CN115297963B - 锗硅酸盐cit-14/ist及其由锗硅酸盐cit-13/oh的制备 - Google Patents
锗硅酸盐cit-14/ist及其由锗硅酸盐cit-13/oh的制备 Download PDFInfo
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- CN115297963B CN115297963B CN202080096173.1A CN202080096173A CN115297963B CN 115297963 B CN115297963 B CN 115297963B CN 202080096173 A CN202080096173 A CN 202080096173A CN 115297963 B CN115297963 B CN 115297963B
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
- B01J20/2808—Pore diameter being less than 2 nm, i.e. micropores or nanopores
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/305—Addition of material, later completely removed, e.g. as result of heat treatment, leaching or washing, e.g. for forming pores
- B01J20/3057—Use of a templating or imprinting material ; filling pores of a substrate or matrix followed by the removal of the substrate or matrix
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3071—Washing or leaching
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
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- B01J29/00—Catalysts comprising molecular sieves
- B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
- B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
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- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/643—Pore diameter less than 2 nm
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
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- C—CHEMISTRY; METALLURGY
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- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
- B01J2235/05—Nuclear magnetic resonance [NMR]
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
- B01J2235/15—X-ray diffraction
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
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- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
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- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
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- C—CHEMISTRY; METALLURGY
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- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/89—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by mass-spectroscopy
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Analytical Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Dispersion Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
- Separation Of Gases By Adsorption (AREA)
- Control Of Position, Course, Altitude, Or Attitude Of Moving Bodies (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201962947434P | 2019-12-12 | 2019-12-12 | |
| US62/947,434 | 2019-12-12 | ||
| PCT/US2020/064421 WO2021119380A1 (en) | 2019-12-12 | 2020-12-11 | Germanosilicate cit-14/ist and its preparation from germanosilicate cit-13/oh |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115297963A CN115297963A (zh) | 2022-11-04 |
| CN115297963B true CN115297963B (zh) | 2023-12-26 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202080096173.1A Active CN115297963B (zh) | 2019-12-12 | 2020-12-11 | 锗硅酸盐cit-14/ist及其由锗硅酸盐cit-13/oh的制备 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US12358800B2 (https=) |
| EP (1) | EP4017631A4 (https=) |
| JP (1) | JP7557535B2 (https=) |
| KR (1) | KR20220108180A (https=) |
| CN (1) | CN115297963B (https=) |
| CA (1) | CA3160530A1 (https=) |
| WO (1) | WO2021119380A1 (https=) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12552676B2 (en) * | 2022-11-01 | 2026-02-17 | Chevron U.S.A. Inc. | Molecular sieve SSZ-124, its synthesis and use |
| SE2351321A1 (en) * | 2023-11-20 | 2025-05-21 | Husqvarna Ab | Robotic lawnmower system |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106185976A (zh) * | 2016-07-22 | 2016-12-07 | 太原理工大学 | 一种多级孔丝光沸石分子筛及其制备方法 |
| CN107873015A (zh) * | 2015-06-01 | 2018-04-03 | 加州理工学院 | 具有新的cit‑13拓扑结构的晶体锗硅酸盐材料及其制备方法 |
| CN108698839A (zh) * | 2016-03-04 | 2018-10-23 | 加州理工学院 | 新的锗硅酸盐组合物及其制备方法 |
| WO2019231595A1 (en) * | 2018-05-31 | 2019-12-05 | California Institute Of Technology | Methods of preparing crystalline germanosilicate materials of cit-13 topology |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4544538A (en) | 1982-07-09 | 1985-10-01 | Chevron Research Company | Zeolite SSZ-13 and its method of preparation |
| US6040258A (en) | 1997-08-13 | 2000-03-21 | California Institute Of Technology | Zeolite CIT-5 and method of making |
| DE60130758T2 (de) | 2000-05-31 | 2008-05-21 | Chevron U.S.A. Inc., San Ramon | Zeolith ssz-53 |
| US6508860B1 (en) | 2001-09-21 | 2003-01-21 | L'air Liquide - Societe Anonyme A'directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude | Gas separation membrane with organosilicon-treated molecular sieve |
| US6827843B2 (en) | 2002-12-26 | 2004-12-07 | Chevron U.S.A., Inc. | Hydrocarbon conversion using molecular sieve SSZ-63 |
| US7083714B2 (en) | 2003-03-26 | 2006-08-01 | Chevron U.S.A. Inc. | Hydrocarbon conversion using molecular sieve SSZ-65 |
| US8105481B2 (en) | 2007-12-19 | 2012-01-31 | Chevron U.S.A. Inc. | Reduction of organic halide contamination in hydrocarbon products |
| CN103889573B (zh) | 2011-10-24 | 2016-08-24 | 道达尔炼油法国 | 用于制备加氢转化催化剂的方法、由此获得的催化剂及其在加氢转化方法中的用途 |
| US9278344B2 (en) | 2012-03-23 | 2016-03-08 | Chevron U.S.A. Inc. | Hybrid fischer-tropsch catalysts |
| US9821297B2 (en) | 2015-03-10 | 2017-11-21 | California Institute Of Technology | Methods to produce molecular sieves with LTA topology and compositions derived therefrom |
| US10828625B2 (en) | 2015-06-01 | 2020-11-10 | California Institute Of Technology | Crystalline germanosilicate materials of new CIT-13 topology and methods of preparing the same |
| JP6906049B2 (ja) * | 2016-11-17 | 2021-07-21 | シェブロン ユー.エス.エー. インコーポレイテッド | アルミニウム置換モレキュラーシーブcit−13 |
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2020
- 2020-11-02 CA CA3160530A patent/CA3160530A1/en active Pending
- 2020-12-11 JP JP2022530332A patent/JP7557535B2/ja active Active
- 2020-12-11 CN CN202080096173.1A patent/CN115297963B/zh active Active
- 2020-12-11 US US17/783,759 patent/US12358800B2/en active Active
- 2020-12-11 KR KR1020227023838A patent/KR20220108180A/ko active Pending
- 2020-12-11 EP EP20897712.4A patent/EP4017631A4/en active Pending
- 2020-12-11 WO PCT/US2020/064421 patent/WO2021119380A1/en not_active Ceased
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107873015A (zh) * | 2015-06-01 | 2018-04-03 | 加州理工学院 | 具有新的cit‑13拓扑结构的晶体锗硅酸盐材料及其制备方法 |
| CN108698839A (zh) * | 2016-03-04 | 2018-10-23 | 加州理工学院 | 新的锗硅酸盐组合物及其制备方法 |
| CN106185976A (zh) * | 2016-07-22 | 2016-12-07 | 太原理工大学 | 一种多级孔丝光沸石分子筛及其制备方法 |
| WO2019231595A1 (en) * | 2018-05-31 | 2019-12-05 | California Institute Of Technology | Methods of preparing crystalline germanosilicate materials of cit-13 topology |
Non-Patent Citations (5)
| Title |
|---|
| Fluoride-free synthesis of germanosilicate CIT-13 and its inverse sigma transformation to form CIT-14;Kang J H等;Chemistry of Materials;第32卷(第5期);2014-2024 * |
| Synthesis and characterization of CIT-13, a germanosilicate molecular sieve with extra-large pore openings;Kang J H等;Chemistry of Materials;第28卷(第17期);6250-6259 * |
| Synthesis of Germanosilicate Molecular Sieves from Mono- and Di-Quaternary Ammonium OSDAs Constructed from Benzyl Imidazolium Derivatives: Stabilization of Large Micropore Volumes Including New Molecular Sieve CIT-13;Boal BW等;CHEMISTRY OF MATERIALS;第28卷(第7期);2158-2164 * |
| The role of crystallization parameters for the synthesis of germanosilicate with UTL topology;Shvets O V等;Chemistry–A European Journal;第14卷(第32期);10134-10140 * |
| 新型开放骨架锗酸盐化合物的合成、结构与表征;徐燕;中国博士学位论文全文数据库 (工程科技Ⅰ辑)(第8期);B014-531 * |
Also Published As
| Publication number | Publication date |
|---|---|
| US20230032494A1 (en) | 2023-02-02 |
| EP4017631A1 (en) | 2022-06-29 |
| JP2023506619A (ja) | 2023-02-17 |
| KR20220108180A (ko) | 2022-08-02 |
| CA3160530A1 (en) | 2021-06-03 |
| EP4017631A4 (en) | 2024-07-03 |
| WO2021119380A1 (en) | 2021-06-17 |
| JP7557535B2 (ja) | 2024-09-27 |
| CN115297963A (zh) | 2022-11-04 |
| US12358800B2 (en) | 2025-07-15 |
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| CN115297963B (zh) | 锗硅酸盐cit-14/ist及其由锗硅酸盐cit-13/oh的制备 | |
| US10828625B2 (en) | Crystalline germanosilicate materials of new CIT-13 topology and methods of preparing the same | |
| JP2023506619A5 (https=) |
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