JPH01143812A - Solid polyhydric alcohol-in-oil type emulsified cosmetic - Google Patents

Abstract

PURPOSE:To obtain the title cosmetic, consisting essentially of a silicone oil, solid wax and polyhydric alcohol and polyoxyalkylene-modified organopolysiloxane and having excellent stability and moist feeling in applying to the skin. CONSTITUTION:The title cosmetic, obtained by emulsifying (A) a silicone oil, especially a volatile silicone oil expressed by formula I or II (i is 1-4; j is 0-3), (B) a solid wax, especially a 25-52C straight-chain and/or branched hydrocarbon wax as a principal ingredient and (C) a polyhydric alcohol with (D) one or more of polyoxyalkylene-modified organopolysiloxanes expressed by formulas III-VI (R is 1-3C alkyl or phenyl; R' is H or 1-12C alkyl; p is an integer of 1-5; m is an integer of 5-100; n and x are integers of 1-50; t and y are integers of 0-50) and having excellent stability and further moist feeling and wetness in applying to the skin in spite of a solid form.

Description

[Detailed Description of the Invention] [Industrial Application Field] The present invention provides a polyhydric alcohol in solid oil that essentially contains silicone oil, solid wax, polyhydric alcohol, and polyoxyalkylene-modified organopolysiloxane. Regarding emulsified cosmetics, in detail, they are solid polyhydric alcohol-in-oil emulsified cosmetics that have good stability and have a novel feel when applied to the skin, which is soft and moisturizing. Regarding.

[Prior art] Commonly used base types for solid cosmetics include solid oil-based types made of solidified oil, and solid pressed types made of pressed powder or a mixture of powder and oil. Each type of cosmetic is used differently depending on the purpose and method of use. For example, solid oil-based cosmetics such as lipsticks are generally used, and foundations used in puffs and sponges are generally pressed solid types. In recent years, lipsticks containing water and polyhydric alcohol have been studied and put on the market, but lipsticks containing large amounts of polyhydric alcohol are not known on the market because it is difficult to obtain stable products. . When a volatile oil agent is used, it is difficult to obtain one with good stability, and there are many restrictions such as the need to fill it in a highly airtight container, so it does not exist as a product. In other words, in the prior art, no solid oil-in-polyhydric alcohol emulsion cosmetics with good stability have been found, and no cosmetics containing a large amount of polyhydric alcohol using a volatile oil are known. do not have.

On the other hand, emulsified cosmetics are generally used as basic cosmetics because they can contain water, polyhydric alcohol, etc. and have high treatment properties. In the case of an emulsion type, the content state that can be selected is a fluid emulsion or a less fluid cream. If it is in the form of a milky lotion, it is filled in a bottle or tube-shaped container. For this reason, although emulsified cosmetics have high effects on the skin, they have poor portability.

Furthermore, in recent years, studies have been conducted on cosmetics using silicone oil as a water-repellent base. This is because silicone oil has excellent water repellency, so the coating film of the cosmetic is resistant to water and sweat and difficult to remove after application.
It is used in oil-based solids where the oil phase is a continuous phase, emulsion-like water-in-oil emulsions, and cream-like cosmetics. Further, studies have also been conducted regarding the formulation of volatile oil agents. This is aimed at suppressing the stickiness of oil, which is a disadvantage of oily solids and water-in-oil emulsified creams, by using a volatile oil that evaporates after being applied to the skin. However, solid emulsified cosmetics using silicone oil, especially solid emulsified cosmetics using volatile silicone oil, are not known because they are difficult to stabilize.

[Problems to be Solved by the Invention] In view of the above circumstances, the present inventors have attempted to obtain a solid cosmetic with good stability and excellent feel in an emulsion system using silicone oil. As a result of intensive research,
Polyhydric alcohol type emulsified cosmetics in solid oil, which are made by emulsifying silicone oil, solid wax, and polyhydric alcohol using polyoxyalkylene-modified organopolysiloxane, have extremely good stability and are gentle on the skin. It has a novel feel when applied, such as a moist feeling when applied, and also has an excellent feeling when used, such as ``spread'', ``stickiness'', and ``stickiness'', and has the advantage of expanding the range of container shapes that can be filled. Heading: The present invention has been completed.

[Means for solving the problems] That is, the present invention uses silicone oil, solid wax,
Polyhydric alcohol and the following structural formulas [1], [2], [3]
, [4] and one or more types of polyoxyanylkylene-modified organopolysiloxanes shown in [4].

The configuration of the present invention will be described below.

The polyhydric alcohol-in-solid oil emulsion cosmetic described in the present invention is within the temperature range (0°C to 50°C) normally used as a cosmetic.
Items that have no fluidity and are solidified (including paste)
shows.

The silicone oils used in the present invention are those commonly used in cosmetics, including dialkylpolysiloxanes such as dimethylpolysiloxane, dimethylcyclopolysiloxane, and diethylpolysiloxane, alkylarylpolysiloxanes such as methylphenylpolysiloxane, diarylpolysiloxanes, and fatty acid-modified silicone oils. Polysiloxanes, higher alcohol-modified polysiloxanes, amino-modified polysiloxanes, and polyoxyalkylene-modified organopolysiloxanes other than structural formulas [1], [2], [3], and [4] are used.

The amount of silicone oil to be blended depends on other oil phase components, but it is preferably 30 to 97% by weight in the oil phase and 5 to 85% by weight in the total cosmetic composition. In particular, if you are looking for a product with a less sticky feel during use, it is preferable to use volatile silicone oils represented by structural formulas [5] and [6], and the blending amount is 30 to 97% by weight in the oil phase. Can be blended in any ratio.

The solid waxes used in the present invention are usually those used in cosmetics, and may include petroleum waxes such as paraffin wax and microcrystalline wax, mineral waxes such as osikelite and ceresin, natural waxes such as carnauba wax and candelilla wax, or Examples include mixtures of two or more waxes with a melting point of 50°C or higher,
Particularly preferred is a mixture of linear and/or branched hydrocarbons containing linear hydrocarbons having 25 to 52 carbon atoms as a main component. The type of wax to be used is selected depending on the type of oil component used, but wax esters such as carnauba wax and candelilla wax can produce good results when used alone. It is preferable to mix it with a hydrocarbon wax.

In addition, generally commercially available hydrocarbon solid waxes are obtained as a mixture, so there is a distribution of carbon numbers, and they also contain isoparaffins and naphthenes. It is fine as long as it is something.

The amount of solid wax blended can be adjusted depending on the required hardness, but the ratio of oil phase component to solid wax is 20:
The ratio is preferably 1 to 3:1, and preferably 5 to 20% by weight based on the total cosmetic composition.

The polyoxyalkylene-modified organopolysiloxane used in the present invention has the general formula [1], [2], [3].
, [4], the polyoxyalkylene-modified organopolysiloxane containing 5 to 40% of polyoxyalkylene groups in the molecule and having a molecular weight of 1000 or more is used. The amount of polyoxyalkylene-modified organopolysiloxane to be blended is selected depending on the amount of the aqueous phase to be emulsified, but is preferably 0.2 to 10% by weight based on the total cosmetic composition.

Examples of polyhydric alcohols used in the present invention include ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene gelcol, 1,3-
Butylene gelcol, tetramethylene gelcol, 2.
3-butylene gelcol, pentamethylene gelcol,
dihydric alcohols such as glycerin, trimethylolpropane, trihydric alcohols such as 1,2,6-hexandriol, tetrahydric alcohols such as pentaerythritol, pentahydric alcohols such as xylitol, sorbitol,
Hexavalent alcohols such as mannitol, polyhydric alcohol polymers such as diethylene glycol, dipropylene glycol, triethylene glycol, polypropylene glycol, polyglycerin, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol dimethyl ether , dihydric alcohol alkyl ethers such as ethylene glycol diethyl ether, ethylene glycol dibutyl ether, dihydric alcohol alkyl ethers such as diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, ethylene glycol monomethyl ether acetate, propylene glycol monomethyl Dihydric alcohol ether esters such as ether acetate, glycerin monoalkyl ethers such as patylated alcohol, sugar alcohols such as sorbitol, maltitol, maltotriose, mannitol, sucrose, erythritol, fructose, maltose, xylitol, starch-degrading sugar reducing alcohols etc. The amount of polyhydric alcohol blended in the present invention is preferably 5% by weight or more based on the total cosmetic composition, and the ratio of polyhydric alcohol and other components in the polyhydric alcohol phase is 50% by weight. It is preferable that it is above.

Further, in the present invention, pigment powder can be blended in addition to the essential components of silicone oil, solid wax, polyhydric alcohol, and polyoxyalkylene-modified organopolysiloxane. The pigment powder used in this case is not particularly limited as long as it is normally used in cosmetics, and any pigment powder such as an inorganic pigment, an organic pigment, a metal pigment, etc. can be blended. Talc, kaolin, calcium carbonate, zinc white, titanium dioxide, red iron oxide, yellow iron oxide, black iron oxide, ultramarine blue, titanium chloride mica, bismuth oxychloride, red iron oxide, caking pigment, gunjo pink, chromium hydroxide, Mica titanium, yellow iron oxide, chromium oxide, aluminum cobalt oxide, dark blue, black iron oxide, carbon black, none.

Hydrosilicic acid, magnesium silicate, bentonite, mica, zirconium oxide, magnesium oxide, zinc oxide, titanium oxide, light calcium carbonate, heavy calcium carbonate,
Examples include light magnesium carbonate, heavy magnesium carbonate, and calamine.

Here, it is particularly preferable that the pigment powder be subjected to a hydrophobic treatment. Hydrophobic treatment methods include surface treatment with high viscosity silicone, surface coating with silicone resin that has been reacted with alkylhydrodiene polysiloxane, alkene treatment of this, cation activator, and anion activator. Examples include those treated with one or more types of nonionic activators, those whose surfaces are coated with wax, etc., but there are no particular limitations as long as the surfaces are hydrophobic.

Further, the amount of pigment powder blended is preferably 50% by weight or less in the total cosmetic composition.

Furthermore, the solid polyhydric alcohol-in-oil type emulsified cosmetic composition of the present invention may contain components commonly used in cosmetic compositions within a range that does not impair the effects of the present invention.

For example, water phase components include water, mucopolysaccharides (sodium hyaluronate, etc.), moisturizing agents such as organic acids and organic salts (amino acids, amino acid salts, oxyacid salts, etc.), and oil phase components include petrolatum, lanolin, silicone wax, and high-grade Solid and semi-solid oils such as fatty acids and higher alcohols, squalane, liquid paraffin, ester oils, triglycerides, volatile hydrocarbon oils, liquid oils such as fluorocarbons, cationic surfactants, anionic surfactants, and nonionic surfactants. Surfactants such as active agents, drugs such as vitamin E1 and vitamin E acetate, astringents, antioxidants, preservatives, fragrances, PH adjusters such as dibasic sodium phosphate, clay minerals, thickeners, ultraviolet absorbers etc. can be blended into the emulsified cosmetic composition of the present invention. Among the above-mentioned components that can be blended, it is preferable to blend water within a range that does not impair the effects of the invention, in order to impart a sharp feeling of use.

[Effects of the Invention] The polyhydric alcohol-in-solid oil emulsified cosmetic of the present invention has an oil phase containing volatile silicone oil and solid wax as the outer phase, and uses polyoxyalkylene-modified organopolysiloxane as an emulsifier. This allows a large amount of polyhydric alcohol to be blended, and it is in a solid form with no fluidity.
It has excellent temperature stability with no cracks or cracks, and has a novel feeling of ``moistness'' when applied, and also has an excellent feeling of ``spreading'', ``sticky'', and ``sticky''. It is characterized by the fact that In particular, when used as a makeup cosmetic, it is novel in that it has good makeup retention, can contain various polyhydric alcohols as an internal component even though it is solid, and has a soft and moisturizing feel during use. Ta. It also has the effect of expanding the range of container shapes that can be filled due to its excellent stability.

[Examples] The present invention will be described in detail below using Examples, but the scope of the present invention is not limited thereto in any way. In addition, all compounding amounts in the examples represent weight %.

Example 1 (1) Decamethylcyclopentasiloxane 38 (2
) Aristowax 165°F 10(
3) Polyoxyalkylene-modified organopolysiloxane 2 (general formula [1], molecular weight aoo.

Polyoxyethylene group 20% by weight) (4) Glycerin 50 (1)
The raw materials of (3) to (3) were heated to 80° C., and (4) was added thereto, and after emulsification, the materials were cooled to a chamber @ to obtain the desired solid oil-in-oil polyhydric alcohol type emulsified cosmetic. Examples 2.3 and Comparative Examples 1 to 6 were produced in the same manner as in Example 1.

Example 2 (1) Decamethylcyclopentasiloxane 38・(
2) Ceresin B 10 (
3) Polyoxyalkylene-modified organopolysiloxane 2 (general formula [1], molecular weight 6000, polyoxyethylene group 20% by weight) (4) Glycerin 50 Example 3 (1) Decamethylcyclopentasiloxane 38 (2)
) PM Wax 8210 (3) Polyoxyalkylene-modified organopolysiloxane 2 (General formula [1], molecular weight 6000, polyoxyethylene group 20% by weight) (4) Glycerin 50 Comparative Example 1 (1) Decamethylcyclopentasiloxane 38 (2
) Dextrin palmitic acid partial ester 10 (3) Polyoxyalkylene-modified organopolysiloxane 2 (General formula [1], molecular weight 6000, polyoxyethylene group 20% by weight) (4) Glycerin 50 Comparative Example 2 (-1) Decamethylcyclo Pentasiloxane 38 (
2) Stearic acid 10(3)
Polyoxyalkylene-modified organopolysiloxane 2 (general formula [1], molecular weight 6000, polyoxyethylene group 20% by weight) (4) Glycerin 50 Comparative Example 3 (1) Decamethylcyclopentasiloxane 38 (2)
) Hardened castor oil 10 (3) Polyoxyalkylene-modified organopolysiloxane 2 (General formula [11, molecular weight 6000, polyoxyethylene group 20% by weight) (4) Glycerin 50 Waxes of Examples 1 to 3 and Comparative Examples 1 to 3 The solid polyhydric alcohol-in-oil type emulsified cosmetics obtained using the method were left in constant temperature baths at 25°C and 50°C, and the stability of cracks, warping, separation, etc. was investigated over time. Shown in 1.

・ Stability: No cracking at 25℃, 50℃ + 3veek,
A case where there was no change in state due to separation was considered good, and a case where a change in state was observed was judged as poor.

As is clear from Table 1, the solid water-in-oil emulsion cosmetics of Examples 1 to 3 were stable without cracking, cracking, or separation due to volatilization.

Example 4 (1) Dimethylpolysiloxane (6 cps) 3
8(2) Aristowax 165°F
10(3) Polyoxyalkylene-modified organopolysiloxane 2 (general formula [1], molecular weight 6000, polyoxyethylene group 20% by weight) (4) Glycerin 50 Comparative Example 4 (1) Decamethylcyclopentasiloxane 38(2)
) Aristowax 165°F 10(
3) Diglyceryl diisostearate 2 (4) Glycerin 50 Comparative Example 5 (1) Liquid paraffin 38 (2
) Aristowax 165°F 10(
3) Polyoxyalkylene-modified organopolysiloxane 2 (general formula [1], molecular weight 6000, polyoxyethylene group 20% by weight) (4) Glycerin 50 Comparative Example 6 (1) Decamethylcyclopentasiloxane 85 (2)
) Aristowax 165°F 10(
3) Polyoxyalkylene-modified organopolysiloxane 2 (general formula [1], molecular weight 6000, polyoxyethylene group 20% by weight) (4) Glycerin 3 Solid water-in-oil of Example 1.4 and Comparative Example 5.6 The feel of the emulsified cosmetic was evaluated. Table 2 shows the results.
Shown below. The product obtained in Comparative Example 4 separated immediately after emulsification and did not form a good solid form.

Panel: 20 people Number of people who answered “Good”: 15 or more 07-14 people
△ 6 people or less × The solid emulsified cosmetic obtained in Example 1.4 was moist and had a novel feel that was not sticky.

Example 5 Foundation (1) Decamethylcyclopentasiloxane 38 (2
) Aristowax 165°F 10(3)
Polyoxyalkylene-modified organopolysiloxane 2 (general formula [1], molecular weight 6000, polyoxyethylene group 20% by weight) (4) Hydrophobized pigment powder 30 (5)
) Glycerin 20 (6) Preservative appropriate amount (7) Flavoring
After heating appropriate amounts of (1) to (3) and (7) to 80°C and dissolving them, add (4) and disperse with a homogenizer at 80°C. Add the mixture of (5) and (6) previously heated to 80°C to a colander and emulsify. Thereafter, it was filled into a container and cooled to room temperature to obtain the desired polyhydric alcohol-in-oil type emulsion foundation.

Comparative Example 7 °(1) Decamethylcyclopentasiloxane 38(
2) Carnauba Rou 10(3)
Polyoxyalkylene-modified organopolysiloxane 2 (general formula [1], molecular weight 6000, polyoxyethylene group 20% by weight) (4) Hydrophobized pigment powder 30 (5)
) Glycerin 20 Preservative
Appropriate amount of fragrance
An appropriate amount was produced by the same method as in Example 5.

The solid foundations obtained in Example 5 and Comparative Example 7 were filled into glass bottles and left in constant temperature baths at 25°C and 50°C to examine their stability. Table 3 shows the results.

Table 3 Stability: 25°C, 50°C, 3 weeks The case where there was no change in condition due to cracking, cracking, or separation was considered good, and the case where a change in condition was observed was judged as poor.

As is clear from Table 3, the solid foundation of Example 5 was stable.

Example 6 Polyhydric alcohol type emulsion foundation in stick oil (1) Octamethylcyclotetrasiloxane 15 (2
) Tecamethylcyclopentasiloxane 20(3)
Glyceryl triisooctanate 3 (4) Polyoxyalkylene-modified organopolysiloxane 2 (General formula [3], molecular weight 8000, polyoxyethylene group 30% by weight) (5) Ceresin wax 10 (
6) Hydrophobized pigment powder 30 (7)
) Fragrance Appropriate amount (8) Ion exchange water 2 (9) Glycerin 12 (10) 1.3 Butylene gellicol 6 (11) Preservative
Appropriate amounts (1) to (5) and (
After heating and dissolving 7) at 80°C, add (6) and disperse with a homogenizer at 80°C. The mixture of (8) to (11) previously heated to 80°C is added to a colander and emulsified.

Thereafter, it was filled into a stick-shaped container and cooled to room temperature to obtain the desired stick-shaped emulsified foundation.

Example 7 Solid cosmetic containing urea (1) Trimethylsiloxysilicate 3 (2
) Dimethylpolysiloxane 10(3)
Decamethylcyclopentasiloxane 20(4) Hydrocarbon wax (32-40 carbon atoms) 10(
5) Polyoxyalkylene modified organopolysiloxane 2 (general formula [1], molecular weight 3000, polyoxyethylene group 20% by weight) (6) Propylene glycol 25 (
7) Tetraethylene glycol 15 (8)
) Urea 3 (9) Glycine 3 (10) Diglycerin 3 (11) Ion exchange water 5 (12) Preservative
Appropriate amount (1) to (5) 80
After heating to ℃ and melting, preheating to 80℃ (6)
Add the mixture of (12) to emulsify and disperse. Thereafter, it was filled into an ointment container and cooled to room temperature to obtain the desired urea-containing solid cosmetic.

Example 8 Compact emulsified foundation (1) Decamethylcyclopentasiloxane 38
(2) Dimethylpolysiloxane (6cs)
2 (3) Jojoba oil 2
(4) Ceresin 8
(5) Microcrystalline wax 1 (
6) Polyoxyalkylene-modified organopolysiloxane 2 (general formula [4], molecular weight 8000, polyoxyethylene group 40% by weight) (7) Hydrophobized pigment powder 20 (
8) Ion exchange water 5 (9)
) Sodium L glutamate 1 (1
0) Glycerin 15 (1
1) Dipropylene glycol 6 (1)
2) Appropriate amount of preservative (13
)Fragrance Appropriate amount (1)~
After heating (6) and (13) to 80°C, add (7) and disperse. Next, (8) ~ () heated to 80°C in advance
Add the mixture of 12) and emulsify and disperse. Thereafter, it was filled in a medium tray in a fluid state, cooled to chamber 'a, and placed in a compact container to obtain the desired compact emulsified foundation. The obtained compact emulsified foundation was moist, non-sticky, and convenient to carry.

The manufacturing method of the following examples is to heat and dissolve the oil phase component at 80°C, disperse the powder, emulsify and disperse the water phase component that has been heated in advance, and place it in a container in a fluid state. Filled. After that, it was cooled to obtain the desired product. All of them had good stability and excellent usability, such as a moist feeling.

Example 9 Blush (1) Dimethylpolysiloxane (1,5cs)
20(2) Decamethylcyclopentasiloxane 10
(3) Cetyl isooctanate 15 (4) Polyoxyalkylene-modified organopolysiloxane 3 (General formula [1], molecular weight 6000, polyoxyethylene group 20% by weight) (5) Hydrocarbon wax 12 (6)
) Dimethyl distearyl ammonium chloride 0.2 (7) Fragrance
Appropriate amount (8) Hydrophobized pigment powder 30 (9) Propylene glycol 5 (10) Ion exchange water
1.7 (11) Sodium hyaluronate 0.1 (12) Sodium chondroitin sulfate 1.5 (13) Polyethylene glycol 1.5 (13) Preservative Example 10 Lipstick (1) Octamethylcyclotetrasiloxane 15 (2
) Dimethylpolysiloxane (6cs) 30(
3) Carnavalou 3(4)
Aristowax 165°F 13 (
5) Polyoxyalkylene-modified organopolysiloxane 5 (general formula [2], molecular weight 6000, polyoxyethylene group 15% by weight) (6) Iron oxide field 0.5
(7) Iron oxide yellow 1 (8)
Red No. 204 0.7 (
9) Titanium dioxide 11 (10
) Dibutylhydroxytoluene Appropriate amount (11) Fragrance Appropriate amount (12) Ion exchange water 3 (13) Glycerin 17 (14) Atelocollage >0.3 (15) Sodium pyrrolidone carboxylate 0.5
Example 11 Lip treatment (1) Squalane 10 (2
) Lanolin 2 (3) Octamethylcyclotetrasiloxane 34.69 (4) Isoparaffin (boiling point 155°C) 10 (5) Trimethylsiloxysilicate 3 (6) Hydrocarbon wax
8(7) Polyoxyalkylene-modified organopolysiloxane 3 (General formula [3], molecular weight 10,000, polyoxyethylene group 30% by weight) (8) Ion-exchanged water 3(9)
Glycerin 25 (10) Sodium lactate 0.3 (11) L-
Sodium glutamate 0.3 (12) Sodium hyaluronate 0.1 (13) Sorbitol 0.5 (14) Red 202
No. 0.01 (15) Menthol 0.1 (16) Fragrance Appropriate Amount Patent Applicant Shiseido Co., Ltd.

Claims (1)

[Scope of Claims] (1) Silicone oil, solid wax, polyhydric alcohol, and polyoxyalkylene-modified organopolymer represented by the following structural formulas [1], [2], [3], and [4]. A polyhydric alcohol-in-solid emulsion cosmetic containing one or more siloxanes. ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [1] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [2] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [3] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [ 4] (wherein, R is an alkyl group having 1 to 3 carbon atoms or a phenyl group, R' is hydrogen or an alkyl group having 1 to 12 carbon atoms, p is an integer of 1 to 5, and m is an integer of 5 to 100. (2) The silicone oil has the following structural formula [5]
The polyhydric alcohol-in-solid oil emulsion cosmetic according to claim 1, which is a volatile silicone oil represented by [6]. ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [5] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [6] (3) The main component of the solid wax is linear and/or branched with 25 to 52 carbon atoms. The solid oil-in-polyhydric alcohol emulsion cosmetic according to claim 1 or 2, which is a hydrocarbon wax. (4) The amount of silicone oil is 5 to 80% of the total amount of cosmetics.
A solid oil-in-oil polyhydric alcohol type emulsified cosmetic according to claims 1 to 3, which is % by weight. (5) The amount of volatile silicone oil is 1% relative to the total amount of cosmetics.
Claims 2 to 4 which are 0 to 60% by weight
A solid polyhydric alcohol-in-oil type emulsified cosmetic as described in 2. (6) The amount of solid wax is 3 to 30% of the total amount of cosmetics.
Solid oil-in-oil polyhydric alcohol type emulsified cosmetics according to claims 1 to 5, which are % by weight. (7) The solid oil-in-polyhydric alcohol emulsion cosmetic contains pigments, humectants, solid/semi-solid oils, fluid oils, surfactants,
Claims 1 to 6 contain one or more of the following: drugs, astringents, antioxidants, preservatives, fragrances, PH regulators, clay minerals, thickeners, and ultraviolet absorbers. Polyhydric alcohol emulsion cosmetic in solid oil.