JPH01102505A - Optical parts - Google Patents
Optical partsInfo
- Publication number
- JPH01102505A JPH01102505A JP62261130A JP26113087A JPH01102505A JP H01102505 A JPH01102505 A JP H01102505A JP 62261130 A JP62261130 A JP 62261130A JP 26113087 A JP26113087 A JP 26113087A JP H01102505 A JPH01102505 A JP H01102505A
- Authority
- JP
- Japan
- Prior art keywords
- optical
- optical component
- polycarbonate resin
- bis
- hydroxyphenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000003287 optical effect Effects 0.000 title claims abstract description 42
- 229920005668 polycarbonate resin Polymers 0.000 claims abstract description 15
- 239000004431 polycarbonate resin Substances 0.000 claims abstract description 15
- 238000000859 sublimation Methods 0.000 claims abstract description 11
- 230000008022 sublimation Effects 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 7
- 238000002834 transmittance Methods 0.000 claims abstract description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 5
- 230000000977 initiatory effect Effects 0.000 claims abstract description 3
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- ZPSZXWVBMOMXED-UHFFFAOYSA-N 2-(2-bromo-5-chlorophenyl)acetic acid Chemical compound OC(=O)CC1=CC(Cl)=CC=C1Br ZPSZXWVBMOMXED-UHFFFAOYSA-N 0.000 claims description 2
- 239000013307 optical fiber Substances 0.000 claims description 2
- 239000002344 surface layer Substances 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 abstract description 7
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 229920001577 copolymer Polymers 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract description 2
- 239000000975 dye Substances 0.000 description 19
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 14
- 239000001294 propane Substances 0.000 description 7
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- -1 carbonate ester Chemical class 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 3
- 229910003460 diamond Inorganic materials 0.000 description 3
- 239000010432 diamond Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- MPVDXIMFBOLMNW-ISLYRVAYSA-N 7-hydroxy-8-[(E)-phenyldiazenyl]naphthalene-1,3-disulfonic acid Chemical compound OC1=CC=C2C=C(S(O)(=O)=O)C=C(S(O)(=O)=O)C2=C1\N=N\C1=CC=CC=C1 MPVDXIMFBOLMNW-ISLYRVAYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 125000005027 hydroxyaryl group Chemical group 0.000 description 1
- 230000010365 information processing Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
Landscapes
- Optical Filters (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Coloring (AREA)
- Optical Record Carriers And Manufacture Thereof (AREA)
- Optical Head (AREA)
Abstract
Description
【発明の詳細な説明】
□〔産業上の利用分野〕
本発明は光学用部品に関する。詳しくは光学用途に用い
られる基板、レンズ、光７アイパー等として用いて好適
な光学用部品に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to optical components. Specifically, the present invention relates to optical components suitable for use as substrates, lenses, optical 7-eyepers, etc. used in optical applications.
ポリカーボネート樹脂は、優れた機械的特性を有するた
め、広範な分野て利用されている。Polycarbonate resins have excellent mechanical properties and are therefore used in a wide range of fields.
近年では殊に、透明かつ耐熱性の高いことから、光学的
用途への展開が急速に進んでいる。具体的な例としては
、
０コンパクトデイスクや光ディスクを代表とする光学的
読取装置の情報記憶媒体の基盤０コンパクトデイスクの
ピックアップレンズや、光学的制御装置の集光レンズ
０光フアイバー
などが挙げられる。In recent years, its use in optical applications has been rapidly progressing, especially because of its transparency and high heat resistance. Specific examples include pickup lenses for compact discs, which are the base of information storage media for optical reading devices, typically typified by compact discs and optical discs, and optical fibers, condensing lenses for optical control devices.
ポリカーボネート樹脂による光学用部品は、広範な分野
で利用されておシ、その多くは各種の着色剤によりて着
色して使用される。 “透光性を持つ着色した部品を
得るためには、各種の染料を配合することが知られてい
るが、ポリカーボネート樹脂の加工温度である２６０℃
以上の耐熱性を要求される場合、染料の分解や昇華ある
いは分散不足といった現象を生じ、光学的特性が著しく
低下する。Optical parts made of polycarbonate resin are used in a wide range of fields, and most of them are colored with various colorants. “In order to obtain colored parts with translucency, it is known that various dyes are blended, but at 260°C, which is the processing temperature of polycarbonate resin.
When higher heat resistance is required, phenomena such as decomposition, sublimation, or insufficient dispersion of the dye occur, resulting in a significant deterioration of optical properties.
したがって、光学部品においては、光学的特性を損なう
ことなく着色可能な製品は得られていない。Therefore, in optical parts, products that can be colored without impairing optical properties have not been obtained.
本発明者らは、特定の条件を満足する染料を選定するこ
とによシ、光学的特性を損なうことなく着色が可能な光
学部品を得られることを見出し、本発明に到達した。The present inventors have discovered that by selecting a dye that satisfies specific conditions, it is possible to obtain an optical component that can be colored without impairing optical properties, and have arrived at the present invention.
すなわち、本発明は、着色が可能で、かつ光学的特性に
優れた光学用部品を得ることを目的としたものである。That is, an object of the present invention is to obtain an optical component that can be colored and has excellent optical properties.
以下、本発明を具体的に説明する。 The present invention will be explained in detail below.
本発明ハ、ビス（ヒドロキシフェニル）アルカン系ポリ
カーボネート樹脂に、
ｆ（） 融点が２５０℃以下
（ロ）昇華開始温度が２３０℃以上
ｅ）溶剤にとかした状態での７００ｍｍ−１０００ｎｍ
の波長を持つ光の透過率が９０％以上という特性を満足
する染料を／ −／ ０００ ｐｐｍ添加した素材から
なる光学用部品に存する。The present invention c) bis(hydroxyphenyl)alkane-based polycarbonate resin f() has a melting point of 250°C or lower (b) has a sublimation initiation temperature of 230°C or higher e) 700 mm to 1000 nm when dissolved in a solvent
The present invention relates to an optical component made of a material to which / -/ 000 ppm of a dye is added which satisfies the characteristic that the transmittance of light having a wavelength of 90% or more is achieved.
ここにポリカーボネート樹脂は、種々のジヒドロキシジ
アリール化合物とホスゲンとを反応させるホスゲン法、
またはジヒドロキシジアリール化合物とジフェニルカー
ボネートなどの炭酸エステルとを反応させるエステル交
換法によって得られる重合体または共重合体であり、代
表的なものとしては、ａ、２−ビス（ターヒドロキシフ
ェニル）プロパン（ビスフェノールＡ）から製造された
ポリカーボネート樹脂があげられる。Here, the polycarbonate resin is produced using a phosgene method in which various dihydroxydiaryl compounds and phosgene are reacted,
Alternatively, it is a polymer or copolymer obtained by a transesterification method in which a dihydroxydiaryl compound and a carbonate ester such as diphenyl carbonate are reacted.A typical example is a,2-bis(terhydroxyphenyl)propane (bisphenol). Examples include polycarbonate resins produced from A).
上記ジヒドロキシジアリール化合物としては、ビスフェ
ノールＡの他、ビス（ターヒドロキシフェニル）メタン
、／、１〜ビス（＜＝−ヒドロキシフェニル）エタン、
２．２−ビス（ターヒドロキシフェニル）ブタン、コ、
−一ビス（ターヒドロキシフェニル）オクタン、ビス（
４Ｉ−ヒドロキシフェニル）フェニルメタン、２．コー
ビス（ターヒドロキシ−３−メチルフェニル）プロパン
、／、１〜ビス（ＩＩ−ヒドロキシ−３−第３゜ブチル
フェニル）プロパン、コツ２−ビス（リーヒトロキシー
３−ブロモフェニル）フロパン、コ、１２−ビス（ター
ヒドロキシ−３，タジ゛ブロモフェニル）プロパン、コ
、コービス（ｌＩ−ヒドロキシ−３，タジクロロフェニ
ル）プロパンのよウナビス（ヒドロキシアリール）アル
カン［、／ｌ１〜ビス（４！−ヒドロキシフェニル）シ
クロペンタン、ｌ、ｌ−ビス（ターヒドロキシフェニル
）シクロヘキサンのようなビス（ヒドロキシアリール）
シクロアルカン［，４’ Ｈ４”−ジヒドロキシジフェ
ニルエーテル、ｕ、＜＜’−ジヒドロキシー３．３′−
ジメチルジフェニルエーテル、のようなジヒドロキシジ
アリールエーテル類、＜＜、ｕ’−ジヒドロキシジフェ
ニルスルフィド、ｇ、ｕ’−ジヒドロキシ−３，３′−
ジメチルジフェニルスルフィドのようなジヒドロキシジ
アリールスルフィド［、ａｐｅ’−ジヒドロキシジフェ
ニルスルホキシド、＜＜、＜ｔ’−ジヒドロキシ−３，
３′−ジメチルジフェニルスルホキシドのようなジヒド
ロキシジアリールスルホキシド類、す、ψ′−ジヒドロ
キシジフェニルスルホン、＃、ｌＩ’−ジヒドロキシー
３．３’−ジメチルジフェニルスルホンのようなジヒド
ロキシジアリールスルホン類等があげられる。In addition to bisphenol A, the dihydroxydiaryl compounds include bis(terhydroxyphenyl)methane, /, 1-bis(<=-hydroxyphenyl)ethane,
2.2-bis(terhydroxyphenyl)butane,
-monobis(terhydroxyphenyl)octane, bis(
4I-hydroxyphenyl)phenylmethane, 2. Corbis(terhydroxy-3-methylphenyl)propane, /, 1-bis(II-hydroxy-3-tert-butylphenyl)propane, 2-bis(terhydroxy-3-bromophenyl)propane, co, 12 -bis(hydroxyaryl)alkanes such as bis(terhydroxy-3,tadibromophenyl)propane, co-bis(lI-hydroxy-3,tadichlorophenyl)propane [,/l1~bis(4!-hydroxyphenyl)] Bis(hydroxyaryl) such as cyclopentane, l,l-bis(terhydroxyphenyl)cyclohexane
Cycloalkane[,4'H4''-dihydroxydiphenyl ether, u,<<'-dihydroxy-3.3'-
Dihydroxydiarylethers such as dimethyl diphenyl ether, <<, u'-dihydroxydiphenyl sulfide, g, u'-dihydroxy-3,3'-
Dihydroxydiaryl sulfide such as dimethyl diphenyl sulfide [, ape'-dihydroxydiphenyl sulfoxide, <<, <t'-dihydroxy-3,
Examples include dihydroxydiarylsulfoxides such as 3'-dimethyldiphenylsulfoxide, dihydroxydiarylsulfones such as ψ'-dihydroxydiphenylsulfone, #,lI'-dihydroxy-3,3'-dimethyldiphenylsulfone, and the like.
これらは単独でまたは一種以上混合して使用されるが、
これらの他にピペラジン、ジピペリジル、ハイドロキノ
ン、レゾルシン、り、ｑ′−ジヒドロキシジフェニル等
を混合して使用してもよい。These can be used alone or in combination, but
In addition to these, piperazine, dipiperidyl, hydroquinone, resorcinol, q'-dihydroxydiphenyl, etc. may be used in combination.
また、使用される着色剤については
（イ）融点が２ＳＯ℃以下
←）昇華開始温度が２３０℃以上
（ハ）クロロホルム１００−に０．０ ／ Ｉｔ溶解し
という特性を満足する染料を／ −７０００ｐｐｍ好ま
しくは５〜／ ００ ｐｐｍ配合される。In addition, the coloring agent to be used should be (a) having a melting point of 2SO℃ or lower←) a sublimation starting temperature of 230℃ or higher, and (c) a dye that satisfies the following properties: 0.0/It dissolves in chloroform 100-7000ppm/-7000ppm. Preferably, it is blended in an amount of 5 to 100 ppm.
と、こに、融点が２５Ｏ℃を越える場合、ポリカーボネ
ート樹脂を加工する際に染料が充分に溶融せず、部品中
に凝集して存在し、集光された細径の光線の透過を妨げ
る。また昇華開始温度は高い方が望ましく、ポリカーボ
ネート樹脂の加工時に、昇華しないためには、２３０℃
以上の昇華開始塩度が必要である。殊に、コンパクトデ
ィスクや光ディスクの基盤の様な情報記録基盤を射出成
形する場合には、光学的歪みを低減するために、３２０
〜３６０℃という高温で加工されるため、耐熱性の高い
染料であることが要求される。しかも基盤の表層に形成
される微細な情報記録用凹凸は、染料の昇華が多いと、
昇華した染料の金型への付着によって凹部が埋められ、
情報記録のエラーが増大する。In particular, if the melting point exceeds 250° C., the dye will not be sufficiently melted during processing of the polycarbonate resin, and will cohere in the parts, impeding the transmission of the focused small diameter light beam. In addition, it is desirable that the sublimation start temperature is high, and in order to prevent sublimation during processing of polycarbonate resin, a temperature of 230℃ is recommended.
It is necessary to have a salinity at the start of sublimation. In particular, when injection molding an information recording base such as a base for a compact disc or an optical disc, 320 mm is used to reduce optical distortion.
Since it is processed at a high temperature of ~360°C, it is required that the dye has high heat resistance. Moreover, the fine unevenness for recording information formed on the surface layer of the substrate is caused by a large amount of dye sublimation.
The recesses are filled by the adhesion of sublimated dye to the mold,
Increased errors in information recording.
尚、本発明において規定する昇華開始温度とは、示差熱
重量分析法において、昇温速度ｇ℃／分の条件で測定し
、重量曲線の減少開始温度で示している。The sublimation start temperature defined in the present invention is measured by differential thermogravimetry at a heating rate of g° C./min, and is indicated by the temperature at which the weight curve starts to decrease.
また、本発明の光学用部品は、光学的情報処理装置に常
用される７００−１０００ｎｍの波長を持つレーザー光
の透過率が高いことが要求され、そのためにはクロロホ
ルム１００−に料を使用する必要がある。Furthermore, the optical component of the present invention is required to have high transmittance for laser light having a wavelength of 700 to 1000 nm, which is commonly used in optical information processing devices, and for this purpose, it is necessary to use chloroform as a material. There is.
こうした条件を満足する染料としては、ペリノン系の染
料が望ましく、具体的な例として、カラーインデックス
としてソルベントオレンジ６０、ソルベントオレンジ６
７又はソルベントオレンジ７８の染料が挙げられる。As a dye that satisfies these conditions, perinone-based dyes are desirable, and specific examples include Solvent Orange 60 and Solvent Orange 6 as color indexes.
7 or Solvent Orange 78 dyes.
こうした染料は、スクリエー式混線機や加熱ロール並び
に、射出成形時に添加する等の、当該業者に周知の方法
にて、ポリカーボネート樹脂に配合される。Such dyes are incorporated into the polycarbonate resin by methods well known to those skilled in the art, such as by addition to a scrier mixer, heated rolls, or during injection molding.
本発明に規定される光学部品は、射出成形機や圧縮成形
機、押出成形機などの、樹脂成形加工機によって製造さ
れる。The optical component defined in the present invention is manufactured using a resin molding machine such as an injection molding machine, a compression molding machine, or an extrusion molding machine.
以下、本発明を具体的な例によって説明する。 The present invention will be explained below using specific examples.
尚、本発明は以下の実施例によりて限定されるものでは
ない。Note that the present invention is not limited to the following examples.
実施例１−タ
粘度平均分子量／９０００のコ、２−ビス（り−ヒドロ
キシフェニル）プロパンのポリカーボネートに、表−ｌ
に示す染料を配合し、ＵＯφベント押出機で２３０℃に
て練込み、ペレット化した。そのペレットを１２０℃で
乾燥後、射出成形機（各機製作所製 Ｍ−７ＯＯｐｌで
、ｌコ０■φのコンパクトディスクの成形を実施した。Example 1 A polycarbonate of 2-bis(ly-hydroxyphenyl)propane with a viscosity average molecular weight of 9000 was prepared using Table 1.
The dye shown in was blended and kneaded at 230° C. using a UOφ vent extruder and pelletized. After drying the pellets at 120° C., they were molded into compact discs with a diameter of 0 mm using an injection molding machine (M-7OOpl manufactured by Kagaki Seisakusho).
成形条件としては、樹脂温度、ｙｔｏ℃、金型温度ｔｚ
℃でありた。The molding conditions include resin temperature, yto℃, mold temperature tz
It was ℃.
比較例１〜３
比較例として、上記実施例における染料を除いペレット
、及び、表−／に示す染料を配合したペレットによシ同
様にコンパクトディスクを成形した。Comparative Examples 1 to 3 As Comparative Examples, compact discs were molded in the same manner as in the above examples except for the dyes, and pellets containing the dyes shown in Table 1-2.
得られたディスク基盤の特性の評価法は次の通シ、
（１） 光線透過率
走査型分光度計（Ｃ光源２°視野）を用い？ ！ Ｏｎ
ｍの波長域での全光線透過率を測定した。The characteristics of the obtained disk substrate were evaluated as follows: (1) Using a light transmittance scanning spectrometer (C light source, 2° field of view). ! On
The total light transmittance in the wavelength range of m was measured.
（２］ 凝集物個数
ディスク基盤／ ｊ ｇｒ をクラス１００のクリーン
ルーム中で、塩化メチレンｕｔＯｗｔにて溶解し、Ｏ，
ＵＺμのニュークリボアフィルターにて加圧ろ通抜、フ
ィルターを３００１１の塩化メチレンにて洗浄し、更に
風乾して、フィルターに残った微少凝集物を採取する。(2) Aggregate number disk base/j gr was dissolved in methylene chloride utOwt in a class 100 clean room, and O,
Pressurized filtration was carried out using a UZμ Nuclebore filter, the filter was washed with 30011 methylene chloride, and further air-dried to collect the minute aggregates remaining on the filter.
このうち、１０μ以上の大きさを持つ異物の個数を顕微
鏡下で数える。Among these, the number of foreign particles having a size of 10 μ or more is counted under a microscope.
（３）昇華特性
前述のディスク基盤を射出成形する際に、金型の変色を
連続的に観察し、染料が付着して、変色するまでの成形
ショツト数を観察する。まえ連続１０００シヨツト成形
して、金型表面の色の変化が無い場合は、１０００シヨ
ツト成形後の金型を、クロロホルムを染み込ませたガー
ゼにて拭い、ガーゼの汚れを観察する。(3) Sublimation characteristics When injection molding the above-mentioned disk substrate, the discoloration of the mold is continuously observed, and the number of molding shots until the dye adheres and the discoloration occurs is observed. If there is no change in the color of the mold surface after 1000 consecutive shots are molded, wipe the mold after 1000 shots with gauze impregnated with chloroform and observe the stains on the gauze.
表−７染料の内容と配合量
＊１ 三菱化成工業■ ダイヤレジン（商標）オレンジ
Ｈ８＊２ 日本化薬■ カヤセット （商標）オレンジ
ＡＮ＊３ 住友化学■ スミプラスト（商標）オレンジ
６゜＊４ 三菱化成■ ダイヤレジン（商標）オレンジ
Ｇ＊５ Ｉ ダイヤレジン（商標）イエロ
ーＧＲＭ表−一 染料の特性
表−３ディスク基盤の評価
〔発明の効果〕
本発明によれば光学特性を低下させずに着色した光学部
品が得られる。Table 7 Contents and blending amounts of dyes *1 Mitsubishi Chemical Industries ■ Diamond Resin (trademark) Orange H8 *2 Nippon Kayaku ■ Kayaset (trademark) Orange AN *3 Sumitomo Chemical ■ Sumiplast (trademark) Orange 6° *4 Mitsubishi Chemical ■ Diamond Resin (trademark) Orange G*5 I Diamond Resin (trademark) Yellow GRM Table-1 Dye characteristic table-3 Evaluation of disk substrate [Effects of the invention] According to the present invention, coloring was achieved without deteriorating optical properties. An optical component is obtained.
Claims (6)
ボネート樹脂に、 （イ）融点が２５０℃以下 （ロ）昇華開始温度が２３０℃以上 （ハ）溶剤にとかした状態での７００ｎｍ〜１０００ｎ
ｍの波長を持つ光の透過率が９０％以上 という特性を満足する染料を１〜１０００ｐｐｍ添加し
た素材からなる光学用部品。(1) Bis(hydroxyphenyl)alkane-based polycarbonate resin, (a) melting point of 250°C or lower (b) sublimation initiation temperature of 230°C or higher (c) 700nm to 1000n when dissolved in a solvent
An optical component made of a material containing 1 to 1000 ppm of a dye that satisfies the characteristic of having a transmittance of 90% or more for light having a wavelength of m.
ジ６０、ソルベントオレンジ６７又はソルベントオレン
ジ７８である特許請求の範囲第１項に記載の光学用部品
。(2) The optical component according to claim 1, wherein the dye is a color index and is Solvent Orange 60, Solvent Orange 67, or Solvent Orange 78.
等の光学的読取装置の情報媒体の基盤である特許請求の
範囲第１項に記載の光学用部品。(3) The optical component according to claim 1, wherein the optical component is a base of an information medium of an optical reader such as a compact disc or an optical disc.
ーである特許請求の範囲第１項に記載の光学用部品。(4) The optical component according to claim 1, wherein the optical component is a lens, an optical filter, or an optical fiber.
皮膜を形成したコールド色の部品である特許請求の範囲
第１項に記載の光学用部品。(5) The optical component according to claim 1, wherein the optical component is a cold-colored component having a film mainly composed of aluminum formed on the surface layer.
のポリカーボネート樹脂を使用し、３３０〜３６０℃の
加工温度で成形したものである特許請求の範囲第１項に
記載の光学用部品。(6) Optical parts have a molecular weight of 12,000 to 18,000
The optical component according to claim 1, which is molded using polycarbonate resin at a processing temperature of 330 to 360°C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62261130A JPH01102505A (en) | 1987-10-16 | 1987-10-16 | Optical parts |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62261130A JPH01102505A (en) | 1987-10-16 | 1987-10-16 | Optical parts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01102505A true JPH01102505A (en) | 1989-04-20 |
Family
ID=17357511
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62261130A Pending JPH01102505A (en) | 1987-10-16 | 1987-10-16 | Optical parts |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01102505A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002322290A (en) * | 2001-04-26 | 2002-11-08 | Teijin Chem Ltd | Colored master pellet for optical molded product and colored optical disk substrate |
| US6686041B2 (en) | 2000-04-28 | 2004-02-03 | Teijin Chemicals Ltd | Coloring master pellet for optical molded article and colored optical disk substrate |
| EP2248841B2 (en) † | 2002-04-22 | 2015-03-11 | Mitsubishi Chemical Corporation | Hollow container comprising an aromatic polycarbonate composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5910909A (en) * | 1982-07-12 | 1984-01-20 | Mitsubishi Rayon Co Ltd | Composition for near infrared transmission filter |
| JPS5923307A (en) * | 1982-07-29 | 1984-02-06 | Mitsubishi Rayon Co Ltd | Resin composition for near infrared transmitting filter |
| JPS615203A (en) * | 1984-06-19 | 1986-01-11 | Mitsubishi Chem Ind Ltd | Infrared-ray transmitting filter |
-
1987
- 1987-10-16 JP JP62261130A patent/JPH01102505A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5910909A (en) * | 1982-07-12 | 1984-01-20 | Mitsubishi Rayon Co Ltd | Composition for near infrared transmission filter |
| JPS5923307A (en) * | 1982-07-29 | 1984-02-06 | Mitsubishi Rayon Co Ltd | Resin composition for near infrared transmitting filter |
| JPS615203A (en) * | 1984-06-19 | 1986-01-11 | Mitsubishi Chem Ind Ltd | Infrared-ray transmitting filter |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6686041B2 (en) | 2000-04-28 | 2004-02-03 | Teijin Chemicals Ltd | Coloring master pellet for optical molded article and colored optical disk substrate |
| JP2002322290A (en) * | 2001-04-26 | 2002-11-08 | Teijin Chem Ltd | Colored master pellet for optical molded product and colored optical disk substrate |
| EP2248841B2 (en) † | 2002-04-22 | 2015-03-11 | Mitsubishi Chemical Corporation | Hollow container comprising an aromatic polycarbonate composition |
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