JP7426215B2 - Odor substance adsorbent - Google Patents

Description

TECHNICAL FIELD The present invention relates to an odorant adsorbent.

In recent years, consumer needs for deodorization have been increasing. Among these, aldehyde compounds such as formaldehyde and acetaldehyde are considered to be causative agents of sick building syndrome, and are difficult to adsorb to common adsorbents (e.g., general-purpose activated carbon), so they are particularly difficult to absorb. It is a substance with high demand for odor. For example, hydrazine compounds are known as adsorbents for such odorous substances.

Among them, adipic acid dihydrazide, which has relatively high deodorizing performance, is widely used (see, for example, Patent Document 1).

International Publication No. 2009/122975

However, when adipic acid dihydrazide as a hydrazine compound is used as an adsorbent, there are cases where deodorizing performance is not exhibited. Specifically, we have confirmed that even if adipic acid dihydrazide is dissolved in water and impregnated into glass fibers and then left at room temperature for a certain period of time, the deodorizing performance is not fully demonstrated. Furthermore, this phenomenon is noticeable in applications that include a step of heating to 130° C. or higher during the manufacturing process. For example, in the field of plastic mixing used in the manufacture of building materials, the molding and coating drying processes are sometimes exposed to temperatures of 200°C for about 10 minutes, which often results in no deodorizing performance at all. .

Until now, the cause of this phenomenon has not been accurately understood, and there have been many situations in which hydrazine compounds such as adipic acid dihydrazide cannot be used.

The present inventors have conducted intensive studies to investigate the cause of the above problem, and as a result, have discovered that when a hydrazine compound is dried, its activity is significantly reduced.

In order to suppress the deterioration of deodorizing performance due to such drying, it is also possible to use a moisture absorbent in combination. However, when using such moisture absorbers, the degree to which deodorizing performance can be maintained depends on the surrounding humidity, and optimizing it requires trial and error, and it is difficult to obtain consistently high deodorizing performance. Hateful. Therefore, there is a need for a method that can suppress the deterioration of deodorizing performance due to drying as described above without using a moisture absorbent.

As mentioned above, when an adsorbent is used in combination with adipic acid dihydrazide water, the degree to which deodorizing performance can be maintained depends on the surrounding humidity, and optimizing it requires trial and error, resulting in a stable and high level of deodorizing performance. It is difficult to obtain deodorizing performance. Therefore, an object of the present invention is to provide an odorous substance adsorbent that can improve deodorizing performance both at room temperature and after thermal history.

As a result of intensive research to achieve the above object, the present inventors have found that the above problems can be solved by using an adsorbent that uses an organic solvent with a boiling point of at least 200°C or higher as a solvent. I found out what I can do. Based on such knowledge, the present inventors conducted further research and completed the present invention. That is, the present invention includes the configurations shown below.
Item 1. Contains a hydrazine compound and a solvent,
An odorous substance adsorbent, wherein the solvent contains at least an organic solvent with a boiling point of 200°C or higher.
Item 2. Item 2. The odorous substance adsorbent according to Item 1, wherein the organic solvent is a protic organic solvent.
Item 3. Item 3. The odorous substance adsorbent according to Item 1 or 2, wherein the organic solvent is glycerin and/or diglycerin.
Item 4. Item 3. The odorous substance adsorbent according to item 2 or 3, which is used for industrial products in which all manufacturing steps are performed at temperatures below 130°C.
Item 5. Item 5. The odorous substance adsorbent according to any one of Items 1 to 4, wherein the content of the organic solvent is 5% by mass or more when the total amount of the solvent is 100% by mass.
Item 6. Item 2. The odorous substance adsorbent according to Item 1, wherein the organic solvent contains at least one selected from the group consisting of glycerin, diglycerin, and an aprotic organic solvent.
Section 7. Item 6. The odorous substance adsorbent according to item 6, which is used for industrial products in which at least one manufacturing step is performed at 130°C or higher.
Section 8. Item 8. The odorous substance adsorbent according to item 6 or 7, wherein the content of the organic solvent is 40% by mass or more when the total amount of the solvent is 100% by mass.
Item 9. The hydrazine compound may include propionic acid hydrazide, lauric acid hydrazide, salicylic acid hydrazide, form hydrazide, acetohydrazide, p-hydroxybenzoic acid hydrazide, naphthoic acid hydrazide, 3-hydroxy-2-naphthoic acid hydrazide, benzhydrazide, carbodihydrazide, Acid dihydrazide, malonic acid dihydrazide, succinic acid dihydrazide, glutaric acid dihydrazide, adipic acid dihydrazide, azelaic acid dihydrazide, sebacic acid dihydrazide, dodecanedioic acid dihydrazide, maleic acid dihydrazide, fumaric acid dihydrazide, tartaric acid dihydrazide, malic acid dihydrazide, diglycolic acid Dihydrazide, isophthalic acid dihydrazide, terephthalic acid dihydrazide, 2,6-naphthalenedicarboxylic acid dihydrazide, 2,6-naphthoic acid dihydrazide, citric acid trihydrazide, pyromellitic acid trihydrazide, 1,2,4-benzenetricarboxylic acid trihydrazide, nitrilotrihydrazide Acetic acid trihydrazide, 1,3,5-cyclohexanetricarboxylic acid trihydrazide, ethylenediaminetetraacetic acid tetrahydrazide, 1,4,5,8-naphthoic acid tetrahydrazide, tert-butylhydrazine, isopropylhydrazine, butylhydrazine, benzylhydrazine, phenyl Hydrazine, 3-amino-1,2,4-triazole, 4-amino-1,2,4-triazole, 3-amino-5-phenyl-1,2,4-triazole, 4-aminourazole, and amino Item 8. The odorous substance adsorbent according to any one of Items 1 to 8, which is at least one member selected from the group consisting of guanidine.
Item 10. Item 10. The odorous substance adsorbent according to any one of Items 1 to 9, further comprising an inorganic porous material.
Item 11. Item 11. The odorous substance adsorbent according to Item 10, wherein the inorganic porous material is at least one selected from the group consisting of silicon-containing compounds, activated carbon, alumina, ceramics, and calcium carbonate.
Item 12. Item 12. The odorous substance adsorbent according to any one of Items 1 to 11, wherein the odorous substance is at least one selected from the group consisting of aldehyde compounds, ketone compounds, and carboxylic acid compounds.
Item 13. An industrial product comprising the odorant adsorbent according to any one of items 1 to 12.
Section 14. An industrial product comprising the odorant adsorbent according to any one of Items 1 to 5 and 9 to 12, wherein all steps of the manufacturing process are performed at a temperature below 130°C.
Item 15. An industrial product comprising the odorant adsorbent according to any one of items 6 to 12, in which at least one step of the manufacturing process is performed at 130°C or higher.
Section 16. A method for adsorbing odorous substances, comprising the step of bringing an odorous substance into contact with the odorous substance adsorbent according to any one of Items 1 to 12.
Section 17. An odorous substance comprising a step of bringing an odorous substance into contact with an industrial product comprising an odorous substance adsorbent according to any one of Items 1 to 5 and 9 to 12, the manufacturing process of which is carried out at a temperature below 130°C. adsorption method.
Section 18. Adsorption of odorous substances, comprising a step of bringing odorous substances into contact with an industrial product comprising the odorous substance adsorbent according to any one of items 6 to 12, in which at least one step of the manufacturing process is carried out at 130°C or higher. Method.

The odorous substance adsorbent of the present invention can sufficiently adsorb odorous substances and exhibit excellent deodorizing performance both at room temperature and under heating.

In this specification, "contain" is a concept that includes all of "comprise," "consist essentially of," and "consist of." Furthermore, in this specification, when a numerical range is expressed as "A to B", it means greater than or equal to A and less than or equal to B.

As used herein, "without heating" refers to the case of use in industrial products in which all steps in the manufacturing process are performed at temperatures below 130°C, and may simply be referred to as "without heating." In addition, "under heating" means when used for industrial products in which at least one step in the manufacturing process is performed at 130°C or higher (including cases where all steps are performed at 130°C or higher), and simply "under heating" There is something to be said.

1. Odorous substance adsorbent The odorous substance adsorbent of the present invention contains a hydrazine compound and a solvent, and the solvent contains at least an organic solvent having a boiling point of 200°C or higher.

(1-1) Hydrazine compound There are no particular limitations on the hydrazine compound, and conventionally known compounds can be used. For example, acid hydrazide compounds, alkyl hydrazine compounds, other hydrazine compounds, etc. can be used. . Examples of acid hydrazide compounds include acid monohydrazide compounds having one hydrazide group in the molecule, acid dihydrazide compounds having two hydrazide groups in the molecule, acid trihydrazide compounds having three hydrazide groups in the molecule, etc. can be used. Among these, acid hydrazide compounds are preferred, and acid dihydrazide compounds or acid trihydrazide compounds are more preferred, from the viewpoints of deodorizing performance under heating and without heating, storage stability of the adsorbent, and suppression of coloring. Among these, general-purpose compounds are preferred as such hydrazine compounds. These hydrazine compounds are compounds that have the ability to adsorb odorous substances (aldehyde compounds, ketone compounds, carboxylic acid compounds, etc.).

The molecular weight of the hydrazine compound is, for example, preferably 30 or more, more preferably 60 or more, and even more preferably 90 or more, from the viewpoint of deodorizing performance and deodorizing speed under non-heating and heating. Further, the molecular weight of the hydrazine compound is preferably, for example, 300 or less, more preferably 280 or less, and even more preferably 260 or less, from the viewpoint of deodorizing performance and deodorizing speed under non-heating and heating. Further, the molecular weight of the hydrazine compound is preferably, for example, 100 or more, and more preferably 130 or more, from the viewpoint of heat resistance and storage stability as additional performance. Further, the molecular weight of the hydrazine compound is preferably, for example, 300 or less, more preferably 270 or less, from the viewpoint of heat resistance and storage stability as additional performance.

Specifically, such hydrazine compounds include propionic acid hydrazide, lauric acid hydrazide, salicylic acid hydrazide, form hydrazide, acetohydrazide, p-hydroxybenzoic acid hydrazide, naphthoic acid hydrazide, 3-hydroxy- 2-Naphthoic acid hydrazide, benzhydrazide, carbodihydrazide, oxalic acid dihydrazide, malonic acid dihydrazide, succinic acid dihydrazide, glutaric acid dihydrazide, adipic acid dihydrazide, azelaic acid dihydrazide, sebacic acid dihydrazide, dodecanedioic acid dihydrazide, maleic acid dihydrazide, fumar Acid dihydrazide, tartaric acid dihydrazide, malic acid dihydrazide, diglycolic acid dihydrazide, isophthalic acid dihydrazide, terephthalic acid dihydrazide, 2,6-naphthalenedicarboxylic acid dihydrazide, 2,6-naphthoic acid dihydrazide, citric acid trihydrazide, pyromellitic acid trihydrazide, 1 , 2,4-benzenetricarboxylic acid trihydrazide, nitrilotriacetic acid trihydrazide, 1,3,5-cyclohexanetricarboxylic acid trihydrazide, ethylenediaminetetraacetic acid tetrahydrazide, 1,4,5,8-naphthoic acid tetrahydrazide, etc. Examples of alkylhydrazine compounds include tertiary-butylhydrazine, isopropylhydrazine, butylhydrazine, benzylhydrazine, phenylhydrazine, etc., and other hydrazine compounds include 3-amino-1,2,4-triazole, 4-amino- Examples include 1,2,4-triazole, 3-amino-5-phenyl-1,2,4-triazole, 4-aminourazole, and aminoguanidine. Among them, acid hydrazide compounds are preferred from the viewpoint of safety, deodorizing performance under heating and unheated conditions, deodorizing speed under unheated conditions and under heating, coloration suppression, excellent balance of heat resistance and storage stability. More preferred are adipic acid dihydrazide, succinic acid dihydrazide, dodecanedioic acid dihydrazide, and the like. These hydrazine compounds can be used alone or in combination of two or more.

The content of the hydrazine compound in the odorant adsorbent of the present invention is not particularly limited, and includes odor eliminating performance under heating and under heating, deodorizing speed under unheating and under heating, coloring suppression, heat resistance, and storage. From the viewpoint of further improving stability, the total amount of the odorous substance adsorbent of the present invention is 100% by mass, for example, preferably 0.1% by mass or more, more preferably 1.0% by mass or more, even more preferably 3.0% by mass or more, and For example, the content is preferably 90.0% by mass or less, more preferably 50.0% by mass or less, and even more preferably 20.0% by mass or less. Furthermore, even when the odorous substance adsorbent of the present invention contains an inorganic porous material, the optimum content of the hydrazine compound in the odorous substance adsorbent is the same. As will be described later, in the odor substance adsorbent of the present invention, an emulsion can be used as the synthetic resin, but the above-mentioned total amount is the content calculated without considering the solvent contained in the emulsion. be.

(1-2) Solvent As described above, the odorous substance adsorbent of the present invention contains a hydrazine compound and a solvent, and the solvent contains at least an organic solvent having a boiling point of 200°C or higher. In other words, from the viewpoint of suppressing the drying deactivation of the hydrazine compound and improving the deodorizing performance and deodorizing speed under heating and non-heating, the hydrazine compound is dissolved or It is preferable to disperse it into a solution or suspension and use this as an odorant adsorbent.

Such an organic solvent with a boiling point of 200°C or higher is preferably 200°C or higher, from the viewpoint of further suppressing deterioration of deodorizing performance and deodorizing speed due to drying deactivation under unheated and heated conditions. The temperature is 240°C or higher, more preferably 280°C or higher. When an aprotic organic solvent having a boiling point of 200°C or higher is used, the boiling point is preferably 250°C or higher, more preferably 280°C or higher, and even more preferably 350°C or higher. Further, the upper limit of the boiling point of the organic solvent is not particularly limited, but is usually 600°C.

Examples of organic solvents with a boiling point of 200°C or higher that satisfy the above conditions include diethylene glycol, dipropylene glycol, 1,3-butanediol, 1,4-butanediol, and 1,5-protic organic solvents. Examples include polyhydric alcohols such as pentanediol, glycerin, and diglycerin; ethers such as tripropylene glycol monobutyl ether (Dawanol TPnB), polyethylene glycol, and polypropylene glycol; and as aprotic organic solvents, bis(2-ethylhexyl adipate) ), adipate esters such as diisononyl adipate and diisodecyl adipate; dimethyl phthalate, diethyl phthalate, dibutyl phthalate, bis(2-ethylhexyl) phthalate, diisononyl phthalate, diisodecyl phthalate, butylbenzyl phthalate, etc. Phthalate esters; Other esters such as tris(2-ethylhexyl) trimellitate, tributyl phosphate, and γ-butyrolactone; Aromatic hydrocarbons such as methylnaphthalene, dimethylnaphthalene, isopropylnaphthalene, and diisopropylnaphthalene; N-methylpyrrolidone, etc. can be mentioned. Among these, protic organic solvents are preferred, and glycerin and diglycerin are particularly preferred, from the viewpoints of deodorizing performance and deodorizing speed without heating, solubility of the above-mentioned hydrazine compound, and the like. In addition, from the viewpoint of deodorizing performance and deodorizing speed under heating, solubility of the above-mentioned hydrazine compound, etc., glycerin, diglycerin, and aprotic organic solvents are preferable, and glycerin and diglycerin are particularly preferable. These organic solvents having a boiling point of 200° C. or higher can be used alone or in combination of two or more.

In the present invention, all the solvents can be organic solvents with a boiling point of 200°C or higher, or the organic solvents with a boiling point of 200°C or higher and an aqueous solvent such as water, ethylene glycol, propylene glycol, A mixed solvent with an organic solvent having a boiling point of less than 200°C such as diethylene glycol monomethyl ether or diethylene glycol monoethyl ether can also be used. In particular, from the viewpoint of deodorizing performance and deodorizing speed without heating, the content of organic solvents with a boiling point of 200°C or higher is preferably 5% by mass or more, and 40% by mass, assuming the total amount of solvent is 100% by mass. The content is more preferably 60% by mass or more, even more preferably 80% by mass or more. In addition, from the viewpoint of deodorizing performance and deodorizing speed under heating, the content of organic solvent is preferably 40% by mass or more, more preferably 60% by mass or more, and 80% by mass, assuming the total amount of solvent is 100% by mass. The above is more preferable. In addition, it is preferable to use aqueous solvents in small amounts because of concerns about deterioration of deodorizing performance and deodorization speed due to drying, and organic solvents with a boiling point of less than 200°C are not sufficiently effective in suppressing deterioration of deodorizing performance and deodorization speed due to drying. Since this is not possible, the content of the organic solvent with a boiling point of 200°C or higher can be set to 100% by mass, which is also the upper limit. In addition, from the viewpoint of deodorizing performance and deodorizing speed without heating, when a protic organic solvent is used as an organic solvent with a boiling point of 200° C. or higher, it is preferable that its content is not too large. On the other hand, from the viewpoint of deodorizing performance and deodorizing speed under heating, when a protic organic solvent is used as an organic solvent with a boiling point of 200° C. or higher, the content thereof is preferably large, and 100% by mass is most preferable. As will be described later, in the odor substance adsorbent of the present invention, an emulsion can be used as the synthetic resin, but the total amount of solvent and the content of the aqueous solvent mentioned above are based on the amount of solvent contained in the emulsion. This is the content calculated without consideration.

In addition, in the present invention, the content of the solvent is not particularly limited, and from the viewpoint of further improving the deodorizing performance and deodorizing speed under non-heating and heating, the total amount of the odorant adsorbent is 100% by mass, For example, it is preferably 30.0% by mass or more, more preferably 50.0% by mass or more, even more preferably 70.0% by mass or more, and, for example, it is preferably 99.9% by mass or less, more preferably 99.0% by mass or less, and still more preferably 98.0% by mass or less. preferable. Furthermore, even when the odorous substance adsorbent of the present invention contains an inorganic porous material, the content of the solvent in the odorous substance adsorbent is the same. Note that, as described later, in the odor substance adsorbent of the present invention, an emulsion can be used as the synthetic resin, but the above-mentioned solvent content was calculated without considering the solvent contained in the emulsion. content.

(1-3) Inorganic porous material The odor substance adsorbent of the present invention can also contain an inorganic porous material. Inorganic porous materials themselves do not adsorb odorous substances at all (they have almost no deodorizing performance), but when used in combination with a hydrazine compound, they are more effective in deodorizing both unheated and heated conditions than when inorganic porous materials are not used. It is also possible to reduce the amount of the hydrazine compound used while maintaining performance and deodorization speed. Therefore, it is also possible to obtain excellent deodorizing performance with a smaller amount of hydrazine compound.

Such inorganic porous materials are not particularly limited, and include compounds containing silicon (silica, activated clay, zeolite, clay, talc, etc.), activated carbon, alumina, ceramics, calcium carbonate, and the like. Among these, compounds containing silicon are preferred, and silica is more preferred, from the viewpoint of easily maintaining deodorizing performance and deodorizing speed even if the amount of the hydrazine compound used is reduced. These inorganic porous materials can be used alone or in combination of two or more.

When using silica as such an inorganic porous material, there are no particular restrictions on its type, and any of wet process silica (precipitated process silica, gel process silica, etc.), dry process silica, fused silica, etc. can be employed.

In addition, when employing a compound containing silicon as the inorganic porous material, it is also possible to have a substituted or unsubstituted amino group on the surface. Such materials can be obtained by chemical modification with a silane coupling agent having a substituted or unsubstituted amino group. Chemical modification can be carried out according to conventional methods. Examples of the silane coupling agent having a substituted or unsubstituted amino group that can be used in this case include a silane coupling agent having a methacrylic group, a silane coupling agent having a vinyl group, a silane coupling agent having an amino group, and a glycidyl group. Examples include silane coupling agents having a mercapto group, silane coupling agents having a mercapto group, etc., and compounds containing silicon (especially silica) modified with substituted or unsubstituted amino groups of these silane coupling agents may also be employed. It is possible.

When using an inorganic porous material, the content of the inorganic porous material in the odorant adsorbent of the present invention is not particularly limited, and the deodorizing performance and deodorizing speed both under non-heating and under heating can be further improved. From this point of view, assuming the total amount of the odorant adsorbent to be 100% by mass, it is preferably 0.1% by mass or more, more preferably 1.0% by mass or more, even more preferably 2.0% by mass or more, and, for example, preferably 99.9% by mass or less. , more preferably 95.0% by mass or less, further preferably 90.0% by mass or less. As will be described later, in the odor substance adsorbent of the present invention, an emulsion can be used as the synthetic resin, but the above-mentioned total amount is the content calculated without considering the solvent contained in the emulsion. be.

(1-4) Odorous Substance Adsorbent As mentioned above, the odorous substance adsorbent of the present invention has a form in which the solid content is a hydrazine compound alone, or a form in which the hydrazine compound contains an inorganic porous material. In either form, it is preferable to dissolve or disperse it in a solvent containing an organic solvent with a boiling point of at least 200° C. or higher to form a solution or suspension, and use this as an odorous substance adsorbent. As a result, deterioration in deodorizing performance and deodorizing speed due to drying can be particularly suppressed.

It is also possible to use a mixture of each of the above-mentioned components and a synthetic resin. Examples of synthetic resins include polyacrylic resins (acrylic resins, methacrylic resins, etc.), polyvinyl acetate resins (vinyl acetate resins, etc.), polyvinyl chloride resins (vinyl chloride resins, etc.), and polyolefin resins (olefin resins). etc.), ethylene-vinyl acetate copolymer resin (EVA resin), polyurethane resin (urethane resin, etc.), polystyrene resin (styrene resin, etc.), polyepoxy resin (epoxy resin, etc.), silicone resin (silicone resin) etc.), alkyd resins (alkyd resins, etc.), fluorine resins (polytetrafluoroethylene resins, etc.), nylon resins, polyester resins (polyester, etc.; excluding polyester fibers), polyamide resins (aramid resins, etc.), Examples include PET resins (polyethylene terephthalate, etc.), ether resins (polyphenylene ether resins, etc.), polyamine resins, amino resins (melamine resins, urea resins, etc.), phenol resins, and the like. Copolymer resins containing one or more of the above resins can also be employed. Moreover, an emulsion made of the above-mentioned resin can also be employed. These resins can be used alone or in combination of two or more. Among these, polyacrylic resins (acrylic resin, methacrylic resin, etc.) are preferred.

When a resin is contained in the odorous substance adsorbent of the present invention, the content of the resin is not particularly limited. The total amount of adsorbent is 100% by mass, preferably 0.1% by mass or more, more preferably 1.0% by mass or more, and even more preferably 5.0% by mass or more. Further, the content of the resin is preferably 95.0% by mass or less, more preferably 90.0% by mass or less, and even more preferably 85.0% by mass or less, from the viewpoints of economy, workability, etc. In addition, when employ|adopting an emulsion as resin, the above-mentioned content means content of solid content.

In the odorous substance adsorbent of the present invention, when an emulsion is employed as the synthetic resin, the content of the hydrazine compound is not particularly limited, and the deodorizing performance under non-heating and under heating, the deodorizing performance under non-heating and under heating, From the viewpoint of further improving speed, coloration suppression, heat resistance, and storage stability, the odorant adsorbent of the present invention is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, and 0.1% by mass, based on 100% by mass. % or more, and for example, 90.0% by mass or less is preferable, more preferably 50.0% by mass or less, and even more preferably 20.0% by mass or less.

In the odorous substance adsorbent of the present invention, when an emulsion is used as the synthetic resin, the content of the solvent is not particularly limited, and the deodorizing performance under non-heating and under heating, the deodorizing speed under non-heating and under heating. From the viewpoint of further improving coloration suppression, heat resistance, and storage stability, the odorant adsorbent of the present invention is preferably 30.0% by mass or more, more preferably 50.0% by mass or more, and 70.0% by mass, based on 100% by mass. The above is more preferable, and for example, 99.99% by mass or less is preferable, 99.95% by weight or less is more preferable, and even more preferably 99.0% by weight or less.

In the odor substance adsorbent of the invention, when an emulsion is used as the synthetic resin, the content of the inorganic porous material is not particularly limited, and the deodorizing performance under non-heating and under heating, and the deodorizing performance under non-heating and under heating From the viewpoint of further improving odor rate, coloration suppression, heat resistance, and storage stability, the odorant adsorbent of the present invention is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, and 1.0% by mass, based on 100% by mass. It is more preferably at least 99.0% by mass, more preferably at most 90.0% by mass, even more preferably at most 80.0% by mass.

Furthermore, it is also possible to use inorganic materials for processed products such as building materials other than resin. Examples of such inorganic materials for processed products such as building materials include cement, asphalt, concrete, plaster, mortar, diatomaceous earth, montmorillonite, beidellite, nontronite, saponite, hectorite, kaolinite, and ceramic.

When the odorous substance adsorbent of the present invention contains an inorganic material for processed products such as building materials, there is no particular restriction on the content of the inorganic material for processed products such as building materials, and the content of the inorganic material for processed products such as building materials is not particularly limited. From the viewpoint of deodorizing speed, the total amount of the odorous substance adsorbent of the present invention is 100% by mass, preferably 0.1% by mass or more, more preferably 1.0% by mass or more, and even more preferably 5.0% by mass or more. Further, the content of the inorganic material for processed products such as building materials is preferably 95.0% by mass or less, more preferably 90.0% by mass or less, and even more preferably 85.0% by mass or less from the viewpoints of economy, workability, etc.

The odor substance adsorbent of the present invention is generally formulated with known additives, such as non-volatile acids, chelating agents, antioxidants, light stabilizers, etc., depending on its purpose, use, etc. Various third components used in the above can be blended.

Preferred nonvolatile acids include succinic acid, fumaric acid, maleic acid, and boric acid, and salts of these acids can also be used. These nonvolatile acids can be used alone or in combination of two or more. By blending such a nonvolatile acid, the storage stability of the adsorbent can be further improved.

When a nonvolatile acid is used, its content is not particularly limited, and is preferably 1 to 10% by mass, based on 100% by mass of the total amount of the odorant adsorbent of the present invention.

Examples of the chelating agent include ethylenediaminetetraacetic acid, glycol etherdiaminetetraacetic acid, oxalic acid, and citric acid, and salts thereof can also be employed. These chelating agents can be used alone or in combination of two or more. By incorporating such a chelating agent, the storage stability of the adsorbent can be further improved.

When a chelating agent is used, its content is not particularly limited, and is preferably 1 to 10% by mass, based on 100% by mass of the total amount of the odorant adsorbent of the present invention.

Examples of the antioxidant include phenolic antioxidants, amine antioxidants, and the like. Specific examples of the phenolic antioxidant include 2,6-di-tert-butyl-4-methylphenol, 2,2'-methylenebis(4-methyl-6-tert-butylphenol), and the like. Further, specific examples of the amine antioxidant include alkyldiphenylamine, N,N'-di-sec-butyl-p-phenylenediamine, and the like. These antioxidants can be used alone or in combination of two or more.

When an antioxidant is used, its content is not particularly limited, and is preferably 1 to 10% by mass, based on 100% by mass of the total amount of the odorant adsorbent of the present invention.

Examples of the light stabilizer include hindered amine light stabilizers such as bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate. These light stabilizers can be used alone or in combination of two or more.

When using a light stabilizer, its content is not particularly limited, but is preferably 1 to 10% by mass, based on 100% by mass of the total amount of the odorant adsorbent of the present invention.

These third components can be used alone or in combination depending on the purpose.

The odor substance adsorbent of the present invention is used for industrial products in which all steps in the manufacturing process are carried out at temperatures below 130°C, and at least one step in the manufacturing process is carried out at temperatures above 130°C (all steps are carried out at temperatures above 130°C). It can be used for any purpose used in industrial products (including when it is carried out in a factory).

Specifically, in the case of applications for industrial products where the entire manufacturing process is performed at a temperature below 130°C, both the product temperature and the ambient temperature (dryer temperature, etc.) must be below 130°C during the entire manufacturing process. It is preferable that there be. The temperature at this time is preferably 120°C or lower, more preferably 110°C or lower, and even more preferably 100°C or higher, from the viewpoint of the deodorizing performance and deodorizing speed of the odorous substance adsorbent of the present invention. Further, the lower limit of the temperature when the odorous substance adsorbent of the present invention is used in industrial products in which all steps in the manufacturing process are performed at less than 130°C is not particularly limited, but may be set to 0°C, for example. In particular, room temperature is economical.

In addition, in the case of applications for industrial products where at least one step in the manufacturing process is performed at a temperature of 130°C or higher (including cases in which all steps are performed at a temperature of 130°C or higher), the product temperature must be ℃ or higher (including cases where the product temperature reaches 130℃ or higher in all processes), or if the ambient temperature (dryer temperature, etc.) is 130℃ or higher (atmospheric temperature in all processes is 130℃ or higher). (including cases). In addition, there are particular restrictions on the upper limit of the temperature when the odorous substance adsorbent of the present invention is used in industrial products in which at least one step in the manufacturing process is performed at 130°C or higher (including cases in which all steps are performed at 130°C or higher). However, it is preferable to set the temperature to a temperature that does not exceed the boiling point of the hydrazine compound or the organic solvent used, and a temperature that does not impair the quality of the application (building materials, etc.) in which the odor substance adsorbent of the present invention is used. From this point of view, the upper limit of the heating temperature is usually 1000°C. In addition, it is also possible to particularly improve the deodorizing performance by employing the hydrazine compound contained in the odorous substance adsorbent of the present invention for purposes of heating above its melting point.

Among these, when a protic organic solvent is used as an organic solvent with a boiling point of 200°C or higher, it is preferably used for industrial products where all steps in the manufacturing process are performed at lower than 130°C. However, when using glycerin and diglycerin among protic organic solvents, all steps in the manufacturing process are performed at temperatures below 130°C for use in industrial products, and at least one step in the manufacturing process is performed at temperatures above 130°C. It can be suitably used for both industrial products (including cases where all steps are carried out at 130°C or higher). In addition, if an aprotic organic solvent with a boiling point of 200°C or higher is used, at least one step in the manufacturing process is conducted at 130°C or higher (including cases where all steps are performed at 130°C or higher) for industrial products. It is preferable to use it for applications where it is used for.

Applications for industrial products that are manufactured at temperatures below 130°C include, for example, paints, adhesives, inks, sealants, paper products, binders, resin emulsions, pulp, wood materials, and wood products. , plastic products, films, textile products, filters, etc.

In addition, applications for industrial products in which at least one step in the manufacturing process is performed at 130°C or higher (including cases in which all steps are performed at 130°C or higher) include building materials (wallpaper, flooring, ceiling materials, handrails, etc.). etc.), heating plastics, textile products (kneaded type), filters, etc.

(1-5) Odorous substances The above-mentioned odorous substance adsorbent of the present invention can efficiently and quickly adsorb odorous substances (particularly aldehyde compounds, ketone compounds, and carboxylic acid compounds) without heating or under heating. . The odorous substance adsorbent of the present invention is effective against the above-mentioned odorous substances singly or in combination of two or more.

The odorous substances to be adsorbed by the odorous substance adsorbent of the present invention are not particularly limited, and examples thereof include formaldehyde, acetaldehyde, propionaldehyde, acrolein, n-butyraldehyde, isobutyraldehyde, pentanal, hexanal, heptanal, octanal, Aldehyde odorants (aldehyde compounds) such as nonenal, decanal, 3-methyl-butyraldehyde, crotonaldehyde, and 2,4-heptadienal; ketone odorants (ketones) such as acetone, methyl ethyl ketone, methyl isobutyl ketone, diethyl ketone, and diacetyl Compounds): Organic acid-based odorous substances (carboxylic acid compounds) such as formic acid, acetic acid, propionic acid, butyric acid, valeric acid, isovaleric acid, caproic acid, 3-methylbutanoic acid, and 4-methyloctanoic acid, among others. The odorant adsorbent of the present invention is effective in adsorbing aldehyde compounds, particularly formaldehyde and/or acetaldehyde.

2. Industrial product containing odorous substance adsorbent The odorous substance adsorbent of the present invention can be used by being included (blended) in an industrial product. The industrial product includes the present invention (industrial product of the present invention).

The above-mentioned industrial products refer to industrial products and industrial raw materials that are conventionally widely known. Specifically, construction materials (wallpaper, flooring materials, ceiling materials, handrails, etc.), heating plastics, filters, paints, adhesives, inks, sealants, paper products, binders, resin emulsions, pulp, wood materials, and wood products. , plastic products, films, textile products, etc.

The content of the odorous substance adsorbent of the present invention in the industrial product of the present invention is not particularly limited, and can be appropriately set depending on the industrial product and its intended use.

3. Method for adsorbing odorous substances using an odorous substance adsorbent The method for adsorbing odorous substances of the present invention involves bringing the odorous substances into contact with the odorous substance adsorbent of the present invention. Let it absorb. Specifically, an odorous substance is brought into contact with an industrial product comprising an odorous substance adsorbent of the present invention. In this case, when a protic organic solvent is used as the organic solvent with a boiling point of 200°C or higher, it is preferably used for industrial products in which all steps in the manufacturing process are performed at lower than 130°C. However, when glycerin and diglycerin are used among protic organic solvents, industrial products in which all steps in the manufacturing process are carried out at temperatures below 130°C and at least one step in the manufacturing process are carried out at temperatures above 130°C (all steps are carried out at temperatures above 130°C). It can be suitably used for both industrial products (including cases where the process is carried out at 130°C or higher). In addition, if an aprotic organic solvent with a boiling point of 200°C or higher is used, at least one step in the manufacturing process must be conducted at 130°C or higher (including cases where all steps are performed at 130°C or higher). Preferably used in products. According to the above-mentioned adsorption method, the odorous substance adsorbent of the present invention efficiently and quickly adsorbs the above-mentioned odorous substances, so that the above-mentioned odorous substances can be efficiently and quickly removed. For example, when a building material such as wallpaper containing the odorous substance adsorbent of the present invention is installed indoors, the above-mentioned odorous substance contained in the indoor air comes into contact with the building material such as wallpaper through the natural circulation of the indoor air. , adsorbed (deodorized).

Further, an adsorption device such as a fixed bed, a moving bed, or a fluidized bed is filled with the odorous substance adsorbent of the present invention or a filler coated with the odorous substance adsorbent of the present invention, and the gas containing the above-mentioned odorous substance is charged into the adsorption device. The aeration treatment also allows the above-mentioned odorous substances to be efficiently and quickly adsorbed and removed over a long period of time.

Hereinafter, the present invention will be specifically explained with reference to Examples. However, the present invention is not limited to the embodiments described below. The following hydrazine compounds and organic solvents were used.
Adipic acid dihydrazide (ADH): manufactured by Tokyo Chemical Industry Co., Ltd. Propylene glycol: manufactured by Fujifilm Wako Pure Chemical Industries, Ltd. (protic organic solvent; boiling point 188°C)
Dipropylene glycol: manufactured by Fujifilm Wako Pure Chemical Industries, Ltd. (protic organic solvent; boiling point 232°C)
Diisononyl adipate: manufactured by Fujifilm Wako Pure Chemical Industries, Ltd. (aprotic organic solvent; boiling point 250°C)
Polyethylene glycol 200: manufactured by Fujifilm Wako Pure Chemical Industries, Ltd. (protic organic solvent; boiling point 250°C)
Glycerin: manufactured by Fujifilm Wako Pure Chemical Industries, Ltd. (protic organic solvent; boiling point 290°C)
Diglycerin: manufactured by Fujifilm Wako Pure Chemical Industries, Ltd. (protic organic solvent; boiling point 265-290°C)
Bis(2-ethylhexyl) phthalate: Manufactured by Fujifilm Wako Pure Chemical Industries, Ltd. (aprotic organic solvent; boiling point 384°C)
Bisisononyl phthalate: Manufactured by Fuji Film Wako Pure Chemical Industries, Ltd. (aprotic organic solvent; boiling point 403°C).

Reference example 1: 1mL of water (immediately)
10 mg of adipic acid dihydrazide was added to 1 mL of water and dissolved in an ultrasonic bath to obtain an adsorbent (adsorption liquid).

1 mL of the obtained adsorbent (adsorption liquid) was applied to a glass filter paper (GA-200 manufactured by Advantech Toyo Co., Ltd.) 5 cm x 5 cm. The sample immediately after application was used as the deodorizing test sample (room temperature) of Reference Example 1.

Reference example 2: 1 mL of water (after drying)
10 mg of adipic acid dihydrazide was added to 1 mL of water and dissolved in an ultrasonic bath to obtain an adsorbent (adsorption liquid).

1 mL of the obtained adsorbent (adsorption liquid) was applied to a glass filter paper (GA-200 manufactured by Advantech Toyo Co., Ltd.) 5 cm x 5 cm. Next, it was air-dried at room temperature for 3 days to obtain a deodorization test sample (room temperature) of Comparative Example 2.

Further, the obtained deodorizing test sample (room temperature) was heated for 10 minutes in a dryer set at 200°C to obtain a deodorizing test sample (200°C) of Reference Example 2.

Comparative example 1: Propylene glycol 1mL
The same procedure was used as Comparative Example 2 except that 1 mL of propylene glycol was used instead of 1 mL of water and adipic acid dihydrazide was suspended in propylene glycol. 200℃) was obtained.

Example 1: 1 mL of dipropylene glycol
The adsorbent (absorbent liquid) of Example 1 was used in the same manner as Reference Example 2, except that 1 mL of dipropylene glycol was used instead of 1 mL of water, and adipic acid dihydrazide was suspended in dipropylene glycol. A sample (room temperature) and a sample for deodorization test (200°C) were obtained.

Example 2: 1 mL of diisononyl adipate
The adsorbent (adsorption liquid) of Example 2 was used for deodorization test in the same manner as Reference Example 2, except that 1 mL of diisononyl adipate was used instead of 1 mL of water, and adipic acid dihydrazide was suspended in diisononyl adipate. A sample (room temperature) and a sample for deodorization test (200°C) were obtained.

Example 3: Polyethylene glycol 200 1mL
The adsorbent (adsorption liquid) of Example 3 was used in the same manner as Reference Example 2, except that 1 mL of polyethylene glycol 200 was used instead of 1 mL of water, and adipic acid dihydrazide was suspended in polyethylene glycol 200. A sample (room temperature) and a sample for deodorization test (200°C) were obtained.

Example 4: 1 mL of glycerin
The adsorbent (adsorption liquid) of Example 4, the deodorizing test sample (room temperature), and the deodorizing test sample (200°C) were prepared in the same manner as Reference Example 2, except that 1 mL of glycerin was used instead of 1 mL of water. Obtained.

Example 5: 1 mL of bis(2-ethylhexyl) phthalate
The adsorption of Example 5 was carried out in the same manner as Reference Example 2, except that 1 mL of bis(2-ethylhexyl) phthalate was used instead of 1 mL of water, and adipic acid dihydrazide was suspended in bis(2-ethylhexyl) phthalate. A deodorizing agent (adsorption liquid), a deodorizing test sample (room temperature), and a deodorizing test sample (200°C) were obtained.

Example 6: 1 mL of bisisononyl phthalate
The adsorbent (absorbent liquid) of Example 6 was used in the same manner as Reference Example 2, except that 1 mL of bisisononyl phthalate was used instead of 1 mL of water, and adipic acid dihydrazide was suspended in bisisononyl phthalate. A sample (room temperature) and a sample for deodorization test (200°C) were obtained.

Test example 1 (acetaldehyde adsorption performance)
One unheated sample for deodorization test or one heated sample for deodorization test obtained in Examples 1 to 6, Reference Examples 1 to 2, and Comparative Example 1 was placed in a 1L sampling bag (Smart Bag PA, GL Sciences, Inc.) After sealing, the air inside the sampling bag was removed using a piston. Thereafter, 1 L of acetaldehyde gas adjusted to 14 ppm was injected, and the residual gas concentration after 2 hours and 24 hours was measured using a detection tube (Gastech Co., Ltd.) to evaluate the residual rate relative to the initial concentration. The results are shown in Table 1. For comparison, Table 1 also shows "natural reduction" in which no adsorbent is used.

Reference example 3: 1mL of water (immediately)
10 mg of adipic acid dihydrazide was added to 1 mL of water and dissolved in an ultrasonic bath to obtain an adsorbent (adsorption liquid). This adsorbent (adsorption liquid) has the same composition as Reference Example 1.

1 mL of the obtained adsorbent (adsorption liquid) was applied to a glass filter paper (GA-200 manufactured by Advantech Toyo Co., Ltd.) 5 cm x 5 cm. The sample immediately after application was used as the deodorizing test sample (room temperature) of Reference Example 3. This sample is the same deodorization test sample (room temperature) as Reference Example 1.

Reference example 4: 1 mL of water (after drying)
10 mg of adipic acid dihydrazide was added to 1 mL of water and dissolved in an ultrasonic bath to obtain an adsorbent (adsorption liquid). This adsorbent (adsorption liquid) has the same composition as Reference Example 2.

1 mL of the obtained adsorbent (adsorption liquid) was applied to a glass filter paper (GA-200 manufactured by Advantech Toyo Co., Ltd.) 5 cm x 5 cm. Next, it was air-dried at room temperature for 5 days to obtain a deodorization test sample (room temperature) of Reference Example 4.

In addition, 1 mL of the obtained adsorbent (adsorption liquid) was applied to a glass filter paper (GA-200 manufactured by Advantech Toyo Co., Ltd.). Next, it was heated in a dryer set at 40°C for 5 days to obtain a deodorizing test sample (40°C) of Reference Example 4.

Further, the obtained deodorizing test sample (room temperature) was heated for 10 minutes in a dryer set at 200°C to obtain a deodorizing test sample (200°C) of Reference Example 4.

Example 7: Glycerin 1mL
Same as Reference Example 4 except that 1 mL of glycerin was used instead of 1 mL of water. A sample for deodorization test (200°C) was obtained. This adsorbent (adsorption liquid) has the same composition as in Example 4.

Example 8: Glycerin 0.75mL
Same as Reference Example 4 except that 0.75 mL of glycerin was used instead of 1 mL of water. Adsorbent (adsorption liquid) of Example 8, deodorizing test sample (room temperature), deodorizing test sample (40°C) And a sample for deodorization test (200°C) was obtained.

Example 9: Glycerin 0.50mL
Same as Reference Example 4 except that 0.50 mL of glycerin was used instead of 1 mL of water. Adsorbent (adsorption liquid) of Example 9, deodorizing test sample (room temperature), deodorizing test sample (40°C) And a sample for deodorization test (200°C) was obtained.

Example 10: Glycerin 0.25mL
Same as Reference Example 4 except that 0.25 mL of glycerin was used instead of 1 mL of water. Adsorbent (adsorption liquid) of Example 10, deodorizing test sample (room temperature), deodorizing test sample (40°C) And a sample for deodorization test (200°C) was obtained.

Example 11: Glycerin 0.75mL Water 0.25mL
Same as Reference Example 4, except that 0.75 mL of glycerin and 0.25 mL of water were used instead of 1 mL of water. (40°C) and a sample for deodorization test (200°C) were obtained.

Example 12: Glycerin 0.50mL Water 0.50mL
Same as Reference Example 4 except that 0.50 mL of glycerin and 0.50 mL of water were used instead of 1 mL of water. (40°C) and a sample for deodorization test (200°C) were obtained.

Example 13: Glycerin 0.25mL Water 0.75mL
Same as Reference Example 4 except that 0.25 mL of glycerin and 0.75 mL of water were used instead of 1 mL of water. (40°C) and a sample for deodorization test (200°C) were obtained.

Example 14: Diglycerin 1mL
Same as Reference Example 4 except that 1 mL of diglycerin was used instead of 1 mL of water, the adsorbent (adsorption liquid) of Example 14, the deodorizing test sample (room temperature), the deodorizing test sample (40°C) And a sample for deodorization test (200°C) was obtained.

Test example 2 (acetaldehyde adsorption performance)
A deodorization test was conducted in the same manner as in Test Example 1 above. Specifically, one sheet of deodorizing test samples (room temperature), deodorizing test samples (40°C), or deodorizing test samples (200°C) obtained in Examples 7 to 14 and Reference Examples 3 to 4 was used. The sample was placed in a 1L sampling bag (Smart Bag PA, manufactured by GL Sciences, Inc.), and after sealing, the air inside the sampling bag was removed using a piston. Thereafter, 1 L of acetaldehyde gas adjusted to 14 ppm was injected, and the residual gas concentration after 2 hours and 24 hours was measured using a detection tube (Gastech Co., Ltd.) to evaluate the residual rate relative to the initial concentration. The results are shown in Table 2. For comparison, Table 2 also shows "natural reduction" in which no adsorbent is used.

Comparative example 2: Glycerin only
2 parts by mass of glycerin was added to 98 parts by mass of acrylic emulsion (Ultrasol C-63 manufactured by Aica Kogyo Co., Ltd.; adjusted to have a solid content of 10% by mass), dissolved in an ultrasonic bath, and compared. The adsorbent (adsorption liquid) of Example 2 was used.

The obtained adsorbent (adsorbent liquid) was wet applied to a thickness of 10 μm on a 20 cm × 21 cm foamed vinyl chloride (E-7001 white manufactured by Akrisande Co., Ltd.) using a bar coater, and air-dried overnight at room temperature. Then, by heating it for 10 minutes in a dryer set at 200°C, an odor substance adsorbent was formed on the foamed vinyl chloride, and this was used as a sample for deodorization test (200°C).

Reference Example 5: Instead of 2 parts by mass of organic solvent-free glycerin, 0.2 parts by mass of adipic acid dihydrazide, 0.2 parts by mass of dodecanedioic acid dihydrazide, and 1.6 parts by mass of silica (Mizukasorb C-6; gel method silica) were added. In the same manner as Comparative Example 2, an adsorbent (adsorption liquid) of Reference Example 5 and a deodorizing test sample (200°C) were obtained. In other words, in the adsorbent (adsorption liquid) and deodorizing test sample (200°C) of Reference Example 5, if the total amount of hydrazine compound, organic solvent, and inorganic porous material is 100% by mass, adipic acid dihydrazide is 10% by mass. , 10% by weight of dodecanedioic acid dihydrazide and 80% by weight of silica.

Example 15: Glycerin Instead of 2 parts by mass of glycerin, 0.2 parts by mass of adipic acid dihydrazide, 0.2 parts by mass of dodecanedioic acid dihydrazide, 0.2 parts by mass of glycerin, and 1.4 parts by mass of silica (Mizukasorb C-6; gel method silica) were added. Except for this, the adsorbent (adsorption liquid) of Example 15 and a sample for deodorization test (200° C.) were obtained in the same manner as in Comparative Example 2. In other words, in the adsorbent (adsorption liquid) and deodorizing test sample (200°C) of Example 15, if the total amount of the hydrazine compound, organic solvent, and inorganic porous material is 100% by mass, 10% by mass of adipic acid dihydrazide. , 10% by mass of dodecanedioic acid dihydrazide, 10% by mass of glycerin, and 70% by mass of silica.

Test example 3 (acetaldehyde adsorption performance)
One sample for the deodorization test was placed in a 3L sampling bag (Smart Bag PA, manufactured by GL Sciences, Inc.), and after sealing, the air inside the sampling bag was removed using a piston. After that, 3L of acetaldehyde gas adjusted to 14ppm was injected, and the residual gas concentration was measured after 10 minutes, 1 hour, 2 hours, 4 hours, and 24 hours using a detection tube (Gastech Co., Ltd.). evaluated. The results are shown in Table 3. In addition, in this Test Example 3, when compared with Test Examples 1 and 2, the content of the odorant adsorbent in the deodorization test sample was adjusted to be smaller.

As mentioned above, when water is used alone as a solvent, the deodorizing performance is excellent to a certain extent immediately after being applied to the base material, but when it is dried for a certain period of time afterwards, the deodorizing performance is Speed decreased significantly. On the other hand, when an organic solvent with a boiling point of 200°C or higher was used as the solvent, no extreme deterioration in deodorizing performance was observed even after drying for a certain period of time. The above effects were confirmed not only when the specific organic solvent was used alone, but also when it was used as a mixed solvent with water.

Claims (18)

Contains a hydrazine compound and a solvent,
The solvent contains at least an organic solvent with a boiling point of 200°C or higher (excluding polyethylene glycol) ,
Odor substance adsorbent. The odorous substance adsorbent according to claim 1, wherein the organic solvent is at least one selected from the group consisting of polyhydric alcohol, tripropylene glycol monobutyl ether, and polypropylene glycol . The odorous substance adsorbent according to claim 1 or 2, wherein the organic solvent is glycerin and/or diglycerin. The odorous substance adsorbent according to claim 2 or 3, which is used for industrial products in which all manufacturing steps are performed at a temperature below 130°C. The odorous substance adsorbent according to any one of claims 1 to 4, wherein the content of the organic solvent is 5% by mass or more when the total amount of the solvent is 100% by mass. Contains a hydrazine compound and a solvent,
The solvent contains at least an organic solvent with a boiling point of 200°C or higher, and the organic solvent contains at least one selected from the group consisting of glycerin, diglycerin, and an aprotic organic solvent.
Odor substance adsorbent. The odorous substance adsorbent according to claim 6, which is used for industrial products in which at least one step in the manufacturing process is performed at 130°C or higher. The odorous substance adsorbent according to claim 6 or 7, wherein the content of the organic solvent is 40% by mass or more, where the total amount of the solvent is 100% by mass. The hydrazine compound may include propionic acid hydrazide, lauric acid hydrazide, salicylic acid hydrazide, form hydrazide, acetohydrazide, p-hydroxybenzoic acid hydrazide, naphthoic acid hydrazide, 3-hydroxy-2-naphthoic acid hydrazide, benzhydrazide, carbodihydrazide, Acid dihydrazide, malonic acid dihydrazide, succinic acid dihydrazide, glutaric acid dihydrazide, adipic acid dihydrazide, azelaic acid dihydrazide, sebacic acid dihydrazide, dodecanedioic acid dihydrazide, maleic acid dihydrazide, fumaric acid dihydrazide, tartaric acid dihydrazide, malic acid dihydrazide, diglycolic acid Dihydrazide, isophthalic acid dihydrazide, terephthalic acid dihydrazide, 2,6-naphthalenedicarboxylic acid dihydrazide, 2,6-naphthoic acid dihydrazide, citric acid trihydrazide, pyromellitic acid trihydrazide, 1,2,4-benzenetricarboxylic acid trihydrazide, nitrilotrihydrazide Acetic acid trihydrazide, 1,3,5-cyclohexanetricarboxylic acid trihydrazide, ethylenediaminetetraacetic acid tetrahydrazide, 1,4,5,8-naphthoic acid tetrahydrazide, tert-butylhydrazine, isopropylhydrazine, butylhydrazine, benzylhydrazine, phenyl Hydrazine, 3-amino-1,2,4-triazole, 4-amino-1,2,4-triazole, 3-amino-5-phenyl-1,2,4-triazole, 4-aminourazole, and amino The odorous substance adsorbent according to any one of claims 1 to 8, which is at least one selected from the group consisting of guanidine. The odorous substance adsorbent according to any one of claims 1 to 9, further comprising an inorganic porous material. The odorous substance adsorbent according to claim 10, wherein the inorganic porous material is at least one selected from the group consisting of silicon-containing compounds, activated carbon, alumina, ceramics, and calcium carbonate. The odorous substance adsorbent according to any one of claims 1 to 11, wherein the odorous substance is at least one selected from the group consisting of aldehyde compounds, ketone compounds, and carboxylic acid compounds. An industrial product comprising the odorant adsorbent according to any one of claims 1 to 12. An industrial product comprising the odorant adsorbent according to any one of claims 1 to 5 and 9 to 12, wherein all steps of the manufacturing process are carried out at a temperature below 130°C. An industrial product comprising the odorant adsorbent according to any one of claims 6 to 12, wherein at least one step of the manufacturing process is performed at 130°C or higher. A method for adsorbing odorous substances, comprising the step of bringing an odorous substance into contact with the odorous substance adsorbent according to any one of claims 1 to 12. An odorous product comprising the step of bringing an odorous substance into contact with an industrial product comprising the odorous substance adsorbent according to any one of claims 1 to 5 and 9 to 12, the entire manufacturing process of which is carried out at a temperature below 130°C. Methods of adsorption of substances. A method for removing odorous substances, comprising the step of bringing an odorous substance into contact with an industrial product comprising the odorous substance adsorbent according to any one of claims 6 to 12, in which at least one step of the manufacturing process is carried out at 130°C or higher. Adsorption method.