JPH01283211A - Emulsified enamel remover - Google Patents
Emulsified enamel removerInfo
- Publication number
- JPH01283211A JPH01283211A JP11073488A JP11073488A JPH01283211A JP H01283211 A JPH01283211 A JP H01283211A JP 11073488 A JP11073488 A JP 11073488A JP 11073488 A JP11073488 A JP 11073488A JP H01283211 A JPH01283211 A JP H01283211A
- Authority
- JP
- Japan
- Prior art keywords
- poe
- emulsified
- enamel
- water
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 210000003298 dental enamel Anatomy 0.000 title claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract description 14
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract description 8
- 239000000975 dye Substances 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- 229940057995 liquid paraffin Drugs 0.000 abstract description 2
- 239000002304 perfume Substances 0.000 abstract 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 abstract 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 abstract 1
- 229920000053 polysorbate 80 Polymers 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229940124543 ultraviolet light absorber Drugs 0.000 abstract 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 abstract 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 31
- -1 polyoxyethylene Polymers 0.000 description 11
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
- 229930195729 fatty acid Natural products 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 10
- 229920001214 Polysorbate 60 Polymers 0.000 description 8
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- 239000004359 castor oil Substances 0.000 description 6
- 235000019438 castor oil Nutrition 0.000 description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 6
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000001593 sorbitan monooleate Substances 0.000 description 4
- 229940035049 sorbitan monooleate Drugs 0.000 description 4
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- 230000005856 abnormality Effects 0.000 description 3
- 238000005238 degreasing Methods 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 235000011069 sorbitan monooleate Nutrition 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- RKJGFHYCZPZJPE-UHFFFAOYSA-N 2,2-bis(16-methylheptadecanoyloxymethyl)butyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(CC)(COC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C RKJGFHYCZPZJPE-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 235000004443 Ricinus communis Nutrition 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920001983 poloxamer Polymers 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 229940118594 trimethylolpropane triisostearate Drugs 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- QYIXCDOBOSTCEI-QCYZZNICSA-N (5alpha)-cholestan-3beta-ol Chemical compound C([C@@H]1CC2)[C@@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@H](C)CCCC(C)C)[C@@]2(C)CC1 QYIXCDOBOSTCEI-QCYZZNICSA-N 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- DXMNMEWATKSWOT-UHFFFAOYSA-N 1-[2,3-di(nonyl)phenoxy]-2,3-di(nonyl)benzene Chemical compound CCCCCCCCCC1=CC=CC(OC=2C(=C(CCCCCCCCC)C=CC=2)CCCCCCCCC)=C1CCCCCCCCC DXMNMEWATKSWOT-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- JPPRXACMNPYJNK-UHFFFAOYSA-N 1-docosoxydocosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCCCCCC JPPRXACMNPYJNK-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- JWKSQNWLEIABLH-UHFFFAOYSA-N 1-octan-2-yloxydodecane Chemical compound CCCCCCCCCCCCOC(C)CCCCCC JWKSQNWLEIABLH-UHFFFAOYSA-N 0.000 description 1
- QQXJNLYVPPBERR-UHFFFAOYSA-N 1-phenyldecan-1-one Chemical compound CCCCCCCCCC(=O)C1=CC=CC=C1 QQXJNLYVPPBERR-UHFFFAOYSA-N 0.000 description 1
- JNAYPSWVMNJOPQ-UHFFFAOYSA-N 2,3-bis(16-methylheptadecanoyloxy)propyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C JNAYPSWVMNJOPQ-UHFFFAOYSA-N 0.000 description 1
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 208000035450 Malformed Nails Diseases 0.000 description 1
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 229920002359 Tetronic® Polymers 0.000 description 1
- CMPDPBDUZTUXAD-UHFFFAOYSA-N [3-hydroxy-2-(16-methylheptadecanoyloxy)propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(CO)OC(=O)CCCCCCCCCCCCCCC(C)C CMPDPBDUZTUXAD-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- QYIXCDOBOSTCEI-UHFFFAOYSA-N alpha-cholestanol Natural products C1CC2CC(O)CCC2(C)C2C1C1CCC(C(C)CCCC(C)C)C1(C)CC2 QYIXCDOBOSTCEI-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- UNZOESWLBMZBEY-YHZPTAEISA-N bis(16-methylheptadecyl) (z)-but-2-enedioate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)\C=C/C(=O)OCCCCCCCCCCCCCCCC(C)C UNZOESWLBMZBEY-YHZPTAEISA-N 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
- 229940074928 isopropyl myristate Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- ZPIRTVJRHUMMOI-UHFFFAOYSA-N octoxybenzene Chemical compound CCCCCCCCOC1=CC=CC=C1 ZPIRTVJRHUMMOI-UHFFFAOYSA-N 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野コ
本発明は新規な乳化エナメルリムーバーに関する。ざら
に詳しくは、使用後のマイルド感に優れ、爪の損傷度合
を著しく改善し、かつエナメルを再塗布した場合の経時
のもち(はがれ)にも優れた乳化エナメルリムーバーに
関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a novel emulsified enamel remover. More specifically, the present invention relates to an emulsified enamel remover that provides an excellent mild feeling after use, significantly improves the degree of damage to nails, and has excellent retention (peeling) over time when enamel is reapplied.
[従来の技術]
従来エナメルリムーバーは、アセトン、酢酸エチル、酢
酸ブチル、そしてアルコール等を主基剤とし、必要に応
じて油分、水、染料などが配合されていた。この様な液
状のエナメルリムーバーは除去力に優れたもので広く愛
用きれているが、二枚重、ワレなと爪の損傷をひきおこ
す原因となっていた。[Prior Art] Conventionally, enamel removers have been made of acetone, ethyl acetate, butyl acetate, alcohol, etc. as main bases, and oils, water, dyes, etc. have been added as necessary. Such liquid enamel remover has excellent removal power and is widely used, but it is double coated and cracks, causing damage to the nails.
ところで、通常爪には7.0〜1).0%の水分と0゜
1〜1.0重量%の脂質が存在している。そして、爪体
からの水分補給がされながら爪の保護がなされている。By the way, nails usually have a rating of 7.0 to 1). There is 0% water and 0.1-1.0% fat by weight. The nail is protected while being supplied with water from the nail body.
しかし、エナメルリムーバーを使用することにより、溶
剤による脱水作用、脱脂作用とともに爪巾の水分揮散が
高まり、爪は柔軟性を失い経時で2枚重、ワレなどの爪
の損傷をひきおこす結果となる。従来のエナメルリムー
バーは油分、水分などが配合されているにもかかわらず
、溶剤による脱水作用、脱脂作用が非常に高いものであ
った。However, the use of enamel remover increases the dehydration and degreasing effects of the solvent as well as the water volatilization from the nail width, resulting in the nails losing flexibility and causing damage to the nails such as double layering and cracking over time. Although conventional enamel removers contain oil and water, they have extremely high dehydration and degreasing effects due to the use of solvents.
[発明が解決しようとしている課題]
本発明者らは、このような事情にかんがみ、鋭意研究を
重ねた結果、溶剤と多価アルコールと界面活性剤と水と
を含有する乳化エナメルリムーバーが、溶剤の脱水作用
、脱脂作用を弱め、しかも多価アルコールによる保湿効
果をもたせた非常に爪にマイルドな画期的なものである
ことを見いだし、この知見に基づいて本発明を完成させ
るに至った。[Problems to be Solved by the Invention] In view of the above circumstances, the present inventors have conducted intensive research and found that an emulsified enamel remover containing a solvent, a polyhydric alcohol, a surfactant, and water is We have discovered that it is a revolutionary product that is extremely mild to the nails by weakening the dehydrating and degreasing effects of polyhydric alcohol, and also has the moisturizing effect of polyhydric alcohol.Based on this knowledge, we have completed the present invention.
[課題を解決するための手段]
すなわち、本発明は溶剤と、多価アルコールと、界面活
性剤と、水とを含有することを特徴とする乳化エナメル
リムーバーである。[Means for Solving the Problems] That is, the present invention is an emulsified enamel remover characterized by containing a solvent, a polyhydric alcohol, a surfactant, and water.
以下に本発明の構成について述べる。The configuration of the present invention will be described below.
本発明で用いられる溶剤は、通常美爪料に用いられるも
のでよく例えばアセトン、酢酸nブチル、酢酸エチル等
である。しかも、水との混合系において2層分離する領
域でなければならない。The solvent used in the present invention may be one commonly used in nail polishes, such as acetone, n-butyl acetate, ethyl acetate, and the like. Moreover, it must be in a region where two layers can be separated in a mixed system with water.
これら成分の好ましい配合量は、例えばアセトン、酢酸
ブチル、水混合系においては、アセトン0〜50.0重
量%、酢酸ブチル30,0〜80.0重量%、水は5.
0〜30.0重量%である。For example, in a mixed system of acetone, butyl acetate, and water, the preferred blending amounts of these components are 0 to 50.0% by weight of acetone, 30.0 to 80.0% by weight of butyl acetate, and 5.0% by weight of water.
It is 0 to 30.0% by weight.
本発明で用いられる多価アルコールは、従来、化粧品に
用いられる周知のものでよい。例えば、プロピレングリ
コール、ジプロピレングリコール、1.3−ブチレング
リコール、ダイナマイトグリセリン、ソルビトール、マ
ルヂト−ルなどが挙げられ、これらの成分の一種または
二種以上が配合できる。これら成分の好ましい配合量は
1.0〜10゜0重量%であり、更に好ましくは3.0
〜7.0重量%である。1.0重量%未満では界面活性
剤との組合せにおいて、安定な乳化系が得られない。ま
た、10.0重量%を越えると、安定な乳化系が得られ
ず、また、使用後のざっばりざに欠は好ましくない。The polyhydric alcohol used in the present invention may be any of the well-known polyhydric alcohols conventionally used in cosmetics. Examples include propylene glycol, dipropylene glycol, 1,3-butylene glycol, dynamite glycerin, sorbitol, and malditol, and one or more of these components can be blended. The preferred blending amount of these components is 1.0 to 10% by weight, more preferably 3.0% by weight.
~7.0% by weight. If the amount is less than 1.0% by weight, a stable emulsion system cannot be obtained in combination with a surfactant. Moreover, if it exceeds 10.0% by weight, a stable emulsified system cannot be obtained, and it is not preferable that it becomes rough after use.
本発明で用いられる界面活性剤は、親水性の界面活性剤
であれば使用可能である。例えば、ポリオキシエチレン
(以下POEと略記する)ソルビタンモノオレエート、
POE−ソルビタンモノステアレート、POE−ソルビ
タンモノオレート、POEソルビタンテトラオレエート
等のPOEソルビタン脂肪酸エステル類、POEソルビ
ットモノラウレ−1−1POEソルビツトモノオレエー
ト、POEソルビットペンタオレエート、POEソルビ
ットモノステアレート等のPOEソルビット脂肪酸エス
テル類、POEグリセリンモノステアレート、POEグ
リセリンモノイソステアレート、POEグリセリントリ
イソステアレート等のPOEグリセリン脂肪酸エステル
類、POEモノオレエート、POEジステアレート、P
OEモノジメジエート、ジステアリン酸エチレングリコ
ール等のPOE脂肪酸エステル類、POEラウリルエー
テル、POEオレイルエーテル、POEステアリルエー
テル、POEベヘニルエーテル、POE2−オクチルド
デシルエーテル、POEコレスタノールエーテル等のP
OEアルキルエーテル類、POEオクチルフェニルエー
テル、POEノニルフェニルエーテル、POEジノニル
フェニルエーテル等のPOEアルキルフェニルエーテル
類、プルロニック等のプルロニック型類、POE−PQ
Pセチルエーテル、POE−POE2−デ゛シルテトラ
デシルエーテル、POE−POPモノブチルエーテル、
POE−POP水添ラノリン、POE−P叶グリセリン
エニテル等のPOE4POPアルキルエーテル類、テト
ロニック等のテトラPOE・テトラPOPエチレンジア
ミン縮合物類、POEヒマシ油、POE硬化ヒマシ油、
POE硬化硬化ヒマシフモノイソステアレートOE硬化
ヒ!シ油トリイソステアレート、POE硬化硬化ヒマシ
フモノピログルタミン酸モノイソステアリン酸ジエステ
ルOE硬化ヒマシ油マレイン酸等のPOEヒマシ油硬化
ヒマシ油誘導体、POEソルビットミツロウ等のPOE
ミツロウ・ラノリン誘導体、ヤシ油脂肪酸ジェタノール
アミド、ラウリン酸モノエタノールアミド、脂肪酸イソ
プロパツールアミド等のアルカノールアミド、POEプ
ロピレングリコール脂肪酸エステル、POEアルキルア
ミン、POE脂肪酸アミド、ショ糖脂肪酸エステル、P
OEノニルフェニルホルムアルデヒド縮合物、アルキル
エトキシジメチルアミンオキシド、トリオレイルリン酸
等が挙げられる。これら成分の一種または二種以上を使
用できる。これら成分の好ましい配合量は0.1〜7.
0重量%であり、更に好ましくは2.0〜4.0重量%
である。0.1重量%未満または、7.0重量%を越え
ると、安定な乳化系が得られず好ましくない。The surfactant used in the present invention can be any hydrophilic surfactant. For example, polyoxyethylene (hereinafter abbreviated as POE) sorbitan monooleate,
POE sorbitan fatty acid esters such as POE-sorbitan monostearate, POE-sorbitan monooleate, POE sorbitan tetraoleate, POE sorbitan monolaure-1-1, POE sorbitan monooleate, POE sorbitan pentaoleate, POE sorbitan monooleate POE sorbitol fatty acid esters such as stearate, POE glycerin fatty acid esters such as POE glycerin monostearate, POE glycerin monoisostearate, POE glycerin triisostearate, POE monooleate, POE distearate, POE
POE fatty acid esters such as OE monodimedieate and ethylene glycol distearate, POE lauryl ether, POE oleyl ether, POE stearyl ether, POE behenyl ether, POE 2-octyl dodecyl ether, POE cholestanol ether, etc.
OE alkyl ethers, POE alkylphenyl ethers such as POE octylphenyl ether, POE nonylphenyl ether, POE dinonylphenyl ether, Pluronic types such as Pluronic, POE-PQ
P cetyl ether, POE-POE2-decyltetradecyl ether, POE-POP monobutyl ether,
POE-POP hydrogenated lanolin, POE4POP alkyl ethers such as POE-P Kano Glycerin Enitel, tetra-POE/tetra-POP ethylenediamine condensates such as Tetronic, POE castor oil, POE hydrogenated castor oil,
POE hardening hardening castor monoisostearate OE hardening! POE such as castor oil triisostearate, POE cured castor monopyroglutamic acid monoisostearate diester OE hydrogenated castor oil maleic acid, etc. POE castor oil hydrogenated castor oil derivatives, POE sorbitol beeswax etc.
Beeswax and lanolin derivatives, alkanolamides such as coconut oil fatty acid jetanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, POE propylene glycol fatty acid ester, POE alkylamine, POE fatty acid amide, sucrose fatty acid ester, POE
Examples include OE nonylphenyl formaldehyde condensate, alkyl ethoxydimethylamine oxide, trioleyl phosphoric acid, and the like. One or more of these components can be used. The preferred blending amount of these components is 0.1 to 7.
0% by weight, more preferably 2.0 to 4.0% by weight
It is. If it is less than 0.1% by weight or more than 7.0% by weight, a stable emulsion system cannot be obtained, which is not preferable.
本発明で用いられる水の配合量は1.0〜30.0重量
%であり、更に好ましくは10.0〜20.0重量%で
ある。1,0重量%未満では爪へのマイルド感がな<
、30.0重量%を越えると、除去力か劣り好ましくな
い。The amount of water used in the present invention is 1.0 to 30.0% by weight, more preferably 10.0 to 20.0% by weight. If it is less than 1.0% by weight, it will not feel mild to the nails.
If it exceeds 30.0% by weight, the removal power will be poor and this is not preferred.
本発明の乳化エナメルリムーバーには、上記必須成分以
外に通常美爪料類に使用される成分、例えば流動パラフ
ィン、スクワランなどの炭化水素系油分、イソプロピル
ミリステート、トリメチロールプロパントリイソステア
レート、トリメチロールプロパントリー2−エヂルヘキ
サノエート、グリセリルジイソステアレート、ジイソス
テアリルマレート、セチル−2−エチルヘキザノエート
などのエステル系油分、メヂルボリシロキサンなどのシ
リコン系油分、炭化水素系ワックス、エステル系ワック
ス、高級脂肪酸等の油分、薬剤、染料、香料、紫外線吸
収剤等を適量配合することができる。もちろん、これら
は本発明の目的を損なわない質的、量的条件下で使用さ
れなければならない。In addition to the above-mentioned essential ingredients, the emulsified enamel remover of the present invention contains ingredients commonly used in nail polishes, such as hydrocarbon oils such as liquid paraffin and squalane, isopropyl myristate, trimethylolpropane triisostearate, and trimethylolpropane triisostearate. Ester-based oils such as methylolpropanetri-2-edylhexanoate, glyceryl diisostearate, diisostearyl maleate, and cetyl-2-ethylhexanoate, silicone-based oils such as methylbolysiloxane, and hydrocarbon-based oils. Appropriate amounts of waxes, ester waxes, oils such as higher fatty acids, drugs, dyes, fragrances, ultraviolet absorbers, etc. can be blended. Of course, these must be used under qualitative and quantitative conditions that do not impair the purpose of the present invention.
[発明の効果]
本発明は使用後のマイルド感に優れ、爪の損傷度合を著
しく改善し、かつエナメルを再塗布した場合の経時のも
ち(はがれ)にも優れた乳化エナメルリムーバーに関す
る。[Effects of the Invention] The present invention relates to an emulsified enamel remover that provides an excellent mild feeling after use, significantly improves the degree of damage to nails, and has excellent retention (peel-off) over time when enamel is reapplied.
[実施例コ
以下、実施例にJ:って本発明の詳細な説明する。本発
明はこれらに限定きれるものではない。[Example J: Hereinafter, the present invention will be described in detail in Examples. The present invention is not limited to these.
配合量は重量%である。The blending amount is in weight%.
実施例に先立ち、効果試験方法及び評価方法について詳
述する。Prior to Examples, effectiveness testing methods and evaluation methods will be described in detail.
1囮安坐立
50m Q、サンプル管に入れ50℃恒温槽て1ケ月間
観察した。1 Decoy sitting 50m Q, placed in a sample tube and observed for 1 month in a constant temperature bath at 50°C.
0 分離が全く認められない。0 No separation observed at all.
○ 分離が僅かに認められる。○ Slight separation is observed.
△ 分離が認められる。△ Separation is observed.
× 完全に分離している。× Completely separated.
ヱ韮±1芝 使用直後に官能評価を行った。ヱ韮±1shiba Sensory evaluation was performed immediately after use.
O非常にマイルド感がある。O It has a very mild feel.
○ ややマイルド感がある。○ It has a slightly mild feel.
△ ややマイルド感がない。△ Slightly lacking in mild feeling.
、爪」11傷。, 11 scratches on nails.
人
O爪の異状(2枚爪、ワレ)を認めた人 3以下○ 爪
の異状(2枚爪、ワレ)を認めた人 4〜7△ 爪の異
状(2枚爪、ワレ)を認めた人 8〜15× 爪の異状
(2枚爪、ワレ)を認めた大 16以上実施例1、比較
例1.2
比較例1.2は常法により、実施例1は下記のような製
法で製造した。Person O Person who recognized abnormality of nail (two nails, crack) 3 or less○ Person who recognized abnormality of nail (two nail, crack) 4-7△ Person who recognized abnormality of nail (two nail, crack) Person 8 to 15 × Nail abnormalities (two nails, cracks) Large 16 or more Example 1, Comparative Example 1.2 Comparative Example 1.2 was produced using the conventional method, and Example 1 was produced using the following method. Manufactured.
(以下余白)
製造法
■、■を混合しホモミキサー処理しなから■を徐添する
。これに■■■■を混合したものを徐添し乳化する。(Left below) Production method Mix ■ and ■ and process with a homomixer, then gradually add ■. A mixture of ■■■■ is gradually added to this and emulsified.
表−1から明らかなように実施例1ば、乳化安定性、マ
イル1く感、爪の損傷度合の改善に優れ、他の緒特性(
除去力、におい等)にも優れていた。As is clear from Table 1, Example 1 was excellent in improving emulsion stability, mileage feeling, and degree of nail damage, and had other properties (
It also had excellent removal power, odor, etc.).
また、エナメル除去後、再度エナメルを塗布した場合の
経時のもち(はがれ)にも優れていた。Furthermore, after enamel removal, enamel was reapplied with excellent durability (peeling) over time.
実施例2〜8 実施例1に準じて製造した。Examples 2-8 It was manufactured according to Example 1.
エナメルリムーバーは、乳化安定性、マイルド感、爪の
損傷度合の改善に優れ、他の緒特性(除去力、におい等
)にも優れていた。また、エナメル除去後、再度エナメ
ルを塗布した場合の経時のもち(はがれ)にも優れてい
た。The enamel remover was excellent in emulsion stability, mild feeling, and improvement in the degree of damage to nails, and was also excellent in other properties (removal power, odor, etc.). Furthermore, after enamel removal, enamel was reapplied with excellent durability (peeling) over time.
特許出願人 株式会社 資生堂Patent applicant: Shiseido Co., Ltd.
Claims (1)
を含有することを特徴とする乳化エナメルリムーバー。(1) An emulsified enamel remover characterized by containing a solvent, a polyhydric alcohol, a surfactant, and water.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63110734A JP2696222B2 (en) | 1988-05-07 | 1988-05-07 | Emulsified enamel remover |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63110734A JP2696222B2 (en) | 1988-05-07 | 1988-05-07 | Emulsified enamel remover |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH01283211A true JPH01283211A (en) | 1989-11-14 |
JP2696222B2 JP2696222B2 (en) | 1998-01-14 |
Family
ID=14543162
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP63110734A Expired - Fee Related JP2696222B2 (en) | 1988-05-07 | 1988-05-07 | Emulsified enamel remover |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2696222B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20000012772A (en) * | 1999-12-24 | 2000-03-06 | 윤길준 | Enamel remover |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62155206A (en) * | 1985-12-27 | 1987-07-10 | Towa Kagaku Kk | Manicure enamel remover |
JPH01106810A (en) * | 1987-10-19 | 1989-04-24 | Hideyo Kawakami | Light removing agent for manicure and production thereof |
-
1988
- 1988-05-07 JP JP63110734A patent/JP2696222B2/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62155206A (en) * | 1985-12-27 | 1987-07-10 | Towa Kagaku Kk | Manicure enamel remover |
JPH01106810A (en) * | 1987-10-19 | 1989-04-24 | Hideyo Kawakami | Light removing agent for manicure and production thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20000012772A (en) * | 1999-12-24 | 2000-03-06 | 윤길준 | Enamel remover |
Also Published As
Publication number | Publication date |
---|---|
JP2696222B2 (en) | 1998-01-14 |
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