JP7154193B2 - 酸素還元触媒のためのイオン液体および八面体Pt-Ni-Cu合金ナノ粒子からなる組成物 - Google Patents

酸素還元触媒のためのイオン液体および八面体Pt-Ni-Cu合金ナノ粒子からなる組成物 Download PDF

Info

Publication number
JP7154193B2
JP7154193B2 JP2019123610A JP2019123610A JP7154193B2 JP 7154193 B2 JP7154193 B2 JP 7154193B2 JP 2019123610 A JP2019123610 A JP 2019123610A JP 2019123610 A JP2019123610 A JP 2019123610A JP 7154193 B2 JP7154193 B2 JP 7154193B2
Authority
JP
Japan
Prior art keywords
nickel
platinum
ionomer
auxiliary
cathode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2019123610A
Other languages
English (en)
Japanese (ja)
Other versions
JP2020022955A (ja
JP2020022955A5 (enExample
Inventor
カン フーアン
リーチン ゾウ
ホンフェイ ジア
久雄 加藤
ジェンモン ポン
シャオチェン シェン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Akron
Original Assignee
University of Akron
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of Akron filed Critical University of Akron
Publication of JP2020022955A publication Critical patent/JP2020022955A/ja
Publication of JP2020022955A5 publication Critical patent/JP2020022955A5/ja
Application granted granted Critical
Publication of JP7154193B2 publication Critical patent/JP7154193B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8647Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8647Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
    • H01M4/8652Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites as mixture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8663Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers
    • H01M4/8668Binders
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/9008Organic or organo-metallic compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/92Metals of platinum group
    • H01M4/921Alloys or mixtures with metallic elements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/92Metals of platinum group
    • H01M4/925Metals of platinum group supported on carriers, e.g. powder carriers
    • H01M4/926Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M2004/8678Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
    • H01M2004/8689Positive electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M2008/1095Fuel cells with polymeric electrolytes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Catalysts (AREA)
  • Inert Electrodes (AREA)
  • Fuel Cell (AREA)
JP2019123610A 2018-07-09 2019-07-02 酸素還元触媒のためのイオン液体および八面体Pt-Ni-Cu合金ナノ粒子からなる組成物 Active JP7154193B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US16/030,103 2018-07-09
US16/030,103 US11043678B2 (en) 2018-07-09 2018-07-09 Composite made of ionic liquid and octahedral Pt—Ni—Cu alloy nanoparticles for oxygen reduction catalysis

Publications (3)

Publication Number Publication Date
JP2020022955A JP2020022955A (ja) 2020-02-13
JP2020022955A5 JP2020022955A5 (enExample) 2021-10-14
JP7154193B2 true JP7154193B2 (ja) 2022-10-17

Family

ID=69102312

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2019123610A Active JP7154193B2 (ja) 2018-07-09 2019-07-02 酸素還元触媒のためのイオン液体および八面体Pt-Ni-Cu合金ナノ粒子からなる組成物

Country Status (3)

Country Link
US (1) US11043678B2 (enExample)
JP (1) JP7154193B2 (enExample)
CN (1) CN110707330A (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20200112031A1 (en) * 2018-10-08 2020-04-09 Toyota Motor Engineering & Manufacturing North America, Inc. Cascade adsorption mechanism for overcoming activation energy barrier in oxygen reduction reaction
US11189851B2 (en) * 2019-01-03 2021-11-30 Toyota Motor Engineering & Manufacturing North America, Inc. Catalyst layer composition for improved performance of membrane assembly electrode with ionic liquid
US12098469B2 (en) 2020-09-30 2024-09-24 Alliance For Sustainable Energy, Llc Compositions including ionic liquids and methods of making the same
US11731110B2 (en) * 2021-09-03 2023-08-22 Toyota Motor Engineering & Manufacturing North America, Inc. Protonated dimeric ionic liquid to enhance performance of membrane assembly electrode (MEA)
US11819826B2 (en) * 2021-09-03 2023-11-21 Toyota Motor Engineering & Manufacturing North America, Inc. Ionic liquid to enhance performance and durability of membrane assembly electrode (MEA)
WO2024018944A1 (ja) * 2022-07-22 2024-01-25 Toppanホールディングス株式会社 電極触媒層、膜電極接合体、および、固体高分子形燃料電池

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060058185A1 (en) 2004-08-18 2006-03-16 Symyx Technologies, Inc. Platinum-copper-nickel fuel cell catalyst
US20110177428A1 (en) 2010-01-20 2011-07-21 Ut-Battelle, Llc Superbase-Derived Protic Ionic Liquids
US20140113218A1 (en) 2012-10-23 2014-04-24 The Johns Hopkins University Encapsulated Nanoporous Metal Nanoparticle Catalysts

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5827602A (en) * 1995-06-30 1998-10-27 Covalent Associates Incorporated Hydrophobic ionic liquids
US5872602A (en) 1995-12-13 1999-02-16 Johnson; Robert E. Fluoroscopic imaging system with image enhancement apparatus and method
US8003270B2 (en) * 2005-08-17 2011-08-23 Idatech, Llc Fuel cell stacks and systems with fluid-responsive temperature regulation
JP5109130B2 (ja) * 2005-08-19 2012-12-26 国立大学法人 東京大学 プロトン伝導性ハイブリッド材料及びそれを用いた燃料電池用触媒層
US20070227300A1 (en) * 2006-03-31 2007-10-04 Quantumsphere, Inc. Compositions of nanometal particles containing a metal or alloy and platinum particles for use in fuel cells
US20110189589A1 (en) * 2010-01-29 2011-08-04 The Johns Hopkins University Composite porous catalysts
WO2015006527A1 (en) 2013-07-10 2015-01-15 The University Of Akron Functional gas-assisted impregnation method for producing noble metal alloy catalysts with defined morphology
WO2017053564A1 (en) * 2015-09-25 2017-03-30 Carnegie Mellon University Far superior oxidation catalysts based on macrocyclic compounds
US10777823B2 (en) 2017-04-03 2020-09-15 Toyota Jidosha Kabushiki Kaisha Ionic liquid as promotor to enhance the performance of oxygen reduction catalyst for fuel cell application

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060058185A1 (en) 2004-08-18 2006-03-16 Symyx Technologies, Inc. Platinum-copper-nickel fuel cell catalyst
US20110177428A1 (en) 2010-01-20 2011-07-21 Ut-Battelle, Llc Superbase-Derived Protic Ionic Liquids
US20140113218A1 (en) 2012-10-23 2014-04-24 The Johns Hopkins University Encapsulated Nanoporous Metal Nanoparticle Catalysts

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
ACS Catalysis,2015年,vol.5,p.2296 -2300,Supporting Information,DOI:10.1021/cs502112g
Journal of the Electrochemical Society,2017年,vol.164,no.13,p.F1448 -F1459,DOI:10.1149/2.1071713jes

Also Published As

Publication number Publication date
JP2020022955A (ja) 2020-02-13
US20200014034A1 (en) 2020-01-09
US11043678B2 (en) 2021-06-22
CN110707330A (zh) 2020-01-17

Similar Documents

Publication Publication Date Title
JP7154193B2 (ja) 酸素還元触媒のためのイオン液体および八面体Pt-Ni-Cu合金ナノ粒子からなる組成物
Rheinländer et al. Comparing hydrogen oxidation and evolution reaction kinetics on polycrystalline platinum in 0.1 M and 1 M KOH
Jiang et al. Investigations of fuel cell reactions at the composite microelectrode| solid polymer electrolyte interface. I. Hydrogen oxidation at the nanostructured Pt| Nafion® membrane interface
US9997788B2 (en) Methods of producing porous platinum-based catalysts for oxygen reduction
JP7013306B2 (ja) 燃料電池に用いられる酸素還元触媒の性能を向上させるプロモーターとしてのイオン液体
Vecchio et al. EDTA-derived CoNC and FeNC electro-catalysts for the oxygen reduction reaction in acid environment
Chen et al. A binary palladium–bismuth nanocatalyst with high activity and stability for alkaline glucose electrooxidation
Zhang et al. Non-precious Ir–V bimetallic nanoclusters assembled on reduced graphene nanosheets as catalysts for the oxygen reduction reaction
Brkovic et al. Non-stoichiometric tungsten-carbide-oxide-supported Pt–Ru anode catalysts for PEM fuel cells–From basic electrochemistry to fuel cell performance
JPWO2009107518A1 (ja) 触媒およびその製造方法ならびにその用途
Qazzazie et al. Platinum nanowires anchored on graphene-supported platinum nanoparticles as a highly active electrocatalyst towards glucose oxidation for fuel cell applications
Speder et al. The colloidal tool-box approach for fuel cell catalysts: Systematic study of perfluorosulfonate-ionomer impregnation and Pt loading
Matsumoto Ethanol and methanol oxidation activity of PtPb, PtBi, and PtBi2 intermetallic compounds in alkaline media
Shinozaki et al. Enhanced oxygen reduction activity on Pt/C for Nafion-free, thin, uniform films in rotating disk electrode studies
Sacco et al. Anodically-grown TiO2 nanotubes: Effect of the crystallization on the catalytic activity toward the oxygen reduction reaction
Wang et al. Bimetal–organic-frameworks-derived yolk–shell-structured porous Co 2 P/ZnO@ PC/CNTs hybrids for highly sensitive non-enzymatic detection of superoxide anion released from living cells
Woodroof et al. Exchange current density of the hydrogen oxidation reaction on Pt/C in polymer solid base electrolyte
Behnken et al. Oxygen Reduction Reaction Activity of Mesostructured Cobalt‐Based Metal Oxides Studied with the Cavity‐Microelectrode Technique
Locatelli et al. IrO2–SnO2 mixtures as electrocatalysts for the oxygen reduction reaction in alkaline media
Raoof et al. Improved hydrogen evolution on glassy carbon electrode modified with novel Pt/cetyltrimethylammonium bromide nanoscale aggregates
KR20150107749A (ko) 전하 이동 유기 착물 기반의 orr을 위한 비-pgm 촉매
Habibi et al. Comparative electrooxidation of C1–C4 alcohols on Pd| CC nanoparticle anode catalyst in alkaline medium
Sieben et al. Methanol oxidation on carbon supported Pt–Ru catalysts prepared by electrodeposition–Evaluation of Nafion® 117 film effect
CN112510217B (zh) 一种碳负载铂钇催化剂及其制备方法和应用
Ojani et al. High electrocatalysis of ethylene glycol oxidation based on nickel particles electrodeposited into poly (m-toluidine)/Triton X-100 composite

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20191206

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20210902

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20210902

A871 Explanation of circumstances concerning accelerated examination

Free format text: JAPANESE INTERMEDIATE CODE: A871

Effective date: 20210902

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20211202

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20211214

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20220302

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20220524

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20220906

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20221004

R150 Certificate of patent or registration of utility model

Ref document number: 7154193

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150