JP7557535B2 - ゲルマノシリケートｃｉｔ－１４／ｉｓｔ及びゲルマノシリケートｃｉｔ－１３／ｏｈからのその調製 - Google Patents

ゲルマノシリケートｃｉｔ－１４／ｉｓｔ及びゲルマノシリケートｃｉｔ－１３／ｏｈからのその調製 Download PDF

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JP7557535B2
JP7557535B2 JP2022530332A JP2022530332A JP7557535B2 JP 7557535 B2 JP7557535 B2 JP 7557535B2 JP 2022530332 A JP2022530332 A JP 2022530332A JP 2022530332 A JP2022530332 A JP 2022530332A JP 7557535 B2 JP7557535 B2 JP 7557535B2
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cit
ist
germanosilicate
composition
crystalline microporous
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JP2023506619A (ja
JP2023506619A5 (https=
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イー デイビス マーク
フン カン ジョン
シエ ダン
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California Institute of Technology
Chevron USA Inc
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Chevron USA Inc
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/2808—Pore diameter being less than 2 nm, i.e. micropores or nanopores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/305—Addition of material, later completely removed, e.g. as result of heat treatment, leaching or washing, e.g. for forming pores
    • B01J20/3057—Use of a templating or imprinting material ; filling pores of a substrate or matrix followed by the removal of the substrate or matrix
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3071—Washing or leaching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
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    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
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    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
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    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
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    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
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    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
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  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Control Of Position, Course, Altitude, Or Attitude Of Moving Bodies (AREA)
JP2022530332A 2019-12-12 2020-12-11 ゲルマノシリケートｃｉｔ－１４／ｉｓｔ及びゲルマノシリケートｃｉｔ－１３／ｏｈからのその調製 Active JP7557535B2 (ja)

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US201962947434P 2019-12-12 2019-12-12
US62/947,434 2019-12-12
PCT/US2020/064421 WO2021119380A1 (en) 2019-12-12 2020-12-11 Germanosilicate cit-14/ist and its preparation from germanosilicate cit-13/oh

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JP2023506619A JP2023506619A (ja) 2023-02-17
JP2023506619A5 JP2023506619A5 (https=) 2023-03-20
JP7557535B2 true JP7557535B2 (ja) 2024-09-27

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EP (1) EP4017631A4 (https=)
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CN (1) CN115297963B (https=)
CA (1) CA3160530A1 (https=)
WO (1) WO2021119380A1 (https=)

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Publication number Priority date Publication date Assignee Title
US12552676B2 (en) * 2022-11-01 2026-02-17 Chevron U.S.A. Inc. Molecular sieve SSZ-124, its synthesis and use
SE2351321A1 (en) * 2023-11-20 2025-05-21 Husqvarna Ab Robotic lawnmower system

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JP2018521933A (ja) 2015-06-01 2018-08-09 カリフォルニア インスティチュート オブ テクノロジー 新規ｃｉｔ−１３位相の結晶質ゲルマノケイ酸塩物質およびその調製方法
JP2019508351A (ja) 2016-03-04 2019-03-28 カリフォルニア インスティチュート オブ テクノロジー 新規ゲルマノシリケート組成物及びその製造方法
WO2019231595A1 (en) 2018-05-31 2019-12-05 California Institute Of Technology Methods of preparing crystalline germanosilicate materials of cit-13 topology

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US6040258A (en) 1997-08-13 2000-03-21 California Institute Of Technology Zeolite CIT-5 and method of making
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US6508860B1 (en) 2001-09-21 2003-01-21 L'air Liquide - Societe Anonyme A'directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude Gas separation membrane with organosilicon-treated molecular sieve
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US10828625B2 (en) 2015-06-01 2020-11-10 California Institute Of Technology Crystalline germanosilicate materials of new CIT-13 topology and methods of preparing the same
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JP2018521933A (ja) 2015-06-01 2018-08-09 カリフォルニア インスティチュート オブ テクノロジー 新規ｃｉｔ−１３位相の結晶質ゲルマノケイ酸塩物質およびその調製方法
JP2019508351A (ja) 2016-03-04 2019-03-28 カリフォルニア インスティチュート オブ テクノロジー 新規ゲルマノシリケート組成物及びその製造方法
WO2019231595A1 (en) 2018-05-31 2019-12-05 California Institute Of Technology Methods of preparing crystalline germanosilicate materials of cit-13 topology

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Elke VERHEYEN et al.，"Design of zeolite by inverse sigma transformation"，Nature Materials，2012年10月21日，Vol.11, No.12，p.1059-1064，DOI: 10.1038/NMAT3455
KANG, Jong Hun，"I. Shape Selectivity of Small-pore Molecular Sieves for the Methanol-to-Olefins Reaction and II. Synthesis and Topotactic Transformation of Germanosilicate CIT-13", Dissertation (Ph.D.), Abstract，[online]，California Institute of Technology，2020年02月29日，[令和6年8月27日検索], インターネット<URL: https://web.archive.org/web/20200228154411/https://thesis.library.caltech.edu/11702>
KANG, Jong Hun，"I. Shape Selectivity of Small-pore Molecular Sieves for the Methanol-to-Olefins Reaction and II. Synthesis and Topotactic Transformation of Germanosilicate CIT-13", Dissertation (Ph.D.), Thesis，[online]，California Institute of Technology，2020年08月15日，[令和6年8月27日検索], インターネット<URL: https://web.archive.org/web/20200815141458/https://thesis.library.caltech.edu/11702/>，DOI: 10.7907/PG34-B728

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EP4017631A1 (en) 2022-06-29
CN115297963B (zh) 2023-12-26
JP2023506619A (ja) 2023-02-17
KR20220108180A (ko) 2022-08-02
CA3160530A1 (en) 2021-06-03
EP4017631A4 (en) 2024-07-03
WO2021119380A1 (en) 2021-06-17
CN115297963A (zh) 2022-11-04
US12358800B2 (en) 2025-07-15

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