JPH01281927A - Sheeny foamed sheet and its manufacture - Google Patents

Sheeny foamed sheet and its manufacture

Info

Publication number
JPH01281927A
JPH01281927A JP63112188A JP11218888A JPH01281927A JP H01281927 A JPH01281927 A JP H01281927A JP 63112188 A JP63112188 A JP 63112188A JP 11218888 A JP11218888 A JP 11218888A JP H01281927 A JPH01281927 A JP H01281927A
Authority
JP
Japan
Prior art keywords
layer
transfer
base
sheet
resistant resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP63112188A
Other languages
Japanese (ja)
Inventor
Eiji Hinishi
日西 英二
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toppan Inc
Original Assignee
Toppan Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toppan Printing Co Ltd filed Critical Toppan Printing Co Ltd
Priority to JP63112188A priority Critical patent/JPH01281927A/en
Publication of JPH01281927A publication Critical patent/JPH01281927A/en
Pending legal-status Critical Current

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  • Decoration By Transfer Pictures (AREA)
  • Laminated Bodies (AREA)
  • Printing Methods (AREA)

Abstract

PURPOSE:To obtain the sheeny foamed sheet having a metal-deposited layer without cracks and a stereo effect pattern by a method in which a transfer layer containing a heat resistant resin layer embedded with a metal-deposited layer is formed as a transfer sheet, and while said transfer layer is transferred onto a foamable base, said base is foamed. CONSTITUTION:The transfer sheet composed of a transfer sheet-base 1 and a transfer layer 2 is provided. The transfer layer 2 is composed of a releasing layer 21, a pattern printing layer 22, a heat resistant resin layer 23, a metal- deposited layer 24, a heat resistant resin layer 25, a foam-suppressing ink layer 26 and an adhering varnish layer 27. This transfer sheet is lapped on a foamable base 3, and its transfer is achieved under heating and pressurizing, and then the transfer sheet-base 1 is torn off and removed. Then the releasing layer 21 is coated with transparent resin as a top coat layer 4. Next, the whole is heated at least at the foaming temperature of the base 3, and the top coat layer 4 is dried and then the base 3 is foamed. Thus, the sheeny foamed sheet having the metal-deposited layer without cracks and a three dimensional pattern, is obtained.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 本発明は、金属蒸着層により光輝感を付与した発泡シー
ト及びその製造方法に関する。更に詳しくは、例えば発
泡塩ビシート等のクッション性のあるシー1・に光輝感
をイボ与したソー1−で、−g家庭の台所又は店舗の法
制や壁装材等の建装材に適する発泡シートとその製造方
法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a foamed sheet provided with a glittering effect by a metal vapor-deposited layer, and a method for producing the same. In more detail, for example, it is a material that has a cushioning property, such as a foamed PVC sheet, and is given a shine, and is made of foam that is suitable for home kitchens, store regulations, and building materials such as wall coverings. It relates to a sheet and its manufacturing method.

〈従来技術〉 発泡シート表面にパール顔料や金属粉を含むインキを印
刷したり、あるいはパール顔料や金属粉を混練して成形
した発泡性シートは従来から知られている。しかし、こ
れらのシートは照明光等の光の反射による光輝感はなく
、またパール顔料や金属粉を混練する方法ではこれらの
顔料や粉末が  /ハツチ内に付着して清掃が困難であ
る。
<Prior Art> Foamable sheets formed by printing ink containing a pearl pigment or metal powder on the surface of the foam sheet or kneading pearl pigment or metal powder have been known for some time. However, these sheets do not have a shiny appearance due to the reflection of light such as illumination light, and in the method of kneading pearl pigments and metal powders, these pigments and powders adhere to the inside of the hatch and are difficult to clean.

一方、基材ソー1〜上に設けた金属蒸着層が光を反射し
て光輝感を有することは良く知られているが、発泡によ
ってクツション性を付与したソートを基材として、その
表面に光輝性の金属蒸着層を設けたものは未だに知られ
ていない。
On the other hand, it is well known that the metal vapor deposited layer provided on the base material Saw 1 reflects light and has a glittering effect. There is still no known product with a metal vapor-deposited layer.

〈発明が解決しようとする課題〉 発泡シート」二に金属蒸着層を形成してこのンー1−を
発泡させると、発泡による樹脂の流動により金属蒸着層
にクラックが生じ、金属蒸着層が白化又は虹模様が生し
、本来の光輝感が失われてしまう。
<Problems to be Solved by the Invention> When a metal vapor deposited layer is formed on a foamed sheet (2) and this (1) is foamed, cracks occur in the metal vapor deposited layer due to the flow of the resin due to the foaming, and the metal vapor deposited layer becomes white or A rainbow pattern appears and the original shine is lost.

本発明は、このような課題を解決してクラックのない金
属蒸着層を有する発泡シー]・とその製造方法を提供す
ることを目的とし、また、これに加えて、陰影による立
体感のある柄模様を有する光輝性の発泡シートを提供す
ることを目的とする。
The purpose of the present invention is to solve these problems and provide a foamed sheet having a crack-free metal vapor deposited layer and a method for manufacturing the same. An object of the present invention is to provide a glittering foam sheet having a pattern.

〈問題点を解決するだめの手段〉 この目的を達成するため、本発明は発泡によりクツショ
ン性を有する基材の発泡面に、金属蒸着層を埋め込んだ
耐熱性樹脂層が積層されたシーI・を提供する また、このソートの金属茄着層上に、透明樹脂層を介し
て不透明な柄模様が形成されたシートを提イ共する。
<Means for Solving the Problems> In order to achieve this object, the present invention has developed a sheet metal material in which a heat-resistant resin layer in which a metal vapor deposited layer is embedded is laminated on the foamed surface of a base material that has cushioning properties through foaming. We also provide a sheet with an opaque pattern formed on the metal layer of this sort through a transparent resin layer.

更に、このシートを製造する方法として、転写シートベ
ース上に、金属蒸着層を埋め込んだ面1熱性樹脂層を含
む転写層を形成して転写シートとし発泡性基材Gこ転写
層を転写すると共に、発泡させる方法を提供する。
Furthermore, as a method for manufacturing this sheet, a transfer layer including a surface 1 thermal resin layer in which a metal vapor deposition layer is embedded is formed on a transfer sheet base to form a transfer sheet, and the transfer layer is transferred to a foamable base G. , provides a method for foaming.

く作用〉 本発明によれば、金属蒸着層は面4熱性樹脂に埋め込ま
れて一体化しているので、基(オの発泡によるクランク
が生しることはなく、光輝感を維持したまま発泡によっ
て生した凹凸に沿った金属蒸着層が得られる。
Effect> According to the present invention, since the metal vapor deposited layer is embedded and integrated with the thermal resin on the first side, cranks due to the foaming of the base (e) will not occur, and the metal vapor deposition layer will not be produced due to the foaming while maintaining the brightness. A metal vapor deposited layer that conforms to the resulting unevenness is obtained.

また、請求項2の発明によれば、不透明インキによる柄
模様の部分は光を遮賠し、反則も生しないので、奈着面
に影ができる。この影により、柄模様はあたかも盛り上
がった模様に見えるのである。
Further, according to the second aspect of the invention, the patterned portion made of opaque ink blocks light and does not cause any fouling, so that a shadow is formed on the non-wearing surface. This shadow makes the pattern look like a raised pattern.

更に請求項3の発明によれば、厚い基材であっても容易
に金属蒸着層を設けることができ、耐熱性樹脂として熱
硬化型樹脂を用いても、基材を発泡する前に樹脂を硬化
させることができる。
Furthermore, according to the invention of claim 3, it is possible to easily provide a metal vapor deposition layer even on a thick base material, and even when a thermosetting resin is used as the heat-resistant resin, the resin is coated before foaming the base material. Can be hardened.

〈実施例〉 以下、図面を参照して本発明を説明する。図面の第1図
は転写シートの断■1M、第2図は光輝性発泡シートの
断面図である。
<Example> The present invention will be described below with reference to the drawings. FIG. 1 is a cross-sectional view of the transfer sheet 1M, and FIG. 2 is a cross-sectional view of the glitter foam sheet.

本発明に係る転写シートは、転写シートベース1と、転
写層2とから成る。転写シーI・ベース1は転写後に基
材3から剥離除去されるものであり、転写層2は転写後
に基材3に接着して一体化するものである。
The transfer sheet according to the present invention consists of a transfer sheet base 1 and a transfer layer 2. The transfer sheet I/base 1 is to be peeled off and removed from the base material 3 after the transfer, and the transfer layer 2 is to be adhered to and integrated with the base material 3 after the transfer.

転写ソートベース1はポリエステルフィル11、ポリプ
ロピレンフィルム等の平滑性の良い樹脂フィルム又はこ
れらの樹脂フィルムに支持体として紙等を貼り合わせた
複合品が使用できる。
As the transfer sorting base 1, a polyester film 11, a resin film with good smoothness such as a polypropylene film, or a composite product made by laminating these resin films with paper or the like as a support can be used.

転写層2は剥離層21、柄印刷層22、耐熱性樹脂層2
3、金属蒸着層24、耐熱性樹脂層25、発泡抑制イン
キ層26、接着ニス層27とから成る。
The transfer layer 2 includes a release layer 21, a pattern printing layer 22, and a heat-resistant resin layer 2.
3. Consists of a metal vapor deposition layer 24, a heat-resistant resin layer 25, a foaming-inhibiting ink layer 26, and an adhesive varnish layer 27.

剥離層21は転写後に転写シートベース1のみを剥離除
去するためのもので、アクリル系樹脂、塩酢ビ系樹脂等
、ベース1と離型性の良い樹脂を用いる。
The peeling layer 21 is for peeling and removing only the transfer sheet base 1 after the transfer, and is made of a resin that has good releasability from the base 1, such as an acrylic resin or a salt-vinyl acetate resin.

柄印刷層22は、発泡シートに意匠性を(=J与するだ
めのもので、不透明又は半透明のアクリル系、塩酢ビ系
の着色インキで印刷 したものである。
The pattern printing layer 22 is intended to give a design to the foam sheet, and is printed with opaque or translucent acrylic or salt-vinyl acetate colored ink.

不透明インキを用いれは光を遮蔽し、金属蒸着層24上
に影を作って立体感を得ることができる。半透明着色イ
ンキを用いれば光を透過して着色金属絵柄を得るごとが
できる。
Opaque ink can be used to block light and create a shadow on the metal vapor deposited layer 24 to provide a three-dimensional effect. By using translucent colored ink, it is possible to obtain a colored metallic pattern by allowing light to pass through.

なお、柄印刷層22のインキとしてベース1と離型性の
良いインキを用いれば、剥離層21と柄印刷層22の順
序を入れ替えることもできる。
Note that if an ink with good release properties from the base 1 is used as the ink for the pattern printing layer 22, the order of the release layer 21 and the pattern printing layer 22 can be changed.

耐熱性樹脂層23及び25は、その間に金属蒸着層24
を埋め込んで、一体化し、発泡時に金属蒸着層24にク
ラ、りが生しるのを防くものである。耐熱性樹脂層23
及び25としては、発泡時の熱で軟化しない透明な樹脂
であれば良いが、反応により架橋した硬化型樹脂が望ま
しい。例えば2液硬化型のウレタン樹脂である。
The heat-resistant resin layers 23 and 25 have a metal vapor deposition layer 24 between them.
This is to prevent cracks and cracks from forming in the metal vapor deposited layer 24 during foaming. Heat resistant resin layer 23
And 25 may be any transparent resin that does not soften due to heat during foaming, but a curable resin crosslinked by reaction is preferable. For example, it is a two-part curable urethane resin.

金属蔽着層24は光輝感を付与するためのもので、アル
ミニウム、スス、銅、根等を常法により真空蒸着して形
成できる。
The metal shielding layer 24 is for imparting a glittering effect, and can be formed by vacuum-depositing aluminum, soot, copper, roots, etc. by a conventional method.

発泡抑制インキ層26は基材の発泡を抑制するだめのも
ので、例えば、耐熱性樹脂層25及び接着層27に密着
性の良い塩酢ビ系の樹脂に1〜リアジン環を含む発泡抑
制剤を添加したインキで絵柄を印刷する。
The foaming suppressing ink layer 26 is for suppressing foaming of the base material, and is made of, for example, a foaming suppressing agent containing 1 to lyazine rings in a salt-vinyl acetate resin that has good adhesion to the heat-resistant resin layer 25 and the adhesive layer 27. The pattern is printed using ink containing .

接着ニス層27は転写層2全体を基It 3に接着する
と共に、発泡時に軟化して耐熱性樹脂層25や金属蒸着
層24に強い応力がかかるのを防くものである。塩酢ビ
系、アクリル系等の熱接着性樹脂が使用できる。
The adhesive varnish layer 27 adheres the entire transfer layer 2 to the base It 3 and also prevents strong stress from being applied to the heat-resistant resin layer 25 and the metal vapor deposition layer 24 due to softening during foaming. Heat-adhesive resins such as salt-vinyl acetate and acrylic resins can be used.

金属蒸着層24を除く他の層は、いずれも、グラビア印
刷、シルクスクリーン印刷、オフセット印刷あるいはグ
ラビアコート、ロールコート等の方法で印刷又は塗布す
ることができる。剥離層21、柄印刷層22、耐熱性樹
脂層23をインラインで、また耐熱性樹脂層25、発泡
抑制インキ層26、接着ニス層27を別のインラインで
印刷又は塗布することが簡便である。
All of the other layers except the metal vapor deposition layer 24 can be printed or coated by a method such as gravure printing, silk screen printing, offset printing, gravure coating, or roll coating. It is convenient to print or apply the release layer 21, pattern printing layer 22, and heat-resistant resin layer 23 in-line, and the heat-resistant resin layer 25, foam-suppressing ink layer 26, and adhesive varnish layer 27 separately in-line.

この転写シートを、発泡性基材3の上に重ね、加熱加圧
して転写する。転写後転写シートベース1は剥離除去す
る。
This transfer sheet is placed on the foamable base material 3 and transferred under heat and pressure. After the transfer, the transfer sheet base 1 is peeled off and removed.

発泡性基材3は後に発泡して意匠性とクツション性を付
与するもので、例えばガラス繊維紙、アマヘスト紙等に
発泡性塩ヒ樹脂を塗布したシートが使用できる。
The foamable base material 3 is one that is later foamed to provide design and cushioning properties, and for example, a sheet of glass fiber paper, amahest paper, etc. coated with a foamable abrasive resin can be used.

転写は、発泡性基材3が発泡しない温度で行なう。発泡
性塩ビ樹脂の場合には、この発泡性塩ビシート表面が1
00〜150°Cの状態で、ロール間で転写ソールと発
泡性塩ビ樹脂を加圧して転写する。
The transfer is performed at a temperature at which the foamable base material 3 does not foam. In the case of foamable PVC resin, the surface of this foamable PVC sheet is 1
The transfer sole and the foamable PVC resin are transferred under pressure between rolls at a temperature of 00 to 150°C.

この後、転写した面、すなわち剥離層21上に透明な+
Ai l指を塗布してトップコート層4とする。シノプ
コ−1・層4は発泡ソート表面を保護するもので、塩ビ
系樹脂等が使用できる。
After that, a transparent +
Ai Il finger is applied to form the top coat layer 4. Synopco-1 Layer 4 protects the surface of the foamed sort, and can be made of vinyl chloride resin or the like.

次いで、全体を基材3の発泡温度以」二に加熱して、I
・ツブコート層4を乾燥させると共に基材3を発泡させ
る。発泡性塩ヒ樹脂の場合にば200〜240°Cで]
〜3分間加熱すれば良い。なお、発泡抑制インキ層26
の存在する部分は基材3の発泡が抑制され、第2圓に示
ずように凹部を形成して、凹凸をイ1与することができ
る。
Next, the whole is heated to a temperature higher than the foaming temperature of the base material 3, and the I
- Dry the base coat layer 4 and foam the base material 3. In the case of foamable acetic resin, at 200 to 240°C]
Just heat it for ~3 minutes. Note that the foaming suppressing ink layer 26
Foaming of the base material 3 is suppressed in the area where the bubbles exist, and a concave portion can be formed as shown in the second circle to give unevenness.

く試験例〉 転写シートベースとして坪量50g/rdの上質紙に2
0μのポリプロピレン層を設けた複合紙を使用した。
Test example> As a transfer sheet base, 2
A composite paper with a 0μ polypropylene layer was used.

この転写シートベースのポリプロピレン層上に、順に、
柄印刷層、剥離層、耐熱性透明樹脂層を、グラビア印刷
機でインラインで印刷]シた。
On the polypropylene layer of this transfer sheet base, in order:
The pattern printing layer, release layer, and heat-resistant transparent resin layer were printed in-line using a gravure printing machine.

柄印刷層の絵柄は砂目を素゛材とした3色柄抽象パター
ンで、不透明の白、半透明の黄、青の塩酢ビ系のインキ
を使用し、印刷版の深さは白板のみ60μ、他の版は3
5μとした。
The design of the pattern printing layer is a three-color abstract pattern using sand grain as the material, using opaque white, translucent yellow, and blue salt-vinyl acetate inks, and the depth of the printing plate is only the white board. 60μ, other versions are 3
It was set to 5μ.

剥離層は柄印刷層に用いたインキのメジウムと同系のメ
ジウムによるもので、版深60〃のへ夕飯を用いた。
The release layer was made of a medium of the same type as the ink medium used for the pattern printing layer, and a plate depth of 60 was used.

耐熱性樹脂層は透明な2液硬化型のウレタン樹脂で、版
深60μのへ夕飯を用いた。
The heat-resistant resin layer was a transparent two-component curing urethane resin with a plate depth of 60 μm.

この耐熱性樹脂層上に厚さ600オングストロームのア
ルミニウムを真空蒸着した。
Aluminum with a thickness of 600 angstroms was vacuum-deposited on this heat-resistant resin layer.

次に、グラビア印刷機により、耐熱性樹脂層、発泡抑制
インキ層、接着ニス層をインラインで印刷した。
Next, a heat-resistant resin layer, a foam-suppressing ink layer, and an adhesive varnish layer were printed in-line using a gravure printing machine.

耐熱性樹脂層は透明な2液硬化型のウレタン樹脂であり
、接着ニス層は塩酢ビ系のニスで、版深60μのへ夕飯
を用いた。
The heat-resistant resin layer was a transparent two-component curing type urethane resin, and the adhesive varnish layer was a salt-vinyl acetate-based varnish with a plate depth of 60 μm.

この後、耐熱性樹脂層を硬化架橋させてアルミニラ1、
層とその両側の耐熱性樹脂層を強固に一体化させて転写
シートとした。
After that, the heat-resistant resin layer is cured and cross-linked to form Aluminum 1.
The layer and the heat-resistant resin layers on both sides were firmly integrated to form a transfer sheet.

一方、ガラス繊維紙を支持体とし、この上に厚さ200
 μの発泡性塩ビ樹脂層を形成したシートを基材とした
。この基材表面を120°Cに維持した状態で転写シー
1−を重ね、ロール間で加圧して転写し、転写ソートベ
ースのみを剥離除去した。
On the other hand, a glass fiber paper is used as a support, and a thickness of 200
The base material was a sheet on which a foamable PVC resin layer of μ was formed. With the surface of this base material maintained at 120[deg.] C., transfer sheet 1- was stacked on top of the other, pressure was applied between rolls for transfer, and only the transfer sorting base was peeled off and removed.

次いで柄模様面(転写面)に透明塩ビ系ペーストを10
0 μ厚に塗布し、220°C発泡炉に2分間挿入し、
発泡塩ビ層を2倍に発泡させて、建装材を得た。
Next, apply 10% of transparent PVC paste to the pattern surface (transfer surface).
Apply to a thickness of 0μ, insert into a 220°C foaming oven for 2 minutes,
A building material was obtained by foaming the foamed PVC layer twice.

得られた埋装+1は、無地部分に光輝感のある金属蒸着
層をもち、隠蔽性の高い自活と、金属光沢感のある黄、
前納がよく調和した砂目柄であり、しかも自活の部分は
透明樹脂層を介して、アルミ蒸着層と段差がある為、角
度によって自活の影が見えることによって、立体感のあ
る意匠効果の優れたクツション性埋装拐であった。
The obtained embedding +1 has a metal vapor deposited layer with a glittery feel on the plain part, and has a self-supporting layer with high concealability, a yellow color with a metallic luster,
The grain pattern is well-balanced in the front, and since the self-supporting part has a step between the transparent resin layer and the aluminum vapor deposition layer, the shadow of the self-supporting part can be seen depending on the angle, giving it an excellent three-dimensional design effect. It was a cushion-related abduction.

〈効果〉 (1)請求項1の発明によれば、金属蒸着層にクラック
を生しることなく、発泡面に金属蒸着層を有する発泡シ
ートが得られるので、極めて光輝感が優れたクツション
性のシートが得られる。
<Effects> (1) According to the invention of claim 1, a foam sheet having a metal vapor deposited layer on the foamed surface can be obtained without cracks occurring in the metal vapor deposited layer, so cushioning properties with extremely excellent shine can be obtained. sheets are obtained.

(2)請求項2の発明によれば、上記(1)の効果に加
えて、立体感に富んだ柄模様が得られる。
(2) According to the invention of claim 2, in addition to the effect of (1) above, a pattern with rich three-dimensional effect can be obtained.

(3)請求項3の発明によれば、厚い基材を用いて上記
(1)のシートを得ることができる。
(3) According to the third aspect of the invention, the sheet of (1) above can be obtained using a thick base material.

図面は本発明の実施例を示し、第1@は転写シートの断
面図、第2図は、発泡シートの断面図である。
The drawings show embodiments of the present invention, in which the first drawing is a cross-sectional view of a transfer sheet, and the second drawing is a cross-sectional view of a foam sheet.

1・・転写シートベース 2・・・転写層21・・・剥
離Ji       22・・・柄印刷層23・・・耐
熱性樹脂層   24・・・金属蒸着層25・・・耐熱
性樹脂層   26・・・発泡抑制インキ層27・・・
接着ニス層    3・・基材4・・・トップコート 第1図
1... Transfer sheet base 2... Transfer layer 21... Peeling Ji 22... Pattern printing layer 23... Heat resistant resin layer 24... Metal vapor deposited layer 25... Heat resistant resin layer 26... ...Foaming suppression ink layer 27...
Adhesive varnish layer 3...Base material 4...Top coat Figure 1

Claims (3)

【特許請求の範囲】[Claims] (1)発泡によりクッション性を有する基材の発泡面に
、金属蒸着層を埋め込んだ耐熱性樹脂層が積層されてい
ることを特徴とする光輝性発泡シート。
(1) A glitter foam sheet characterized in that a heat-resistant resin layer in which a metal vapor-deposited layer is embedded is laminated on the foamed surface of a base material that has cushioning properties due to foaming.
(2)金属蒸着層上に、透明樹脂層を介して、不透明な
柄模様が形成されていることを特徴とする請求項1記載
の光輝性発泡シート。
(2) The glitter foam sheet according to claim 1, wherein an opaque pattern is formed on the metal vapor deposited layer via a transparent resin layer.
(3)転写シートベース上に、金属蒸着層を埋め込んだ
耐熱性樹脂層を含む転写層を形成して転写シートとし、
発泡性基材に転写層を転写すると共に、発泡させること
を特徴とする光輝性発泡シートの製造方法。
(3) A transfer sheet is formed by forming a transfer layer including a heat-resistant resin layer embedded with a metal vapor deposition layer on the transfer sheet base,
A method for producing a glitter foam sheet, which comprises transferring a transfer layer to a foam base material and foaming the sheet.
JP63112188A 1988-05-09 1988-05-09 Sheeny foamed sheet and its manufacture Pending JPH01281927A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63112188A JPH01281927A (en) 1988-05-09 1988-05-09 Sheeny foamed sheet and its manufacture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63112188A JPH01281927A (en) 1988-05-09 1988-05-09 Sheeny foamed sheet and its manufacture

Publications (1)

Publication Number Publication Date
JPH01281927A true JPH01281927A (en) 1989-11-13

Family

ID=14580463

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63112188A Pending JPH01281927A (en) 1988-05-09 1988-05-09 Sheeny foamed sheet and its manufacture

Country Status (1)

Country Link
JP (1) JPH01281927A (en)

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