JP6961870B1 - Visible disinfectant - Google Patents

Visible disinfectant Download PDF

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JP6961870B1
JP6961870B1 JP2020220041A JP2020220041A JP6961870B1 JP 6961870 B1 JP6961870 B1 JP 6961870B1 JP 2020220041 A JP2020220041 A JP 2020220041A JP 2020220041 A JP2020220041 A JP 2020220041A JP 6961870 B1 JP6961870 B1 JP 6961870B1
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雅巳 内田
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雅巳 内田
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    • AHUMAN NECESSITIES
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    • A01N43/06Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
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    • AHUMAN NECESSITIES
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    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/02Acyclic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01PBIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P1/00Disinfectants; Antimicrobial compounds or mixtures thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01PBIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
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    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50Solvents
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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  • Life Sciences & Earth Sciences (AREA)
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Abstract

【課題】ウイルスや菌の感染が拡大すると、ウイルスの除去や除菌を正しくできていたのか、という問題に直面する。洗浄剤や消毒剤が透明であると、洗浄・消毒をしても見えづらく正しく実施できているかわからないということ。洗浄液・消毒液の効果を有効にするためには、適切な一定以上の除去時間を経過させる必要があるが、散布後にすぐ拭き取ってしまい除去時間が取れていないこと。透明な液体が除菌効果のあるものか安易に確認できないこと、水不足の地域では大量の水で洗浄・消毒ができないこと。【解決手段】洗浄剤や消毒剤に視認できるように着色し、塩基性から酸性側に反応すると無色になるPH指示薬を、塩基性物質に含有させ、洗浄力・消毒力が視認でき、目視により対象物に洗浄・消毒を実施し、色の消失時間でウイルスや菌の除去時間をつくり、必要最小限の液剤で洗浄や消毒の実施安定性の向上を提供。PROBLEM TO BE SOLVED: To face a problem of whether a virus or a bacterium has been correctly removed or eradicated when the infection of the virus or the bacterium spreads. If the cleaning agent and disinfectant are transparent, it is difficult to see even if they are cleaned and disinfected, and it is not possible to know whether they are being carried out correctly. In order to make the effect of the cleaning solution / disinfectant effective, it is necessary to allow an appropriate removal time to elapse, but the removal time must not be taken because it is wiped off immediately after spraying. It is not possible to easily confirm whether the clear liquid has a sterilizing effect, and it is not possible to wash and disinfect with a large amount of water in areas where water is scarce. SOLUTION: A basic substance contains a PH indicator that is colored so that it can be visually recognized as a cleaning agent or a disinfectant and becomes colorless when it reacts to the acidic side from the basic, so that the cleaning power and the disinfecting power can be visually recognized. Cleaning and disinfecting the object, creating a time to remove viruses and bacteria by the time when the color disappears, and improving the stability of cleaning and disinfecting with the minimum necessary liquid.

Description

本発明は透明な洗浄剤・消毒剤に色をつけ視認でき、塩基性から酸性側に反応すると無色になるPH指示薬を、塩基性物質と混合させ、洗浄や消毒の実施安定性の向上と洗浄力・消毒力が視認でき、最小限の液量で洗浄・消毒をする、みえる除菌液In the present invention, a transparent cleaning agent / disinfectant is colored and visually recognizable, and a PH indicator that becomes colorless when it reacts from the basic to the acidic side is mixed with a basic substance to improve the stability of cleaning and disinfection and cleaning. A visible disinfectant that can visually check the power and disinfecting power and cleans and disinfects with the minimum amount of liquid .

タイヤホイールの表面に泡状に洗浄液を付着させ、洗浄物の表面に付着する汚れを離脱させる洗浄剤において、洗浄剤が、界面活性剤と、アルカリ性から中性に変化すると変色する指示薬を含有し、炭酸ガスと反応してアルカリ化合物が消失する洗浄剤がある。 A cleaning agent that adheres the cleaning liquid to the surface of the tire wheel in the form of bubbles to remove stains adhering to the surface of the cleaning object. The cleaning agent contains a surfactant and an indicator that discolors when the cleaning agent changes from alkaline to neutral. , There are cleaning agents that react with carbon dioxide gas to eliminate alkaline compounds.

特許第3464491号Patent No. 3464491

ウイルスや菌の感染拡大が起こるのは、その除去方法や衛生管理を正しくおこなうことができているのか、という問題に直面する。 When the spread of viruses and fungi occurs, we face the problem of whether the removal method and hygiene management are properly performed.

洗浄剤・消毒剤が透明であると、医師たちの着用する防護服や衣服、診察台や受付カウンターなどに消毒をほどこしても、きちんと消毒できているのかがわからないということ。 If the cleaning agent / disinfectant is transparent, even if the protective clothing and clothes worn by doctors, the examination table, the reception counter, etc. are disinfected, it is not possible to know whether the disinfectant has been properly disinfected.

透明な洗浄剤・消毒剤は、表面処理の際に目的の部分に確実に散布や塗布、噴霧し、菌、ウイルスなどを除去、除菌できているかが不確定である。 It is uncertain whether the transparent cleaning agent / disinfectant can be reliably sprayed, applied, or sprayed on the target portion during surface treatment to remove bacteria, viruses, and the like.

洗浄剤・消毒剤の効果を有効にするためには、除去時間というものを取らなくてはいけなく、適切な一定以上の時間を経過させる必要があり、テーブルなどに透明な消毒液をスプレー等で散布した直後に、布等ですぐに拭き取りすると、菌やウイルス除去時間が短く、まだ生きている病原体が布に付着し残った病原体を広めてしまう。 In order to make the effect of the cleaning agent / disinfectant effective, it is necessary to take a removal time, it is necessary to elapse an appropriate time or more, and a transparent disinfectant solution is sprayed on the table etc. Immediately after spraying with a cloth, if it is wiped off immediately with a cloth or the like, the time for removing bacteria and viruses is short, and the pathogens that are still alive adhere to the cloth and spread the remaining pathogens.

一般的な、指・手肌用の洗浄剤・消毒剤は無色透明なものであり、見ただけではその液体が水なのか消毒液なのかわかりづらく、どの程度の洗浄力、除菌力があるのかもわからない、除菌消毒液と書いてあるラベルを見て判断しているに過ぎず不安がある。 Generally, cleaning agents and disinfectants for fingers and hands are colorless and transparent, and it is difficult to tell whether the liquid is water or disinfectant just by looking at it. I don't know if there is one, but I'm worried because I'm just looking at the label that says "Disinfectant disinfectant".

食事の前に利用する、おしぼりやウェットティッシュなどが、実際は濡れているだけで包装の中で菌が発生していても気づく手段がなく、除菌効果があるのか安易に確認できないこと。 Even if the towels and wet wipes used before meals are actually wet and bacteria are growing in the packaging, there is no way to notice them, and it is not possible to easily confirm whether they have a sterilizing effect.

危機意識の低い幼児や子供がきちんと洗浄・消毒できているかを、指導や見守る必要があるが幼稚園、保育園のように人数が多くなると目が届かずきちんと除菌できているか不安がのこる。 It is necessary to give guidance and watch over whether infants and children with low crisis awareness are properly cleaned and disinfected, but when the number of people is large, such as in kindergartens and nursery schools, it is difficult to see and there is concern about whether the bacteria can be properly sterilized.

消毒するのに使われるヨウ素液は焦げ茶色で、指や手首に洗浄剤・消毒剤がきちんと掛けられているか確認することが出来るが、その色を落とすのに大量に水を使うことになり、水が豊かである場所では有効だが、水が不足の地域、環境では有効とは言えない。 The iodine solution used for disinfection is dark brown, and you can check if the cleaning agent / disinfectant is properly applied to your fingers and wrists, but you will use a large amount of water to remove the color. It is effective in places where water is abundant, but not in areas and environments where water is scarce.

普段の手洗いは、水が豊富な地域では蛇口をひねれば大量の水で洗うことができるが、水不足の地域では大量の水で手洗いができないこと。 You can usually wash your hands with a large amount of water by twisting the faucet in a water-rich area, but you cannot wash your hands with a large amount of water in a water-scarce area.

透明な塩基性物質の洗浄剤・消毒剤に色をつけ、溶剤の洗浄力・消毒力を視認させ、対象物に対し洗浄や消毒の実施の安定性を向上させ、アルカリ性の効力を失うと色を消失し、最小限の液量で洗浄・消毒をする、みえる除菌液Color the cleaning and disinfecting agents of transparent basic substances, make the cleaning and disinfecting power of the solvent visible, improve the stability of cleaning and disinfecting the object, and color when the alkaline effect is lost. A visible disinfectant that disappears and cleans and disinfects with the minimum amount of liquid.

洗浄・消毒の対象物にきちんと洗浄液・消毒液が散布、塗布、噴霧されているか、その問題解決が透明な洗浄液・消毒液に色をつけ可視化し、色が消えることよりも、色が見えることを優先した、みえる除菌液の提供。Whether the cleaning solution / disinfectant is properly sprayed, applied, or sprayed on the object to be cleaned / disinfected, or the problem is solved by coloring and visualizing the transparent cleaning / disinfecting solution so that the color can be seen rather than disappearing. Providing a visible disinfectant solution with priority.

着色された、透明な洗浄剤・消毒剤は洗浄力・消毒力を視認でき、散布や噴霧、塗布された表面に色がつき目視でき、洗浄・消毒の実施安定性を向上させ、着色された色は塩基性を失うと無色になり、必要最低限の液量で菌やウイルス、汚れの除去や衛生管理を実施する、みえる除菌液Colored, transparent cleaning agents and disinfectants can visually recognize the cleaning and disinfecting power, and the sprayed, sprayed, and applied surfaces can be visually recognized, improving the stability of cleaning and disinfecting, and coloring. The color becomes colorless when it loses its basicity, and it is a visible disinfectant that removes bacteria, viruses, and stains and performs hygiene management with the minimum required amount of liquid.

無水エタノールで溶解したPH指示薬と、塩基性物質を含有する洗浄剤・消毒剤で、塩基性側では色がつき、洗浄力・消毒力を視認でき、着色された色は酸性側に反応し塩基性を失うと無色になり、最小限の液量で洗浄・消毒をする、みえる除菌液A PH indicator dissolved in absolute ethanol and a cleaning agent / disinfectant containing a basic substance. The basic side is colored, and the detergency / disinfecting power can be visually recognized. A visible disinfectant that becomes colorless when it loses its properties and is cleaned and disinfected with the minimum amount of liquid.

公知で洗剤とは界面活性剤を主成分とし汚れや菌を除去する、洗浄剤とは中和作用で汚れや菌を除去し、洗剤より洗浄力が高いとされ、みえる除菌液はアルカリ性から酸性に向う中和作用を主として利用する。Removing dirt and bacteria mainly composed of surfactant and detergent known, dirt and bacteria were removed by neutralization effects a cleaning agent, is a higher detergency than the detergents appear sterilization solution is an alkaline It mainly utilizes the neutralizing action toward acidity.

みえる除菌液の成分は、アルカリ性に反応して色がつくPH指示薬を無水エタノールで溶し、塩基性物質と混ぜ合わせ着色する。 The components of the visible disinfectant solution are a PH indicator that changes color in response to alkalinity, dissolved in absolute ethanol, mixed with a basic substance, and colored.

前記PH指示薬が、フェノールフタレイン、チモールフタレイン、O−クレゾールフタレイン、チトリルまたはその誘導体からなる群から選ばれる1種以上からなる、みえる除菌液 A visible disinfectant , wherein the PH indicator comprises one or more selected from the group consisting of phenolphthalein, thymolphthalein, O-cresolphthalein, titril or derivatives thereof.

前記塩基性物質が、アルカリ性の機能水から選ばれる、アルカリイオン水、強アルカリ性電解水、電解次亜水、次亜塩素酸ナトリウムや、アルカリ金属およびアルカリ土類金属の水酸化物、水に溶解すると水酸化物イオンを生じアルカリ性となる水溶液、アンモニヤおよびリン酸ナトリウム、アルカノールアミンまたはその誘導体からなる群から選ばれる1種以上からなる、みえる除菌液The basic substance is dissolved in alkaline ionized water, strongly alkaline electrolyzed water, electrolyzed hypochlorite, sodium hypochlorite, hydroxides of alkali metals and alkaline earth metals, and water selected from alkaline functional waters. A visible disinfectant solution consisting of one or more selected from the group consisting of an aqueous solution that produces hydroxide ions and becomes alkaline, ammonia and sodium phosphate, alkanolamine or a derivative thereof.

菌やウイルス、汚れの除去を主として目的とする、みえる除菌液の配合には、チモールフタレイン溶液とPH10.5以上のアルカリ性の機能水およびPH10.5以上の水酸化物が好ましいく、着色された溶剤は紫外線や常温での影響をほとんど受けず、透明な容器で洗浄力・消毒力の効果が視認でき、除菌力に優れ、一般生菌は30秒〜1分で除菌ができ、人に無害で環境にもやさしく、未開封なら1年〜2年間は保存可能となる、みえる除菌液の提供。 For the formulation of a visible disinfectant solution whose main purpose is to remove bacteria, viruses, and stains, a timole phthalein solution, alkaline functional water having a pH of 10.5 or more, and a hydroxide having a pH of 10.5 or more are preferable and colored. The solvent is almost unaffected by ultraviolet rays and normal temperature, and the effects of detergency and disinfection can be visually recognized in a transparent container. Providing a visible disinfectant solution that is harmless to humans and environmentally friendly and can be stored for 1 to 2 years if unopened.

消毒剤としてあらゆる菌・ウイルスに対して、殺菌、除菌、消毒、を行うという観点では、日本薬局方が定める76.9〜81.4v/v%が必要であるため、エタノールとPH10.5以上のアルカリ性の機能水およびPH10.5以上の水酸化物の1種類以上を、無水エタノールにチモールフタレインを0.1w/v%〜10w/v%で溶解した溶液と混合し、エタノール濃度を76.9〜81.4vol%含有する、みえる除菌液の提供。From the viewpoint of sterilizing, sterilizing, and disinfecting all bacteria and viruses as a disinfectant, 76.9 to 81.4 v / v% specified by the Japanese Pharmacy is required, so ethanol and PH 10.5 One or more of the above alkaline functional waters and hydroxides having a pH of 10.5 or more are mixed with a solution of timolephthaline in absolute ethanol at 0.1 w / v% to 10 w / v% to adjust the ethanol concentration. Provision of a visible disinfectant solution containing 76.9 to 81.4 vol%.

日本薬局方により、消毒剤と表記できない、エタノール76.9v/v%以下を、洗浄剤として、PH10.5以上のアルカリ性の機能水およびPH10.5以上の水酸化物の1種類以上の溶液と無水エタノールにチモールフタレインを0.1w/v%〜10w/v%で溶かした溶液を1w/v%〜20w/v%混合し、着色した、みえる除菌液を提供。According to the Japanese Pharmacopoeia, ethanol 76.9v / v% or less, which cannot be described as a disinfectant, is used as a cleaning agent with one or more solutions of alkaline functional water with a pH of 10.5 or more and a hydroxide with a pH of 10.5 or more. A solution prepared by dissolving Timor Phthalene at 0.1 w / v% to 10 w / v% in absolute ethanol was mixed at 1 w / v% to 20 w / v% to provide a colored, visible disinfectant solution.

ウイルス除去・除菌剤として、あらゆる菌・ウイルスに対して、殺菌、除菌・消毒、を行うという観点では、日本薬局方が定めるエタノール濃度が76.9〜81.4v/v%必要であるが、エタノール63v/v%の濃度があれば、一部の菌・ウイルスを除き十分な殺菌効果が期待できることから、洗浄剤として、エタノールとPH10.5以上のアルカリ性の機能水およびPH10.5以上の水酸化物の1種類以上を混ぜ、無水エタノールにチモールフタレインを0.1w/v%〜10w/v%で溶した溶液を混合し、エタノール濃度を63%以上〜76.9%含有する、みえる除菌液を提供。From the viewpoint of sterilizing, sterilizing and disinfecting all bacteria and viruses as a virus removing and disinfecting agent, the ethanol concentration specified by the Japanese Pharmacy is required to be 76.9 to 81.4 v / v%. However, if the concentration of ethanol is 63 v / v%, a sufficient bactericidal effect can be expected except for some bacteria and viruses. Therefore, as a cleaning agent, ethanol, alkaline functional water having a pH of 10.5 or more, and pH 10.5 or more can be expected. 1 or more of the hydroxides of the above are mixed, and a solution of timolephthalene dissolved in absolute ethanol at 0.1 w / v% to 10 w / v% is mixed, and the ethanol concentration is 63% or more to 76.9%. Provides a visible disinfectant solution.

物に対しての除菌、汚れ落としは対象物や用途によりエタノール濃度の調整必要で、エタノール63v/v%未満の濃度で、十分な除菌、汚れ落とし期待できることから、洗浄剤として、エタノールとPH10.5以上のアルカリ性の機能水およびPH10.5以上の水酸化物の1種類以上と、無水エタノールにチモールフタレインを0.1w/v%〜10w/v%で溶した溶液を混合し、エタノール濃度を63%未満で含有する、みえる除菌液を提供。For sterilization and stain removal of objects, it is necessary to adjust the ethanol concentration depending on the object and application, and since sufficient sterilization and stain removal can be expected at a concentration of less than 63 v / v% of ethanol, ethanol is used as a cleaning agent. A solution of timolephthalene dissolved in absolute ethanol at 0.1 w / v% to 10 w / v% is mixed with one or more kinds of alkaline functional water having a pH of 10.5 or more and a hydroxide having a pH of 10.5 or more. Provided a visible disinfectant solution containing an ethanol concentration of less than 63%.

みえる除菌液はアルカリ性から酸性に向う中和作用を主として利用していることから、無水エタノールに0.1w/v%〜10w/v%で溶解したPH指示薬は、中性〜塩基性の透明な消毒剤や洗浄剤に、PH10.5以上のアルカリ性の機能水およびPH10.5以上の水酸化物の1種類以上を混合させると色がつき、可視化剤及び着色添加剤として提供できる。 Since the visible disinfectant solution mainly utilizes the neutralizing action from alkaline to acidic, the PH indicator dissolved in absolute ethanol at 0.1 w / v% to 10 w / v% is neutral to basic transparent. When one or more kinds of alkaline functional water having a pH of 10.5 or more and a hydroxide having a pH of 10.5 or more are mixed with a disinfectant or a cleaning agent, the mixture is colored and can be provided as a visualization agent and a coloring additive.

これにより市販及び製造されている中性〜塩基性の透明な消毒剤や洗浄剤を、みえる洗浄剤・消毒剤にでき、量産や普及が安易にできることが期待でき、感染防止が期待できる。 As a result, neutral to basic transparent disinfectants and cleaning agents that are commercially available and manufactured can be turned into visible cleaning agents and disinfectants, and it can be expected that mass production and disinfection can be easily performed, and infection prevention can be expected.

いちばん安易に普及でき、実施できる例として、無水エタノールにPH指示薬を0.1w/v%〜10w/v%で溶解した溶剤を、可視化剤とし、市販、購入済み及び製造済みのPH10.5以上のアルカリ性の透明な洗浄剤や消毒剤に混合させ、着色し、洗浄や消毒の洗浄力・消毒力を視認でき、透明なスプレーボトルやミストボトル等の容器に入れ、散布、噴霧等で洗浄・消毒を実施すると、色の消失時間が1〜4分程度で、洗浄・消毒に必要な時間で色が消失し、洗浄や消毒の実施安定性の向上ができる。 As an example that can be most easily disseminated and can be implemented, a solvent obtained by dissolving a PH indicator in absolute ethanol at 0.1 w / v% to 10 w / v% is used as a visualization agent, and the pH is 10.5 or more, which has been commercially available, purchased, and manufactured. It is mixed with an alkaline transparent cleaning agent or disinfectant, colored, and the cleaning and disinfecting power can be visually confirmed. When disinfection is performed, the color disappearance time is about 1 to 4 minutes, the color disappears in the time required for cleaning and disinfection, and the stability of cleaning and disinfection can be improved.

市販、購入済み及び製造済みの、PH7の中性〜PH10.5未満のアルカリ性の透明な洗浄剤や消毒剤に着色するには、このままでは塩基性が弱いのでPH12以上の強塩基性物質と無水エタノールにPH指示薬を0.1w/v%〜10w/v%で混合した溶剤を、着色添加剤とし、混合させ、安易に運べる容器に入れ、着色添加剤として混合し、洗浄や消毒を実施する。 In order to color commercially available, purchased and manufactured alkaline transparent detergents and disinfectants with a pH of 7 to less than 10.5, the basicity is weak as it is, so it is anhydrous with a strong basic substance with a pH of 12 or higher. A solvent in which a PH indicator is mixed with ethanol at 0.1 w / v% to 10 w / v% is used as a coloring additive, mixed, placed in an easily transportable container, mixed as a coloring additive, and cleaned and disinfected. ..

前記のPH指示薬とは、フェノールフタレイン、チモールフタレイン、O−クレゾールフタレイン、チトリルまたはその誘導体からなる群から選ばれる1種以上からなるものとし、用途により選択し、混合する。 The PH indicator shall consist of one or more selected from the group consisting of phenolphthalein, thymolphthalein, O-cresolphthalein, titril or a derivative thereof, and shall be selected and mixed according to the intended use.

前記の、PH10.5以上のアルカリ性の透明な洗浄剤や消毒剤とは、アルカリ性の機能水から選ばれる、アルカリイオン水、強アルカリ性電解水、電解次亜水、次亜塩素酸ナトリウム、アルカリ金属およびアルカリ土類金属の水酸化物、水に溶解すると水酸化物イオンを生じアルカリ性となる水溶液、アンモニヤおよびリン酸ナトリウム、アルカノールアミンまたはその誘導体からなる群から選ばれる1種以上からなるものとし、用途により選択し、混合する。 The above-mentioned alkaline transparent cleaning agent and disinfectant having a pH of 10.5 or more are alkaline ionized water, strongly alkaline electrolyzed water, electrolyzed hypochlorite, sodium hypochlorite, and alkali metal, which are selected from alkaline functional water. It shall consist of one or more selected from the group consisting of hydroxides of alkaline earth metals, aqueous solutions that generate hydroxide ions when dissolved in water and become alkaline, ammonia and sodium phosphate, alkanolamine or derivatives thereof. Select according to the application and mix.

無水エタノールで溶したPH指示薬と、塩基性物質を含有する洗浄剤・消毒剤で、塩基性側では色がつき、洗浄力・消毒力を視認でき、着色された色は酸性側に反応し塩基性を失うと無色になり、必要最小限の水で洗浄・消毒するものを以下は、みえる除菌液とし実施例をあげる。A PH indicator dissolved in absolute ethanol and a cleaning agent / disinfectant containing a basic substance. The basic side is colored, and the cleaning power / disinfecting power can be visually recognized. The following is an example of a disinfectant solution that becomes colorless when it loses its properties and is washed and disinfected with the minimum necessary water.

みえる除菌液を、携帯用のボトル容器に入れ、安易に持ち運べるようにし、気になるときに物や手、肌や指に洗浄・消毒を実施する。 Put the visible disinfectant in a portable bottle container so that it can be easily carried, and clean and disinfect things, hands, skin and fingers when you are concerned.

上記の場合、消色に要する時間は対象物が酸性に近いほどより早く消失し、人の肌は弱酸性なため手や肌に直接噴霧または、直接手に取り擦り込ことで、一瞬で色が消失してしまい、色の消失時間を利用した除去時間が取れないことから、下記に有効とされる実施例をあげる。 In the above case, the time required for decolorization disappears faster as the object becomes more acidic, and since human skin is weakly acidic, it can be instantly colored by spraying it directly on the hand or skin or rubbing it directly on the hand. Will disappear, and the removal time using the color disappearance time cannot be taken. Therefore, the following examples are effective.

市販のペーパータオルやティッシュパーパーなどに、スプレーボトルやプッシュボトル等で、みえる除菌液を散布、噴霧、塗布等により染色して洗浄・消毒を実施すると、色の消失時間が15〜30秒程度で、洗浄・消毒に必要な時間で色が消失し、洗浄や消毒の実施安定性の向上ができる。When cleaning and disinfecting a commercially available paper towel or tissue paper by spraying, spraying, or applying a visible disinfectant solution with a spray bottle or push bottle, the color disappears in about 15 to 30 seconds. , The color disappears in the time required for cleaning and disinfection, and the stability of cleaning and disinfection can be improved.

おしぼりやウェットティッシュ、ウェットシートなどに、みえる除菌液を散布や媒染等で染色し、密封包装して、安易に持ち運びできる形態にして洗浄・消毒を実施すると、色の消失時間が30〜40秒程度で、洗洗浄・消毒に必要な時間で色が消失し、洗浄や消毒の実施安定性の向上ができる。 When the visible disinfectant solution is dyed on a squeeze, wet tissue, wet sheet, etc. by spraying or mordanting, sealed and packaged, and cleaned and disinfected in a form that can be easily carried, the color disappearance time is 30 to 40. In about a second, the color disappears in the time required for washing and disinfection, and the stability of cleaning and disinfection can be improved.

消毒綿や不織布などに、みえる除菌液を散布や媒染等で染色し、密封包装して、安易に持ち運びできる形態にして洗浄・消毒を実施すると、色の消失時間が30〜40秒程度で、洗洗浄・消毒に必要な時間で色が消失し、洗浄や消毒の実施安定性の向上ができる。When disinfecting cotton or non-woven fabric is dyed with a visible disinfectant solution by spraying or mordanting, sealed and packaged, and cleaned and disinfected in a form that can be easily carried, the color disappears in about 30 to 40 seconds. , The color disappears in the time required for washing and disinfection, and the stability of cleaning and disinfection can be improved.

みえる除菌液を、面積に小さい対象物に対して実施する例として、塗装をするときに使用するペインターボトルや車のガラスを撥水させるときに使用するスポンジヘッド容器等に入れ、安易に持ち運びできる形態にして、気になるところに安定した塗布幅でピンポイントに洗浄・消毒を実施すると、色の消失時間が30〜40秒程度で、洗洗浄・消毒に必要な時間で色が消失し、洗浄や消毒の実施安定性の向上ができる。 As an example of applying the visible disinfectant solution to an object with a small area, put it in a painter bottle used for painting or a sponge head container used for making car glass water repellent, and carry it easily. When cleaning and disinfecting is performed pinpointly with a stable application width in a form that can be used, the color disappears in about 30 to 40 seconds, and the color disappears in the time required for washing and disinfecting. , Cleaning and disinfection can improve stability.

みえる除菌液を、面積に広い対象物に対して実施する例として、農薬散布で使用する噴霧器入れ、防護服や壁、床、車両、に洗浄・消毒を実施すると、色の消失時間が1分〜2分程度で、洗洗浄・消毒に必要な時間で色が消失し、洗浄や消毒の実施安定性の向上ができる。 As an example of applying a visible disinfectant solution to an object with a large area, if the sprayer used for spraying pesticides, protective clothing, walls, floors, vehicles, etc. are cleaned and disinfected, the color disappearance time is 1 In about 1 to 2 minutes, the color disappears in the time required for washing and disinfection, and the stability of cleaning and disinfection can be improved.

みえる除菌液の利用は、洗浄・消毒をしたい、多くの場所や物、人に有効で、例えば、車の内装、病院内の壁や物、防護服や仮設テントの消毒、診察台等、多くはプラスチック用品、便器、便座、浴室、キッチン、電子レンジ、冷蔵庫、厨房、ガラス、床、おもちゃ、パソコンや電話機などの洗浄・消毒に利用できる。 The use of visible disinfectant is effective for many places, things, and people who want to clean and disinfect, for example, car interiors, walls and things in hospitals, disinfection of protective clothing and temporary tents, examination tables, etc. Many can be used for cleaning and disinfecting plastic supplies, toilet bowls, toilet seats, bathrooms, kitchens, microwave ovens, refrigerators, kitchens, glass, floors, toys, personal computers and telephones.

みえる除菌液の利用は、テーブルや、ベッド、防護服、ドアノブ、トイレ便座、浴槽などの洗浄・消毒に有効なのはスプレー容器やミストスプレー容器などに入れ対象物に噴射し、色の消失後は中和された水や、アルコールが残るので気になる場合は拭き取るか、または乾燥するまで放置することで洗浄・消毒に利用できる。 The visible disinfectant can be used to clean and disinfect tables, beds, protective clothing, door knobs, toilet seats, bathtubs, etc. by putting them in a spray container or mist spray container and spraying them on the object. Neutralized water and alcohol remain, so if you are concerned, you can wipe it off or leave it until it dries to use it for cleaning and disinfection.

ヨウ素系や着色系の洗浄剤・消毒剤は実施後に色を洗い流すために大量の水を使用するが、みえる除菌液で着色された色は酸性側に反応し無色になり中性になり水や、アルコールが残るが、拭き取るだけで、再度洗い流す必要がなく水不足な地域・環境で有効的な洗浄・消毒に利用できる。Iodine-based and coloring-based cleaning agents and disinfectants use a large amount of water to wash away the color after implementation, but the color colored with the visible disinfectant reacts to the acidic side and becomes colorless and neutral and becomes water. Or, alcohol remains, but it can be used for effective cleaning and disinfection in water-scarce areas and environments without having to wash it off again by simply wiping it off.

洗浄剤・消毒剤の可視化により小さな子供や言語、教育の障壁を超えて、最小限の技術で洗浄・消毒を実施することが期待できる。By visualizing cleaning agents and disinfectants, it can be expected that cleaning and disinfection will be carried out with the minimum technology, overcoming the barriers of small children, language, and education.

Claims (1)

エタノールで溶解したPH指示薬のチモールフタレインと、強アルカリ電解水を含有し、PH10.5以上のウイルス・菌や汚れの除去及び除菌液であって、塩基性側では色がつき、除菌力・消毒力が視認でき、着色された色は酸性側に反応し塩基性を失うと無色になる、みえる除菌液。 It contains thymolphthalein, a PH indicator dissolved in ethanol, and strong alkaline electrolyzed water, and is a sterilizing solution for removing viruses, bacteria and stains with a pH of 10.5 or higher. A visible disinfectant that has visible power and disinfecting power, and the colored color reacts to the acidic side and becomes colorless when it loses its basicity.
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JP2000273497A (en) * 1999-03-25 2000-10-03 Nisshin Medeiko:Kk Spray type cleaning agent
JP2002256291A (en) * 2001-03-01 2002-09-11 Arutan Kk Detergent composition containing ph indicator and coloring cleansing composition

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JPS5027846B1 (en) * 1969-05-16 1975-09-10
US5929004A (en) 1997-10-10 1999-07-27 No Touch North America Detergent for cleaning tire wheels and cleaning method
JP6112448B2 (en) * 2012-11-30 2017-04-12 株式会社ケミコート Cleaning composition and cleaning method

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JPS5358506A (en) * 1976-11-09 1978-05-26 Dainichi Seika Kogyo Kk Detergent composition
JP2000273497A (en) * 1999-03-25 2000-10-03 Nisshin Medeiko:Kk Spray type cleaning agent
JP2002256291A (en) * 2001-03-01 2002-09-11 Arutan Kk Detergent composition containing ph indicator and coloring cleansing composition

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