JPH01110599A - Fragrant detergent composition for flush toilet - Google Patents
Fragrant detergent composition for flush toiletInfo
- Publication number
- JPH01110599A JPH01110599A JP26748987A JP26748987A JPH01110599A JP H01110599 A JPH01110599 A JP H01110599A JP 26748987 A JP26748987 A JP 26748987A JP 26748987 A JP26748987 A JP 26748987A JP H01110599 A JPH01110599 A JP H01110599A
- Authority
- JP
- Japan
- Prior art keywords
- water
- pref
- ingredients
- compound
- propylene oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title abstract description 15
- 239000003599 detergent Substances 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- 239000004166 Lanolin Substances 0.000 claims abstract description 5
- 125000002877 alkyl aryl group Chemical group 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 229940039717 lanolin Drugs 0.000 claims abstract description 5
- 235000019388 lanolin Nutrition 0.000 claims abstract description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 125000003158 alcohol group Chemical group 0.000 claims description 3
- 238000013329 compounding Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 35
- 150000001875 compounds Chemical class 0.000 abstract description 12
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract description 10
- 238000004090 dissolution Methods 0.000 abstract description 7
- 238000002844 melting Methods 0.000 abstract description 7
- 230000008018 melting Effects 0.000 abstract description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 2
- 229920001400 block copolymer Polymers 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 description 22
- 238000004140 cleaning Methods 0.000 description 16
- 125000003118 aryl group Chemical group 0.000 description 14
- 239000002202 Polyethylene glycol Substances 0.000 description 13
- 229920001223 polyethylene glycol Polymers 0.000 description 13
- 239000007864 aqueous solution Substances 0.000 description 6
- -1 nonylphenyl Chemical group 0.000 description 6
- 239000012459 cleaning agent Substances 0.000 description 5
- 229920001214 Polysorbate 60 Polymers 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000001877 deodorizing effect Effects 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000002386 air freshener Substances 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004067 bulking agent Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Abstract
Description
【発明の詳細な説明】 ［産業上の利用分野］ 本発明は水洗トイレット用芳香洗浄剤組成物に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to an aromatic cleaning composition for flush toilets.
水洗トイレット用芳書洗浄剤は、固形状であって、容器
に収納して、もしくはそのままの状態で水洗トイレット
の貯水タンク内に直接投入するか、あるいは貯水タンク
の丁洗い部に取りつけることにより、タンク内の貯留水
にその組成物を徐々に溶解または分散させ、水洗時の流
水と共にトイレット便器などを洗浄し、かつ芳香を漂わ
せ、トイレット内をされやかに保つための薬剤である。The cleaning agent for flush toilets is in solid form, and can be stored in a container or put directly into the water tank of the flush toilet, or attached to the washing section of the water tank. This is a drug that gradually dissolves or disperses the composition in the water stored in the tank, cleans the toilet bowl with the flushing water, and emits a fragrance to keep the inside of the toilet fresh.
［従来の技術］
かかる水洗トイレット用芳呑洗浄剤組成物には、芳容成
分および洗浄成分のほかに主基剤が配合されている。こ
の主基剤は、芳容成分や洗浄成分を固形化するためのバ
インダーとしての役割のほか、流水や貯水への配合成分
の溶解速度をコントロールして適度な芳容性と洗浄性を
適度な期間持続させる役割を６している。こうした主基
剤としては、ポリエチレングリコール、あるいはポリエ
チレングリコールの片末端または両末端の０１１をアル
キル基などで置換してエーテルまたはエステルとしたも
の（以下、ポリエチレングリコールタイプという）、プ
ロピレンオキシドとエチレンオキシドのみからなる両末
端が水素原子の共重合体タイプのものなどが用いられて
いる（たとえば特開昭５１−３９７０５号、同５３−３
１７０９号、同５５−１３１０９８号および同５７−１
７９２９８号各公報参照）。[Prior Art] In addition to aromatic components and cleaning components, such aromatic cleaning agent compositions for flush toilets contain a main base. This main base material not only plays a role as a binder to solidify the aromatic ingredients and cleaning ingredients, but also controls the dissolution rate of the ingredients in running water or stored water to achieve the appropriate aromaticity and cleaning properties. It plays the role of sustaining it for a certain period of time. Such main base materials include polyethylene glycol, 011 at one or both ends of polyethylene glycol is substituted with an alkyl group to form an ether or ester (hereinafter referred to as polyethylene glycol type), and only propylene oxide and ethylene oxide. A copolymer type with hydrogen atoms at both ends (for example, JP-A-51-39705, JP-A-53-3) is used.
No. 1709, No. 55-131098 and No. 57-1
(Refer to each publication No. 79298).
［発明で解決しようとする問題点］
しかしながら、これらの従来の水洗トイレット用芳谷洗
浄剤の主基剤は、それぞれっぎのような問題点を９して
いる。 ″
ポリエチレングリコールタイプのものでは、水溶性がよ
すぎて持続性に劣る点、および水溶性が水温によって左
右される点に基本的な問題がある。すなわち、水溶性が
よすぎると配合成分の溶出速度が大きくなり、短時間で
効果が失われてしまう。この点を補うべく分子量を高く
するとある程度水溶性を抑えることはできるが、その高
分子量化に長時間を要するため高価となるほか、ハンド
リングが難しくなるなどの新たな問題が生ずる。また、
水溶性が水温によって左右されやすいと夏期と冬期で溶
解性が異なり、その結果、年間を通じて適度な持続性が
要求される水洗トイレット用芳香洗浄剤の主基剤として
は好ましくない。[Problems to be Solved by the Invention] However, the main bases of these conventional Yoshitani cleaning agents for flush toilets each have the following problems. ″ The basic problem with polyethylene glycol type products is that they are too water soluble, resulting in poor sustainability, and that water solubility is affected by water temperature.In other words, if the water solubility is too high, the ingredients may elute. The speed increases, and the effect is lost in a short time.To compensate for this, increasing the molecular weight can suppress water solubility to some extent, but it takes a long time to increase the molecular weight, making it expensive and difficult to handle. New problems arise, such as the difficulty of
If the water solubility is easily affected by water temperature, the solubility will be different in summer and winter, and as a result, it is not preferred as a main base for an aromatic cleaning agent for flush toilets that requires moderate sustainability throughout the year.
一方、両末端が水素原子のプロピレンオキシドとエチレ
ンオキシドのみの共重合体タイプのものでは、分子量を
高くする以外にプロピレンオキシドユニットの含量を大
きくすることによって水溶性を低下させることができ、
これらの：Ｊ３整により目的とする適度な水溶性をえよ
うとしている。しかし、プロピレンオキシドユニットの
含量を大きくするとえられる固形物の融点および硬度が
低ドし、極端なばあい夏期においては液状になってしま
うこともあり、最適の水溶性と硬度を年間を通じてうろ
ことは困難である。分子量を高める手段として、ポリア
ルキレン化合物をホルマールなどで結合する方法なども
あるが、高分子量の原料をさらに反応させて高分子量化
することは技術的に難しく、またえられたものも高価と
なる。On the other hand, in the case of a copolymer of only propylene oxide and ethylene oxide, which have hydrogen atoms at both ends, water solubility can be lowered by increasing the content of propylene oxide units in addition to increasing the molecular weight.
We are trying to obtain the desired water solubility by adjusting these :J3. However, if the content of propylene oxide units is increased, the melting point and hardness of the solid material will be lowered, and in extreme cases it may become liquid in the summer. It is difficult. One way to increase the molecular weight is to bond polyalkylene compounds with formal, etc., but it is technically difficult to further react high molecular weight raw materials to increase the molecular weight, and the resulting product is also expensive. .
本発明は、適度な溶解速度を有しかつ溶解性が水温に依
存しない主基剤が配合されてなる水洗トイレット用芳香
洗浄剤組成物を提供することを目的とする。An object of the present invention is to provide an aromatic cleaning composition for flush toilets, which contains a main base having an appropriate dissolution rate and whose solubility does not depend on water temperature.
ｃ問題点を解決するための手段〕
かかる１］的は、主基剤として一般式（Ｉ）＝（式中、
Ｒはアルキル基またはアルキルアリール基、あるいはＲ
Ｏがラノリンアルコール残基、■は１０以上の整数、ｎ
は１００以上の整数、れぞれブロック重合ユニットであ
る）で示される化合物を用いることにより達成される。Means for Solving Problem c] Such 1] target has the general formula (I)=(in the formula,
R is an alkyl group or an alkylaryl group, or R
O is a lanolin alcohol residue, ■ is an integer of 10 or more, n
is an integer of 100 or more, each of which is a block polymerization unit).
［作用および実施例］
前記一般式＋１１で示される化合物は、プロピレンオキ
シドとエチレンオキシドとのブロック共重合体であり、
プロピレンオキシドユニットの末端にラノリンアルコー
ルの残基、あるいは酸素原子を介してアルキル基または
アルキルアリール基を有しているものである。アルキル
基としては、炭素数が１５以上のものが好ましく、たと
えばペンタデシル、ヘキサデシル、ヘプタデシル、オク
タデシル、ノナデシル、エイコシル、ヘキサデシル、ト
コシルなどがあげられる。[Function and Examples] The compound represented by the general formula +11 is a block copolymer of propylene oxide and ethylene oxide,
The terminal of the propylene oxide unit has a lanolin alcohol residue, or an alkyl group or alkylaryl group via an oxygen atom. The alkyl group preferably has 15 or more carbon atoms, such as pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosyl, hexadecyl, tocosyl, and the like.
アルキルアリール基としては、炭素数が７以上のものが
好ましく、たとえばノニルフェニル、オクチルフェニル
などがあげられる。炭素数が７未満となると水への溶解
速度が速くなる傾向にある。The alkylaryl group preferably has 7 or more carbon atoms, such as nonylphenyl and octylphenyl. When the number of carbon atoms is less than 7, the dissolution rate in water tends to be faster.
プロピレンオキシドユニットの重合度ｍは１０以上であ
ることが必要である。１０未満のばあいは水への溶解速
度が速くなり好ましくない。■が大きくなければなるほ
ど溶解速度が小さくなるが、それと同時に融点を低下さ
せる。好ましい１はｌＯ〜６０であり、プロピレンオキ
シドユニットの含量は化合物（１）全体の約５〜２５重
量９６とするのが好ましい。エチレンオキシドの重合度
ｎは、夏期における液化現象（融解現象）を避けるため
に１００以上、好ましくは１５０〜１０００とすること
を要する。It is necessary that the degree of polymerization m of the propylene oxide unit is 10 or more. If it is less than 10, the rate of dissolution in water becomes high, which is not preferable. The larger (2) is, the lower the dissolution rate is, but at the same time the melting point is lowered. Preferably, 1 is 10 to 60, and the content of propylene oxide units is preferably about 5 to 25 96 by weight of the entire compound (1). The degree of polymerization n of ethylene oxide must be 100 or more, preferably 150 to 1000, in order to avoid liquefaction (melting) during summer.
かかる化合物（１）の融点は約６０〜６５℃である。The melting point of such compound (1) is about 60-65°C.
本発明の水洗トイレット用芳香洗浄剤組成物は、前記化
合物（１１を主基剤とするほかは、通常の芳香成分、洗
浄成分、その他の凶加剤が配合される。これらの成分の
配合割合は商品設計によって適宜選定されるが、通常つ
ぎの範囲で選定される。In addition to the above-mentioned compound (11) as the main base, the aromatic cleaning composition for flush toilets of the present invention contains ordinary aromatic components, cleaning components, and other harmful agents.The blending ratio of these components is selected as appropriate depending on the product design, but is usually selected within the following range.
（ｆｆｌ量部）
一般式＋１）示される主基剤 ５０〜７５芳谷（
消臭）成分 １０〜２０洗浄成分
ｌＯ〜５その他
３０〜０芳６（消臭）成分としでは、調合δ料に代表
される芳香成分やリンゴ酸、グリオキザールなどの消臭
成分があげられ、洗浄成分としてはエーテル型非イオン
系界面活性剤、α−オレフィン炭化水素化合物、アルキ
ルエーテル硫酸塩などの通常この分野で使用される物質
がそのまま用いられうる。その他の成分としては、トイ
レット流水に清潔感を与える着色剤、油性成分の乳化可
溶化剤、殺菌剤、キレート剤などがあげられるが、芒硝
やグルコースなどの増量剤、ポリエチレングリコールま
たはその誘導体などの溶解性調節剤なども必要に応じて
適宜配合してもよい。(ffl parts) Main base represented by general formula +1) 50-75 Yoshitani (
Deodorizing) Ingredients 10-20 Cleaning Ingredients
lO~5Others
30-0 aroma 6 (deodorizing) ingredients include aroma ingredients represented by blended δ ingredients, malic acid, glyoxal, and other deodorizing ingredients, and cleaning ingredients include ether-type nonionic surfactants, α - Substances commonly used in this field, such as olefin hydrocarbon compounds and alkyl ether sulfates, can be used as they are. Other ingredients include coloring agents that give toilet flushing a sense of cleanliness, emulsifying and solubilizing agents for oil-based ingredients, disinfectants, and chelating agents, as well as bulking agents such as Glauber's Salt and glucose, and polyethylene glycol or its derivatives. A solubility regulator and the like may also be added as appropriate.
これらの各成分を混合し、成形して水洗］・イレット用
芳谷剤が作製されるのであるが、成形法としては、主基
剤成分を加温溶融したのち撹拌しながら他の成分を混合
し、ついで凝固点付近まで徐冷したのち型に注入して固
化する方法、各成分を微粉末にして均一に混合したのち
圧縮成形する方法などが採用される。These ingredients are mixed, molded, and washed with water.] - An air freshener for islets is produced.The molding method involves heating and melting the main base component, and then mixing the other components while stirring. Then, after slow cooling to near the solidification point, it is poured into a mold and solidified, or after each component is made into fine powder and mixed uniformly, it is compression molded.
つぎに本発明の組成物を実施例に基づいて説明するが、
本発明はかかる実施例のみに限定されるものではない。Next, the composition of the present invention will be explained based on Examples.
The present invention is not limited to such embodiments.
実施例１
つぎの成分のうち、生捕成分を加温溶融したのち撹拌ド
に残りの成分を加えて混合し、凝固点付近まで徐冷した
のち型に入れ、固化して本発明の水洗トイレット用芳谷
剤を作製した。Example 1 Among the following ingredients, after heating and melting the raw trapped ingredients, the remaining ingredients were added to a stirrer and mixed, slowly cooled to around the freezing point, placed in a mold, and solidified to form the flush toilet of the present invention. An aromatic agent was prepared.
（成分） （重量部）
Ｈ３
Ｃ１１０÷Ｃ１１２Ｃ１１０±−→Ｃ１１２ＣＩｌＯヒ
］Ｔ１１６５＋８ ３７ ４０
呑 料
２０洗浄成分 ５
（ポリオキシエチレンソルビタン
脂肪酸エステル）
着色剤 １０実施例２
つぎの成分を実施例１と同様に混合、固化して本発明の
水洗トイレット用芳香洗浄剤を作製した。(Ingredients) (Parts by weight) H3 C110÷C112C110±-→C112C11Ohi]T1165+8 37 40 Drinks
20 Cleaning ingredients 5
(Polyoxyethylene sorbitan fatty acid ester) Colorant 10 Example 2 The following components were mixed and solidified in the same manner as in Example 1 to prepare an aromatic cleaning agent for flush toilets of the present invention.
（成分） （重量部）
Ｈ３
ＣＩＩ Ｏ＋Ｃｌ１２ＣＩＩＯ→−（−Ｃ１１２Ｃ１
１０ヒ一丁１１６０谷 料
２０洗浄成分
５（ポリオキシエチレンソルビタン
脂肪酸エステル）
着色剤 ＩＯ中性無水芒
硝 ５実施例３
つぎの成分を実施例１と同様にして混合、固化して本発
明の水洗トイレット用芳容洗浄剤を作製した
（成分） （重量部）
Ｈ３
ＲＯ＋ Ｃ１１２Ｃ１１０→→Ｃ１１２ＣＩＩＯ−）
５００ ＩＩ ６５（ただし、ＲＯはラノリンアルコ
ールの残基）香 料
２０洗浄成分
５（ポリオキシエチレンソルビタン
脂肪酸エステル）
青色剤 ｌＯ比較例１
実施例１において、主基剤としてポリエチレングリコー
ルｔａｏｏｏを用いたほかは実施例１と同様にして比較
用の水先トイレット用芳香洗浄剤を作製した。(Component) (Parts by weight) H3 CII O+Cl12CIIO→-(-C112C1
10 Hi 1 Chou 1160 Valley Fee
20 cleaning ingredients
5 (polyoxyethylene sorbitan fatty acid ester) Colorant IO neutral anhydrous sodium sulfate 5 Example 3 The following components were mixed and solidified in the same manner as in Example 1 to prepare a fragrance cleanser for flush toilets of the present invention ( Ingredients) (Parts by weight) H3 RO+ C112C110→→C112CIIO-)
500 II 65 (RO is the residue of lanolin alcohol) Fragrance
20 cleaning ingredients
5 (Polyoxyethylene sorbitan fatty acid ester) Blue agent lO Comparative Example 1 A comparative aromatic cleaner for toilets was prepared in the same manner as in Example 1 except that polyethylene glycol taooo was used as the main base. did.
試験例１（流水試験）
第１図に示すように、頂部に入水開口部（１）を有し、
側部に４個の出水孔（２）を有する蓋（３）と直径４０
ｙｕｅで高さ７０曽−の円筒状本体（４）とからなる容
器に、実施例１〜３および比較例１の組成物（５）を各
々５０ｇずつ充填したのち冷却固化した。Test Example 1 (Flowing Water Test) As shown in Figure 1, it has a water entry opening (1) at the top,
Lid (3) with 4 drainage holes (2) on the side and diameter 40
A container consisting of a cylindrical body (4) with a height of 70 mm was filled with 50 g of each of the compositions (5) of Examples 1 to 3 and Comparative Example 1, and then cooled and solidified.
これらの容器を家庭用水洗トイレットのロータンク（貯
水量： Ｉｌｌ！ 、東南機器■製のＴＯＴＯＳ−６７
０）内に設置し、使用可能回数および便器内流水の゛１
也均吸光度（［１３０ｎ１１）を測定（■島原製作所製
の分光光度計ＵＶ−２０５１’Ｗ） した。なお、ロー
タンク内の水および注入水の温度は３０℃または５℃に
維持し、それぞれ１時間に１回自動的にフラッシュ（流
水）するように設定した。使用可能回数とは、上記条件
下に便器内流水の平均吸光度がゼロになるまでの回数を
いう。These containers are used in the low tank of a household flush toilet (water storage capacity: Ill!, TOTOS-67 manufactured by Tonan Kiki ■).
0) installed in the toilet, the number of times it can be used and the amount of water flowing in the toilet bowl.
The average absorbance ([130n11) was measured (spectrophotometer UV-2051'W manufactured by Shimabara Seisakusho). The temperature of the water in the low tank and the injected water was maintained at 30°C or 5°C, and each was set to be flushed automatically once every hour. The number of usable times refers to the number of times the toilet bowl can be used until the average absorbance of the water flowing in the toilet becomes zero under the above conditions.
結果を第１表に示す。The results are shown in Table 1.
［以下余白］
第１表から明らかなように、本発明の組成物を用いると
きは、高温低温のいずれのばあいにも持続性に勝ってお
り、特に高い水温（３０℃）のばあいにおいて優れてい
る。[Left below] As is clear from Table 1, when the composition of the present invention is used, it has excellent durability under both high and low temperatures, and is particularly effective at high water temperatures (30°C). Are better.
試験例２（温度依存性試験）
本発明の芳香洗浄剤組成物の主基剤として用いる前記化
合物（１）の水への溶解性が水温に依存しにくいことを
示すべく、つぎの試験を行なった。Test Example 2 (Temperature Dependency Test) In order to demonstrate that the solubility of the compound (1) in water used as the main base of the aromatic cleaning composition of the present invention does not easily depend on water temperature, the following test was conducted. Ta.
実施例３で使用した化合物（１）の２２重量２６水溶液
およびポリエチレングリコール２００００の１．８ｆｆ
ｉ量％水溶液をそれぞれ１０℃にて調製し、そのときの
粘度をブルックフィールド型回転粘度計によりｉｌｌ定
した。ついで各水溶液の温度を徐々に上げ、２０℃およ
び３０℃における各粘度を８１’）定し、粘度の温度依
存性を調べた。結果を第２図に示す。22 weight 26 aqueous solution of compound (1) used in Example 3 and 1.8ff of polyethylene glycol 20000
I amount % aqueous solutions were each prepared at 10° C., and the viscosity at that time was determined using a Brookfield rotational viscometer. Next, the temperature of each aqueous solution was gradually raised, and the viscosity at 20°C and 30°C was determined (81') to examine the temperature dependence of the viscosity. The results are shown in Figure 2.
第２図から明らかなように、本発明で用いる前記化合物
（１）の本溶液の粘度は温度依存性が小さく、特に高温
領域ではポリエチレングリコ−ル水溶液の粘度が大きく
低下するにもかかわらず、高い粘度を維持している。As is clear from FIG. 2, the viscosity of the solution of the compound (1) used in the present invention has little temperature dependence, and even though the viscosity of the polyethylene glycol aqueous solution decreases significantly especially in the high temperature range, Maintains high viscosity.
このように粘度が一定であれば溶質の水への拡散も一定
となり、その結果、本発明では高温においても溶解性が
それほど変化しない。このことは試験例１の結果と一致
する。他方、ポリエチレングリコールのように高温時に
低粘度となるものでは溶解度が高くなり、持続性に劣る
。As described above, if the viscosity is constant, the diffusion of the solute into water is also constant, and as a result, in the present invention, the solubility does not change much even at high temperatures. This agrees with the results of Test Example 1. On the other hand, substances such as polyethylene glycol which have a low viscosity at high temperatures have high solubility and are poor in durability.
［発明の効用］
本発明の水洗トイレット用芳香洗浄剤組成物によるとき
は、
（１）ポリエチレングリコールタイプのものを主基剤と
する芳容洗浄剤組成物に比して、水への溶解速度が適度
に遅く適切な持続性を有する、（′２Ｊ試験例１〜２か
ら明らかなごとく、本発明の組成物の水への溶解性は水
温に左右されず、したがって夏期、冬期の水温の変化に
よっても溶解速度がそれほど変化せず、年間を通して安
定な持続性が期待できる、
（３）本発明に主基剤として用いる前記化合物（Ｉ）は
、ポリエチレングリコールタイプのものとは異なり親水
性基に加えて疎水性基を６しているので、ポリエチレン
グリコールタイプのものに比してそれ１１体大きな洗浄
力を有している、などの効果を奏する。[Effects of the Invention] When using the aromatic cleaning composition for flush toilets of the present invention, (1) the dissolution rate in water is faster than that of aromatic cleaning compositions whose main base is polyethylene glycol type; (As is clear from '2J Test Examples 1 and 2, the solubility of the composition of the present invention in water is not affected by the water temperature, and therefore the water temperature does not change between summer and winter.) (3) Unlike polyethylene glycol type compounds, the compound (I) used as the main base material in the present invention has a hydrophilic group. In addition, since it has 6 hydrophobic groups, it has 11 times more cleaning power than polyethylene glycol type products.
第１図は試験例１で用いた水洗トイレット用芳香洗浄剤
充填用の容器のＩｔ！！略斜視図、第２図は本発明に用
いる主基剤水溶液とポリエチレングリコール水溶液の粘
度の温度依存性を示すグラフである。Figure 1 shows the It! ! The schematic perspective view and FIG. 2 are graphs showing the temperature dependence of the viscosity of the main base aqueous solution and the polyethylene glycol aqueous solution used in the present invention.
Claims (1)
いはＲＯがラノリンアルコール残基、ｍは１０以上の整
数、ｎは１００以上の整数、▲数式、化学式、表等があ
ります▼とはそ れぞれブロック重合ユニットである）で示される化合物
を配合剤として用いることを特徴とする水洗トイレット
用芳香洗浄剤組成物。[Claims] 1 General formula (I): ▲Mathematical formulas, chemical formulas, tables, etc.▼(I) (In the formula, R is an alkyl group or alkylaryl group, or RO is a lanolin alcohol residue, m is 10 or more , n is an integer of 100 or more, and ▲ has a mathematical formula, chemical formula, table, etc. ▼ is a block polymerization unit, respectively) is used as a compounding agent. thing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26748987A JPH07119439B2 (en) | 1987-10-22 | 1987-10-22 | Fragrance cleaner composition for flush toilet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26748987A JPH07119439B2 (en) | 1987-10-22 | 1987-10-22 | Fragrance cleaner composition for flush toilet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01110599A true JPH01110599A (en) | 1989-04-27 |
| JPH07119439B2 JPH07119439B2 (en) | 1995-12-20 |
Family
ID=17445560
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP26748987A Expired - Lifetime JPH07119439B2 (en) | 1987-10-22 | 1987-10-22 | Fragrance cleaner composition for flush toilet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07119439B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010155939A (en) * | 2008-12-29 | 2010-07-15 | Sanyo Chem Ind Ltd | Slow solubilizing agent and detergent for flush toilet |
| JP6141501B1 (en) * | 2016-09-02 | 2017-06-07 | 第一工業製薬株式会社 | Gel composition |
| JP2021008535A (en) * | 2019-06-28 | 2021-01-28 | 小林製薬株式会社 | Coating agent for toilet bowls |
-
1987
- 1987-10-22 JP JP26748987A patent/JPH07119439B2/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010155939A (en) * | 2008-12-29 | 2010-07-15 | Sanyo Chem Ind Ltd | Slow solubilizing agent and detergent for flush toilet |
| JP6141501B1 (en) * | 2016-09-02 | 2017-06-07 | 第一工業製薬株式会社 | Gel composition |
| JP2018035322A (en) * | 2016-09-02 | 2018-03-08 | 第一工業製薬株式会社 | Gel composition |
| JP2021008535A (en) * | 2019-06-28 | 2021-01-28 | 小林製薬株式会社 | Coating agent for toilet bowls |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH07119439B2 (en) | 1995-12-20 |
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