JP7156466B2 - Ceramic scintillator for photon-counting radiation detector and method for manufacturing fluorescent material for photon-counting radiation detector - Google Patents

Description

The present disclosure relates to perovskite-type ceramic fluorescent materials having compositions comprising yttrium and aluminum, ceramic scintillators and radiation detectors, and methods of making ceramic fluorescent materials.

A radiation imaging system irradiates an object with radiation such as α-rays, β-rays, γ-rays, and X-rays, and forms an image of the radiation transmitted through the object. Radiation imaging systems are used in a variety of application fields, such as medical fields such as tomography, industrial fields such as non-destructive inspection, security fields such as baggage inspection, and academic fields such as high energy physics.

Radiographic imaging systems, currently in primary commercial use, employ radiation detectors that convert the intensity of radiation into electrical signals. The radiation detector includes a scintillator for converting radiation intensity into light and a photodetector such as a CCD for converting light into an electrical signal.

2. Description of the Related Art In various fields, there is a demand for radiographic imaging systems that can acquire images with higher definition and with a lower radiation dose. As such a radiographic imaging system, for example, as disclosed in Patent Document 1, a photon-counting radiation detector that detects radiation using a photon counter capable of counting the number of photons has been studied. there is

Japanese Unexamined Patent Application Publication No. 2012-34901

The X-ray CT apparatus disclosed in Patent Document 1 uses a CdTe scintillator as a radiation detector. CdTe scintillators are relatively expensive and toxic. In addition, since it is not easy to obtain a large CdTe single crystal, it is difficult to increase the radiation detection surface.

In view of such problems, the present disclosure provides a ceramic fluorescent material that can be used for a photon-counting radiation detector, a ceramic scintillator and a radiation detector, and a method for manufacturing the ceramic fluorescent material.

The ceramic fluorescent material of the present disclosure includes a main component having a composition represented by Ce _x (Y _1-y Lu _y ) _1-x AlO ₃ , wherein x and y are 0.001≦x<1, 0≦ It satisfies y≦1.

The main component has a perovskite structure and is a phosphor containing Ce as a light-emitting element. Less than atomic %, 0 atomic % or more and 49.95 atomic % or less of Y, 0 atomic % or more and 49.5 atomic % or less of Lu, and the total of Ce, Y and Lu is 50 atomic %, and Al is 50 atomic % may be included in the proportion of

The ceramic fluorescent material may contain the main component at a rate of 95% by mass or more.

The x may satisfy 0.006≦x<1.

The x may satisfy 0.01≦x≦0.1.

The y may satisfy 0<y<0.5.

The y may satisfy 0.0003≦y≦0.01.

The y may satisfy 0.4≦y≦0.6.

The ceramic fluorescent material may include a CeO ₂ phase as a heterophase, and an area ratio of the CeO ₂ phase in a BSE image of a cross section of the ceramic fluorescent material may be 0.5% or less.

A ceramic scintillator of the present disclosure includes any of the ceramic fluorescent materials described above and has a relative density of 99% or more.

A radiation detector of the present disclosure includes the ceramic scintillator and a photoelectric conversion element that converts light into an electrical signal, current value, or voltage value.

The method for producing the ceramic fluorescent material of the present disclosure is such that the composition after firing is Ce _x (Y _1-y Lu _y ) _1-x AlO ₃ (0.001≦x<1, 0≦y≦1). a step of preparing raw materials containing Ce, Al, Y, and Lu respectively; a step of mixing and pulverizing the raw materials to obtain a raw material powder; molding the raw material powder to form a compact; and sintering the compact at a temperature of 1600° C. to 1800° C. in a reducing atmosphere.

According to the present disclosure, a ceramic fluorescent material that has a small fluorescence decay time constant and that can be used in a photon-counting radiation detector, and a method for manufacturing the ceramic fluorescent material are provided. Also, a ceramic scintillator and a radiation detector containing a ceramic fluorescent material having such characteristics and capable of being made large can be obtained.

FIG. 2 is an experimental example for determining the decay time constant τ of a ceramic fluorescent material having a composition represented by Ce _x Y _1-y AlO ₃ , showing the relationship between the amount of Ce x and the decay time constant τ of fluorescence. Fig. 1 shows an experimental example of determining the decay time constant τ of a ceramic fluorescent material having a composition represented by _Ce0.03 (Y1 _- yLuy) _{0.97AlO3 ,} showing the relationship between the Lu amount _y and the decay time constant τ of fluorescence. It is a diagram. (a) and (b) are diagrams showing powder X-ray diffraction spectra of ceramic fluorescent materials of experimental examples. (a), (b) and (c) are BSE images of a ceramic fluorescent material fired in an oxygen atmosphere, a ceramic material fired in an air atmosphere, and a ceramic fluorescent material of an experimental example. (a), (b) and (c) are diagrams obtained by performing elemental mapping of Ce on the same regions as in FIGS. 4 (a), (b) and (c). (a), (b) and (c) are diagrams obtained by image processing the BSE images shown in FIGS. 5 (a), (b) and (c).

The inventors of the present application have studied the physical properties required for fluorescent materials and ceramic scintillators that can be used in photon counting radiation detectors, and have studied in detail the compositions of fluorescent materials that can achieve these physical properties.

A conventional intensity-integrating radiation detector irradiates an object with radiation at predetermined time intervals on the order of microseconds to milliseconds (this time interval is called one frame), and the radiation that has passed through the object is incident. Fluorescence emitted from the scintillator is detected by a photodetector and converted into an electrical signal. Radiation is applied to the object for a period shorter than the predetermined time interval described above.

The fluorescent material of the scintillator emits strong fluorescence when irradiated with radiation, but the fluorescence does not become zero immediately after the radiation irradiation is stopped, and the weak fluorescence continues. This is called afterglow. The afterglow is defined by I _r /I ₀ (ppm) using, for example, the emission intensity I ₀ during irradiation and the emission intensity I _r after a certain period of time has passed since the irradiation was stopped. The constant time is selected on the order of milliseconds (ms) in consideration of the signal processing speed from the photodetector, exposure of the object to radiation, and the like.

In order to reduce the effects of noise, etc., the radiographic imaging system subtracts the electrical signal obtained from the radiation detector when the radiation is stopped from the electrical signal obtained from the radiation detector when the radiation is irradiated in each frame. The signal is processed as the intensity of the detected radiation. Therefore, when the afterglow is large, the detected radiation intensity becomes relatively small. For this reason, it is preferable that the afterglow of the fluorescent material is small in the conventional intensity-integrating radiation detector.

Photon-counting radiation detectors, on the other hand, are equipped with photomultiplier tubes, multi-pixel photon counters (silicon photomultipliers), etc. that can measure the number of photons emitted by fluorescent materials in an extremely short period of time. , the number of photons is read out as a pulse signal. In a photon-counting radiation detector, since reading is performed by setting a certain threshold for the emission intensity, the emission intensity of the fluorescent material need not be as high as that required for the conventional intensity-integrating radiation detector described above. . Even if afterglow occurs, if the intensity of the afterglow is equal to or less than the above-described threshold value, the afterglow is not detected. Therefore, the presence or absence of afterglow does not significantly affect the detection of light emission.

On the other hand, in radiographic imaging systems equipped with photon-counting radiation detectors, since the number of emitted light is proportional to the intensity of the radiation, if the fluorescence decay time is long, the emitted light will overlap and the correct number of emitted light cannot be detected. . For this reason, scintillators and fluorescent materials used in photon-counting radiation detectors require that the fluorescence decays in a very short time. A characteristic that attenuates up to As described above, a fluorescent material suitable for use in a photon-counting radiation detector is required to have completely different properties from fluorescent materials for conventional radiation detectors.

The decay time of fluorescence in fluorescent materials mainly depends on the light-emitting element. The inventor of the present application paid attention to Ce as a light-emitting element having a short decay time of fluorescence, and studied a fluorescent material capable of containing Ce as a light-emitting element. As a result, by using YAlO ₃ , that is, yttrium aluminum perovskite (hereinafter sometimes abbreviated as YAP) as a base material and containing Ce at a high concentration, it is possible to realize a fluorescent material with a short fluorescence decay time. Do you get it.

YAP is known as a scintillator for positron emission tomography (hereinafter sometimes abbreviated as PET). However, in PET, it is important to be able to sufficiently attenuate γ-rays. For this reason, a single-crystal YAP containing a heavy element and having a high density is used. According to detailed studies by the inventors of the present application, the amount of Ce that can be added to a single crystal is small, and if the amount of Ce added is increased, Ce is liberated, making it difficult to obtain a single crystal. Based on such findings, the inventor has conceived of a novel ceramic fluorescent material, a ceramic scintillator and radiation detector, and a method for producing the ceramic fluorescent material. The ceramic fluorescent material, the ceramic scintillator and radiation detector, and the method of manufacturing the ceramic fluorescent material of the present disclosure are described in detail below.

(Composition and physical properties of fluorescent material)
The ceramic fluorescent material of the present disclosure includes a main component having a composition represented by the general formula (hereinafter referred to as general formula (1)): Ce _x (Y _1-y Lu _y ) _1-x AlO ₃ . x and y respectively satisfy the following ranges.
0.001≤x<1
0≤y≤1

That is, the main components are 0.05 atomic % or more and less than 50 atomic % of Ce, 0 atomic % or more and 49.95 atomic % or less of Y, and 0 atomic % of Lu with respect to the total amount of Ce, Y, Lu and Al. It contains at least 49.5 atomic % or less, and the total of Ce, Y and Lu is 50 atomic %, and Al is 50 atomic %.

In the above general formula (1), Ce functions as a light-emitting ion. One of the features of the ceramic fluorescent material of the present disclosure is that the material having the composition represented by the above general formula (1) is used for the scintillator as a polycrystalline ceramic instead of a single crystal. By being polycrystalline, more Ce can be dissolved in YAP than in the case of single crystal. As will be described later, the higher the Ce concentration, the shorter the fluorescence decay time. In the present disclosure, the fluorescence decay time of the ceramic fluorescent material is evaluated by the fluorescence decay time constant τ. The decay time constant τ is 1/e (=0 .3679). More specifically, for example, when a pulse X-ray tube is used to generate X-rays at a tube voltage of 30 kV and the fluorescent material is irradiated with X-rays, the emission intensity is 1/e is defined as the decay time constant τ. Since the unit of the attenuation time constant is time, it is nanoseconds (ns) instead of the intensity ratio (ppm) as in afterglow.

Afterglow in fluorescent materials is generally related to the number of defects in the fluorescent material. On the other hand, the decay time constant τ is related to the transition of electrons caused by the excitation of the light-emitting element by the energy source, and the decay time constant τ may differ depending on the type of energy source such as X-rays, ultraviolet rays, and gamma rays. .

x indicating the amount of Ce in the general formula (1) satisfies 0.001≦x<1. When x is 0.001 or more, the attenuation time constant τ can be made about 35 ns or less. This decay time constant τ is a value that is difficult to achieve in single crystal YAP even if Ce is added. As the amount of Ce increases, the decay time constant τ also shortens. When x is 0.006 or more, the decay time constant τ is about 20 ns or less, which is preferable. Further, if x is 0.01 or more, the attenuation time constant τ is about 15 ns or less, which is more preferable.

From the viewpoint of shortening the decay time constant τ, there is no upper limit to the amount of Ce, and x may be less than 1. However, when the amount of Ce increases, it becomes difficult to obtain a ceramic fluorescent material that is a uniform ceramic body. Therefore, x is preferably 0.1 or less from the viewpoint of ease of manufacture.

y, which indicates the amount of Lu, is related to the amount of light emission and satisfies 0≦y≦1. In order to increase the light emission amount, y preferably satisfies 0.4≦y≦0.6. However, since the photon-counting radiation detector can detect photons with high sensitivity, the photon-counting radiation detector may be realized even if the emission intensity is not high. In this case, the amount of Lu can be determined from other viewpoints, such as ease of manufacture and effective atomic number. Since Lu has a higher melting point than Y, the melting point of YAP ceramics increases as the amount of Lu increases, making it difficult to obtain dense ceramics. From the viewpoint of obtaining a transparent ceramic that transmits light, the smaller the amount of Lu, the better. For example, y preferably satisfies 0<y<0.5.

The density of the ceramic fluorescent material of the present disclosure is preferably 99% or higher in the relative density evaluation described below. The calculation method of relative density is as follows. First, in the general formula (1), when x = 0 and y = 0 (composition formula: YAlO ₃ ), the lattice constant is quoted from ICDD (International Center for Diffraction Data) data, and the volume is calculated based on it. do. Next, the formula weight is calculated as the mass from the composition formula of the sample whose relative density is to be calculated. Then, the density obtained from the volume and the formula weight is defined as the theoretical density. Next, the measured density of the fluorescent material is measured and divided by the theoretical density to calculate the relative density. If the relative density is low, light will not be transmitted, so the relative density is preferably 99% or more.

The ceramic fluorescent material of the present disclosure preferably contains 95% by mass or more of the main component described above. The ceramic fluorescent material may contain unreacted raw materials, by-products, unavoidable impurities, etc. in a proportion of less than 0.5% by mass, in addition to the main component. For example, the ceramic fluorescent material may contain the raw material cerium oxide (CeO ₂ ) as a heterophase. When the ceramic fluorescent material contains cerium oxide as a heterophase, it may be difficult to distinguish between the main component, that is, Ce dissolved in the main phase and Ce present in the heterophase by elemental analysis or the like. In this case, by observing a cross-section of the ceramic fluorescent material, the proportion of hetero-phases can be assessed. The area ratio of the CeO ₂ phase in the cross-sectional BSE image of the ceramic fluorescent material of the present disclosure is preferably 0.5% or less. Here, observation of the cross section is performed at a magnification of 1000 times to 5000 times.

(Manufacturing method of fluorescent material)
An example of a method for manufacturing a fluorescent material according to the present disclosure will be described. First, raw materials containing Ce, Al, Y and Lu are prepared after sintering in a ratio represented by the general formula (1). That is, in the manufacturing process, for example, in the pulverization process of raw materials, if Al ₂ O ₃ is mixed from media or the like, the amount of Al is subtracted from the ratio represented by general formula (1) by the amount of the mixture. Prepare raw materials for Specifically, raw materials such as oxides or carbonates of Ce _, Al, Y, and Lu _are prepared, and the composition ratio represented by the general formula (1) and Weigh the raw materials so that Next, if necessary, a solvent is added to the weighed raw material, and the mixture is mixed and pulverized by a ball mill or the like. A raw material powder is obtained by drying the mixture. A compact is obtained by granulating raw material powder with a suitable sieve and press-molding. After that, the compact is sintered by holding it in a reducing atmosphere at a temperature of 1600° C. to 1800° C. for 0.5 to 12 hours. Thereby, a polycrystalline ceramic fluorescent material is obtained. The reducing atmosphere means, for example, nitrogen gas to which hydrogen is added.

In the ceramic fluorescent material having the composition represented by the general formula ( ₁ ), Ce is considered to exist in a trivalent form, but the raw material containing Ce that is generally readily available is CeO2. Medium Ce exists in the tetravalent state. Therefore, in order to introduce Ce into YAP, it is necessary to reduce Ce, and it is preferable to sinter the raw material in a reducing atmosphere. This makes it possible to introduce Ce into YAP at a high concentration.

In addition to the manufacturing method described above, the ceramic fluorescent material of the present disclosure can also be manufactured by an inorganic salt method or the like.

Since the ceramic fluorescent material of the present disclosure can be produced by a process similar to that of general ceramics, it is a fluorescent material with excellent productivity at low cost, and it is relatively easy to manufacture a large-area ceramic scintillator. It is possible to fabricate Therefore, by using the ceramic scintillator of the present disclosure, unlike a single crystal scintillator, by arranging a large amount of fluorescent material or processing a large-area ceramic scintillator, a radiation detector with a large radiation detection surface can be easily manufactured. Obtainable.

(Embodiment using fluorescent material)
[Ceramic scintillator]
The resulting polycrystalline ceramic fluorescent material is cut into plates of appropriate thickness by, for example, an inner circumference slicer, and held in an oxygen atmosphere at a temperature of, for example, 1250° C. to 1350° C. for 0.5 to 12 hours. heat treatment by A ceramic scintillator is then obtained by subjecting the surface to optical polishing. When the fluorescent material obtained by sintering has a desired shape, it is possible to obtain a ceramic scintillator by applying the heat treatment and optical polishing described above.

[Radiation detector]
A radiation detector can be configured by combining the ceramic scintillator of the present disclosure with a photomultiplier tube capable of measuring light with high sensitivity or a photodetector such as a multi-pixel photon counter (silicon photomultiplier). can. For example, the radiation detector includes a photomultiplier tube, a multi-pixel photon counter, or other photodetector having a light-receiving surface, and a ceramic scintillator disposed on the light-receiving surface of the photodetector. The ceramic scintillator of the present disclosure described above can be used as the ceramic scintillator. The photodetector is preferably sensitive to light and capable of measuring very short light emissions. More preferably, it has detection sensitivity in the wavelength range of about 530 nm or more and about 600 nm or less. As described above, the decay time constant of fluorescence in the fluorescent material constituting the scintillator of the present invention is small. For this reason, it is possible to detect radiation in combination with a photodetector with high time resolution, and it can be suitably combined with a photomultiplier tube capable of measuring the number of photons, a multi-pixel photon counter, etc. is.

(Example)
[Experimental example 1]
Fluorescent materials with various compositions were prepared and the results of examining their characteristics will be described.

Y ₂ O ₃ (purity 5N), CeO ₂ (purity 4N), and Al ₂ O ₃ (purity 5N) were prepared as raw materials, and samples 1 to 6 in Table 1 below were prepared so that the total weight was 200 g. Raw materials were weighed at the indicated ratios (element ratios). However, Al ₂ O ₃ is mixed from alumina balls used as media in the pulverization process, and is added to the raw material Al ₂ O ₃ for obtaining the ceramic fluorescent material of general formula (1). Therefore, in general formula (1), raw materials were weighed so that the ratio of the sum of Ce and Y to Al was 1:0.98 instead of 1:1.

Into a polypropylene pot with a capacity of 1 L, the weighed raw material of each sample, 1250 g of Al ₂ O ₃ balls with a diameter of 5 mm, and 200 mL of ethanol were put, and the pot was rotated at 100 rpm for 40 hours. , the raw materials were mixed and pulverized. The raw material was collected in an alumina container, and heated together with the container at 120° C. by a hot plate to evaporate the ethanol and dry the raw material. After that, the raw material was pulverized with an alumina mortar and passed through a sieve with an opening of 500 μm.

The raw material was placed in a mold, and a pressure of 30 MPa was applied to the mold using a uniaxial pressure molding machine to obtain a powder compact. After vacuum-sealing this molded body in a vinyl bag, a pressure of 294 MPa was applied using a cold isostatic pressing device to further press and harden.

The molded body was heat-treated (fired) at 1700° C. for 6 hours in a nitrogen atmosphere containing 2% hydrogen to obtain ceramic fluorescent materials of Samples 1 to 6.

[Experimental example 2]
As raw materials, Lu ₂ O ₃ (purity 5N), Y ₂ O ₃ (purity 5N), CeO ₂ (purity 4N), and Al ₂ O ₃ (purity 5N) were prepared, weighed according to the composition shown in Table 2, and tested. Ceramic fluorescent materials of Samples 7 to 11 were obtained in the same manner as in Example 1.

[Measurement of properties]
The fluorescence decay time constant τ of the prepared samples 1 to 11 was determined. Using a pulse X-ray tube, generate X-rays at a tube voltage of 30 kV, irradiate samples 1 to 11 with X-rays, and attenuate the time until the emission intensity decays to 1/e after stopping the X-ray irradiation. It was obtained as the time constant τ. Quantaurus-τ (Quantaurus-Tau), a fluorescence lifetime measuring device manufactured by Hamamatsu Photonics, was used for fluorescence measurement. FIG. 1 shows the relationship between the Ce composition x of Samples 1 to 6 and the decay time constant τ. FIG. 2 shows the relationship between the Lu composition y and the decay time constant τ of samples 7-11.

A powder X-ray diffraction spectrum of Sample 3 was measured. The results are shown in FIGS. 3(a) and (b). For comparison, the powder X-ray diffraction spectrum of a sample prepared under the same conditions as Sample 3 of Experimental Example 1 except that the atmosphere during firing was air or oxygen atmosphere is also shown.

SEM (Scanning Electron Microscope) observation of the structure of the sample fired in the oxygen atmosphere, the sample fired in the air atmosphere, and the sample 3 was performed using JSM-7001F manufactured by JEOL. BSE (backscattered electron) images observed at a magnification of 5000 are shown in FIGS. 4(a) to 4(c). FIGS. 5A to 5C show results of Ce elemental mapping obtained by analyzing the Ce element by EDX (Energy Dispersive X-ray Spectroscopy) in the same region as in FIG. In addition, FIGS. 6(a) to 6(c) show regions of the CeO ₂ phase indicated in black by performing binarization processing on FIGS. 5(a) to 5(c). Table 3 shows the area ratio of the CeO ₂ phase in the cross section.

[Discussion]
As shown in FIG. 1, in the ceramic fluorescent material represented by the general formula (1), as the amount of Ce added increases, the decay time constant τ becomes shorter. In FIG. 1, the decay time constant τ of single crystal Ce-PYAP was measured and shown together. It was found that when the amount x of Ce is 0.001 or more, the attenuation time constant τ can be made about 35 ns or less. It is also found that when the amount x of Ce is 0.006 or more, the decay time constant τ is about 20 ns or less, and when x is 0.01 or more, the decay time constant τ is about 15 ns or less. rice field.

As shown in FIG. 2, in the ceramic fluorescent material represented by the general formula (1), as the amount y of Lu increases, the attenuation time constant τ tends to become slightly shorter. is found not to change significantly. This is considered to indicate that, as described above, the decay time constant τ is largely dependent on the light-emitting element without being significantly affected by the base material to which Ce is added.

Thus, for example, different amounts of Lu can be used to tune the effective atomic number of a ceramic fluorescent material without significantly changing the decay time constant τ.

FIG. 3(a) shows the powder X-ray diffraction spectrum of Sample 3 produced, and FIG. 3(b) shows an enlarged part of it. A large peak derived from Ce _0.03 Y _0.97 AlO ₃ is observed near 34.5° (perovskite structure is identified). As shown in Figs. 3(a) and 3(b), the samples prepared in the oxygen atmosphere or in the air atmosphere show a peak derived from CeO2 near 28.2 ° _C , whereas in the reducing atmosphere This peak is not seen in the prepared sample 3. From these results, it is important to perform sintering in a reducing atmosphere when producing the ceramic fluorescent material of the present disclosure. I know it can be dissolved.

In FIGS. 4(a) to 4(c), the regions shown in white are considered to be the CeO ₂ phase precipitated at the grain boundary of the phase having the composition represented by the general formula (1). As shown in this figure, the more oxygen is contained in the atmosphere during firing, the more CeO ₂ does not form a solid solution in the main phase and exists as a large heterogeneous phase. On the other hand, the CeO ₂ phase is small in sample 3 of the example fired in a reducing atmosphere. 4(a) to 4(c), in addition to the main phase and the CeO ₂ phase, the garnet phase (area darker than the main phase) and pores (black) are considered to be shown.

As shown in Table 3, the area of the CeO ₂ phase in the observed cross section of the prepared sample 3 is 0.01%, and the amount of CeO ₂ not solid-dissolved in the main phase is very small. On the other hand, in the sample fired in an oxygen atmosphere, the reduction of CeO ₂ did not proceed sufficiently, so it is difficult to form a solid solution in the main phase and remains as CeO ₂ . According to the ceramic phosphor materials of the present disclosure, the proportion of CeO ₂ phase regions in cross-sectional BSE images is about 0.5% or less.

From the above results, according to the ceramic fluorescent material of the present disclosure, by having the composition of the general formula (1), the decay time constant τ is small, and a fluorescent material that can be used for a photon counting type radiation detector can be obtained. was confirmed.

INDUSTRIAL APPLICABILITY The ceramic fluorescent material, the ceramic scintillator and the radiation detector, and the method for manufacturing the ceramic fluorescent material of the present disclosure are suitably used for fluorescent materials, scintillators and radiation detectors for various applications, such as photon counting for radiographic imaging systems. type radiation detector.

Claims (10)

Ce _x (Y _1-y Lu _y ) _1-x AlO ₃ containing a main component having a composition represented by x and y where 0.001≦x<1
0≤y≤1
A ceramic scintillator for a photon-counting radiation detector containing a fluorescent material satisfying The main component is a phosphor having a perovskite structure and having Ce as a light emitting element,
The ceramic scintillator for the photon counting radiation detector has, with respect to the total amount of Ce, Y, Lu and Al,
0.05 atomic % or more and less than 50 atomic % of Ce,
0 atomic % or more and 49.95 atomic % or less of Y,
0 atomic % or more and 49.5 atomic % or less of Lu,
And,
2. The ceramic scintillator for a photon-counting radiation detector according to claim 1, containing 50 atomic % of Ce, Y and Lu in total and 50 atomic % of Al. 2. The ceramic scintillator for photon counting radiation detector according to claim 1, wherein said ceramic scintillator for photon counting radiation detector contains said main component at a rate of 95% by mass or more. The x is
0.006≦x<1
A ceramic scintillator for a photon counting radiation detector according to any one of claims 1 to 3, satisfying: The x is
0.01≤x≤0.1
A ceramic scintillator for a photon counting radiation detector according to any one of claims 1 to 3, satisfying: The y is
0<y<0.5
A ceramic scintillator for a photon counting radiation detector according to any one of claims 1 to 5, satisfying: The y is
0.0003≤y≤0.01
A ceramic scintillator for a photon counting radiation detector according to any one of claims 1 to 5, satisfying: The y is
0.4≤y≤0.6
A ceramic scintillator for a photon counting radiation detector according to any one of claims 1 to 5, satisfying: 9. The ceramic scintillator for photon counting radiation detectors according to claim 1 , wherein the ceramic scintillator for photon counting radiation detectors has a relative density of 99% or more. _{Ce , Al} , _{Y ,} and A step of preparing raw materials each containing Lu;
a step of mixing and pulverizing the raw materials to obtain a raw material powder;
a step of molding the raw material powder to obtain a molded body;
sintering the compact at a temperature of 1600° C. to 1800° C. in a reducing atmosphere;
A method for producing a fluorescent material for a photon-counting radiation detector, comprising:

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