JP6892255B2 - Tofu-like fluid food and its manufacturing method - Google Patents

Tofu-like fluid food and its manufacturing method Download PDF

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JP6892255B2
JP6892255B2 JP2016241450A JP2016241450A JP6892255B2 JP 6892255 B2 JP6892255 B2 JP 6892255B2 JP 2016241450 A JP2016241450 A JP 2016241450A JP 2016241450 A JP2016241450 A JP 2016241450A JP 6892255 B2 JP6892255 B2 JP 6892255B2
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soymilk
tofu
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望美 照屋
望美 照屋
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NIPPN Corp
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Nippon Flour Mills Co Ltd
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本発明は、豆腐様流動性食品およびその製造方法に関する。詳細には、多価酸のアルカリ金属塩および多価酸のアンモニウム塩からなる群より選ばれる少なくとも1種類の塩基性物質を含む豆乳を酸凝固剤及び/又は塩凝固剤で凝固させ、凝固物を流動化してなる豆腐様流動性食品及びその製造方法に関するものである。 The present invention relates to tofu-like fluid foods and methods for producing the same. Specifically, soymilk containing at least one basic substance selected from the group consisting of an alkali metal salt of a polyhydric acid and an ammonium salt of a polyhydric acid is coagulated with an acid coagulant and / or a salt coagulant to coagulate the coagulated product. It relates to a tofu-like fluid food obtained by fluidizing and a method for producing the same.

近年の健康志向により大豆製品が注目され、中でも豆乳を原料とした様々な食品又は食品中間原料として豆乳加工製品が市場に広く流通している。豆乳には大豆由来の様々な健康機能性成分が含まれており、肥満予防や動脈硬化防止に有効であるとされる大豆タンパク質、骨粗鬆症や更年期障害に有効な女性ホルモン(エストロゲン)様作用を示すイソフラボン、脳の老化予防や血中コレステロールの低減に役立つ大豆レシチン、抗酸化作用による老化と動脈硬化の防止やガン増殖抑制に有効な大豆サポニン、ビフィズス菌増殖を活性化して整腸作用を促すオリゴ糖(スタキオース、ラフィノース)、その他フィチン酸、ビタミンB群、ビタミンE、カリウム、マグネシウム、必須脂肪酸などが上げられる(日本豆乳協会HPよりhttp://www.tounyu.jp/about03.html)。
豆乳を原料とした加工品として最も親しまれているのは、日本の伝統食品でもある豆腐である。豆腐はそのまま喫食してもよいが、具材として茹で、炒め、焼き等の加熱工程等を経て様々な料理へと調理して喫食してもよい。
豆乳は、そのまま飲んでもよいが、調味料や各種食品添加物を配合された調整豆乳や豆乳飲料又は乳酸菌発酵されたヨーグルト様酸性豆乳食品等に加工して飲食されることが多い。
近年では、前記の様な飲食の形態だけではなく、牛乳及びその調製品、クリーム類、ムース類、スプレッド類、マヨネーズ類等の流動性食品又は半固形食品の代用として、豆乳や豆腐をその用途に応じて調味及び加工したペースト状食品が各種料理に使用されるようになり、そのレシピも多様になってきている。しかしながら、加工過程の加熱冷却により大豆特有の豆臭がしたり、タンパク質の変性に伴う凝固や離水によりザラつきやボソつきのある食感になったり、前記流動性食品又は半固形食品の代用品として満足される品質を有しているものではなかった。これらの課題にたいして解決方法が色々提案されているが、その解決には至っていない。
特許文献1には、豆乳に水溶性ヘミセルロース加えて撹拌溶解した後、70〜80℃に加熱し、にがりを加え、必要に応じて均質化を行うことを特徴とした、流動性のある豆腐様食品の製造方法が開示されている。この発明の目的は、豆乳ににがりを添加しても凝固することなく、豆腐に近い風味を有し口当たりが軽く、豆乳独特の青臭さが低減された、飲用にも供することができる流動性のある豆腐様食品を製造することである。水溶性ヘミセルロースは、その構成糖としてウロン酸を含有しており、そのウロン酸が多価の陰イオンとなって陽イオン交換能を持つようになり、ナトリウムイオン、カリウムイオン、カルシウムイオン、マグネシウムイオン等の陽イオンを吸着することが知られている。この発明は、豆乳に添加されたにがりや塩化マグネシウムの一部ないし全部が水溶性ヘミセルロースに吸着(キレート)されることにより、豆乳中の大豆蛋白質の塩凝固が抑制されるために流動性のある豆腐様食品が得られるものである。しかしながら、この発明は、グルコノデルタラクトンや有機酸による豆乳の酸凝固を抑制して流動性のある豆腐様食品を製造できるものではない。また、豆乳に凝固剤を加えて豆腐を製造する際に重曹を添加することを示唆する記載はない。
特許文献2には濃縮豆乳に凝固剤を添加して豆腐を調製し、得られた豆腐に増粘ゲル化剤とオリゴ糖類とを混合し、高速カッター等で滑らかなムース状の水準になるまで擂潰した後冷却することを特徴とした、豆腐ペーストの製造方法が開示されている。豆腐の擂潰物は、そのままの状態では離水して品質が劣化し易く、擂潰物を含む食品にベタつきを生じさせる。この発明は、このような問題を解決することを目的として、擂潰(ペースト)組織をゲル化剤で固定して保水性を高め、製造時及び保存時の離水を防止して品質を維持しようとするものである。豆腐が離水した際のボソ付いた食感を抑制できるものの、ムース状になるまで擂潰するとはいえザラついた食感を抑制できるものではない。
特許文献3には定法により製造された豆腐をペースト化し、難消化性デキストリン及び増粘安定剤を添加して混合した後冷凍することを特徴とする冷凍豆腐ペーストの製造方法が開示されている。この発明は油脂やカロリーの高い糖を添加することなく、カロリーの少ない添加物を添加することで、健康食品としての機能を維持しつつ、冷凍解凍しても冷凍前の食感を維持した冷凍豆腐ペーストを製造することを目的とする。しかしながら、豆腐を製造する工程及びその豆腐をペースト化する工程が必須であり、手間と時間を要するばかりでなく、豆腐をペースト化した際のザラつきを十分に解消できるものではない。
In recent years, soybean products have attracted attention due to health consciousness, and among them, soymilk processed products are widely distributed in the market as various foods made from soymilk or as food intermediate raw materials. Soy milk contains various health functional ingredients derived from soybeans, and exhibits soy protein, which is said to be effective in preventing obesity and arteriosclerosis, and female hormone (estrogen) -like action, which is effective in osteoporosis and menopausal disorders. Isoflavones, soy lecithin that helps prevent brain aging and reduce blood cholesterol, soy saponin that is effective in preventing aging and arteriosclerosis due to antioxidant effects and suppressing cancer growth, and oligos that activate bifidus growth and promote intestinal regulation Sugar (stachyose, raffinose), other phytic acid, B vitamins, vitamin E, potassium, magnesium, essential fatty acids, etc. can be raised (http://www.tounyu.jp/about03.html from the Japan Soybean Milk Association HP).
The most popular processed product made from soy milk is tofu, which is also a traditional Japanese food. The tofu may be eaten as it is, but it may be cooked into various dishes through heating steps such as boiling, stir-frying, and baking as ingredients.
Soymilk may be drunk as it is, but it is often processed into adjusted soymilk containing seasonings and various food additives, soymilk beverages, yogurt-like acidic soymilk foods fermented with lactic acid bacteria, and the like.
In recent years, soymilk and tofu have been used as substitutes for fluid foods such as milk and its preparations, creams, mousses, spreads and mayonnaise, or semi-solid foods, in addition to the above-mentioned forms of eating and drinking. Seasoned and processed pasty foods have come to be used in various dishes, and their recipes are becoming more diverse. However, it has a bean odor peculiar to soybeans due to heating and cooling in the processing process, and has a rough or rough texture due to coagulation and water separation due to protein denaturation. It did not have satisfactory quality. Various solutions have been proposed for these problems, but they have not yet been solved.
Patent Document 1 describes a fluid tofu-like substance, which comprises adding water-soluble hemicellulose to soymilk, stirring and dissolving it, heating it to 70 to 80 ° C., adding bittern, and homogenizing it as necessary. A method for producing food is disclosed. An object of the present invention is that even if bittern is added to soymilk, it does not coagulate, has a flavor close to that of tofu, has a light taste, and has a reduced green odor peculiar to soymilk. To produce a tofu-like food. Water-soluble hemicellulose contains uronic acid as its constituent sugar, and the uronic acid becomes a polyvalent anion and has a cation exchange ability, so that it has sodium ion, potassium ion, calcium ion, and magnesium ion. It is known to adsorb cations such as. According to the present invention, part or all of bittern and magnesium chloride added to soymilk are adsorbed (chelated) on water-soluble hemicellulose, so that salt coagulation of soybean protein in soymilk is suppressed, so that the present invention is fluid. A tofu-like food is obtained. However, the present invention cannot produce a fluid tofu-like food by suppressing acid coagulation of soymilk by glucono delta lactone or an organic acid. In addition, there is no description suggesting that baking soda is added when the coagulant is added to soymilk to produce tofu.
In Patent Document 2, a coagulant is added to concentrated soymilk to prepare tofu, and the obtained tofu is mixed with a thickening gelling agent and an oligosaccharide until it reaches a smooth mousse-like level with a high-speed cutter or the like. A method for producing a tofu paste, which is characterized in that it is crushed and then cooled, is disclosed. As it is, the tofu pickles tend to separate from water and deteriorate in quality, causing stickiness in foods containing the pickles. In the present invention, for the purpose of solving such a problem, the crushed (paste) structure is fixed with a gelling agent to improve water retention, prevent water separation during manufacturing and storage, and maintain quality. Is to be. Although it is possible to suppress the rough texture when the tofu is separated from the water, it is not possible to suppress the rough texture even if it is crushed until it becomes mousse-like.
Patent Document 3 discloses a method for producing frozen tofu paste, which comprises making tofu produced by a conventional method into a paste, adding indigestible dextrin and a thickening stabilizer, mixing the mixture, and then freezing the paste. In this invention, by adding a low-calorie additive without adding fat or high-calorie sugar, the frozen product maintains its function as a health food and maintains the texture before freezing even when frozen and thawed. The purpose is to produce tofu paste. However, the process of producing tofu and the process of pasting the tofu are indispensable, and not only it takes time and effort, but also the roughness when the tofu is pasted cannot be sufficiently eliminated.

特開2007−222101JP-A-2007-222101 特開2002−209JP 2002-209 特開平6−46784JP-A-6-468784

ザラつきがなく滑らかな食感をしており、静置保存、ソース等への加熱加工処理及び加熱加工処理後の凍結解凍をしても離水しがたく食感が損なわれない豆腐様流動性食品を提供する。 It has a smooth texture without roughness, and it has a tofu-like fluidity that does not easily separate from water and does not impair the texture even if it is stored in a static state, heat-processed on a sauce, etc., and frozen and thawed after the heat-processing treatment. Serve food.

本発明者等は上記課題を解決する為鋭意研究を重ねた結果、特定量の多価酸のアルカリ金属塩および多価酸のアンモニウム塩からなる群より選ばれる少なくとも1種類の塩基性物質を含む豆乳を特定量の酸凝固剤及び/又は塩凝固剤で凝固させ、凝固物を流動化することにより、ザラつきがなく滑らかな食感をしており、静置保存、ソース等への加熱加工処理及び加熱加工処理後の凍結解凍をしても離水しがたく食感が損なわれないことを見いだし、本発明を完成するに至った。
すなわち本発明は以下の通りである。
[1]多価酸のアルカリ金属塩および多価酸のアンモニウム塩からなる群より選ばれる少なくとも1種類の塩基性物質を含む豆乳を酸凝固剤及び/又は塩凝固剤で凝固させ、凝固物を流動化してなる豆腐様流動性食品であって、豆乳100質量部に対し前記塩基性物質の量が0.01〜0.07質量部であり、酸凝固剤及び/又は塩凝固剤の量が0.08質量部以上である前記豆腐様流動性食品。
[2]前記前記塩基性物質を含む豆乳が塩化ナトリウムを含む、[2]に記載の豆腐様流動性食品。
[3]前記塩基性物質が、重曹(炭酸水素ナトリウム)、炭酸水素アンモニウム、リン酸水素2カリウム、リン酸水素2ナトリウムからなる群から選択される、[1]又は[2]に記載の豆腐様流動性食品。
[4]多価酸のアルカリ金属塩および多価酸のアンモニウム塩からなる群より選ばれる少なくとも1種類の塩基性物質を含む豆乳を調製する工程、前記塩基性物質を含む豆乳を酸凝固剤及び/又は塩凝固剤で凝固させる工程、及び凝固物を流動化する工程を含む豆腐様流動性食品の製造方法であって、豆乳100質量部に対し前記塩基性物質の量が0.01〜0.07質量部であり、酸凝固剤及び/又は塩凝固剤の量が0.08質量部以上である前記方法。
[5]前記塩基性物質を含む豆乳を調製する工程において、さらに塩化ナトリウムを添加する請求項4に記載の方法。
[6]前記塩基性物質が、重曹(炭酸水素ナトリウム)、炭酸水素アンモニウム、リン酸水素2カリウム、リン酸水素2ナトリウムからなる群から選択される、[4]又は[5]に記載の方法。
As a result of intensive studies to solve the above problems, the present inventors include at least one basic substance selected from the group consisting of a specific amount of an alkali metal salt of a polyhydric acid and an ammonium salt of a polyhydric acid. By coagulating soymilk with a specific amount of acid coagulant and / or salt coagulant and fluidizing the coagulated product, it has a smooth texture without roughness, and is stored statically or heat-processed into a sauce. It has been found that even if the product is frozen and thawed after the treatment and the heat processing treatment, it is difficult to separate water and the texture is not impaired, and the present invention has been completed.
That is, the present invention is as follows.
[1] Soy milk containing at least one basic substance selected from the group consisting of an alkali metal salt of a polyhydric acid and an ammonium salt of a polyhydric acid is coagulated with an acid coagulant and / or a salt coagulant to coagulate the coagulated product. A fluidized tofu-like fluid food in which the amount of the basic substance is 0.01 to 0.07 parts by mass with respect to 100 parts by mass of soymilk, and the amount of acid coagulant and / or salt coagulant is The tofu-like fluid food having an amount of 0.08 parts by mass or more.
[2] The tofu-like fluid food according to [2], wherein the soymilk containing the basic substance contains sodium chloride.
[3] The tofu according to [1] or [2], wherein the basic substance is selected from the group consisting of baking soda (sodium hydrogen carbonate), ammonium hydrogen carbonate, dipotassium hydrogen phosphate, and disodium hydrogen phosphate. Like fluid food.
[4] A step of preparing soymilk containing at least one basic substance selected from the group consisting of an alkali metal salt of a polyhydric acid and an ammonium salt of a polyhydric acid, the soymilk containing the basic substance is used as an acid coagulant and / Or a method for producing a tofu-like fluid food including a step of coagulating with a salt coagulant and a step of fluidizing the coagulated product, wherein the amount of the basic substance is 0.01 to 0 with respect to 100 parts by mass of soymilk. .07 parts by mass and the amount of acid coagulant and / or salt coagulant is 0.08 parts by mass or more.
[5] The method according to claim 4, wherein sodium chloride is further added in the step of preparing soymilk containing the basic substance.
[6] The method according to [4] or [5], wherein the basic substance is selected from the group consisting of baking soda (sodium hydrogen carbonate), ammonium hydrogen carbonate, dipotassium hydrogen phosphate, and disodium hydrogen phosphate. ..

本発明によれば、ザラつきがなく滑らかな食感をしており、静置保存、ソース等への加熱加工処理及び加熱加工処理後の凍結解凍をしても離水しがたく食感が損なわれない豆腐様流動性食品を提供することができる。本発明の豆腐様流動性食品はそのザラつきのない滑らかな食感から、牛乳及びその調製品、クリーム類、ムース類、スプレッド類、マヨネーズ類等の流動性食品又は半固形食品の代用食品として適している。更に、通常の方法で製造された豆腐を単に磨砕した豆腐ペーストは、ザラついた食感がし、室温又は冷蔵保存により離水し、加熱加工及び加熱加工物を冷凍解凍すると離水が起こってボソつき及びザラつきが生じる一方で、本発明の豆腐様流動性食品は、室温又は冷蔵保存しても離水が生じず、ソース等の調理素材として加熱加工しても水分蒸発による食感変化が起こり難く、そのソースを冷凍解凍しても離水による食感変化が起こらない。 According to the present invention, it has a smooth texture without roughness, and even if it is stored in a static state, heat-processed on a sauce or the like, and freeze-thawed after the heat-processing treatment, it is difficult to separate water and the texture is impaired. It is possible to provide a tofu-like fluid food that does not exist. The tofu-like fluid food of the present invention is suitable as a substitute food for milk and its preparations, creams, mousses, spreads, mayonnaise and other fluid foods or semi-solid foods because of its smooth texture without roughness. ing. Furthermore, the tofu paste, which is simply ground tofu produced by the usual method, has a rough texture and is separated from water by storage at room temperature or refrigerated, and when the heat-processed and heat-processed products are frozen and thawed, water separation occurs and the sauce becomes lumpy. On the other hand, the tofu-like fluid food of the present invention does not separate from water even when stored at room temperature or refrigerated, and even if it is heat-processed as a cooking material such as a sauce, the texture changes due to water evaporation. It is difficult, and even if the sauce is frozen and thawed, the texture does not change due to water separation.

本発明において「豆腐様食品」とは豆乳を含む溶液を凝固剤で凝固したものであり、「豆腐様流動性食品」とは豆腐様食品を流動化した食品をいう。豆腐様流動化食品は牛乳及びその調製品、クリーム類、ムース類、スプレッド類、マヨネーズ類等の流動性食品又は半固形食品の代用食品として使用することができる。 In the present invention, the "tofu-like food" is a coagulated solution containing soymilk with a coagulant, and the "tofu-like fluid food" is a fluidized tofu-like food. The tofu-like fluidized food can be used as a substitute for milk and its preparations, liquid foods such as creams, mousses, spreads and mayonnaise, or semi-solid foods.

本発明において「豆乳」とは浸漬大豆に加水して湿式粉砕及び均質化処理して生呉とするか、大豆粉砕物に加水後適当な時間放置して生呉とし、必要に応じてタンパク質濃度の調節を目的として生呉を加熱処理し、次いで固液分離によりオカラを除去して製造される液のことを言う。 In the present invention, "soy milk" is obtained by adding water to soaked soybeans and wet-grinding and homogenizing the soybeans to obtain raw kure, or by leaving the soybean crushed product for an appropriate time to obtain raw kure, and if necessary, protein concentration. It is a liquid produced by heat-treating soybeans for the purpose of adjusting soybeans and then removing okara by solid-liquid separation.

本発明において「豆乳」は大豆又は大豆粉砕物の何れを原料として調製してもよい。豆乳を大豆から調製する場合、十分に浸漬させた大豆に4〜6倍容量の水を加えて湿式粉砕し、必要に応じて均質化処理して生呉とし、そのままおからを絞り取って、又は、数分程度焦げないように攪拌しながら煮沸した後におからを絞り取って調製することができる。豆乳を大豆粉砕物から調製する場合、大豆粉砕物に5〜8倍容量の水を加え1〜2時間放置してからおからを絞り取って、又は、数分程度焦げないように攪拌しながら煮沸した後おからを絞り取って調製することができる。この様にして調製される豆乳は、市販の豆乳も含め何れも本発明の原料として使用することができる。 In the present invention, "soy milk" may be prepared from either soybeans or ground soybeans as a raw material. When soymilk is prepared from soybeans, 4 to 6 times the volume of water is added to the soybeans soaked in the soybeans and wet-ground, and if necessary, homogenized to make raw okara, and the okara is squeezed out as it is. Alternatively, it can be prepared by squeezing the okara after boiling while stirring so as not to burn for about several minutes. When preparing soymilk from crushed soybeans, add 5 to 8 times the volume of water to the crushed soybeans, leave it for 1 to 2 hours, squeeze the okara, or stir for several minutes without burning. After boiling, it can be prepared by squeezing the okara. Any of the soymilk prepared in this manner, including commercially available soymilk, can be used as a raw material of the present invention.

本発明においては豆乳の大豆固形分濃度は特に限定されるものではない。JAS規格では、豆乳は大豆固形分が8%以上、調製豆乳が6%以上、豆乳飲料が4%以上と規定されているが、これに拘束されない。本発明に使用する豆乳のBrixは、好ましくは5〜17、さらに好ましくは8〜14、より好ましくは11〜13である。豆乳の大豆固形分濃度が5質量%未満であっても本発明の効果は得られるが、豆乳の風味が弱くなる傾向にある。豆乳の大豆固形分濃度が17質量%を超えると、固形の浮遊物が生じ易く食感を損なう傾向にある。 In the present invention, the soybean solid content concentration of soymilk is not particularly limited. The JAS standard stipulates that soymilk has a soybean solid content of 8% or more, prepared soymilk of 6% or more, and soymilk beverage of 4% or more, but is not bound by this. The Brix of soymilk used in the present invention is preferably 5 to 17, more preferably 8 to 14, and even more preferably 11 to 13. Even if the soybean solid content concentration of soymilk is less than 5% by mass, the effect of the present invention can be obtained, but the flavor of soymilk tends to be weakened. When the soybean solid content concentration of soymilk exceeds 17% by mass, solid suspended matter is likely to be generated and the texture tends to be impaired.

豆乳の大豆固形分濃度は適宜調製することができる。大豆固形分濃度が低い場合には、例えば特開平09−248128や特開2006―136298等に記載されている濃縮方法及び公知の濃縮方法により所望の大豆固形分濃度に調製することができる。また豆乳の大豆固形分濃度が高い場合には、水で希釈することにより所望の大豆固形分濃度に調製することができる。なお、豆乳の大豆固形分濃度は、糖用屈折計(例えば株式会社アタゴ社製 MASTER 53T Brix0.0−53.0%)を用いて簡易的に測定することができ、その標準関係式は「豆乳の大豆固形分濃度=糖用屈折計示度(Brix)×0.93」である。本発明では、大豆固形分濃度として換算係数0.93を乗じないBrixで表記する。 The soybean solid content concentration of soymilk can be appropriately adjusted. When the soybean solid content concentration is low, it can be adjusted to a desired soybean solid content concentration by, for example, the concentration method described in JP-A-09-248128 or JP-A-2006-136298 and the known concentration method. When the soybean milk has a high soybean solid content concentration, it can be adjusted to a desired soybean solid content concentration by diluting with water. The soybean solid content concentration of soymilk can be easily measured using a sugar refractometer (for example, MASTER 53T Brix 0.0-53.0% manufactured by Atago Co., Ltd.), and the standard relational expression is ". Soybean solid content concentration of soymilk = refractometer reading for sugar (Brix) × 0.93 ”. In the present invention, the soybean solid content concentration is expressed in Brix without multiplying by a conversion coefficient of 0.93.

本発明において「塩基性物質」は、多価酸のアルカリ金属塩および多価酸のアンモニウム塩からなる群より選ばれる少なくとも1種類の塩基性物質である。本発明において塩基性物質としては食品に使用可能な多価酸のアルカリ金属塩または多価酸のアンモニウム塩であって、水溶液が塩基性を示すものであれば特に制限なく使用することができる。本発明において塩基性物質は、豆乳に添加して豆乳をアルカリ性にすることにより酸凝固剤による凝固速度を遅延させることができ、また1価カチオンにより、塩凝固剤に含まれる2価カチオンと豆乳蛋白質との架橋凝固を拮抗的に抑制させることができる。本発明において塩基性物質は、炭酸水素塩、リン酸水素塩、ピロリン酸塩であることが好ましく、例えば重曹(炭酸水素ナトリウム)、炭酸水素アンモニウム、リン酸水素2カリウム、リン酸水素2ナトリウム、ピロリン酸4ナトリウム、ピロリン酸4カリウムなどの単塩又は混合したものを使用することができる。さらに好ましくは重曹(炭酸水素ナトリウム)、炭酸水素アンモニウム、リン酸水素2カリウム、リン酸水素2ナトリウムであり、最も好ましくは重曹(炭酸水素ナトリウム)である。
本発明において塩基性物質は、豆乳100質量部に対して0.01〜0.07質量部添加することができる。好ましくは0.03〜0.06質量部、さらに好ましくは0.03〜0.05質量部添加することができる。0.01質量部未満では、凝固剤による豆乳の大豆蛋白の凝固力が強く、ザラついた食感になる。0.07質量部を超えると、凝固剤による豆乳の大豆蛋白の凝固力が弱くなり、粘度が得られない。また、加熱中にガスが発生して豆乳に泡立ちが生じるため、作業性が悪くなる。
In the present invention, the "basic substance" is at least one basic substance selected from the group consisting of an alkali metal salt of a polyhydric acid and an ammonium salt of a polyhydric acid. In the present invention, the basic substance is an alkali metal salt of a polyhydric acid or an ammonium salt of a polyhydric acid that can be used in foods, and can be used without particular limitation as long as the aqueous solution exhibits basicity. In the present invention, the basic substance can delay the coagulation rate by the acid coagulant by adding it to the soymilk to make the soymilk alkaline, and the monovalent cation causes the divalent cation and the soymilk contained in the salt coagulant. Cross-linking coagulation with protein can be suppressed antagonistically. In the present invention, the basic substance is preferably hydrogen carbonate, hydrogen phosphate, pyrophosphate, for example, baking soda (sodium hydrogen carbonate), ammonium hydrogen carbonate, dipotassium hydrogen phosphate, disodium hydrogen phosphate, etc. A single salt such as tetrasodium pyrophosphate and tetrapotassium pyrophosphate or a mixture thereof can be used. More preferably, baking soda (sodium hydrogen carbonate), ammonium hydrogen carbonate, dipotassium hydrogen phosphate, disodium hydrogen phosphate, and most preferably baking soda (sodium hydrogen carbonate).
In the present invention, the basic substance can be added in an amount of 0.01 to 0.07 parts by mass with respect to 100 parts by mass of soymilk. It is possible to add 0.03 to 0.06 parts by mass, more preferably 0.03 to 0.05 parts by mass. If it is less than 0.01 parts by mass, the coagulation power of soybean protein in soymilk by the coagulant is strong, and the texture becomes rough. If it exceeds 0.07 parts by mass, the coagulation power of soybean protein in soymilk by the coagulant becomes weak and the viscosity cannot be obtained. In addition, gas is generated during heating and soymilk foams, resulting in poor workability.

本発明において、「凝固剤」は酸凝固剤及び/又は塩凝固剤であり、塩凝固剤としては塩化カルシウム、塩化マグネシウム、硫酸カルシウム、硫酸マグネシウム、乳酸カルシウム等の二価カチオン塩又はニガリを、酸凝固剤としてグルコノデルタラクトン(GDL)、乳酸、リンゴ酸、酢酸、コハク酸、酒石酸、クエン酸等の有機酸を例示することができる。
凝固剤の添加量は、使用する凝固剤の種別によって適宜変更することができるが、豆乳100質量部に対して0.08質量部以上添加することができる。好ましくは0.08〜0.5質量部である。凝固剤の添加量が0.08質量部未満では、大豆タンパク質の凝固が起こり難く、粘度不足となり不適である。凝固剤の添加量が0.5質量部を超えると、添加量に依存して凝固剤の異味(エグミ、苦味、酸味)が感じられる傾向にある。
In the present invention, the "coagulant" is an acid coagulant and / or a salt coagulant, and the salt coagulant is a divalent cationic salt such as calcium chloride, magnesium chloride, calcium sulfate, magnesium sulfate, calcium lactate, or biting. Examples of the acid coagulant include organic acids such as gluconodeltalactone (GDL), lactic acid, malic acid, acetic acid, succinic acid, tartrate acid, and citric acid.
The amount of the coagulant added can be appropriately changed depending on the type of coagulant used, but 0.08 part by mass or more can be added with respect to 100 parts by mass of soymilk. It is preferably 0.08 to 0.5 parts by mass. If the amount of the coagulant added is less than 0.08 parts by mass, soybean protein is unlikely to coagulate, resulting in insufficient viscosity, which is unsuitable. When the amount of the coagulant added exceeds 0.5 parts by mass, the coagulant tends to have an unpleasant taste (acriding, bitterness, acidity) depending on the amount added.

本発明において、塩基性物質を含む豆乳にさらに塩化ナトリウムを添加することができる。塩化ナトリウムの添加により豆乳の凝固剤による凝固が遅延緩和され、よりザラつきのない滑らかな食感になる。塩化ナトリウムの添加量は特に限定されないが、好ましくは豆乳100質量部に対して0.05〜1.5質量部添加する。塩化ナトリウムの添加量が豆乳100質量部に対して2質量部を超えると塩味が感じられるので、用途によっては好ましくない。 In the present invention, sodium chloride can be further added to soymilk containing a basic substance. The addition of sodium chloride delays and alleviates the coagulation of soymilk by the coagulant, resulting in a smoother texture with less roughness. The amount of sodium chloride added is not particularly limited, but is preferably 0.05 to 1.5 parts by mass with respect to 100 parts by mass of soymilk. If the amount of sodium chloride added exceeds 2 parts by mass with respect to 100 parts by mass of soymilk, a salty taste is felt, which is not preferable depending on the application.

本発明の前記豆腐様流動性食品において、食品に利用される改質剤であれば何れも使用可能である。澱粉(食用の澱粉及びその変性澱粉)、タンパク質(大豆タンパク質等)、酵素製剤(トランスグルタミナーゼ等)、増粘多糖類(キサンタンガム、ローカストビーンガム等)、糖類(単糖、2糖、オリゴ糖、デキストリン等)、油脂類、乳化油脂類、食物繊維(おからやふすま等の天然繊維質、結晶セルロース等の精製繊維質、難消化性澱粉等の加工繊維質)乳化剤、香料など、本発明の品質を損なわない程度で添加することができる。 In the tofu-like fluid food of the present invention, any modifier used in food can be used. Starch (edible starch and its modified starch), protein (soybean protein, etc.), enzyme preparation (transglutaminase, etc.), thickening polysaccharide (xanthan gum, locust bean gum, etc.), sugar (monosaccharide, disaccharide, oligosaccharide, etc.) Dextrin, etc.), fats and oils, emulsified fats and oils, dietary fiber (natural fibers such as okara and bran, purified fibers such as crystalline cellulose, processed fibers such as resistant starch) emulsifiers, fragrances, etc. It can be added to the extent that quality is not impaired.

本発明の豆腐様流動性食品の粘度は、使用の目的によって適宜調整することができる。なお、流動化工程の条件を一定にした場合の豆腐様流動食品の粘度は豆乳中の大豆タンパク質の凝固の程度の目安となる。市販されているジューサーミキサーを使用し、15秒攪拌することにより流動化工程を行った場合、品温を15℃に保ち、C型粘度計で計測した場合の粘度は好ましくは300cp以上4000cp以下、さらに好ましくは、1000〜3000cpである。300cp未満では、豆乳中の大豆タンパク質の凝固の程度が低く、凝固していない豆乳に近い物性となるためこのような粘度の豆腐様流動性食品を使用してベシャメルソース等のソースを製造すると、加熱撹拌時にソースの粘度上昇が起き難く、このようにして得たソースを冷凍解凍すると離水が生じてボソつき及びザラつきが生じやすくなる傾向にある。4000cpを超える場合は、市販の充填豆腐や絹ごし豆腐のペーストに対して豆乳中の大豆タンパク質の凝固緩和の程度が低くなるため、このような粘度の豆腐様流動性食品を使用してベシャメルソース等のソースを製造すると、加熱撹拌時に粘度が高くなり、水分の加熱蒸発によって大豆タンパク質凝固物のボソつき及びザラつきが生じやすくなり、このようにして得たソースを冷凍解凍すると離水が生じてボソつき及びザラつきが生じやすくなる傾向にある。 The viscosity of the tofu-like fluid food of the present invention can be appropriately adjusted depending on the purpose of use. The viscosity of the tofu-like liquid food when the conditions of the fluidization process are constant is a measure of the degree of coagulation of soybean protein in soymilk. When the fluidization step is performed by stirring for 15 seconds using a commercially available juicer mixer, the product temperature is maintained at 15 ° C., and the viscosity measured with a C-type viscometer is preferably 300 cp or more and 4000 cp or less. More preferably, it is 1000 to 3000 cp. If it is less than 300 cp, the degree of coagulation of soy protein in soymilk is low, and the physical properties are close to those of non-coagulated soymilk. Therefore, when a sauce such as bechamel sauce is produced using a tofu-like fluid food having such a viscosity, The viscosity of the sauce is unlikely to increase during heating and stirring, and when the sauce thus obtained is frozen and thawed, water separation tends to occur, and the sauce tends to be rough and rough. If it exceeds 4000 cp, the degree of coagulation relaxation of soy protein in soymilk is lower than that of commercially available filled tofu or silken tofu paste. When the sauce is produced, the viscosity becomes high during heating and stirring, and the soy protein coagulated product tends to become rough and rough due to the heating and evaporation of water. Roughness and roughness tend to occur.

本発明の前記豆腐様流動性食品の製造方法は、塩基性物質を含む豆乳を調製する工程、多価酸のアルカリ金属塩および多価酸のアンモニウム塩からなる群より選ばれる少なくとも1種類の塩基性物質を含む豆乳を酸凝固剤及び/又は塩凝固剤で凝固させる工程、及び凝固物を流動化する工程を含む。 The method for producing a tofu-like fluid food of the present invention is a step of preparing soymilk containing a basic substance, at least one base selected from the group consisting of an alkali metal salt of a polyhydric acid and an ammonium salt of a polyhydric acid. It includes a step of coagulating soymilk containing a sex substance with an acid coagulant and / or a salt coagulant, and a step of fluidizing the coagulated product.

塩基性物質を含む豆乳を調製する工程は、例えば、豆乳に塩基性物質を添加混合することにより調製することができる。塩基性物質は、豆乳100質量部に対して0.01〜0.07質量部添加することができる。好ましくは0.03〜0.06質量部、さらに好ましくは0.03〜0.05質量部添加することができる。0.01質量部未満では、凝固剤による豆乳の大豆蛋白の凝固力が強く、ザラついた食感になる。0.07質量部を超えると、凝固剤による豆乳の大豆蛋白の凝固力が弱くなり、粘度が得られない。また、加熱中にガスが発生して豆乳に泡立ちが生じるため、作業性が悪くなる。 The step of preparing soymilk containing a basic substance can be prepared, for example, by adding and mixing the basic substance to soymilk. The basic substance can be added in an amount of 0.01 to 0.07 parts by mass with respect to 100 parts by mass of soymilk. It is possible to add 0.03 to 0.06 parts by mass, more preferably 0.03 to 0.05 parts by mass. If it is less than 0.01 parts by mass, the coagulation power of soybean protein in soymilk by the coagulant is strong, and the texture becomes rough. If it exceeds 0.07 parts by mass, the coagulation power of soybean protein in soymilk by the coagulant becomes weak and the viscosity cannot be obtained. In addition, gas is generated during heating and soymilk foams, resulting in poor workability.

塩基性物質を含む豆乳を酸凝固剤及び/又は塩凝固剤で凝固させる工程は、通常豆腐製造時に豆乳を酸凝固剤及び/又は塩凝固剤で凝固させる方法、すなわち豆乳に酸凝固剤及び/又は塩凝固剤を添加混合し、加熱凝固させることができる。例えば20℃以下の塩基性物質を含む豆乳に、酸凝固剤及び/又は塩凝固剤を添加混合し、分散機を用いて回転速度300rpmで1〜30秒、好ましくは10〜20秒凝固剤を分散したものを充填容器などの容器に入れ、80から100℃の温度下で10から15分間静置することにより凝固させることができる。凝固剤の添加量は、使用する凝固剤の種別によって適宜変更することができるが、豆乳100質量部に対して0.08質量部以上添加することができる。好ましくは0.08〜0.5質量部である。凝固剤の添加量が0.08質量部未満では、大豆タンパク質の凝固が起こり難く、粘度不足となり不適である。凝固剤の添加量が0.5質量部を超えると、添加量に依存して凝固剤の異味(エグミ、苦味、酸味)が感じられる傾向にある。 The step of coagulating soymilk containing a basic substance with an acid coagulant and / or a salt coagulant is usually a method of coagulating soymilk with an acid coagulant and / or a salt coagulant during the production of tofu, that is, the soymilk is coagulated with an acid coagulant and /. Alternatively, a salt coagulant can be added and mixed, and heat coagulated. For example, an acid coagulant and / or a salt coagulant is added and mixed with soymilk containing a basic substance at 20 ° C. or lower, and a coagulant is added at a rotation speed of 300 rpm for 1 to 30 seconds, preferably 10 to 20 seconds using a disperser. The dispersed substance can be solidified by placing it in a container such as a filling container and allowing it to stand at a temperature of 80 to 100 ° C. for 10 to 15 minutes. The amount of the coagulant added can be appropriately changed depending on the type of coagulant used, but 0.08 part by mass or more can be added with respect to 100 parts by mass of soymilk. It is preferably 0.08 to 0.5 parts by mass. If the amount of the coagulant added is less than 0.08 parts by mass, soybean protein is unlikely to coagulate, resulting in insufficient viscosity, which is unsuitable. When the amount of the coagulant added exceeds 0.5 parts by mass, the coagulant tends to have an unpleasant taste (acriding, bitterness, acidity) depending on the amount added.

凝固物を流動化する工程は、例えば凝固物をミキサーなどで物理的に撹拌することにより行うことができる。例えば市販されているジューサーミキサーを使用して5〜20秒間程度撹拌することにより行うことができる。 The step of fluidizing the coagulated product can be performed, for example, by physically stirring the coagulated product with a mixer or the like. For example, it can be carried out by stirring for about 5 to 20 seconds using a commercially available juicer mixer.

本発明において、塩基性物質を含む豆乳を調製する工程において、さらに塩化ナトリウムを添加することができる。塩化ナトリウムの添加により豆乳の凝固剤による凝固が遅延緩和され、よりザラつきのない滑らかな食感になる。塩化ナトリウムの添加量は特に限定されないが、好ましくは豆乳100質量部に対して0.05〜1.5質量部添加する。塩化ナトリウムの添加量が2質量%を超えると塩味が感じられるので、用途によっては好ましくない。 In the present invention, sodium chloride can be further added in the step of preparing soymilk containing a basic substance. The addition of sodium chloride delays and alleviates the coagulation of soymilk by the coagulant, resulting in a smoother texture with less roughness. The amount of sodium chloride added is not particularly limited, but is preferably 0.05 to 1.5 parts by mass with respect to 100 parts by mass of soymilk. If the amount of sodium chloride added exceeds 2% by mass, a salty taste is felt, which is not preferable depending on the application.

以下本発明を具体的に説明する為に実施例を示すが、本発明は以下の実施例のみに限定されるものではない。 Hereinafter, examples will be shown for the purpose of specifically explaining the present invention, but the present invention is not limited to the following examples.

[製造例1(豆乳の製造)]
(1)洗浄した100質量部の大豆を水に浸漬し、吸水して膨潤した浸漬大豆230質量部を得た。
(2)浸漬大豆100質量部に水200重量を加え、湿式粉砕、次いで均質化して生呉を得た。
(3)生呉を98℃で10分間加熱した後、圧搾ろ過によりオカラを除去して豆乳を得た。
なお得られた豆乳は、使用するまで冷蔵保管した。
[Production Example 1 (Production of soymilk)]
(1) 100 parts by mass of washed soybeans were immersed in water to obtain 230 parts by mass of soybeans swollen by absorbing water.
(2) 200% by weight of water was added to 100 parts by mass of soybeans, wet pulverized, and then homogenized to obtain raw soybeans.
(3) Raw bean curd refuse was heated at 98 ° C. for 10 minutes, and then okara was removed by squeezing filtration to obtain soymilk.
The obtained soymilk was refrigerated until it was used.

[製造例2 豆腐様食品]
表1の配合に従って、豆腐及びクリーム状豆腐を製造した。
(1)Brix11に調製した豆乳100質量部に重曹0.05質量部を混合し、分散機(スリーワンモータ TYPE HEIDOn 3000H)を用いて回転速度300rpmで攪拌均質化した。
(2)塩凝固剤である塩化マグネシウム0.1質量部及び酸凝固剤である乳酸0.1質量部を重曹含有豆乳に添加し、更に20秒攪拌均質化した。なお、工程(1)と(2)は、豆乳の凝固が進行しないように品温15℃で行った。
(3)200ml容量の充填容器に投入し、92℃で15分間静置して凝固させた。
(4)得られた豆乳凝固物を家庭用ジューサーミキサーに投入し、15秒間攪拌混合して豆腐様流動性食品を得た。
(5)評価例1及び2に従ってクリーム状豆腐を評価した。
[Manufacturing example 2 Tofu-like food]
Tofu and creamy tofu were produced according to the formulation shown in Table 1.
(1) 0.05 parts by mass of baking soda was mixed with 100 parts by mass of soymilk prepared in Brix 11, and the mixture was stirred and homogenized at a rotation speed of 300 rpm using a disperser (Three-One Motor TYPE HEIDOn 3000H).
(2) 0.1 part by mass of magnesium chloride as a salt coagulant and 0.1 part by mass of lactic acid as an acid coagulant were added to soymilk containing baking soda, and the mixture was further homogenized by stirring for 20 seconds. The steps (1) and (2) were carried out at a product temperature of 15 ° C. so that the soymilk did not coagulate.
(3) It was put into a filling container having a capacity of 200 ml and allowed to stand at 92 ° C. for 15 minutes to solidify.
(4) The obtained coagulated soymilk was put into a household juicer mixer and stirred and mixed for 15 seconds to obtain a tofu-like fluid food.
(5) Creamy tofu was evaluated according to Evaluation Examples 1 and 2.

Figure 0006892255
Figure 0006892255

[評価例1 粘度測定]
豆腐様流動性食品の粘度は、品温を15℃に保ち、ローターNo.3を装着したC型粘度計(TOKI SANGYO社製のVISCOMETER、MODEL TVC−7)を用いて回転速度20rpmで測定した。
なお、製造例2で使用した豆乳の粘度は、ローターNo.2を装着したC型粘度計で同様に測定したところ、44cpであった。豆乳のBrixにもよるが、豆乳の粘度は概ね20〜50cp程度である。
[Evaluation Example 1 Viscosity measurement]
The viscosity of the tofu-like fluid food was such that the product temperature was kept at 15 ° C and the rotor No. It was measured at a rotation speed of 20 rpm using a C-type viscometer (VISCOMETER, MODEL TVC-7 manufactured by TOKI SANGYO) equipped with No. 3.
The viscosity of the soymilk used in Production Example 2 is based on the rotor No. When it was measured in the same manner with a C-type viscometer equipped with 2, it was 44 cp. Although it depends on the Brix of soymilk, the viscosity of soymilk is about 20 to 50 cp.

[評価例2 官能評価]
豆腐の食感につき、官能評価を実施10名の熟練パネラーにより下記表2の評価基準に基づいて評価を行った。なお、市販の充填豆腐(ジョイアス・フーズ社製の「やわらかきぬ」)を製造例2の工程(4)に従ってペースト状にしたものを3点とした。
<評価基準>
[Evaluation example 2 Sensory evaluation]
The texture of tofu was evaluated by sensory evaluation based on the evaluation criteria in Table 2 below by 10 skilled panelists. A paste of commercially available filled tofu (“soft” manufactured by Joyus Foods Co., Ltd.) according to step (4) of Production Example 2 was given as 3 points.
<Evaluation criteria>

Figure 0006892255
Figure 0006892255

[試験1 重曹(炭酸水素ナトリウム)の検討]
豆乳に、塩基性物質として表3記載の重曹を混合して均質化した以外は製造例2に従って豆腐様流動性食品を製造した。凝固剤としては、豆乳100質量部に対し塩凝固剤として塩化マグネシウム0.1質量部、酸凝固剤として乳酸0.1質量部を使用した。
[Test 1 Examination of baking soda (sodium hydrogen carbonate)]
A tofu-like fluid food was produced according to Production Example 2 except that soymilk was homogenized by mixing baking soda shown in Table 3 as a basic substance. As the coagulant, 0.1 part by mass of magnesium chloride was used as the salt coagulant and 0.1 part by mass of lactic acid was used as the acid coagulant with respect to 100 parts by mass of soymilk.

Figure 0006892255
Figure 0006892255

比較例2の重曹不含豆乳に凝固剤を添加して加熱凝固させると、十分に凝固し、絹ごし豆腐に近い豆腐が得られた。ミキサーで撹拌混合して得られた豆腐ペーストは、粘度が高く、ザラつきがあり、滑らかさに劣るものであった。比較例1では、重曹の添加量が多すぎ、豆乳の凝固がほとんど起こらず豆乳と大差ない状態であり、加熱時に発泡が生じて作業性が悪化したため、官能評価を実施しなかった。
実施例1〜5では、重曹含有豆乳に凝固剤を添加して加熱凝固させると、凝固が緩和された豆腐様食品が得られ、比較例2の豆腐よりも柔らかく滑らかなものであった。ミキサーで撹拌混合して得られた豆腐様流動性食品は、重曹の添加量の増加に依存して粘度が低下し、それらの食感はザラつきがなく滑らかな良好なものであった。重曹の添加量によって粘度を調節できる本発明の豆腐様流動性食品は、各種の料理に使用される牛乳等の流動性食品あるいはクリーム等の半固形食品の代用食品に利用することができる。
When a coagulant was added to the baking soda-free soymilk of Comparative Example 2 and coagulated by heating, the tofu was sufficiently coagulated and a tofu similar to silken tofu was obtained. The tofu paste obtained by stirring and mixing with a mixer had high viscosity, was rough, and was inferior in smoothness. In Comparative Example 1, the amount of baking soda added was too large, soymilk was hardly coagulated and was not much different from soymilk, and foaming occurred during heating to deteriorate workability. Therefore, sensory evaluation was not performed.
In Examples 1 to 5, when a coagulant was added to the baking soda-containing soymilk and heat-coagulated, a tofu-like food in which coagulation was relaxed was obtained, which was softer and smoother than the tofu of Comparative Example 2. The tofu-like fluid food obtained by stirring and mixing with a mixer had a decrease in viscosity depending on the increase in the amount of baking soda added, and their texture was smooth and good without any roughness. The tofu-like fluid food of the present invention whose viscosity can be adjusted by the amount of baking soda added can be used as a substitute food for fluid foods such as milk used in various dishes or semi-solid foods such as cream.

[試験2 塩化ナトリウム添加の検討]
製造例2の工程(1)において、豆乳に重曹と共に表4記載の塩化ナトリウムを混合して均質化した以外は製造例2に従って豆腐様流動性食品を製造した。凝固剤としては、豆乳100質量部に対し塩凝固剤として塩化マグネシウム0.1質量部、酸凝固剤として乳酸0.1質量部、塩基性物質としては重曹0.05質量部を使用した。
[Test 2 Examination of addition of sodium chloride]
In the step (1) of Production Example 2, a tofu-like fluid food was produced according to Production Example 2 except that soymilk was homogenized by mixing sodium chloride shown in Table 4 together with baking soda. As the coagulant, 0.1 part by mass of magnesium chloride as a salt coagulant, 0.1 part by mass of lactic acid as an acid coagulant, and 0.05 part by mass of sodium bicarbonate were used as a basic substance with respect to 100 parts by mass of soy milk.

Figure 0006892255
Figure 0006892255

豆乳100質量部に対して塩化ナトリウム0.5質量部以下の場合、塩化ナトリウムの添加量の増加に伴って豆腐様流動性食品の粘度は上昇し、それ以上添加すると粘度は低下した。これらを官能評価したところ、何れも実施例3と同等もしくはやや良好なものであった。
本発明では、塩化ナトリウムは食感をやや向上させるのみならず、実施例3の様に粘度がもともと低い場合には粘度を増加させる粘度調節機能を有していることがわかった。
When the amount of sodium chloride was 0.5 parts by mass or less with respect to 100 parts by mass of soymilk, the viscosity of the tofu-like fluid food increased as the amount of sodium chloride added increased, and the viscosity decreased when more sodium chloride was added. When these were sensory-evaluated, they were all equivalent to or slightly better than those of Example 3.
In the present invention, it was found that sodium chloride not only slightly improves the texture, but also has a viscosity adjusting function of increasing the viscosity when the viscosity is originally low as in Example 3.

[製造例3 豆腐様食品]
(1)Brix11に調製した豆乳100質量部に、重曹0.01質量部及び食塩0.5質量部を混合し、分散機を用いて回転速度300rpmで攪拌均質化した。
(2)表5記載の凝固剤を液中に分散し20秒攪拌均質化した。なお、工程(1)と(2)は、豆乳の凝固が進行しないように品温15℃で行った。
(3)200ml容量の充填容器に流し込み、92℃の温度下で15分間静置して凝固させた。
(4)得られた豆乳凝固物を家庭用ジューサーミキサーに投入し、15秒攪拌混合して豆腐様流動性食品を得た。
(5)評価例1及び2に従って豆腐様流動性食品を評価した。
[Manufacturing example 3 Tofu-like food]
(1) 0.01 part by mass of baking soda and 0.5 part by mass of salt were mixed with 100 parts by mass of soymilk prepared in Brix 11, and homogenized by stirring at a rotation speed of 300 rpm using a disperser.
(2) The coagulant shown in Table 5 was dispersed in the liquid and homogenized by stirring for 20 seconds. The steps (1) and (2) were carried out at a product temperature of 15 ° C. so that the soymilk did not coagulate.
(3) It was poured into a filling container having a capacity of 200 ml and allowed to stand at a temperature of 92 ° C. for 15 minutes to solidify.
(4) The obtained coagulated soymilk was put into a household juicer mixer and stirred and mixed for 15 seconds to obtain a tofu-like fluid food.
(5) The tofu-like fluid food was evaluated according to Evaluation Examples 1 and 2.

[試験3 凝固剤の検討]
凝固剤を表4記載の凝固剤を使用して製造例3に従って豆腐様流動性食品を製造した。本試験では、豆腐様流動性食品の粘度を高めるために重曹の添加量を0.01質量部、食塩の添加量を0.5質量部にした。
[Test 3 Examination of coagulant]
A tofu-like fluid food was produced according to Production Example 3 using the coagulant shown in Table 4. In this test, the amount of baking soda added was 0.01 parts by mass and the amount of salt added was 0.5 parts by mass in order to increase the viscosity of the tofu-like fluid food.

Figure 0006892255
Figure 0006892255

塩化マグネシウムと乳酸の当重量混合物、塩化マグネシウム及びグルコノデルタラクトンでは、その添加量の増加に伴って豆腐様流動性食品の粘度は高くなった。塩化マグネシウムの様に強い豆乳の凝固作用を示す凝固剤を使用することで、高粘度でありながら食感良好な豆腐様流動性食品が得られた。なお、凝固剤を0.5質量部超添加しても豆乳の凝固に差は見られなかったので、本試験では0.5質量部超を添加した試験は実施しなかった。 In the equivalent weight mixture of magnesium chloride and lactic acid, magnesium chloride and glucono delta lactone, the viscosity of the tofu-like fluid food increased with the increase in the amount added. By using a coagulant that has a strong coagulation effect on soymilk such as magnesium chloride, a tofu-like fluid food having a high viscosity and a good texture was obtained. Since there was no difference in the coagulation of soymilk even when more than 0.5 parts by mass of the coagulant was added, the test in which more than 0.5 parts by mass was added was not carried out in this test.

乳酸等の有機酸は、塩化マグネシウム等の2価カチオン塩及びデルタグルコノラクトンよりも豆乳の凝固力が弱いことは良く知られている。乳酸では0.3質量部以上加えることで粘度が低下したが、それらの食感は十分に許容されるものであった。
なお、実施例16は、実施例5に食塩を0.5質量添加したものである。実施例5の様に粘度が高い場合には、食塩はザラつきをなくしつつ、粘度を下げる方向への調節に使用できると考えられる。
各比較例では、凝固剤の添加量が低いために豆乳の凝固がほとんど起こらず、豆乳と大差ない状態であったので、官能評価を実施しなかった。
It is well known that organic acids such as lactic acid have a weaker coagulation power of soymilk than divalent cation salts such as magnesium chloride and delta gluconolactone. The viscosity of lactic acid decreased by adding 0.3 parts by mass or more, but their textures were sufficiently acceptable.
In Example 16, 0.5% by mass of salt was added to Example 5. When the viscosity is high as in Example 5, it is considered that the salt can be used for adjusting the viscosity in the direction of lowering the viscosity while eliminating the roughness.
In each comparative example, since the amount of the coagulant added was low, soymilk was hardly coagulated and was in a state not much different from that of soymilk, so sensory evaluation was not performed.

[試験4 塩基性物質の種類の検討]
重曹(炭酸水素ナトリウム)に代えて、炭酸水素アンモニウム、リン酸水素2カリウム、リン酸水素2ナトリウムを0.05質量部添加した以外は製造例2に従って豆腐様流動性食品を得た。結果を表6に示す。
[Test 4 Examination of types of basic substances]
A tofu-like fluid food was obtained according to Production Example 2 except that 0.05 parts by mass of ammonium hydrogen carbonate, dipotassium hydrogen phosphate, and disodium hydrogen phosphate were added instead of baking soda (sodium hydrogen carbonate). The results are shown in Table 6.

Figure 0006892255
Figure 0006892255

何れの塩基性物質を使用しても、粘度が適正に低く、ザラつきのない滑らかな食感であった。 Regardless of which basic substance was used, the viscosity was appropriately low, and the texture was smooth without roughness.

[試験5 豆腐様流動性食品の離水試験]
比較例1(120cp)、比較例2(豆腐)、実施例1(320cp)、実施例5(3000cp)、実施例8(2320cp)、実施例18(3360cp)、実施例28(300cp)について、離水試験を行った。
(1)静置保存試験
各100mlを100ml容メスシリンダーに充填し、冷蔵庫で5時間静置した。比較例1、3では、メスシリンダー上部に液体の層ができると共にガラス壁の各所で液体が浮き出ていた。それに対して実施例5、8、13、18、31では、水が浮き出すことはなく、均質な豆腐様流動性食品を維持していた。
[Test 5 Water separation test for tofu-like fluid food]
Regarding Comparative Example 1 (120 cp), Comparative Example 2 (tofu), Example 1 (320 cp), Example 5 (3000 cp), Example 8 (2320 cp), Example 18 (3360 cp), and Example 28 (300 cp). A water separation test was conducted.
(1) Standing storage test 100 ml of each was filled in a 100 ml measuring cylinder and allowed to stand in a refrigerator for 5 hours. In Comparative Examples 1 and 3, a layer of liquid was formed on the upper part of the graduated cylinder, and the liquid was raised in various places on the glass wall. On the other hand, in Examples 5, 8, 13, 18 and 31, water did not float and a homogeneous tofu-like fluid food was maintained.

(2)加熱加工及び冷凍解凍試験
小麦粉8質量部とバター8質量部とを加熱混合してルーを調製し、ルーを加熱しながら各豆腐様流動性食品100質量部を徐々に添加混合してベシャメル様ソースを製造した。
得られた各ベシャメル様ソース100gを樹脂製容器に充填して密封し、−50℃で急速冷凍した後、家庭用冷凍冷蔵庫の冷凍室で2週間保存した。冷凍保存後、室温で解凍して冷凍解凍ベシャメル様ソースを得た。
豆腐様流動性食品の代わりに牛乳を添加混合した一般的なベシャメルソースの点数を5点として、ベシャメル様ソース(加熱加工)及び冷凍解凍ベシャメル様ソース(冷凍解凍)を下記表6の評価基準に基づいて熟練のパネラー10名により評価し、結果を表7に示した。
(2) Heat processing and freezing and thawing test 8 parts by mass of wheat flour and 8 parts by mass of butter are heated and mixed to prepare a roux, and 100 parts by mass of each tofu-like fluid food is gradually added and mixed while heating the roux. Manufactured Bechamel-like sauce.
100 g of each of the obtained bechamel-like sauces was filled in a resin container, sealed, rapidly frozen at −50 ° C., and then stored in the freezer compartment of a household refrigerator / freezer for 2 weeks. After cryopreservation, it was thawed at room temperature to obtain a frozen thawed bechamel-like sauce.
A general bechamel sauce in which milk is added and mixed instead of tofu-like fluid food is set to 5 points, and bechamel-like sauce (heat processing) and frozen-thawed bechamel-like sauce (freeze-thawed) are used as the evaluation criteria in Table 6 below. Based on this, 10 skilled panelists evaluated the results, and the results are shown in Table 7.

Figure 0006892255
Figure 0006892255

Figure 0006892255
Figure 0006892255

実施例1、5、8、18及び28の豆腐様流動性食品を使用したベシャメル様ソースでは、加熱加工に伴う水分蒸発があってもボソつきが生じ難く、滑らかな食感であった。更に、冷凍解凍しても離水による食感劣化が起こり難く、牛乳及びクリーム等の牛乳加工品の代用として十分に使用可能であった。比較例1では、ボソつきが生じ難いものの加熱加工により粘度上昇が少なく、ソースとして不適であった。更に、冷凍解凍すると大豆タンパク質の冷凍変性及び大豆タンパク質凝固物の離水により食感が著しく劣化した。比較例2では、加熱加工及び冷凍解凍の双方で食感劣化が著しく、「す」が入った状態に近いボソついた食感になった。 The bechamel-like sauce using the tofu-like fluid foods of Examples 1, 5, 8, 18 and 28 had a smooth texture with less lumpiness even if water was evaporated due to heat processing. Further, even if frozen and thawed, the texture is less likely to deteriorate due to water separation, and it can be sufficiently used as a substitute for processed milk products such as milk and cream. In Comparative Example 1, although it was difficult to cause lumpiness, the viscosity did not increase much due to heat processing, and it was not suitable as a sauce. Furthermore, when frozen and thawed, the texture was significantly deteriorated due to freeze denaturation of soybean protein and water separation of soybean protein coagulated product. In Comparative Example 2, the texture was significantly deteriorated in both the heat processing and the freezing and thawing, and the texture became rough, which was close to the state in which "su" was contained.

(3)加熱調理試験
小麦粉8質量部、サラダ油8質量部、食塩0.5質量部を加熱混合してルーを調製し、ルーを加熱しながら各豆腐様流動性食品100質量部を徐々に添加混合し、更に1分30秒間加熱混合してベシャメル様ソースを得た。茹でマカロニ100gが入ったココット型にベシャメル様ソース50gを満遍なく広げ、その上に粉チーズ3gを均等に振りかけ、1000wのトースターで15分加熱しマカロニグラタン様食品を得た。−50℃で急速冷凍して家庭用冷凍冷蔵庫の冷凍室で2週間保存した。これを電子レンジ500w1分半の条件で再加熱した。
豆腐様流動性食品の代わりに牛乳を使用して得た一般的なマカロニグラタンの点数を5点として、マカロニグラタン様食品(加熱加工)及び冷凍解凍マカロニグラタン様食品(冷凍解凍)を上記評価基準に基づいて熟練のパネラー10名により評価し、結果を表5に示した。
(3) Cooking test 8 parts by mass of wheat flour, 8 parts by mass of salad oil, and 0.5 parts by mass of salt are mixed by heating to prepare a roux, and 100 parts by mass of each tofu-like fluid food is gradually added while heating the roux. The mixture was further mixed by heating for 1 minute and 30 seconds to obtain a bechamel-like sauce. 50 g of bechamel-like sauce was spread evenly on a cocotte mold containing 100 g of boiled macaroni, 3 g of grated cheese was evenly sprinkled on it, and heated with a 1000 w toaster for 15 minutes to obtain a macaroni gratin-like food. It was deep-frozen at -50 ° C and stored in the freezer compartment of a household refrigerator-freezer for 2 weeks. This was reheated under the condition of microwave oven 500w for one and a half minutes.
The above evaluation criteria are macaroni gratin-like food (heat processing) and frozen-thawed macaroni gratin-like food (frozen and thawed), with the score of general macaroni gratin obtained by using milk instead of tofu-like fluid food as 5 points. Based on the above, 10 skilled panelists evaluated the results, and the results are shown in Table 5.

Figure 0006892255
Figure 0006892255

比較例1、2では、ベシャメル様ソースと同様に評価が悪かった。実施例1、5、8、18、28では離水がなく、官能評価によりボソつきがなく滑らかな食感が維持されていることが認められた。
なお、市販充填豆腐(ジョイアス・フーズ社製の「やわらかきぬ」)のペースト(官能評価基準の3点に設定した対象例)を使用して(1)〜(3)の試験を実施したところ、比較例2と同様の結果であった。
In Comparative Examples 1 and 2, the evaluation was bad as in the Bechamel-like sauce. In Examples 1, 5, 8, 18 and 28, it was confirmed that there was no water separation, and the sensory evaluation showed that there was no lumpiness and a smooth texture was maintained.
The tests (1) to (3) were carried out using a paste of commercially available filled tofu (“Soft Kinu” manufactured by Joyus Foods Co., Ltd.) (target example set to 3 points of sensory evaluation criteria). The result was the same as that of Comparative Example 2.

Claims (2)

原料豆乳に多価酸のアルカリ金属塩および多価酸のアンモニウム塩からなる群より選ばれる少なくとも1種類の塩基性物質と塩化ナトリウムと添加し、前記塩基性物質と塩化ナトリウムとを含む豆乳を調製する工程、
前記塩基性物質と塩化ナトリウムとを含む豆乳を酸凝固剤及び/又は塩凝固剤で凝固させる工程、及び
凝固物を流動化する工程
を含む豆腐様流動性食品の製造方法であって、
原料豆乳100質量部に対し前記塩基性物質の量が0.01〜0.07質量部であり、塩化ナトリウムの量が0.05〜1.5質量部であり、酸凝固剤及び/又は塩凝固剤の量が0.08質量部以上である前記方法。
At least one basic substance selected from the group consisting of an alkali metal salt of a polyhydric acid and an ammonium salt of a polyhydric acid and sodium chloride are added to the raw material soymilk to prepare soymilk containing the basic substance and sodium chloride. Step to prepare,
A method for producing a tofu-like fluid food, which comprises a step of coagulating soymilk containing the basic substance and sodium chloride with an acid coagulant and / or a salt coagulant, and a step of fluidizing the coagulated product.
The amount of the basic substance is 0.01 to 0.07 parts by mass, the amount of sodium chloride is 0.05 to 1.5 parts by mass, and the acid coagulant and / or salt is 100 parts by mass with respect to 100 parts by mass of the raw material soymilk. The method according to the method, wherein the amount of the coagulant is 0.08 parts by mass or more.
前記塩基性物質が、重曹、炭酸水素アンモニウム、リン酸水素2カリウム、リン酸水素2ナトリウムからなる群から選択される、請求項に記載の方法。 The method according to claim 1 , wherein the basic substance is selected from the group consisting of baking soda, ammonium hydrogen carbonate, dipotassium hydrogen phosphate, and disodium hydrogen phosphate.
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