replaced with new liquid.
実施例及び比較例の液の安定性、処理廿は第１表のよう
である。The stability and processing times of the liquids of Examples and Comparative Examples are shown in Table 1.
本発明は上述した如く構成されてＡる。特許請求の範り
ｍ第１項、第２項に記載した構成を有−する銅箔黒化処
理液の管理方法においては、黒化処理液の安定性、長寿
命化、連続使用を達成できる効果を有してＡる。The present invention is constructed as described above. In the method for managing a copper foil blackening treatment liquid having the structure described in claims 1 and 2, it is possible to achieve stability, long life, and continuous use of the blackening treatment liquid. It has an effect.
Claims (2)
理液において、銅箔処理面積に対応して過硫酸カリウム
と水酸化ナトリウムとを補給することを特徴とする銅箔
黒化処理液の管理方法。(1) A copper foil blackening treatment solution that uses potassium persulfate as an oxidizing agent, and is characterized in that potassium persulfate and sodium hydroxide are replenished in accordance with the copper foil treatment area. Management method.
５０〜１２５０ｇ、水酸化ナトリウム４００〜６００ｇ
を補給することを特徴とする特許請求の範囲第１項記載
の銅箔黒化処理液の管理方法。(2) For every 50m^2 of copper foil treatment area, add 7 parts of potassium persulfate.
50-1250g, sodium hydroxide 400-600g
A method for managing a copper foil blackening treatment liquid according to claim 1, characterized in that the copper foil blackening treatment liquid is replenished with the following:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12645588A JPH01294871A (en) | 1988-05-23 | 1988-05-23 | Method for controlling copper foil blackening solution |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12645588A JPH01294871A (en) | 1988-05-23 | 1988-05-23 | Method for controlling copper foil blackening solution |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01294871A true JPH01294871A (en) | 1989-11-28 |
Family
ID=14935647
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12645588A Pending JPH01294871A (en) | 1988-05-23 | 1988-05-23 | Method for controlling copper foil blackening solution |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01294871A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009084652A (en) * | 2007-10-01 | 2009-04-23 | Hitachi Chem Co Ltd | Oxidation treatment method and oxidation treatment liquid for metal |
| CN104060262A (en) * | 2014-05-26 | 2014-09-24 | 安徽红桥金属制造有限公司 | Novel process for treating cast piece surface blackening |
| KR101699790B1 (en) * | 2016-08-01 | 2017-01-25 | 와이엠티 주식회사 | Composition for blackening metal thin film |
-
1988
- 1988-05-23 JP JP12645588A patent/JPH01294871A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009084652A (en) * | 2007-10-01 | 2009-04-23 | Hitachi Chem Co Ltd | Oxidation treatment method and oxidation treatment liquid for metal |
| CN104060262A (en) * | 2014-05-26 | 2014-09-24 | 安徽红桥金属制造有限公司 | Novel process for treating cast piece surface blackening |
| KR101699790B1 (en) * | 2016-08-01 | 2017-01-25 | 와이엠티 주식회사 | Composition for blackening metal thin film |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2118549T3 (en) | PROCEDURE AND DEVICE FOR THE DEPOSITION BY ELECTROLYSIS OF THE METAL LAYERS. | |
| GB2123036A (en) | Electroplating non-metallic surfaces | |
| JPH01294871A (en) | Method for controlling copper foil blackening solution | |
| DD232514A5 (en) | METHOD FOR PRODUCING A CATHODE WITH LOW HYDROGEN SUPPLY VOLTAGE | |
| US5458763A (en) | Method for forming wiring pattern | |
| CA2296900A1 (en) | Electroplating solution for electroplating lead and lead/tin alloys | |
| CN111020643B (en) | Double-sided smooth copper foil and preparation method and device thereof | |
| JP2001348684A (en) | Surface-roughening agent for aluminum of aluminum alloy and surface-roughening method using the agent | |
| CN103233259B (en) | The oxidation processing technique of CTP plate | |
| JP2752445B2 (en) | Epoxy resin etching method | |
| KR100298012B1 (en) | Method of manufacturing metal foil by electrolysis | |
| ATE32106T1 (en) | PROCESS FOR PRODUCTION OF ACTIVE ALUMINUM OXIDE. | |
| JP4918342B2 (en) | Copper foil roughening treatment method | |
| DE2962623D1 (en) | A method of treating aluminium foil or a lithographic printing plate support and products so obtained | |
| JPH01178496A (en) | Production of plate base for lithography | |
| IL98645A (en) | Alkaline etching solution | |
| JPS5644795A (en) | Anodic oxidation of aluminum | |
| CN114086229B (en) | Groove liquid for preparing liquid absorption core and preparation method of liquid absorption core | |
| DE3676053D1 (en) | METHOD AND DEVICE FOR PRODUCING A HIGH-THIN METAL FILM BY GALVANIC COATING. | |
| JPS5558394A (en) | Dip coloring method of aluminum or alloy thereof | |
| JP3157678U (en) | Electrolytic plating system | |
| US20050000815A1 (en) | Plate for offset printing and method for manufacturing said plate | |
| SU1696614A1 (en) | Electrolyte for removal of copper coats | |
| US5174869A (en) | Method of producing aluminum support for printing plate | |
| JPS56130494A (en) | Coloring method for copper or copper alloy material |