JPH01104144A - Treatment of fiber substance obtained by treating natural husk and high fiber substance obtained by treatment thereof - Google Patents

Treatment of fiber substance obtained by treating natural husk and high fiber substance obtained by treatment thereof

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Publication number
JPH01104144A
JPH01104144A JP62261891A JP26189187A JPH01104144A JP H01104144 A JPH01104144 A JP H01104144A JP 62261891 A JP62261891 A JP 62261891A JP 26189187 A JP26189187 A JP 26189187A JP H01104144 A JPH01104144 A JP H01104144A
Authority
JP
Japan
Prior art keywords
fibrous material
solution
treatment
sodium hypochlorite
lignin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62261891A
Other languages
Japanese (ja)
Other versions
JP2535182B2 (en
Inventor
Takeko Suda
武子 須田
Yukio Murakami
村上 行雄
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Individual
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP62261891A priority Critical patent/JP2535182B2/en
Publication of JPH01104144A publication Critical patent/JPH01104144A/en
Application granted granted Critical
Publication of JP2535182B2 publication Critical patent/JP2535182B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • General Preparation And Processing Of Foods (AREA)

Abstract

PURPOSE:To obtain a high fiber substance extremely softened, by treating a fibrous substance obtained by treating natural husks, reacting the prepared substance with a chlorine-based bleaching agent to remove remaining lignin and expanding cellulose. CONSTITUTION:Natural husks are treated with a mixed solution of caustic soda and sodium hypochlorite to give a fibrous substance, which is immersed in a chlorine-based bleaching agent such as about 4.2% solution of sodium hypochlorite at about 36 deg.C for about 25min and then the chlorine-based bleaching agent is washed away. Optionally the prepared high fiber substance is further immersed in an oxygen-based bleaching agent such as solution of sodium percarbonate, more extremely softened and the oxygen-based bleaching agent is washed away.

Description

【発明の詳細な説明】 (イ)産業上の利用分野 本発明は、昭和61年特許11g276453号の処理
方法で天然のモミを処理して得られた繊維性物質の処理
方法、及びその処理により得られる高繊維物質に係り、
特に前記繊維性物質を塩素系漂白剤、例えば次亜塩素酸
ソーダー溶液、又はこれと酸素系漂白剤、例えば過炭酸
ソーダー溶液を併用処理することにより、極めて効率よ
く前記繊維性物質を更に一段と軟質化した高繊維物質に
変えることができる処理方法、及び該高繊維物質に関す
る。
Detailed Description of the Invention (a) Industrial Application Field The present invention relates to a method for treating a fibrous material obtained by treating natural fir using the treatment method disclosed in Patent No. 11g276453 of 1988, and a method for treating a fibrous material obtained by the treatment. Regarding the high fiber material obtained,
In particular, by treating the fibrous material with a chlorine bleach, such as a sodium hypochlorite solution, or a combination of this with an oxygen bleach, such as a sodium percarbonate solution, the fibrous material can be made even softer with great efficiency. The present invention relates to a processing method capable of converting the high-fiber material into a high-fiber material, and to the high-fiber material.

(ロ) 従来の技術 昭和61年特許願第276453号の処理方法で天然の
モミを処理する段階で、苛性ソーダーと次亜塩素酸ソー
ダーの混合溶液で処理する際に、混合溶液中の次亜塩素
酸ソーダー溶液の濃度を少くとも496、混合溶液中の
苛性ソーダー溶液の濃度を少くと6396にして処理す
ると、該高繊維物質に相似の物質を得ることができる。
(b) Conventional technology When treating natural fir with a mixed solution of caustic soda and sodium hypochlorite in the treatment method of Patent Application No. 276453 filed in 1986, hypochlorite in the mixed solution When treated with a sodium chlorate solution having a concentration of at least 496 and a caustic soda solution in the mixed solution having a concentration of at least 6396, a material similar to the high fiber material can be obtained.

この物質は、食品補材としての勝れた実用性を持ってい
る。
This substance has excellent utility as a food supplement.

しかし、処理液を洗滌除去する段階で、苛性ソーダーが
除去しにくいために強力な洗滌を必要とする。このため
に、得られた物質の60%前後が微粉状となって、洗庭
水と共に流出して失われてしまう欠点があった。
However, at the stage of washing and removing the processing solution, strong washing is required because caustic soda is difficult to remove. For this reason, there was a drawback that about 60% of the obtained substance became fine powder and was washed away with the cleaning water and lost.

(ハ) 目的 本発明は、前記した従来技術の欠点を除くためになされ
たもので、その目的とするところは、昭和61年特許1
lii第276453号の処理方法で天然のモミを処理
して得られた繊維性物質を、塩素系漂白剤、例えば次亜
塩素酸ソーダー溶液、又はこれと酸素系漂白剤、例えば
過炭酸ソーダー溶液を併用して処理することで、この処
理液を洗滌除去することが容易であるために、得られる
高繊維物質の洗滌段階での流出によって失われる量は、
前記従来技術に比較して非常に少く、微かに596前後
である。従ってランニングコストを低くすることが可能
であるとともに、良質の高繊維物質を効率良く得ること
ができることにある。
(C) Purpose The present invention was made to eliminate the drawbacks of the prior art described above, and its purpose is to
The fibrous material obtained by treating natural fir using the treatment method of No. 276453 is treated with a chlorine bleach, such as a sodium hypochlorite solution, or with an oxygen bleach, such as a sodium percarbonate solution. By using the combined treatment, it is easy to wash and remove this processing solution, so the amount of the resulting high-fiber material lost through outflow during the washing step is
The number is very small compared to the conventional technology, and is slightly around 596. Therefore, it is possible to reduce running costs and to efficiently obtain high-quality, high-fiber materials.

この高繊維物質は、ケーキ、クツキー、麺類など、広範
の繊維食品用食品補材として勝れた実用性を持っている
This high fiber material has excellent utility as a food supplement for a wide range of fiber foods such as cakes, kutskies, noodles, etc.

に)構成 まず第1発明の方法について説明すると、昭和61年特
許願第276453号の処理方法で天然のモミを処理し
て得られた繊維性物質、この繊維性物質は、少くとも天
然のモミの形状をとどめる程度に処理した繊維性物質を
、塩素系漂白剤、例えば次亜塩素酸ソーダー溶液中に浸
漬すると、繊維性物質中の残存リグニンは、水やアルカ
リに可溶の塩化リグニンとして徐々に溶解除去される、
とともに繊維性物質中のセルロースは膨潤されて一段と
柔軟性を増し、第3iA明の高繊維物質が得られる。
2) Structure First of all, to explain the method of the first invention, a fibrous material obtained by treating natural fir using the treatment method of Patent Application No. 276453 of 1988. When a fibrous material that has been treated to the extent that it retains its shape is immersed in a chlorine bleach solution, such as a sodium hypochlorite solution, the remaining lignin in the fibrous material gradually becomes chlorinated lignin that is soluble in water and alkali. removed by dissolution,
At the same time, the cellulose in the fibrous material is swollen and becomes more flexible, resulting in a highly fibrous material of 3 iA light.

第工発明の方法を一例を引いて説明すると、天然のモミ
の形状をとどめる程度に処理した繊維性物II(処理段
階の一例を示すと、混合処理液中の濃度として苛性ソー
ダー1.04 %、次亜塩素酸ンーグーα7596、液
温42℃の混合処理液中に天然のモミを浸漬して約20
分間断続撹拌した後、処理液を洗滌除去して得られる。
To explain the method of the invention of the first step with reference to an example, the fibrous material II is treated to maintain the shape of natural fir (an example of the treatment step is that the concentration of caustic soda in the mixed treatment liquid is 1.04%). , hypochlorous acid Ngu α7596, mixed treatment solution with a liquid temperature of 42℃, soaking natural fir for about 20 minutes.
After stirring intermittently for a minute, the treatment solution is washed away.

)を、塩素系漂白剤として次亜塩素酸ソ、−ダーを用い
た場合、液温36℃の次亜塩素酸ソーダー4.296溶
液中に繊維性物質を25分間浸−すると、繊維性物質中
の残存リグニンの少くとも一部は、水やアルカリに可溶
の塩化リグニンとして溶解除去され、繊維性物質中のセ
ルロースは膨潤されて一段と柔軟性を増して、第3発明
の高繊維物質に変る。
), when sodium hypochlorite is used as a chlorine bleach, when a fibrous material is immersed in a 4.296 solution of sodium hypochlorite at a temperature of 36°C for 25 minutes, the fibrous material At least a part of the residual lignin in the material is dissolved and removed as chlorinated lignin that is soluble in water or alkali, and the cellulose in the fibrous material is swollen and becomes more flexible, resulting in the high fibrous material of the third invention. Change.

これを処理液から取り出して、洗滌し次亜塩素酸ソーダ
ーを除去して乾燥すれば、高繊維物質が得られる。該高
繊維物質をミキサーにかけて、粉状とすれば、食物繊維
として広範な食品補材に用いることができる。
If this is taken out from the treatment solution, washed to remove the sodium hypochlorite, and dried, a high fiber material can be obtained. If the high-fiber substance is blended and made into powder, it can be used as dietary fiber in a wide variety of food supplements.

クツキー、ケーキ、パン、ビスケット等の食品補材とし
て最適である。
Ideal as a food supplement for kutsky, cakes, bread, biscuits, etc.

こうして得た高繊維物質は無味無臭で、食用として口当
りが滑かで、在来の食物繊維独得のざらつきを感するこ
とはほとんど無く実用性の高いことを特徴とするもので
ある。
The high-fiber substance obtained in this way is tasteless and odorless, has a smooth texture for edible use, has almost no roughness unique to conventional dietary fibers, and is highly practical.

ついで、第2発明の方法について説明すると、第1発明
の方法で得られた高繊維物質を、乾燥処理の前の段階で
酸素系漂白剤、−例として過炭酸ソーダーを用いた場合
、過炭酸ソーダーの例えば3%溶液中に10分間浸漬す
ると、該高繊維物質中のセルロースは更に膨潤され、第
4発明の高繊維物質に変る。これを処理液から取り出し
て、洗滌し過炭酸ソーダーを除去して乾燥すれば、高繊
維物質が得られる。該高繊維物質をミキサーにかけて、
粉状とすれば、食物繊維として広範な食品補材に用いる
ことができる。
Next, the method of the second invention will be explained. When the high fiber material obtained by the method of the first invention is treated with an oxygen bleach, for example, soda percarbonate, in a step before drying, When immersed in, for example, a 3% solution of soda for 10 minutes, the cellulose in the high fiber material is further swollen and transformed into the high fiber material of the fourth invention. If this is removed from the treatment solution, washed to remove the sodium percarbonate, and dried, a high fiber material is obtained. applying the high fiber material to a mixer;
If it is in powder form, it can be used as dietary fiber in a wide range of food supplements.

ラドン、ソバ等麺類の食品補材として最適である。Radon is ideal as a food supplement for noodles such as buckwheat.

こうして得た高繊維物質は無味無臭で、食用として口当
りが滑かで、在来の食物繊維独得のざらつきを感するこ
とはほとんど無く実用性の高いことを特徴とするもので
ある。
The high-fiber substance obtained in this way is tasteless and odorless, has a smooth texture for edible use, has almost no roughness unique to conventional dietary fibers, and is highly practical.

(ホ) 効果 セルロース、ヘミセルロース、リクニンヲ総称して食物
繊維という。
(E) Effect: Cellulose, hemicellulose, and licorice are collectively called dietary fiber.

食物繊維を品質的に評価すると、リグニンの含有量が少
いほど良質とされている。
When evaluating the quality of dietary fiber, it is said that the lower the lignin content, the better the quality.

そうした意味においても本発明は、昭和61年特許wi
第276453号の処理の方法で得られたuam性物質
物質然のモミに含まれるケイ酸の少くとも一部は、水や
アルカリに可溶のケイ酸ソーダーとして既に除去されて
いるので、消化上に問題はない。)中の残存リグニンの
少くとも一部を塩素系漂白剤、例えば次亜塩素酸ソーダ
ー溶液で水やアルカリに可溶の塩化リグニンとして溶解
除去するので、リグニンの含有量を減らすことができる
、とともにセルロースを膨潤して柔軟性を増すので、本
発明によって得られた高繊維物質は一段と良質の食物繊
維である。
In this sense as well, the present invention is based on the 1986 patent wi
At least a part of the silicic acid contained in the UAM material obtained by the treatment method of No. 276453 has already been removed as sodium silicate, which is soluble in water and alkali. There is no problem. ) at least a part of the residual lignin in the chlorine-based bleach, such as a sodium hypochlorite solution, is dissolved and removed as chlorinated lignin that is soluble in water and alkali, thereby reducing the lignin content. The high fiber material obtained by the present invention is a better quality dietary fiber since it swells the cellulose and increases its flexibility.

現代の食生活において、食物繊維の摂取量の不足は、つ
とに指摘されているところだが、本発明によって得られ
た高繊維物質は、無味無臭の上に口当りも滑かで、非常
に実用性の高い繊維食品用食品補材として広範に用いる
ことができるという効果がある。
It is often pointed out that there is a lack of dietary fiber intake in modern diets, but the high-fiber substance obtained by the present invention is tasteless and odorless and has a smooth texture, making it extremely practical. It has the effect that it can be widely used as a food supplement for high-fiber foods.

Claims (1)

【特許請求の範囲】 1 昭和61年特許願第276453号の処理方法で天
然のモミを処理して得られた繊維性物質を、塩素系漂白
剤、例えば次亜塩素酸ソーダー溶液に浸漬して、前記繊
維性物質中の残存リグニンの少くとも一部を、水やアル
カリに可溶の塩化リグニンとして溶解除去するとともに
、前記繊維性物質を更に一段と軟質化することを特徴と
する前記繊維性物質の処理方法。 2 昭和61年特許願第276453号の処理方法で天
然のモミを処理して得られた繊維性物質を、塩素系漂白
剤、例えば次亜塩素酸ソーダー溶液と、酸素系漂白剤、
例えば過炭酸ソーダー溶液を併用して浸漬し、前記繊維
性物質中の残存リグニンの少くとも一部を、水やアルカ
リに可溶の塩化リグニンとして溶解除去するとともに、
前記繊維性物質を効果的に更に一段と軟質化することを
特徴とする前記繊維性物質の処理方法。 3 昭和61年特許願第276453号の処理方法で天
然のモミを処理して得られた繊維性物質を、塩素系漂白
剤、例えば次亜塩素酸ソーダー溶液に浸漬して、前記繊
維性物質中の残存リグニンの少くとも一部を、水やアル
カリに可溶の塩化リグニンとして溶解除去するとともに
、更に前記繊維性物質を一段と軟質化し、前記塩素系漂
白剤、例えば次亜塩素酸ソーダーを洗滌除去して得られ
る高繊維物質。 4 昭和61年特許願第276453号の処理方法で天
然のモミを処理して得られた繊維性物質を、塩素系漂白
剤、例えば次亜塩素酸ソーダー溶液に浸漬して、前記繊
維性物質中の残存リグニンの少くとも一部を、水やアル
カリに可溶の塩化リグニンとして溶解除去するとともに
、更に前記繊維性物質を一段と軟質化し、前記塩素系漂
白剤、例えば次亜塩素酸ソーダーを洗滌除去して得られ
た高繊維物質を、酸素系漂白剤、例えば過炭酸ソーダー
溶液に浸漬して更に一段と効果的に前記高繊維物質を軟
質化し、酸素系漂白剤、例えば過炭酸ソーダーを洗滌除
去して得られる高繊維物質。
[Scope of Claims] 1. A fibrous material obtained by treating natural fir using the treatment method of Patent Application No. 276453 of 1985 is soaked in a chlorine bleach, for example, a sodium hypochlorite solution. The fibrous material is characterized in that at least a part of the residual lignin in the fibrous material is dissolved and removed as chlorinated lignin soluble in water or alkali, and the fibrous material is further softened. processing method. 2. The fibrous material obtained by treating natural fir using the treatment method of Patent Application No. 276453 of 1986 is treated with a chlorine bleach, such as a sodium hypochlorite solution, an oxygen bleach,
For example, by immersion in combination with a sodium percarbonate solution, at least a portion of the remaining lignin in the fibrous material is dissolved and removed as chlorinated lignin that is soluble in water or alkali, and
A method for treating a fibrous material, characterized in that the fibrous material is effectively further softened. 3. A fibrous material obtained by treating natural fir using the treatment method of Patent Application No. 276453 of 1986 is soaked in a chlorine bleach, for example, a sodium hypochlorite solution, to remove the fibrous material from the fibrous material. At least a part of the remaining lignin is dissolved and removed as chlorinated lignin soluble in water or alkali, and the fibrous material is further softened, and the chlorine bleach, such as sodium hypochlorite, is washed away. High fiber material obtained by 4 A fibrous material obtained by treating natural fir using the treatment method of Patent Application No. 276453 of 1986 is immersed in a chlorine bleach, for example, a sodium hypochlorite solution, to remove the fibrous material from the fibrous material. At least a part of the remaining lignin is dissolved and removed as chlorinated lignin soluble in water or alkali, and the fibrous material is further softened, and the chlorine bleach, such as sodium hypochlorite, is washed away. The high fiber material obtained is immersed in an oxygen bleach, such as a sodium percarbonate solution, to further soften the high fiber material even more effectively, and the oxygen bleach, such as sodium percarbonate, is washed away. High fiber material obtained by
JP62261891A 1987-10-19 1987-10-19 Method for treating fibrous substance obtained by treating natural fir, and high fibrous substance obtained by the treatment Expired - Lifetime JP2535182B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62261891A JP2535182B2 (en) 1987-10-19 1987-10-19 Method for treating fibrous substance obtained by treating natural fir, and high fibrous substance obtained by the treatment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62261891A JP2535182B2 (en) 1987-10-19 1987-10-19 Method for treating fibrous substance obtained by treating natural fir, and high fibrous substance obtained by the treatment

Publications (2)

Publication Number Publication Date
JPH01104144A true JPH01104144A (en) 1989-04-21
JP2535182B2 JP2535182B2 (en) 1996-09-18

Family

ID=17368202

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP2535182B2 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991011919A1 (en) * 1990-02-07 1991-08-22 Fuji Oil Company, Limited Process for producing water-soluble vegetable fiber, and biodegradable film, sizing agent, chewing gum and low-calorie food obtained from said fiber
GB2256570A (en) * 1990-02-07 1992-12-16 Fuji Oil Co Ltd Food, chewing gum and film products from vegetable fibres
US5342641A (en) * 1991-07-02 1994-08-30 Fuji Oil Co., Ltd. Food additive comprising water-soluble hemicellulose
US5710270A (en) * 1992-03-23 1998-01-20 Fuji Oil Co., Ltd. Water-soluble polysaccharide and a process for producing the same
US6004616A (en) * 1990-02-07 1999-12-21 Fuji Oil Company, Ltd. Biodegradable vegetable film

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991011919A1 (en) * 1990-02-07 1991-08-22 Fuji Oil Company, Limited Process for producing water-soluble vegetable fiber, and biodegradable film, sizing agent, chewing gum and low-calorie food obtained from said fiber
GB2256570A (en) * 1990-02-07 1992-12-16 Fuji Oil Co Ltd Food, chewing gum and film products from vegetable fibres
GB2256570B (en) * 1990-02-07 1994-05-04 Fuji Oil Co Ltd Process for production of water-soluble vegetable fibers, biodegradable film, paste, chewing gum and low calorie food products
US6004616A (en) * 1990-02-07 1999-12-21 Fuji Oil Company, Ltd. Biodegradable vegetable film
US6280526B1 (en) 1990-02-07 2001-08-28 Fuji Oil Company, Limited Process for production of water-soluble vegetable fibers, biodegradable film, paste, chewing gum and low calorie food products
US5342641A (en) * 1991-07-02 1994-08-30 Fuji Oil Co., Ltd. Food additive comprising water-soluble hemicellulose
US5710270A (en) * 1992-03-23 1998-01-20 Fuji Oil Co., Ltd. Water-soluble polysaccharide and a process for producing the same

Also Published As

Publication number Publication date
JP2535182B2 (en) 1996-09-18

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