JP7100076B2 - Soil conditioner and its manufacturing method - Google Patents
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特許法第３０条第２項適用 ・発行者名 ：株式会社吉田レミコン 刊行物名 ：「農地の土壌改良資材 リコ・ソイル」のリーフレット 発行年月日：令和１年１０月１９日 ・発行者名 ：株式会社吉田レミコン 刊行物名 ：河北新報 令和２年１月２６日付朝刊、第１６面広告 発行年月日：令和２年１月２６日Application of Article 30, Paragraph 2 of the Patent Act ・ Issuer name: Yoshida Remicon Co., Ltd. Publication name: Leaflet of “Rico Soil, a soil improvement material for farmland” Date of issue: October 19, 1st year ・ Issuer Name: Yoshida Remicon Co., Ltd. Publication name: Hebei Shinpo Morning edition dated January 26, 2nd year, 16th page advertisement Publication date: January 26th, 2nd year
本発明は、土壌改良材およびその製造方法に関する。 The present invention relates to a soil conditioner and a method for producing the same.
従来、培土は、基土を田土または山土、山砂等に依存し、それに必要に応じて堆肥類などの有機質資材、川砂などの無機質資材を配合して製造されている。しかし、山土、山砂等は近年、良質でかつ均一なものを大量に採取することが困難であり、その大量採取がまた自然破壊につながる懸念も出てきている。 Conventionally, hilling soil depends on rice field soil, mountain soil, mountain sand, etc. as the base soil, and is produced by blending organic materials such as compost and inorganic materials such as river sand as necessary. However, in recent years, it has been difficult to collect a large amount of high-quality and uniform mountain soil, mountain sand, etc., and there is a concern that the large amount collection will lead to the destruction of nature.
さらに、山砂、山土は病害虫に汚染されている可能性があり、事前に薬液、加熱等で土の消毒を行わなければならない欠点もある。ところで、上水（浄水）汚泥は、年間を通じて一定箇所から得られ、性質の変化が少なく、病害虫や雑草種子などの混入がないので消毒の必要もない利点を有している。しかし、現在、上水汚泥は、ほとんどが廃棄物となって埋め立てられていた。 Furthermore, mountain sand and mountain soil may be contaminated with pests, and there is a drawback that the soil must be disinfected in advance with a chemical solution, heating, or the like. By the way, clean water (purified) sludge is obtained from a certain place throughout the year, has little change in properties, and has the advantage that it does not need to be disinfected because it is not contaminated with pests or weed seeds. However, most of the clean water sludge is now landfilled as waste.
また、牡蠣は一部で殻付の状態で消費者に提供されるが、ほとんどの場合むき身の状態で販売されている。したがって殻は加工の段階で身と分離され、廃棄物となっている。 In addition, some oysters are provided to consumers in the form of shells, but in most cases they are sold in the form of peeled oysters. Therefore, the shell is separated from the body at the processing stage and becomes waste.
この牡蠣殻の有効利用を図るための一環として、牡蠣殻を粉砕して肥料に用いたり、牡蠣殻は酸性の水の中ではアルカリ成分を溶出するので、pHの調整等に用いたりすることがある。また、牡蠣殻のアルカリ成分の効果を利用して、牡蠣殻を水の浄化や脱臭に利用することも提案されている。 As a part of effective utilization of this oyster shell, oyster shell can be crushed and used as fertilizer, or oyster shell can be used for pH adjustment because alkaline components elute in acidic water. be. It has also been proposed to utilize the oyster shell for water purification and deodorization by utilizing the effect of the alkaline component of the oyster shell.
牡蠣殻を用いた土壌改良材として、家畜の生排泄物と鶏糞炭化物とを混合、攪拌して得た水分調整排泄物に対し、乾燥卵殻を混合、攪拌すると共に、ｐＨ調整材としての牡蠣殻および／または施用後成分調整材としてのゼオライトの適量を添加したものを熟成、発酵した上、粒状化してなる土壌改良材が開示されている（例えば、特許文献１参照）。 As a soil conditioner using oyster shells, dried eggshells are mixed and stirred with the water-adjusted excrement obtained by mixing and stirring raw livestock excrement and charcoal chicken manure, and oyster shells as a pH adjusting material. And / or a soil conditioner obtained by adding an appropriate amount of zeolite as a component adjusting material after application, aging, fermenting, and granulating is disclosed (see, for example, Patent Document 1).
しかしながら、特許文献１に記載の土壌改良材では、上水汚泥の活用が図られないという課題があった。 However, the soil conditioner described in Patent Document 1 has a problem that the clean water sludge cannot be utilized.
本発明は、このような課題に着目してなされたもので、山土、山砂を用いずに、牡蠣殻および上水汚泥の有効利用を図ることができる土壌改良材およびその製造方法を提供することを目的とする。 The present invention has been made focusing on such a problem, and provides a soil conditioner capable of effectively utilizing oyster shells and clean water sludge without using mountain soil and mountain sand, and a method for producing the same. The purpose is to do.
上記目的を達成するために、本発明に係る土壌改良材は、牡蠣殻の除塩された粉砕粉末と、上水汚泥と、ゼオライトと、腐敗生成物を発酵させて分解する機能を有する微生物を含む水と、バインダーとの混合造粒固化物から成り、前記粉砕粉末２５重量部と、前記上水汚泥６０重量部と、前記ゼオライト１０重量部と、前記微生物０．０５重量部を含む水３０重量部と、前記バインダー５重量部とを含み、前記バインダーは高分子系中性固化材から成り、酸化カルシウム３５～８０重量部と、酸化マグネシウム１５～３０重量部とを含むことを、特徴とする。
In order to achieve the above object, the soil improving material according to the present invention comprises crushed oyster shell powder, clean water sludge, zeolite, and microorganisms having a function of fermenting and decomposing spoilage products. Water containing 25 parts by weight of the crushed powder, 60 parts by weight of the clean water sludge, 10 parts by weight of the zeolite, and 0.05 parts by weight of the microorganism. It contains 30 parts by weight and 5 parts by weight of the binder, and the binder is made of a polymer-based neutral solidifying material and is characterized by containing 35 to 80 parts by weight of calcium oxide and 15 to 30 parts by weight of magnesium oxide . And.
本発明に係る土壌改良材の製造方法は、牡蠣殻の除塩された粉砕粉末と、上水汚泥と、ゼオライトと、腐敗生成物を発酵させて分解する機能を有する微生物を含む水と、高分子系中性固化材から成り酸化カルシウム３５～８０重量部と酸化マグネシウム１５～３０重量部とを含むバインダーとを、前記粉砕粉末２５重量部と、前記上水汚泥６０重量部と、前記ゼオライト１０重量部と、前記微生物０．０５重量部を含む水３０重量部と、前記バインダー５重量部との比率で混合し、造粒固化することを、特徴とする。 The method for producing the soil improving material according to the present invention includes desalted crushed powder of oyster shells, clean water sludge, zeolite, water containing microorganisms having a function of fermenting and decomposing spoilage products, and high water. A binder composed of a molecular neutral solidifying material and containing 35 to 80 parts by weight of calcium oxide and 15 to 30 parts by weight of magnesium oxide is used, 25 parts by weight of the crushed powder, 60 parts by weight of the clean water sludge, and 10 parts of the zeolite. It is characterized in that 30 parts by weight of water containing 0.05 parts by weight of the microorganism and 5 parts by weight of the binder are mixed and granulated and solidified.
本発明に係る土壌改良材およびその製造方法によれば、山土、山砂を用いずに、牡蠣殻および上水汚泥の有効利用を図ることができる。また、本発明に係る土壌改良材により高い土壌改良効果を得ることができる。 According to the soil conditioner and the method for producing the same according to the present invention, oyster shells and clean water sludge can be effectively used without using mountain soil and mountain sand. In addition, a high soil improvement effect can be obtained by the soil improvement material according to the present invention.
本発明によれば、山土、山砂を用いずに、牡蠣殻および上水汚泥の有効利用を図ることができる土壌改良材およびその製造方法を提供することができる。 According to the present invention, it is possible to provide a soil conditioner capable of effectively utilizing oyster shells and clean water sludge without using mountain soil and mountain sand, and a method for producing the same.
以下、本発明の実施の形態について説明する。
本発明の実施の形態の土壌改良材は、牡蠣殻の除塩された粉砕粉末と、上水汚泥と、ゼオライトと、腐敗生成物を発酵させて分解する機能を有する微生物と、バインダーとの混合造粒固化物から成ることを、特徴とする。
本発明の実施の形態の土壌改良材の製造方法は、牡蠣殻の除塩された粉砕粉末と、上水汚泥と、ゼオライトと、腐敗生成物を発酵させて分解する機能を有する微生物と、バインダーと、水とを混合し、造粒固化することを、特徴とする。
Hereinafter, embodiments of the present invention will be described.
The soil conditioner according to the embodiment of the present invention is a mixture of desalted pulverized oyster shell powder, clean water sludge, zeolite, microorganisms having a function of fermenting and decomposing putrefactive products, and a binder. It is characterized by being composed of granulated solidified material.
The method for producing the soil conditioner according to the embodiment of the present invention includes desalted pulverized oyster shell powder, clean water sludge, zeolite, microorganisms having a function of fermenting and decomposing putrefactive products, and a binder. And water are mixed and granulated and solidified.
牡蠣殻の除塩は、屋外の雨ざらしにより行ってもよい。上水汚泥は、浄水場の浄水処理における沈でん処理工程で沈でんさせて除去された、濁りなどの不純物による泥状のものである。上水汚泥は、河川、湖沼水に浮遊する自然物を主体とするもので、浄水過程および排水処理に用いられる薬物以外の異物をほとんど含んでいない。上水汚泥には、問題となる量の重金属は含まれていない。 Desalination of oyster shells may be carried out outdoors in the rain. The clean water sludge is mud-like due to impurities such as turbidity, which is removed by sedimentation in the sedimentation treatment step in the water purification treatment of the water purification plant. Clean water sludge is mainly composed of natural substances floating in rivers and lakes, and contains almost no foreign substances other than drugs used in the water purification process and wastewater treatment. Water sludge does not contain problematic amounts of heavy metals.
ゼオライトは、オングストロームレベルの無数の細孔を有することから、イオン交換機能を有し、微生物の棲家となるとともに有害物質を閉じ込める効果がある。腐敗生成物を発酵させて分解する機能を有する微生物としては、光合成細菌や、発酵型の乳酸菌、酵母などの細菌の集合体（市販の通称「ＥＭ菌」）を用いることができる。 Zeolites have innumerable pores at the angstrom level, so they have an ion exchange function, and have the effect of becoming a habitat for microorganisms and trapping harmful substances. As a microorganism having a function of fermenting and decomposing a putrefactive product, a photosynthetic bacterium, a fermented lactic acid bacterium, an aggregate of bacteria such as yeast (commercially available, commonly known as "EM bacterium") can be used.
本発明の実施の形態の土壌改良材において、前記粉砕粉末15～35重量部と、前記上水汚泥50～70重量部と、前記ゼオライト5～15重量部と、前記微生物0.02～0.05重量部と、前記バインダー5～10重量部とを含むことが好ましい。 In the soil conditioner of the embodiment of the present invention, the crushed powder is 15 to 35 parts by weight, the clean water sludge is 50 to 70 parts by weight, the zeolite is 5 to 15 parts by weight, and the microorganism is 0.02 to 0.05 parts by weight. , The binder preferably contains 5 to 10 parts by weight.
前記バインダーはセメント系結合材から成り、二酸化けい素24～27重量部と、酸化アルミニウム8.0～9.0重量部と、酸化第二鉄1.5～2.0重量部と、酸化カルシウム50.0～60.0重量部と、酸化マグネシウム3.0～4.0重量部と、三酸化硫黄1.5～2.5重量部とを含んでもよい。前記バインダーは、特に高分子系セメント固化材から成ることが好ましい。
この構成のバインダーは、一定の物理的強度と化学的性能を具備するため、牡蠣殻の再資源化に適している。
前記バインダーは高分子系中性固化材から成り、酸化カルシウム35～80重量部と、酸化マグネシウム15～30重量部とを含んでもよい。この構成のバインダーも、一定の物理的強度と化学的性能を具備するため、牡蠣殻の再資源化に適している。
The binder is made of a cement-based binder and is oxidized with 24 to 27 parts by weight of silica dioxide, 8.0 to 9.0 parts by weight of aluminum oxide, 1.5 to 2.0 parts by weight of ferric oxide, 50.0 to 60.0 parts by weight of calcium oxide. It may contain 3.0 to 4.0 parts by weight of magnesium and 1.5 to 2.5 parts by weight of sulfur trioxide. The binder is particularly preferably made of a polymer-based cement solidifying material.
The binder of this composition has a certain physical strength and chemical performance, and is therefore suitable for recycling oyster shells.
The binder is made of a polymer-based neutral solidifying material and may contain 35 to 80 parts by weight of calcium oxide and 15 to 30 parts by weight of magnesium oxide. The binder of this structure also has a certain physical strength and chemical performance, and is therefore suitable for recycling oyster shells.
本発明の実施の形態の土壌改良材の製造方法では、牡蠣殻の除塩された粉砕粉末と、上水汚泥と、腐敗生成物を発酵させて分解する機能を有する微生物とをプレミックスした後、プラントに投入して、ゼオライトとバインダーとを混錬し、造粒することが好ましい。
混合造粒固化物は、一定の大きさに造粒してあることが好ましい。その場合、取り扱い、保存が容易となり、使用場所や使用方法の制限を受けにくくすることができる。
本発明の実施の形態の土壌改良材の製造方法では、牡蠣殻の除塩された粉砕粉末と、上水汚泥と、ゼオライトと、腐敗生成物を発酵させて分解する機能を有する微生物と、バインダーとの総重量に対し、１０～４０重量％の水を混合することが好ましい。
In the method for producing a soil conditioner according to an embodiment of the present invention, after premixing a desalted crushed powder of oyster shells, clean water sludge, and a microorganism having a function of fermenting and decomposing putrefactive products. , It is preferable to put it in a plant, knead the zeolite and the binder, and granulate.
The mixed granulated solidified product is preferably granulated to a certain size. In that case, it becomes easy to handle and store, and it is possible to reduce the restrictions on the place and method of use.
In the method for producing a soil conditioner according to an embodiment of the present invention, a desalted pulverized powder of oyster shell, clean water sludge, zeolite, a microorganism having a function of fermenting and decomposing putrefactive products, and a binder. It is preferable to mix 10 to 40% by weight of water with respect to the total weight of the above.
本発明の実施の形態の土壌改良材およびその製造方法によれば、山土、山砂を用いずに、牡蠣殻および上水汚泥の有効利用を図ることができる。また、本発明に係る土壌改良材により、高い土壌改良効果を得ることができ、米などの農作物の収穫量の増加、根の成長、糖度の向上をもたらすことができる。 According to the soil conditioner of the embodiment of the present invention and the method for producing the same, it is possible to effectively utilize oyster shells and clean water sludge without using mountain soil and mountain sand. In addition, the soil conditioner according to the present invention can obtain a high soil conditioner effect, can increase the yield of agricultural products such as rice, grow roots, and improve the sugar content.
下記の表１に示すＮｏ.１～１８の配合割合の、上水汚泥と、牡蠣殻の除塩された粉砕粉末と、ゼオライトと、バインダーと、腐敗生成物を発酵させて分解する機能を有する微生物（発酵菌）と、１７．５重量％の水とをそれぞれ混合し、造粒固化して、土壌改良材を製造した。Ｎｏ.９～１３では、ゼオライトの代わりに山砂を使用した。
バインダーには、市販の高分子系セメント固化材（宇部三菱株式会社製、商品名「高炉Ｂ種他」）を使用した。このバインダーには、二酸化けい素24～27重量部と、酸化アルミニウム8.0～9.0重量部と、酸化第二鉄1.5～2.0重量部と、酸化カルシウム50.0～60.0重量部と、酸化マグネシウム3.0～4.0重量部と、三酸化硫黄1.5～2.5重量部とが含まれる。腐敗生成物を発酵させて分解する機能を有する微生物（発酵菌）には、光合成細菌や、発酵型の乳酸菌、酵母などの細菌の集合体を含む市販品（販売元：株式会社ＥＭ生活 、商品名「ＥＭ－１」）を用いた。なお、表１で、「％」は重量％を意味する。
It has the function of fermenting and decomposing clean water sludge, desalted crushed powder of oyster shells, zeolite, binder, and putrefactive products in the blending ratios of Nos. 1 to 18 shown in Table 1 below. Microorganisms (fermenting bacteria) and 17.5% by weight of water were mixed and granulated and solidified to produce a soil conditioner. In Nos. 9 to 13, mountain sand was used instead of zeolite.
As the binder, a commercially available polymer-based cement solidifying material (manufactured by Ube Mitsubishi Corporation, trade name "blast furnace class B, etc.") was used. This binder contains 24 to 27 parts by weight of silicon dioxide, 8.0 to 9.0 parts by weight of aluminum oxide, 1.5 to 2.0 parts by weight of ferric oxide, 50.0 to 60.0 parts by weight of calcium oxide, and 3.0 to 4.0 parts by weight of magnesium oxide. And 1.5 to 2.5 parts by weight of sulfur trioxide. Microorganisms (fermenting bacteria) that have the function of fermenting and decomposing putrefactive products include commercially available products containing aggregates of bacteria such as photosynthetic bacteria, fermented lactic acid bacteria, and yeast (sold by EM Seikatsu Co., Ltd., products). The name "EM-1") was used. In Table 1, "%" means% by weight.
表１のＮｏ.１～１８の配合で製造した土壌改良材について、造粒状態を観察した。造粒状態は、粒径（固化状況）、多孔質性、初期アルカリ性発現状況、通気性、含有物状況から判断し、総合評価を行った。その結果を表２に示す。
表２で、◎は現時点で最良のもの、○は良好なもの、△は多少課題があるが使用可のもの、×は課題があり、使用工夫の必要があるものを示す。
表２の結果から、農地への施用にはＮｏ.１６が最適であった。
The granulation state of the soil conditioner produced with the formulations of Nos. 1 to 18 in Table 1 was observed. The granulated state was judged from the particle size (solidification status), porosity, initial alkalinity development status, air permeability, and content status, and comprehensive evaluation was performed. The results are shown in Table 2.
In Table 2, ◎ indicates the best one at the present time, ○ indicates the one that is good, Δ indicates the one that can be used although there are some problems, and × indicates the one that has problems and needs to be devised.
From the results in Table 2, No. 16 was the most suitable for application to agricultural land.
また、バインダーを変えて、同様に以下の表３に示すＮｏ.１～１２の配合割合で土壌改良材を製造した。バインダーには、市販の高分子系中性固化材（テクニカ合同株式会社製、商品名「エコポリマー」）を使用した。このバインダーには、酸化カルシウム35～80重量部と、酸化マグネシウム15～30重量部とが含まれる。 Further, the binder was changed, and the soil conditioner was similarly produced at the blending ratios of Nos. 1 to 12 shown in Table 3 below. As the binder, a commercially available polymer-based neutral solidifying material (manufactured by Technica Joint Co., Ltd., trade name “Ecopolymer”) was used. This binder contains 35 to 80 parts by weight of calcium oxide and 15 to 30 parts by weight of magnesium oxide.
表３のＮｏ.１～１２の配合で製造した土壌改良材について、造粒状態を観察した。造粒状態は、粒径（固化状況）、多孔質性、初期アルカリ性発現状況、通気性、含有物状況、強（硬）度から判断し、総合評価を行った。その結果を表４に示す。
表４で、◎は現時点で最良のもの、○は良好なもの、△は多少課題があるが使用可のもの、×は課題があり、使用工夫の必要があるものを示す。
表４の結果から、農地への施用にはＮｏ.１が最適であった。また、果菜等畑作にはＮｏ.５が、花卉等栽培にはＮｏ.８が最適であった。
The granulation state of the soil conditioner produced with the formulations of Nos. 1 to 12 in Table 3 was observed. The granulated state was judged from the particle size (solidification status), porosity, initial alkalinity development status, air permeability, content status, and strength (hardness), and comprehensive evaluation was performed. The results are shown in Table 4.
In Table 4, ◎ indicates the best one at the present time, ○ indicates the one that is good, Δ indicates the one that can be used although there are some problems, and × indicates the one that has problems and needs to be devised.
From the results in Table 4, No. 1 was the most suitable for application to agricultural land. In addition, No. 5 was optimal for upland farming such as fruit vegetables, and No. 8 was optimal for cultivation of flowers and the like.
実施例１の表１のＮｏ.１６の配合の土壌改良材を施用した圃場と非施用圃場とで稲を生育し、生育状況の比較試験を行った。試験は、平成29年5月から10月にかけて、宮城県登米市中田町浅水の日当たりの良い場所で行った。圃場は、それぞれ広さ992平方メートル（一反歩）であった。施用圃場、非施用圃場の深さ12～15ｃｍまでの表層に土壌改良材500kg～600kgをロータリー耕起で混合して準備した。その施用圃場と非施用圃場とにササニシキの苗を植え、土壌改良材の有無以外は同様の条件で生育させた。
その結果を図１～図３に示す。
Rice was grown in the field to which the soil conditioner of No. 16 in Table 1 of Example 1 was applied and the field to which the soil conditioner was not applied, and a comparative test of the growth state was conducted. The test was conducted from May to October 2017 in a sunny place in Asamizu, Nakada-cho, Tome City, Miyagi Prefecture. Each field was 992 square meters (one step). A soil conditioner of 500 kg to 600 kg was mixed by rotary plowing on the surface layer of the applied field and the non-applied field to a depth of 12 to 15 cm. Sasanishiki seedlings were planted in the applied and non-applied fields and grown under the same conditions except for the presence or absence of soil conditioners.
The results are shown in FIGS. 1 to 3.
図１に示すとおり、施用圃場（Ａ）では、非施用圃場（Ｂ）に比べて米の収穫量が大きく増加した。また、図２に示すとおり、施用圃場（Ａ）では、非施用圃場（Ｂ）に比べて稲の根の長さが長く、生育状況が良好であった。また、図３に示すとおり、施用圃場（Ｂ）では、非施用圃場（Ａ）に比べて、収穫された米の糖度が高かった。
これらの結果から、本実施例の土壌改良材は、圃場への施用により、米の収穫量の増加、根の成長、糖度の向上をもたらすことが確認できた。
As shown in FIG. 1, in the applied field (A), the yield of rice was significantly increased as compared with the non-applied field (B). Further, as shown in FIG. 2, in the applied field (A), the root length of the rice was longer than that in the non-applied field (B), and the growing condition was good. Further, as shown in FIG. 3, the sugar content of the harvested rice was higher in the applied field (B) than in the non-applied field (A).
From these results, it was confirmed that the soil conditioner of this example brought about an increase in rice yield, root growth and sugar content by application to the field.
Claims (2)
前記粉砕粉末２５重量部と、前記上水汚泥６０重量部と、前記ゼオライト１０重量部と、前記微生物０．０５重量部を含む水３０重量部と、前記バインダー５重量部とを含み、
前記バインダーは高分子系中性固化材から成り、酸化カルシウム３５～８０重量部と、酸化マグネシウム１５～３０重量部とを含むことを、特徴とする土壌改良材。 It consists of a mixed granulated solidified product of oyster shell desalted ground powder, clean water sludge, zeolite, water containing microorganisms having the function of fermenting and decomposing putrefactive products, and a binder.
25 parts by weight of the crushed powder, 60 parts by weight of the clean water sludge, 10 parts by weight of the zeolite, 30 parts by weight of water containing 0.05 parts by weight of the microorganism, and 5 parts by weight of the binder.
The soil improving material is characterized in that the binder is made of a polymer-based neutral solidifying material and contains 35 to 80 parts by weight of calcium oxide and 15 to 30 parts by weight of magnesium oxide .
Calcium oxide 35 ~ A binder containing 80 parts by weight and 15 to 30 parts by weight of magnesium oxide was added to 25 parts by weight of the crushed powder, 60 parts by weight of the clean water sludge, 10 parts by weight of the zeolite, and 0.05 parts by weight of the microorganism. A method for producing a soil improving material, which comprises mixing 30 parts by weight of water containing water with 5 parts by weight of the binder to granulate and solidify.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2003023852A (en) | 2001-07-17 | 2003-01-28 | Okinawa Midori Sangyo:Kk | Culture soil for plant cultivation, method for cultivating plant at high position using the soil, and bed for cultivating plant at high position |
| JP2007160286A (en) | 2005-12-09 | 2007-06-28 | Hiroshi Hasegawa | Adjusting treatment base material of crushed organic matter of crustacean |
| JP2014151316A (en) | 2013-02-04 | 2014-08-25 | Yoshida Remicon Co Ltd | Deodorizer using oyster shells and method for manufacturing the same |
| CN108587632A (en) | 2018-06-22 | 2018-09-28 | 广州新农科肥业科技有限公司 | A kind of shell waste soil conditioner and the preparation method and application thereof |
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| JP2003023852A (en) | 2001-07-17 | 2003-01-28 | Okinawa Midori Sangyo:Kk | Culture soil for plant cultivation, method for cultivating plant at high position using the soil, and bed for cultivating plant at high position |
| JP2007160286A (en) | 2005-12-09 | 2007-06-28 | Hiroshi Hasegawa | Adjusting treatment base material of crushed organic matter of crustacean |
| JP2014151316A (en) | 2013-02-04 | 2014-08-25 | Yoshida Remicon Co Ltd | Deodorizer using oyster shells and method for manufacturing the same |
| CN108587632A (en) | 2018-06-22 | 2018-09-28 | 广州新农科肥业科技有限公司 | A kind of shell waste soil conditioner and the preparation method and application thereof |
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