JPH01249867A - Woodblock print ink composition - Google Patents
Woodblock print ink compositionInfo
- Publication number
- JPH01249867A JPH01249867A JP63077869A JP7786988A JPH01249867A JP H01249867 A JPH01249867 A JP H01249867A JP 63077869 A JP63077869 A JP 63077869A JP 7786988 A JP7786988 A JP 7786988A JP H01249867 A JPH01249867 A JP H01249867A
- Authority
- JP
- Japan
- Prior art keywords
- ink composition
- alkali
- printing ink
- parts
- soluble
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 26
- 239000011347 resin Substances 0.000 claims abstract description 18
- 229920005989 resin Polymers 0.000 claims abstract description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000839 emulsion Substances 0.000 claims abstract description 10
- 239000000049 pigment Substances 0.000 claims abstract description 10
- 238000009835 boiling Methods 0.000 claims abstract description 6
- 239000003960 organic solvent Substances 0.000 claims abstract description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract description 9
- 239000004925 Acrylic resin Substances 0.000 abstract description 3
- 229920000178 Acrylic resin Polymers 0.000 abstract description 3
- 239000006229 carbon black Substances 0.000 abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract 2
- 230000008719 thickening Effects 0.000 abstract 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 238000005299 abrasion Methods 0.000 description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- -1 burnt schenner Chemical compound 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 150000002689 maleic acids Chemical class 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229960002887 deanol Drugs 0.000 description 2
- 239000012972 dimethylethanolamine Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- DTCCVIYSGXONHU-CJHDCQNGSA-N (z)-2-(2-phenylethenyl)but-2-enedioic acid Chemical compound OC(=O)\C=C(C(O)=O)\C=CC1=CC=CC=C1 DTCCVIYSGXONHU-CJHDCQNGSA-N 0.000 description 1
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical compound [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 1
- MFYSUUPKMDJYPF-UHFFFAOYSA-N 2-[(4-methyl-2-nitrophenyl)diazenyl]-3-oxo-n-phenylbutanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C(=O)C)N=NC1=CC=C(C)C=C1[N+]([O-])=O MFYSUUPKMDJYPF-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000010424 printmaking Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229920005792 styrene-acrylic resin Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- RBKBGHZMNFTKRE-UHFFFAOYSA-K trisodium 2-[(2-oxido-3-sulfo-6-sulfonatonaphthalen-1-yl)diazenyl]benzoate Chemical compound C1=CC=C(C(=C1)C(=O)[O-])N=NC2=C3C=CC(=CC3=CC(=C2[O-])S(=O)(=O)O)S(=O)(=O)[O-].[Na+].[Na+].[Na+] RBKBGHZMNFTKRE-UHFFFAOYSA-K 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は版画インキ組成物に関し、更に詳細には貯蔵安
定性に優れた版画インキ組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to a printing ink composition, and more particularly to a printing ink composition having excellent storage stability.
（従来の技術）
従来、版画インキは、油性タイプ又は中性（油中水滴型
エマルション）タイプのものが用いられていたが、油性
タイプの臭気・毒性や、中性タイプのエマルションの不
安定性のため、近年、顔料と、アルカリ可溶型樹脂と、
高沸点有機溶剤を主成分とする水性タイプの版画インキ
が用いられるようになってきている。(Prior art) Conventionally, printing inks have been oil-based or neutral (water-in-oil emulsion), but oil-based inks have odor and toxicity, and neutral emulsions have instability. Therefore, in recent years, pigments, alkali-soluble resins,
Water-based printing inks containing high-boiling point organic solvents as their main ingredients have come into use.
（発明が解決しようとする課題）
しかしながら、前記版画インキは長期間保存した場合、
インキ中の液状物が上層に分離する、所謂「水湧き」現
象が発生してしまい、使用時に撹拌・混合して用いなけ
ればならないという不具合があり、この「水湧き」現象
を防止するには、版画インキ中の、顔料や充填剤等の粉
体の割合を増やしたり、又は、アルカリ可溶型樹脂の割
合を増やしたりすることにより達成し得るが、粉体の割
合を増やした場合は、刷り上げた版画の耐摩擦性が弱く
なり、作品の耐久性が低下するという不具合、又、樹脂
の割合を増やした場合は、版画インキの曳糸性が強くな
り、該インキをローラー等を用いて版木に転写する時、
−旦版木に転写されたインキがローラー等に引っ張られ
版木上でムラになり、作品の出来映えが低下するという
不具合点が発生してしまい、「水湧き」を防止すると同
時に上記「版画の耐摩擦性の低下」や「版画インキの過
度の曳光性ｊを発生させない解決手段は見出されていな
かった。(Problem to be solved by the invention) However, when the printing ink is stored for a long period of time,
The so-called "water gushing" phenomenon occurs when the liquid in the ink separates into the upper layer, and the problem is that it must be stirred and mixed before use.To prevent this "water gushing" phenomenon, This can be achieved by increasing the proportion of powder such as pigments and fillers in the printing ink, or by increasing the proportion of alkali-soluble resin, but if the proportion of powder is increased, The problem is that the abrasion resistance of the printed print becomes weaker, reducing the durability of the work.Also, when the proportion of resin is increased, the threadability of the print ink becomes stronger, making it difficult to use the ink with a roller, etc. When transferring to a woodblock,
-The ink that has been transferred to the block is pulled by rollers and becomes uneven on the block, resulting in problems such as deteriorating the quality of the work. No solution has been found that does not cause a decrease in abrasion resistance or an excessive light-repelling property of the printing ink.
（課題を解決するための手段）
そこで、本発明者は、上記不具合点に鑑み、「水湧き」
現象を防止し、貯蔵安定性に優れ、しかも、版画の耐摩
擦性の低下や版画インキの過度の曳糸性の発生しない版
画インキ組成物を得るべく鋭意研究を重ね、遂に、本発
明を完成させたものであって、本発明は顔料と、アルカ
リ可溶型樹脂と、高沸点水溶性有機溶剤とより少なくと
もなる版画インキにおいて、アルカリ増粘型アクリ、ル
エマルジョンを含むことを特徴とする版画インキ組成物
を要旨とするものである。(Means for Solving the Problems) Therefore, in view of the above-mentioned disadvantages, the inventors have developed a "water spring"
In order to obtain a print ink composition that prevents this phenomenon, has excellent storage stability, and does not reduce the abrasion resistance of the print or cause excessive stringiness of the print ink, the present invention was finally completed. The present invention relates to a printing ink comprising at least a pigment, an alkali-soluble resin, and a high-boiling water-soluble organic solvent, which is characterized by containing an alkali-thickened acrylic emulsion. The gist is an ink composition.
以下、本発明の詳細な説明する。The present invention will be explained in detail below.
顔料は着色剤として使用するものであり、従来公知の各
種無機及び有機顔料を使用することが出来るが、具体的
には、カーボンブラック、酸化チタン、ベンガラ、カド
ミウムレッド、レーキレッド、カーミン３Ｂ、同６Ｂ、
黄土、バリウム黄、ハンザエロー〇、同ＬＯＧ、紺青、
群青、バーントシェンナー、フタロシアニンブルー、フ
タロシアニングリーン等を適宜単独若しくは複数組合せ
て使用でき、その使用量は版画インキ組成物全量に対し
て３〜２５重量％が好ましい。The pigment is used as a coloring agent, and various conventionally known inorganic and organic pigments can be used, but specific examples include carbon black, titanium oxide, red iron, cadmium red, lake red, carmine 3B, and the like. 6B,
Ocher, barium yellow, Hansa yellow, same LOG, dark blue,
Ultramarine blue, burnt schenner, phthalocyanine blue, phthalocyanine green, etc. can be appropriately used alone or in combination, and the amount used is preferably 3 to 25% by weight based on the total amount of the printing ink composition.
アルカリ可溶型樹脂は、上記顔料の定着剤及び展色剤と
して使用するものであり、具体的には、（メタ）アクリ
ル樹脂、スチレン−アクリル樹脂、スチレン−マレイン
酸樹脂、マレイン酸樹脂、フマル酸樹脂、ロジン変性マ
レイン酸樹脂等を用いることができ、その使用量は水性
版画インキ組成物全量に対して５〜２０重量％が好まし
い。Alkali-soluble resins are used as fixing agents and coloring agents for the above pigments, and specifically include (meth)acrylic resins, styrene-acrylic resins, styrene-maleic acid resins, maleic acid resins, and fumaric acid resins. Acid resins, rosin-modified maleic acid resins, etc. can be used, and the amount used is preferably 5 to 20% by weight based on the total amount of the aqueous printing ink composition.
高沸点水溶性有機溶剤は練り板等の非吸収面における版
画インキ組成物の乾燥防止剤として使用するものであり
、具体的には、エチレングリコール、ジエチレングリコ
ール、トリエチレングリコール、プロピレングリコール
、ジプロピレングリコール等のグリコール類、グリセリ
ン、ベンジルアルコール等の単独若しくは複数混合して
用いることができ、その使用量は版画インキ組成物全量
に対し１０〜７０重量％が好ましい。High-boiling point water-soluble organic solvents are used as drying preventive agents for printing ink compositions on non-absorbing surfaces such as mixing plates, and specifically include ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, and dipropylene glycol. Glycols such as glycerin, benzyl alcohol, etc. can be used alone or in combination, and the amount used is preferably 10 to 70% by weight based on the total amount of the printing ink composition.
本発明の骨子であるアルカリ増粘型アクリルエマルジョ
ンは「水湧き」防止剤として用いるもので、エマルジョ
ン自体のｐＨは酸性で、アルカリ物質で中和すると、エ
マルジョンのアクリル樹脂粒子が膨潤し大きくなるとい
う特性を有するものであって具体的には、ビニゾール１
０２０（大同化成■製）プライマルＡＳＥ−６０、同７
５．同９５．同１０８（ローム・アンド・ハース社製）
ビス力レックスＨＶ３０． 同ＶＭ、同ＶＳ、同ＶＧ３
．同ＶＧ２ （７ライド・コロイド社製）等が好ましく
用いられ、その使用量は版画インキ組成物全量に対し０
．１〜４゜０重量％が好ましい。The alkali-thickened acrylic emulsion, which is the essence of the present invention, is used as an agent to prevent "water gushing"; the pH of the emulsion itself is acidic, and when neutralized with an alkaline substance, the acrylic resin particles in the emulsion swell and become larger. It has the characteristics, specifically, Vinizol 1
020 (manufactured by Daido Kasei ■) Primal ASE-60, Daido Kasei 7
5. 95. Same 108 (manufactured by Rohm and Haas)
Vistoriki Rex HV30. Same VM, same VS, same VG3
．． The same VG2 (manufactured by 7Ride Colloid Co., Ltd.) etc. are preferably used, and the amount used is 0% based on the total amount of the printing ink composition.
．． 1 to 4.0% by weight is preferred.
尚、上記成分以外に必要に応じて、炭酸カルシウム、硫
酸バリウム等の体質顔料や、ヒドロキシエチルセルロー
ス、ヒドロキシプロピルセルロース等のヒドロキシアル
キルセルロースの様に曳糸性の無い樹脂や、防腐・防カ
ビ剤、アルキルベンゼンスルホン酸ソーダ等の界面活性
剤、低級脂肪族アルコールといった浸透・乾燥促進剤等
の添加剤を適宜用いてもよい。In addition to the above ingredients, if necessary, extender pigments such as calcium carbonate and barium sulfate, non-stringinable resins such as hydroxyalkyl cellulose such as hydroxyethyl cellulose and hydroxypropyl cellulose, preservatives and antifungal agents, Additives such as surfactants such as sodium alkylbenzenesulfonate and penetration/drying accelerators such as lower aliphatic alcohols may be used as appropriate.
又１本発明の版画インキ組成物は上記成分を三本ロール
ミルや横型ボールミル等の分散機にて混合分散すること
により容易に得ることができる。Furthermore, the printing ink composition of the present invention can be easily obtained by mixing and dispersing the above components in a dispersing machine such as a three-roll mill or a horizontal ball mill.
（作用）
本発明に係る版画インキ組成物が、「水湧き性」がなく
貯蔵安定性に優れ、且つ１版画の耐摩擦性にも優れ、又
、版画インキ組成物の曳糸性も適正であるのは１版画イ
ンキ組成物中において、アルカリ増粘型アクリルエマル
ジョンの樹脂粒子が膨潤し、この膨潤物とアルカリ可溶
型樹脂とが絡み合い、顔料や充填剤の沈降を抑制し「水
湧き」を防止し、又、アルカリ増粘型アクリルエマルジ
ョンを用いることにより、粉体の使用量が少なくてすむ
ので版画の耐摩耗性、乍向−１：’−Ｌ、’、更り、″
、該アルカリ増粘型アクリル１マルジヨンは曳糸性を有
し゛（いないので、過度の曳糸性を付与しないと推察さ
れる。(Function) The print ink composition according to the present invention has no "water springing property" and is excellent in storage stability, and also has excellent abrasion resistance for a single print, and the print ink composition has appropriate threadability. One reason is that in the print ink composition, the resin particles of the alkali-thickened acrylic emulsion swell, and this swollen product and alkali-soluble resin intertwine, suppressing the settling of pigments and fillers, and causing "water gushing". In addition, by using an alkali-thickened acrylic emulsion, the amount of powder used can be reduced, improving the abrasion resistance of prints.
Since the alkali-thickened acrylic 1-mulsion has no stringiness, it is presumed that it does not impart excessive stringiness.
（実施例）
以下、本発明を実施例により更に詳細に説明するが、「
部」とあるものは「重量部」を示すものである。(Example) Hereinafter, the present invention will be explained in more detail with reference to Examples.
"Parts" indicates "parts by weight."
実施例１
カーボンブラック １０部沈降性硫
酸バリウム １５部ロジン変性マレイン
酸樹脂 １０部ジメチルエタノールアミン
５部グリセリン ７
部トリエチレングリコール ２６部イソプロ
ピルアルコール ５部プライマルＡＳＥ−
６０ ２部（ローム・アンド・ハース社製
）
水
２０部上記成分をラボミキサーに入れ、１時間プミキシ
ングした後、３本ロールミルにて２回通しを行ない、黒
色の版画インキ組成物を得た。Example 1 Carbon black 10 parts Precipitated barium sulfate 15 parts Rosin modified maleic acid resin 10 parts Dimethylethanolamine
5 parts glycerin 7
Part triethylene glycol 26 parts Isopropyl alcohol 5 parts Primal ASE-
60 2 parts (manufactured by Rohm and Haas) Water
20 parts of the above ingredients were placed in a lab mixer, mixed for 1 hour, and then passed twice in a three-roll mill to obtain a black printing ink composition.
実施例２
カー・ミン６Ｂ １０部沈降性
硫酸バリウム １５部ロジン変性マレイ
ン酸樹脂 １０部ジメチルエタノールアミン
５部エチレングリコール ２
０部トリエチレングリコール ３部部ビス力
レックスＨＶ３０ １部（アライドコロイ
ド社製）
水
９部上記成分をラボミキサーに入れ、１時間プミキシ
ングした後、３本ロールミルにて２回通しを行ない、赤
色の版画インキ組成物を得た。Example 2 Ka Min 6B 10 parts Precipitated barium sulfate 15 parts Rosin modified maleic acid resin 10 parts Dimethylethanolamine
5 parts ethylene glycol 2
0 parts triethylene glycol 3 parts Bisryk Rex HV30 1 part (manufactured by Allied Colloid) Water
9 parts of the above ingredients were placed in a lab mixer, mixed for 1 hour, and then passed twice in a 3-roll mill to obtain a red printing ink composition.
比較例１
実施例１のプライマルＡＳＥ ６０ ２部をグリセリ
ンにかえた以外は実施例１と同様になして黒色の版画イ
ンキ組成物を得た。Comparative Example 1 A black printing ink composition was obtained in the same manner as in Example 1, except that 2 parts of Primal ASE 60 in Example 1 was replaced with glycerin.
比較例２
実施例２のビス力しックストエＶ３０ １部をエチレン
グリコールにかえた以外は実施例２と同様になして赤色
の版画インキ組成物を得た。Comparative Example 2 A red printing ink composition was obtained in the same manner as in Example 2, except that 1 part of the V30 of Example 2 was replaced with ethylene glycol.
（効果）
上記実施例１，２比較例１，２について試験を行なった
。結果を表１に示す。(Effect) Tests were conducted on the above Examples 1 and 2 and Comparative Examples 1 and 2. The results are shown in Table 1.
表１
※水湧き率：各版画インキを低温（−２０°Ｃ）に２４
時間保存した後、高温（５０”Ｃ）に２４時間保存し、
これを繰り返す冷熱サイクル試験を５回繰り返した後、
版画インキ組成物上層に分離した液状物の、版画インキ
組成物に対する重量比。Table 1 *Water spring rate: Each printmaking ink was heated to a low temperature (-20°C) for 24 hours.
After storing for an hour, store at high temperature (50”C) for 24 hours,
After repeating this repeated heating and cooling cycle test five times,
The weight ratio of the liquid separated in the upper layer of the print ink composition to the print ink composition.
更に、実施例１，２により得られた版画インキ組成物を
用い、版画を刷ったが、何れも、作品の出来映え良好で
、版画の耐摩擦性も良好であった。Further, prints were printed using the print ink compositions obtained in Examples 1 and 2, and in both cases, the workmanship was good and the prints had good abrasion resistance.
以上詳細に説明したように、本発明に係る版画インキ組
成物は、「水湧き」のない貯蔵安定性に優れたものであ
り、且つ、他の版画インキとしての特性においても優れ
たものである。As explained in detail above, the print ink composition according to the present invention has excellent storage stability without "watering up" and also has excellent properties as other print inks. .
更に、本発明が版画用インキのみならず、通常の絵具と
しても用い得ること、勿論である。Furthermore, it goes without saying that the present invention can be used not only as a printing ink but also as a regular paint.
特許出願人 ぺんてる株式会社Patent applicant: Pentel Co., Ltd.
Claims (1)
とより少なくともなる版画インキにおいて、アルカリ増
粘型アクリルエマルジョンを含むことを特徴とする版画
インキ組成物。A printing ink composition comprising at least a pigment, an alkali-soluble resin, and a high-boiling water-soluble organic solvent, the printing ink composition comprising an alkali-thickened acrylic emulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63077869A JPH01249867A (en) | 1988-03-30 | 1988-03-30 | Woodblock print ink composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63077869A JPH01249867A (en) | 1988-03-30 | 1988-03-30 | Woodblock print ink composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01249867A true JPH01249867A (en) | 1989-10-05 |
Family
ID=13646064
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63077869A Pending JPH01249867A (en) | 1988-03-30 | 1988-03-30 | Woodblock print ink composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01249867A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0466493A1 (en) * | 1990-07-13 | 1992-01-15 | Binney & Smith Inc. | Aqueous permanent coloring composition |
| US5288160A (en) * | 1990-07-13 | 1994-02-22 | Binney & Smith | Aqueous permanent coloring composition |
-
1988
- 1988-03-30 JP JP63077869A patent/JPH01249867A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0466493A1 (en) * | 1990-07-13 | 1992-01-15 | Binney & Smith Inc. | Aqueous permanent coloring composition |
| US5288160A (en) * | 1990-07-13 | 1994-02-22 | Binney & Smith | Aqueous permanent coloring composition |
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