JP7475264B2 - ３－イソプロペニル－６－ヘプテナール化合物及び６－イソプロペニル－３－メチル－３，９－デカジエニル＝カルボキシレート化合物の製造方法並びにその中間体 - Google Patents

３－イソプロペニル－６－ヘプテナール化合物及び６－イソプロペニル－３－メチル－３，９－デカジエニル＝カルボキシレート化合物の製造方法並びにその中間体 Download PDF

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JP7475264B2
JP7475264B2 JP2020205403A JP2020205403A JP7475264B2 JP 7475264 B2 JP7475264 B2 JP 7475264B2 JP 2020205403 A JP2020205403 A JP 2020205403A JP 2020205403 A JP2020205403 A JP 2020205403A JP 7475264 B2 JP7475264 B2 JP 7475264B2
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compound
methyl
isopropenyl
reaction
formula
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JP2022092538A (ja
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啓弘 馬場
剛 金生
尚樹 石橋
祐輔 長江
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Shin Etsu Chemical Co Ltd
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Shin Etsu Chemical Co Ltd
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Priority to JP2020205403A priority Critical patent/JP7475264B2/ja
Priority to EP21212942.3A priority patent/EP4011858A1/en
Priority to CN202111483900.2A priority patent/CN114621073A/zh
Priority to US17/543,877 priority patent/US11807602B2/en
Publication of JP2022092538A publication Critical patent/JP2022092538A/ja
Priority to JP2024015428A priority patent/JP2024050787A/ja
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Publication of JP7475264B2 publication Critical patent/JP7475264B2/ja
Priority to JP2025061400A priority patent/JP2025106372A/ja
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/587—Monocarboxylic acid esters having at least two carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/41—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by hydrogenolysis or reduction of carboxylic groups or functional derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
    • C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
    • C07C29/40—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones with compounds containing carbon-to-metal bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/30—Preparation of ethers by reactions not forming ether-oxygen bonds by increasing the number of carbon atoms, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/14—Preparation of carboxylic acid esters from carboxylic acid halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/27—Preparation of carboxylic acid esters from ortho-esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/475—Preparation of carboxylic acid esters by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of groups between different molecules
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D309/04—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D309/06—Radicals substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5442—Aromatic phosphonium compounds (P-C aromatic linkage)

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2020205403A 2020-12-10 2020-12-10 ３－イソプロペニル－６－ヘプテナール化合物及び６－イソプロペニル－３－メチル－３，９－デカジエニル＝カルボキシレート化合物の製造方法並びにその中間体 Active JP7475264B2 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2020205403A JP7475264B2 (ja) 2020-12-10 2020-12-10 ３－イソプロペニル－６－ヘプテナール化合物及び６－イソプロペニル－３－メチル－３，９－デカジエニル＝カルボキシレート化合物の製造方法並びにその中間体
EP21212942.3A EP4011858A1 (en) 2020-12-10 2021-12-07 Processes for preparing a 3-isopropenyl-6-heptenal compound and a 6-isopropenyl-3-methyl-3,9-decadienyl carboxylate compound, and an intermediate therefor
CN202111483900.2A CN114621073A (zh) 2020-12-10 2021-12-07 庚烯醛化合物和癸二烯基羧酸酯化合物及其中间体的制备方法
US17/543,877 US11807602B2 (en) 2020-12-10 2021-12-07 Processes for preparing a 3-isopropenyl-6-heptenal compound and a 6- isopropenyl-3-methyl-3,9-decadienyl carboxylate compound, and an intermediate therefor
JP2024015428A JP2024050787A (ja) 2020-12-10 2024-02-05 ３－イソプロペニル－６－ヘプテナール化合物及び６－イソプロペニル－３－メチル－３，９－デカジエニル＝カルボキシレート化合物の製造方法並びにその中間体
JP2025061400A JP2025106372A (ja) 2020-12-10 2025-04-02 ３－イソプロペニル－６－ヘプテナール化合物及び６－イソプロペニル－３－メチル－３，９－デカジエニル＝カルボキシレート化合物の製造方法並びにその中間体

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2020205403A JP7475264B2 (ja) 2020-12-10 2020-12-10 ３－イソプロペニル－６－ヘプテナール化合物及び６－イソプロペニル－３－メチル－３，９－デカジエニル＝カルボキシレート化合物の製造方法並びにその中間体

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JP2024015428A Division JP2024050787A (ja) 2020-12-10 2024-02-05 ３－イソプロペニル－６－ヘプテナール化合物及び６－イソプロペニル－３－メチル－３，９－デカジエニル＝カルボキシレート化合物の製造方法並びにその中間体

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JP2022092538A JP2022092538A (ja) 2022-06-22
JP7475264B2 true JP7475264B2 (ja) 2024-04-26

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JP2020205403A Active JP7475264B2 (ja) 2020-12-10 2020-12-10 ３－イソプロペニル－６－ヘプテナール化合物及び６－イソプロペニル－３－メチル－３，９－デカジエニル＝カルボキシレート化合物の製造方法並びにその中間体
JP2024015428A Pending JP2024050787A (ja) 2020-12-10 2024-02-05 ３－イソプロペニル－６－ヘプテナール化合物及び６－イソプロペニル－３－メチル－３，９－デカジエニル＝カルボキシレート化合物の製造方法並びにその中間体
JP2025061400A Pending JP2025106372A (ja) 2020-12-10 2025-04-02 ３－イソプロペニル－６－ヘプテナール化合物及び６－イソプロペニル－３－メチル－３，９－デカジエニル＝カルボキシレート化合物の製造方法並びにその中間体

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JP2024015428A Pending JP2024050787A (ja) 2020-12-10 2024-02-05 ３－イソプロペニル－６－ヘプテナール化合物及び６－イソプロペニル－３－メチル－３，９－デカジエニル＝カルボキシレート化合物の製造方法並びにその中間体
JP2025061400A Pending JP2025106372A (ja) 2020-12-10 2025-04-02 ３－イソプロペニル－６－ヘプテナール化合物及び６－イソプロペニル－３－メチル－３，９－デカジエニル＝カルボキシレート化合物の製造方法並びにその中間体

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US (1) US11807602B2 (https=)
EP (1) EP4011858A1 (https=)
JP (3) JP7475264B2 (https=)
CN (1) CN114621073A (https=)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018535983A (ja) 2015-11-18 2018-12-06 プロビビ インコーポレイテッド オレフィンメタセシスを介した脂肪族オレフィン誘導体の生成

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4201874A (en) * 1978-03-13 1980-05-06 Zoecon Corporation 3-Isopropenyl-6-heptenoic acid
JP4110490B2 (ja) * 1998-03-30 2008-07-02 曽田香料株式会社 β−シネンサールの製造法
JP4999939B2 (ja) 2010-01-12 2012-08-15 信越化学工業株式会社 クワシロカイガラムシの性誘引剤及び誘引方法
WO2019216412A1 (ja) * 2018-05-11 2019-11-14 高砂香料工業株式会社 ジエナール化合物および香料組成物

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018535983A (ja) 2015-11-18 2018-12-06 プロビビ インコーポレイテッド オレフィンメタセシスを介した脂肪族オレフィン誘導体の生成

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Chemistry Letters，2007年，Vol.36, No.7，pp.886-887
J. Org. Chem.，1980年，Vol.45，pp.2910-2912
Synthetic Communications，1990年，Vol.20, No.4，pp.495-501

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Publication number Publication date
JP2025106372A (ja) 2025-07-15
CN114621073A (zh) 2022-06-14
JP2022092538A (ja) 2022-06-22
US11807602B2 (en) 2023-11-07
EP4011858A1 (en) 2022-06-15
US20220185763A1 (en) 2022-06-16
JP2024050787A (ja) 2024-04-10

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