JP7370800B2 - metal exterior material - Google Patents

metal exterior material Download PDF

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JP7370800B2
JP7370800B2 JP2019187608A JP2019187608A JP7370800B2 JP 7370800 B2 JP7370800 B2 JP 7370800B2 JP 2019187608 A JP2019187608 A JP 2019187608A JP 2019187608 A JP2019187608 A JP 2019187608A JP 7370800 B2 JP7370800 B2 JP 7370800B2
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metal
coating film
exterior material
fluororesin coating
metal exterior
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JP2021063353A (en
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松岡竜央
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IG Kogyo Co Ltd
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本発明は建築、構築物の外装を形成する金属製外装材に関するものである。 The present invention relates to a metal exterior material that forms the exterior of buildings and structures.

一般に、板材の化粧面にロールコーター、フローコーター、インクジェットプリンター等により加飾を施した外装材は数多く上市されている。(例えば、特許文献1参照)。 In general, there are many exterior materials on the market in which the decorative surface of a board is decorated using a roll coater, flow coater, inkjet printer, etc. (For example, see Patent Document 1).

特開2019-058877号公報Japanese Patent Application Publication No. 2019-058877

特許文献1は「被膜構成体の製造方法及び建築板」に係り、第一の被膜の表面に電磁波を照射した後に、第一の被膜の表面に水性塗料を塗布して第二の被膜を作製することで、被膜構成体を製造することが記載されている。 Patent Document 1 relates to a "method for manufacturing a film structure and a building board," and after irradiating the surface of a first film with electromagnetic waves, a water-based paint is applied to the surface of the first film to produce a second film. It is described that a coating structure is produced by:

しかしながら、特許文献1には、第一の被膜の表面に電磁波を照射した後に、前記第一の被膜の表面に水性塗料を塗布して第二の被膜を作製することが記載されているが、フッ素塗膜上に水性フッ素塗料を形成した際の親水性の向上を図る構成が記載されていない。 However, Patent Document 1 describes that after irradiating the surface of the first coating with electromagnetic waves, a water-based paint is applied to the surface of the first coating to produce a second coating. There is no description of a structure for improving hydrophilicity when a water-based fluorine paint is formed on a fluorine coat.

本発明はこのような欠点を解決するために、金属製表面材と裏面材間に芯材を形成し、金属性表面材の上下端部に雌雄連結構造を形成した横長で長尺状の金属製外装材において、金属製表面材は金属基材上に化成被膜、プライマーを介してフッ素樹脂塗膜を形成し、該フッ素樹脂塗膜は艶消し材と、顔料と、骨材とからなる表面凹凸を備え、該フッ素樹脂塗膜に対してコロナ放電を施し、該コロナ放電を施したフッ素樹脂塗膜上に、該フッ素樹脂塗膜表面に形成された凹凸を覆うようにして水性フッ素塗料を塗布および硬化させた塗膜を形成した金属製外装材を提供するものである。
In order to solve these drawbacks, the present invention provides a horizontally elongated metal material in which a core material is formed between the metal surface material and the back surface material, and a male and female connection structure is formed at the upper and lower ends of the metal surface material. In the case of exterior materials, the metal surface material forms a fluororesin coating film on the metal base material via a chemical conversion film and a primer, and the fluororesin coating film has a surface composed of a matte material, pigment, and aggregate. corona discharge is applied to the fluororesin coating film , and a water-based fluororesin paint is applied on the corona discharged fluororesin coating film so as to cover the irregularities formed on the surface of the fluororesin coating film. The present invention provides a metal exterior material having a coated and cured coating formed thereon.

本発明に係る金属製外装材によれば、フッ素樹脂塗装鋼板よりなる金属製表面材の表面のフッ素樹脂塗膜に対して、コロナ放電をすることにより、(1)フッ素樹脂塗膜の表面を一時的に不安定化(活性化)することにより、フッ素樹脂塗膜の表面を親水性化し、水性フッ素塗料を付着しやすく、かつ密着性も向上できる。(2)水性フッ素塗料にワックス剤を添加することにより摩擦係数を低下し、傷付きを防止できる。などの特徴、効果がある。
According to the metal exterior material according to the present invention, by applying corona discharge to the fluororesin coating film on the surface of the metal surface material made of a fluororesin-coated steel plate, (1) the surface of the fluororesin coating film is By temporarily destabilizing (activating) the surface of the fluororesin coating, it becomes hydrophilic, making it easier to attach the water-based fluororesin coating, and improving adhesion. (2) By adding a wax agent to the water-based fluorine paint, the coefficient of friction can be lowered and scratches can be prevented. It has the following characteristics and effects.

本発明に係る金属製外装材における金属製表面材の代表例を示す拡大端面図である。It is an enlarged end view showing a representative example of a metal surface material in a metal exterior material according to the present invention. 本発明に係る金属製外装材の代表例を示す断面図である。1 is a sectional view showing a representative example of a metal exterior material according to the present invention. 本発明に係る金属製外装材の施工状態を示す断面図である。FIG. 2 is a sectional view showing the construction state of the metal exterior material according to the present invention. 本発明に係る金属製外装材の代表例を示す部分拡大断面図である。FIG. 1 is a partially enlarged sectional view showing a representative example of a metal exterior material according to the present invention.

以下に図面を用いて、本発明に係る金属製外装材の一実施例について詳細に説明する。すなわち、図1(a)、(b)は本発明に係る金属製外装材Aの金属製表面材1の代表例を示す拡大端面図、図2は本発明に係る金属製外装材Aを示す断面図、図3は施工状態を示す断面図、図4は金属製外装材Aの代表例を示す部分拡大断面図であり、化粧面6部分省略して破線で示した断面図である。また、αは躯体、βは固定具、γは連結目地である。 An embodiment of the metal exterior material according to the present invention will be described in detail below with reference to the drawings. That is, FIGS. 1(a) and 1(b) are enlarged end views showing a representative example of the metal surface material 1 of the metal exterior material A according to the present invention, and FIG. 2 shows the metal exterior material A according to the present invention. 3 is a sectional view showing a construction state, and FIG. 4 is a partially enlarged sectional view showing a typical example of the metal exterior material A, in which 6 parts of the decorative surface are omitted and are shown by broken lines. Further, α is the building frame, β is the fixture, and γ is the connecting joint.

本発明に係る金属製外装材Aは図2に示すように、金属製表面材1と裏面材2で例えば合成樹脂発泡体からなる芯材3をサンドイッチした金属製外装材Aである。なお、図2~図4(a)、(b)においては、化粧面6部分の凹凸模様(エンボス模様)を省略して簡略化して示してある。 As shown in FIG. 2, the metal exterior material A according to the present invention is a metal exterior material A in which a core material 3 made of, for example, a synthetic resin foam is sandwiched between a metal surface material 1 and a back surface material 2. In addition, in FIGS. 2 to 4(a) and (b), the uneven pattern (embossed pattern) of the decorative surface 6 portion is omitted and shown in a simplified manner.

金属製表面材1と裏面材2は金属薄板、例えば鉄、アルミニウム、銅、ステンレス、チタン、アルミ・亜鉛合金メッキ鋼板、クラッド鋼板、サンドイッチ鋼板(制振鋼板等)等(勿論、これらを各種色調に塗装したカラー鋼板を含む)の一種をエンボスロール成形、あるいはプレス成形し、各種形状に加工したものである。また、裏面材2としてはアルミニウム蒸着紙、クラフト紙、アスファルトフェルト、金属箔(Al、Fe、Pb、Cu)、合成樹脂シート、ゴムシート、布シート、石膏紙、水酸化アルミ紙、ガラス繊維不織布等の1種、または2種以上をラミネートしたもの、あるいは防水処理、難燃処理されたシート状物からなるものでも良い。 The metal surface material 1 and the back surface material 2 are metal thin plates, such as iron, aluminum, copper, stainless steel, titanium, aluminum/zinc alloy plated steel plates, clad steel plates, sandwich steel plates (vibration damping steel plates, etc.) (of course, these can be made in various colors). (including painted colored steel sheets) is embossed roll-formed or press-formed and processed into various shapes. In addition, as the backing material 2, aluminum vapor-deposited paper, kraft paper, asphalt felt, metal foil (Al, Fe, Pb, Cu), synthetic resin sheet, rubber sheet, cloth sheet, gypsum paper, aluminum hydroxide paper, glass fiber nonwoven fabric It may also be a laminate of one or more of the above, or a sheet-like material treated with waterproofing or flame retardant treatment.

芯材3は例えばポリウレタンフォーム、ポリイソシアヌレートフォーム、フェノールフォーム、塩化ビニルフォーム、ポリエチレンフォーム、ポリスチレンフォーム、ユリアフォーム等、の合成樹脂発泡体からなるものであり、金属製表面材1、もしくは裏面材2の裏面側に合成樹脂発泡体の原液を吐出し、加熱して反応・発泡・硬化させて金属製表面材1と裏面材2を芯材3により一体に形成するものである。また、芯材3中には各種難燃材として軽量骨材(パーライト粒、ガラスビーズ、石膏スラグ、タルク石、シラスバルーン、水酸化アルミニウム等)、繊維状物(グラスウール、ロックウール、カーボン繊維、グラファイト等)を混在させ、耐火性、防火性を向上させることもできる。 The core material 3 is made of synthetic resin foam such as polyurethane foam, polyisocyanurate foam, phenol foam, vinyl chloride foam, polyethylene foam, polystyrene foam, urea foam, etc., and is made of a metal surface material 1 or back material. A synthetic resin foam stock solution is discharged onto the back side of the metal sheet 2 and heated to cause reaction, foaming, and hardening, thereby integrally forming the metal surface material 1 and the back surface material 2 using the core material 3. In addition, the core material 3 contains various flame retardant materials such as lightweight aggregates (perlite grains, glass beads, gypsum slag, talcum stone, shirasu balloons, aluminum hydroxide, etc.), fibrous materials (glass wool, rock wool, carbon fiber, Graphite, etc.) can also be mixed to improve fire resistance and fire prevention properties.

金属製外装材A同士は、係合片10が嵌合溝16へ、係合溝11には嵌合片14が連結されることにより、図3に示すように連結されるものである。勿論、図では横張りにて形成しているが、横方向に施工することにより縦張りに形成することもできる。 The metal exterior materials A are connected to each other as shown in FIG. 3 by connecting the engaging pieces 10 to the fitting grooves 16 and the fitting pieces 14 to the engaging grooves 11. Of course, in the figure, it is formed horizontally, but it can also be formed vertically by performing construction in the horizontal direction.

金属製外装材Aの全体形状の一例としては図2~図4(a)、(b)に示すように、長尺で金属製の薄板からなる金属製表面材1と裏面材2間に芯材3をサンドイッチし、幅方向の一端に形成した雄型連結部4、他端に形成した雌型連結部5とから形成し、化粧面6の下端には側壁7、上端には側壁8を形成したものである。 As an example of the overall shape of the metal exterior material A, as shown in FIGS. 2 to 4(a) and (b), there is a core between the metal surface material 1 and the back surface material 2 made of long thin metal plates. The material 3 is sandwiched, and a male connecting portion 4 is formed at one end in the width direction, and a female connecting portion 5 is formed at the other end. It was formed.

さらに詳説すると、雄型連結部4は化粧面6下端を裏面側に屈曲した側壁7と、側壁7の先端を上方へ突出した上面9と、上面9の先端を下方に屈曲した係合片10と、上面9と係合片10とからなる係合溝11とから形成したものである。 More specifically, the male connecting portion 4 includes a side wall 7 with the lower end of the decorative surface 6 bent toward the back side, an upper surface 9 with the tip of the side wall 7 projecting upward, and an engaging piece 10 with the tip of the upper surface 9 bent downward. and an engagement groove 11 consisting of an upper surface 9 and an engagement piece 10.

雌型連結部5は化粧面6の上端を裏面側に屈曲した側壁8と、側壁8の先端を上方に屈曲した目地底面12と、目地底面12の先端を折り返し下方に突出した下面13と、目地底面12と下面13とからなる嵌合片14と、下面13の先端を上方に屈曲して突出した固定面15と、下面13と固定面15とから形成した嵌合溝16とから形成したものである。なお、Pは防水性強化のために形成したパッキンである。 The female connecting portion 5 includes a side wall 8 with the upper end of the decorative surface 6 bent toward the back side, a joint bottom surface 12 with the tip of the side wall 8 bent upward, and a lower surface 13 with the tip of the joint bottom surface 12 folded back and protruding downward. It is formed from a fitting piece 14 consisting of a joint bottom surface 12 and a lower surface 13, a fixing surface 15 that protrudes by bending the tip of the lower surface 13 upward, and a fitting groove 16 formed from the lower surface 13 and the fixing surface 15. It is something. Note that P is a packing formed to enhance waterproofness.

化粧面6は、図1(a)、(b)に金属製表面材1の端面を示すようにフッ素樹脂を金属製基材1a上に化成被膜、プライマーを介してフッ素樹脂塗膜1bを形成したフッ素樹脂塗装鋼板(プレコート鋼板)よりなる金属製表面材1である。 The decorative surface 6 is formed by forming a fluororesin coating film 1b on a metal base material 1a via a chemical conversion coating and a primer, as shown in FIGS. This is a metal surface material 1 made of a fluororesin-coated steel plate (pre-coated steel plate).

また、フッ素樹脂塗膜1bには艶消し材1c、顔料1d、骨材1eを形成するために微細な凹凸が形成されている。 Further, fine irregularities are formed on the fluororesin coating film 1b in order to form a matte material 1c, a pigment 1d, and an aggregate 1e.

フッ素樹脂塗装鋼板Bの表面に対し、水性フッ素塗料Dを加飾塗料として形成するには密着性が弱いという大きな欠点があった。これはフッ素樹脂塗装鋼板Bの表面は安定してしかも撥水性のために水性塗料は弾かれ、かつ密着性が弱いという性質があった。 When the water-based fluorine paint D was applied as a decorative paint to the surface of the fluororesin-coated steel plate B, there was a major drawback in that the adhesion was weak. This is because the surface of the fluororesin-coated steel plate B is stable and water-repellent, so water-based paints are repelled and the adhesion is weak.

そこで、本願発明の金属製外装材Aにおいて、図1(a)に示すようにフッ素樹脂塗装鋼板Bよりなる金属製表面材1の表面のフッ素樹脂塗膜1bに対してコロナ放電Cを施すことにより、フッ素樹脂塗膜1bの表面を一時的に不安定化(活性化)することによりフッ素樹脂塗膜1bを親水性化し、水性フッ素塗料Dを付着しやすく、かつ密着性も向上した。勿論、最後には乾燥・焼き付け・硬化工程を経て接着一体化するものである。 Therefore, in the metal exterior material A of the present invention, as shown in FIG. By temporarily destabilizing (activating) the surface of the fluororesin coating film 1b, the fluororesin coating film 1b was made hydrophilic, making it easier to adhere the water-based fluororesin paint D, and improving adhesion. Of course, the final step is to go through a drying, baking, and curing process to bond and integrate them.

コロナ放電C(局部破壊放電)は尖った電極(針電極)の周りに不均一な電界が生じることにより起こる持続的な放電の総称であり、この際、針電極周辺に認められる発光部をコロナと呼ぶ。コロナ放電Cによって流れる電流は小さく、数μA程度である。 Corona discharge C (local destructive discharge) is a general term for continuous discharge that occurs due to the generation of a non-uniform electric field around a sharp electrode (needle electrode). It is called. The current flowing due to the corona discharge C is small, on the order of several μA.

その他の実施例としては、水性フッ素塗料Dにワックス剤を添加することにより摩擦係数を低下し、傷付きを防止できる金属製外装材Aとなる。 As another example, by adding a wax agent to the water-based fluorine paint D, the coefficient of friction is reduced, resulting in a metal exterior material A that can prevent scratches.

また、水性フッ素塗料Dに乾燥助剤を添加することにより乾燥時間を短縮すると共に、乾燥させて水分を蒸発させることにより密着性を向上できる金属製外装材Aとなる。 Further, by adding a drying aid to the water-based fluorine paint D, the drying time can be shortened, and the metal exterior material A can improve adhesion by drying and evaporating water.

さらに、図1(b)に示すように、化粧面6の艶消し材1c、顔料1d、骨材1eの微細な凹凸を利用し、凸と凸間に水性フッ素塗料Dを塗り込むと、傷の原因となる物体の摩擦は凸の上部に接触するものの、凸と凸の間にある塗料を傷付ける確率は少なくなる。この効果により凸の上部には傷が付くものの、殆どの部分には傷が付かない状態になる。この方法はロールコーター塗装に適している。 Furthermore, as shown in FIG. 1(b), if the fine unevenness of the matte material 1c, pigment 1d, and aggregate 1e on the decorative surface 6 is applied, and the water-based fluorine paint D is applied between the protrusions, it will cause scratches. Although the friction of the object that causes this comes into contact with the top of the convexity, the probability of damaging the paint between the convexities is reduced. Due to this effect, although the upper part of the convexity is scratched, most of the parts are not scratched. This method is suitable for roll coater painting.

α 躯体
β 固定具
γ 連結目地
A 金属製外装材
B フッ素樹脂塗装鋼板
C コロナ放電
D 水性フッ素塗料
P パッキン
1 金属製表面材
1a 金属製基材
1b フッ素樹脂塗膜
1c 艶消し材
1d 顔料
1e 骨材
2 裏面材
3 芯材
4 雄型連結部
5 雌型連結部
6 化粧面
7 側壁
8 側壁
9 上面
10 係合片
11 係合溝
12 目地底面
13 下面
14 嵌合片
15 固定面
16 嵌合溝
α Building block β Fixing device γ Connection joint A Metal exterior material B Fluorine resin coated steel plate C Corona discharge D Water-based fluorine paint P Packing 1 Metal surface material 1a Metal base material 1b Fluorine resin coating 1c Matte material 1d Pigment 1e Bone Material 2 Back material 3 Core material 4 Male connecting portion 5 Female connecting portion 6 Decorative surface 7 Side wall 8 Side wall 9 Top surface 10 Engagement piece 11 Engagement groove 12 Joint bottom surface 13 Bottom surface 14 Fitting piece 15 Fixed surface 16 Fitting groove

Claims (2)

金属製表面材と裏面材間に芯材を形成し、金属性表面材の上下端部に雌雄連結構造を形成した横長で長尺状の金属製外装材において、金属製表面材は金属基材上に化成被膜、プライマーを介してフッ素樹脂塗膜を形成し、該フッ素樹脂塗膜は艶消し材と、顔料と、骨材とからなる表面凹凸を備え、該フッ素樹脂塗膜に対してコロナ放電を施し、該コロナ放電を施したフッ素樹脂塗膜上に、該フッ素樹脂塗膜表面に形成された凹凸を覆うようにして水性フッ素塗料を塗布および硬化させた塗膜を形成したことを特徴とする金属製外装材。 In a horizontally long metal exterior material in which a core material is formed between a metal surface material and a back surface material, and a male and female connection structure is formed at the upper and lower ends of the metal surface material, the metal surface material is a metal base material. A fluororesin coating film is formed on top via a chemical conversion coating and a primer, and the fluororesin coating film has a surface unevenness made of a matte material, pigment, and aggregate, and corona is applied to the fluororesin coating film. A water-based fluorine paint is applied and cured to cover the unevenness formed on the surface of the fluororesin coating film, and a coating film is formed on the fluororesin coating film subjected to the corona discharge. Metal exterior material. 前記水性フッ素塗料にワックス剤を添加したことを特徴とする請求項1に記載の金属製外装材。
The metal exterior material according to claim 1, wherein a wax agent is added to the water-based fluorine paint.
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