JPH01135637A - Manufacture of thermocuring resin decorative sheet having three-dimensional feeling - Google Patents
Manufacture of thermocuring resin decorative sheet having three-dimensional feelingInfo
- Publication number
- JPH01135637A JPH01135637A JP29414187A JP29414187A JPH01135637A JP H01135637 A JPH01135637 A JP H01135637A JP 29414187 A JP29414187 A JP 29414187A JP 29414187 A JP29414187 A JP 29414187A JP H01135637 A JPH01135637 A JP H01135637A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- extender pigment
- printing
- impregnated
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005989 resin Polymers 0.000 title claims abstract description 29
- 239000011347 resin Substances 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 238000001029 thermal curing Methods 0.000 title 1
- 238000007639 printing Methods 0.000 claims abstract description 25
- 239000000049 pigment Substances 0.000 claims abstract description 14
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 14
- 239000004606 Fillers/Extenders Substances 0.000 claims abstract description 12
- 230000000694 effects Effects 0.000 claims abstract description 12
- 239000000945 filler Substances 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 5
- 239000002245 particle Substances 0.000 claims description 5
- 229920000877 Melamine resin Polymers 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 8
- 239000004640 Melamine resin Substances 0.000 abstract description 7
- 239000004641 Diallyl-phthalate Substances 0.000 abstract description 4
- 239000011324 bead Substances 0.000 abstract description 4
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 3
- 238000000465 moulding Methods 0.000 abstract description 3
- 239000012508 resin bead Substances 0.000 abstract description 3
- 239000005995 Aluminium silicate Substances 0.000 abstract description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 abstract description 2
- 235000012211 aluminium silicate Nutrition 0.000 abstract description 2
- 239000004927 clay Substances 0.000 abstract description 2
- 239000003822 epoxy resin Substances 0.000 abstract description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract description 2
- 229920000647 polyepoxide Polymers 0.000 abstract description 2
- 238000005187 foaming Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 230000001360 synchronised effect Effects 0.000 abstract 1
- 239000000123 paper Substances 0.000 description 12
- 238000004049 embossing Methods 0.000 description 5
- 238000007646 gravure printing Methods 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 238000007645 offset printing Methods 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 description 1
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野］
本発明は、立体感を有する熱硬化性樹脂化粧板の製造方
法に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a method for manufacturing a thermosetting resin decorative board having a three-dimensional effect.
従来の立体感を存する熱硬化性樹脂化粧板の製造方法と
しては、ローラーエンボス、型板エンボスにより、化粧
板表面の柄模様と位置合わせをしながらエンボスを施す
ことが行われている。As a conventional method for producing a thermosetting resin decorative board with a three-dimensional effect, embossing is performed by roller embossing or template embossing while aligning the pattern with the pattern on the surface of the decorative board.
（発明が解決しようとする問題点］
しかしながら、上記従来の製造方法においては、化粧板
表面の柄模様とエンボス加工の位置を完全に一致させる
ことはきわめて困難であり、また、エンボス版の製作が
高価につく問題点があった。(Problems to be Solved by the Invention) However, in the conventional manufacturing method described above, it is extremely difficult to perfectly match the pattern pattern on the surface of the decorative board and the position of the embossing, and it is also difficult to manufacture the embossing plate. The problem was that it was expensive.
本発明の目的は、上記従来の製造方法の問題点を解決し
た立体感を有する熱硬化性樹脂化粧板の製造方法を提供
することにある。An object of the present invention is to provide a method for manufacturing a thermosetting resin decorative board having a three-dimensional effect that solves the problems of the conventional manufacturing method described above.
本発明者らは、上記目的を達成するために鋭意研究を重
ねた結果、導管部を体質顔料を含むインキにて、盛り上
げ印刷を行ない、熱硬化性樹脂を含浸、熱圧成型を行な
う事により、盛り上げ印刷部分の艷と他の部分の艶差が
生じ、立体感のある化粧板が出来ることを見出し、本発
明を完成するに到ったものである。すなわち、
本発明は、
「化粧原紙に通常の印刷インキを用いて所望の絵柄の通
常印刷層を形成し、次いで体質顔料を含むインキを用い
て所望の絵柄の盛り上げ印刷層を形成し、次いで前記二
種の印刷層を形成した化粧原紙に熱硬化性樹脂を含浸さ
せ、乾燥して含浸紙を形成し、この含浸紙を基材と合わ
せ、次いで、加熱加圧成型処理を施すことを特徴とする
立体感を有する熱硬化性樹脂化粧板の製造法。」を要旨
とするものである。As a result of intensive research to achieve the above object, the inventors of the present invention have developed a method of printing the conduit part with an ink containing an extender pigment, impregnating it with a thermosetting resin, and performing hot-pressure molding. They discovered that there is a difference in gloss between the raised print part and the other parts, and that a decorative board with a three-dimensional effect can be produced, and this led to the completion of the present invention. That is, the present invention provides the following methods: ``A normal printing layer with a desired pattern is formed on a decorative base paper using a normal printing ink, a raised printing layer with a desired pattern is formed using an ink containing an extender pigment, and then the above-mentioned The decorative base paper on which two types of printing layers have been formed is impregnated with a thermosetting resin, dried to form an impregnated paper, this impregnated paper is combined with a base material, and then heated and pressure molded. ``A method for producing a thermosetting resin decorative board with a three-dimensional effect.''
化粧原紙は、チタン紙、クラフト紙、薄葉紙等印刷用途
及び熱硬化性樹脂含浸に適するものが使用されるが、好
ましくは、含浸性、意匠性の点でチタン紙が使用され、
坪量６０〜１２０ｇ／ｒｒｆのものが適している。As the decorative base paper, materials suitable for printing purposes and thermosetting resin impregnation, such as titanium paper, kraft paper, and tissue paper, are used, but titanium paper is preferably used in terms of impregnability and design.
A material having a basis weight of 60 to 120 g/rrf is suitable.
通常の印刷法としては、グラビア印刷法、グラビアオフ
セット印刷、シルクスクリーン印刷、フレキソ印刷等を
挙げることができる。Typical printing methods include gravure printing, gravure offset printing, silk screen printing, flexographic printing, and the like.
盛り上げ印刷のインキ樹脂としては、セルロース誘導体
、スチレン樹脂、 （メタ）アクリル樹脂、ロジンエス
テル樹脂、ポリ酢酸ビニル、クマロン樹脂、ポリ塩化ビ
ニル、塩ビー酢ビ共重合樹脂、ポリエステル、ポリウレ
タン、ブチラール樹脂、ポリアミド、メラミン樹脂等が
使用される。Ink resins for raised printing include cellulose derivatives, styrene resin, (meth)acrylic resin, rosin ester resin, polyvinyl acetate, coumaron resin, polyvinyl chloride, vinyl chloride-vinyl acetate copolymer resin, polyester, polyurethane, butyral resin, Polyamide, melamine resin, etc. are used.
そして、好ましくは、盛り上げ印刷部が化粧板表面に艶
消し部となって露出するため、硬化型樹脂、例えばメラ
ミン樹脂等の使用が望ましい。Preferably, since the raised printed portion is exposed as a matte portion on the surface of the decorative board, it is desirable to use a curable resin such as melamine resin.
前記インキ樹脂に含有させる体質顔料は、平均粒径５〜
３０μ程度の多孔質フィラーが望ましい。The extender pigment contained in the ink resin has an average particle size of 5 to 5.
A porous filler of about 30 μm is desirable.
フィラーとしてケイソウ土、シラスバルーン、尿素樹脂
ビーズ、エポキシ樹脂ビーズ、ヘンゾグアナミン樹脂ビ
ーズ、メラミン樹脂ビーズ、アクリル樹脂ビーズ、パー
ライト、パルプパウダー、有機ベントナイト、タルク、
炭酸カルシウム、硫酸バリウム、カオリン、クレー等の
体質顔料や有機発泡フィラー等を使用する。Fillers include diatomaceous earth, Shirasu balloons, urea resin beads, epoxy resin beads, Henzoguanamine resin beads, melamine resin beads, acrylic resin beads, perlite, pulp powder, organic bentonite, talc,
Extender pigments such as calcium carbonate, barium sulfate, kaolin, clay, organic foam fillers, etc. are used.
又、望ましくは、１０〜２０μの粒径のものが印刷適正
及び意匠性で望ましい。Furthermore, particles having a particle size of 10 to 20 μm are desirable for printability and design.
盛り上げ印刷の印刷方法としては、シルクスクリーン印
刷、グラビア印刷、グラビアオフセット印刷、凹版印刷
などが利用できる。特に意匠性を考慮するとグラビア印
刷が望ましく版深が８０μ〜２００μ程度の盛り上げ版
が最適である。As printing methods for raised printing, silk screen printing, gravure printing, gravure offset printing, intaglio printing, etc. can be used. Especially considering the design, gravure printing is preferable, and a raised plate having a plate depth of about 80 to 200 μ is most suitable.
化粧原紙に含浸する熱硬化性樹脂としては、メラミン樹
脂、ジアリルフタレート樹脂、グアナミン樹脂、ポリエ
ステル樹脂、フェノール樹脂等が使用されるが、特に意
匠効果の点でメラミン樹脂、ジアリルフタレート樹脂の
使用が好ましい。Melamine resins, diallyl phthalate resins, guanamine resins, polyester resins, phenol resins, etc. are used as thermosetting resins to be impregnated into the decorative base paper, but the use of melamine resins and diallyl phthalate resins is particularly preferred from the point of view of design effects. .
これら熱硬化性樹脂は通常の含浸機を用いた含浸法によ
り化粧原紙に含浸させる。These thermosetting resins are impregnated into decorative base paper by an impregnation method using a conventional impregnation machine.
Ｃ実施例〕
まず、次の条件で第１図に示すような化粧シートＡを作
成した。Example C] First, a decorative sheet A as shown in FIG. 1 was prepared under the following conditions.
・Ｏ化粧原紙１・・・米坪８０ｇ／ ｒｒｆ化粧板用着
色原紙Ｐ？ｌ−２２Ｐ （真人四層）
○通常印刷層２・・・グラビア印刷により、下記の配合
割合からなる通常のグラビアインキ
で木目模様を印刷した。・O Decorative base paper 1...80g/RRF colored base paper for decorative board P? l-22P (Masato 4 layers) Normal printing layer 2: A wood grain pattern was printed by gravure printing using a normal gravure ink having the following blending ratio.
酢酸セルロース ５〜６重量％
着色顔料 １５〜３５重量％ジブチルフタ
レート （可製剤）
２〜３重量％
溶 剤 ５６〜７８重量％○盛り上げ印
刷層３・・・木目模様に完全同調した導管部を版深１０
０ μ、のグラビア版にて下記配合インキにて印刷した
。Cellulose acetate 5-6% by weight Colored pigment 15-35% by weight Dibutyl phthalate (available) 2-3% by weight Solvent 56-78% by weight depth 10
It was printed using the following blended ink on a 0μ gravure plate.
メラミン樹脂 ２０部
多孔質フィラー ３０部
（ケイソウ土）
着色顔料
溶剤
次いで得られた化粧シートＡを公知の通常のジアリルフ
タレート樹脂、メラミン樹脂に使用されている含浸装置
を使用し、以下の形で含浸、乾燥を行なった。Melamine resin 20 parts Porous filler 30 parts (diatomaceous earth) Colored pigment solvent Next, the obtained decorative sheet A was impregnated in the following manner using a known impregnation device used for ordinary diallyl phthalate resin and melamine resin. , and was dried.
日産化学■製 サントツブＭ−７００ サントノブＭ−７００１００重量部 （メラミン樹脂水溶液） 硬化剤ＨＡ−１０，３／／ 〃 Ｈ八−２０，０５〃 浸透剤Ｍ−７０ １．３ 〃 １２０°Ｃ４分乾燥し、樹脂量１０８ｇ／ボとした。Santotsubu M-700 manufactured by Nissan Chemical ■ Santo Nobu M-700 100 parts by weight (melamine resin aqueous solution) Hardening agent HA-10,3// 〃 〃H8-20,05〃 Penetrant M-70 1.3 It was dried at 120°C for 4 minutes to give a resin amount of 108g/bot.
これを印刷面を上にし、パーティクルボードからなる基
板４上に重ね、更にその上から賦型板をのせて全体の上
下をクツション紙ではさみ、１４０’Ｃｌ５ｋｇ／ｃＩ
Ｉｌで５分間プレスしたところ、第２図に示すような、
導管部のみ艷の消えた立体感のある化粧板Ｂを得た。This was placed on the substrate 4 made of particle board with the printed side facing up, and then a molding plate was placed on top of it, and the top and bottom of the whole was sandwiched between cushion paper.
When pressed for 5 minutes with Il, as shown in Figure 2,
A decorative board B with a three-dimensional effect was obtained in which only the conduit part had disappeared.
〔発明の効果］
導管部に体質顔料を含むインキにて盛り上げ印刷を行な
う事により通常印刷層と同調したマット感を保持する意
匠感良好で、かつ、立体感を有する化粧板が得られる。[Effects of the Invention] By performing raised printing on the conduit portion with an ink containing an extender pigment, a decorative board with a good design feeling that maintains a matte feel in sync with the normal printed layer and a three-dimensional effect can be obtained.
第１図は本発明における化粧シートの概略断面図、第２
図は第１図の化粧シートを使用した本発明の化粧板の概
略断面図である。FIG. 1 is a schematic cross-sectional view of the decorative sheet in the present invention, and FIG.
The figure is a schematic sectional view of a decorative board of the present invention using the decorative sheet of FIG. 1.
Claims (1)
通常印刷層を形成し、次いで体質顔料を含むインキを用
いて所望の絵柄の盛り上げ印刷層を形成し、次いで前記
二種の印刷層を形成した化粧原紙に熱硬化性樹脂を含浸
させ、乾燥して含浸紙を形成し、この含浸紙を基材と合
わせ、次いで、加熱加圧成型処理を施すことを特徴とす
る立体感を有する熱硬化性樹脂化粧板の製造法。 ２、体質顔料として多孔質フィラーを使用し、粒径が５
〜３０μであることを特徴とする特許請求の範囲第１項
記載の立体感を有する熱硬化性樹脂化粧板の製造法。[Scope of Claims] 1. A regular printing layer with a desired pattern is formed on a decorative base paper using a normal printing ink, and then a raised printing layer with a desired pattern is formed using an ink containing an extender pigment, and then a raised printing layer with a desired pattern is formed using an ink containing extender pigment. The decorative base paper on which the two types of printing layers have been formed is impregnated with a thermosetting resin, dried to form an impregnated paper, this impregnated paper is combined with a base material, and then heated and pressure molded. A method for producing a thermosetting resin decorative board having a three-dimensional effect. 2. Use a porous filler as an extender pigment, and the particle size is 5.
A method for producing a thermosetting resin decorative board having a three-dimensional effect according to claim 1, wherein the thickness is 30 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62294141A JP2622132B2 (en) | 1987-11-24 | 1987-11-24 | Manufacturing method of thermosetting resin decorative board with three-dimensional appearance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62294141A JP2622132B2 (en) | 1987-11-24 | 1987-11-24 | Manufacturing method of thermosetting resin decorative board with three-dimensional appearance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01135637A true JPH01135637A (en) | 1989-05-29 |
| JP2622132B2 JP2622132B2 (en) | 1997-06-18 |
Family
ID=17803841
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62294141A Expired - Fee Related JP2622132B2 (en) | 1987-11-24 | 1987-11-24 | Manufacturing method of thermosetting resin decorative board with three-dimensional appearance |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2622132B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7563501B2 (en) | 2003-09-25 | 2009-07-21 | General Dynamics Land Systems | Integral pigments in composite surfaces |
| CN115124283A (en) * | 2022-07-27 | 2022-09-30 | 吉林省上层上品装饰材料有限公司 | Novel colorful diatom ooze wall material and manufacturing process thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50101466A (en) * | 1974-01-10 | 1975-08-12 | ||
| JPS57160635A (en) * | 1981-03-30 | 1982-10-04 | Toppan Printing Co Ltd | Manufacture of thermocuring resin decorative board |
| JPS58162343A (en) * | 1982-03-20 | 1983-09-27 | 永大産業株式会社 | Manufacture of decorative material |
| JPS59232864A (en) * | 1983-06-15 | 1984-12-27 | 大日本印刷株式会社 | Manufacture of decorative material |
-
1987
- 1987-11-24 JP JP62294141A patent/JP2622132B2/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50101466A (en) * | 1974-01-10 | 1975-08-12 | ||
| JPS57160635A (en) * | 1981-03-30 | 1982-10-04 | Toppan Printing Co Ltd | Manufacture of thermocuring resin decorative board |
| JPS58162343A (en) * | 1982-03-20 | 1983-09-27 | 永大産業株式会社 | Manufacture of decorative material |
| JPS59232864A (en) * | 1983-06-15 | 1984-12-27 | 大日本印刷株式会社 | Manufacture of decorative material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7563501B2 (en) | 2003-09-25 | 2009-07-21 | General Dynamics Land Systems | Integral pigments in composite surfaces |
| CN115124283A (en) * | 2022-07-27 | 2022-09-30 | 吉林省上层上品装饰材料有限公司 | Novel colorful diatom ooze wall material and manufacturing process thereof |
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| Publication number | Publication date |
|---|---|
| JP2622132B2 (en) | 1997-06-18 |
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