JPH01195002A - Method for manufacturing reinforced decorative laminated sheet emphasized on grain - Google Patents
Method for manufacturing reinforced decorative laminated sheet emphasized on grainInfo
- Publication number
- JPH01195002A JPH01195002A JP1896688A JP1896688A JPH01195002A JP H01195002 A JPH01195002 A JP H01195002A JP 1896688 A JP1896688 A JP 1896688A JP 1896688 A JP1896688 A JP 1896688A JP H01195002 A JPH01195002 A JP H01195002A
- Authority
- JP
- Japan
- Prior art keywords
- grain
- pigment
- emphasized
- veneer
- thermosetting resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 238000000034 method Methods 0.000 title claims description 20
- 239000000049 pigment Substances 0.000 claims abstract description 22
- 229920005989 resin Polymers 0.000 claims abstract description 18
- 239000011347 resin Substances 0.000 claims abstract description 18
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 10
- 239000001023 inorganic pigment Substances 0.000 claims abstract description 5
- 239000012860 organic pigment Substances 0.000 claims abstract description 5
- 239000011121 hardwood Substances 0.000 claims description 4
- 239000002023 wood Substances 0.000 abstract description 11
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 238000005470 impregnation Methods 0.000 abstract description 3
- -1 watching red Chemical compound 0.000 abstract description 3
- FWLHAQYOFMQTHQ-UHFFFAOYSA-N 2-N-[8-[[8-(4-aminoanilino)-10-phenylphenazin-10-ium-2-yl]amino]-10-phenylphenazin-10-ium-2-yl]-8-N,10-diphenylphenazin-10-ium-2,8-diamine hydroxy-oxido-dioxochromium Chemical compound O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.Nc1ccc(Nc2ccc3nc4ccc(Nc5ccc6nc7ccc(Nc8ccc9nc%10ccc(Nc%11ccccc%11)cc%10[n+](-c%10ccccc%10)c9c8)cc7[n+](-c7ccccc7)c6c5)cc4[n+](-c4ccccc4)c3c2)cc1 FWLHAQYOFMQTHQ-UHFFFAOYSA-N 0.000 abstract description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 2
- AUNAPVYQLLNFOI-UHFFFAOYSA-L [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O Chemical compound [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O AUNAPVYQLLNFOI-UHFFFAOYSA-L 0.000 abstract description 2
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 abstract description 2
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 abstract description 2
- 229920000767 polyaniline Polymers 0.000 abstract description 2
- 229920003002 synthetic resin Polymers 0.000 abstract description 2
- 239000000057 synthetic resin Substances 0.000 abstract description 2
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 abstract description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 235000007575 Calluna vulgaris Nutrition 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920006305 unsaturated polyester Polymers 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 241000190021 Zelkova Species 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
Landscapes
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はＷＰＣ（ウッド・プラスチック・コンビネーシ
ョン）化した化粧板に関し、特に広葉樹の杢目を強調し
た化粧板の製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a WPC (wood-plastic combination) decorative board, and particularly to a method for manufacturing a decorative board that emphasizes the grain of hardwood.
（従来の技術）
近年、減圧下で排気した木材の仮導管に樹脂を注入して
熱圧硬化せしめる、所謂、木材と合成樹脂の複合化（Ｗ
ＰＣ）が普及してきた。(Prior art) In recent years, the so-called composite of wood and synthetic resin (W
PC) has become popular.
一方、木材の材質感を高めると共に高級化のイメージを
得る方法として、近年木材の杢目を強調することが行わ
れている。このような杢目強調方法としては、■木材中
に存在する微量成分や色素分が反応する小口強調剤や小
口出し剤を塗布する方法、■ブラッシング等により単板
表面に凹凸を形成させ、凹部を凸部より濃色に着色させ
る杢目逆転方法、及び■熱硬化樹脂液中に予め染料を添
加せしめる方法が広く知られている。On the other hand, in recent years, emphasis on the grain of wood has been used as a way to enhance the quality of wood and give it an image of luxury. Methods for emphasizing the wood grain include: ■ Applying an edge-enhancing agent or edge-extending agent that reacts with trace components and pigments present in the wood; ■ Forming unevenness on the surface of the veneer by brushing, etc. to remove the concavities. A method of reversing the grain pattern in which the convex portions are colored darker than the convex portions, and a method of (2) adding a dye to the thermosetting resin liquid in advance are widely known.
（発明が解決しようとする問題点）
しかしながら■の方法を用いた場合には、夏材部が春材
部より濃色化され杢目が強調される結果、全体に濃色化
されるという欠点があり、■の方法の場合には、春材部
が凹部、夏材部が凸部となるため、強調される杢目は本
来の杢目と逆転した形となり不゛自然な杢目を形成する
という欠点があった。更に■の場合には、杢目が今一つ
不鮮明である上、着色配合の異なる調整タンクを必要と
し、又は含浸釜の洗浄若しくは多数の釜が必要となると
いう欠点があった。(Problem to be Solved by the Invention) However, when method (■) is used, the summer wood area becomes darker in color than the spring wood area and the heather grain is emphasized, resulting in a disadvantage that the entire area becomes darker in color. In the case of method (■), the spring wood part becomes a concave part and the summer wood part becomes a convex part, so the emphasized heather grain becomes the reverse of the original heather grain, forming an unnatural heather grain. There was a drawback to that. Furthermore, in the case of (2), there were disadvantages in that the grain was not very clear, and that adjustment tanks with different coloring formulations were required, or the impregnation pots had to be cleaned or a large number of pots were required.
そこで、本発明者等は従来のかかる欠点を解決すべく鋭
意検討を重ねた結果、単板に熱硬化性樹脂を含浸せしめ
る際に、該熱硬化性樹脂中に顔料等を予め添加しておく
ことにより、容易に杢目を強調し得ることを見出し本発
明に到達した。Therefore, the inventors of the present invention have made extensive studies to solve these conventional drawbacks, and have found that when impregnating a veneer with a thermosetting resin, pigments or the like are added in advance to the thermosetting resin. The inventors have discovered that the grains can be easily emphasized by this method, and have arrived at the present invention.
従って、本発明の目的は、化粧板の杢目を強調すること
のできる簡便な方法を提供することにある。Therefore, an object of the present invention is to provide a simple method that can emphasize the grain of a decorative board.
（問題点を解決するための手段）
本発明の上記の目的は、広葉樹の単板に熱硬化性樹脂液
を含浸せしめこれを熱圧硬化する広葉樹のｗｐｃ化にお
いて、含浸樹液中に少なくとも杢目を強調することので
きる顔料を添加することを特徴とする杢目を強調した強
化化粧板の製造方法によって達成された。(Means for Solving the Problems) The above-mentioned object of the present invention is to impregnate a hardwood veneer with a thermosetting resin liquid and cure it under heat and pressure. This was achieved by a method for manufacturing a reinforced decorative board that emphasizes the grain, which is characterized by adding a pigment that can emphasize the grain.
本発明で使用する事のできる熱硬化性樹脂の硬化後は透
明であっても不透明であっても良く、例えば、スチレン
、メチルメタクリレート、ジアリルフタレート、飽和又
は不飽和ポリエステル、メラミン、フェノール樹脂等の
含浸木材用として通常使用される樹脂や収縮低減剤を含
有する不飽和ポリエステルその他の公知の熱硬化性樹脂
組成物の中から適宜選択して使用することができる。The thermosetting resin that can be used in the present invention may be transparent or opaque after curing, and examples include styrene, methyl methacrylate, diallyl phthalate, saturated or unsaturated polyester, melamine, phenolic resin, etc. The thermosetting resin composition can be appropriately selected from resins commonly used for impregnated wood, unsaturated polyester containing a shrinkage reducing agent, and other known thermosetting resin compositions.
本発明において、熱硬化性樹脂液を単板に含浸せしめる
方法としては、公知の方法の中から適宜選択することが
できるが、特に減圧して板場管中の空気を排出し、脱泡
した樹脂液中に浸漬した後加圧して該樹脂液を板場管中
に注入する方法が、短時間に大量に樹脂液を前記単板中
に含浸せしめることができるので好ましい。In the present invention, the method of impregnating the veneer with the thermosetting resin liquid can be appropriately selected from among known methods, but in particular, the method of impregnating the veneer with the thermosetting resin liquid can be appropriately selected from known methods, but in particular, the method is A method in which the veneer is immersed in a resin liquid and then pressurized to inject the resin liquid into the veneer tube is preferable because a large amount of the resin liquid can be impregnated into the veneer in a short period of time.
ｗｐｃ化に際する熱圧硬化の条件は、使用する樹脂の種
類に応じて公知の条件の中から適宜選択して設定する。Conditions for heat-pressure curing during WPC conversion are appropriately selected and set from known conditions depending on the type of resin used.
上記熱圧硬化時に、単板と基材合板を強固に接着させる
ために使用される接着剤は、公知の接着剤の中から適宜
選択することができる。The adhesive used to firmly adhere the veneer and the base plywood during the heat-pressure curing can be appropriately selected from known adhesives.
本発明で使用する有機又は無機の顔料は公知の顔料の中
から適宜選択して使用することができる。The organic or inorganic pigment used in the present invention can be appropriately selected from known pigments.
染料のみでは杢目強調が不十分である上耐光性も顔料よ
り劣るので、耐光性の良好な顔料を主として用い、必要
な場合に微妙な調色剤として染料を適宜使用する事が好
ましい。Since dyes alone do not sufficiently emphasize the grain and are also inferior to pigments in light resistance, it is preferable to primarily use pigments with good light resistance, and to use dyes as a subtle toning agent when necessary.
本発明で使用することのできる顔料としては、無機系の
ものとして例えば酸化チタン、弁柄、クロムイエロー等
を挙げることができ、有機系のものとしては例えばクロ
ムバーミリオン、ウオッチングレッド、シアニンブルー
、アニリンブラック、不溶性アゾ顔料及びイソインドリ
ノン等を挙げることができる。これらの顔料は単板中の
板場管に入り込めるように、１５μｍ以下、好ましくは
１０μｍ以下とする。これらの顔料は単独で用いても混
合して用いても良い。Examples of pigments that can be used in the present invention include inorganic pigments such as titanium oxide, Bengara, and chrome yellow, and organic pigments such as chrome vermilion, watching red, and cyanine blue. , aniline black, insoluble azo pigments and isoindolinone. The diameter of these pigments is 15 μm or less, preferably 10 μm or less so that they can enter the plate tubes in the veneer. These pigments may be used alone or in combination.
熱硬化性樹脂中に添加する顔料の量は適宜選択すること
ができるが０．１重量％以上とすることが好ましい。顔
料の添加量を増加させるに従い、顔料が沈降し易くなる
ので例えばフローセンの添加を採用して沈降を防止する
ことが好ましい。The amount of pigment added to the thermosetting resin can be selected as appropriate, but it is preferably 0.1% by weight or more. As the amount of pigment added increases, the pigment tends to sediment, so it is preferable to prevent sedimentation by adding, for example, fluorene.
（作用）
本発明の如く、予め顔料を含有する熱硬化性樹脂を単板
に含浸させることにより染・顔料も単板中に移行するか
ら上記樹脂を熱圧硬化させて、単板の強化を図ると同時
に染・顔料を固定することによって杢目が強調されるこ
とになる。−回のｗｐｃ化による杢目強調が不十分な場
合には、上記ｗｐｃ化の工程を繰り返すことにより杢目
強調を確実なものとすることができる。(Function) As in the present invention, by impregnating the veneer with a thermosetting resin containing pigment in advance, the dye/pigment is also transferred into the veneer, so the resin is hardened under heat and pressure to strengthen the veneer. At the same time, the heathered grain is emphasized by fixing the dye and pigment. - If the heathered grain emphasis by the wpc conversion is insufficient, the heather grain emphasis can be ensured by repeating the above wpc conversion process.
（発明の効果）
本発明によれば、ブラッシング等の特別の操作も杢目強
調のための特別な装置も必要としないので操作が単純で
あり製造コストも低減することができる。(Effects of the Invention) According to the present invention, there is no need for special operations such as brushing or a special device for highlighting the grain, so the operation is simple and the manufacturing cost can be reduced.
（実施例）
以下、本発明を実施例によって更に詳述するが、本発明
はこれによって限定されるものではない。(Examples) Hereinafter, the present invention will be explained in more detail with reference to Examples, but the present invention is not limited thereto.
実施例１゜
１．０ｍ／ｍ厚の欅の単板に下記の配合の熱硬化性樹脂
液を、３０ｋｇ／ｃｆｆｌの加圧下で４時間強制注入し
た。Example 1 A thermosetting resin liquid having the following composition was forcibly injected into a 1.0 m/m thick zelkova veneer under a pressure of 30 kg/cffl for 4 hours.
（配合）
不飽和ポリエステル（ＷＰＣ−７
大日本インキ■製） １００ｍｔ％有機過酸化物
（バーブチル１ 日本油脂■製）２ｍｔ％
不溶性アゾ（ＯＰレット ５Ｒ−ＰＳ
御国色素■製） ０．２ｍｔ％
イソイントリノン（ＯＰエロー２ＧＬ−ＰＳ御国色素■
製） ０．２ｍｔ％
７ニリンブラソク ＰＢ−ＰＳ 御国色素■製）０．
１ｍｔ％
実施例２゜
実施例１で使用した有機顔料の代わりに下記の無機顔料
の組み合わせを使用した他は、実施例１と同様の結果を
得た。(Composition) Unsaturated polyester (WPC-7 manufactured by Dainippon Ink ■) 100 mt% Organic peroxide (Barbutyl 1 manufactured by NOF ■) 2 mt% Insoluble azo (OPlet 5R-PS manufactured by Mikuni Shiki ■) 0.2 mt% Iso Intrinon (OP Yellow 2GL-PS Mikuni Color ■
(Manufactured by Mikuni Shiki ■) 0.2mt% 7 Nirinburasoku PB-PS Manufactured by Mikuni Shiki ■) 0.
1mt% Example 2 The same results as in Example 1 were obtained, except that the following combination of inorganic pigments was used instead of the organic pigment used in Example 1.
弁柄 ０．０５ｍｔ％ クロムエロー ０．０６ｍｔ％ カーボンブランク ０．０３５ｍｔ％Bengara 0.05mt% Chrome Yellow 0.06mt% Carbon blank 0.035mt%
Claims (1)
熱圧硬化する広葉樹のＷＰＣ化において、含浸樹液中に
少なくとも杢目を強調することのできる顔料を添加する
ことを特徴とする杢目を強調した強化化粧板の製造方法
。 ２）顔料として無機系顔料と有機系顔料を併用する特許
請求の範囲第１項に記載の杢目を強調した強化化粧板の
製造方法。 ３）顔料と共に染料を併用する特許請求の範囲第１項又
は第２項に記載の杢目を強調した強化化粧板の製造方法
。[Scope of Claims] 1) In converting hardwood to WPC by impregnating a hardwood veneer with a thermosetting resin liquid and curing it under heat pressure, at least a pigment capable of emphasizing the grains is added to the impregnated sap. A method for manufacturing a reinforced decorative board with emphasized heathered grain. 2) A method for manufacturing a reinforced decorative board with emphasized grains as set forth in claim 1, in which an inorganic pigment and an organic pigment are used in combination as pigments. 3) A method for manufacturing a reinforced decorative board with emphasized grains according to claim 1 or 2, in which a dye is used in combination with a pigment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1896688A JPH01195002A (en) | 1988-01-29 | 1988-01-29 | Method for manufacturing reinforced decorative laminated sheet emphasized on grain |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1896688A JPH01195002A (en) | 1988-01-29 | 1988-01-29 | Method for manufacturing reinforced decorative laminated sheet emphasized on grain |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01195002A true JPH01195002A (en) | 1989-08-04 |
Family
ID=11986396
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1896688A Pending JPH01195002A (en) | 1988-01-29 | 1988-01-29 | Method for manufacturing reinforced decorative laminated sheet emphasized on grain |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01195002A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009006498A (en) * | 2007-06-26 | 2009-01-15 | Wood One:Kk | Grain emphasis method of woody material |
| JP2009517245A (en) * | 2005-11-28 | 2009-04-30 | エルジー・ケム・リミテッド | In-line process and apparatus therefor for producing wood plastic composite panels with appearance and texture like natural wood |
| CN103342923A (en) * | 2013-07-18 | 2013-10-09 | 东北林业大学 | Environment-friendly wood veneer dyeing agent and dyeing method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6319202A (en) * | 1986-07-11 | 1988-01-27 | 山陽国策パルプ株式会社 | Reinforced decorative material |
-
1988
- 1988-01-29 JP JP1896688A patent/JPH01195002A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6319202A (en) * | 1986-07-11 | 1988-01-27 | 山陽国策パルプ株式会社 | Reinforced decorative material |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009517245A (en) * | 2005-11-28 | 2009-04-30 | エルジー・ケム・リミテッド | In-line process and apparatus therefor for producing wood plastic composite panels with appearance and texture like natural wood |
| JP2009006498A (en) * | 2007-06-26 | 2009-01-15 | Wood One:Kk | Grain emphasis method of woody material |
| CN103342923A (en) * | 2013-07-18 | 2013-10-09 | 东北林业大学 | Environment-friendly wood veneer dyeing agent and dyeing method thereof |
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