JPH01290503A - Ozone reactor - Google Patents
Ozone reactorInfo
- Publication number
- JPH01290503A JPH01290503A JP12140288A JP12140288A JPH01290503A JP H01290503 A JPH01290503 A JP H01290503A JP 12140288 A JP12140288 A JP 12140288A JP 12140288 A JP12140288 A JP 12140288A JP H01290503 A JPH01290503 A JP H01290503A
- Authority
- JP
- Japan
- Prior art keywords
- pipe member
- discharge
- induction electrode
- peripheral surface
- electrodes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims description 13
- 230000006698 induction Effects 0.000 claims abstract description 15
- 230000002093 peripheral effect Effects 0.000 claims abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 10
- 230000005684 electric field Effects 0.000 abstract description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 abstract description 4
- 239000001301 oxygen Substances 0.000 abstract description 4
- 229910001220 stainless steel Inorganic materials 0.000 abstract description 3
- 239000010935 stainless steel Substances 0.000 abstract description 3
- 239000000919 ceramic Substances 0.000 abstract description 2
- 239000004020 conductor Substances 0.000 abstract description 2
- 239000011521 glass Substances 0.000 abstract description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052721 tungsten Inorganic materials 0.000 abstract description 2
- 239000010937 tungsten Substances 0.000 abstract description 2
- 230000009466 transformation Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 15
- 239000003989 dielectric material Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/10—Preparation of ozone
- C01B13/11—Preparation of ozone by electric discharge
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2201/00—Preparation of ozone by electrical discharge
- C01B2201/20—Electrodes used for obtaining electrical discharge
- C01B2201/22—Constructional details of the electrodes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2201/00—Preparation of ozone by electrical discharge
- C01B2201/30—Dielectrics used in the electrical dischargers
- C01B2201/34—Composition of the dielectrics
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明はオゾン反応器に係り、特に強力な酸化剤とし
て、殺菌、脱臭、脱色等に用いられるオゾンを、酸素か
ら放電によって生成するオゾン発生器用オゾン反応器に
関する。[Detailed Description of the Invention] [Field of Industrial Application] This invention relates to an ozone reactor, and particularly relates to an ozone reactor that generates ozone, which is used as a particularly strong oxidizing agent for sterilization, deodorization, decolorization, etc., from oxygen by electrical discharge. Regarding the handy ozone reactor.
従来の上記オゾン発生器におけるオゾン反応器としては
、無声放電方式、沿面放電方式、ストリーマコロナ放電
方式があり、種々提案されている。As the ozone reactor in the conventional ozone generator, there are a silent discharge method, a creeping discharge method, and a streamer corona discharge method, and various types have been proposed.
無声放電方式は、第3図に示すように、はf等面積の@
極a + bを所定の間隙1をおいて対向設置し、こ
の間隙f内におかれる誘電体Cを介して電極a、bに電
源dから交流高電圧を印加することにより無声放電を発
生させるものである。In the silent discharge method, as shown in Figure 3,
Poles a + b are placed facing each other with a predetermined gap 1 in between, and a silent discharge is generated by applying an AC high voltage from a power source d to electrodes a and b via a dielectric C placed within this gap f. It is something.
また沿面放電方式は、第4図に示すように、誘電体Cの
表面に放電極aが、同裏面に誘導電極すが設けられ、電
源dから交流高電圧を印加して誘電体Cの表面に沿面放
電を起させるものである。In addition, in the creeping discharge method, as shown in Fig. 4, a discharge electrode a is provided on the front surface of a dielectric material C, and an induction electrode is provided on the back surface of the dielectric material C, and a high AC voltage is applied from a power source d to This causes creeping discharge.
さらにストリーマコロナ放電方式は、第5図に示すよう
に、放電ff1aと誘導雷′If4bとの間に電源dよ
り交流高電圧を印加し、放t 極aよりストリーマコロ
ナ放電を発生させるものである。この場合図示のように
、誘電体Cを介在させることもある。Furthermore, in the streamer corona discharge method, as shown in Fig. 5, a high AC voltage is applied from a power source d between the discharge ff1a and the induction lightning 'If4b, and a streamer corona discharge is generated from the discharge pole a. . In this case, a dielectric C may be interposed as shown in the figure.
しかるに前記無声放電方式では、大きい印加電圧が必要
であり、これを小さくするため誘電体Cと電iaとの間
の間隙j (ギャップ)を高い寸法精度をもって極力小
さくすることが必要となり、そのため組立てが容易でな
く、また静電容量が大きいため、発熱量が大きいうえ、
高周波化のための電力損失が大きいという問題がある。However, the silent discharge method requires a large applied voltage, and in order to reduce this, it is necessary to make the gap j (gap) between the dielectric C and the electric current as small as possible with high dimensional accuracy. It is not easy to use, and the capacitance is large, so it generates a lot of heat, and
There is a problem in that power loss due to high frequency is large.
また沿面放電方式では、電界が極部的に集中しやすいと
共に平均電界が低く、電極aの尖鋭部を例えば、r=
0.5m/ m以上に丸めて尖鋭でなくすることが必要
となり、加えて静電容量が大きいうえ誘電体の発熱量が
非常に大きいなどの問題がある。In addition, in the creeping discharge method, the electric field tends to concentrate locally and the average electric field is low.
It is necessary to round it to 0.5 m/m or more so that it is not sharp, and in addition, there are problems such as the capacitance is large and the amount of heat generated by the dielectric is extremely large.
さらにストリーマコロナ放電方式は、印加電圧が大きい
など、前記無声放電方式と同様な問題がある。Furthermore, the streamer corona discharge method has the same problems as the silent discharge method, such as the large applied voltage.
この発明は上記の点に鑑み、静電容量を小さくして電源
高周波化時の損失を少なくすると同時に、小型であって
組立てが容易であり、効率よく酸素からオゾンを生成す
ることができる高性能なオゾン発生器におけるオゾン反
応器を提供することを目的としてなされたものである。In view of the above points, this invention has been developed to reduce capacitance and reduce loss when the power frequency is increased, and at the same time, it is small and easy to assemble, and has high performance that can efficiently generate ozone from oxygen. The purpose of this invention is to provide an ozone reactor in an ozone generator.
〔課題を解決するための手段〕
上記従来技術が有する課題を解決するためこの考案は、
固体誘電体としての管部材の外周面軸方向中央部付近に
円筒状の誘導電極を嵌着し、前記管部材の内周面にそっ
て1ないし複数本の細線状の放電極を配設してなり、前
記各電極を電源に接続するようにしたことを特徴とする
ものである。[Means for solving the problem] In order to solve the problem of the above-mentioned conventional technology, this invention is as follows.
A cylindrical induction electrode is fitted near the axial center of the outer peripheral surface of a tube member as a solid dielectric, and one or more thin wire-shaped discharge electrodes are arranged along the inner peripheral surface of the tube member. The device is characterized in that each of the electrodes is connected to a power source.
管部材の外周の誘導電極と内周の放電極に交流高電圧が
印加されると、放電極の電界は固体誘電体としての管部
材により平均電界化される。また放電極は細い線状であ
るため、管部材の内部空間部に強いストリーマコロナ放
電が起り、同時に管部材に近接した部分において沿面放
電も発生し、これらにより管部材の内部を流れる酸素を
効率よくオゾン化することができる。When an AC high voltage is applied to the induction electrode on the outer periphery and the discharge electrode on the inner periphery of the tube member, the electric field of the discharge electrode is averaged by the tube member as a solid dielectric. In addition, since the discharge electrode is a thin wire, a strong streamer corona discharge occurs in the inner space of the tube member, and at the same time, a creeping discharge occurs in the vicinity of the tube member, which makes it possible to efficiently control the oxygen flowing inside the tube member. Can be easily ozonated.
以下この考案の実施例を第1図、第2図を参照して説明
する。An embodiment of this invention will be described below with reference to FIGS. 1 and 2.
固体誘電体としての管部材1は、耐熱ガラス、弗素系樹
脂、セラミック、PVC等からなり、この管部材1の軸
方向中央部付近の外周面に該管部材1のはゾ1/2の長
さを有する円筒状の誘導電極2か外嵌固着されている。The tube member 1 as a solid dielectric is made of heat-resistant glass, fluorine-based resin, ceramic, PVC, etc. A cylindrical induction electrode 2 having a diameter is fixedly fitted onto the outside.
この誘導電極2は、銅板、アルミニウム板、ステンレス
板等の導電材料からなっている。The induction electrode 2 is made of a conductive material such as a copper plate, an aluminum plate, or a stainless steel plate.
前記管部材lの内部には、管部材1の内周面に沿うよう
にして1ないし複数本の放電極3.3か管部材1の全長
にわって配設され、この放電極3゜3はステンレススチ
ール、タングステン等からなっており、その半径が0.
05 m/ m乃至それ以下の極めて細い細線状に形成
されている。Inside the pipe member 1, one or more discharge electrodes 3.3 are disposed along the inner peripheral surface of the pipe member 1 along the entire length of the pipe member 1, and the discharge electrodes 3.3 is made of stainless steel, tungsten, etc., and its radius is 0.
It is formed into an extremely thin wire shape of 0.05 m/m or less.
上記誘導電極2および放電極3,3は、導線4゜4を介
して交流電源5に接続されるようになっており、これら
電極2,3に交流高電圧を印加することができるように
配線される。The induction electrode 2 and the discharge electrodes 3, 3 are connected to an AC power source 5 via conductive wires 4.4, and the wiring is arranged so that an AC high voltage can be applied to these electrodes 2, 3. be done.
したがって電源5から誘導電極2および放電極3.3に
交流高電圧を印加すると、誘導電極2の電界は固体誘電
体としての管部材1により平等電界化される。また放電
1f13.3は、半径が0.0511ノIm以下と極め
て細い線材であるから、管部材1内の空間に強いストリ
ーマコロナ放電が発生し、同時に放電極3が管部材1の
内周面に近接している部分では沿面放電が発生する。こ
れにより静電容量が小さく、電源高周波化のための電力
も少なくてすむ。Therefore, when a high AC voltage is applied from the power source 5 to the induction electrode 2 and the discharge electrode 3.3, the electric field of the induction electrode 2 is made equal by the tube member 1 as a solid dielectric. Furthermore, since the discharge 1f13.3 is an extremely thin wire with a radius of 0.0511 mm or less, a strong streamer corona discharge occurs in the space inside the tube member 1, and at the same time, the discharge electrode 3 is connected to the inner peripheral surface of the tube member 1. Creeping discharge occurs in areas close to. As a result, the capacitance is small, and less power is required for increasing the frequency of the power supply.
以上説明したようにこの発明によれば、放電極を極めて
細い細線電極とし、かつこれを固体誘電体としての管部
材の内周面にそって配設しであるので、沿面放電におい
て問題となる電界の局部的集中が減少すると共に印加電
圧を沿面放電と同様に低くすることができる。またスト
リーマコロナ放電と沿面放電が同時に発生するので、オ
ゾンの生成効率が高く、しかも静電容量が無声放電方式
に比し1150、沿面放電方式に比し1/10と小さく
することができる。そして固体誘電体としての管部材の
内部が空気流路を兼ねるので、ケースか不要となり、オ
ゾン反応器を小型化することができ、寸法精度もラフで
よいことと相俟って安価に提供することができる。また
高周波化のための電圧が小さくてすむため、電源装置も
小型で安価となり、しかも静電容量が小さくできるため
高周波化しても電力損失が少ないなどの効果がある。As explained above, according to the present invention, the discharge electrode is an extremely thin wire electrode, and this is arranged along the inner peripheral surface of the tube member as a solid dielectric, which causes problems in creeping discharge. The local concentration of the electric field is reduced and the applied voltage can be made as low as creeping discharge. Furthermore, since the streamer corona discharge and the creeping discharge occur simultaneously, the ozone generation efficiency is high, and the capacitance can be reduced to 1150 compared to the silent discharge method and 1/10 compared to the creeping discharge method. Since the inside of the tube member, which is a solid dielectric, also serves as an air flow path, there is no need for a case, and the ozone reactor can be made smaller, and the dimensional accuracy can be rough, so it can be provided at a low price. be able to. In addition, since the voltage required for increasing the frequency is small, the power supply device is also small and inexpensive, and since the capacitance can be made small, power loss is small even when the frequency is increased.
第1図はこの発明の一実施例を示す縦断側面図、第2図
は第1図のA−A線相当断面図、第3図ないし第5図は
従来技術を示すもので、第3図は無声放電方式、第4図
は沿面放電方式、第5図はストリーマコロナ放電方式を
示す説明図である。
1・・・固体誘電体としての管部材、2・・・誘導電極
、3・・・放電極、5・・・交流電源。
出願人 石川島播磨重工業株式会社FIG. 1 is a vertical sectional side view showing one embodiment of the present invention, FIG. 2 is a sectional view corresponding to the line A-A in FIG. 4 is an explanatory diagram showing a silent discharge method, FIG. 4 is a creeping discharge method, and FIG. 5 is a streamer corona discharge method. DESCRIPTION OF SYMBOLS 1... Pipe member as a solid dielectric, 2... Induction electrode, 3... Discharge electrode, 5... AC power supply. Applicant Ishikawajima Harima Heavy Industries Co., Ltd.
Claims (1)
円筒状の誘導電極を嵌着し、前記管部材の内周面にそつ
て1ないし複数本の細線状の放電極を配設してなり、前
記各電極を電源に接続するようにしたことを特徴とする
オゾン反応器。A cylindrical induction electrode is fitted near the axial center of the outer peripheral surface of a tube member as a solid dielectric, and one or more thin wire-shaped discharge electrodes are arranged along the inner peripheral surface of the tube member. An ozone reactor characterized in that each of the electrodes is connected to a power source.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63121402A JP2576590B2 (en) | 1988-05-18 | 1988-05-18 | Ozone reactor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63121402A JP2576590B2 (en) | 1988-05-18 | 1988-05-18 | Ozone reactor |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH01290503A true JPH01290503A (en) | 1989-11-22 |
JP2576590B2 JP2576590B2 (en) | 1997-01-29 |
Family
ID=14810290
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP63121402A Expired - Fee Related JP2576590B2 (en) | 1988-05-18 | 1988-05-18 | Ozone reactor |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2576590B2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000005170A1 (en) * | 1998-07-21 | 2000-02-03 | Drimal Jiri | Device for producing ozone |
CN106744700A (en) * | 2017-01-11 | 2017-05-31 | 广州市钜业环保科技发展有限公司 | A kind of ozone generator |
-
1988
- 1988-05-18 JP JP63121402A patent/JP2576590B2/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000005170A1 (en) * | 1998-07-21 | 2000-02-03 | Drimal Jiri | Device for producing ozone |
CN106744700A (en) * | 2017-01-11 | 2017-05-31 | 广州市钜业环保科技发展有限公司 | A kind of ozone generator |
Also Published As
Publication number | Publication date |
---|---|
JP2576590B2 (en) | 1997-01-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
LAPS | Cancellation because of no payment of annual fees |