JP6854499B1 - Method for producing valuable resources derived from mushroom waste medium - Google Patents

Method for producing valuable resources derived from mushroom waste medium Download PDF

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JP6854499B1
JP6854499B1 JP2020175284A JP2020175284A JP6854499B1 JP 6854499 B1 JP6854499 B1 JP 6854499B1 JP 2020175284 A JP2020175284 A JP 2020175284A JP 2020175284 A JP2020175284 A JP 2020175284A JP 6854499 B1 JP6854499 B1 JP 6854499B1
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斉司 古川
斉司 古川
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プロスペックAz株式会社
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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Abstract

【課題】きのこ廃培地からペレット等の有価物を製造する方法を提供する。【解決手段】きのこ廃培地を乾燥させる乾燥工程、前記乾燥工程後にペレット化するペレット成形工程からなるきのこ廃培地由来の有価物の製造方法であり、前記乾燥工程がきのこ廃培地を任意の方法で含水率25%超、55%以下の粉体にする第1の工程、前記粉体を高温攪拌により含水率17〜25%にする第2の工程からなる。【選択図】なしPROBLEM TO BE SOLVED: To provide a method for producing valuable resources such as pellets from a waste medium of mushrooms. SOLUTION: This method is a method for producing valuable resources derived from a mushroom waste medium, which comprises a drying step of drying the mushroom waste medium and a pellet forming step of pelletizing after the drying step, and the drying step is an arbitrary method for producing the mushroom waste medium. It comprises a first step of making a powder having a water content of more than 25% and 55% or less, and a second step of making the powder into a water content of 17 to 25% by high temperature stirring. [Selection diagram] None

Description

本発明は、きのこ廃培地を燃料、敷料等の有価物にするきのこ廃培地由来の有価物の製造方法に関するものである。 The present invention relates to a method for producing a valuable material derived from a mushroom waste medium, which turns the mushroom waste medium into a valuable resource such as fuel and litter.

近年、きのこ栽培において年間30万トン以上の廃菌床(廃培地)が国内排出されており、悪臭等の環境問題になっている。一方、こうした廃培地を再利用する等、有効活用する試みも広がりつつある。こうした試みとして燃料化や敷料化等が挙げられる。廃培地を乾燥させ、粉体にしたものをそのまま燃料等にするもの、粉体にしたものをさらにペレットにする等、成形してから燃料等にするものがある。 In recent years, more than 300,000 tons of waste bacteria beds (waste media) have been discharged domestically in mushroom cultivation, which has become an environmental problem such as foul odor. On the other hand, attempts to effectively utilize such waste media, such as reuse, are spreading. Examples of such attempts include fuel conversion and litter conversion. There are some that dry the waste medium and use it as a fuel as it is, and some that use the powder as a fuel after molding, such as further pelletizing it.

しかしながら、廃培地は非常に多くの水分を含んでおり、腐敗しやすい、粘性が高い等、再利用する上では多くの問題を有している。このような問題はペレット等の有価物の品質にも影響を与える。例えば、ペレットからカビが発生したり、ペレットの強度にバラつきが生じたりすることが挙げられる。 However, the waste medium contains a large amount of water, and has many problems in reuse, such as being perishable and highly viscous. Such problems also affect the quality of valuable resources such as pellets. For example, mold may be generated from the pellets, or the strength of the pellets may vary.

廃培地を燃料等として再利用するにあたっては、通常、現場(きのこ栽培場)で発生した廃培地を燃料化等するための設備を有する施設まで輸送し、石づきを分離し、乾燥や成形等の処理を行うことになる。これらの工程の設計や運用、管理等を改善等し、上記問題を解決することが求められる。 When reusing the waste medium as fuel, etc., it is usually transported to a facility that has equipment for converting the waste medium generated at the site (mushroom cultivation plant) into fuel, etc., and the stones are separated, dried, molded, etc. Processing will be performed. It is required to solve the above problems by improving the design, operation, management, etc. of these processes.

ここで、きのこ廃培地から燃料等を製造する発明としては、茸栽培に使用した茸栽培用培地の使用済培地を乾燥し、当該乾燥した使用済培地をペレット状、粒状、タブレット状およびフレーク状のいずれかの形状に成形してバイオマス燃料を製造するバイオマス燃料製造方法(特許文献1)がある。 Here, as an invention for producing fuel or the like from mushroom waste medium, the used medium of the mushroom cultivation medium used for mushroom cultivation is dried, and the dried used medium is pelletized, granular, tablet-shaped and flake-shaped. There is a biomass fuel production method (Patent Document 1) in which a biomass fuel is produced by molding into any of the above shapes.

また、燃料製造装置の発明としては、茸栽培に使用した後の廃培地を乾燥させて固形燃料を製造するバイオマス燃料製造装置において、原料を搬送しながら乾燥させて圧縮するスクリューコンベアと、前記スクリューコンベアの始端部に設けられ、ホッパーから投入される原料を前記スクリューコンベア内に定量供給する定量供給機と、前記スクリューコンベアの終端部に設けられ、前記スクリューコンベア内で乾燥、圧縮されて固形化した原料の切断、整粒を行う成形部とを備え、前記スクリューコンベアは、内筒と外筒とを有する二重構造のトラフと、該トラフ内で回転して搬送する2本のスクリューと、前記スクリューの回転軸内及び前記トラフの内筒と外筒との間に熱媒体を導入する手段と、前記内筒内を減圧排気する手段とを備えるとともに、前記スクリューは、スクリューコンベア入口側及び出口側のピッチよりも中間部のピッチを広く形成し、入口側に原料を圧縮して水分を搾り出す水分搾出部を、中間部に原料をほぐして水分を蒸発させる水分蒸発部を、出口側に原料を圧縮して固形化させる原料固形化部をそれぞれ設けたことを特徴とするバイオマス燃料製造装置(特許文献2)がある。 Further, as an invention of the fuel production apparatus, in a biomass fuel production apparatus for producing solid fuel by drying waste medium used for mushroom cultivation, a screw conveyor that dries and compresses while transporting raw materials, and the screw. A fixed-quantity feeder provided at the start end of the conveyor and quantitatively supplying the raw material input from the hopper into the screw conveyor, and a fixed-quantity feeder provided at the end of the screw conveyor, which is dried, compressed and solidified in the screw conveyor. The screw conveyor is provided with a molding unit for cutting and sizing the raw material, and the screw conveyor has a double-structured trough having an inner cylinder and an outer cylinder, two screws that rotate and convey in the trough, and a screw conveyor. A means for introducing a heat medium into the rotating shaft of the screw and between the inner cylinder and the outer cylinder of the trough and a means for decompressing and exhausting the inside of the inner cylinder are provided, and the screw is provided on the screw conveyor inlet side and on the screw conveyor inlet side. The pitch of the middle part is formed wider than the pitch of the outlet side, and the water squeezing part that compresses the raw material and squeezes the water is formed on the inlet side, and the water evaporating part that loosens the raw material and evaporates the water is provided at the outlet. There is a biomass fuel production apparatus (Patent Document 2) characterized in that a raw material solidification section for compressing and solidifying the raw material is provided on each side.

また、きのこ廃培地を乾燥処理する発明としては、菌床栽培キノコの収穫が終わった後にキノコの栽培瓶から掻き出されることによって菌糸が切断されて生長力が失われた直後の雑菌の侵入が少ない段階での含水有機物であるキノコ廃菌床に、好気性菌の種菌を投入して植え付ける工程と、前記キノコ廃菌床を好気性菌の作用によって乾燥させる工程とを有する含水有機物の乾燥方法であって、前記好気性菌の種菌を投入して植え付ける工程では、前記キノコ廃菌床の掻き出し装置から順次排出されてコンベアに乗って順次貯留場所へ移送される間に前記好気性の種菌を投入することを特徴とする含水有機物の乾燥方法(特許文献3)がある。 In addition, as an invention of drying the mushroom waste medium, invasion of various germs immediately after the mycelium is cut and the growth ability is lost by being scraped from the mushroom cultivation bottle after the harvest of the mushrooms grown in the fungus bed is completed. A method for drying a hydrous organic substance, which comprises a step of injecting an aerobic inoculum into a mushroom waste bed, which is a hydrous organic substance at a small stage, and planting the mushroom waste bed by the action of an aerobic bacterium. In the step of injecting and planting the aerobic inoculum, the aerobic inoculum is sequentially discharged from the mushroom waste bed scraping device and sequentially transferred to a storage place on a conveyor. There is a method for drying a hydrous organic substance (Patent Document 3), which is characterized by charging.

また、きのこ廃培地を乾燥処理する装置、方法等の発明としては、きのこ栽培後に発生した廃培地が投入される受入ホッパと、前記受入ホッパからの廃培地と後記戻りコンベアからの乾燥粉体とを含水率調整のために混合する混合機と、前記混合機からの混合廃培地を粉砕する流動乾燥粉砕機と、前記流動乾燥粉砕機内の乾燥粉体を吸引する吸引ブロワーと、 前記吸引ブロワーにより導かれた乾燥粉体を回収する乾粉回収機と、前記乾粉回収機で回収された乾燥粉体を2系統に配分する分配ダンパーと、配分された1系統の乾燥粉体について前記混合機に搬送する戻りコンベアとを備えるとともに、配分された他の1系統の乾燥粉体について振動により粗状と細状に篩い分けを行う振動篩機と、前記振動篩機による粗状乾燥粉体を搬送するスクリューコンベアと、前記振動篩機による細状乾燥粉体を比重選別して乾燥製品を得る比重選別機とを備える一方、前記スクリューコンベアからの粗状乾燥粉体を高温気体と焼却灰に分離するサイクロン焼却機と、を具備することを特徴とするきのこ廃培地乾燥装置(特許文献4)がある。 Further, as inventions of an apparatus, a method, etc. for drying the mushroom waste medium, a receiving hopper into which the waste medium generated after mushroom cultivation is charged, a waste medium from the receiving hopper, and a dry powder from the return conveyor described later are used. With a mixer for adjusting the water content, a fluidized dry crusher for crushing the mixed waste medium from the mixer, a suction blower for sucking the dry powder in the fluidized dry crusher, and the suction blower. A dry powder recovery machine that collects the derived dry powder, a distribution damper that distributes the dry powder collected by the dry powder recovery machine to two systems, and a distribution damper that distributes the distributed dry powder to the mixer. In addition to being provided with a return conveyor, a vibrating sieve that sifts the distributed dry powder into coarse and fine parts by vibration, and the crude dry powder by the vibrating sieve are conveyed. It is equipped with a screw conveyor and a specific gravity sorter for obtaining a dried product by specific gravity sorting of fine dry powder by the vibrating sieve, while separating coarse dry powder from the screw conveyor into high temperature gas and incineration ash. There is a mushroom waste medium drying device (Patent Document 4), which comprises a cyclone incinerator.

また、上記の他に、間伐材等の生木を用いて木質ペレットを製造する工程において用いられる、粉砕した生木を熱風により乾燥する乾燥方法であって、粉砕した生木を熱風乾燥機に供給し、該乾燥機内を一定速度で入口から出口に向けて一定速度で連続的に搬送しながら、該乾燥機内に熱風を供給して、粉砕した生木を乾燥するとともに、該乾燥機に供給される粉砕した生木の含水率A及び該乾燥機に供給される粉砕した生木の時間当たりの供給量Bを連続して計測し、該乾燥機に対して供給される時間当たりの水分供給量(A×B)が、乾燥後の粉砕した生木が予め設定した含水率となるように算出した一定の量となるように、該供給量B を制御することを特徴とする乾燥方法(特許文献5)がある。 In addition to the above, it is a drying method used in the process of producing wood pellets using raw wood such as thinned wood, in which crushed raw wood is dried with hot air, and the crushed raw wood is used in a hot air dryer. While supplying and continuously transporting the inside of the dryer from the inlet to the outlet at a constant speed, hot air is supplied into the dryer to dry the crushed raw wood and supply it to the dryer. The moisture content A of the crushed raw wood and the hourly supply amount B of the crushed raw wood supplied to the dryer are continuously measured, and the water supply per hour supplied to the dryer. A drying method characterized by controlling the supply amount B so that the amount (A × B) is a constant amount calculated so that the crushed raw wood after drying has a preset water content (A x B). There is Patent Document 5).

特許文献1にはペレット状、粒状、タブレット状およびフレーク状のいずれかの形状に成形する前の含水率を13%以下となるように廃培地を乾燥させることが示されている。具体的には、茸栽培施設から回収した含水率60〜70%の廃培地を貯留、脱水機による脱水および送風機による乾燥により含水率を12%程度まで乾燥(1次乾燥)、その後、ペレット成形装置を用いて直径が6mm程度で長さが10〜15mm程度のペレット状に成形、さらに二次乾燥装置の送風、冷却で含水率10%まで乾燥(2次乾燥)するというものである。 Patent Document 1 discloses that the waste medium is dried so that the water content before molding into any of pellet-like, granular, tablet-like and flake-like shapes is 13% or less. Specifically, waste medium with a moisture content of 60 to 70% collected from a mushroom cultivation facility is stored, and the moisture content is dried to about 12% by dehydration with a dehydrator and drying with a blower (primary drying), and then pellet molding. It is formed into pellets having a diameter of about 6 mm and a length of about 10 to 15 mm using an apparatus, and further dried (secondary drying) to a moisture content of 10% by blowing and cooling the secondary drying apparatus.

特許文献2には含水量が70〜80%のシメジ茸等の廃培地と、含水量が50〜60%のえのき茸やエリンギ茸の廃培地とを混合させて相対水量を65%程度とするとともに、消臭剤を混合して燃料製造用の原料を調整し、当該発明に係る装置に投入して所定の含水率になるまで乾燥、固形化することが示されている。 In Patent Document 2, a waste medium such as shimeji mushroom having a water content of 70 to 80% and a waste medium such as enoki mushroom or eringi mushroom having a water content of 50 to 60% are mixed to make the relative water content about 65%. At the same time, it has been shown that a deodorant is mixed to prepare a raw material for fuel production, and the raw material is charged into the apparatus according to the present invention to be dried and solidified until a predetermined water content is reached.

特許文献3にはキノコ廃菌床に、好気性菌の種菌を投入して植え付ける工程とキノコ廃菌床を好気性菌の作用によって乾燥させる工程とを有する含水有機物の乾燥方法が示されている。 Patent Document 3 discloses a method for drying a hydrous organic substance, which comprises a step of inoculating an aerobic inoculum into a mushroom waste bed and a step of drying the mushroom waste bed by the action of an aerobic bacterium. ..

特許文献4にはきのこ栽培後に発生する米ぬかが含まれた含水率60〜70%のきのこ廃培地と、きのこ廃培地を乾燥粉砕した乾燥粉体とを混合し含水率40〜50%に調整した後に乾燥粉砕する処理、比重選別処理等行い、含水率8〜15%の粗状乾燥粉体として焼却処理したり、比重が軽い乾燥粉体を再利用可能な乾燥廃培地にしたりすること等が示されている。 In Patent Document 4, a mushroom waste medium having a water content of 60 to 70% containing rice bran generated after mushroom cultivation and a dry powder obtained by drying and crushing the mushroom waste medium were mixed to adjust the water content to 40 to 50%. After that, it may be dried and crushed, sorted by specific gravity, etc., and incinerated as a coarse dry powder with a moisture content of 8 to 15%, or the dry powder with a light specific gravity may be made into a reusable dry waste medium. It is shown.

特許文献5には含水率が30〜60%の生木粉砕原料を、制御手段を備えた熱風乾燥機を用いて、木質ペレット表面をリグニンで適度にコーティングするために必要とされる含水率8〜13%以下の範囲、より好ましくは9〜12.5%以下の範囲となるように乾燥し、木質ペレットを製造することが示されている。 Patent Document 5 describes a moisture content 8 required for appropriately coating the surface of wood pellets with lignin using a hot air dryer equipped with a control means for a raw wood crushing raw material having a moisture content of 30 to 60%. It has been shown that wood pellets are produced by drying to a range of ~ 13% or less, more preferably 9 to 12.5% or less.

このように、きのこ廃培地から燃料等の有価物を得ることを目的として、製造方法や製造方法等に係るいくつかの発明が存在する。 As described above, there are some inventions relating to a production method, a production method, and the like for the purpose of obtaining valuable resources such as fuel from the waste medium of mushrooms.

しかしながら、特許文献1には廃培地の含水率とペレット化前後の含水率が示されているにとどまり、特許文献2には廃培地の含水率が示されているにとどまる。特許文献3には好気性菌の発酵乾燥により廃培地を所定水分量まで乾燥できることが示されているにとどまる。特許文献4には廃培地に戻りコンベアからの乾燥粉体を混合することで混合廃培地の含水率を40〜50%に調整することと、サイクロン焼却機に供給される粗状の乾燥粉体の含水率が8〜15%であることが示されているにとどまる。特許文献5には30〜60%という変動幅の大きい生木粉砕原料の含水率とペレット成形においてリグニンでコーティングするために必要な含水率が8〜13%であることが示されているにとどまる。 However, Patent Document 1 only shows the water content of the waste medium and the water content before and after pelletization, and Patent Document 2 only shows the water content of the waste medium. Patent Document 3 only shows that the waste medium can be dried to a predetermined water content by fermenting and drying aerobic bacteria. Patent Document 4 states that the water content of the mixed waste medium is adjusted to 40 to 50% by returning to the waste medium and mixing the dry powder from the conveyor, and the crude dry powder supplied to the cyclone incinerator. It is only shown that the water content of is 8 to 15%. Patent Document 5 only shows that the water content of a raw wood crushing raw material having a large fluctuation range of 30 to 60% and the water content required for coating with lignin in pellet molding are 8 to 13%. ..

上記の通り、廃培地から燃料等を製造するにあたっては、廃培地発生のタイミングから燃料化等のための設備を備えた施設への輸送、当該施設における廃培地の処理等が重要なものとなる。これが不十分だと品質面、コスト面に悪影響を及ぼす。 As described above, when producing fuel, etc. from waste medium, it is important to transport the waste medium to a facility equipped with facilities for fuel conversion, etc. from the timing of waste medium generation, and to dispose of the waste medium at the facility. .. If this is insufficient, it will adversely affect quality and cost.

このような問題を鑑みると、特許文献1に係る発明は含水率60〜70%の廃培地を12%まで乾燥した上で成形するものであるが、このような大幅な乾燥を行うとその分、大きなエネルギーが必要になり、装置等に係るコストが大きくなるという問題がある。特許文献2に係る発明は含水率65%程度の混合廃培地をバイオマス燃料製造装置に投入するものであるが、当該装置を必要とし、また、当該装置で廃培地の含水率をどの程度まで下げるのか不明である。特許文献3に係る発明は廃培地を所定水分量まで乾燥するものであるが、種菌の投与が必須であり、どのようなタイミングでどの程度まで乾燥するものか不明である。特許文献4に係る発明は含水率40〜50%の混合廃培地を含水率8〜15%の粗状粉体にして焼却処理するものであるが、これはペレット燃料等の有価物の製造を目的としたものではなく課題も異なる。特許文献5に係る発明は30〜60%という乾燥機投入前の生木破砕原料の含水率を制御するものではないため、一律な運用処理を行うと運転に要するエネルギーが過剰になる可能性がある。また、当該発明はペレット成形におけるリグニンとの作用を期待したものであり、きのこによってリグニンが分解した廃培地とは前提条件が異なるものである。 In view of such a problem, the invention according to Patent Document 1 is formed by drying a waste medium having a water content of 60 to 70% to 12% and then molding the waste medium. There is a problem that a large amount of energy is required and the cost related to the device or the like increases. The invention according to Patent Document 2 is to put a mixed waste medium having a water content of about 65% into a biomass fuel production apparatus, but the apparatus is required, and to what extent the moisture content of the waste medium is reduced by the apparatus. I don't know. The invention according to Patent Document 3 is to dry the waste medium to a predetermined water content, but administration of an inoculum is indispensable, and it is unknown at what timing and to what extent. The invention according to Patent Document 4 is to incinerate a mixed waste medium having a water content of 40 to 50% into a coarse powder having a water content of 8 to 15%, which is used to produce valuable resources such as pellet fuel. The issues are different, not the intended ones. Since the invention according to Patent Document 5 does not control the water content of the raw wood crushing raw material of 30 to 60% before being put into the dryer, there is a possibility that the energy required for operation will be excessive if uniform operation processing is performed. is there. Further, the present invention is expected to act with lignin in pellet molding, and the preconditions are different from those of the waste medium in which lignin is decomposed by mushrooms.

また、特許文献1〜5に係る発明は廃培地を燃料等の有価物にするにあたり以下の課題を解決することが示唆されていない。 Further, it is not suggested that the inventions according to Patent Documents 1 to 5 solve the following problems in converting the waste medium into a valuable resource such as fuel.

すなわち、課題の一つに廃培地の品質低下に伴う製造物(燃料等)の品質低下防止がある。廃培地の状態によっては、乾燥工程において乾燥機内で団子状態(ダマ)になることがある。これは燃料等の品質低下要因の一つとなる。 That is, one of the problems is prevention of quality deterioration of products (fuel, etc.) due to quality deterioration of waste medium. Depending on the state of the waste medium, it may become a dumpling state (lump) in the dryer during the drying process. This is one of the factors that reduce the quality of fuel and the like.

さらに、廃培地の腐敗の進行は悪臭やカビの発生につながる。腐敗を防止するためには各工程において廃培地の含水率等の管理を適切に行う必要がある。 Furthermore, the progress of putrefaction of the waste medium leads to the development of foul odors and mold. In order to prevent spoilage, it is necessary to properly control the water content of the waste medium in each process.

特許文献1〜5に係る発明は上記のような課題を解決するものではない。 The inventions according to Patent Documents 1 to 5 do not solve the above problems.

特開2008−120890号公報Japanese Unexamined Patent Publication No. 2008-12890 特開2010−77201号公報JP-A-2010-77201 特開2013−226558号公報Japanese Unexamined Patent Publication No. 2013-226558 特開2016−5822号公報Japanese Unexamined Patent Publication No. 2016-5822 特開2015−52418号公報JP-A-2015-52418

本発明が解決しようとする課題は、きのこの廃培地から燃料等の有価物を製造するにあたり、廃培地からの悪臭の発生やカビの発生を抑えるとともに高品質、低コストの有価物の製造方法を提供することである。 The problem to be solved by the present invention is a method for producing valuable resources such as fuel from the waste medium of mushrooms, which suppresses the generation of foul odor and mold from the waste medium and produces high quality and low cost valuable resources. Is to provide.

第1の発明は、少なくとも、きのこ廃培地を乾燥させる乾燥工程、前記乾燥工程後に前記きのこ廃培地をペレット化するペレット成形工程からなるきのこ廃培地由来の有価物の製造方法であり、前記乾燥工程が前記きのこ廃培地を任意の方法で含水率45〜55%の粉体にする第1の工程、前記粉体を高温攪拌により含水率17〜25%にする第2の工程からなることを特徴とするきのこ廃培地由来の有価物の製造方法である。また、第2の発明は、少なくとも、きのこ廃培地を乾燥させる乾燥工程、前記乾燥工程後に前記きのこ廃培地をペレット化するペレット成形工程からなるきのこ廃培地由来の有価物の製造方法であり、前記乾燥工程が前記きのこ廃培地をきのこ収穫から7日以内に任意の方法で含水率25%超、55%以下の粉体にする第1の工程、前記粉体を高温攪拌により含水率17〜25%にする第2の工程からなることを特徴とするきのこ廃培地由来の有価物の製造方法である。また、第の発明は、少なくとも、きのこ廃培地を乾燥させる乾燥工程、前記乾燥工程後に前記きのこ廃培地を貯留する貯留工程、前記貯留工程後に前記きのこ廃培地をペレット化するペレット成形工程からなるきのこ廃培地由来の有価物の製造方法であり、前記乾燥工程が前記きのこ廃培地を任意の方法で含水率45〜55%の粉体にする第1の工程、前記粉体を高温攪拌により含水率17〜25%にする第2の工程からなることを特徴とするきのこ廃培地由来の有価物の製造方法である。また、第4の発明は、少なくとも、きのこ廃培地を乾燥させる乾燥工程、前記乾燥工程後に前記きのこ廃培地を貯留する貯留工程、前記貯留工程後に前記きのこ廃培地をペレット化するペレット成形工程からなるきのこ廃培地由来の有価物の製造方法であり、前記乾燥工程が前記きのこ廃培地をきのこ収穫から7日以内に任意の方法で含水率25%超、55%以下の粉体にする第1の工程、前記粉体を高温攪拌により含水率17〜25%にする第2の工程からなることを特徴とするきのこ廃培地由来の有価物の製造方法である。また、第の発明は、少なくとも、きのこ廃培地を乾燥させる乾燥工程、前記乾燥工程後に前記きのこ廃培地を袋詰めする袋詰め工程からなるきのこ廃培地由来の有価物の製造方法であり、前記乾燥工程が前記きのこ廃培地を任意の方法で含水率35%超、55%以下の粉体にする第1の工程、前記粉体を高温攪拌により含水率25〜35%にする第2の工程からなることを特徴とするきのこ廃培地由来の有価物の製造方法である。また、第の発明は、きのこ廃培地を、高温攪拌により含水率17〜25%にしてからペレット成形する工程、又は、高温攪拌により含水率35%超、55%以下の粉体にしてから袋詰めする工程、に供するために、任意の方法できのこ廃培地の含水率を45〜55%にすることを特徴とするきのこ廃培地粉体の製造方法である。また、第7の発明は、きのこ廃培地を、高温攪拌により含水率17〜25%にしてからペレット成形する工程、又は、高温攪拌により含水率35%超、55%以下の粉体にしてから袋詰めする工程、に供するために、きのこ収穫から7日以内に任意の方法できのこ廃培地の含水率を前記工程の上限値超、55%以下にすることを特徴とするきのこ廃培地粉体の製造方法である。また、第8の発明は、第6又は7の発明の製造方法で製造した粉体を前記目的とする工程に供し、当該工程に係る処理を行うことを特徴とするきのこ廃培地の有価物の製造方法である。また、第の発明は、少なくとも、きのこ廃培地を高温攪拌により乾燥させる乾燥工程、前記乾燥工程後に前記きのこ廃培地をペレット化するペレット成形工程、前記乾燥工程後に前記きのこ廃培地を袋詰めする袋詰め工程からなるきのこ廃培地由来の有価物の製造方法であり、前記乾燥工程後の工程として前記ペレット成形工程又は前記袋詰め工程のいずれかの工程を適宜、選択し、前記ペレット成形工程選択時には前記乾燥工程がきのこ廃培地を含水率17〜25%にするものであり、前記袋詰め工程選択時には前記乾燥工程がきのこ廃培地を含水率25〜35%にするものであることを特徴とするきのこ廃培地由来の有価物の製造方法である。また、第10の発明は、少なくとも、きのこ廃培地を高温攪拌により乾燥させる乾燥工程、前記乾燥工程後に前記きのこ廃培地を貯留する貯留工程、前記貯留工程後に前記きのこ廃培地をペレット化するペレット成形工程、前記乾燥工程後に前記きのこ廃培地を袋詰めする袋詰め工程からなるきのこ廃培地由来の有価物の製造方法であり、前記貯留工程後の工程として前記ペレット成形工程又は前記袋詰め工程のいずれかの工程を適宜、選択し、前記ペレット成形工程選択時には前記乾燥工程がきのこ廃培地を含水率17〜25%にして前記貯留工程が前記含水率範囲を維持するものであり、前記袋詰め工程選択時には前記乾燥工程がきのこ廃培地を含水率25〜35%にして前記貯留工程が前記含水率範囲をするものであることを特徴とするきのこ廃培地由来の有価物の製造方法である。
The first invention is a method for producing valuable resources derived from a mushroom waste medium, which comprises at least a drying step of drying the mushroom waste medium and a pellet forming step of pelletizing the mushroom waste medium after the drying step. Is characterized by comprising a first step of converting the mushroom waste medium into a powder having a water content of 45 to 55% by an arbitrary method, and a second step of converting the powder into a powder having a water content of 17 to 25% by high temperature stirring. This is a method for producing valuable resources derived from the waste medium of mushrooms. The second invention is a method for producing a valuable resource derived from a mushroom waste medium, which comprises at least a drying step of drying the mushroom waste medium and a pellet forming step of pelletizing the mushroom waste medium after the drying step. The drying step is the first step of converting the mushroom waste medium into a powder having a water content of more than 25% and 55% or less by any method within 7 days after harvesting the mushroom. The powder is stirred at a high temperature to have a water content of 17 to 25. It is a method for producing a valuable resource derived from a mushroom waste medium, which comprises a second step of making% . Further, the third invention comprises at least a drying step of drying the mushroom waste medium, a storage step of storing the mushroom waste medium after the drying step, and a pellet forming step of pelletizing the mushroom waste medium after the storage step. A method for producing valuable resources derived from mushroom waste medium, wherein the drying step is a first step of converting the mushroom waste medium into a powder having a water content of 45 to 55% by an arbitrary method, and the powder is water-containing by high-temperature stirring. It is a method for producing a valuable resource derived from a mushroom waste medium, which comprises a second step of adjusting the rate to 17 to 25%. The fourth invention comprises at least a drying step of drying the mushroom waste medium, a storage step of storing the mushroom waste medium after the drying step, and a pellet forming step of pelletizing the mushroom waste medium after the storage step. A method for producing valuable resources derived from a mushroom waste medium, wherein the drying step makes the mushroom waste medium into a powder having a water content of more than 25% and 55% or less by any method within 7 days after harvesting the mushrooms. It is a method for producing a valuable material derived from a mushroom waste medium, which comprises a second step of making the powder have a water content of 17 to 25% by stirring at a high temperature . The fifth invention is a method for producing a valuable resource derived from a mushroom waste medium, which comprises at least a drying step of drying the mushroom waste medium and a bagging step of bagging the mushroom waste medium after the drying step. The drying step is a first step of converting the mushroom waste medium into a powder having a water content of more than 35% and 55% or less by an arbitrary method, and a second step of turning the powder into a powder having a water content of 25 to 35% by high-temperature stirring. It is a method for producing a valuable resource derived from a mushroom waste medium, which is characterized by being composed of. In the sixth invention, the mushroom waste medium is made into a powder having a water content of more than 35% and 55% or less by a step of pellet forming after making the mushroom waste medium have a water content of 17 to 25% by high temperature stirring, or after making it into a powder having a water content of more than 35% and 55% or less by high temperature stirring. A method for producing a mushroom waste medium powder, which comprises setting the water content of the mushroom waste medium to 45 to 55% by any method for use in the bagging step. Further, in the seventh invention, the mushroom waste medium is made into a powder having a water content of more than 35% and 55% or less by a step of pellet forming after making the mushroom waste medium have a water content of 17 to 25% by high temperature stirring, or after making the powder with a water content of more than 35% and 55% or less by high temperature stirring. in order to provide the step of bagging, the upper limit of the water content of the mushroom waste medium in any manner within 7 days from the mushroom harvest as before climate than, mushroom waste medium, characterized by the following 55% This is a powder manufacturing method. The invention of eighth, subjecting the powder produced by the production method of the invention of a 6 or 7 to the step of said object, valuable mushroom waste medium, wherein the TURMERIC row processing according to the process It is a manufacturing method of. Further, the ninth invention is at least a drying step of drying the mushroom waste medium by high temperature stirring, a pellet forming step of pelletizing the mushroom waste medium after the drying step, and bagging the mushroom waste medium after the drying step. A method for producing valuable resources derived from mushroom waste medium, which comprises a bagging step. As a step after the drying step, either the pellet forming step or the bagging step is appropriately selected, and the pellet forming step is selected. Occasionally, the drying step makes the mushroom waste medium have a water content of 17 to 25%, and when the bagging step is selected, the drying step makes the mushroom waste medium have a water content of 25 to 35%. This is a method for producing valuable resources derived from the waste medium of mushrooms. Further, the tenth invention is at least a drying step of drying the mushroom waste medium by high temperature stirring, a storage step of storing the mushroom waste medium after the drying step, and pellet molding for pelletizing the mushroom waste medium after the storage step. A method for producing valuable resources derived from mushroom waste medium, which comprises a bagging step of bagging the mushroom waste medium after the step and the drying step, and the step after the storage step is either the pellet forming step or the bagging step. The step is appropriately selected, and when the pellet forming step is selected, the drying step sets the mushroom waste medium to a water content of 17 to 25%, and the storage step maintains the water content range. At the time of selection, the drying step is a method for producing valuable resources derived from mushroom waste medium, characterized in that the mushroom waste medium has a water content of 25 to 35% and the storage step has a water content range.

本発明は、きのこ廃培地から高品質な燃料等の有価物を衛生的かつ低コストで製造できる効果が期待できる。 The present invention can be expected to have the effect of producing valuable resources such as high-quality fuel from mushroom waste medium hygienically and at low cost.

図1は粉体化処理場兼保管場におけるきのこ廃培地粉体の外観である。FIG. 1 shows the appearance of the mushroom waste medium powder in the powder processing plant and storage plant. 図2はきのこ廃培地の乾燥日数と含水率の関係図である。FIG. 2 is a diagram showing the relationship between the number of days for drying the mushroom waste medium and the water content. 図3はきのこ廃培地から石づきを分離した場合の含水率とpHの関係図である。FIG. 3 is a diagram showing the relationship between the water content and pH when stones are separated from the mushroom waste medium. 図4はきのこ廃培地から石づきを分離しなかった場合の含水率とpHの関係図である。FIG. 4 is a diagram showing the relationship between the water content and pH when stones are not separated from the mushroom waste medium. 図5はきのこ廃培地から有価物を得るための工程フロー図である。FIG. 5 is a process flow chart for obtaining valuable resources from the waste medium of mushrooms.

本発明の実施の形態を以下に説明する。 Embodiments of the present invention will be described below.

(1)菌床
きのこ廃培地からペレット用資材としてペレット製造に供するための処理方法について説明する。ここで、ペレット用資材とは最終製造物である燃料や敷料等の有価物(リサイクル製品)を製造するための資材であり、きのこ収穫後の廃培地を粉体状になるまで水分を下げ、乾燥機に投入可能な状態にしたものを意味する。まず、粉体化するきのこ廃培地を用意した。本実施例では、富山きのこセンター(ホクト株式会社)においてブナシメジ栽培後に排出される廃培地を用いた(きのこ収穫直後の廃培地含水率は約65%)。菌床は広葉樹のオガクズ、米ぬかから構成される。一般的に菌床はオガクズ等の木質基材、米ぬか等の栄養源から構成され、多量の水分を含むものである。木質基材としては他にブナ、ナラ、トチ等の広葉樹、スギ、マツ等の針葉樹を用いることも可能であるし、栄養源としては米ぬかだけでなく、むぎぬか(フスマ)、トウモロコシぬか、小麦粉等を用いてもできる。また、栽培するきのこの種類についてもブナシメジに限定するものでない。ブナシメジ以外にシイタケの廃培地についても本実施例と同様の結果が得られることが確認されている(記載は省略)。これらを踏まえ、本発明は前記以外にエリンギ、マイタケ、エノキタケ、ヒラタケ等、きのこ全般に適用されるものである。
(1) A treatment method for producing pellets from a fungus bed mushroom waste medium as a pellet material will be described. Here, the pellet material is a material for producing valuable resources (recycled products) such as fuel and litter, which is the final product, and the waste medium after harvesting mushrooms is reduced in water until it becomes powdery. It means that it is ready to be put into a dryer. First, a powdered mushroom waste medium was prepared. In this example, a waste medium discharged after cultivation of Bunashimeji mushrooms was used at the Toyama Mushroom Center (Hokuto Corporation) (the water content of the waste medium immediately after harvesting mushrooms is about 65%). The fungus bed is composed of hardwood sawdust and rice bran. Generally, the fungus bed is composed of a wood base material such as sawdust and a nutrient source such as rice bran, and contains a large amount of water. Hardwoods such as beech, nara, and tochi, and conifers such as sugi and pine can also be used as the wood base material, and not only rice bran but also muginuka (bran), corn bran, and wheat flour can be used as nutrient sources. Etc. can also be used. In addition, the types of mushrooms to be cultivated are not limited to Bunashimeji mushrooms. It has been confirmed that the same results as in this example can be obtained for the waste medium of shiitake mushrooms other than Bunashimeji (the description is omitted). Based on these, the present invention is applied to mushrooms in general, such as King trumpet mushroom, Maitake mushroom, Enokitake mushroom, and Pleurotus ostreatus.

(2)粉体化
用意したきのこ廃培地(概ね350〜400kg)から石づきを分離したものを送風(エアレーション)により乾燥させた。エアレーションは通常空気をそのまま用いたもの、加温したもの(例えば、60℃の温風)で行うことができる。本実施例で用いた菌床は乾燥とともに脆くなり粉体化した(図1)。この繰り返し評価により、木質系基材を主とする菌床の廃培地の場合、収穫から7日以内に含水率55%以下にすることで、臭気の発生を抑え、次工程の乾燥処理に適したものとなり、品質が安定したペレット用資材となることが確認された(乾燥後、少なくとも1週間から2週間は臭気を抑え、ペレット用資材として問題なく使用できることが確認された)。ここで、本発明における含水率は、水分の重量を水分と固形分の重量の和で除したものであり、複数サンプルの平均値を意味する。なお、本実施例におけるエアレーション装置(製造元:株式会社ミライエ)は1メートル程度に堆積した粉体の最下部に設置した棒状に伸びた複数の排気パイプに設けられた複数の穴からエアーを噴き出すものである。含水率50%程度までであれば乾燥機のような大きな熱量を要することなく乾燥できることが確認された。また、乾燥条件を変えることで含水率を50%以下にすることも可能である。例えば、廃培地の堆積量を本実施例よりも少なくすることでエアレーションの効果をより高め、本工程において廃培地を含水率25%超、55%以下の範囲内にすることができる。
(2) Powdering The prepared mushroom waste medium (approximately 350 to 400 kg) was separated from stones and dried by blowing air (aeration). Aeration can be carried out by using normal air as it is or by heating it (for example, warm air at 60 ° C.). The bacterial bed used in this example became brittle and powdered as it dried (Fig. 1). According to this repeated evaluation, in the case of a waste medium of a fungus bed mainly composed of a wood-based base material, the water content is reduced to 55% or less within 7 days after harvesting, thereby suppressing the generation of odor and suitable for the drying treatment in the next step. It was confirmed that the material could be used as a pellet material with stable quality (it was confirmed that the odor was suppressed for at least 1 to 2 weeks after drying and the material could be used as a pellet material without any problem). Here, the water content in the present invention is obtained by dividing the weight of water by the sum of the weight of water and the weight of solid content, and means the average value of a plurality of samples. The aeration device (manufacturer: Miraie Co., Ltd.) in this embodiment blows air from a plurality of holes provided in a plurality of rod-shaped exhaust pipes installed at the bottom of powder deposited at about 1 meter. Is. It was confirmed that if the moisture content is up to about 50%, it can be dried without requiring a large amount of heat like a dryer. It is also possible to reduce the water content to 50% or less by changing the drying conditions. For example, the effect of aeration can be further enhanced by reducing the amount of waste medium deposited as compared with this example, and the waste medium can be kept in the range of water content of more than 25% and 55% or less in this step.

粉体化にあたっては同程度の重量のきのこ廃培地から石づきを分離せずにそのまま乾燥した場合の含水率についても確認した(図2)。図2は同時期におけるきのこ廃培地の乾燥日数と含水率(堆積物頂上から深さ約40cmの試料)の一例である。石づきを分離した場合の方が早く乾燥する傾向にあることが確認された。また、堆積したきのこの廃培地を乾燥する過程において、攪拌前に内部(深さ約40cmと約80cm)の温度差を確認したところ、石づきを分離した場合の最大温度差は8.2℃、最小温度差は0.4℃、平均温度差は6.0℃、石づきを分離しない場合の最大温度差は17.0℃、最小温度差は2.4℃、平均温度差は8.2℃であった。 In powdering, the water content when the stones were dried as they were without being separated from the mushroom waste medium of the same weight was also confirmed (Fig. 2). FIG. 2 shows an example of the drying days and water content of the mushroom waste medium (a sample having a depth of about 40 cm from the top of the sediment) at the same time. It was confirmed that the stones tended to dry faster when separated. In addition, in the process of drying the waste medium of the accumulated mushrooms, the temperature difference inside (depths of about 40 cm and about 80 cm) was confirmed before stirring, and the maximum temperature difference when the stones were separated was 8.2 ° C. The minimum temperature difference is 0.4 ° C, the average temperature difference is 6.0 ° C, the maximum temperature difference without separating the mushrooms is 17.0 ° C, the minimum temperature difference is 2.4 ° C, and the average temperature difference is 8.2 ° C. Met.

また、きのこ廃培地の含水率とpHの関係を確認した(図3、図4)。図3は石づきを分離した場合、図4は石づきを分離しない場合の含水率とpHの関係の一例である。本工程で想定する含水率範囲内において、石づきを分離した場合には含水率が低下するほどpHが上昇する負の相関が確認された。石づきを分離しない場合はこのような傾向は確認されなかった。 In addition, the relationship between the water content and pH of the mushroom waste medium was confirmed (FIGS. 3 and 4). FIG. 3 shows an example of the relationship between the water content and pH when the stones are separated, and FIG. 4 shows the case where the stones are not separated. Within the water content range assumed in this step, a negative correlation was confirmed in which the pH increased as the water content decreased when stones were separated. This tendency was not confirmed when the stones were not separated.

きのこ収穫後、何の処理もせずに廃培地を放置しつづけると、きのこ収穫から7日を超えたあたりで腐敗が起こることが確認された。この場合、時間経過とともにpHが低下する傾向にあることが確認された。 After harvesting the mushrooms, it was confirmed that if the waste medium was left untreated without any treatment, putrefaction would occur more than 7 days after the mushrooms were harvested. In this case, it was confirmed that the pH tended to decrease with the passage of time.

(3)乾燥
廃培地を粉体にした後、投入ホッパーを通じて粉体を熱風式乾燥機に投入した。本実施例で用いた乾燥機は内部が回転して粉体を攪拌するとともに熱風を送り込むパドルドライヤー(ヒルデブランド社製:型番HD14/WTD)である。乾燥機に投入した粉体を30秒で含水率20%にした(乾燥機の処理量は1064kg/時)。ここで、乾燥機に投入するきのこ廃培地の含水率が55%以下の場合は乾燥機内でのダマの発生は確認されなかった。一方、含水率が55%を超えるとダマが発生しやすくなることが確認された。
(3) Drying After the waste medium was made into powder, the powder was put into a hot air dryer through a charging hopper. The dryer used in this embodiment is a paddle dryer (manufactured by Hildebrand Co., Ltd .: model number HD14 / WTD) that rotates inside to agitate powder and send hot air. The powder charged into the dryer was brought to a moisture content of 20% in 30 seconds (the processing amount of the dryer was 1064 kg / hour). Here, when the water content of the mushroom waste medium put into the dryer was 55% or less, no lumps were confirmed in the dryer. On the other hand, it was confirmed that when the water content exceeds 55%, lumps are likely to occur.

また、本発明に係るシステムの構成では乾燥工程における含水率17〜25%を実現するものとすることで狙いとする品質のペレットを製造できることが確認された。乾燥工程における乾燥後の廃培地含水率とペレットの性状を表1に示す。乾燥工程において含水率が25%を超えると保管中にペレットからカビが発生する場合があった。含水率25%以下にした場合には数週間経ってもカビの発生は認められなかった。また、肉眼評価では含水率25%程度からペレットの表面にテカリが生じ、含水率20%以下とした場合にはペレットの表面に高級感のある光沢が確認された。含水率をさらに下げていくと(含水率10%以下では)ペレットの結合性が弱くなることが確認された。また、ペレットを水中に投下した場合、含水率25%を超えるものは容易に分解することが確認されたが、含水率25%以下では分解し難くなることが確認された。

Figure 0006854499
Further, it was confirmed that the system configuration according to the present invention can produce pellets of the desired quality by achieving a water content of 17 to 25% in the drying process. Table 1 shows the water content of the waste medium after drying and the properties of the pellets in the drying step. If the moisture content exceeds 25% in the drying step, mold may be generated from the pellets during storage. When the water content was 25% or less, no mold was observed even after several weeks. Further, in the macroscopic evaluation, shine was generated on the surface of the pellet from a water content of about 25%, and when the water content was 20% or less, a high-grade luster was confirmed on the surface of the pellet. It was confirmed that when the water content was further lowered (at a water content of 10% or less), the bondability of the pellets became weaker. Further, when the pellets were dropped into water, it was confirmed that those having a water content of more than 25% were easily decomposed, but those having a water content of 25% or less were confirmed to be difficult to decompose.
Figure 0006854499

(4)貯留・ミキシング
乾燥機による乾燥後、上記含水率の粉体を貯留用ミキサーに数時間から数日間貯留した。当該工程は次工程(ペレット化)におけるペレットの生産を安定的に行うためのバッファとしての機能を担うとともに粉体含水率を一定に維持し、品質を安定化するための工程でもある。本実施例に用いたミキサーは粉体の最大貯留量が5トンであり、攪拌、温風エアレーション、排気を通じて粉体の含水率を維持することができるものである。さらに当該ミキサーは粉塵捕集及び脱臭機構を備えたものである。これにより一定の乾燥状態で静置するほど、また、エアレーション等の処理を行うほど、粉体からにおい等の揮発成分が放出するとともに微粉の分離が促される。ただし、当該工程を省略してもペレットの品質が低下することはない。なお、本発明におけるミキサー、ミキシングとは、貯留装置や貯留という語とともに用いていない場合でもミキシング前後に粉体を静置することがあるため、貯留装置や貯留の意味を含むことがある。
(4) Storage / Mixing After drying with a dryer, the powder having the above water content was stored in a storage mixer for several hours to several days. This step functions as a buffer for stable production of pellets in the next step (pelletization), and is also a step for maintaining a constant powder water content and stabilizing the quality. The mixer used in this example has a maximum powder storage capacity of 5 tons, and can maintain the water content of the powder through stirring, warm air aeration, and exhaust. Further, the mixer is equipped with a dust collecting and deodorizing mechanism. As a result, the more the powder is allowed to stand in a constant dry state, and the more the treatment such as aeration is performed, the more volatile components such as odor are released from the powder, and the separation of fine powder is promoted. However, even if the step is omitted, the quality of the pellets does not deteriorate. In addition, the mixer and mixing in the present invention may include the meaning of storage device and storage because the powder may be allowed to stand before and after mixing even when it is not used together with the terms storage device and storage.

(5)ペレット化
貯留後、含水率20%の粉体をペレット成形用装置(ペレタイザー:新興工機株式会社製)に投入し、燃料用ペレットとした。本実施例で用いたペレタイザーはリングダイ方式であり、能力は1.5トン/時である。得られたペレットの性状等は以下の通りである。
・直径約6mm
・長さ概ね10〜30mm
・円柱状
・かさ密度0.5〜0.6kg/m
・含水率約17%
・灰分4〜8%
・臭気は製造直後、製造数週間後とも無
・カビ発生は製造直後、製造数週間後とも無
・色合いはこげ茶(良品)
成形時のペレタイザーの摩擦熱の影響によりペレットの含水率は17%まで下がっていた。繰り返し評価によりペレット化を通じて含水率は3〜5%低下することが確認された。図4に係る石づきを分離しなかった場合の粉体から得られたペレットに関しても上記品質と同程度のものが得られることが確認された。
(5) Pelletization After storage, a powder having a water content of 20% was put into a pellet molding apparatus (pelletizer: manufactured by Shinko Koki Co., Ltd.) to prepare pellets for fuel. The pelletizer used in this embodiment is a ring die type and has a capacity of 1.5 tons / hour. The properties of the obtained pellets are as follows.
・ Approximately 6 mm in diameter
・ Length approximately 10 to 30 mm
・ Columnar ・ Bulk density 0.5-0.6kg / m 3
・ Moisture content about 17%
・ Ash content 4-8%
・ No odor immediately after production and several weeks after production ・ No mold growth immediately after production and several weeks after production ・ Dark brown color (good product)
Due to the influence of frictional heat of the pelletizer during molding, the water content of the pellets was reduced to 17%. Repeated evaluation confirmed that the water content decreased by 3 to 5% through pelletization. It was confirmed that the pellets obtained from the powder when the stones according to FIG. 4 were not separated were of the same quality as the above.

粉体製造について以下、説明する。
(1)乾燥
粉体状有価物とする場合においても乾燥機投入まではペレットの製造と同じである。すなわち、きのこ収穫時から7日以内に廃培地を含水率55%以下にして次工程の乾燥処理に供した。粉体の製造においては、乾燥機に投入した粉体を15秒で含水率30%とした。繰り返し評価の結果、粉体では袋詰め等の処理により含水率を高め(25〜35%)に設定しても、数週間経ってもカビが発生しない等、品質を維持できることが確認された。
The powder production will be described below.
(1) Drying Even when it is made into powdery valuable resources, it is the same as the production of pellets until it is put into the dryer. That is, within 7 days from the time of harvesting the mushrooms, the waste medium was reduced to a water content of 55% or less and subjected to the drying treatment in the next step. In the production of the powder, the powder put into the dryer had a water content of 30% in 15 seconds. As a result of repeated evaluations, it was confirmed that even if the water content of the powder is set to a high value (25 to 35%) by a treatment such as bagging, the quality can be maintained such that mold does not occur even after several weeks.

(2)貯留・ミキシング
乾燥機による乾燥後、上記含水率の粉体を貯留ミキサーに数時間から数日間、貯留した。当該工程の作用効果はペレット製造の場合と同様である。
(2) Storage / Mixing After drying with a dryer, the powder having the above water content was stored in a storage mixer for several hours to several days. The action and effect of this step are the same as in the case of pellet production.

(3)粉体袋詰め
貯留後、粉体を粉体袋詰め機に投入し、燃料用とした。得られた粉体の性状等は以下の通りである。
・粒径 概ね0.1〜0.4mm
・含水率約30%
・きのこ由来のかおり
粉体袋詰め機で500〜600kgの粉体をフレコンバックに詰めた。
(3) Powder bagging After storage, the powder was put into a powder bagging machine and used as fuel. The properties of the obtained powder are as follows.
・ Particle size approximately 0.1 to 0.4 mm
・ Moisture content about 30%
-A flexible container bag was packed with 500 to 600 kg of powder using a mushroom powder bagging machine.

以上、実施例1、2を通じて、きのこ廃培地由来の有価物製造方法を検討し、悪臭等の問題を解決し、狙いとする品質の有価物を製造できることが確認された。 As described above, through Examples 1 and 2, it was confirmed that the method for producing valuable resources derived from the waste medium of mushrooms was examined, problems such as foul odors were solved, and valuable resources of the desired quality could be produced.

まず、きのこ農家において発生したきのこ廃培地を7日以内に含水率を55%以下とすることで、特別な装置や投与物、操作を必要とせず、腐敗等の進行を遅らせ、臭気を抑制できることが示唆された。また、pHが石づきの分離処理の適否や廃培地の腐敗進行等の指標にし得ることが示唆された。例えば、石づきを分離処理した場合、含水率が小さくなるほどpHは上昇するという負の相関が確認されたことから(図3)、これを根拠に廃培地が適切に処理されたと判断することができる。本実施例ではpH測定時の含水率の範囲が石づきの有無で必ずしも一致するものではないが、平均pHに関して見ても、石づきを分離したものの方が高い結果となった。これは、含水率とpHが負の相関を示すか否かというだけでなく、石づきを分離することで平均pHが上がったか否かでも処理の適否を判断し得るものである。例えば、石づきを分離した場合の平均pHが石づきを(事前に測定しておいた又は比較対象として測定した)分離しなかった場合の平均pHと比較して大きいこと(例えば、含水率45〜55%における数値で見ると平均pHの差が1以上)を石づきが適切に分離処理されたきのこ廃培地であると判断できることが示唆された。石づきを分離した廃培地のみをペレット用資材とする場合にはこれらの適否判断において不適と判断された廃培地をペレット製造工程から除外してもよい。また、このようなpHを指標とする判断は廃培地から石づきを分離処理せずにペレット用資材とする場合にも有用である。石づきは良質なペレット製造の阻害要因となり得るため一般的に分離除去されるものであるが、本実施例では適切な処理を行うことで石づきを分離したものと同程度の品質のペレットを製造できることが確認できた。例えば、図4に示される含水率47〜63%の範囲内やその近傍において、初期pHと比較し、経時的なpH低下幅が概ね1以内であればペレット製造に適したものであると判断することができる。また、含水率55%以下にするまでのpHの低下幅が1より大きい廃培地についてはペレット製造工程からの除外対象と判断することができる。 First, by reducing the water content of the mushroom waste medium generated in mushroom farmers to 55% or less within 7 days, it is possible to delay the progress of putrefaction and suppress odor without the need for special equipment, administration, or operation. Was suggested. It was also suggested that pH can be used as an index for the suitability of stone separation treatment and the progress of putrefaction of waste medium. For example, when the stones were separated and treated, a negative correlation was confirmed that the pH increased as the water content decreased (Fig. 3), and it can be judged that the waste medium was properly treated based on this (Fig. 3). .. In this example, the range of water content at the time of pH measurement does not always match depending on the presence or absence of stones, but the average pH of the separated stones was higher. This can determine the suitability of the treatment not only by whether or not the water content and pH show a negative correlation, but also by whether or not the average pH is raised by separating the stones. For example, the average pH when the mushrooms are separated is higher than the average pH when the mushrooms are not separated (pre-measured or measured for comparison) (eg, water content 45-55). It was suggested that it can be judged that the stones are the mushroom waste medium that has been properly separated and treated) when the difference in average pH is 1 or more in terms of the numerical value in%. When only the waste medium from which the stones have been separated is used as the pellet material, the waste medium judged to be unsuitable in these suitability judgments may be excluded from the pellet production process. In addition, such a judgment using pH as an index is also useful when stones are used as a pellet material without being separated from the waste medium. Since stones can be an obstacle to the production of high-quality pellets, they are generally separated and removed. However, in this example, pellets of the same quality as those separated from stones can be produced by performing appropriate treatment. Was confirmed. For example, in the range of the water content of 47 to 63% shown in FIG. 4 or in the vicinity thereof, if the pH decrease with time is approximately 1 or less as compared with the initial pH, it is judged to be suitable for pellet production. can do. Further, a waste medium having a pH decrease of more than 1 until the water content is 55% or less can be determined to be excluded from the pellet production process.

また、本実施例では最初の乾燥処理をエアレーションにより行っているが、上記条件を満たすものであれば最終製造物の品質に影響はないと考えられる。従って、廃培地を構成する成分を変質させない(腐敗その他強制的な化学変化を起こさない)方法、すなわち物理的、機械的な乾燥方法であればどのような形態の乾燥であってもよい。例えば、減圧、真空乾燥でもよいし、送風による場合には常温や熱風だけでなく冷風によるものでもよい。また、人力で廃培地をバラして天日干しで乾燥させるものであってもよいし、スポンジのような吸水性素材に廃培地を接触させて乾燥させるものであってもよく、これらを組み合わせたものでもよい。ただし、微生物を投与する等、廃培地中の成分を予測不能なものに変化させる方法は除かれる。 Further, in this embodiment, the first drying treatment is performed by aeration, but if the above conditions are satisfied, it is considered that the quality of the final product is not affected. Therefore, any form of drying may be used as long as it is a method that does not alter the components constituting the waste medium (does not cause putrefaction or other forced chemical changes), that is, a physical or mechanical drying method. For example, decompression and vacuum drying may be used, and in the case of blowing air, not only normal temperature and hot air but also cold air may be used. Further, the waste medium may be manually separated and dried in the sun, or the waste medium may be brought into contact with a water-absorbent material such as a sponge and dried, and these may be combined. It may be a thing. However, methods of changing the components in the waste medium to unpredictable ones, such as administration of microorganisms, are excluded.

上記条件を満たす廃培地は一定期間品質を維持したまま次工程に供するまでストック可能である。例えば、次工程において廃培地の含水率を17〜25%にしてペレットを製造する場合には前工程で含水率25%超、55%以下の範囲にし、次工程において廃培地の含水率を25〜35%にして粉体を製造する場合には前工程で含水率35%超、55%以下の範囲にすることで仕掛品として図1に示すように大量にストックすることができる。これにより廃培地が発生するきのこ農家において廃培地を所定の含水率まで乾燥させ、重量を軽くしてから必要に応じて次工程の乾燥処理を行う現場に輸送する運用が可能になる。 Waste medium satisfying the above conditions can be stocked until it is used in the next step while maintaining its quality for a certain period of time. For example, when the pellet is produced by setting the water content of the waste medium to 17 to 25% in the next step, the water content should be in the range of more than 25% and 55% or less in the previous step, and the water content of the waste medium should be set to 25 in the next step. When the powder is produced at ~ 35%, a large amount of work-in-process can be stocked as a work-in-process by setting the water content in the range of more than 35% and 55% or less in the previous step. This makes it possible for mushroom farmers who generate waste medium to dry the waste medium to a predetermined water content, reduce the weight, and then transport it to the site where the next step of drying treatment is performed as needed.

また、きのこ廃培地の含水率を55%以下とすることで熱風攪拌式乾燥機においてダマの発生を抑制できることが確認された。ダマの発生はきのこ廃培地の攪拌混合によって生じ得るものであることから、ダマを抑制にあたっては特定の攪拌乾燥に限定されるものではなくパドル式、プロペラ式、ディスクタービン式、アンカー式、スクープ式等、高温状態(少なくともエアレーションの温度以上)で攪拌するものであればどのような形態のものでもよい。 It was also confirmed that the occurrence of lumps can be suppressed in the hot air stirring type dryer by setting the water content of the mushroom waste medium to 55% or less. Since the generation of lumps can be caused by stirring and mixing mushroom waste medium, the control of lumps is not limited to specific stirring and drying, but is not limited to paddle type, propeller type, disc turbine type, anchor type, and scoop type. Any form may be used as long as it is agitated in a high temperature state (at least above the aeration temperature).

上記工程を経て得られた廃培地を用い、乾燥工程以降の工程において廃培地を所望の含水率にすることで狙いとする品質の有価物を製造することができた。特に、乾燥工程においてペレットを製造する場合には含水率を17〜25%、粉体を製造する場合には含水率を25〜35%の範囲内にすることで品質面とコスト面を両立しつつ目的とする有価物を製造することができた。 Using the waste medium obtained through the above steps, it was possible to produce valuable resources of the desired quality by adjusting the waste medium to a desired water content in the steps after the drying step. In particular, when pellets are manufactured in the drying process, the moisture content is set within the range of 17 to 25%, and when powder is manufactured, the moisture content is set within the range of 25 to 35% to achieve both quality and cost. At the same time, we were able to produce the desired valuable resources.

また、当該乾燥工程後を分岐点としてペレットを製造するライン、粉体を製造するラインの2系統にすることができる(図5)。図5には乾燥工程の後に貯留・ミキシング工程が示されているがこの工程については省略するものでもよい。最終製造物の需要に応じて、適宜いずれかの系統を選択し、乾燥工程を停止することなく製造ラインの切り替えが可能になる。すなわち、ペレットの製造から粉体の製造に切り替えること又は粉体の製造からペレットの製造に切り替えることができる。例えば、ペレットの製造から粉体の製造に切り替える例として以下の運用が挙げられる。まず、ペレットの製造では乾燥工程において、例えば、含水率50%の廃培地を含水率20%となるようにする。ここで、要請に応じるため、ペレット製造から粉体製造に切り替える必要が生じたとする。この場合、まず、廃培地の含水率が25%となるように乾燥工程の運用を変更する(例えば、廃培地の含水率が25%になるよう乾燥機の乾燥温度を下げる)。そして、粉体製造にライン替えした後に廃培地の含水率が30%になるように乾燥工程の運用をさらに変更する。このように乾燥工程において廃培地の含水率25%を目安としてライン替えすることでペレット、粉体のいずれも品質低下の影響を抑え、装置全体を停止することなく、スムーズなライン替えを行うことができる。 Further, it is possible to have two systems, a line for producing pellets and a line for producing powders, with the drying step as a branching point (FIG. 5). Although FIG. 5 shows a storage / mixing step after the drying step, this step may be omitted. Depending on the demand for the final product, one of the systems can be appropriately selected, and the production line can be switched without stopping the drying process. That is, it is possible to switch from pellet production to powder production or from powder production to pellet production. For example, the following operation can be mentioned as an example of switching from pellet production to powder production. First, in the production of pellets, in the drying step, for example, a waste medium having a water content of 50% is adjusted to have a water content of 20%. Here, it is assumed that it becomes necessary to switch from pellet production to powder production in order to meet the request. In this case, first, the operation of the drying step is changed so that the water content of the waste medium is 25% (for example, the drying temperature of the dryer is lowered so that the water content of the waste medium is 25%). Then, after changing the line to powder production, the operation of the drying process is further changed so that the water content of the waste medium becomes 30%. In this way, by changing the line with the water content of the waste medium of 25% as a guide in the drying process, the influence of quality deterioration of both pellets and powder can be suppressed, and the line can be changed smoothly without stopping the entire device. Can be done.

また、実施例1のペレット製造の場合には乾燥工程後に廃培地の含水率を25%以下にする必要があったが、実施例2の粉体製造の場合にはペレットの場合よりも高めの含水率(25〜35%)にしてもカビが発生しない等、品質に影響がなかった。この点について、ペレットの場合はペレット内部に水分が固定化されるのに対し、粉体の場合はそのようなことがないのが理由の一つとして考えられる。 Further, in the case of pellet production of Example 1, it was necessary to reduce the water content of the waste medium to 25% or less after the drying step, but in the case of powder production of Example 2, it was higher than that of pellets. Even if the water content was (25 to 35%), there was no effect on the quality, such as no mold. Regarding this point, it is considered that one of the reasons is that in the case of pellets, water is immobilized inside the pellets, whereas in the case of powders, such a situation does not occur.

本発明は上述した実施形態に限定されることはなく、その要旨を逸脱しない範囲内において適宜変更することができる。 The present invention is not limited to the above-described embodiment, and can be appropriately modified without departing from the gist thereof.

本発明によれば、きのこ廃培地からの臭気を抑制し、良質な有価物製造方法に利用することができる。

According to the present invention, it is possible to suppress the odor from the waste medium of mushrooms and use it for a high-quality method for producing valuable resources.

Claims (10)

少なくとも、きのこ廃培地を乾燥させる乾燥工程、前記乾燥工程後に前記きのこ廃培地をペレット化するペレット成形工程からなるきのこ廃培地由来の有価物の製造方法であり、前記乾燥工程が前記きのこ廃培地を任意の方法で含水率45〜55%の粉体にする第1の工程、前記粉体を高温攪拌により含水率17〜25%にする第2の工程からなることを特徴とするきのこ廃培地由来の有価物の製造方法。 At least, it is a method for producing valuable resources derived from a mushroom waste medium, which comprises a drying step of drying the mushroom waste medium and a pellet forming step of pelletizing the mushroom waste medium after the drying step, and the drying step is a method for producing the mushroom waste medium. Derived from a mushroom waste medium, which comprises a first step of making a powder having a water content of 45 to 55% by an arbitrary method, and a second step of making the powder into a powder having a water content of 17 to 25% by high temperature stirring. Method of manufacturing valuable materials. 少なくとも、きのこ廃培地を乾燥させる乾燥工程、前記乾燥工程後に前記きのこ廃培地をペレット化するペレット成形工程からなるきのこ廃培地由来の有価物の製造方法であり、前記乾燥工程が前記きのこ廃培地をきのこ収穫から7日以内に任意の方法で含水率25%超、55%以下の粉体にする第1の工程、前記粉体を高温攪拌により含水率17〜25%にする第2の工程からなることを特徴とするきのこ廃培地由来の有価物の製造方法。 At least, it is a method for producing valuable resources derived from a mushroom waste medium, which comprises a drying step of drying the mushroom waste medium and a pellet forming step of pelletizing the mushroom waste medium after the drying step, and the drying step is a method for producing the mushroom waste medium. From the first step of making a powder having a water content of more than 25% and 55% or less by any method within 7 days from the harvest of mushrooms, and the second step of making the powder into a water content of 17 to 25% by high temperature stirring. A method for producing a valuable resource derived from a mushroom waste medium. 少なくとも、きのこ廃培地を乾燥させる乾燥工程、前記乾燥工程後に前記きのこ廃培地を貯留する貯留工程、前記貯留工程後に前記きのこ廃培地をペレット化するペレット成形工程からなるきのこ廃培地由来の有価物の製造方法であり、前記乾燥工程が前記きのこ廃培地を任意の方法で含水率45〜55%の粉体にする第1の工程、前記粉体を高温攪拌により含水率17〜25%にする第2の工程からなることを特徴とするきのこ廃培地由来の有価物の製造方法。 Valuables derived from mushroom waste medium, which consist of at least a drying step of drying the mushroom waste medium, a storage step of storing the mushroom waste medium after the drying step, and a pellet forming step of pelletizing the mushroom waste medium after the storage step. A production method, wherein the drying step is a first step of converting the mushroom waste medium into a powder having a water content of 45 to 55% by an arbitrary method, and a first step of converting the powder into a powder having a water content of 17 to 25% by high temperature stirring. A method for producing a valuable resource derived from a mushroom waste medium, which comprises two steps. 少なくとも、きのこ廃培地を乾燥させる乾燥工程、前記乾燥工程後に前記きのこ廃培地を貯留する貯留工程、前記貯留工程後に前記きのこ廃培地をペレット化するペレット成形工程からなるきのこ廃培地由来の有価物の製造方法であり、前記乾燥工程が前記きのこ廃培地をきのこ収穫から7日以内に任意の方法で含水率25%超、55%以下の粉体にする第1の工程、前記粉体を高温攪拌により含水率17〜25%にする第2の工程からなることを特徴とするきのこ廃培地由来の有価物の製造方法。 Valuables derived from mushroom waste medium, which consist of at least a drying step of drying the mushroom waste medium, a storage step of storing the mushroom waste medium after the drying step, and a pellet forming step of pelletizing the mushroom waste medium after the storage step. A production method, wherein the drying step is a first step of converting the mushroom waste medium into a powder having a water content of more than 25% and 55% or less by any method within 7 days from the mushroom harvest, and the powder is stirred at a high temperature. A method for producing a valuable resource derived from a mushroom waste medium, which comprises a second step of adjusting the water content to 17 to 25%. 少なくとも、きのこ廃培地を乾燥させる乾燥工程、前記乾燥工程後に前記きのこ廃培地を袋詰めする袋詰め工程からなるきのこ廃培地由来の有価物の製造方法であり、前記乾燥工程が前記きのこ廃培地を任意の方法で含水率35%超、55%以下の粉体にする第1の工程、前記粉体を高温攪拌により含水率25〜35%にする第2の工程からなることを特徴とするきのこ廃培地由来の有価物の製造方法。 At least, it is a method for producing valuable resources derived from a mushroom waste medium, which comprises a drying step of drying the mushroom waste medium and a bagging step of baging the mushroom waste medium after the drying step, and the drying step is a method for producing the mushroom waste medium. Mushrooms are characterized by comprising a first step of making a powder having a water content of more than 35% and 55% or less by an arbitrary method, and a second step of making the powder into a water content of 25 to 35% by high-temperature stirring. A method for producing valuable resources derived from waste medium. きのこ廃培地を、高温攪拌により含水率17〜25%にしてからペレット成形する工程、又は、高温攪拌により含水率35%超、55%以下の粉体にしてから袋詰めする工程、に供するために、任意の方法できのこ廃培地の含水率を45〜55%にすることを特徴とするきのこ廃培地粉体の製造方法。 To be used in a step of pellet-forming the mushroom waste medium after making it into a water content of 17 to 25% by high-temperature stirring, or a step of making a powder having a water content of more than 35% and 55% or less by high-temperature stirring and then bundling it. In addition , a method for producing a mushroom waste medium powder, which comprises setting the water content of the mushroom waste medium to 45 to 55% by any method. きのこ廃培地を、高温攪拌により含水率17〜25%にしてからペレット成形する工程、又は、高温攪拌により含水率35%超、55%以下の粉体にしてから袋詰めする工程、に供するために、きのこ収穫から7日以内に任意の方法できのこ廃培地の含水率を前記工程の上限値超、55%以下にすることを特徴とするきのこ廃培地粉体の製造方法。 To be used in a step of pellet-forming the mushroom waste medium after making it into a water content of 17 to 25% by high-temperature stirring, or a step of making a powder having a water content of more than 35% and 55% or less by high-temperature stirring and then bundling it. the upper limit of the water content of the mushroom waste medium in any manner within 7 days from the mushroom harvest as before climate than, the production method of the mushroom waste medium powder, characterized by a 55% or less. 請求項6又は7に記載の製造方法で製造した粉体を前記目的とする工程に供し、当該工程に係る処理を行うことを特徴とするきのこ廃培地の有価物の製造方法。 The method according to claim 6 or subjecting the powder produced by the production method according to 7 to the step of said object, valuable mushroom waste medium, wherein the TURMERIC row processing according to the process. 少なくとも、きのこ廃培地を高温攪拌により乾燥させる乾燥工程、前記乾燥工程後に前記きのこ廃培地をペレット化するペレット成形工程、前記乾燥工程後に前記きのこ廃培地を袋詰めする袋詰め工程からなるきのこ廃培地由来の有価物の製造方法であり、前記乾燥工程後の工程として前記ペレット成形工程又は前記袋詰め工程のいずれかの工程を適宜、選択し、前記ペレット成形工程選択時には前記乾燥工程がきのこ廃培地を含水率17〜25%にするものであり、前記袋詰め工程選択時には前記乾燥工程がきのこ廃培地を含水率25〜35%にするものであることを特徴とするきのこ廃培地由来の有価物の製造方法。 At least, a mushroom waste medium consisting of a drying step of drying the mushroom waste medium by high temperature stirring, a pellet forming step of pelletizing the mushroom waste medium after the drying step, and a bagging step of bagging the mushroom waste medium after the drying step. It is a method for producing a valuable resource derived from the substance, and either the pellet forming step or the bagging step is appropriately selected as a step after the drying step, and when the pellet forming step is selected, the drying step is a mushroom waste medium. Is to have a water content of 17 to 25%, and when the bagging process is selected, the drying step is a valuable resource derived from the mushroom waste medium having a water content of 25 to 35%. Manufacturing method. 少なくとも、きのこ廃培地を高温攪拌により乾燥させる乾燥工程、前記乾燥工程後に前記きのこ廃培地を貯留する貯留工程、前記貯留工程後に前記きのこ廃培地をペレット化するペレット成形工程、前記乾燥工程後に前記きのこ廃培地を袋詰めする袋詰め工程からなるきのこ廃培地由来の有価物の製造方法であり、前記貯留工程後の工程として前記ペレット成形工程又は前記袋詰め工程のいずれかの工程を適宜、選択し、前記ペレット成形工程選択時には前記乾燥工程がきのこ廃培地を含水率17〜25%にして前記貯留工程が前記含水率範囲を維持するものであり、前記袋詰め工程選択時には前記乾燥工程がきのこ廃培地を含水率25〜35%にして前記貯留工程が前記含水率範囲をするものであることを特徴とするきのこ廃培地由来の有価物の製造方法。
At least, a drying step of drying the mushroom waste medium by high temperature stirring, a storage step of storing the mushroom waste medium after the drying step, a pellet forming step of pelletizing the mushroom waste medium after the storage step, and the mushroom after the drying step. It is a method for producing valuable resources derived from mushroom waste medium, which comprises a bagging step of packing the waste medium, and either the pellet forming step or the bagging step is appropriately selected as a step after the storage step. When the pellet forming step is selected, the drying step makes the mushroom waste medium have a water content of 17 to 25%, and the storage step maintains the water content range. When the bagging step is selected, the drying step is to waste mushrooms. A method for producing valuable resources derived from mushroom waste medium, wherein the storage step has a water content of 25 to 35% and the storage step is within the water content range.
JP2020175284A 2020-10-19 2020-10-19 Method for producing valuable resources derived from mushroom waste medium Active JP6854499B1 (en)

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JPH07312975A (en) * 1994-05-19 1995-12-05 Sekou Kanri Sekkei Jimusho:Kk Sawdust regeneration treatment apparatus and regeneration treatment of sawdust
JP2009073973A (en) * 2007-09-21 2009-04-09 Research Institute Of Tsukuba Biotech Ltd Solid fuel and its manufacturing method
JP2013226556A (en) * 2007-12-31 2013-11-07 Shinyodo:Kk Method for drying water-containing organic matter
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JP2010077201A (en) * 2008-09-24 2010-04-08 Takumi Shikagawa Apparatus for producing biomass fuel
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JP2013047592A (en) * 2011-08-29 2013-03-07 Hildebrand Kk Stirring drying device
JP2016005822A (en) * 2014-05-26 2016-01-14 忠行 猪野 Waste mushroom culture medium dryer, method for processing waste mushroom culture medium, method for producing reusable object and method for producing dried waste culture medium
JP3197705U (en) * 2015-01-16 2015-06-04 株式会社大川鉄工 Steam generator using waste mushroom bed material fuel
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