KR102497005B1 - Mineral nano liquid fertilizer for growing sprout crops and manufacturing method thereof - Google Patents
Mineral nano liquid fertilizer for growing sprout crops and manufacturing method thereof Download PDFInfo
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- KR102497005B1 KR102497005B1 KR1020210132290A KR20210132290A KR102497005B1 KR 102497005 B1 KR102497005 B1 KR 102497005B1 KR 1020210132290 A KR1020210132290 A KR 1020210132290A KR 20210132290 A KR20210132290 A KR 20210132290A KR 102497005 B1 KR102497005 B1 KR 102497005B1
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/23—Solutions
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
Description
본 발명은 새싹작물 재배용 미네랄 나노 액상비료 및 그 제조방법에 관한 것으로서, 더욱 상세하게는 셀레늄, 게르마늄 및 바나듐을 포함하는 나노입자 미네랄을 이용하여 액상비료를 제조함으로써, 새싹작물의 잎뿐만 아니라 뿌리로 직접 흡수되어 새싹작물의 발근 및 생장이 촉진되고, 이로 인해 작황이 증대되며, 균형있는 영양성분을 공급할 수 있고, 새싹작물의 생육을 효과적으로 증대시킬 수 있는 새싹작물 재배용 미네랄 나노 액상비료 및 그 제조방법에 관한 것이다.The present invention relates to a mineral nano-liquid fertilizer for sprout crop cultivation and a method for manufacturing the same, and more particularly, by preparing a liquid fertilizer using nanoparticle minerals including selenium, germanium and vanadium, to produce not only the leaves but also the roots of sprout crops. Mineral nano-liquid fertilizer for sprout crops that can be directly absorbed to promote rooting and growth of sprout crops, thereby increasing yield, supplying balanced nutrients, and effectively increasing the growth of sprout crops, and manufacturing method thereof It is about.
종래에 농산물 생산량의 증대에 초점을 맞추어 농업기술이 발전되어 왔으며, 기술이 체계화된 각종 농자재의 개발과 생산, 농민들의 적절한 활용으로 인해 단위면적당 농산물의 생산량은 빠르게 증가해왔으며, 이와 같이 농산물의 생산량을 증가시키는 과정에서 화학비료(무기질비료) 및 작물보호제(화학농약)의 사용량은 지속적으로 증가되었다.Conventionally, agricultural technology has been developed with a focus on increasing the production of agricultural products, and the production of agricultural products per unit area has increased rapidly due to the development and production of various agricultural materials systematized with the technology and the appropriate use of farmers. In the process of increasing the amount of chemical fertilizers (inorganic fertilizers) and crop protection agents (chemical pesticides), the amount of use has been continuously increased.
하지만, 1990년대 이후, 과도한 화학비료 및 작물보호제에 포함된 질소 및 인산의 과다 투입으로 인한 지하수 오염 등의 환경문제가 대두되어 화학비료의 대량 사용이 사람 및 가축에 미치는 폐해에 대한 우려가 증가하기 시작하였다.However, since the 1990s, environmental problems such as groundwater contamination due to excessive use of nitrogen and phosphoric acid included in chemical fertilizers and crop protection agents have emerged, and concerns about harms to people and livestock caused by the large-scale use of chemical fertilizers have increased. started.
이에 따라, 정부는 친환경농업의 전격적 지원과 함께 화학비료의 감축을 기획하였으며, 자연 친화적인 농자재의 개발과 사용이 권장되어, 화학비료의 대안으로 천연 소재를 활용한 부산물 비료에 대한 관심이 증대되고 있다.Accordingly, the government has planned the reduction of chemical fertilizers along with full support for eco-friendly agriculture, and the development and use of nature-friendly agricultural materials are encouraged, and interest in by-product fertilizers using natural materials as an alternative to chemical fertilizers is increasing. there is.
부산물 비료는 척백해진 농토의 지력을 회복하고 환경친화적인 농업을 실천하기 위해 그 필요성이 강조되고 있으며, 이에 발맞추어 정부의 친환경농업의 육성정책과 같이하면서 부산물 비료의 수요가 증대하고 있는 추세이다.The need for by-product fertilizer is being emphasized in order to restore the fertility of farmland and to practice environmentally friendly agriculture.
부산물 비료는 부숙 여부에 따라 크게 부숙 유기질 비료와 유기질 비료로 구분되며, 부숙 유기질 비료는 대부분 가축의 분뇨, 음식물 쓰레기, 톱밥 등의 유기성 자원을 혼합한 후, 부숙 처리한 비료를 의미하고, 유기질 비료는 각종 박류를 이용하여 부숙하지 않은 상태의 유기물질을 활용한 비료를 의미한다.By-product fertilizers are largely divided into ripened organic fertilizers and organic fertilizers depending on whether they are ripened. Ripened organic fertilizers refer to fertilizers mixed with organic resources such as livestock manure, food waste, sawdust, and then processed to ripen. Organic fertilizers means a fertilizer using organic matter in an unripe state by using various types of tartar.
부산물 비료는 식물이 필요로 하는 영양분을 공급하고, 지력을 회복시키며, 흙을 부드럽게 만들고 내한력을 증강시키는 역할을 할 뿐만 아니라, 양분용탈을 방지하고 양분의 유효성을 증대시키는 역할을 할 수 있는 것으로 알려져 왔다.By-product fertilizer not only supplies nutrients needed by plants, restores fertility, softens the soil and enhances cold resistance, but also prevents nutrient leaching and increases the effectiveness of nutrients. has been known
하지만, 부산물 비료는 상기한 장점 등으로 인해 중요한 의미가 있지만, 화학비료에 비해 중량 대비 질소, 인 또는 칼륨 등의 함량이 작고, 작물의 생장에 필수적으로 필요한 아미노산과 각종 미네랄이 충분치 못하여, 영양제로서의 역할이 제한적으로 작용하여 작물의 균형적인 성장에 방해가 되고, 부산물 비료가 공급된 지역의 작물에 면역력 감소로 인한 병충해가 자주 발생하여 작물의 생산 수량이 감소하며, 작물의 맛과 품질도 함께 저하되는 문제가 있다.However, although by-product fertilizers have an important meaning due to the above advantages, they have a lower content of nitrogen, phosphorus, or potassium by weight compared to chemical fertilizers, and do not have enough amino acids and various minerals essential for the growth of crops. Its role is limited, which interferes with the balanced growth of crops, and pests and diseases often occur in crops in areas where by-product fertilizer is supplied due to reduced immunity, reducing the yield of crops and degrading the taste and quality of crops. there is a problem
따라서, 상기한 바와 같은 문제점을 해결할 수 있도록 작물 생장을 위해 균형있는 영양소 및 유효성분을 공급할 수 있으면서도, 병충해 발생을 효과적으로 방지할 뿐만 아니라, 식물의 생육을 증대시킬 수 있는 비료에 관한 연구가 필요한 실정이다.Therefore, it is necessary to study fertilizers that can supply balanced nutrients and active ingredients for crop growth in order to solve the above problems, effectively prevent the occurrence of pests and diseases, and increase plant growth. am.
본 발명은 셀레늄, 게르마늄 및 바나듐을 포함하는 나노입자 미네랄을 이용하여 액상비료를 제조함으로써, 새싹작물의 잎뿐만 아니라 뿌리로 직접 흡수되어 새싹작물의 발근 및 생장이 촉진되고, 이로 인해 작황이 증대되며, 균형있는 영양성분을 공급할 수 있고, 새싹작물의 생육을 효과적으로 증대시킬 수 있는 새싹작물 재배용 미네랄 나노 액상비료 및 그 제조방법을 제공하는데 있다.In the present invention, by preparing a liquid fertilizer using nanoparticle minerals including selenium, germanium and vanadium, it is directly absorbed into the roots as well as the leaves of sprout crops to promote rooting and growth of sprout crops, thereby increasing crop yield It is to provide a mineral nano-liquid fertilizer for sprout crops that can supply balanced nutrients and effectively increase the growth of sprout crops and a manufacturing method thereof.
또한, 본 발명은 곤충이나 해충이 새싹작물이 재배되는 토양에 모이거나 번식하는 것을 방지하고, 청결한 상태로 새싹작물의 모종을 발아시켜 재배할 수 있으며, 비료 또는 수분의 흡수 효율이 향상되어 작물의 생산량이 증대될 수 있는 새싹작물 재배용 미네랄 나노 액상비료 및 그 제조방법을 제공하는데 있다.In addition, the present invention prevents insects or pests from gathering or breeding in the soil where sprout crops are grown, can germinate and cultivate seedlings of sprout crops in a clean state, and improves the absorption efficiency of fertilizers or moisture, It is to provide a mineral nano-liquid fertilizer for sprout crops that can increase production and a manufacturing method thereof.
본 발명이 해결하고자 하는 다양한 과제들은 이상에서 언급한 과제들에 제한되지 않으며, 언급되지 않은 또 다른 과제들은 아래의 기재로부터 당업자에게 명확하게 이해될 수 있을 것이다.Various problems to be solved by the present invention are not limited to the above-mentioned problems, and other problems not mentioned will be clearly understood by those skilled in the art from the following description.
본 발명에 따른 새싹작물 재배용 미네랄 나노 액상비료는 나노입자 미네랄, 비드, 미생물담체, 항충추출물, 혼합비료 및 해안 심층 암반수를 포함한다.The mineral nano-liquid fertilizer for sprout crops according to the present invention includes nanoparticle minerals, beads, microbial carriers, anti-worm extracts, mixed fertilizers, and deep coastal bedrock water.
상기 나노입자 미네랄 1 내지 5 중량부, 비드 0.5 내지 1.5 중량부, 미생물담체 1 내지 3 중량부, 항충추출물 0.1 내지 1 중량부, 혼합비료 5 내지 15 중량부 및 해안 심층 암반수 100 내지 200 중량부의 중량 비율로 포함될 수 있다.1 to 5 parts by weight of the nanoparticle minerals, 0.5 to 1.5 parts by weight of beads, 1 to 3 parts by weight of microbial carrier, 0.1 to 1 part by weight of antiworm extract, 5 to 15 parts by weight of mixed fertilizer, and 100 to 200 parts by weight of coastal bedrock water may be included in proportion.
상기 나노입자 미네랄은 셀레늄 1 내지 10 중량부, 게르마늄 1 내지 10 중량부 및 바나듐 1 내지 10 중량부의 중량 비율로 포함될 수 있다.The nanoparticle mineral may be included in a weight ratio of 1 to 10 parts by weight of selenium, 1 to 10 parts by weight of germanium, and 1 to 10 parts by weight of vanadium.
또한, 본 발명에 따른 새싹작물 재배용 미네랄 나노 액상비료의 제조방법은 미네랄 나노 액상비료를 제조하기 위한 재료를 준비하는 재료 준비 단계(S100); 상기 준비된 재료를 계량하여 혼합하는 혼합 단계(S200); 및 상기 혼합된 재료를 숙성하여 미네랄 나노 액상비료를 제조하는 숙성 단계(S300)를 포함한다.In addition, the method for manufacturing a mineral nano-liquid fertilizer for sprout crops according to the present invention includes a material preparation step (S100) of preparing a material for preparing a mineral nano-liquid fertilizer; Mixing step (S200) of weighing and mixing the prepared material; and an aging step (S300) of preparing a mineral nano-liquid fertilizer by aging the mixed material.
상기 재료 준비 단계(S100)에서 상기 재료는 나노입자 미네랄, 비드, 미생물담체, 항충추출물, 혼합비료 및 해안 심층 암반수가 준비되며, 상기 혼합 단계(S200)는 상기 나노입자 미네랄 1 내지 5 중량부, 비드 0.5 내지 1.5 중량부, 미생물담체 1 내지 3 중량부, 항충추출물 0.1 내지 1 중량부, 혼합비료 5 내지 15 중량부 및 해안 심층 암반수 100 내지 200 중량부의 중량 비율로 포함되고, 상기 나노입자 미네랄은 셀레늄 1 내지 10 중량부, 게르마늄 1 내지 10 중량부 및 바나듐 1 내지 10 중량부의 중량 비율로 포함되고, 상기 숙성 단계(S300)에서는 상기 혼합된 재료를 8 내지 12℃의 온도에서 10 내지 30시간 동안 숙성할 수 있다.In the material preparation step (S100), the materials are prepared with nanoparticle minerals, beads, microbial carriers, antiparasitic extracts, mixed fertilizers, and deep coastal bedrock water, and in the mixing step (S200), 1 to 5 parts by weight of the nanoparticle minerals, 0.5 to 1.5 parts by weight of beads, 1 to 3 parts by weight of microbial carrier, 0.1 to 1 part by weight of antibiotic extract, 5 to 15 parts by weight of mixed fertilizer, and 100 to 200 parts by weight of deep coastal bedrock water, the nanoparticle minerals 1 to 10 parts by weight of selenium, 1 to 10 parts by weight of germanium, and 1 to 10 parts by weight of vanadium, and in the aging step (S300), the mixed material is mixed at a temperature of 8 to 12 ° C. for 10 to 30 hours can mature
기타 실시 예들의 구체적인 사항들은 상세한 설명에 포함되어 있다.Details of other embodiments are included in the detailed description.
본 발명에 따른 새싹작물 재배용 미네랄 나노 액상비료의 제조방법은 셀레늄, 게르마늄 및 바나듐을 포함하는 나노입자 미네랄을 이용하여 액상비료를 제조함으로써, 새싹작물의 잎뿐만 아니라 뿌리로 직접 흡수되어 새싹작물의 발근 및 생장이 촉진되고, 이로 인해 작황이 증대되며, 균형있는 영양성분을 공급할 수 있고, 새싹작물의 생육을 효과적으로 증대시킬 수 있는 미네랄 나노 액상비료를 제조할 수 있다.The method for producing a mineral nano-liquid fertilizer for sprout crops according to the present invention prepares a liquid fertilizer using nanoparticle minerals including selenium, germanium, and vanadium, which is directly absorbed into the roots as well as the leaves of the sprout crops, thereby rooting the sprout crops. And it is possible to prepare a mineral nano-liquid fertilizer that promotes growth, thereby increasing yield, supplying balanced nutrients, and effectively increasing the growth of sprout crops.
또한, 본 발명에 따른 새싹작물 재배용 미네랄 나노 액상비료는 곤충이나 해충이 새싹작물이 재배되는 토양에 모이거나 번식하는 것을 방지하고, 청결한 상태로 새싹작물의 모종을 발아시켜 재배할 수 있으며, 비료 또는 수분의 흡수 효율이 향상되어 작물의 생산량이 증대될 수 있다.In addition, the mineral nano-liquid fertilizer for sprout crops according to the present invention prevents insects or pests from gathering or breeding in the soil where sprout crops are grown, can germinate and cultivate seedlings of sprout crops in a clean state, and can be used as a fertilizer or The efficiency of water absorption is improved, so the yield of crops can be increased.
본 발명의 기술적 사상의 실시예는, 구체적으로 언급되지 않은 다양한 효과를 제공할 수 있다는 것이 충분히 이해될 수 있을 것이다.It will be fully understood that embodiments of the technical idea of the present invention can provide various effects not specifically mentioned.
도 1은 본 발명에 따른 새싹작물 재배용 미네랄 나노 액상비료를 보여주는 사진이다.
도 2는 본 발명에 따른 새싹작물 재배용 미네랄 나노 액상비료의 제조방법을 개략적으로 설명하기 위한 순서도이다.
도 3은 실시예에 따라 제조된 미네랄 나노 액상비료를 새싹보리에 시비한 후 게르마늄, 셀레늄, 아연의 함량을 분석한 시험성적서이다.
도 4는 실시예에 따라 제조된 미네랄 나노 액상비료를 새싹완두콩에 시비한 후 게르마늄, 셀레늄, 아연의 함량을 분석한 시험성적서이다.
도 5는 실시예에 따라 제조된 미네랄 나노 액상비료를 새싹브로콜리에 시비한 후 게르마늄, 셀레늄, 아연의 함량을 분석한 시험성적서이다.
도 6은 실시예에 따라 제조된 미네랄 나노 액상비료를 새싹밀에 시비한 후 게르마늄, 셀레늄, 아연의 함량을 분석한 시험성적서이다.
도 7a는 실시예에 따른 비료를 육묘에 시비한 후 육묘의 생육을 보여주는 사진이다.
도 7b는 비교예에 따른 비료를 육묘에 시비한 후 육묘의 생육을 보여주는 사진이다.1 is a photograph showing a mineral nano-liquid fertilizer for sprout crop cultivation according to the present invention.
2 is a flowchart schematically illustrating a method of manufacturing a mineral nano-liquid fertilizer for sprout crop cultivation according to the present invention.
3 is a test report in which the contents of germanium, selenium, and zinc were analyzed after the mineral nano liquid fertilizer prepared according to the example was applied to sprout barley.
4 is a test report of analyzing the contents of germanium, selenium, and zinc after applying the mineral nano-liquid fertilizer prepared according to the embodiment to sprout peas.
5 is a test report of analyzing the contents of germanium, selenium, and zinc after applying the mineral nano liquid fertilizer prepared according to the embodiment to sprout broccoli.
6 is a test report of analyzing the contents of germanium, selenium, and zinc after applying the mineral nano liquid fertilizer prepared according to the embodiment to sprout wheat.
Figure 7a is a photograph showing the growth of seedlings after the fertilizer according to the embodiment is applied to the seedlings.
Figure 7b is a photograph showing the growth of seedlings after fertilizing the fertilizer according to the comparative example to the seedlings.
본 발명의 이점 및 특징, 그리고 그것들을 달성하는 방법은 상세하게 후술되어 있는 실시예를 참조하면 명확해질 것이다. 그러나 본 발명은 여기서 설명되는 실시예들에 한정되지 않고 다른 형태로 구체화될 수도 있다. 오히려, 여기서 소개되는 실시예들은 개시된 내용이 철저하고 완전해질 수 있도록 그리고 당업자에게 본 발명의 사상이 충분히 전달될 수 있도록 하기 위해 제공되는 것이다.The advantages and features of the present invention, and how to achieve them, will become clear with reference to the detailed description of the embodiments below. However, the present invention is not limited to the embodiments described herein and may be embodied in other forms. Rather, the embodiments introduced herein are provided so that the disclosed content will be thorough and complete and the spirit of the present invention will be sufficiently conveyed to those skilled in the art.
본 출원에서 사용한 용어는 단지 특정한 실시예를 설명하기 위해 사용된 것으로, 본 발명을 한정하려는 의도가 아니다. 단수의 표현은 문맥상 명백하게 다르게 뜻하지 않는 한, 복수의 표현을 포함한다.Terms used in this application are only used to describe specific embodiments, and are not intended to limit the present invention. Singular expressions include plural expressions unless the context clearly dictates otherwise.
다르게 정의되지 않는 한, 기술적이거나 과학적인 용어를 포함해서 여기서 사용되는 모든 용어들은 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에 의해 일반적으로 이해되는 것과 동일한 의미가 있다. 일반적으로 사용되는 사전에 정의되어 있는 것과 같은 용어들은 관련 기술의 문맥상 가지는 의미와 일치하는 의미가 있는 것으로 해석되어야 하며, 본 출원에서 명백하게 정의하지 않는 한, 이상적이거나 과도하게 형식적인 의미로 해석되지 않는다.Unless defined otherwise, all terms used herein, including technical or scientific terms, have the same meaning as commonly understood by one of ordinary skill in the art to which the present invention belongs. Terms such as those defined in commonly used dictionaries should be interpreted as having meanings consistent with the meanings in the context of the related art, and unless explicitly defined in this application, they should not be interpreted in ideal or excessively formal meanings. don't
이하, 첨부된 도면을 참조하여 본 발명에 따른 새싹작물 재배용 미네랄 나노 액상비료에 대하여 바람직한 실시예를 들어 상세하게 설명한다.Hereinafter, with reference to the accompanying drawings, a preferred embodiment of the mineral nano-liquid fertilizer for sprout crops according to the present invention will be described in detail.
도 1은 본 발명에 따른 새싹작물 재배용 미네랄 나노 액상비료를 보여주는 사진이다.1 is a photograph showing a mineral nano-liquid fertilizer for sprout crop cultivation according to the present invention.
도 1을 참조하면, 본 발명에 따른 새싹작물 재배용 미네랄 나노 액상비료는 나노입자 미네랄을 포함한다.Referring to Figure 1, the mineral nano-liquid fertilizer for sprout crops according to the present invention includes nanoparticle minerals.
상기 나노입자 미네랄은 나노 단위로 분쇄된 셀레늄, 게르마늄 및 바나듐으로 이루어진 미네랄이 이용될 수 있고, 상기 나노입자 미네랄은 새싹작물의 잎과 뿌리 등에 직접 흡수되어 영양분을 제공하고 새싹작물의 생육을 촉진할 수 있는데, 상기 나노입자 미네랄은 셀레늄 1 내지 10 중량부, 게르마늄 1 내지 10 중량부 및 바나듐 1 내지 10 중량부의 중량 비율로 포함될 수 있다.The nanoparticle mineral may be a mineral composed of selenium, germanium, and vanadium pulverized into nano units, and the nanoparticle mineral is directly absorbed into the leaves and roots of sprout crops to provide nutrients and promote the growth of sprout crops. The nanoparticle mineral may be included in a weight ratio of 1 to 10 parts by weight of selenium, 1 to 10 parts by weight of germanium, and 1 to 10 parts by weight of vanadium.
상기 셀레늄은 인체의 간, 신장 심장, 비장에 분포되어 있고, 몸 안의 유해산소를 없애는 강력한 항산화(抗酸化) 효소인 글루타치온 퍼옥시다제의 구성성분으로 세포 내 과산화물의 농도를 낮추거나 제거하는 작용으로, 면역증강효과, 항순환기효과, 항바이러스효과 등이 있다. 또한, 암예방과 치료, 간경화증의 간 재생, 노화지연 등의 효과가 있으며, 비소, 수은, 납, 카드뮴 등의 중금속을 제거하거나 해독하는 기능을 한다.The selenium is distributed in the liver, kidney heart, and spleen of the human body and is a component of glutathione peroxidase, a powerful antioxidant enzyme that eliminates free radicals in the body. , immune enhancing effect, anticirculatory effect, and antiviral effect. In addition, it has effects such as cancer prevention and treatment, liver regeneration in liver cirrhosis, and aging delay, and functions to remove or detoxify heavy metals such as arsenic, mercury, lead, and cadmium.
상기 셀레늄은 주로 셀레노메치오닌과 셀레노시스테인 등의 셀레노 아미노산형태로 존재하며, 유기 셀레늄은 무기 셀레늄보다 체내 흡수율이 높다. 식물은 토양으로부터 흡수한 셀레늄을 이용하여 셀레노메치오닌을 생합성작용 후 단백질에 저장한다. 동물은 메치오닌을 생합성할 수 없기 때문에, 식물성을 섭취하여 셀레노메치오닌을 간에서 셀레노시스테인으로 전환시켜 단백질합성에 이용하거나 몸 밖으로 배설하게 된다. 셀레늄을 섭취하면 인체 내 비타민 E 섭취를 줄일 수 있으며, 항산화력이 비타민 E의 2000배가 된다고 한다. 상기 셀레늄의 결핍은 주로 어린이들과 가임기의 여성들이 걸리며, 심장질병발생, 암 면역기능 저하, 적혈구기능 저하, 근육통, 심근의 퇴화, 췌장기능퇴화를 가져올 수 있다.The selenium mainly exists in the form of selenoamino acids such as selenomethionine and selenocysteine, and organic selenium has a higher absorption rate in the body than inorganic selenium. Plants use selenium absorbed from the soil to store selenomethionine as a protein after biosynthesis. Since animals cannot biosynthesize methionine, they consume plants and convert selenomethionine to selenocysteine in the liver, which is used for protein synthesis or excreted outside the body. Taking selenium can reduce the intake of vitamin E in the body, and it is said that its antioxidant power is 2000 times that of vitamin E. The deficiency of selenium mainly affects children and women of childbearing age, and can lead to heart disease, cancer immune function decline, red blood cell function decline, muscle pain, myocardial degeneration, and pancreatic function degeneration.
상기 게르마늄(Germanium)은 자연계에서 동·식물의 체내 뿐만 아니라 흙과 물 등에 분포하며 전자산업분야에서 광범위하게 이용되고 있는데, 상기 게르마늄은 살아있는 모든 식물과 동물세포에 유기물이나 무기물 형태로 존재하는 미량 원소로, 석탄, 인삼, 알로에, 마늘 등의 여러 가지 식물에도 게르마늄이 많이 포함되어 있으며, 자연 식품 이외에도 캔참치, 우유, 버터 등과 같은 가공식품을 통해서도 섭취할 수 있으며, 섭취된 게르마늄은 96% 정도가 인체에 흡수된다.Germanium is distributed in soil and water as well as in the body of animals and plants in nature and is widely used in the electronics industry. Germanium is a trace element present in organic or inorganic form in all living plants and animal cells. A lot of germanium is also contained in various plants such as furnace, coal, ginseng, aloe, and garlic. In addition to natural foods, it can also be consumed through processed foods such as canned tuna, milk, and butter. Ingested germanium accounts for about 96%. absorbed by the body
또한, 유기 게르마늄의 경우 항암 및 인터페론 유발효과에 의한 면역기능 활성이 보고 되고 있으며, 다양한 실험동물을 대상으로 한 연구결과에서 면역기능 향상과 정상화 효과가 있는 것으로 확인되고 있다.In addition, in the case of organic germanium, immune function activation by anti-cancer and interferon-inducing effects has been reported, and it has been confirmed that there is an effect of improving and normalizing immune function in the results of studies targeting various experimental animals.
이들 면역기능 활성화 기작은 주로 활성산소 공급과 자유라디칼 억제 및 중금속 원소의 무독화 기작에 의한 것으로 알려지고 있으며, 유기 게르마늄 화합물은 동물을 대상으로 한 연구결과에서 다양한 항암효과와 T세포 활성, B 세포 활성, NK 세포 활성과 대식세포 및 림프구의 활성화에 영향을 미치는 것으로 확인되고 있으며, 게르마늄 함유 건강식품은 강력한 항암효과가 있는 것으로 보고 된 바 있다.It is known that these immune function activation mechanisms are mainly due to the supply of active oxygen, inhibition of free radicals, and detoxification of heavy metal elements, and organic germanium compounds have various anticancer effects, T cell activity, and B cell activity, NK cell activity, and activation of macrophages and lymphocytes, and germanium-containing health foods have been reported to have strong anti-cancer effects.
상기 바나듐(Vanadium)은 무기질 물질의 미네랄 종류로, 티타늄과 마찬가지로 열역학적으로는 반응성이 큰 금속이나 실온에서는 잘 부식되지 않으며, 알칼리, 황산, 염산 등에 대해서도 안정한다. 사람의 몸에는 약 0.001g 이하의 바나듐 성분이 들어있으며, 사람과 포유동물에는 필수 미량 영양소로 여겨진다.Vanadium is a type of mineral of inorganic material, and like titanium, it is a thermodynamically reactive metal, but it does not corrode well at room temperature and is stable against alkali, sulfuric acid, hydrochloric acid, and the like. The human body contains less than about 0.001 g of vanadium, and it is considered an essential micronutrient for humans and mammals.
또한, 상기 바나듐은 인체에 필수적인 미네랄 성분으로서 인슐린의 활성을 변화시키거나 인슐린과 유사하게 작용하거나 글루코오스-6-포스파타제(glucose-6-phosphatase)의 활성을 변화시켜 포도당 대사에 영향을 주며, 이와 같은 역할로 당뇨병 치료 및 예방 효과를 갖으며, 또한 콜레스테롤의 생합성 과정을 방해하여 동맥 경화증(Atherosclerosis)을 예방하는 효과도 있는 것으로 알려져 있고, 특히 바나듐 결핍시 심혈관 및 심장질환을 일으키는 것으로 알려져 있다.In addition, the vanadium is an essential mineral component for the human body and affects glucose metabolism by changing the activity of insulin, acting similarly to insulin, or changing the activity of glucose-6-phosphatase. It is known to have an effect of treating and preventing diabetes as a role, and also has an effect of preventing atherosclerosis by interfering with the biosynthetic process of cholesterol, and is known to cause cardiovascular and heart diseases in particular when vanadium is deficient.
또한, 본 발명에 따른 새싹작물 재배용 미네랄 나노 액상비료는 상기 나노입자 미네랄 이외에, 비드, 미생물담체, 항충추출물, 혼합비료 및 해안 심층 암반수를 더 포함할 수 있다.In addition, the mineral nano-liquid fertilizer for sprout crops according to the present invention may further include beads, microbial carriers, anti-worm extracts, mixed fertilizers, and deep coastal bedrock water in addition to the nanoparticle minerals.
또한, 본 발명에 따른 새싹작물 재배용 미네랄 나노 액상비료는 나노입자 미네랄 1 내지 5 중량부, 비드 0.5 내지 1.5 중량부, 미생물담체 1 내지 3 중량부, 항충추출물 0.1 내지 1 중량부, 혼합비료 5 내지 15 중량부 및 해안 심층 암반수 100 내지 200 중량부의 중량 비율로 포함될 수 있다.In addition, the mineral nano-liquid fertilizer for sprout crops according to the present invention contains 1 to 5 parts by weight of nanoparticle minerals, 0.5 to 1.5 parts by weight of beads, 1 to 3 parts by weight of a microbial carrier, 0.1 to 1 part by weight of an insecticide extract, and 5 to 5 parts by weight of a mixed fertilizer. It may be included in a weight ratio of 15 parts by weight and 100 to 200 parts by weight of coastal bedrock water.
상기 비드는 수분이나 영양분을 빠른 속도로 흡수 및 보유하고, 상기 비드에 흡수된 수분이나 영양분은 새싹작물에 장기간에 걸쳐 일정하게 공급될 수 있다.The beads absorb and retain moisture or nutrients at a high speed, and the moisture or nutrients absorbed by the beads can be constantly supplied to sprout crops over a long period of time.
예를 들어, 상기 비드는 하기의 방법으로 제조된 비드가 사용될 수 있다.For example, beads manufactured by the following method may be used as the beads.
상기 비드를 제조하기 위하여, 먼저, 수용성 에틸렌계 불포화 단량체, 셀룰로오스계 화합물, 카르복시(C1-C5)알킬 키토산, 자몽종자추출물, 친수성 첨가제 및 가교제가 일정한 중량비율로 혼합된 혼합용액을 제조할 수 있다.In order to prepare the beads, first, a mixed solution in which water-soluble ethylenically unsaturated monomers, cellulose-based compounds, carboxy (C1-C5) alkyl chitosan, grapefruit seed extract, hydrophilic additives and crosslinking agents are mixed in a constant weight ratio may be prepared. .
상기 단계에서 상기 수용성 에틸렌계 불포화 단량체는 흡수성 중합체에 사용되는 통상의 수용성 에틸렌계 불포화 단량체가 사용될 수 있는데, 예를 들어, 메타아크릴산, 무수말레인산, 크로톤산, 이타콘산, 2-아크릴로일에탄 술폰산, 2-메타아크릴로일에탄술폰산, 2-메타아크릴로일프로판술폰산 또는 2-메타아크릴아미드-2-메틸 프로판 술폰산의 음이온성 단량체와 그 염; 메타아크릴아미드, N-치환메타아크릴레이트, 2-히드록시에틸메타아크릴레이트, 2-히드록시프로필메타아크릴레이트 및 메톡시폴리에틸렌글리콜메타아크릴레이트로 이루어진 군에서 선택된 어느 하나 이상이 사용될 수 있다.In the above step, the water-soluble ethylenically unsaturated monomers may be conventional water-soluble ethylenically unsaturated monomers used in water absorbent polymers, for example, methacrylic acid, maleic anhydride, crotonic acid, itaconic acid, 2-acryloylethanesulfonic acid , 2-methacryloylethanesulfonic acid, 2-methacryloylpropanesulfonic acid or 2-methacrylamide-2-methylpropanesulfonic acid anionic monomers and salts thereof; At least one selected from the group consisting of methacrylamide, N-substituted methacrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate and methoxy polyethylene glycol methacrylate may be used.
상기 셀룰로오스계 화합물은 완전생분해가 가능한 환경 친화적인 천연섬유로 무독성인 비드를 제조할 수 있는 것으로, 예를 들어, 상기 셀룰로오스계 화합물은 메틸 셀룰로오스, 에틸 셀룰로오스, 프로필 셀룰로오스, 카복시메틸 셀룰로오스, 하이드록시에틸 셀룰로오스, 메틸하이드록시에틸 셀룰로오스, 메틸하이드록시프로필 셀룰로오스 및 에틸하이드록시에틸 셀룰로오스로 이루어진 군에서 선택된 어느 하나 이상이 사용될 수 있다.The cellulose-based compound is a completely biodegradable, environmentally friendly natural fiber that can produce non-toxic beads, for example, the cellulose-based compound is methyl cellulose, ethyl cellulose, propyl cellulose, carboxymethyl cellulose, hydroxyethyl Any one or more selected from the group consisting of cellulose, methylhydroxyethyl cellulose, methylhydroxypropyl cellulose and ethylhydroxyethyl cellulose may be used.
상기 카르복시(C1-C5)알킬 키토산은 비드에 항균성을 부여하기 위하여 첨가되는 것으로, 셀룰로오스와 유사한 체인구조를 가지고 있는데, 예를 들어, 상기 카르복시(C1-C5)알킬 키토산은 카르복시메틸 키토산 또는 카르복시에틸 키토산 중에서 선택된 어느 하나 이상이 사용될 수 있다.The carboxy (C1-C5) alkyl chitosan is added to impart antibacterial properties to the beads, and has a chain structure similar to that of cellulose. For example, the carboxy (C1-C5) alkyl chitosan is carboxymethyl chitosan or carboxyethyl Any one or more selected from chitosan may be used.
상기 자몽종자추출물(GSE, Grapefruit seed extract)은 항균, 항진균, 항산화 효과가 있고, 독성 실험에서는 독성이 없는 것으로 확인되었다. 특히, 상기 자몽종자추출물의 성분 중 ascorbic acid, ascorbyl palmitate 및 tocopherol 등이 부패성 및 병원성 미생물의 세포벽 및 세포막의 기능을 약화시키고 효소활성을 억제하며, DNA/RNA에서 비롯되는 세포증식 기작을 방지하여 세균, 효모 및 곰팡이 등에 살균 효과를 나타나며 곰팡이의 생육 및 독소합성에 저해효과를 가진다.The grapefruit seed extract (GSE, Grapefruit seed extract) has antibacterial, antifungal, and antioxidant effects, and was confirmed to be non-toxic in a toxicity test. In particular, among the components of the grapefruit seed extract, ascorbic acid, ascorbyl palmitate, and tocopherol weaken the functions of cell walls and cell membranes of putrefactive and pathogenic microorganisms, inhibit enzyme activity, and prevent cell proliferation mechanisms derived from DNA/RNA, thereby preventing bacterial growth. It has a bactericidal effect on yeast and mold, and has an inhibitory effect on the growth of mold and toxin synthesis.
상기 친수성 첨가제는 고흡수성 수지로 형성된 후 상기 비드 내에서 용출됨으로써, 상기 고흡수성 수지 내부에 미세 공간을 형성하고, 상기 흡수성 중합체 내부에 형성된 미세 공간에 의해 수분이나 영양성분의 흡수력 및 보관력을 증대시킬 수 있다.The hydrophilic additive is formed of the superabsorbent polymer and then eluted from the beads, thereby forming a microspace inside the superabsorbent polymer and increasing the absorption and storage capacity of moisture or nutrients by the microspace formed inside the superabsorbent polymer. can make it
상기 친수성 첨가제는 소디움도데실설페이트, 인산염, 솔비탄 모노라우레이트, 솔비탄 모노팔미테이트, 솔비탄 모노스테아레이트 및 솔비탄 모노올레이트로 이루어진 군에서 선택된 어느 하나 이상이 사용될 수 있다.As the hydrophilic additive, at least one selected from the group consisting of sodium dodecyl sulfate, phosphate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, and sorbitan monooleate may be used.
상기 가교제는 비드의 흡수속도 및 수분을 흡수하여 팽윤된 상태에서의 안정된 겔 강도를 유지하기 위하여 첨가되는 것으로, 예를 들어, 상기 가교제로는 N,N'-메틸렌비스메타아크릴레이트, 에틸렌옥시메타아크릴레이트, 폴리에틸렌옥시메타아크릴레이트, 프로필렌옥시메타아크릴레이트, 글리세린 디아크릴레이트, 글리세린 트리아크릴레이트, 트리메티롤 트리아크릴레이트, 트리알릴아민, 트리아릴시아누레이트, 트리알릴이소시아네이트, 폴리에틸렌글리콜, 디에틸렌글리콜 및 프로필렌글리콜로 이루어진 군에서 선택된 어느 하나 이상이 사용될 수 있다.The crosslinking agent is added to maintain a stable gel strength in a swollen state by absorbing moisture and absorption rate of beads. For example, the crosslinking agent is N,N'-methylenebismethacrylate, ethyleneoxymeth Acrylates, polyethyleneoxy methacrylate, propylene oxy methacrylate, glycerin diacrylate, glycerin triacrylate, trimethylol triacrylate, triallylamine, triarylcyanurate, triallyl isocyanate, polyethylene glycol, di Any one or more selected from the group consisting of ethylene glycol and propylene glycol may be used.
본 발명에서 상기 혼합용액은 수용성 에틸렌계 불포화 단량체 80 내지 120 중량부, 셀룰로오스계 화합물 10 내지 30 중량부, 카르복시(C1-C5)알킬 키토산 5 내지 15 중량부, 자몽종자추출물 1 내지 3 중량부, 친수성 첨가제 5 내지 15 중량부 및 가교제 1 내지 3 중량부의 중량비율로 혼합될 수 있다.In the present invention, the mixed solution contains 80 to 120 parts by weight of water-soluble ethylenically unsaturated monomers, 10 to 30 parts by weight of cellulose compounds, 5 to 15 parts by weight of carboxy (C1-C5) alkyl chitosan, 1 to 3 parts by weight of grapefruit seed extract, 5 to 15 parts by weight of the hydrophilic additive and 1 to 3 parts by weight of the crosslinking agent may be mixed in a weight ratio.
다음으로, 상기 수용성 에틸렌계 불포화 단량체, 셀룰로오스계 화합물, 카르복시(C1-C5)알킬 키토산, 친수성 첨가제 및 가교제가 혼합된 혼합용액에 물을 첨가한 후 교반할 수 있다.Next, water may be added to the mixed solution in which the water-soluble ethylenically unsaturated monomer, cellulose-based compound, carboxy (C1-C5) alkyl chitosan, hydrophilic additive, and crosslinking agent are mixed, followed by stirring.
상기 단계에서 상기 물은 상기 수용성 에틸렌계 불포화 단량체, 셀룰로오스계 화합물, 카르복시(C1-C5)알킬 키토산, 친수성 첨가제 및 가교제를 용해 및 분산하기 위하여 사용될 수 있는데, 상기 수용성 에틸렌계 불포화 단량체, 셀룰로오스계 화합물, 카르복시(C1-C5)알킬 키토산, 친수성 첨가제 및 가교제로 이루어진 혼합용액에 물 600 내지 800 중량부를 첨가한 후 교반할 수 있다.In the above step, the water may be used to dissolve and disperse the water-soluble ethylenically unsaturated monomer, cellulose-based compound, carboxy (C1-C5) alkyl chitosan, hydrophilic additive, and crosslinking agent, wherein the water-soluble ethylenically unsaturated monomer, cellulose-based compound , Carboxy (C1-C5) alkyl chitosan, 600 to 800 parts by weight of water may be added to a mixed solution consisting of a hydrophilic additive and a crosslinking agent, followed by stirring.
그 다음으로, 상기 물이 첨가되어 교반된 혼합용액에 중합개시제를 첨가하여 중합체를 형성할 수 있다.Next, a polymer may be formed by adding a polymerization initiator to the mixed solution in which the water is added and stirred.
상기 단계에서 상기 중합개시제는 상기 물이 첨가되어 교반된 혼합용액의 반응을 촉진하기 위하여 첨가되는 것으로, 상기 중합개시제로는 벤조인 에테르(benzoin ether), 디알킬아세토페논(dialkyl acetophenone), 하이드록실 알킬케톤(hydroxyl alkylketone), 페닐글리옥실레이트(phenyl glyoxylate), 벤질디메틸케탈(Benzyl Dimethyl Ketal), 아실포스핀(acyl phosphine) 및 알파-아미노케톤(α-aminoketone)으로 이루어진 군에서 선택된 어느 하나 이상이 사용될 수 있고, 바람직하게는 2,4,6-트리메틸-벤조일-트리메틸 포스핀 옥사이드(2,4,6-trimethyl-benzoyl-trimethyl phosphine oxide)가 사용될 수 있다.In the above step, the polymerization initiator is added to promote the reaction of the mixed solution in which the water is added and stirred. Examples of the polymerization initiator include benzoin ether, dialkyl acetophenone, hydroxyl At least one selected from the group consisting of hydroxyl alkylketone, phenyl glyoxylate, benzyl dimethyl ketal, acyl phosphine and α-aminoketone may be used, and preferably 2,4,6-trimethyl-benzoyl-trimethyl phosphine oxide may be used.
상기 단계에서 상기 중합개시제는 물이 첨가되어 교반된 혼합용액에 중합개시제 0.1 내지 1 중량부를 첨가함으로써 진행될 수 있다.In the above step, the polymerization initiator may proceed by adding 0.1 to 1 part by weight of the polymerization initiator to a mixed solution in which water is added and stirred.
이어서, 상기 중합체를 건조한 후 상기 건조된 중합체를 분쇄하여 비드를 제조할 수 있다.Then, after drying the polymer, beads may be prepared by pulverizing the dried polymer.
상기 단계에서 상기 중합체의 건조는 80 내지 90℃의 온도에서 수행될 수 있고, 상기 분쇄는 상기 건조된 중합체를 핀 밀(pin mill), 해머 밀(hammer mill), 스크류 밀(screw mill), 롤 밀(roll mill), 디스크 밀(disc mill) 또는 조그 밀(jog mill) 등과 같은 공지의 분쇄기를 이용하여 입경이 0.001 내지 1mm가 되도록 분쇄함으로써 진행될 수 있다.In the above step, drying of the polymer may be performed at a temperature of 80 to 90 ° C., and the pulverization may be performed by using a pin mill, a hammer mill, a screw mill, or a roll mill to grind the dried polymer. The mill (roll mill), disc mill (disc mill) or jog mill (jog mill) using a known grinder, such as by grinding to a particle diameter of 0.001 to 1mm can be carried out.
상기 미생물담체는 미네랄 나노 액상비료에 포함되어 시비 후 미생물이 부착하여 생장하고 공기 등이 통과하여 토양이 산성화되는 것을 방지할 수 있는데, 상기 미생물 담체는 하기의 방법으로 제조된 미생물 담체가 사용될 수 있다.The microbial carrier is included in the mineral nano-liquid fertilizer, and after fertilization, microorganisms attach and grow, and air can pass through to prevent acidification of the soil. The microbial carrier prepared by the following method can be used .
먼저, 상기 미생물담체를 제조하기 위하여, 황토, 부엽토, 활성탄, 생분해성 수지, 전분 및 물을 준비할 수 있다.First, in order to prepare the microbial carrier, ocher, humus soil, activated carbon, biodegradable resin, starch and water may be prepared.
상기 단계에서 황토, 부엽토, 활성탄, 생분해성 수지, 전분 및 물은 각각 황토 15 내지 25 중량부, 부엽토 2 내지 6 중량부, 활성탄 8 내지 12 중량부, 생분해성 수지 10 내지 20 중량부, 전분 50 내지 100 중량부 및 물 30 내지 70 중량부의 중량비율로 혼합될 수 있다.In the above step, ocher, humus, activated carbon, biodegradable resin, starch, and water were each 15 to 25 parts by weight of loess, 2 to 6 parts by weight of humus, 8 to 12 parts by weight of activated carbon, 10 to 20 parts by weight of biodegradable resin, and 50 parts by weight of starch. to 100 parts by weight and 30 to 70 parts by weight of water.
상기 황토는 자체온도 조절능력이 뛰어나고 원적외선을 다량 방출하여 인체에 유익한데, 주로 석영을 함유하는 한편, 그 밖에 휘석, 각섬석 등을 함유하는 황갈색 석회질로서, 분해력, 자정력, 흡수력 등이 뛰어나며, 인체에 유익한 약성을 가지는 것으로 알려져 왔다.The ocher has an excellent self-temperature control ability and emits a large amount of far-infrared rays, which is beneficial to the human body. It has been known to have beneficial properties for
최근에 들어서는 황토에 대한 과학적 규명에 많은 연구가 이루어져 황토가 많은 양의 원적외선을 방출하고 유해전자파를 차단할 수 있으며, 황토 한 수저의 양에는 수억 마리의 미생물과 다양한 효소들이 촘촘히 들어 있어, 이들이 순환작용을 하여 여러 면에서 인체에 매우 유익한 영향을 준다는 것이 과학적으로도 입증되었다.Recently, many studies have been conducted on the scientific identification of ocher, so ocher can emit a large amount of far-infrared rays and block harmful electromagnetic waves. It has been scientifically proven that it has a very beneficial effect on the human body in many ways.
상기 부엽토는 나뭇잎이나 작은 가지 등이 미생물에 의해 부패, 분해되어 생긴 흙을 말하고, 원예에 많이 사용되며 배수가 좋고 수분과 양분을 많이 가지고 있다. 또한, 상기 부엽토는 다공질(多孔質)이므로 배수가 좋고 수분과 양분의 보축력(保蓄力)이 강하며, 지온(地溫)을 높이고 영양분이 풍부하고, 인공적으로 낙엽을 모아 쌓아서 부패시킨 것과 자연적으로 부패, 분해된 것이 있으며, 일반적으로는 침엽수(針葉樹)보다 활엽수(闊葉樹)의 낙엽이 유효성분도 많고 부숙(腐熟)이 빨리 되어 좋다.The humus refers to soil formed by decay and decomposition of leaves or small branches by microorganisms, and is widely used in horticulture and has good drainage and a lot of moisture and nutrients. In addition, since the humus soil is porous, it has good drainage, has strong water and nutrient retention, increases the temperature of the ground, is rich in nutrients, and artificially collects and stacks fallen leaves to rot. There are naturally decayed and decomposed ones, and in general, the leaves of broad-leaved trees have more active ingredients than conifers and are good because they decay quickly.
상기 활성탄은 미세세공이 발달된 탄소집합체로서, 활성화과정에 의해 내부 표면적을 변화시킬 수 있으며, 내부의 탄소 원자 관능 기에 의해 주위 액체 또는 기체와 흡착이 이루어지는 흡수성과 흡착성이 우수한 성질을 갖는다.The activated carbon is a carbon aggregate with developed micropores, which can change its internal surface area by an activation process, and has excellent absorbency and adsorption properties in which adsorption with surrounding liquids or gases is achieved by functional groups of carbon atoms therein.
예를 들어, 상기 활성탄은 경도 93 질량분율% 이상, 충전밀도 0.51 내지 0.53g/ml, 비표면적 800 내지 900m2/g, 세공분포는 세공직경이 4Å 내지 7Å, 요오드 흡착력 1,100mg/g 이상, 세공용적 0.51ml/g, pH 7~7.8, 페놀 흡착력 17.5ml/g, M·B 탈색력 153ml/g 이상인 것이 사용될 수 있다.For example, the activated carbon has a hardness of 93% by mass or more, a packing density of 0.51 to 0.53g/ml, a specific surface area of 800 to 900m 2 /g, a pore distribution of 4Å to 7Å in pore diameter, an iodine adsorption capacity of 1,100mg/g or more, Pore volume 0.51ml/g, pH 7-7.8, phenol adsorption power 17.5ml/g, M B decolorization power 153ml/g or more may be used.
상기 생분해성 수지는 자연계에 존재하는 미생물(박테리아, 곰팡이 및 조류)에 의해 물과 이산화탄소 등으로 완전히 분해되는 수지로, 예를 들어, 상기 생분해성 수지는 폴리락트산(poly lactic acid; PLA) 또는 폴리카프로락톤(Polycaprolactone; PCL) 중에서 선택된 어느 하나 이상이 사용될 수 있다.The biodegradable resin is a resin that is completely decomposed into water and carbon dioxide by microorganisms (bacteria, fungi, and algae) existing in nature. For example, the biodegradable resin is polylactic acid (PLA) or polylactic acid. Any one or more selected from caprolactone (Polycaprolactone; PCL) may be used.
상기 전분은 물과 혼합되어 결합제로 사용될 수 있는데, 예를 들어, 상기 전분으로는 옥수수 전분, 찰옥수수 전분, 타피오카 전분, 감자 전분 및 고구마 전분으로 이루어진 군에서 선택된 어느 하나 이상이 사용될 수 있다.The starch may be mixed with water and used as a binder. For example, as the starch, at least one selected from the group consisting of corn starch, waxy corn starch, tapioca starch, potato starch, and sweet potato starch may be used.
다음으로, 상기 황토, 부엽토, 활성탄, 생분해성 수지, 전분 및 물을 혼합하여 혼합물을 제조한 후, 상기 혼합물을 구형 또는 펠릿형으로 성형하여 성형체를 형성할 수 있다.Next, after preparing a mixture by mixing the loess, humus, activated carbon, biodegradable resin, starch, and water, the mixture may be molded into a sphere or pellet to form a molded body.
예를 들어, 상기 성형체는 입경이 0.001 내지 1mm가 되도록 성형될 수 있다.For example, the molded body may be molded to have a particle diameter of 0.001 to 1 mm.
그 다음으로, 상기 성형체를 가열하여 건조함으로써 미생물담체를 제조할 후 있다.Next, a microorganism carrier is prepared by heating and drying the molded body.
상기 단계에서는 상기 성형체를 70 내지 80℃의 온도에서 1 내지 3시간 동안 가열하여 상기 성형체 내부에 존재하는 수분을 제거함으로써, 미생물담체를 제조할 수 있다.In the above step, a microorganism carrier may be prepared by heating the molded body at a temperature of 70 to 80° C. for 1 to 3 hours to remove moisture present in the molded body.
상기 항충추출물은 해충이나 곤충, 오염 물질, 진드기류 등에 대한 항충, 살충, 항균 효과가 있는 천연식물을 이용하여 제조될 수 있는데, 예를 들어, 상기 항충추출물은 쿠아시아 추출물 및 제충국 추출물이 사용될 수 있고, 상기 항충추출물은 쿠아시아 추출물 및 제충국 추출물이 1:1의 중량 비율로 혼합되어 제조될 수 있다.The anti-parasitic extract may be prepared using natural plants having anti-parasitic, insecticidal, and antibacterial effects against pests, insects, pollutants, mites, etc. There, the antichite extract may be prepared by mixing the quasia extract and the pyrethrum extract in a weight ratio of 1:1.
상기 쿠아시아 추출물은 쿠아시아(Quassia amara)로부터 추출될 수 있는데, 상기 쿠아시아(Quassia amara)는 부드럽고 회색의 수피, 복엽, 작고 노란 꽃을 가지고 30cm 정도 자라는 낙엽수이다. 상기 쿠아시아는 나무 전체에 매우 쓴맛을 내는 쿠아신(Quassin)이라고 부르는 레진이 스며들어 있고, 이 성분은 천연 살충제로 사용될 수 있다. 농약으로서 쿠아신은 무당벌레나 벌에 거의 피해를 주지 않으면서 다양한 해충을 구제하기 때문에 가정 원예에서 가장 안전한 재료로 여겨지고 있다.The Quassia extract can be extracted from Quassia amara, which is a deciduous tree that grows to a height of about 30 cm with soft gray bark, bifoliate leaves, and small yellow flowers. The quasia is permeated with a resin called Quassin, which gives a very bitter taste to the whole tree, and this component can be used as a natural insecticide. As a pesticide, quaxin is considered one of the safest ingredients in home gardening because it controls a wide variety of pests while doing little to no ladybugs or bees.
상기 제충국 추출물은 제충국(Insect flower, Pyrethrum, Dalmatian pyrethrum)으로부터 추출될 수 있는데, 상기 제충국은 쌍떡잎식물 초롱꽃목 국화과의 여러해살이풀로서, 제충국의 꽃에는 피레트린(Pyrethrins)이라는 담적황색의 유상 물질을 함유하고 있다. 피레트린은 냉혈동물, 특히 곤충의 신경계를 마비시켜 강한 살충력을 나타내지만, 사람과 같은 온혈동물에는 독성이 없는 안전한 천연 유래의 살충성분이다. 구체적으로, 피레트린은 곤충에 대한 강한 살충 작용을 지니는바 유제 외에 코일(Coil)형 모기향 등으로서 모기, 파리의 구제에 사용되고 있으며, 바퀴벌레, 벼룩, 개미 및 이와 유사한 기어다니는 곤충에 대해서도 적용 가능한 것으로 알려져 있고, 다른 천연살충제 성분과 혼합되어 작물보호제로 사용되고 있다.The pyrethrum extract can be extracted from Insect flower (Pyrethrum, Dalmatian pyrethrum), which is a perennial plant of the dicotyledonous plant Bellflower Asteraceae, and contains pale reddish yellow oily substances called pyrethrins in the flowers of pyrethrum. contains Pyrethrin paralyzes the nervous system of cold-blooded animals, especially insects, and exhibits strong insecticidal power, but is a safe, natural-derived insecticidal ingredient that is non-toxic to warm-blooded animals such as humans. Specifically, since pyrethrin has a strong insecticidal action against insects, it is used as a coil-type mosquito incense in addition to emulsions to control mosquitoes and flies, and is also applicable to cockroaches, fleas, ants and similar crawling insects It is known and used as a crop protection agent in combination with other natural pesticide ingredients.
본 발명에서 상기 항충추출물은 쿠아시아 및 제충국으로 이루어진 천연식물을 추출하여 제조될 수 있고, 상기 천연식물의 추출은 열수 추출법, 유기용매 추출법, 초음파 추출법, 초임계 추출법 등 다양한 추출법을 이용할 수 있는데, 상기 추출의 구성은 공지의 기술인바, 설명의 편의 및 본 발명의 기술적 사상의 명확성을 위하여 상기 천연식물의 추출 방법에 대한 구체적인 설명은 생략하기로 한다.In the present invention, the anti-worm extract can be prepared by extracting natural plants consisting of quasia and pyrethrum, and the extraction of the natural plants can use various extraction methods such as hot water extraction, organic solvent extraction, ultrasonic extraction, supercritical extraction, Since the configuration of the extraction is a known technique, a detailed description of the extraction method of the natural plant will be omitted for convenience of description and clarity of the technical idea of the present invention.
상기 혼합비료는 상기 미네랄 나노 액상비료에 포함되어 영양성분을 공급하기 위하여 포함될 수 있는데, 상기 혼합비료는 장석, 고령토, 탄산칼륨, 구연산 및 인광석을 포함한다.The mixed fertilizer may be included in the mineral nano liquid fertilizer to supply nutrients, and the mixed fertilizer includes feldspar, kaolin, potassium carbonate, citric acid, and phosphate stone.
또한, 상기 혼합비료는 장석 5 내지 10 중량부, 고령토 8 내지 12 중량부, 탄산칼륨 1 내지 5 중량부, 구연산 2 내지 6 중량부 및 인광석 3 내지 7 중량부의 중량 비율로 포함될 수 있다.In addition, the mixed fertilizer may include 5 to 10 parts by weight of feldspar, 8 to 12 parts by weight of kaolin, 1 to 5 parts by weight of potassium carbonate, 2 to 6 parts by weight of citric acid, and 3 to 7 parts by weight of phosphate stone.
상기 장석은 1cm3 당 3만~15만개의 다층다공질로 구성되어 있고, 비표면적이 넓어 오염물질, 중금속 등을 흡착 및 분해하는 작용을 하는 효과가 있다. 또한, 산성이나 강한 알칼리성 물을 약 알칼리성(pH 7.2~7.4)으로 조절하며, 수질을 활성화하여 정수작용을 한다. 또한, 장석은 흡착력이 뛰어나 화학적 산소요구량(COD) 및 생물학적 산소요구량(BOD)을 낮추어 방부작용을 하는 것은 물론 활성화에 따라 생체에 활력을 준다.The feldspar is composed of 30,000 to 150,000 multi-layered porous materials per 1 cm 3 , and has a large specific surface area, and has an effect of adsorbing and decomposing contaminants, heavy metals, and the like. In addition, it adjusts acidic or strongly alkaline water to weakly alkaline (pH 7.2 ~ 7.4) and activates the water quality to purify water. In addition, feldspar has excellent adsorption power and lowers the chemical oxygen demand (COD) and the biological oxygen demand (BOD), which not only acts as a preservative, but also gives vitality to the living body according to activation.
상기 고령토는 규석, 알루미나, 포타시움 등의 성분으로 구성되어 있으며, 작물의 생장 시 작물의 잎과 줄기에 고령토막을 형성하여, 해충의 피해를 저감시키는 효과가 있다.The kaolin is composed of components such as silica, alumina, and potassium, and has an effect of reducing damage from pests by forming kaolin pieces on the leaves and stems of crops during crop growth.
상기 탄산칼륨은 탄산칼리 또는 칼리라고도 하며 K2CO3의 화학식을 갖는 백색 분말로, 식물을 태운 재 속에 함유되어 있다. 상기 탄산칼슘(CaCO3)은 식물 세포막 구성 역할을 하고, 산성토양을 중화시켜 토양반응을 교정시켜 줌으로서 토양미생물의 활동을 촉진시키고 식물성장에 알맞은 토양환경 개량 효과를 가진다.The potassium carbonate, also called potassium carbonate or potassium, is a white powder having a chemical formula of K 2 CO 3 and is contained in the ashes of burned plants. The calcium carbonate (CaCO 3 ) plays a role in constructing plant cell membranes, neutralizes acidic soil, corrects the soil reaction, promotes the activity of soil microorganisms, and has an effect of improving the soil environment suitable for plant growth.
상기 탄산칼륨은 100g의 물에 대해서 0℃에서 105.5g, 100℃에서 156g이 용해될 수 있으며, 수용액은 가수분해에 의해서 pH 11.6의 염기성을 보인다. 수용액에서 탄산칼륨을 결정화시킬 때는 2수화물인 K2CO3·2H2O가 생성된다. 탄산칼륨은 산과 반응시키면 이산화탄소를 발생시키며, 이산화탄소를 흡수하면 중탄산칼륨으로 변한다. 45~50%의 수산화칼륨 용액을 반응조에 넣고 교반하면서 이산화탄소를 불어넣어 탄산칼륨 수용액을 만들고, 거른 후 증발·건조시키거나, 탄산칼륨 수용액에 다시 이산화탄소를 불어넣어 중탄산칼륨으로 결정을 만들고 회전로를 사용해서 가열분해하여 얻는다. 탄산칼륨은 비누, 유리등의 제조원료, 의약품의 제제원료 및 화학조작 등에 사용될 수 있다.The potassium carbonate can dissolve 105.5 g at 0 ° C and 156 g at 100 ° C for 100 g of water, and the aqueous solution shows a basicity of pH 11.6 by hydrolysis. When potassium carbonate is crystallized from an aqueous solution, the dihydrate K 2 CO 3 2H 2 O is produced. When potassium carbonate reacts with an acid, it generates carbon dioxide, and when it absorbs carbon dioxide, it turns into potassium bicarbonate. A 45 to 50% potassium hydroxide solution is put into a reaction tank, and carbon dioxide is blown into the reactor while stirring to make a potassium carbonate aqueous solution, which is filtered and then evaporated and dried, or carbon dioxide is blown into the potassium carbonate solution again to make crystals of potassium bicarbonate and a rotary furnace is used. It is obtained by heating and decomposition. Potassium carbonate can be used as a raw material for manufacturing soap, glass, etc., as a raw material for pharmaceutical preparations, and for chemical manipulation.
상기 구연산은 결정물과 무수물이 있으며, 이를 각각 결정구연산과 무수구연산으로 나뉜다. 결정 무연산은 산성조미료 및 식용유의 산패방지제로서 사용되며, 무수구연산은 수분이 함유되지 않아도 되는 식품 또는 가루식품의 산미료로 사용되며 결정수가 없기 때문에 결정구연산보다 산도가 강하며 사용시에 약 10％ 정도 적게 사용한다.The citric acid has crystals and anhydrides, which are divided into crystalline citric acid and anhydrous citric acid, respectively. Anhydrous citric acid is used as an acidulant for foods or powdered foods that do not require moisture, and has a stronger acidity than crystalline citric acid because there is no crystal water. use.
예를 들어, 상기 구연산으로는 구연산칼륨(시트르산칼륨)이 사용될 수 있는데, 상기 구연산칼륨(시트르산칼륨)은 C6H5K3O7·H2O, 324.41의 분자량을 갖는 무색 또는 백색의 결정 또는 분말 형태를 갖는 물질이다. 상기 구연산칼륨은 물에는 잘 용해되나 글리세린에는 서서히 용해되고 에틸알코올에는 거의 용해되지 않으며, 수용액은 미세한 알칼리성을 가진다. 100mL의 물에 대해서 15℃에서 167g, 30℃에서 199g이 용해될 수 있으며 산도조절제, 각종 도금용 첨가제 또는 보온제 등으로 사용될 수 있다.For example, as the citric acid, potassium citrate (potassium citrate) may be used, and the potassium citrate (potassium citrate) is C 6 H 5 K 3 O 7 H 2 O, a colorless or white crystal having a molecular weight of 324.41. or a substance in the form of a powder. The potassium citrate is well soluble in water but slowly soluble in glycerin and hardly soluble in ethyl alcohol, and the aqueous solution has a slight alkalinity. For 100mL of water, 167g at 15℃ and 199g at 30℃ can be dissolved, and it can be used as an acidity regulator, various additives for plating, or a heat retaining agent.
상기 인광석(Rock phosphate)은 인산칼슘을 다량으로 함유하는 광석으로서 대표적인 물질로 인회석, 인회토, 구아노(guano) 등이 있으며 인산비료의 주원료가 된다. 상기 인광석은 인산과 질소(N), 산화칼슘(CaO), 산화마그네슘(MgO)이 주성분으로 구성된 천연화합물이 2% 구연산(citric acid)에 용해되는 원리를 이용하여 비료 조성에 사용된다.The rock phosphate is an ore containing a large amount of calcium phosphate, and representative materials include apatite, phosphate soil, and guano, which are the main raw materials of phosphate fertilizers. The phosphate rock is used in fertilizer composition using the principle that a natural compound composed of phosphoric acid, nitrogen (N), calcium oxide (CaO), and magnesium oxide (MgO) as main components is dissolved in 2% citric acid.
상기 인광석 내에 함유된 인산은 구연산(citric acid)에 용해되어, 유리 인산으로 변환되는 성질을 가지는데, 상기 구연산은 검은곰팡이(Aspergillus niger)에 의해 생성되어 인산의 분해에 이용된다. 인광석의 구성 성분 중에 칼슘과 인이 주요 구성 물질인데, 칼슘과 인의 비율에 따라 인광석으로부터 조성된 인산비료의 수용성, 구용성 및 불용성 여부가 결정된다. 결과적으로 인의 함량은 칼슘에 비해 적을수록 구용성이 강해 비료의 지속성이 증가되며 인산의 식물체 내 흡수율이 높아져 비료의 가치가 증대된다.Phosphoric acid contained in the phosphate stone has a property of being dissolved in citric acid and converted into free phosphoric acid, which is produced by Aspergillus niger and used for decomposition of phosphoric acid. Calcium and phosphorus are the main constituents of the phosphate stone, and the ratio of calcium and phosphorus determines whether the phosphate fertilizer made from the phosphate stone is water-soluble, mouth-soluble, or insoluble. As a result, the smaller the phosphorus content is compared to calcium, the stronger the mouth solubility, the longer the fertilizer lasts, and the higher the rate of absorption of phosphoric acid in the plant, increasing the value of the fertilizer.
상기 해안 심층 암반수는 일반적으로 해안에서 약 1㎞ 이내의 지하 800m 이상으로부터 용출되는 물을 말하는데, 연안이나 해안의 지하 심층부 암반층에서 암반의 공극이나 균열을 따라 해양 심층부의 해수가 틈입, 육지의 지하 심층 대수층을 따라 흘러 내려온 천연 암반 지하수와 지질학적 시간과 공간의 조건에서 상호 교호작용, 저류, 숙성, 이온화된 것을 일컫는다.The deep coastal bedrock water generally refers to water eluted from more than 800 m underground within about 1 km from the coast, and seawater in the deep ocean penetrates through pores or cracks in the bedrock in the deep underground bedrock of the coast or coast, It refers to the interaction, storage, ripening, and ionization of natural rock groundwater flowing down an aquifer and geological conditions of time and space.
상기 해안 심층 암반수는 주변 지질로부터 영향을 받게 되어 지하의 토양 및 암반의 특성에 따라 수질의 성분뿐만 아니라 유용가치도 달라질 수 있는데, 해양심층수에 비해 칼슘(Ca), 스트롬튬(Sr), 망간(Mn), 아연(Zn), 철(Fe), 구리(Cu), 니켈(Ni), 바나듐(V), 셀레늄(Se) 등의 미네랄이 풍부할 뿐만 아니라, 칼슘과 마그네슘(Mg)의 미네랄 밸런스가 인간의 체액과 유사하다고 학계에 보고되어 있다.The coastal deep bedrock water is influenced by the surrounding geology, and depending on the characteristics of the underground soil and bedrock, not only the components of the water quality but also the useful value may vary. It is rich in minerals such as Mn), zinc (Zn), iron (Fe), copper (Cu), nickel (Ni), vanadium (V), and selenium (Se), as well as mineral balance of calcium and magnesium (Mg). It has been reported in the academic world that is similar to human body fluids.
또한, 질소(N), 인(P), 규산(silicic acid) 등의 무기 영양염이 많이 함유되어 있고 대장균이나 일반세균에 의한 오염이 거의 없으며, 항산화 물질과 필수 미량원소, 다양한 미네랄이 균형있게 포함되어 있어서 활성산소의 제거에도 효능을 나타낸다.
본 발명에서 상기 해안 심층 암반수는 모래여과(Sand filter), 활성탄소여과(Activated Carbon filter), 정밀여과(Micro filter), 한외여과(限外濾過; Ultra filter), 나노여과(Nano filter) 및 역삼투여과(Reverse Osmosis filter)로 이루어진 군에서 선택된 어느 하나 이상을 조합한 필터들을 사용하여 이물질이나 고형물을 여과하고 제거한 후 염분을 제거하여 담수화한 해안심층담수를 의미할 수 있는데, 상기 해안심층담수에는 마그네슘, 칼슘, 칼륨, 인, 나트륨 등 미네랄이 풍부하다.
즉, 본 발명에서 상기 해안 심층 암반수는 담수화된 것으로, 상기 해안 심층 암반수에 포함된 염분(NaCl)이 제거되고 미네랄이 풍부하게 함유된 해안심층담수를 의미할 수 있는데, 상기 해안 심층 암반수에서 염분을 제거하는 해수담수화(海水淡水化, seawater desalination) 과정은 공지의 기술인 바, 상기 해안 심층 암반수를 담수화하는 방법은 설명의 편의 및 본 발명의 기술적 사상의 명확성을 위하여 이에 대한 구체적인 설명은 생략하기로 한다.In addition, it contains a lot of inorganic nutrients such as nitrogen (N), phosphorus (P), and silicic acid, and there is almost no contamination by Escherichia coli or general bacteria, and antioxidant substances, essential trace elements, and various minerals are contained in a balanced It is also effective in removing active oxygen.
In the present invention, the coastal deep bedrock water is sand filtered, activated carbon filter, micro filter, ultra filter, nano filter, and reverse osmosis. It may refer to deep coastal freshwater desalinated by removing salt after filtering and removing foreign substances or solids using filters combining at least one selected from the group consisting of a reverse osmosis filter. The deep coastal freshwater includes magnesium It is rich in minerals such as calcium, potassium, phosphorus and sodium.
That is, in the present invention, the deep coastal bedrock water is desalinated, and may mean deep coastal freshwater in which salt (NaCl) contained in the deep coastal bedrock water is removed and rich in minerals. Since the process of removing seawater desalination is a well-known technique, the detailed description of the method for desalinating the deep coastal bedrock water will be omitted for convenience of description and clarity of the technical idea of the present invention. .
이하, 첨부된 도면을 참조하여 본 발명에 따른 새싹작물 재배용 미네랄 나노 액상비료의 제조방법에 대하여 바람직한 실시예를 들어 상세하게 설명한다.Hereinafter, with reference to the accompanying drawings, a preferred embodiment of a method for manufacturing a mineral nano liquid fertilizer for sprout crops according to the present invention will be described in detail.
도 2는 본 발명에 따른 새싹작물 재배용 미네랄 나노 액상비료의 제조방법을 개략적으로 설명하기 위한 순서도이다.2 is a flowchart schematically illustrating a method of manufacturing a mineral nano-liquid fertilizer for sprout crop cultivation according to the present invention.
도 2를 참조하면, 본 발명에 따른 새싹작물 재배용 미네랄 나노 액상비료의 제조방법은 재료 준비 단계(S100), 혼합 단계(S200) 및 숙성 단계(S300)를 포함한다.Referring to FIG. 2 , the manufacturing method of the mineral nano-liquid fertilizer for sprout crops according to the present invention includes a material preparation step (S100), a mixing step (S200), and a ripening step (S300).
1. 재료 준비 단계(S100)1. Material preparation step (S100)
상기 재료 준비 단계(S100)는 미네랄 나노 액상비료를 제조하기 위한 재료를 준비하는 단계이다.The material preparation step (S100) is a step of preparing a material for preparing a mineral nano-liquid fertilizer.
상기 재료 준비 단계(S100)에서 상기 재료는 나노입자 미네랄, 비드, 미생물담체, 항충추출물, 혼합비료 및 해안 심층 암반수가 준비될 수 있다.In the material preparation step (S100), the materials may include nanoparticle minerals, beads, microbial carriers, anti-worm extracts, mixed fertilizers, and deep coastal bedrock water.
2. 혼합 단계(S200)2. Mixing step (S200)
상기 혼합 단계(S200)는 상기 준비된 재료를 계량하여 혼합하는 단계이다.The mixing step (S200) is a step of weighing and mixing the prepared material.
상기 혼합 단계(S200)에서 상기 재료는 나노입자 미네랄 1 내지 5 중량부, 비드 0.5 내지 1.5 중량부, 미생물담체 1 내지 3 중량부, 항충추출물 0.1 내지 1 중량부, 혼합비료 5 내지 15 중량부 및 해안 심층 암반수 100 내지 200 중량부의 중량 비율로 계량되어 혼합될 수 있다.In the mixing step (S200), the materials include 1 to 5 parts by weight of nanoparticle minerals, 0.5 to 1.5 parts by weight of beads, 1 to 3 parts by weight of a microbial carrier, 0.1 to 1 parts by weight of an insecticide extract, 5 to 15 parts by weight of a mixed fertilizer, and It may be weighed and mixed in a weight ratio of 100 to 200 parts by weight of coastal deep bedrock water.
3. 숙성 단계(S300)3. Aging step (S300)
상기 숙성 단계(S300)는 상기 혼합된 재료를 숙성하여 미네랄 나노 액상비료를 제조하는 단계이다.The aging step (S300) is a step of preparing a mineral nano-liquid fertilizer by aging the mixed material.
상기 숙성 단계(S300)에서는 상기 혼합된 재료를 8 내지 12℃의 온도에서 10 내지 30시간 동안 숙성하여 상기 혼합된 재료의 물성을 안정화시킴으로써 미네랄 나노 액상비료를 제조할 수 있다.In the aging step (S300), a mineral nano-liquid fertilizer may be prepared by aging the mixed material at a temperature of 8 to 12 °C for 10 to 30 hours to stabilize physical properties of the mixed material.
이하, 첨부된 도면을 참조하여 본 발명에 따른 새싹작물 재배용 미네랄 나노 액상비료에 대한 실시예를 들어 더욱 구체적으로 설명하기로 한다.Hereinafter, with reference to the accompanying drawings, an embodiment of the mineral nano liquid fertilizer for sprout crops according to the present invention will be described in more detail.
< 실시예 >< Example >
나노입자 미네랄 3 중량부, 비드 1 중량부, 미생물담체 2 중량부, 항충추출물 0.5 중량부, 혼합비료 10 중량부 및 해안 심층 암반수 150 중량부의 중량 비율로 혼합하여 미네랄 나노 액상비료를 제조하였다.Mineral nano-liquid fertilizer was prepared by mixing 3 parts by weight of nanoparticle minerals, 1 part by weight of beads, 2 parts by weight of microbial carrier, 0.5 parts by weight of anti-insect extract, 10 parts by weight of mixed fertilizer, and 150 parts by weight of deep coastal bedrock water.
< 비교예 ><Comparative Example>
시중에 판매되고 있는 화학비료(N사 제조)를 준비하였고, 이를 비교예에 따른 비료로 사용하였다.A commercially available chemical fertilizer (manufactured by N company) was prepared and used as a fertilizer according to Comparative Example.
1. 함량 분석1. Content analysis
상기 실시예와 같이 제조된 미네랄 나노 액상비료를 새싹작물에 시비한 후, 게르마늄, 셀레늄, 아연의 함량을 분석하였다.After applying the mineral nano-liquid fertilizer prepared as in the above example to sprout crops, the contents of germanium, selenium, and zinc were analyzed.
도 3은 실시예에 따라 제조된 미네랄 나노 액상비료를 새싹보리에 시비한 후 게르마늄, 셀레늄, 아연의 함량을 분석한 시험성적서이고, 도 4는 실시예에 따라 제조된 미네랄 나노 액상비료를 새싹완두콩에 시비한 후 게르마늄, 셀레늄, 아연의 함량을 분석한 시험성적서이며, 도 5는 실시예에 따라 제조된 미네랄 나노 액상비료를 새싹브로콜리에 시비한 후 게르마늄, 셀레늄, 아연의 함량을 분석한 시험성적서이고, 도 6은 실시예에 따라 제조된 미네랄 나노 액상비료를 새싹밀에 시비한 후 게르마늄, 셀레늄, 아연의 함량을 분석한 시험성적서이다.3 is a test report analyzing the contents of germanium, selenium, and zinc after applying the mineral nano liquid fertilizer prepared according to the example to sprout barley, and FIG. 5 is a test report analyzing the contents of germanium, selenium, and zinc after applying the mineral nano liquid fertilizer prepared according to Example to sprout broccoli. 6 is a test report of analyzing the contents of germanium, selenium, and zinc after applying the mineral nano liquid fertilizer prepared according to the embodiment to sprout wheat.
도 3 내지 도 6을 참조하면, 실시예에 따라 제조된 미네랄 나노 액상비료를 새싹보리, 새싹완두콩, 새싹브로콜리, 새싹밀에 시비하여 재배한 경우, 게르마늄, 셀레늄, 아연의 함량이 풍부함을 확인할 수 있다.Referring to FIGS. 3 to 6, when the mineral nano liquid fertilizer prepared according to the embodiment was fertilized and cultivated in sprout barley, sprout pea, sprout broccoli, and sprout wheat, it can be confirmed that the content of germanium, selenium, and zinc is rich. there is.
2. 새싹작물 생육 관찰2. Observation of sprout crop growth
상기 실시예와 비교예에 따른 비료를 육묘에 시비한 후 육묘의 생육을 관찰하였다.After fertilizing the fertilizers according to Examples and Comparative Examples to the seedlings, the growth of the seedlings was observed.
도 7a는 실시예에 따른 비료를 육묘에 시비한 후 육묘의 생육을 보여주는 사진이고, 도 7b는 비교예에 따른 비료를 육묘에 시비한 후 육묘의 생육을 보여주는 사진이다.Figure 7a is a photograph showing the growth of seedlings after the fertilizer according to the embodiment is applied to the seedlings, and Figure 7b is a photograph showing the growth of the seedlings after the fertilizer according to the comparative example is applied to the seedlings.
도 7a 및 도 7b를 참조하면, 실시예에 따른 미네랄 나노 액상비료를 육묘에 시비한 경우, 육모의 생육이 촉진됨을 확인할 수 있다.Referring to Figures 7a and 7b, when the mineral nano liquid fertilizer according to the embodiment is applied to the seedlings, it can be confirmed that the growth of hair growth is promoted.
이상, 본 발명의 바람직한 일 실시예를 설명하였지만, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자라면 본 발명이 그 기술적 사상이나 필수적인 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 일 실시예는 모든 면에서 예시적인 것이며 한정적이 아닌 것으로 이해해야만 한다.Although the preferred embodiment of the present invention has been described above, those skilled in the art will understand that the present invention can be implemented in other specific forms without changing the technical spirit or essential features. You will be able to. Therefore, one embodiment described above should be understood as illustrative in all respects and not limiting.
Claims (3)
상기 준비된 재료를 계량하여 혼합하는 혼합 단계(S200); 및
상기 혼합된 재료를 숙성하여 미네랄 나노 액상비료를 제조하는 숙성 단계(S300)를 포함하고,
상기 재료 준비 단계(S100)에서 상기 재료는 나노입자 미네랄, 비드, 미생물담체, 항충추출물, 혼합비료 및 해안 심층 암반수가 준비되며,
상기 혼합 단계(S200)는 상기 나노입자 미네랄 1 내지 5 중량부, 비드 0.5 내지 1.5 중량부, 미생물담체 1 내지 3 중량부, 항충추출물 0.1 내지 1 중량부, 혼합비료 5 내지 15 중량부 및 해안 심층 암반수 100 내지 200 중량부의 중량 비율로 포함되고,
상기 나노입자 미네랄은 셀레늄 1 내지 10 중량부, 게르마늄 1 내지 10 중량부 및 바나듐 1 내지 10 중량부의 중량 비율로 포함되고,
상기 비드는, 수용성 에틸렌계 불포화 단량체 80 내지 120 중량부, 셀룰로오스계 화합물 10 내지 30 중량부, 카르복시(C1-C5)알킬 키토산 5 내지 15 중량부, 자몽종자추출물 1 내지 3 중량부, 친수성 첨가제 5 내지 15 중량부 및 가교제 1 내지 3 중량부의 중량비율로 혼합된 혼합용액을 제조하고, 상기 수용성 에틸렌계 불포화 단량체, 셀룰로오스계 화합물, 카르복시(C1-C5)알킬 키토산, 친수성 첨가제 및 가교제가 혼합된 혼합용액에 물 600 내지 800 중량부를 첨가한 후 교반하며, 상기 물이 첨가되어 교반된 혼합용액에 중합개시제 0.1 내지 1 중량부를 첨가하여 중합체를 형성하되, 상기 중합개시제는 2,4,6-트리메틸-벤조일-트리메틸 포스핀 옥사이드(2,4,6-trimethyl-benzoyl-trimethyl phosphine oxide)가 사용되고, 상기 중합체를 80 내지 90℃의 온도에서 건조한 후 상기 건조된 중합체를 입경이 0.001 내지 1mm가 되도록 분쇄하는 과정을 거쳐 제조된 비드가 사용되며,
상기 미생물담체는, 황토 15 내지 25 중량부, 부엽토 2 내지 6 중량부, 활성탄 8 내지 12 중량부, 생분해성 수지 10 내지 20 중량부, 전분 50 내지 100 중량부 및 물 30 내지 70 중량부의 중량비율로 준비하되, 상기 활성탄은 경도 93 질량분율% 이상, 충전밀도 0.51 내지 0.53g/ml, 비표면적 800 내지 900m2/g, 세공분포는 세공직경이 4Å 내지 7Å, 요오드 흡착력 1,100mg/g 이상, 세공용적 0.51ml/g, pH 7~7.8, 페놀 흡착력 17.5ml/g, M·B 탈색력 153ml/g 이상인 것이 사용되고, 상기 생분해성 수지는 폴리락트산(poly lactic acid) 또는 폴리카프로락톤(Polycaprolactone) 중에서 선택된 어느 하나 이상이 사용되며, 상기 황토, 부엽토, 활성탄, 생분해성 수지, 전분 및 물을 혼합하여 혼합물을 제조한 후 상기 혼합물을 입경이 0.001 내지 1mm가 되도록 성형하여 성형체하고, 상기 성형체를 70 내지 80℃의 온도에서 1 내지 3시간 동안 가열하여 건조하는 과정을 거쳐 제조된 미생물담체가 사용되며,
상기 항충추출물은 쿠아시아 추출물 및 제충국 추출물이 1:1의 중량 비율로 혼합되어 제조된 항충추출물이 사용되고,
상기 혼합비료는 장석 5 내지 10 중량부, 고령토 8 내지 12 중량부, 탄산칼륨 1 내지 5 중량부, 구연산 2 내지 6 중량부 및 인광석 3 내지 7 중량부의 중량 비율로 포함되고,
상기 해안 심층 암반수는 해수담수화(海水淡水化) 과정을 거쳐 염분(NaCl)이 제거된 해안심층담수이며,
상기 숙성 단계(S300)에서는 상기 혼합된 재료를 8 내지 12℃의 온도에서 10 내지 30시간 동안 숙성하는 것을 특징으로 하는 새싹작물 재배용 미네랄 나노 액상비료의 제조방법.A material preparation step of preparing a material for preparing a mineral nano liquid fertilizer (S100);
Mixing step (S200) of weighing and mixing the prepared material; and
A ripening step (S300) of preparing a mineral nano-liquid fertilizer by aging the mixed material;
In the material preparation step (S100), the materials are prepared with nanoparticle minerals, beads, microbial carriers, antiworm extracts, mixed fertilizers, and deep coastal bedrock water,
In the mixing step (S200), 1 to 5 parts by weight of the nanoparticle mineral, 0.5 to 1.5 parts by weight of beads, 1 to 3 parts by weight of a microorganism carrier, 0.1 to 1 part by weight of an insecticide extract, 5 to 15 parts by weight of a mixed fertilizer and deep seashore It is included in a weight ratio of 100 to 200 parts by weight of bedrock water,
The nanoparticle mineral is included in a weight ratio of 1 to 10 parts by weight of selenium, 1 to 10 parts by weight of germanium, and 1 to 10 parts by weight of vanadium,
The beads, 80 to 120 parts by weight of water-soluble ethylenically unsaturated monomers, 10 to 30 parts by weight of cellulose compounds, 5 to 15 parts by weight of carboxy (C1-C5) alkyl chitosan, 1 to 3 parts by weight of grapefruit seed extract, hydrophilic additive 5 to 15 parts by weight and 1 to 3 parts by weight of a crosslinking agent, preparing a mixed solution, and mixing the water-soluble ethylenically unsaturated monomer, cellulose compound, carboxy (C1-C5) alkyl chitosan, hydrophilic additive and crosslinking agent 600 to 800 parts by weight of water is added to the solution, followed by stirring, and 0.1 to 1 part by weight of a polymerization initiator is added to the mixed solution in which the water is added and stirred to form a polymer, but the polymerization initiator is 2,4,6-trimethyl- Benzoyl-trimethyl phosphine oxide (2,4,6-trimethyl-benzoyl-trimethyl phosphine oxide) is used, and after drying the polymer at a temperature of 80 to 90 ° C., the dried polymer is pulverized so that the particle diameter is 0.001 to 1 mm Beads manufactured through the process are used,
The microbial carrier contains 15 to 25 parts by weight of loess, 2 to 6 parts by weight of humus, 8 to 12 parts by weight of activated carbon, 10 to 20 parts by weight of biodegradable resin, 50 to 100 parts by weight of starch, and 30 to 70 parts by weight of water. Prepared as, but the activated carbon has a hardness of 93% by mass or more, a packing density of 0.51 to 0.53g/ml, a specific surface area of 800 to 900m 2 /g, a pore distribution of 4Å to 7Å in pore diameter, an iodine adsorption capacity of 1,100mg/g or more, Pore volume 0.51ml/g, pH 7-7.8, phenol adsorption power 17.5ml/g, M B decolorization power 153ml/g or more is used, and the biodegradable resin is polylactic acid or polycaprolactone At least one selected from is used, and after preparing a mixture by mixing the loess, humus, activated carbon, biodegradable resin, starch, and water, the mixture is molded to have a particle diameter of 0.001 to 1 mm to form a molded body, and the molded body is 70 A microbial carrier prepared by heating and drying at a temperature of 80 ° C. for 1 to 3 hours is used,
The anti-worm extract is an anti-worm extract prepared by mixing a pyrethrum extract and a pyrethrum extract in a weight ratio of 1: 1 is used,
The mixed fertilizer includes 5 to 10 parts by weight of feldspar, 8 to 12 parts by weight of kaolin, 1 to 5 parts by weight of potassium carbonate, 2 to 6 parts by weight of citric acid, and 3 to 7 parts by weight of phosphate stone,
The coastal deep bedrock water is coastal deep freshwater from which salt (NaCl) has been removed through a seawater desalination process,
In the aging step (S300), the mixed material is aged at a temperature of 8 to 12 ° C. for 10 to 30 hours.
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| KR20040072517A (en) * | 2004-07-19 | 2004-08-18 | 장치호 | Funtional natural insecticide used in phrethrum flower |
| JP2005229865A (en) * | 2004-02-18 | 2005-09-02 | Nogyo Kagaku Kenkyusho:Kk | Material for agriculture and gardening |
| KR20070026281A (en) * | 2006-10-08 | 2007-03-08 | 서희동 | Manufacturing method of activated minerals from the deep sea water and the deep sea rock floor water |
| KR100866587B1 (en) | 2006-04-14 | 2008-11-03 | 주식회사 한국애그로바이오 | Method for preparing a liquid fertilizer containing germanum and selenum, the liquid fertilizer thereof, and method for producing a farm products using the same |
| KR101732080B1 (en) | 2016-09-12 | 2017-05-04 | (주)농업과기술 | A Manufacturing Method Of Composition Of Fluid Fertilizer |
| KR101765438B1 (en) | 2017-03-27 | 2017-08-23 | 안무헌 | A Manufacturing Method Of Fluid Fertilizer Composition Controlling Plant Growth |
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|---|---|---|---|---|
| JP2005229865A (en) * | 2004-02-18 | 2005-09-02 | Nogyo Kagaku Kenkyusho:Kk | Material for agriculture and gardening |
| KR20040072517A (en) * | 2004-07-19 | 2004-08-18 | 장치호 | Funtional natural insecticide used in phrethrum flower |
| KR100866587B1 (en) | 2006-04-14 | 2008-11-03 | 주식회사 한국애그로바이오 | Method for preparing a liquid fertilizer containing germanum and selenum, the liquid fertilizer thereof, and method for producing a farm products using the same |
| KR20070026281A (en) * | 2006-10-08 | 2007-03-08 | 서희동 | Manufacturing method of activated minerals from the deep sea water and the deep sea rock floor water |
| KR101732080B1 (en) | 2016-09-12 | 2017-05-04 | (주)농업과기술 | A Manufacturing Method Of Composition Of Fluid Fertilizer |
| KR101765438B1 (en) | 2017-03-27 | 2017-08-23 | 안무헌 | A Manufacturing Method Of Fluid Fertilizer Composition Controlling Plant Growth |
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