JPH01115972A - Printing ink composition - Google Patents
Printing ink compositionInfo
- Publication number
- JPH01115972A JPH01115972A JP62272677A JP27267787A JPH01115972A JP H01115972 A JPH01115972 A JP H01115972A JP 62272677 A JP62272677 A JP 62272677A JP 27267787 A JP27267787 A JP 27267787A JP H01115972 A JPH01115972 A JP H01115972A
- Authority
- JP
- Japan
- Prior art keywords
- parts
- water
- ink composition
- printing ink
- soluble
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 22
- 239000011347 resin Substances 0.000 claims abstract description 17
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 8
- 238000009835 boiling Methods 0.000 claims abstract description 6
- 239000003960 organic solvent Substances 0.000 claims abstract description 6
- 239000000049 pigment Substances 0.000 claims abstract description 6
- 239000007787 solid Substances 0.000 claims abstract description 6
- 239000000976 ink Substances 0.000 claims description 37
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 12
- 239000004925 Acrylic resin Substances 0.000 abstract description 2
- 229920000178 Acrylic resin Polymers 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 12
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- -1 same 1001tW Chemical compound 0.000 description 7
- 238000005299 abrasion Methods 0.000 description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 5
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 5
- 239000006229 carbon black Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 229960002887 deanol Drugs 0.000 description 5
- 239000012972 dimethylethanolamine Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 150000002689 maleic acids Chemical class 0.000 description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 5
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 2
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 238000010424 printmaking Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- DTCCVIYSGXONHU-CJHDCQNGSA-N (z)-2-(2-phenylethenyl)but-2-enedioic acid Chemical compound OC(=O)\C=C(C(O)=O)\C=CC1=CC=CC=C1 DTCCVIYSGXONHU-CJHDCQNGSA-N 0.000 description 1
- MFYSUUPKMDJYPF-UHFFFAOYSA-N 2-[(4-methyl-2-nitrophenyl)diazenyl]-3-oxo-n-phenylbutanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C(=O)C)N=NC1=CC=C(C)C=C1[N+]([O-])=O MFYSUUPKMDJYPF-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000010187 litholrubine BK Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229920005792 styrene-acrylic resin Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- RBKBGHZMNFTKRE-UHFFFAOYSA-K trisodium 2-[(2-oxido-3-sulfo-6-sulfonatonaphthalen-1-yl)diazenyl]benzoate Chemical compound C1=CC=C(C(=C1)C(=O)[O-])N=NC2=C3C=CC(=CC3=CC(=C2[O-])S(=O)(=O)O)S(=O)(=O)[O-].[Na+].[Na+].[Na+] RBKBGHZMNFTKRE-UHFFFAOYSA-K 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（並業上の利用分野）
本発明は版画インキ組成物に関し、更に詳細には貯蔵安
定性に優れた版画インキ組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Technical field of application) The present invention relates to a printing ink composition, and more particularly to a printing ink composition having excellent storage stability.
（もＩ来の技術）
ｆＪＩ来１版画インキは、油性タイプ又は中性（油中水
滴型エマルション）タイプのものが用いられていたが、
油性タイプの臭気・毒性や、中性タイプのエマルション
の不安定性のため、近年、顔料と、アルカリ可溶型樹脂
と、高沸点有機溶剤を主成分とする水性タイプの版画イ
ンキが用いられるようになってきている。(Technology from the past) The printmaking inks used since fJI have been either oil-based or neutral (water-in-oil emulsion).
Due to the odor and toxicity of oil-based inks and the instability of neutral emulsions, in recent years water-based printing inks containing pigments, alkali-soluble resins, and high-boiling point organic solvents have come to be used. It has become to.
（発明が解決しようとする問題点）
し、かし７ながら、前記版画インキは長期間保存した場
合、インキ中の液状物が上層に分難する。(Problems to be Solved by the Invention) However, when the printing ink is stored for a long period of time, the liquid in the ink separates into the upper layer.
所詞「水湧き」現象が発生し７てしまい、使用時に撹拌
・混合して用いなければならないという問題点があり、
この「水湧き」現象を防止するには、版画インキ中の、
顔料や充填剤等の粉体の割合を増やし７たり、又は、ア
ルカリ可溶型樹脂の゛割合を増やしたりすることにより
達成し得るが、粉体の割合を増やした場合は、刷り上げ
た版画の耐摩擦性が弱くなり、作品の耐久性が低下する
という問題、又、樹脂の割合を増やした場合は、版画イ
ンキの曳糸性が強くなり、該インキをローラー等を用い
て版木に転写する時、−旦版木に転写されたインキがロ
ーラー等に引っチられ版木上でムラになり、作品の出来
映えが低下するという問題点が発生してしまい、「水湧
き」を防止すると同時に上記「版画の耐摩擦性の低下」
や「版画インキの過度の曳糸性」を発生させない解決手
段は見出されていなかった。There is a problem in that the phenomenon of ``water gushing'' occurs and the product must be stirred and mixed before use.
To prevent this "water gushing" phenomenon, it is necessary to
This can be achieved by increasing the proportion of powder such as pigments and fillers7 or by increasing the proportion of alkali-soluble resin, but if the proportion of powder is increased, the printed print will The problem is that the abrasion resistance of the print ink becomes weaker and the durability of the work decreases.Also, when the proportion of resin is increased, the stringiness of the printing ink becomes stronger, and the ink cannot be applied to the woodblock using a roller or the like. When transferring, there is a problem that the ink transferred to the block gets caught by rollers and becomes uneven on the block, reducing the quality of the work. At the same time, the above-mentioned "decrease in abrasion resistance of prints"
No solution has been found that does not cause "excessive stringiness of printing ink."
（問題点を解決するための手段）
そこで、本発明者は、上記問題点に鑑み、１水湧き」現
象を防止し、貯蔵安定性に優れ、しかも１版画の耐摩擦
性の低下や版画インキの過度のツ、糸性の発生しない版
画インキ組成物を得るべく鋭意研究を重ね、遂に、本発
明を完成させたものであって、本発明は顔料と、アルカ
リ可溶型ｇ脂と、高沸点水溶性有機溶剤とより少なくと
もなる版画インキにむいて、常温で固体であり、且つ、
水溶性のポリエチレングリコールを含むことを特徴とす
る版画インキ組成物を要旨とするものである。(Means for Solving the Problems) Therefore, in view of the above problems, the inventors of the present invention have proposed a method that prevents the "one water spring" phenomenon, has excellent storage stability, and prevents a decrease in the abrasion resistance of one print and print ink. The present invention was finally completed after extensive research in order to obtain a printing ink composition that does not generate excessive heat or stringiness. For printing inks consisting of at least a boiling point water-soluble organic solvent, solid at room temperature, and
The gist of the present invention is a printing ink composition characterized by containing water-soluble polyethylene glycol.
以下、本発明の詳細な説明する。The present invention will be explained in detail below.
、＠料は着色剤として使用するものであり、従来公知の
各種無機及び有機顔料を使用することが出来るが、具体
的には、カーボンブラック、酸化チタン、ベンガラ、カ
ドミウムレッド、レーキレッド、カーミン３Ｂ、同６Ｂ
、黄土、バリウム黄、ハンザエロー〇、同１００１ｔＷ
、群青、バーントシェンナー、フタロシアニンブルー、
フタロシアニングリーン等を適宜単独若しくは４数組合
せて使用でき、その使用量は版画インキ組成物全量に対
して３〜２５重量％が好ましい。, @ materials are used as coloring agents, and various conventionally known inorganic and organic pigments can be used, but specifically carbon black, titanium oxide, red iron, cadmium red, lake red, carmine 3B. , same 6B
, loess, barium yellow, Hansa yellow, same 1001tW
, ultramarine, burnt schener, phthalocyanine blue,
Phthalocyanine green and the like can be appropriately used alone or in combination of four or more, and the amount used is preferably 3 to 25% by weight based on the total amount of the printing ink composition.
アルカリ可溶型樹脂は、上記顔料の定着剤及び展色剤と
して使用するものであり、具体的には、（メタ）アクリ
ル樹脂、スチレン−アクリル樹脂、スチレン−マレイン
酸樹脂、マレイン酸樹脂、フマル酸樹脂、ロジン変性マ
レイン酸Ｊ）１５等を用いることができ、その使用量は
水性版画インキ組成物全量に対して５〜２０重量％が好
ましい。Alkali-soluble resins are used as fixing agents and coloring agents for the above pigments, and specifically include (meth)acrylic resins, styrene-acrylic resins, styrene-maleic acid resins, maleic acid resins, and fumaric acid resins. Acid resins, rosin-modified maleic acid J) 15, etc. can be used, and the amount used is preferably 5 to 20% by weight based on the total amount of the aqueous printing ink composition.
高沸点水溶性有機溶剤は練り板等の非吸収面における版
画インキ組成物の乾燥防止剤として使用するものであり
、具体的には、エチレングリコール、ジエチレングリコ
ール、トリエチレングリコール、プロピレングリコール
、ジプロピレングリコール等のグリコール類、グリセリ
ン、ベンジルアルコール等の単独若しくは複数混合して
用いることができ、その使用量は版画インキ組成物全量
に対し１０〜７（ｌ量％が好ましい。High-boiling point water-soluble organic solvents are used as drying preventive agents for printing ink compositions on non-absorbing surfaces such as mixing plates, and specifically include ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, and dipropylene glycol. Glycols such as glycerin, benzyl alcohol, etc. can be used alone or in combination, and the amount used is preferably 10 to 7% (1% by amount) based on the total amount of the printing ink composition.
本発明の骨子である常温で固体であり、且つ、水溶性の
ポリエチレングリコールは「水湧き」防止剤として用い
るものであって、常温で固体のものは「水湧き」の防止
効果が無く、水への溶Ｎ−１ｖＩ１．が悪いものは、特
に刷り上がり面において析出してしまう場合がある為で
あるが、平均分子量としては８００〜４０００のものが
好ましく用いられる。The gist of the present invention is polyethylene glycol, which is solid at room temperature and soluble in water, and is used as a "water seepage" preventive agent. Dissolution of N-1vI1. If the average molecular weight is 800 to 4000, it is preferable to use one with a poor average molecular weight, since it may precipitate especially on the printed surface.
尚、上記成分以外に必要に応じて、炭酸カルシウム、硫
酸バリウム等の体質／’Ｉ料や、ヒドロキシエチルセル
ロース、ヒドロキシプロピルセルロース等のヒドロキシ
アルキルセルロースの様に曳糸性の無い樹脂や、防腐・
防カビ剤、アルキルベンゼンスルホン酸ソーダ等の界面
活性剤、低級脂肪族アルコールといった浸透・乾燥促進
剤等の添加剤を適宜用いてもよい。In addition to the above-mentioned ingredients, if necessary, constitutional materials such as calcium carbonate and barium sulfate, resins without stringiness such as hydroxyalkyl cellulose such as hydroxyethyl cellulose and hydroxypropyl cellulose, and preservatives and
Additives such as antifungal agents, surfactants such as sodium alkylbenzenesulfonate, and penetration/drying accelerators such as lower aliphatic alcohols may be used as appropriate.
又１本発明の版画インキ組成物は上記成分を三本ロール
ミルや横型ボールミル等の分散機にて混合分散すること
により容易に得ることができる。Furthermore, the printing ink composition of the present invention can be easily obtained by mixing and dispersing the above components in a dispersing machine such as a three-roll mill or a horizontal ball mill.
（作用）
本発明に係る版画インキ組成物が、「水湧き性」がなく
貯蔵安定性に優れ、且つ、版画の耐摩擦性にも優れ、又
、版画インキ組成物の曳糸性も適正であるのは、ポリエ
チレングリコールが常温で固体であり且つ水に対する溶
解性（相溶性）が良好であるため、ポリエチレングリコ
ールの保水性が「水湧き」を抑制し、潤滑性が版画の耐
摩耗性を向上し、更に、該ポリエチレングリコールは曳
糸性を有していないので、過度の曳糸性を付与しないと
推察される。(Function) The print ink composition according to the present invention has no "water-splashing property" and has excellent storage stability, and also has excellent print abrasion resistance, and has appropriate spinnability. One reason is that polyethylene glycol is solid at room temperature and has good solubility (compatibility) in water, so its water-retaining properties suppress "water gushing" and its lubricity improves the abrasion resistance of prints. Furthermore, since the polyethylene glycol does not have stringiness, it is presumed that it does not impart excessive stringiness.
（実施例）
以下１本発明を実施例により更に詳細に説明するが、１
部」とあるものは「重量部」を示すものである。(Example) The present invention will be explained in more detail with reference to Examples below.
"Parts" indicates "parts by weight."
実施例１
カーボンブラック １０部沈降性硫酸
バリウム″ １２部ロジン変性マレイン
酸樹脂 １０部ジメチルエタノールアミン
５部グリセリン ７＠
トリエチレングリコール ２７部イソプロピ
ルアルコール ５部ヒドロキシプロピルセ
ルロース ０．５部ポリエチレン
３部グリコール＃２０００
（平均分子量２０００、日本油脂■製）水
２０．５部上記成分をラ
ボミキサーに入れ、１時間プミキシングした後、３本ロ
ールミルにて２回通しを行ない、黒色の版画インキ組成
物を得た。Example 1 Carbon black 10 parts Precipitated barium sulfate 12 parts Rosin modified maleic acid resin 10 parts Dimethylethanolamine
5 parts glycerin 7@
Triethylene glycol 27 parts Isopropyl alcohol 5 parts Hydroxypropyl cellulose 0.5 parts Polyethylene
3-part glycol #2000 (average molecular weight 2000, manufactured by NOF ■) water
20.5 parts of the above ingredients were placed in a lab mixer, mixed for 1 hour, and then passed twice in a three-roll mill to obtain a black print ink composition.
実施例２
カーミン６Ｂ ＩＱ部沈降性
硫酸バリウム １２部ロジン変性マレイ
ン酸樹脂 １０部ジメチルエタノールアミン
５部エチレングリコール １９．
５部トリエチレングリコール ４０部ヒドロ
キシエチルセルロース ０．５部ポリエチレン
３部グリコール＃１０００
（平均分子量２０００、日本油脂Ｗ＠奥）上記成分をラ
ボミキサーに入れ、１時間プミキシングした後、３本ロ
ールミルにて２回通しを行ない、赤色の版画インキ組成
物を得た。Example 2 Carmine 6B IQ part Precipitated barium sulfate 12 parts Rosin modified maleic acid resin 10 parts Dimethylethanolamine
5 parts ethylene glycol 19.
5 parts triethylene glycol 40 parts hydroxyethyl cellulose 0.5 parts polyethylene
3-part glycol #1000 (average molecular weight 2000, NOF W @ Oku) The above ingredients were placed in a lab mixer, mixed for 1 hour, and then passed through twice in a 3-roll mill to obtain a red print ink composition. Ta.
比較例１
カーボンブラック １０部沈降性硫
酸バリウム １２部ロジン変性マレイン
酸樹脂 １０部ジメチルエタノールアミン
５部グリセリン ７部
トリエチレングリコール ２７部イソプロピ
ルアルコール ５部ポリエチレン
３部グリコール＃４００
（平均分子量３９９、日本油脂４劃
水 ２
１部上記各成分を実施例１と同様になして黒色の版画イ
ンキ組成物を得た。Comparative Example 1 Carbon black 10 parts Precipitated barium sulfate 12 parts Rosin modified maleic acid resin 10 parts Dimethylethanolamine
5 parts glycerin 7 parts triethylene glycol 27 parts isopropyl alcohol 5 parts polyethylene
3 part glycol #400 (average molecular weight 399, NOF 4 Bakusui 2
One part of each of the above components was added in the same manner as in Example 1 to obtain a black print ink composition.
比較例２
カーボンブラック １０部沈降性硫酸
バリウム １２部ロジン変性マレイン酸
樹脂 １０部ジメチルエタノールアミン
５部グリセリン ７部ト
リエチレングリコール ２７部イソプロピル
アルコール ５部ポリエチレン
３部グリコール＃６０００
（平均分子量８３１１．日本油脂■復）水
２１部上記各成分
を実施例１と＠様になして黒色の版画インキ組成物を得
た。Comparative Example 2 Carbon black 10 parts Precipitated barium sulfate 12 parts Rosin modified maleic acid resin 10 parts Dimethylethanolamine
5 parts glycerin 7 parts triethylene glycol 27 parts isopropyl alcohol 5 parts polyethylene
3-part glycol #6000 (average molecular weight 8311. NOF ■Fixed) water
21 parts A black printing ink composition was obtained by using the above components in the same manner as in Example 1.
比較例３
カーボンブラック １ｏ部沈降性硫酸
バリウム １２部ロジン変性マレインａ
樹脂 １０部ジメチルエタノールアミン
５部グリセリン ７部ト
リエチレングリコール ２７部イソプロピル
アルコール ５部水
２４部上記各成分を実施例
１と同様になして黒色の版画インキ組成物を得た。Comparative Example 3 Carbon black 10 parts Precipitated barium sulfate 12 parts Rosin modified maleic a
Resin 10 parts dimethylethanolamine
5 parts glycerin 7 parts triethylene glycol 27 parts isopropyl alcohol 5 parts water
24 parts A black printing ink composition was obtained using the above ingredients in the same manner as in Example 1.
（効果）
上記実施例１，２比較例１〜３につし）て試験を行なっ
た。結果を表１に示す。(Effects) Tests were conducted using the above Examples 1 and 2 and Comparative Examples 1 to 3. The results are shown in Table 1.
×水油き率：各版画インキを高速遠心器（国産遠心器１
ｔｌＨ−２００型）で、１０．ＯＯＯｒｐｍ、３０分間
遠心分難し、版画インキ組成物上層に分離した液状物の
、版画インキ組成物に対する重量比。×Water/oil ratio: Each printmaking ink was
tlH-200 type), 10. OOOrpm, centrifugation for 30 minutes, weight ratio of the liquid separated into the upper layer of the printing ink composition to the printing ink composition.
更に、実施例１，２により得られた版画インキ組成物を
用い、版画を刷ったが、何れも１作品の出来映え良好で
、版画の耐摩擦性も良好であった。尚、比較例２の版画
インキはポリエチレングリコールが析出し、良好な版画
を得られなかった。Further, prints were printed using the print ink compositions obtained in Examples 1 and 2, and each print had good quality and the prints had good abrasion resistance. In addition, polyethylene glycol precipitated in the print ink of Comparative Example 2, and a good print could not be obtained.
以上詳細に説明したように、本発明に係る版画インキ組
成物は、「水湧き」のない貯蔵安定性に優れたものであ
り、且つ、他の版画インキとしての特性においても優れ
たものである。As explained in detail above, the print ink composition according to the present invention has excellent storage stability without "watering up" and also has excellent properties as other print inks. .
更に、本発明が版画用インキのみならず１通常の綴具と
しても用いえること、勿論である。Furthermore, it goes without saying that the present invention can be used not only as a printing ink but also as an ordinary binding tool.
特許出願人 ぺんてる株式会社Patent applicant: Pentel Co., Ltd.
Claims (1)
とより少なくともなる版画インキにむいて、常温で固体
であり、且つ、水溶性のポリエチレングリコールを含む
ことを特徴とする版画インキ組成物。A printing ink composition that is solid at room temperature and contains water-soluble polyethylene glycol, which is suitable for printing inks consisting of at least a pigment, an alkali-soluble resin, and a high-boiling water-soluble organic solvent. .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62272677A JPH01115972A (en) | 1987-10-28 | 1987-10-28 | Printing ink composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62272677A JPH01115972A (en) | 1987-10-28 | 1987-10-28 | Printing ink composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01115972A true JPH01115972A (en) | 1989-05-09 |
Family
ID=17517253
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62272677A Pending JPH01115972A (en) | 1987-10-28 | 1987-10-28 | Printing ink composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01115972A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0688049A (en) * | 1992-09-07 | 1994-03-29 | Nippon Kiyouzai Seisakusho:Kk | Ink for print |
-
1987
- 1987-10-28 JP JP62272677A patent/JPH01115972A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0688049A (en) * | 1992-09-07 | 1994-03-29 | Nippon Kiyouzai Seisakusho:Kk | Ink for print |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2006206669A (en) | Ink composition for cloth | |
| JP3369348B2 (en) | Oil-based pigment ink composition for writing implements | |
| JPH01115972A (en) | Printing ink composition | |
| US20060173095A1 (en) | Water-based ink for stencil printing and stencil printing method | |
| JPH02284971A (en) | Ink composition for woodcut print | |
| JP2699179B2 (en) | Water-based ink composition for writing | |
| JP2572585B2 (en) | Aqueous printing ink composition | |
| US20060216421A1 (en) | Aqueous ink for mimeograph printing and method for mimeograph printing | |
| JP3235687B2 (en) | Aqueous ink composition | |
| JPH01249867A (en) | Woodblock print ink composition | |
| JPS63213583A (en) | Water-based pigment ink for pictorial wood printing | |
| JPH03195785A (en) | Ink composition for woodcut print | |
| JP3721243B2 (en) | Water-based stamp stand ink | |
| JP3753818B2 (en) | Oil-based dye ink | |
| JP2003147252A (en) | Water-based printing ink composition and printing method | |
| JPH0819362B2 (en) | Print ink composition | |
| JP3753817B2 (en) | Oil-based pigment ink | |
| JP4801887B2 (en) | Oil-based ink | |
| JPH04139272A (en) | Water-base pigment ink composition | |
| JPH03223373A (en) | Ink composition for wood printing | |
| JPH03221569A (en) | Ink composition for woodcut print | |
| JPH0741719A (en) | Production of water-base printing ink | |
| JP2008088307A (en) | Ink composition for stamp base or permeating seal | |
| JP5662707B2 (en) | Emulsion ink for stencil printing | |
| JP2000007973A (en) | Ink composition |