JP6766105B2 - Glue composition - Google Patents

Glue composition Download PDF

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JP6766105B2
JP6766105B2 JP2018153659A JP2018153659A JP6766105B2 JP 6766105 B2 JP6766105 B2 JP 6766105B2 JP 2018153659 A JP2018153659 A JP 2018153659A JP 2018153659 A JP2018153659 A JP 2018153659A JP 6766105 B2 JP6766105 B2 JP 6766105B2
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paste composition
viscosity
emulsifier
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JP2018196388A (en
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孝行 大林
孝行 大林
良章 粕渕
良章 粕渕
近藤 圭一
圭一 近藤
直哉 森
直哉 森
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Taiyo Kagaku KK
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Description

本発明は、粉末溶解機、攪拌用プロペラ等の分散溶解用の設備が無い等、攪拌能力が不十分な場合や、アルコール等の分散用の溶媒が使用できない一般消費者の使用が主である咀嚼・嚥下困難者向け飲食品用糊料組成物(とろみ調整食品)に関する。 The present invention is mainly used by general consumers when the stirring capacity is insufficient, such as when there is no equipment for dispersing and dissolving such as a powder melting machine and a propeller for stirring, or when a solvent for dispersing alcohol and the like cannot be used. Regarding the paste composition (thickness-adjusted food) for foods and drinks for people who have difficulty chewing and swallowing.

ローカストビーンガム、タラガム、グァーガム、グァーガム酵素分解物、ゼラチン、タマリンドシードガム、カシアガム、寒天、加工デンプン等からなる糊料はゼリー、プリン、ムース等のゲル化目的や、たれ、ドレッシング、ソース等の増粘目的、アイスクリーム等の安定化目的等、加工食品に広く使用されている。 Glue consisting of locust bean gum, tara gum, guar gum, guar gum enzymatic decomposition products, gelatin, tamarind seed gum, cassia gum, agar, processed starch, etc. is used for gelling purposes such as jelly, pudding, mousse, etc. It is widely used in processed foods for thickening purposes, stabilizing ice cream, etc.

糊料を効果的に使用するためには、まず完全に水和させることが必要であり完全に水和して初めてゲル化や粘性が発現する。粉末溶解機、撹拌用プロペラ等の設備がない等、撹拌能力が不十分な工場や一般消費者等が糊料を使用する際には、糊料の表面のみが溶解し、内部は粉末の状態で残る、いわゆる“ダマ”の状態になりやすく、ダマになった糊料は水和が不完全で、その機能を発揮できない状態になりやすい。 In order to use the paste effectively, it is first necessary to completely hydrate it, and gelation and viscosity develop only after complete hydration. When a factory or general consumer with insufficient stirring capacity, such as a powder dissolver or a propeller for stirring, uses the paste, only the surface of the paste is dissolved and the inside is in a powder state. It tends to be in a so-called "lump" state, and the lumped paste tends to be incompletely hydrated and unable to exert its function.

通常糊料を水に分散・溶解する技術として、エタノールに糊料を分散した後、水等の目的物に加配して分散・溶解する技術や、ディスパー等の撹拌・溶解装置を用いて強く撹拌することでダマにならずに溶解する方法が知られている。これは、工業的に用いられる方法であり、ある程度の設備・熟練が必要な上に、家庭等の設備がない環境下では実施が困難であった。
また、糊料を水に分散する技術としては、糊料をデキストリン等の分散剤と混合して使用する技術(例えば、特許文献1参照。)や、糊料に水溶性多糖類と乳化剤の混合溶液をバインダーとして顆粒化し分散性を向上させる技術(例えば、特許文献2参照。)も発表されている。これらの技術は、糊料に対してデキストリンを大量に配合する必要があることや、顆粒化していても投入方法によってはダマが発生し、必ずしも簡単に溶解できるものではなかった。
Usually, as a technique for dispersing and dissolving the paste in water, a technique for dispersing and dissolving the paste in ethanol and then adding it to a target substance such as water to disperse and dissolve it, and a stirring and dissolving device such as a disper are used for strong stirring. There is known a method of dissolving without becoming lumpy by doing so. This is an industrially used method that requires a certain amount of equipment and skill, and is difficult to implement in an environment without equipment such as homes.
Further, as a technique for dispersing the glue in water, there is a technique of mixing the glue with a dispersant such as dextrin (see, for example, Patent Document 1), or mixing a water-soluble polysaccharide and an emulsifier in the glue. A technique for granulating a solution as a binder to improve dispersibility (see, for example, Patent Document 2) has also been announced. In these techniques, it is necessary to add a large amount of dextrin to the paste, and even if it is granulated, lumps occur depending on the injection method, and it is not always easy to dissolve.

また、ジェランガムにクエン酸ナトリウムを混合し溶解性を向上する技術(例えば、特許文献3参照。)も発表されている。これは、あくまでジェランガムの溶解性を向上するための技術であって、ジェランガムの分散性を向上する効果はない。その他にキサンタンガムの粉末表面に金属塩を結着させることにより分散性を向上する技術(例えば、特許文献4参照。)も発表されている。本特許は、キサンタンガムが多くの種類の塩類との反応性を持つことによる効果によるもので、同様に塩類との反応性を有するジェランガム、アルギン酸ナトリウム、カラギナン、ファーセレラン、ペクチンには同様の効果を有することが知られている。
しかしながら、これらの従来技術は適用できる糊料が限定されたり、分散剤を大量に配合する必要がある等、分散性と溶解性双方の向上を満たす技術ではなく、塩類との反応性を利用した技術は塩類の摂取を制限されている病者・高齢者向けの飲食品には積極的に使用できないなどの実態もあり、十分とはいえなかった。
Further, a technique for improving solubility by mixing sodium citrate with gellan gum (see, for example, Patent Document 3) has also been announced. This is just a technique for improving the solubility of gellan gum, and has no effect of improving the dispersibility of gellan gum. In addition, a technique for improving dispersibility by binding a metal salt to the powder surface of xanthan gum (see, for example, Patent Document 4) has also been announced. This patent is due to the effect of xanthan gum having reactivity with many kinds of salts, and has the same effect on gellan gum, sodium alginate, carrageenan, farcerelan, and pectin, which also have reactivity with salts. It is known.
However, these conventional techniques utilize the reactivity with salts, not the techniques that satisfy both the improvement of dispersibility and solubility, such as the applicable pastes are limited and a large amount of dispersant needs to be blended. The technology was not sufficient due to the fact that it could not be actively used for food and drink for the sick and elderly who have restricted salt intake.

特開平10−108633号公報JP-A-10-108633 特許第3186737号公報Japanese Patent No. 3186737 特開平9−187232号公報JP-A-9-187232 特許第3930897号公報Japanese Patent No. 3930897

本発明は、粉末溶解機、攪拌用プロペラ等の設備や、アルコール等の分散用の溶媒が使用できない製造工場や、特に一般消費者の使用が主である咀嚼・嚥下困難者向け糊料組成物(とろみ調整食品)でも、簡単に分散、使用することが可能であり、分散剤の配合量が少なくても良好に分散する糊料組成物の開発を課題とする。 The present invention is a paste composition for people who have difficulty chewing or swallowing, which is mainly used by equipment such as a powder dissolver and a stirring propeller, a manufacturing plant where a solvent for dispersing alcohol and the like cannot be used, and particularly for general consumers. (Thickness-adjusted foods) can also be easily dispersed and used, and the subject is to develop a paste composition that disperses well even if the amount of the dispersant is small.

本発明者らは上記課題を解決するために鋭意努力した結果、糊料表面に乳化剤又は、乳化剤と金属塩を被覆することにより糊料の表面が改質し、水への分散性が著しく向上し、分散した糊料組成物は確実に溶解し糊料のもつ性能を発現することを見出した。 As a result of diligent efforts to solve the above problems, the present inventors have modified the surface of the paste by coating the surface of the paste with an emulsifier or an emulsifier and a metal salt, and the dispersibility in water is remarkably improved. However, it was found that the dispersed paste composition was surely dissolved and exhibited the performance of the paste.

すなわち本発明は、以下に関するものである。
[1]乳化剤又は、乳化剤と金属塩を被覆した糊料を含有することを特徴とする咀嚼・嚥下困難者向け飲食品用の糊料組成物。
[2]乳化剤がポリグリセリン脂肪酸エステル、グリセリン脂肪酸エステル、有機酸モノグリセリド、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、酵素分解レシチンからなる群より選ばれる少なくとも1種以上である前記[1]記載の糊料組成物。
[3]金属塩が塩化カリウムである前記[1]又は[2]記載の糊料組成物。
[4]糊料がキサンタンガム及び/又はカルボキシルメチルセルロースナトリウムである前記[1]〜[3]いずれか記載の糊料組成物。
[5]被覆の方法が糊料又は、糊料と賦形剤に、乳化剤又は、乳化剤と金属塩の溶液を噴霧することである前記[1]〜[4]いずれか記載の糊料組成物。
[6]糊料100重量部に対して乳化剤0.01〜0.5重量部である前記[1]〜[5]いずれか記載の糊料組成物。
[7]乳化剤又は、乳化剤と金属塩を被覆した糊料の比容積が2.2ml/g以下である前記[1]〜[6]いずれか記載の糊料組成物。
[8]賦形剤がデキストリン、澱粉及び糖類からなる群より選ばれる少なくとも1種以上である前記[1]〜[7]いずれか記載の糊料組成物。
[9]20℃イオン交換水99重量部に対してディスパー等の機械撹拌装置を使用せずに糊料1重量部を添加した際に、ダマにならずに分散・溶解し、添加後5分でピーク粘度の90%以上に達する前記[1]〜[8]いずれか記載の糊料組成物。
[10]前記[1]〜[9]いずれか記載の糊料組成物を含有することを特徴とする飲食品。
[11]前記[1]〜[9]いずれか記載の糊料組成物を飲食品に添加し、混合することを特徴とする食品の調製方法。
That is, the present invention relates to the following.
[1] A paste composition for foods and drinks for people who have difficulty chewing or swallowing, which contains an emulsifier or a paste coated with an emulsifier and a metal salt.
[2] The emulsifier is at least one selected from the group consisting of polyglycerin fatty acid ester, glycerin fatty acid ester, organic acid monoglyceride, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, and enzymatically decomposed lecithin. ] The paste composition described.
[3] The paste composition according to the above [1] or [2], wherein the metal salt is potassium chloride.
[4] The paste composition according to any one of [1] to [3] above, wherein the paste is xanthan gum and / or sodium carboxylmethyl cellulose.
[5] The glue composition according to any one of the above [1] to [4], wherein the coating method is spraying a solution of an emulsifier or an emulsifier and a metal salt onto a glue or a glue and an excipient. ..
[6] The paste composition according to any one of [1] to [5] above, wherein the emulsifier is 0.01 to 0.5 parts by weight with respect to 100 parts by weight of the paste.
[7] The paste composition according to any one of [1] to [6] above, wherein the specific volume of the emulsifier or the paste coated with the emulsifier and the metal salt is 2.2 ml / g or less.
[8] The paste composition according to any one of [1] to [7] above, wherein the excipient is at least one selected from the group consisting of dextrin, starch and saccharide.
[9] When 1 part by weight of glue was added to 99 parts by weight of 20 ° C. ion-exchanged water without using a mechanical stirrer such as a disper, it was dispersed and dissolved without becoming lumpy, and 5 minutes after the addition. The paste composition according to any one of [1] to [8] above, which reaches 90% or more of the peak viscosity.
[10] A food or drink containing the paste composition according to any one of the above [1] to [9].
[11] A method for preparing a food, which comprises adding the paste composition according to any one of the above [1] to [9] to a food or drink and mixing them.

分散性、溶解性に優れた糊料組成物を提供することができるため、攪拌・溶解装置をもたず強い攪拌が得られない製造工場の作業性の改善や、特に咀嚼・嚥下困難者用補助組成物として高齢の患者や介護者が簡便に咀嚼・嚥下困難者用食品を調製することが可能となる。 Since it is possible to provide a paste composition having excellent dispersibility and solubility, it is possible to improve workability in a manufacturing plant where strong stirring cannot be obtained without a stirring / dissolving device, and especially for people who have difficulty chewing / swallowing. As an auxiliary composition, elderly patients and caregivers can easily prepare foods for people who have difficulty chewing and swallowing.

本発明には、食品添加物に認可されている乳化剤、糊料、金属塩と、賦形剤が用いられる。
本発明に用いられる乳化剤に関しては特に限定されるものではないが、ポリグリセリン脂肪酸エステル、グリセリン脂肪酸エステル、有機酸モノグリセリド、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、酵素分解レシチン等が挙げられ、好ましくはポリグリセリン脂肪酸エステルが挙げられ、更に好ましくはジグリセリン脂肪酸エステルもしくはヘキサグリセリン脂肪酸エステルが挙げられ、更に好ましくは脂肪酸がステアリン酸であるジグリセリン脂肪酸エステルもしくはヘキサグリセリン脂肪酸エステルが挙げられる。
本発明におけるグリセリン脂肪酸エステルとは、グリセリンと脂肪酸のエステルであり、分子蒸留によってモノエステル含量90%以上とした蒸留モノグリセリド、反応精製によりモノエステル含量40〜50%とした反応モノグリセリド、蒸留モノグリセリドを使いやすくするため油脂を20%程度配合したものなどが挙げられる。
本発明における有機酸モノグリセリドとは、モノグリセリドの水酸基にさらに有機酸をエステル化させたものであり、有機酸はクエン酸、コハク酸、酢酸、ジアセチル酒石酸、乳酸が挙げられる。
In the present invention, emulsifiers, pastes, metal salts and excipients approved as food additives are used.
The emulsifier used in the present invention is not particularly limited, and examples thereof include polyglycerin fatty acid ester, glycerin fatty acid ester, organic acid monoglyceride, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, and enzymatically decomposed lecithin. , Preferably polyglycerin fatty acid ester, more preferably diglycerin fatty acid ester or hexaglycerin fatty acid ester, and further preferably diglycerin fatty acid ester or hexaglycerin fatty acid ester in which the fatty acid is stearic acid.
The glycerin fatty acid ester in the present invention is an ester of glycerin and a fatty acid, and uses a distilled monoglyceride having a monoester content of 90% or more by molecular distillation, a reactive monoglyceride having a monoester content of 40 to 50% by reaction purification, and a distilled monoglyceride. For the sake of ease, examples include those containing about 20% of fats and oils.
The organic acid monoglyceride in the present invention is obtained by further esterifying an organic acid to the hydroxyl group of the monoglyceride, and examples of the organic acid include citric acid, succinic acid, acetic acid, diacetyltartaric acid, and lactic acid.

本発明におけるポリグリセリン脂肪酸エステルのポリグリセリンとは、グリセリンを脱水縮合する等して得られるグリセリン骨格を基本単位として分子内に水酸基とエーテルを有する物質をいう。一般的に流通しているポリグリセリンの種類は、ジグリセリン、トリグリセリン、テトラグリセリン、ペンタグリセリン、ヘキサグリセリン、デカグリセリン等が例示される。 The polyglycerin of the polyglycerin fatty acid ester in the present invention refers to a substance having a hydroxyl group and an ether in the molecule with the glycerin skeleton obtained by dehydration condensation of glycerin as a basic unit. Examples of the types of polyglycerin that are generally distributed include diglycerin, triglycerin, tetraglycerin, pentaglycerin, hexaglycerin, and decaglycerin.

ポリグリセリン脂肪酸エステルの脂肪酸は、特に限定するものではないが、例えば炭素数が8〜22であり、飽和もしくは不飽和の直鎖の脂肪酸やヒドロキシ体等の単独又は混合の脂肪酸であり、好ましくは炭素数12〜18の飽和脂肪酸である。
ポリグリセリン脂肪酸エステルのエステル化度は、特に限定するものではないが、好ましくはモノエステル含量50%以上であり、更に好ましくは70%以上である。これらポリグリセリン脂肪酸エステルはポリグリセリンと脂肪酸を不活性ガス存在下にて加熱エステル化反応し、場合によっては蒸留精製することによって得られるが、この方法に限定されるものではない。
The fatty acid of the polyglycerin fatty acid ester is not particularly limited, but is, for example, a fatty acid having 8 to 22 carbon atoms, a saturated or unsaturated linear fatty acid, a hydroxy compound, or the like, and is preferable. It is a saturated fatty acid having 12 to 18 carbon atoms.
The degree of esterification of the polyglycerin fatty acid ester is not particularly limited, but is preferably a monoester content of 50% or more, and more preferably 70% or more. These polyglycerin fatty acid esters can be obtained by subjecting polyglycerin and fatty acids to a heat esterification reaction in the presence of an inert gas, and in some cases, distillation purification, but the method is not limited to this method.

本発明におけるショ糖脂肪酸エステルとは、ショ糖の水酸基に脂肪酸がエステル化したものであり、ショ糖と脂肪酸の反応モル比によって親水性から疎水性まで各種のショ糖エステルが得られる。
本発明におけるソルビタン脂肪酸エステルとは、ソルビットの分子内脱水によりつくられるソルビタンと脂肪酸のエステルであり、脂肪酸の種類、ソルビタンと脂肪酸の反応モル比によって多くの種類のソルビタン脂肪酸エステルが得られる。
本発明におけるプロピレングリコール脂肪酸エステルとは、プロピレングリコールと脂肪酸のエステルであり、プロピレングリコールには2つの水酸基がありモノエステルとジエステルが得られる。分子蒸留によりモノエステル含量90%以上とした分子蒸留品とモノエステル含量約70%の反応品に分類される。
The sucrose fatty acid ester in the present invention is obtained by esterifying a fatty acid to a hydroxyl group of sucrose, and various sucrose esters ranging from hydrophilic to hydrophobic can be obtained depending on the reaction molar ratio of sucrose and fatty acid.
The sorbitan fatty acid ester in the present invention is an ester of sorbitan and fatty acid produced by intramolecular dehydration of sorbit, and many types of sorbitan fatty acid ester can be obtained depending on the type of fatty acid and the reaction molar ratio of sorbitan and fatty acid.
The propylene glycol fatty acid ester in the present invention is an ester of propylene glycol and a fatty acid, and propylene glycol has two hydroxyl groups to obtain a monoester and a diester. It is classified into a molecular distilled product having a monoester content of 90% or more by molecular distillation and a reaction product having a monoester content of about 70%.

本発明における酵素分解レシチンとは、植物レシチン又は卵黄レシチンを水又はアルカリ性水溶液でpH調整後、酵素分解して得られたもの、又はこれをエタノール、イソプロピルアルコール若しくはアセトンで抽出して得られたものであり、主成分はリゾレシチン及びフォスファチジン酸である。 The enzymatically decomposed lecithin in the present invention is obtained by enzymatically decomposing plant lecithin or egg yolk lecithin with water or an alkaline aqueous solution after adjusting the pH, or by extracting this with ethanol, isopropyl alcohol or acetone. The main components are lecithin and phosphatidic acid.

本発明に用いられる金属塩に関しては特に限定されるものではないが、カリウム塩、カルシウム塩、ナトリウム塩、マグネシウム塩等が挙げられ、好ましくはカリウム塩、更に好ましくは塩化カリウムが挙げられる。 The metal salt used in the present invention is not particularly limited, and examples thereof include potassium salt, calcium salt, sodium salt, magnesium salt and the like, preferably potassium salt, and more preferably potassium chloride.

本発明に用いられる糊料に関しては特に限定されるものではないが、キサンタンガム、グァーガム、ローカストビーンガム、タラガム、グァーガム酵素分解物、ゼラチン、タマリンドシードガム、カシアガム、寒天、加工デンプン、脱アシル型ジェランガム、ネイティブ型ジェランガム、サイリウムシードガム、トラガントガム、カラヤガム、アラビアガム、マクロホモプシスガム、ラムザンガム、アルギン酸、アルギン酸塩類(ナトリウム、カリウム、カルシウム、アンモニウム)、アルギン酸プロピレングリコールエステル、アグロバクテリウムスクシノグリカン、ガティガム、カラギナン、ファーセレラン、ペクチン、カードラン、微結晶セルロース、発酵セルロース、微小繊維状セルロース、メチルセルロース、エチルセルロース、カルボキシメチルセルロースナトリウム、カルボキシメチルセルロースカルシウム、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、ヒドロキシメチルプロピルセルロース、ダイズ多糖類、プルラン、納豆菌ガム、グルコマンナン等が挙げられ、好ましくはキサンタンガム、グァーガム、ローカストビーンガム、グァーガム酵素分解物、加工デンプン、脱アシル型ジェランガム、ネイティブ型ジェランガム、カルボキシメチルセルロースナトリウム、グルコマンナンが挙げられ、更に好ましくはキサンタンガム、カルボキシメチルセルロースナトリウムが挙げられる。
本発明におけるキサンタンガムとは、微生物キサントモナス・キャンペストリス(Xanthomonas campestris)がブドウ糖等を発酵して、その菌体外に蓄積した多糖類を精製し粉末にした天然のガム質である。
本発明におけるローカストビーンガムとは、豆科の多年性の常緑樹であるカロブ樹の種子から得られる主としてマンノースとガラクトースからなる多糖類である。
本発明におけるタラガムとは、タラの種子から得られたガラクトマンナンを主成分とする多糖類である。
The paste used in the present invention is not particularly limited, but xanthan gum, guar gum, locust bean gum, tara gum, guar gum enzymatic decomposition product, gelatin, tamarind seed gum, cassia gum, agar, processed starch, and deacylated gellan gum. , Native gellan gum, psyllium seed gum, tragant gum, karaya gum, arabic gum, macrohomopsis gum, lambzan gum, alginic acid, alginates (sodium, potassium, calcium, ammonium), propylene glycol alginate, agrobacterium succinoglycan, gati gum, Caraginan, Farselelan, Pectin, Cardran, Microcrystalline Cellulose, Fermented Cellulose, Microfibrous Cellulose, Methyl Cellulose, Ethyl Cellulose, Sodium Carboxymethyl Cellulose, Carboxymethyl Cellulose Calcium, Hydroxypropyl Cellulose, Hydroxypropyl Methyl Cellulose, Hydroxymethylpropyl Cellulose, Soybean Polysaccharides, Examples thereof include xanthan gum, natto fungus gum, glucomannan and the like, preferably xanthan gum, guar gum, locust bean gum, guar gum enzymatic decomposition products, processed starch, deacylated gellan gum, native gellan gum, sodium carboxymethyl cellulose and glucomannan. More preferably, xanthan gum and sodium carboxymethyl cellulose are mentioned.
The xanthan gum in the present invention is a natural gum obtained by fermenting glucose or the like by the microorganism Xanthomonas campestris and purifying the polysaccharide accumulated outside the cells to make a powder.
The locust bean gum in the present invention is a polysaccharide mainly composed of mannose and galactose obtained from the seeds of the carob tree, which is a perennial evergreen tree of the legume family.
The cod gum in the present invention is a polysaccharide containing galactomannan as a main component obtained from cod seeds.

本発明におけるグァーガムとは、グァーの種子から得られたガラクトマンナンを主成分とする多糖類である。
本発明におけるグァーガム酵素分解物とは、グァーガムを酵素で分解して得られたものでガラクトマンナンを主成分とする多糖類である。
本発明におけるゼラチンとは、動物の骨や皮などに含まれるコラーゲンを精製し加水分解して得られる動物性蛋白質である。
本発明におけるタマリンドシードガムとは、タマリンドの種子から得られた、多糖類を主成分とするもので、グルコース、キシロース、ガラクトースから構成キシログルカン多糖類である。
Guar gum in the present invention is a polysaccharide containing galactomannan as a main component obtained from guar seeds.
The guar gum enzymatic decomposition product in the present invention is a polysaccharide obtained by enzymatically decomposing guar gum and containing galactomannan as a main component.
Gelatin in the present invention is an animal protein obtained by purifying and hydrolyzing collagen contained in animal bones and skins.
The tamarind seed gum in the present invention is a xyloglucan polysaccharide composed of glucose, xylose, and galactose, which is mainly composed of a polysaccharide obtained from tamarind seeds.

本発明におけるカシアガムとは、エビスグサモドキの種子を粉砕して得られた多糖類を主成分とするものである。
本発明における寒天とは、テングサ、オゴノリ等の紅藻類に存在する多糖類である。
本発明における加工澱粉とは、天然澱粉に物理的・化学的処理を施した多糖類である。
本発明における脱アシル型ジェランガム及びネイティブ型ジェランガムとは、コーンシロップ等を基質とするグラム陰性菌(Pseudomonas elodea)の培養液より、分離して得られる直鎖状酸性多糖類である。
The cassia gum in the present invention is mainly composed of a polysaccharide obtained by crushing seeds of sicklepod.
The agar in the present invention is a polysaccharide present in red algae such as Gelidiaceae and Gracilaria.
The modified starch in the present invention is a polysaccharide obtained by physically and chemically treating natural starch.
The deacylated gellan gum and the native gellan gum in the present invention are linear acidic polysaccharides obtained by separating from a culture solution of Gram-negative bacteria (Pseudomonas elodea) using corn syrup or the like as a substrate.

本発明におけるサイリウムシードガムとは、オオバコ科ブロンドサイリウム(Plantago ovata FORSK.)の種子の外皮を粉砕して得られたもの又はこれを水で抽出して得られる酸性多糖類と中性多糖類の混合物である。
本発明におけるトラガントガムとは、マメ科トラガント(Astragalus gummifer LABILL.)の分泌液を乾燥して得られる多糖類を主成分とするものである。
The psyllium seed gum in the present invention is obtained by crushing the outer skin of the seeds of Plantain ovata FORSK. Or an acidic polysaccharide and a neutral polysaccharide obtained by extracting this with water. It is a mixture.
The tragant gum in the present invention is mainly composed of a polysaccharide obtained by drying the secretory fluid of the leguminous tragant (Astragalus gummifer LABILL.).

本発明におけるカラヤガムとは、アオギリ科カラヤ(Sterculia urens ROXB.)又はベニノキ科キバナワタモドキ(Cochlospermum gossypium A.P.DeCandolle)の幹枝の分泌液を乾燥して得られる多糖類を主成分とするものである。
本発明におけるアラビアガムとは、マメ科アラビアゴムノキ(Acacia senegal WILLDENOW)又はその他同属植物の分泌液を乾燥して得られたもの、又はこれを脱塩して得られる多糖類を主成分とするものである。
本発明におけるマクロホモプシスガムとは、不完全菌類(Macrophomopsis)の培養液より分離して得られる中性ホモ多糖類である。
The karaya gum in the present invention is mainly composed of a polysaccharide obtained by drying the secretion of the trunk branch of Sterculiaceae Karaya (Sterculia urens ROXB.) Or Bixaceae Kibanawatamodoki (Cochlospermum gossypium AP DeCandle). Is.
The gum arabic in the present invention is obtained by drying the secretory fluid of the leguminous gum arabic (Acacia senegal WILLDENOW) or other plants of the same genus, or a polysaccharide obtained by desalting the same. Is.
The macrohomopsis gum in the present invention is a neutral homopolysaccharide obtained by separating from a culture solution of Fungi imperfecti (Macrophomopsis).

本発明におけるラムザンガムとは、グラム陰性細菌(Alcaligenes(ATCC31961))の培養液より分離して得られる多糖類を主成分とするものである。
本発明におけるアルギン酸とは、褐藻類(Phaeophyceae)より、水又はアルカリ性水溶液で抽出し、精製して得られる高分子多糖類で、マンヌロン酸とグルロン酸の2種類のウロン酸が直鎖状に結合した構造をもつ。
The lambzan gum in the present invention is mainly composed of a polysaccharide obtained by separating from a culture solution of Gram-negative bacteria (Alcaligenes (ATCC31961)).
Alginic acid in the present invention is a high molecular weight polysaccharide obtained by extracting from brown algae (Phaeophyceae) with water or an alkaline aqueous solution and purifying it, and two types of uronic acids, mannuronic acid and gluuronic acid, are linearly bonded. Has a structure.

本発明におけるアルギン酸塩類(ナトリウム、カリウム、カルシウム、アンモニウム)とはアルギン酸と同様に褐藻類(Phaeophyceae)より、水又はアルカリ性水溶液で抽出し、精製して得られる高分子多糖類で、重合したウロン酸分子中のカルボキシル基に各々ナトリウムイオン、カリウムイオン、カルシウムイオン、アンモニウムイオンが結合した塩である。 The alginates (sodium, potassium, calcium, ammonium) in the present invention are high-molecular-weight polysaccharides obtained by extracting from brown algae (Phaeophyceae) with water or an alkaline aqueous solution and purifying them in the same manner as alginic acid. It is a salt in which sodium ion, potassium ion, calcium ion, and ammonium ion are bound to the carboxyl group in the molecule, respectively.

本発明におけるアルギン酸プロピレングリコールエステルとは、アルギン酸のカルボキシル基をプロピレンオキシドでエステル化したものである。
本発明におけるアグロバクテリウムスクシノグリカンとは、細菌(Agrobacterium tumefaciences)の培養液より、分離して得られるスクシノグリカンを主成分とする多糖類である。
本発明におけるガティガムとは、シクンシ科ガティノキ(Anogeissus latifolia WALL.)の幹の分泌液を乾燥して得られる多糖類を主成分とするものである。
The propylene glycol alginate in the present invention is obtained by esterifying the carboxyl group of alginic acid with propylene oxide.
The Agrobacterium succinoglycan in the present invention is a polysaccharide containing succinoglycan as a main component, which is obtained by separating from a culture solution of a bacterium (Agrobacterium tumefaciens).
The gati gum in the present invention is mainly composed of a polysaccharide obtained by drying the secretory fluid of the trunk of Combretaceae gatinoki (Anogeisus latifolia WALL.).

本発明におけるカラギナンとは、紅藻植物のスギノリ科のスギノリ属、ツノマタ属、イリデヤ属、ミリン科のキリンサイ属、その他海藻を水で抽出したもので、ガラクトース及びアンヒドロガラクトースを成分とする多糖類の硫酸エステルのカルシウム、カリウム、ナトリウム、アンモニウム、マグネシウム塩を主成分とするものである。 The carrageenan in the present invention is a polysaccharide composed of galactose and anhydrogalactose, which is obtained by extracting water from the genus Eucheuma, the genus Chondrus, the genus Iridaya, the genus Eucheuma of the family Mirin, and other seaweeds of the red algae plant. It is mainly composed of calcium, potassium, sodium, ammonium and magnesium salts of the sulfate ester of.

本発明におけるファーセレランとは、ススカケベニ科フルセラリア(Furcellaria fastigiata HUD.)の全藻より、水又はアルカリ性水溶液で抽出して得られる多糖類を主成分とするものである。
本発明におけるペクチンとは、アカザ科サトウアイコン(Beta vulgaris LINNE var. rapa DUMORTIER)、キク科ヒマワリ(Helianthus annuus LINNE)、ミカン科アマダイダイ(Citeus sinensis OSBECK)、ミカン科グレープフルーツ(Citrus paradisi MACF.)、ミカン科ライム(Citrus aurantifolia SWINGLE)、ミカン科レモン(Citrus limon BURM.f.)又はバラ科リンゴ(Malus pumila MILLER)より、水又は酸性水溶液で抽出したものより得られたもの又はこれをアルカリ性水溶液若しくは酵素で分解したものより得られたものである。
The furcereran in the present invention is mainly composed of a polysaccharide obtained by extracting with water or an alkaline aqueous solution from the whole algae of the family Furcellaria fastigiata HUD.
The pectin in the present invention is Sato icon (Beta vulgaris LINNE var. Rapa DUMORTIER), Asteraceae sunflower (Helianthus annuus LINNE), Rutaceae Amadaidai (Citeus sinensis Rutaceae), Citeus sinensis Obtained from water or acidic aqueous solution from Rutaceae lime (Citrus aurantifolia SWINGLE), Rutaceae lemon (Citrus lilon BURM.f.) or Rutaceae apple (Malus pumila MILLER), or an alkaline aqueous solution or enzyme. It was obtained from the one decomposed in.

本発明におけるカードランとは、微生物(Agrobacterium biovar1、又はAlcaligenes faecalis)が産生する多糖類で、ブドウ糖が直鎖状に1,3位でβグルコシド結合したβ−1,3−グルカンである。
本発明における微結晶セルロースとは、パルプから得られた結晶セルロースを主成分とするものである。
The curdlan in the present invention is a polysaccharide produced by a microorganism (Agrobacterium biovar1 or Alcaligenes faecalis), and is β-1,3-glucan in which glucose is linearly bound to β-glucoside at the 1,3 position.
The microcrystalline cellulose in the present invention is mainly composed of crystalline cellulose obtained from pulp.

本発明における発酵セルロースとは、Acetobacter acetiの亜種xylinumにより産生される直鎖状の多糖類である。
本発明における微小繊維状セルロースとは、パルプ又は綿を微小繊維状にして得られたセルロースを主成分とするものである。
本発明におけるメチルセルロースとは、セルロースをアルカリ触媒下に塩化メチル又はジメチル硫酸を反応させて得られる水溶性セルロースエーテルの一種である。
本発明におけるカルボキシメチルセルロースナトリウム、カルボキシメチルセルロースカルシウムとはセルロースの水酸基の一部をカルボキシメチル基で置換したもので、各々ナトリウムイオン、カルシウムイオンが結合した塩である。
The fermented cellulose in the present invention is a linear polysaccharide produced by the subspecies xylinum of Acetobacter aceti.
The fine fibrous cellulose in the present invention is mainly composed of cellulose obtained by making pulp or cotton into fine fibrous form.
Methyl cellulose in the present invention is a kind of water-soluble cellulose ether obtained by reacting cellulose with methyl chloride or dimethyl sulfate under an alkali catalyst.
The sodium carboxymethyl cellulose and calcium carboxymethyl cellulose in the present invention are those in which a part of the hydroxyl group of cellulose is replaced with a carboxymethyl group, and are salts to which sodium ions and calcium ions are bound, respectively.

本発明におけるヒドロキプロピルメチルセルロースとは、セルロースのメチル及びヒドロキシプロピルの混合エーテルである。
本発明におけるヒドロキシプロピルセルロースとは、セルロースのヒドロキシプロピルエーテルである。
本発明におけるヒドロキシメチルプロピルセルロースとは、メトキシル基を19〜30質量%、ヒドロキシプロポキシル基を4〜12質量%有する非イオン性水溶性セルロースエーテルである。
本発明におけるダイズ多糖類とは、大豆の子葉部分から得られる水溶性の多糖類である。
The hydrokipropylmethyl cellulose in the present invention is a mixed ether of methyl cellulose and hydroxypropyl cellulose.
The hydroxypropyl cellulose in the present invention is a hydroxypropyl ether of cellulose.
The hydroxymethylpropyl cellulose in the present invention is a nonionic water-soluble cellulose ether having 19 to 30% by mass of a methoxyl group and 4 to 12% by mass of a hydroxypropoxyl group.
The soybean polysaccharide in the present invention is a water-soluble polysaccharide obtained from the cotyledon portion of soybean.

本発明におけるプルランとは、黒酵母(Aureo basidiumpullulans(DEBARY)ARN.)の培養液より分離して得られた水溶性の中性多糖類である。
本発明における納豆菌ガムとは、納豆菌(Bacillus subtilis)の培養液より分離して得られるポリグルタミン酸を主成分とするものである。
Pullulan in the present invention is a water-soluble neutral polysaccharide obtained by separating from a culture solution of black yeast (Aureo basidium pullulans (DEBARY) ARN.).
The Bacillus natto gum in the present invention is mainly composed of polyglutamic acid obtained by separating from a culture solution of Bacillus subtilis.

本発明におけるグルコマンナンとは、サトイモ科コンニャク(Amonphophallus Konjac)の根茎を乾燥、粉砕後、含水エタノールで洗浄して得られたもの、又はこれを水で抽出して得られたもので、グルコースとマンノースで構成される多糖類からなる。 Glucomannan in the present invention is obtained by drying and crushing the rhizome of Araceae konjac and then washing it with hydrous ethanol, or by extracting it with water and using glucose. It consists of a polysaccharide composed of mannose.

本発明における乳化剤又は、乳化剤と金属塩の被覆の方法についてその方法は特に限定するものではないが、糊料と乳化剤、又は乳化剤と金属塩を湿潤することにより付着させ乾燥する方法や、乳化剤、又は乳化剤と金属塩含有溶液を糊料に噴霧し乾燥する方法等にて、糊料粒子表面へ乳化剤、又は乳化剤と金属塩を被覆させることができ、例えば、回転式滴下型造粒装置、流動層造粒装置、転動造粒装置、攪拌造粒装置、押出造粒装置等の公知の装置によって被覆する方法などが挙げられる。中でも糊料に乳化剤、又は乳化剤と金属塩を均一に付着することができる点で糊料に乳化剤、又は乳化剤と金属塩含有溶液を噴霧し同時に流動乾燥することが好ましい。
流動乾燥の方法については特に限定するものではないが、乳化剤0.1〜1重量%もしくはあわせて金属塩1〜30重量%を含む水溶液又は低沸点溶剤溶液を噴霧後流動乾燥することが望ましい。乳化剤と金属塩の被覆量は、糊料100重量部に対して乳化剤が0.01重量部以上、0.5重量部以下、金属塩が1重量部以上、10重量部以下であることが好ましい。糊料100重量部に対して乳化剤の被覆量が0.5重量部を越えると糊料の水への溶解性が悪くなり所望の粘度や強度が得られなかったり、風味に影響が及ぶ場合があるため好ましくない。0.01重量部未満では乳化剤の被覆量が少なく、分散性が低下し、糊料の水への分散性を改善する効果が不十分であるため好ましくない。糊料100重量部に対して金属塩の被覆量が10重量部を超えると糊料の水溶解時の粘度発現性が低下する為好ましくない。1重量部未満では金属塩の被覆量が少なく、分散性が低下し、糊料の水への分散性を改善する効果が不十分である為好ましくない。
The method of coating the emulsifier or the emulsifier and the metal salt in the present invention is not particularly limited, but the method of adhering and drying the emulsifier and the emulsifier by wetting the emulsifier and the metal salt, or the emulsifier. Alternatively, the surface of the emulsifier particles can be coated with the emulsifier or the emulsifier and the metal salt by spraying the emulsifier and the metal salt-containing solution onto the paste and drying the paste, for example, a rotary dropping type granulator, a flow. Examples thereof include a method of coating with a known device such as a layer granulation device, a rolling granulation device, a stirring granulation device, and an extrusion granulation device. Above all, it is preferable to spray the emulsifier or the emulsifier and the metal salt-containing solution on the paste and simultaneously fluidize and dry it because the emulsifier or the emulsifier and the metal salt can be uniformly adhered to the paste.
The method of fluid drying is not particularly limited, but it is desirable to spray an aqueous solution containing 0.1 to 1% by weight of an emulsifier or 1 to 30% by weight of a metal salt or a low boiling point solvent solution and then fluidize and dry. The coating amount of the emulsifier and the metal salt is preferably 0.01 part by weight or more and 0.5 part by weight or less for the emulsifier and 1 part by weight or more and 10 parts by weight or less for the metal salt with respect to 100 parts by weight of the paste. .. If the coating amount of the emulsifier exceeds 0.5 parts by weight with respect to 100 parts by weight of the paste, the solubility of the paste in water may deteriorate, and the desired viscosity and strength may not be obtained, or the flavor may be affected. It is not preferable because it exists. If it is less than 0.01 parts by weight, the amount of the emulsifier coated is small, the dispersibility is lowered, and the effect of improving the dispersibility of the paste in water is insufficient, which is not preferable. If the coating amount of the metal salt exceeds 10 parts by weight with respect to 100 parts by weight of the glue, the viscosity development of the glue when dissolved in water is lowered, which is not preferable. If it is less than 1 part by weight, the amount of the metal salt coated is small, the dispersibility is lowered, and the effect of improving the dispersibility of the paste in water is insufficient, which is not preferable.

本発明における乳化剤、金属塩被覆工程後の糊料組成物の比容積は2.5ml/g以下、さらには2.2ml/g以下であることが好ましい。比容積は、一定容量の容器にすりきり一杯の糊料組成物を充填し、充填された糊料組成物の重量を測定することにより求められる。糊料組成物の比容積は必要以上に大きくなると被覆に必要な乳化剤、金属塩量が多くなるとともに糊料の粒が大きくなって水への溶解に時間がかかって所望の粘度や強度が速やかに得られなかったり、風味に影響が及ぶ場合があり好ましくない。
また、得られた糊料組成物と賦形剤や食品等の粉末の比容積に差が大きいと予め粉体混合して使用する際に均一な混合物が得られなかったり、分級して成分のバラツキが発生し所望の粘度や強度が得られない場合がある。また、本発明の糊料組成物に、デキストリン、澱粉及び糖類から選ばれる1種以上の賦形剤を添加後、混合又は造粒するか、あるいは賦形剤を糊料に添加後に乳化剤、又は乳化剤と金属塩の被覆を行なうことができる。本発明における糊料組成物における賦形剤の添加割合は特に限定されないが、好ましくは糊料100重量部に対し、賦形剤が20〜400重量部である。
このような賦形剤としては特に限定されるものではないが、デキストリン、アミロデキストリン、エリトロデキストリン、アクロデキストリン、マルトデキストリン、シクロデキストリン等のデキストリン、トウモロコシ、モチトウモロコシ、馬鈴薯、甘藷、小麦、米、もち米、タピオカ、サゴヤシ等由来の澱粉や、物理的又は化学的処理を施した加工澱粉(酸分解澱粉、酸化澱粉、α化澱粉、クラフト化澱粉、カルボキシメチル基、ヒドロキシアルキル基を導入したエーテル化澱粉、アセチル基等を導入したエステル化澱粉、澱粉の2箇所以上の水酸基間に多官能基を結合させた架橋澱粉、乳化性澱粉、湿熱・乾燥処理澱粉等)の澱粉、ショ糖、果糖、ぶどう糖、麦芽糖、澱粉糖化物、還元澱粉水飴、トレハロース等の糖類等が挙げられ、好ましくはデキストリンが挙げられ、更に好ましくはDE=3〜30のデキストリンが挙げられる。
The specific volume of the emulsifier and the paste composition after the metal salt coating step in the present invention is preferably 2.5 ml / g or less, more preferably 2.2 ml / g or less. The specific volume is determined by filling a container with a constant volume with a full amount of the glue composition and measuring the weight of the filled glue composition. When the specific volume of the paste composition becomes larger than necessary, the amount of emulsifier and metal salt required for coating increases, and the particles of the paste become large, which takes time to dissolve in water and rapidly increases the desired viscosity and strength. It is not preferable because it may not be obtained or the flavor may be affected.
Further, if there is a large difference in the specific volume of the obtained paste composition and the powder of the excipient, food, etc., a uniform mixture cannot be obtained when the powder is mixed in advance and used, or the components are classified. In some cases, variations may occur and the desired viscosity and strength may not be obtained. Further, the paste composition of the present invention is mixed or granulated after adding one or more excipients selected from dextrin, starch and sugar to the paste composition, or an emulsifier or an emulsifier after adding the excipient to the paste. The emulsifier and the metal salt can be coated. The addition ratio of the excipient in the paste composition in the present invention is not particularly limited, but the excipient is preferably 20 to 400 parts by weight with respect to 100 parts by weight of the paste.
Such excipients are not particularly limited, but are dextrins such as dextrin, amylodextrin, erythrodextrin, acrodextrin, maltdextrin, cyclodextrin, corn, mochi corn, horse bells, sweet potato, wheat, rice. Introduced starch derived from glutinous rice, tapioca, sago palm, etc., and processed starch (acid-decomposed starch, oxidized starch, pregelatinized starch, kraft starch, carboxymethyl group, hydroxyalkyl group) that has been physically or chemically treated. Ethereated starch, esterified starch with acetyl groups, etc., crosslinked starch in which a polyfunctional group is bonded between two or more hydroxyl groups of starch, emulsifying starch, moist heat / drying treated starch, etc.) starch, sucrose, Examples thereof include saccharides such as fructose, glucose, malt sugar, starch saccharified product, reduced starch candy, and trehalose, preferably dextrin, and more preferably dextrin with DE = 3 to 30.

本発明の糊料組成物は、通常、糊料を水ないし水分を含む飲食品に溶解させる際に発生する、いわゆる“ダマ”が顕著に抑制されている。糊料を効果的に使用するためには、まず完全に水和させることが必要であり、完全に水和して所望する粘度や強度が発現する。糊料の表面のみが溶解し、内部は粉末の状態で残る、いわゆるダマの状態になった糊料は水和が不完全で、その機能を発揮できない状態になりやすい。また、糊料、特に増粘剤に求められる要件として、迅速な粘度付与(粘度発現の速さ)が挙げられる。糊料の水和速度が速いほど、対象とする飲食品へ迅速に所望の粘度を付与することが可能である。
糊料を水和した際、粘度の発現する速度は、糊料の粒径が細かくなるほど速く、粒径が大きくなるほど遅くなる傾向にある。しかしながら、粒径が細かい糊料は表面積が大きいため、粉末の表面のみが水和しやすく、ダマの発生を抑制するためには、ディスパー等の攪拌・溶解装置を用いて攪拌強度を上げる、攪拌時間を長くするといった厳しい攪拌条件が要求されてきた。本発明の糊料組成物は、ダマの抑制及び粘度発現の速さの相反する特性を両立し、例えば、手攪拌など、10回転/秒以下といった弱い攪拌条件でも使用することができ、一般消費者が家庭等の攪拌設備がない環境下で使用することができる。特に咀嚼・嚥下困難者用補助組成物として高齢の患者や介護者が簡便に咀嚼・嚥下困難者用食品を調製することが可能となる。
In the paste composition of the present invention, so-called "lumps" that are usually generated when the paste is dissolved in water or a food or drink containing water are remarkably suppressed. In order to use the paste effectively, it is first necessary to completely hydrate it, and then completely hydrate it to develop the desired viscosity and strength. Only the surface of the paste is dissolved, and the inside remains in a powder state. The paste in a so-called lump state is incompletely hydrated and tends to be in a state where its function cannot be exhibited. Further, as a requirement required for a paste, particularly a thickener, rapid viscosity imparting (speed of viscosity development) can be mentioned. The faster the hydration rate of the paste, the faster it is possible to impart the desired viscosity to the target food or drink.
When the paste is hydrated, the rate at which the viscosity develops tends to be faster as the particle size of the paste is smaller, and slower as the particle size is larger. However, since a paste having a fine particle size has a large surface area, only the surface of the powder is likely to be hydrated, and in order to suppress the occurrence of lumps, the stirring strength is increased by using a stirring / dissolving device such as a disper. Strict stirring conditions such as lengthening the time have been required. The paste composition of the present invention has both the contradictory properties of suppressing lumps and developing viscosity, and can be used under weak stirring conditions such as 10 rotations / sec or less, such as manual stirring, and is generally consumed. It can be used in an environment where a person does not have a stirring facility such as a home. In particular, as an auxiliary composition for people with chewing / swallowing difficulties, elderly patients and caregivers can easily prepare foods for people with chewing / swallowing difficulties.

本発明におけるピーク粘度とは、糊料、特に増粘剤が理想的な状態で分散・溶解した際に発する粘度数値のことである。具体的には一定量の糊料を一定量の水に分散溶解させた際、糊料を水に投入した直後から時間の経過とともに粘度は上昇する傾向がみられるが、この上昇傾向は一定時間経過後認められなくなり、その時の粘度をピーク粘度とした。
例えば、糊料の中で増粘剤として使用されるキサンタンガムの場合、キサンタンガム1gを20℃の水99gに溶解すると、溶解後徐々に粘度は上昇を開始し、溶解30分後に安定化する。したがって本願では溶解30分後の粘度をピーク粘度と称した。本発明品ではピーク粘度の90%以上に達する所要時間が5分以内であり、ピーク粘度の90%以上に達するまでに所要時間が10分以上かかる乳化剤を被覆していない糊料組成物と比較すると、実際に消費者が手撹拌で増粘した飲食品を調製した場合の作業時間は大幅に短縮され、溶解作業開始後すばやく粘度が発現する事実を実感することが可能となる。
The peak viscosity in the present invention is a viscosity value generated when a paste, particularly a thickener, is dispersed and dissolved in an ideal state. Specifically, when a certain amount of glue is dispersed and dissolved in a certain amount of water, the viscosity tends to increase with the passage of time immediately after the glue is put into water, but this increasing tendency is for a certain period of time. It disappeared after the lapse of time, and the viscosity at that time was defined as the peak viscosity.
For example, in the case of xanthan gum used as a thickener in a paste, when 1 g of xanthan gum is dissolved in 99 g of water at 20 ° C., the viscosity gradually starts to increase after dissolution and stabilizes 30 minutes after dissolution. Therefore, in the present application, the viscosity 30 minutes after dissolution is referred to as peak viscosity. In the product of the present invention, it takes less than 5 minutes to reach 90% or more of the peak viscosity, and it takes 10 minutes or more to reach 90% or more of the peak viscosity, as compared with an emulsifier-free paste composition. Then, when the consumer actually prepares the food and drink thickened by hand stirring, the working time is significantly shortened, and it becomes possible to realize the fact that the viscosity develops quickly after the start of the melting work.

本発明の糊料組成物は、乳化剤又は、乳化剤と金属塩を被覆した糊料を含有するものであれば他の増粘性素材及び/又は金属塩を併用することができる。特に限定するものではないが、増粘性素材として例えばグァーガム、ローカストビーンガム、カラギナン、タマリンドシードガム、カラヤガム、カルボシキメチルセルロース塩類、アルギン酸塩類、タラガム、グァーガム酵素分解物、加工澱粉より選ばれる少なくとも1種以上を糊料組成物に粉体混合する方法や、塩類としてカリウム塩、カルシウム塩、ナトリウム塩、マグネシウム塩より選ばれる少なくとも1種以上を糊料組成物に粉体混合する方法、さらには、糊料組成物に増粘性素材及び/又は塩類を含む溶液を噴霧し乾燥する方法等で調製することができる。 The paste composition of the present invention may be used in combination with an emulsifier or another thickening material and / or a metal salt as long as it contains an emulsifier and a paste coated with a metal salt. Although not particularly limited, at least one selected from, for example, guar gum, locust bean gum, carrageenan, tamarind seed gum, carrageenan, carboshikimethyl cellulose salts, alginates, tara gum, guar gum enzymatic decomposition products, and processed starch as thickening materials. A method of powder-mixing the above into a paste composition, a method of powder-mixing at least one selected from potassium salt, calcium salt, sodium salt, and magnesium salt as salts into the paste composition, and further, glue. The composition can be prepared by spraying a solution containing a thickening material and / or salts on the composition and drying the composition.

本発明の糊料組成物を添加する飲食品として、例えば、水、牛乳、乳飲料、乳酸菌飲料、果汁入り清涼飲料、炭酸飲料、果汁飲料、菜汁飲料、茶飲料、スポーツ飲料、機能性飲料、ビタミン補給飲料、栄養補給バランス飲料、粉末飲料、日本酒、焼酎、ウィスキー、カクテル、赤ワイン等の酒、コンソメスープ、ポタージュスープ、クリームスープ、中華スープ、味噌汁、シチュウ、カレー、グラタン等のスープ類、粥といった米飯食品等の液状の最終食品を挙げることができ、これらに直接添加して手攪拌のような比較的弱い攪拌で分散・混合して所望の粘度や強度を付与できる。 Foods and drinks to which the paste composition of the present invention is added include, for example, water, milk, milk drinks, lactic acid bacteria drinks, soft drinks containing fruit juice, carbonated drinks, fruit juice drinks, vegetable juice drinks, tea drinks, sports drinks, and functional drinks. , Vitamin supplement drink, nutrition supplement balance drink, powder drink, sake such as Japanese sake, shochu, whiskey, cocktail, red wine, consomme soup, potage soup, cream soup, Chinese soup, miso juice, stew, curry, gratin and other soups, Examples of liquid final foods such as rice foods such as porridge can be mentioned, and they can be directly added to them and dispersed and mixed with relatively weak stirring such as manual stirring to impart desired viscosity and strength.

更には、飲食品の製造時に本発明の糊料組成物を添加することもできる。飲食品としては、本発明の糊料組成物を含有していれば、特に限定されるものではなく、またその含有量も特に限定されるものではない。飲食品は、当業者に公知の製造方法により、本発明の糊料組成物を適宜加えて製造することができる。 Furthermore, the paste composition of the present invention can be added during the production of foods and drinks. The food and drink is not particularly limited as long as it contains the paste composition of the present invention, and the content thereof is not particularly limited. Foods and drinks can be produced by appropriately adding the paste composition of the present invention by a production method known to those skilled in the art.

例えば、アイスクリーム、アイスミルク、ラクトアイス、シャーベット、氷菓等の冷菓類、カスタードプリン,ミルクプリン及び果汁入りプリン等のプリン類、ゼリー、ババロア及びヨーグルト等のデザート類、チューインガムや風船ガム等のガム類、マーブルチョコレート等のコーティングチョコレートの他、イチゴチョコレート、ブルーベリーチョコレート及びメロンチョコレート等の風味を付加したチョコレート等のチョコレート類、ソフトキャンディー(キャラメル、ヌガー、グミキャンディー、マシュマロ等を含む)、タフィ等のキャラメル類、ソフトビスケット、ソフトクッキー等の菓子類、セパレートドレッシングやノンオイルドレッシングなどのドレッシング、ケチャップ、たれ、ソースなどのソース類、ストロベリージャム、ブルーベリージャム、マーマレード、リンゴジャム、杏ジャム、プレザーブ等のジャム類、シロップ漬のチェリー、アンズ、リンゴ、イチゴ等の加工用果実、ハム、ソーセージ、焼き豚等の畜肉加工品、魚肉ハム、魚肉ソーセージ、魚肉すり身、蒲鉾、竹輪、はんぺん、薩摩揚げ、伊達巻き、鯨ベーコン等の水産練り製品、うどん、冷麦、そうめん、ソバ、中華そば、スパゲッティ、マカロニ、ビーフン、はるさめ及びワンタン等の麺類、その他、各種総菜類等を挙げることができる。 For example, ice cream, ice milk, lacto ice, sherbet, cold confectionery such as ice cream, pudding such as custard pudding, milk pudding and pudding with fruit juice, desserts such as jelly, bavarois and yogurt, gums such as chewing gum and bubble gum. , Coated chocolate such as marble chocolate, chocolates such as chocolate with flavor such as strawberry chocolate, blueberry chocolate and melon chocolate, soft candy (including caramel, nougat, gummy candy, marshmallow, etc.), caramel such as toffee , Soft biscuits, sweets such as soft cookies, dressings such as separate dressing and non-oil dressing, sauces such as ketchup, sauce, sauce, jams such as strawberry jam, blueberry jam, marmalade, apple jam, apricot jam, preservative , Fruits for processing such as syrup-pickled cherries, apricots, apples, strawberries, processed meat products such as ham, sausage, grilled pork, fish meat ham, fish meat sausage, fish meat ground meat, jam, bamboo ring, hampen, fried Satsuma, date roll, whale Examples include marine products such as bacon, noodles such as udon, cold barley, somen, buckwheat, Chinese soba, spaghetti, macaroni, beefun, harusame and wantan, and various other delicatessen items.

また、このような一般飲食品に加えて、蛋白質・リン・カリウム調整食品、塩分調整食品、油脂調整食品、整腸作用食品、カルシウム・鉄・ビタミン強化食品、低アレルギー食品、濃厚流動食、ミキサー食、及びキザミ食等の特殊食品や治療食を挙げることができる。
本発明の糊料組成物を含む飲食品には、各種のカルシウム類、ビタミン類、鉄分、ミネラル類、食物繊維などの微量栄養素、粉末みそ、粉末ソース、かつおぶしの粉末、脱脂粉乳、粉末ポタージュなどの粉末調味料、乾燥わかめや乾燥野菜の粉末又は小片、細かく砕いた魚肉や肉製品の小片などの小片固形物、フルーツフレーバー、ミルクフレーバーなどの食品香料などのうち任意のものを適宜添加してもよい。これらの任意原料は、一旦糊料組成物を含む飲食品を製した後で加配してもよく、また加工前の糊料組成物へ加配しておいてもよい。
In addition to such general foods and drinks, protein / phosphorus / potassium-adjusted foods, salt-adjusted foods, fat-adjusted foods, intestinal-regulating foods, calcium / iron / vitamin-enriched foods, hypoallergenic foods, concentrated liquid foods, mixers Examples include foods, special foods such as scratched foods, and therapeutic foods.
Foods and drinks containing the paste composition of the present invention include various calcium, vitamins, iron, minerals, micronutrients such as dietary fiber, powdered miso, powder sauce, dried bonito powder, defatted milk powder, powdered potage, etc. Add any of the powdered seasonings, powdered or small pieces of dried bonito and dried vegetables, small solids such as finely crushed fish meat and small pieces of meat products, and food fragrances such as fruit flavor and milk flavor as appropriate. May be good. These optional raw materials may be added after the food or drink containing the paste composition is once produced, or may be added to the paste composition before processing.

本発明の糊料組成物は、特に咀嚼・嚥下困難者の喫食時に飲食品にとろみを付与させる、咀嚼・嚥下困難者向けの増粘剤(とろみ調整食品)に有用である。咀嚼・嚥下困難者の喫食用にとろみが付与された飲食品は、介護現場で水やお茶等の飲食品をスプーンを用いて攪拌しながら、増粘剤(とろみ調整食品)を添加して調製されているため、手攪拌といった弱い攪拌条件でもダマが生じないことが望まれており、生じたダマが残存していると誤嚥の原因となる可能性がある。また、所望する粘度の発現が遅いと、攪拌時間が長くなったり、必要以上の増粘剤を添加するため、介護者の負担が大きくなったり、所望する粘度から大きく逸脱した状態に調製された飲食品を喫食してしまう可能性もある。一方、本発明の糊料組成物は、手攪拌のような弱い攪拌条件時に発生するダマの抑制効果に優れ、さらに粘度発現も速く、かつ少量の添加で所望のとろみを付与することができる、更には増粘剤(とろみ調整食品)中の賦形剤配合量を従来品より大幅に低下させることも可能であるため、咀嚼・嚥下困難者の喫食用にとろみが付与された食品を簡便に調製することができる。
以下、実施例及び比較例を挙げて本発明を具体的に説明するが、本発明はこれらに限定するものではない。
The paste composition of the present invention is particularly useful as a thickener (thickening-adjusted food) for people with chewing / swallowing who has difficulty in chewing / swallowing, which imparts thickness to foods and drinks when eating. Foods and drinks that have been thickened for eating by people who have difficulty chewing or swallowing are prepared by adding a thickener (thickening-adjusted food) while stirring foods and drinks such as water and tea with a spoon at the care site. Therefore, it is desired that lumps do not occur even under weak stirring conditions such as manual stirring, and if the generated lumps remain, it may cause aspiration. Further, if the desired viscosity is slowly developed, the stirring time becomes long, and a thickening agent is added more than necessary, which increases the burden on the caregiver or is prepared in a state of greatly deviating from the desired viscosity. There is also the possibility of eating food and drink. On the other hand, the paste composition of the present invention has an excellent effect of suppressing lumps generated under weak stirring conditions such as manual stirring, develops viscosity quickly, and can impart a desired thickness with a small amount of addition. Furthermore, since it is possible to significantly reduce the amount of excipients in the thickener (thickening-adjusted food) compared to conventional products, it is possible to easily prepare foods with thickening for eating by people who have difficulty chewing or swallowing. Can be prepared.
Hereinafter, the present invention will be specifically described with reference to Examples and Comparative Examples, but the present invention is not limited thereto.

実施例1
70℃のイオン交換水50gにモノステアリン酸ジグリセリン(太陽化学株式会社製)0.25gを撹拌分散しバインダー溶液の調製を行った。キサンタンガム(太陽化学株式会社製)500gを流動状態に調整し、モノステアリン酸ジグリセリン溶液50.25gを噴霧後、乾燥して糊料組成物(本発明品1)490gを得た。本発明品1の比容積は1.8ml/gであった。
Example 1
A binder solution was prepared by stirring and dispersing 0.25 g of diglycerin monostearate (manufactured by Taiyo Kagaku Co., Ltd.) in 50 g of ion-exchanged water at 70 ° C. 500 g of xanthan gum (manufactured by Taiyo Kagaku Co., Ltd.) was adjusted to a fluid state, 50.25 g of a diglycerin monostearate solution was sprayed, and then dried to obtain 490 g of a paste composition (Product 1 of the present invention). The specific volume of the product 1 of the present invention was 1.8 ml / g.

実施例2
実施例1において、モノステアリン酸ジグリセリンをモノステアリン酸ペンタグリセリン(太陽化学株式会社製)に変更する以外は実施例1と同様にして、糊料組成物(本発明品2)485gを得た。本発明品2の比容積は1.8ml/gであった。
Example 2
In Example 1, 485 g of a paste composition (Product 2 of the present invention) was obtained in the same manner as in Example 1 except that diglycerin monostearate was changed to pentaglycerin monostearate (manufactured by Taiyo Kagaku Co., Ltd.). .. The specific volume of the product 2 of the present invention was 1.8 ml / g.

実施例3
実施例1において、モノステアリン酸ジグリセリンをモノオレイン酸ペンタグリセリン(太陽化学株式会社製)に変更する以外は実施例1と同様にして、糊料組成物(本発明品3)485gを得た。本発明品3の比容積は1.8ml/gであった。
Example 3
In Example 1, 485 g of a paste composition (Product 3 of the present invention) was obtained in the same manner as in Example 1 except that diglycerin monostearate was changed to pentaglycerin monooleate (manufactured by Taiyo Kagaku Co., Ltd.). .. The specific volume of the product 3 of the present invention was 1.8 ml / g.

実施例4
実施例1において、モノステアリン酸ジグリセリンをジアセチル酒石酸モノステアリン酸グリセリン(太陽化学株式会社製)に変更する以外は実施例1と同様にして、糊料組成物(本発明品4)485gを得た。本発明品4の比容積は1.8ml/gであった。
Example 4
In Example 1, 485 g of a paste composition (Product 4 of the present invention) was obtained in the same manner as in Example 1 except that diglycerin monostearate was changed to glycerin monostearate monostearate (manufactured by Taiyo Kagaku Co., Ltd.). It was. The specific volume of the product 4 of the present invention was 1.8 ml / g.

実施例5
実施例1において、モノステアリン酸ジグリセリンを自己乳化型ステアリン酸モノ・ジグリセリド(太陽化学株式会社製)に変更する以外は実施例1と同様にして、糊料組成物(本発明品5)485gを得た。本発明品5の比容積は1.8ml/gであった。
Example 5
In Example 1, 485 g of a paste composition (Product 5 of the present invention) was obtained in the same manner as in Example 1 except that diglycerin monostearate was changed to self-emulsifying mono-diglyceride stearate (manufactured by Taiyo Kagaku Co., Ltd.). Got The specific volume of the product 5 of the present invention was 1.8 ml / g.

実施例6
70℃のイオン交換水50gにモノステアリン酸ジグリセリン(太陽化学株式会社製)0.05gを撹拌分散しバインダー溶液の調製を行った。キサンタンガム(太陽化学株式会社製)500gを流動状態に調整し、モノステアリン酸ジグリセリン溶液50.05gを噴霧後、乾燥して糊料組成物(本発明品6)485gを得た。本発明品6の比容積は1.8ml/gであった。
Example 6
A binder solution was prepared by stirring and dispersing 0.05 g of diglycerin monostearate (manufactured by Taiyo Kagaku Co., Ltd.) in 50 g of ion-exchanged water at 70 ° C. 500 g of xanthan gum (manufactured by Taiyo Kagaku Co., Ltd.) was adjusted to a fluid state, 50.05 g of a diglycerin monostearate solution was sprayed, and then dried to obtain 485 g of a paste composition (Product 6 of the present invention). The specific volume of the product 6 of the present invention was 1.8 ml / g.

実施例7
70℃のイオン交換水100gにモノステアリン酸ジグリセリン(太陽化学株式会社製)0.5gを撹拌分散しバインダー溶液の調製を行った。キサンタンガム(太陽化学株式会社製)500gを流動状態に調整し、モノステアリン酸ジグリセリン溶液100.5gを噴霧後、乾燥して糊料組成物(本発明品7)485gを得た。本発明品7の比容積は1.8ml/gであった。
Example 7
A binder solution was prepared by stirring and dispersing 0.5 g of diglycerin monostearate (manufactured by Taiyo Kagaku Co., Ltd.) in 100 g of ion-exchanged water at 70 ° C. 500 g of xanthan gum (manufactured by Taiyo Kagaku Co., Ltd.) was adjusted to a fluid state, 100.5 g of a diglycerin monostearate solution was sprayed, and then dried to obtain 485 g of a paste composition (Product 7 of the present invention). The specific volume of the product 7 of the present invention was 1.8 ml / g.

実施例8
70℃のイオン交換水200gにモノステアリン酸ジグリセリン(太陽化学株式会社製)2.5gを撹拌分散しバインダー溶液の調製を行った。キサンタンガム(太陽化学株式会社製)500gを流動状態に調整し、モノステアリン酸ジグリセリン溶液202.5gを噴霧後、乾燥して糊料組成物(本発明品8)480gを得た。本発明品8の比容積は2.0ml/gであった。
Example 8
A binder solution was prepared by stirring and dispersing 2.5 g of diglycerin monostearate (manufactured by Taiyo Kagaku Co., Ltd.) in 200 g of ion-exchanged water at 70 ° C. 500 g of xanthan gum (manufactured by Taiyo Kagaku Co., Ltd.) was adjusted to a fluid state, 202.5 g of a diglycerin monostearate solution was sprayed, and then dried to obtain 480 g of a paste composition (Product 8 of the present invention). The specific volume of the product 8 of the present invention was 2.0 ml / g.

実施例9
70℃のイオン交換水200gにモノステアリン酸ジグリセリン(太陽化学株式会社製)5gを撹拌分散しバインダー溶液の調製を行った。キサンタンガム(太陽化学株式会社製)500gを流動状態に調整し、モノステアリン酸ジグリセリン溶液205gを噴霧後、乾燥して糊料組成物(本発明品9)480gを得た。本発明品9の比容積は2.2ml/gであった。
Example 9
A binder solution was prepared by stirring and dispersing 5 g of diglycerin monostearate (manufactured by Taiyo Kagaku Co., Ltd.) in 200 g of ion-exchanged water at 70 ° C. 500 g of xanthan gum (manufactured by Taiyo Kagaku Co., Ltd.) was adjusted to a fluid state, 205 g of a diglycerin monostearate solution was sprayed, and then dried to obtain 480 g of a paste composition (Product 9 of the present invention). The specific volume of the product 9 of the present invention was 2.2 ml / g.

実施例10
実施例1において、キサンタンガムをカルボキシメチルセルロースナトリウム(太陽化学株式会社製)に変更する以外は実施例1と同様にして、糊料組成物(本発明品10)485gを得た。本発明品10の比容積は1.7ml/gであった。
Example 10
In Example 1, 485 g of a paste composition (Product 10 of the present invention) was obtained in the same manner as in Example 1 except that xanthan gum was changed to sodium carboxymethyl cellulose (manufactured by Taiyo Kagaku Co., Ltd.). The specific volume of the product 10 of the present invention was 1.7 ml / g.

比較例1
実施例1において、モノステアリン酸ジグリセリンをイオン交換水に溶解せず、粉部に配合する以外は実施例1と同様にして糊料組成物(比較品1)480gを得た。比較品1の比容積は1.8ml/gであった。
Comparative Example 1
In Example 1, 480 g of a paste composition (Comparative Product 1) was obtained in the same manner as in Example 1 except that diglycerin monostearate was not dissolved in ion-exchanged water and was added to the powder portion. The specific volume of Comparative Product 1 was 1.8 ml / g.

比較例2
実施例1において、モノステアリン酸ジグリセリンをイオン交換水に溶解せず、粉部に配合する以外は実施例1と同様にして糊料組成物(比較品2)480gを得た。比較品2の比容積は3.0ml/gであった。
本発明品1〜10と比較品1、2の糊料組成物の配合表を表1に示す。
Comparative Example 2
In Example 1, 480 g of a paste composition (Comparative Product 2) was obtained in the same manner as in Example 1 except that diglycerin monostearate was not dissolved in ion-exchanged water and was added to the powder portion. The specific volume of Comparative Product 2 was 3.0 ml / g.
Table 1 shows the composition table of the paste compositions of the products 1 to 10 of the present invention and the paste compositions of the comparative products 1 and 2.

Figure 0006766105
Figure 0006766105

試験例1
低回転ディスパー(特殊機加工業製)を使用し、20℃のイオン交換水99gに対して、本発明品1〜10と比較品1、2の糊料組成物1gを600r/minで撹拌中に一気に投入し30秒間撹拌を続けた。
撹拌直後の溶液を目視観察して分散性を評価し、ダマにならず分散するものを5点、小さなダマが少数見られるものを4点、小さなダマが多数見られるものを3点、大きめのダマができているものを2点、大きなダマができて分散できていないものを1点、として評価した。
その後、静置して2分、5分、10分、30分経過時点の粘度をB型粘度計(東京計器製:回転速度12r/min、30秒後、No.3ローター)で測定した。測定結果は、30分後の粘度測定結果を100%として“測定結果÷30分後の粘度×100”で粘度到達率の100分率で表した。測定結果を表2に示す。
また、粘度発現性の速さを5点:2分でピーク粘度の90%以上に達する、4点:5分でピーク粘度の90%以上に達する、3点:10分でピーク粘度の90%以上に達する、2点:10分経過してもピーク粘度の90%に達しない、1点:ピーク粘度が明らかに低く粘度が発現していない、として評価した。分散性と粘度発現性の評価結果を表3に示す。
Test Example 1
Using a low-speed dispar (manufactured by a special machine processing industry), 1 g of the paste composition of the products 1 to 10 of the present invention and the paste compositions of the comparative products 1 and 2 is being stirred at 600 r / min with respect to 99 g of ion-exchanged water at 20 ° C. The mixture was poured at once and stirred for 30 seconds.
The dispersibility was evaluated by visually observing the solution immediately after stirring, and 5 points were for those that dispersed without becoming lumps, 4 points were for those with a small number of small lumps, and 3 points were for those with many small lumps. Those with lumps were evaluated as 2 points, and those with large lumps that could not be dispersed were evaluated as 1 point.
Then, the viscosity at the time when 2 minutes, 5 minutes, 10 minutes, and 30 minutes had passed after standing still was measured with a B-type viscometer (manufactured by Tokyo Keiki Co., Ltd .: rotation speed 12 r / min, 30 seconds later, No. 3 rotor). The measurement result was expressed as 100% of the viscosity arrival rate by "measurement result ÷ viscosity after 30 minutes × 100" with the viscosity measurement result after 30 minutes as 100%. The measurement results are shown in Table 2.
In addition, the speed of viscosity development reaches 90% or more of the peak viscosity at 5 points: 2 minutes, reaches 90% or more of the peak viscosity at 4 points: 5 minutes, and 90% of the peak viscosity at 3 points: 10 minutes. When the above was reached, 2 points: 90% of the peak viscosity was not reached even after 10 minutes had passed, and 1 point: the peak viscosity was clearly low and the viscosity was not developed. Table 3 shows the evaluation results of dispersibility and viscosity development.

Figure 0006766105
Figure 0006766105

Figure 0006766105
Figure 0006766105

表2、3より明らかなように本発明品1〜8、10では分散性が優れ、ダマの発生もほとんどなく均一に分散し粘度発現率も5分後までにはピーク粘度の90%以上に達し、素早い粘度発現性が実現された。
これに比べ比較品1及び2は表面改質がされておらず分散性が劣り、ダマが多量に発生して粘度の発現速度も遅い結果となった。
As is clear from Tables 2 and 3, the products 1 to 8 and 10 of the present invention have excellent dispersibility, are uniformly dispersed with almost no lumps, and the viscosity expression rate is 90% or more of the peak viscosity by 5 minutes. Achieved and quick viscosity development was realized.
Compared with this, Comparative Products 1 and 2 were not surface-modified and had poor dispersibility, a large amount of lumps were generated, and the rate of viscosity development was slow.

実施例11
70℃のイオン交換水100gにモノステアリン酸ジグリセリン(太陽化学株式会社製)0.25gと塩化カリウム(後藤化学株式会社製)25gを撹拌分散しバインダー溶液の調製を行った。キサンタンガム(太陽化学株式会社製)500gを流動状態に調整し、バインダー溶液125.25gを噴霧後、乾燥して糊料組成物(本発明品11)510gを得た。本発明品11の比容積は2.1ml/gであった。
Example 11
A binder solution was prepared by stirring and dispersing 0.25 g of diglycerin monostearate (manufactured by Taiyo Kagaku Co., Ltd.) and 25 g of potassium chloride (manufactured by Goto Chemical Co., Ltd.) in 100 g of ion-exchanged water at 70 ° C. 500 g of xanthan gum (manufactured by Taiyo Kagaku Co., Ltd.) was adjusted to a fluid state, 125.25 g of a binder solution was sprayed, and then dried to obtain 510 g of a paste composition (product 11 of the present invention). The specific volume of the product 11 of the present invention was 2.1 ml / g.

実施例12
実施例11において、モノステアリン酸ジグリセリンをモノステアリン酸ペンタグリセリン(太陽化学株式会社製)に変更する以外は実施例11と同様にして、糊料組成物(本発明品12)510gを得た。本発明品12の比容積は2.0ml/gであった。
Example 12
In Example 11, 510 g of a paste composition (Product 12 of the present invention) was obtained in the same manner as in Example 11 except that diglycerin monostearate was changed to pentaglycerin monostearate (manufactured by Taiyo Kagaku Co., Ltd.). .. The specific volume of the product 12 of the present invention was 2.0 ml / g.

実施例13
実施例11において、モノステアリン酸ジグリセリンをモノオレイン酸ペンタグリセリン(太陽化学株式会社製)に変更する以外は実施例11と同様にして、糊料組成物(本発明品13)510gを得た。本発明品13の比容積は2.1ml/gであった。
Example 13
In Example 11, 510 g of a paste composition (Product 13 of the present invention) was obtained in the same manner as in Example 11 except that diglycerin monostearate was changed to pentaglycerin monooleate (manufactured by Taiyo Kagaku Co., Ltd.). .. The specific volume of the product 13 of the present invention was 2.1 ml / g.

実施例14
実施例11において、モノステアリン酸ジグリセリンをジアセチル酒石酸モノステアリン酸グリセリン(太陽化学株式会社製)に変更する以外は実施例11と同様にして、糊料組成物(本発明品14)505gを得た。本発明品14の比容積は2.1ml/gであった。
Example 14
In Example 11, 505 g of a paste composition (Product 14 of the present invention) was obtained in the same manner as in Example 11 except that diglycerin monostearate was changed to glycerin monostearate diacetyltartarate (manufactured by Taiyo Kagaku Co., Ltd.). It was. The specific volume of the product 14 of the present invention was 2.1 ml / g.

実施例15
実施例11において、モノステアリン酸ジグリセリンを自己乳化型ステアリン酸モノ・ジグリセリド(太陽化学株式会社製)に変更する以外は実施例11と同様にして、糊料組成物(本発明品15)510gを得た。本発明品15の比容積は2.0ml/gであった。
Example 15
In Example 11, 510 g of a paste composition (Product 15 of the present invention) was obtained in the same manner as in Example 11 except that diglycerin monostearate was changed to self-emulsifying mono-diglyceride stearate (manufactured by Taiyo Kagaku Co., Ltd.). Got The specific volume of the product 15 of the present invention was 2.0 ml / g.

実施例16
70℃のイオン交換水100gにモノステアリン酸ジグリセリン(太陽化学株式会社製)0.25gと塩化カリウム(後藤化学株式会社製)5gを撹拌分散しバインダー溶液の調製を行った。キサンタンガム(太陽化学株式会社製)500gを流動状態に調整し、バインダー溶液105.25gを噴霧後、乾燥して糊料組成物(本発明品16)490gを得た。本発明品16の比容積は1.8ml/gであった。
Example 16
A binder solution was prepared by stirring and dispersing 0.25 g of diglycerin monostearate (manufactured by Taiyo Kagaku Co., Ltd.) and 5 g of potassium chloride (manufactured by Goto Kagaku Co., Ltd.) in 100 g of ion-exchanged water at 70 ° C. 500 g of xanthan gum (manufactured by Taiyo Kagaku Co., Ltd.) was adjusted to a fluid state, 105.25 g of a binder solution was sprayed, and then dried to obtain 490 g of a paste composition (product 16 of the present invention). The specific volume of the product 16 of the present invention was 1.8 ml / g.

実施例17
70℃のイオン交換水200gにモノステアリン酸ジグリセリン(太陽化学株式会社製)0.25gと塩化カリウム(後藤化学株式会社製)50gを撹拌分散しバインダー溶液の調製を行った。キサンタンガム(太陽化学株式会社製)500gを流動状態に調整し、バインダー溶液250.25gを噴霧後、乾燥して糊料組成物(本発明品17)530gを得た。本発明品17の比容積は2.2ml/gであった。
Example 17
A binder solution was prepared by stirring and dispersing 0.25 g of diglycerin monostearate (manufactured by Taiyo Kagaku Co., Ltd.) and 50 g of potassium chloride (manufactured by Goto Chemical Co., Ltd.) in 200 g of ion-exchanged water at 70 ° C. 500 g of xanthan gum (manufactured by Taiyo Kagaku Co., Ltd.) was adjusted to a fluid state, 250.25 g of a binder solution was sprayed, and then dried to obtain 530 g of a paste composition (product 17 of the present invention). The specific volume of the product 17 of the present invention was 2.2 ml / g.

実施例18
70℃のイオン交換水200gにモノステアリン酸ジグリセリン(太陽化学株式会社製)0.25gと塩化カリウム(後藤化学株式会社製)25gとキサンタンガム(太陽化学株式会社製)0.5gを撹拌分散しバインダー溶液の調製を行った。キサンタンガム(太陽化学株式会社製)500gを流動状態に調整し、バインダー溶液225.75gを噴霧後、乾燥して糊料組成物(本発明品18)500gを得た。本発明品18の比容積は3.2ml/gであった。
Example 18
0.25 g of diglycerin monostearate (manufactured by Taiyo Kagaku Co., Ltd.), 25 g of potassium chloride (manufactured by Goto Kagaku Co., Ltd.) and 0.5 g of xanthan gum (manufactured by Taiyo Kagaku Co., Ltd.) were stirred and dispersed in 200 g of ion-exchanged water at 70 ° C. A binder solution was prepared. 500 g of xanthan gum (manufactured by Taiyo Kagaku Co., Ltd.) was adjusted to a fluid state, and 225.75 g of a binder solution was sprayed and then dried to obtain 500 g of a paste composition (product 18 of the present invention). The specific volume of the product 18 of the present invention was 3.2 ml / g.

比較例3
実施例11において、モノステアリン酸ジグリセリンと塩化カリウムをイオン交換水に溶解せず、粉部に配合する以外は実施例11と同様にして糊料組成物(比較品3)495gを得た。比較品3の比容積は2.1ml/gであった。
本発明品10〜18と比較品3の糊料組成物の配合表を表4に示す。
Comparative Example 3
In Example 11, 495 g of a paste composition (Comparative Product 3) was obtained in the same manner as in Example 11 except that diglycerin monostearate and potassium chloride were not dissolved in ion-exchanged water and were blended in the powder portion. The specific volume of Comparative Product 3 was 2.1 ml / g.
Table 4 shows the composition table of the paste composition of the products 10 to 18 of the present invention and the comparative product 3.

Figure 0006766105
Figure 0006766105

試験例2
低回転ディスパー(特殊機加工業製)を使用し、20℃のイオン交換水99gに対して、本発明品11〜18と比較品3の糊料組成物1gを600r/minで撹拌中に一気に投入し30秒間撹拌を続けた。撹拌直後の溶液を目視観察して分散性を評価し、ダマにならず分散するものを5点、小さなダマが少数見られるものを4点、小さなダマが多数見られるものを3点、大きめのダマができているものを2点、大きなダマができて分散できていないものを1点、として評価した。
その後、静置して2分、5分、10分、30分経過時点の粘度をB型粘度計(東京計器製:回転速度12r/min、30秒後、No.3ローター)で測定した。測定結果は、30分後の粘度測定結果を100%として“測定結果÷30分後の粘度×100”で粘度到達率の100分率で表した。測定結果を表5に示す。
また、粘度発現性の速さを5点:2分でピーク粘度の90%以上に達する、4点:5分でピーク粘度の90%以上に達する、3点:10分でピーク粘度の90%以上に達する、2点:10分経過してもピーク粘度の90%に達しない、1点:ピーク粘度が明らかに低く粘度が発現していない、として評価した。分散性と粘度発現性の評価結果を表6に示す。
Test Example 2
Using a low-speed disperser (manufactured by a special machine processing industry), 1 g of the paste composition of the products 11 to 18 of the present invention and the paste composition of the comparative product 3 was stirred at 600 r / min at once with respect to 99 g of ion-exchanged water at 20 ° C. It was added and stirring was continued for 30 seconds. The dispersibility was evaluated by visually observing the solution immediately after stirring, and 5 points were for those that dispersed without becoming lumps, 4 points were for those with a small number of small lumps, and 3 points were for those with many small lumps. Those with lumps were evaluated as 2 points, and those with large lumps that could not be dispersed were evaluated as 1 point.
Then, the viscosity at the time when 2 minutes, 5 minutes, 10 minutes, and 30 minutes had passed after standing still was measured with a B-type viscometer (manufactured by Tokyo Keiki Co., Ltd .: rotation speed 12 r / min, 30 seconds later, No. 3 rotor). The measurement result was expressed as 100% of the viscosity arrival rate by "measurement result ÷ viscosity after 30 minutes × 100" with the viscosity measurement result after 30 minutes as 100%. The measurement results are shown in Table 5.
In addition, the speed of viscosity development reaches 90% or more of the peak viscosity at 5 points: 2 minutes, reaches 90% or more of the peak viscosity at 4 points: 5 minutes, and 90% of the peak viscosity at 3 points: 10 minutes. When the above was reached, 2 points: 90% of the peak viscosity was not reached even after 10 minutes had passed, and 1 point: the peak viscosity was clearly low and the viscosity was not developed. Table 6 shows the evaluation results of dispersibility and viscosity development.

Figure 0006766105
Figure 0006766105

Figure 0006766105
Figure 0006766105

表6、7より明らかなように本発明品11〜17では分散性が優れ、ダマの発生もほとんどなく均一に分散し粘度発現率も5分後までにはピーク粘度の90%以上に達し、素早い粘度発現性が実現された。糊料に乳化剤と金属塩をあわせて被覆することで分散性がさらに向上することが確認できる結果となった。
これに比べ比較品3は表面改質がされておらず分散性が劣り、ダマが多量に発生して粘度の発現速度も遅い結果となった。
As is clear from Tables 6 and 7, the products 11 to 17 of the present invention have excellent dispersibility, are uniformly dispersed with almost no lumps, and the viscosity development rate reaches 90% or more of the peak viscosity by 5 minutes. Quick viscosity development was realized. It was confirmed that the dispersibility was further improved by coating the paste with an emulsifier and a metal salt.
Compared to this, Comparative Product 3 was not surface-modified and had poor dispersibility, and a large amount of lumps were generated, resulting in a slow rate of viscosity development.

実施例19
実施例1で調製した糊料組成物30gとデキストリン(DE=12)70gを混合し、糊料組成物(本発明品19)100gを得た。
Example 19
30 g of the paste composition prepared in Example 1 and 70 g of dextrin (DE = 12) were mixed to obtain 100 g of the paste composition (Product 19 of the present invention).

実施例20
実施例1で調製した糊料組成物150gとデキストリン(DE=12)350gを流動状態に調整し、70℃の温湯50gを噴霧後、乾燥して糊料組成物(本発明品20)480gを得た。
Example 20
150 g of the paste composition prepared in Example 1 and 350 g of dextrin (DE = 12) are adjusted to a fluid state, 50 g of hot water at 70 ° C. is sprayed, and then dried to obtain 480 g of the paste composition (product 20 of the present invention). Obtained.

実施例21
70℃のイオン交換水50gにモノステアリン酸ジグリセリン(太陽化学株式会社製)0.25gを撹拌分散しバインダー溶液の調製を行った。カルボキシメチルセルロースナトリウム(太陽化学株式会社製)500gを流動状態に調整し、70℃のモノステアリン酸ジグリセリン溶液50.25gを噴霧後、乾燥して糊料組成物A 490gを得た。糊料組成物Aの比容積は1.6ml/gであった。
糊料組成物A 150gとデキストリン(DE=12)350gを流動状態に調整し、70℃の温湯50gを噴霧後、乾燥して糊料組成物(本発明品21)480gを得た。
Example 21
A binder solution was prepared by stirring and dispersing 0.25 g of diglycerin monostearate (manufactured by Taiyo Kagaku Co., Ltd.) in 50 g of ion-exchanged water at 70 ° C. 500 g of sodium carboxymethyl cellulose (manufactured by Taiyo Kagaku Co., Ltd.) was adjusted to a fluid state, 50.25 g of a diglycerin monostearate solution at 70 ° C. was sprayed, and then dried to obtain 490 g of a paste composition A. The specific volume of the paste composition A was 1.6 ml / g.
150 g of the paste composition A and 350 g of dextrin (DE = 12) were adjusted to a fluid state, 50 g of warm water at 70 ° C. was sprayed, and then dried to obtain 480 g of the paste composition (Product 21 of the present invention).

比較例4
比較例1で調製した糊料組成物30gとデキストリン(DE=12)70gを混合し、糊料組成物(比較品4)100gを得た。
Comparative Example 4
30 g of the paste composition prepared in Comparative Example 1 and 70 g of dextrin (DE = 12) were mixed to obtain 100 g of the paste composition (Comparative Product 4).

比較例5
比較例1で調製した糊料組成物150gとデキストリン(DE=12)350gを流動状態に調整し、70℃の温湯50gを噴霧後、乾燥して糊料組成物(比較品5)480gを得た。
Comparative Example 5
150 g of the paste composition prepared in Comparative Example 1 and 350 g of dextrin (DE = 12) are adjusted to a fluid state, 50 g of hot water at 70 ° C. is sprayed, and then dried to obtain 480 g of the paste composition (Comparative Product 5). It was.

比較例6
実施例21において、モノステアリン酸ジグリセリンをイオン交換水に溶解せず、粉部に配合する以外は実施例21と同様にして糊料組成物(比較品6)480gを得た。
本発明品19〜21と比較品4〜6の糊料組成物の配合表を表7に示す。
Comparative Example 6
In Example 21, 480 g of a paste composition (Comparative Product 6) was obtained in the same manner as in Example 21 except that diglycerin monostearate was not dissolved in ion-exchanged water and was added to the powder portion.
Table 7 shows the composition table of the paste compositions of the products 19 to 21 of the present invention and the products 4 to 6 of the comparative products.

Figure 0006766105
Figure 0006766105

試験例3
20℃のイオン交換水99gに対して、本発明品19〜21と比較品4〜6の糊料組成物1gを一気に投入して2秒静置した後にスパーテルを用いて10秒間手で撹拌し(3回転/秒)、撹拌後の溶液の状態を観察した。撹拌直後の溶液を目視観察して分散性を評価し、ダマにならず分散するものを5点、小さなダマが少数見られるものを4点、小さなダマが多数見られるものを3点、大きめのダマができているものを2点、大きなダマができて分散できていないものを1点、として評価した。
その後、静置して2分、5分、10分、30分経過時点の粘度をB型粘度計(東京計器製:回転速度12r/min、30秒後、No.3ローター)で測定した。測定結果は、30分後の粘度測定結果を100%として“測定結果÷30分後の粘度×100”で粘度到達率の100分率で表した。測定結果を表8に示す。
また、粘度発現性の速さを5点:2分でピーク粘度の90%以上に達する、4点:5分でピーク粘度の90%以上に達する、3点:10分でピーク粘度の90%以上に達する、2点:10分経過してもピーク粘度の90%に達しない、1点:ピーク粘度が明らかに低く粘度が発現していない、として評価した。分散性と粘度発現性の評価結果を表9に示す。
Test Example 3
To 99 g of ion-exchanged water at 20 ° C., 1 g of the paste composition of the products 19 to 21 of the present invention and the paste composition of the comparative products 4 to 6 was added at once, allowed to stand for 2 seconds, and then manually stirred with a spartel for 10 seconds. (3 rotations / sec), the state of the solution after stirring was observed. The dispersibility was evaluated by visually observing the solution immediately after stirring, and 5 points were for those that dispersed without becoming lumps, 4 points were for those with a small number of small lumps, and 3 points were for those with many small lumps. Those with lumps were evaluated as 2 points, and those with large lumps that could not be dispersed were evaluated as 1 point.
Then, the viscosity at the time when 2 minutes, 5 minutes, 10 minutes, and 30 minutes had passed after standing still was measured with a B-type viscometer (manufactured by Tokyo Keiki Co., Ltd .: rotation speed 12 r / min, 30 seconds later, No. 3 rotor). The measurement result was expressed as 100% of the viscosity arrival rate by "measurement result ÷ viscosity after 30 minutes × 100" with the viscosity measurement result after 30 minutes as 100%. The measurement results are shown in Table 8.
In addition, the speed of viscosity development reaches 90% or more of the peak viscosity at 5 points: 2 minutes, reaches 90% or more of the peak viscosity at 4 points: 5 minutes, and 90% of the peak viscosity at 3 points: 10 minutes. When the above was reached, 2 points: 90% of the peak viscosity was not reached even after 10 minutes had passed, and 1 point: the peak viscosity was clearly low and the viscosity was not developed. Table 9 shows the evaluation results of dispersibility and viscosity development.

Figure 0006766105
Figure 0006766105

Figure 0006766105
Figure 0006766105

表8、9より明らかなように本発明品19〜21では分散性が優れ、ダマの発生もほとんどなく均一に分散し粘度発現率も5分後までにはピーク粘度の90%以上に達し、素早い粘度発現性が実現された。
これに比べ比較品4〜6は表面改質がされておらず分散性が劣り、ダマが多量に発生した。
糊料表面に乳化剤を被覆することにより糊料の表面が改質し、水への分散性が著しく向上し、分散した糊料組成物は確実に溶解するが、糊料に乳化剤を粉体混合する工程では粘度発現性の向上効果は見られない。
As is clear from Tables 8 and 9, the products 19 to 21 of the present invention have excellent dispersibility, are uniformly dispersed with almost no lumps, and the viscosity development rate reaches 90% or more of the peak viscosity by 5 minutes. Quick viscosity development was realized.
Compared with this, Comparative Products 4 to 6 were not surface-modified and had poor dispersibility, and a large amount of lumps were generated.
By coating the surface of the paste with an emulsifier, the surface of the paste is modified, the dispersibility in water is significantly improved, and the dispersed paste composition is surely dissolved, but the emulsifier is powder-mixed with the paste. No effect of improving viscosity development is observed in the process.

実施例22
実施例11で調製した糊料組成物31.515gとデキストリン(DE=12)68.485gを混合し、糊料組成物(本発明品22)100gを得た。
Example 22
31.515 g of the paste composition prepared in Example 11 and 68.485 g of dextrin (DE = 12) were mixed to obtain 100 g of the paste composition (product 22 of the present invention).

実施例23
実施例11で調製した糊料組成物157.575gとデキストリン(DE=12)342.425gを流動状態に調整し、70℃の温湯50gを噴霧後、乾燥して糊料組成物(本発明品23)480gを得た。
Example 23
157.575 g of the paste composition prepared in Example 11 and 342.425 g of dextrin (DE = 12) were adjusted to a fluid state, sprayed with 50 g of hot water at 70 ° C., and dried to dry the paste composition (the product of the present invention). 23) 480 g was obtained.

実施例24
70℃のイオン交換水100gにグァーガム酵素分解物(太陽化学株式会社製)32.5gを撹拌分散しバインダー溶液の調製を行った。実施例11で調製した糊料組成物367.675gとデキストリン(DE=12)99.825gを流動状態に調整し、70℃のバインダー溶液132.5gを噴霧後、乾燥して糊料組成物(本発明品24)480gを得た。
Example 24
A binder solution was prepared by stirring and dispersing 32.5 g of a guar gum enzymatic decomposition product (manufactured by Taiyo Kagaku Co., Ltd.) in 100 g of ion-exchanged water at 70 ° C. 367.675 g of the paste composition prepared in Example 11 and 99.825 g of dextrin (DE = 12) were adjusted to a fluid state, and 132.5 g of a binder solution at 70 ° C. was sprayed and then dried to obtain the paste composition (the paste composition (DE = 12). The product of the present invention 24) 480 g was obtained.

実施例25
70℃のイオン交換水100gにモノステアリン酸ジグリセリン(太陽化学株式会社製)0.25gと塩化カリウム25gを撹拌分散しバインダー溶液の調製を行った。キサンタンガム(太陽化学株式会社製)500gとデキストリン(DE=12)142.6gを流動状態に調整し、70℃のバインダー溶液125.25gを噴霧後、乾燥して糊料組成物B 630gを得た。糊料組成物Bの比容積は2.1ml/gであった。
70℃のイオン交換水100gにグァーガム酵素分解物(太陽化学株式会社製)32.5gを撹拌分散しバインダー溶液の調製を行った。糊料組成物B 467.5gを流動状態に調整し、70℃のバインダー溶液132.5gを噴霧後、乾燥して糊料組成物(本発明品25)480gを得た。
Example 25
A binder solution was prepared by stirring and dispersing 0.25 g of diglycerin monostearate (manufactured by Taiyo Kagaku Co., Ltd.) and 25 g of potassium chloride in 100 g of ion-exchanged water at 70 ° C. 500 g of xanthan gum (manufactured by Taiyo Kagaku Co., Ltd.) and 142.6 g of dextrin (DE = 12) were adjusted to a fluid state, 125.25 g of a binder solution at 70 ° C. was sprayed, and then dried to obtain 630 g of paste composition B. .. The specific volume of the paste composition B was 2.1 ml / g.
A binder solution was prepared by stirring and dispersing 32.5 g of a guar gum enzymatic decomposition product (manufactured by Taiyo Kagaku Co., Ltd.) in 100 g of ion-exchanged water at 70 ° C. 467.5 g of the paste composition B was adjusted to a fluid state, 132.5 g of the binder solution at 70 ° C. was sprayed, and then dried to obtain 480 g of the paste composition (product 25 of the present invention).

実施例26
70℃のイオン交換水100gにグァーガム酵素分解物(太陽化学株式会社製)32.5gを撹拌分散しバインダー溶液の調製を行った。実施例1で調製した糊料組成物350.175gとデキストリン(DE=12)117.325gを流動状態に調整し、70℃のバインダー溶液132.5gを噴霧後、乾燥して糊料組成物(本発明品26)485gを得た。
Example 26
A binder solution was prepared by stirring and dispersing 32.5 g of a guar gum enzymatic decomposition product (manufactured by Taiyo Kagaku Co., Ltd.) in 100 g of ion-exchanged water at 70 ° C. 350.175 g of the paste composition prepared in Example 1 and 117.325 g of dextrin (DE = 12) were adjusted to a fluid state, and 132.5 g of a binder solution at 70 ° C. was sprayed and then dried to obtain the paste composition (the paste composition (DE = 12). The product of the present invention 26) 485 g was obtained.

実施例27
70℃のイオン交換水100gに塩化カリウム(後藤化学株式会社製)10gとグァーガム酵素分解物(太陽化学株式会社製)40gを撹拌分散しバインダー溶液の調製を行った。実施例1で調製した糊料組成物367.675gとデキストリン(DE=12)99.825gを流動状態に調整し、70℃のバインダー溶液150gを噴霧後、乾燥して糊料組成物(本発明品27)490gを得た。
Example 27
A binder solution was prepared by stirring and dispersing 10 g of potassium chloride (manufactured by Goto Chemical Co., Ltd.) and 40 g of a guar gum enzymatic decomposition product (manufactured by Taiyo Kagaku Co., Ltd.) in 100 g of ion-exchanged water at 70 ° C. The paste composition prepared in Example 1 (367.675 g) and 99.825 g of dextrin (DE = 12) were adjusted to a fluid state, sprayed with 150 g of a binder solution at 70 ° C., and dried to dry the paste composition (the present invention). Product 27) 490 g was obtained.

比較例7
比較例3で調製した糊料組成物31.515gとデキストリン(DE=12)68.485gを混合し、糊料組成物(比較品7)100gを得た。
Comparative Example 7
31.515 g of the paste composition prepared in Comparative Example 3 and 68.485 g of dextrin (DE = 12) were mixed to obtain 100 g of the paste composition (comparative product 7).

比較例8
比較例3で調製した糊料組成物157.575gとデキストリン(DE=12)342.425gを流動状態に調整し、70℃の温湯50gを噴霧後、乾燥して糊料組成物(比較品8)480gを得た。
Comparative Example 8
157.575 g of the paste composition prepared in Comparative Example 3 and 342.425 g of dextrin (DE = 12) were adjusted to a fluid state, sprayed with 50 g of hot water at 70 ° C., and dried to dry the paste composition (Comparative Product 8). ) 480 g was obtained.

比較例9
70℃のイオン交換水100gに塩化カリウム(後藤化学株式会社製)25gを撹拌分散しバインダー溶液の調製を行った。キサンタンガム(太陽化学株式会社製)500gを流動状態に調整し、70℃のバインダー溶液150gを噴霧後、乾燥して糊料組成物C 515gを得た。糊料組成物Cの比容積は2.2ml/gであった。
70℃のイオン交換水100gにグァーガム酵素分解物(太陽化学株式会社製)32.5gを撹拌分散しバインダー溶液の調製を行った。糊料組成物C 367.5gとデキストリン(DE=12)100gを流動状態に調整し、70℃のバインダー溶液132.5gを噴霧後、乾燥して糊料組成物(比較品9)490gを得た。
本発明品22〜27と比較品7〜9の糊料組成物の配合表を表10に示す。
Comparative Example 9
A binder solution was prepared by stirring and dispersing 25 g of potassium chloride (manufactured by Goto Chemical Co., Ltd.) in 100 g of ion-exchanged water at 70 ° C. 500 g of xanthan gum (manufactured by Taiyo Kagaku Co., Ltd.) was adjusted to a fluid state, 150 g of a binder solution at 70 ° C. was sprayed, and then dried to obtain 515 g of a paste composition C. The specific volume of the paste composition C was 2.2 ml / g.
A binder solution was prepared by stirring and dispersing 32.5 g of a guar gum enzymatic decomposition product (manufactured by Taiyo Kagaku Co., Ltd.) in 100 g of ion-exchanged water at 70 ° C. 367.5 g of the paste composition C and 100 g of dextrin (DE = 12) are adjusted to a fluid state, 132.5 g of a binder solution at 70 ° C. is sprayed, and then dried to obtain 490 g of the paste composition (comparative product 9). It was.
Table 10 shows the composition table of the paste compositions of the products 22 to 27 of the present invention and the paste products 7 to 9 of the comparative products.

Figure 0006766105
Figure 0006766105

試験例4
20℃のイオン交換水99gに対して、本発明品22〜27と比較品7〜9の糊料組成物1gを一気に投入して2秒静置した後にスパーテルを用いて10秒間手で撹拌し(3回転/秒)、撹拌後の溶液の状態を観察した。撹拌直後の溶液を目視観察して分散性を評価し、ダマにならず分散するものを5点、小さなダマが少数見られるものを4点、小さなダマが多数見られるものを3点、大きめのダマができているものを2点、大きなダマができて分散できていないものを1点、として評価した。
その後、静置して2分、5分、10分、30分経過時点の粘度をB型粘度計(東京計器製:回転速度12r/min、30秒後、No.3ローター)で測定した。測定結果は、30分後の粘度測定結果を100%として“測定結果÷30分後の粘度×100”で粘度到達率の100分率で表した。測定結果を表11に示す。
また、粘度発現性の速さを5点:2分でピーク粘度の90%以上に達する、4点:5分でピーク粘度の90%以上に達する、3点:10分でピーク粘度の90%以上に達する、2点:10分経過してもピーク粘度の90%に達しない、1点:ピーク粘度が明らかに低く粘度が発現していない、として評価した。分散性と粘度発現性の評価結果を表12に示す。
Test Example 4
To 99 g of ion-exchanged water at 20 ° C., 1 g of the paste composition of the products 22 to 27 of the present invention and the paste composition of the comparative products 7 to 9 was added at once, allowed to stand for 2 seconds, and then manually stirred with a spartel for 10 seconds. (3 rotations / sec), the state of the solution after stirring was observed. The dispersibility was evaluated by visually observing the solution immediately after stirring, and 5 points were for those that dispersed without becoming lumps, 4 points were for those with a small number of small lumps, and 3 points were for those with many small lumps. Those with lumps were evaluated as 2 points, and those with large lumps that could not be dispersed were evaluated as 1 point.
Then, the viscosity at the time when 2 minutes, 5 minutes, 10 minutes, and 30 minutes had passed after standing still was measured with a B-type viscometer (manufactured by Tokyo Keiki Co., Ltd .: rotation speed 12 r / min, 30 seconds later, No. 3 rotor). The measurement result was expressed as 100% of the viscosity arrival rate by "measurement result ÷ viscosity after 30 minutes × 100" with the viscosity measurement result after 30 minutes as 100%. The measurement results are shown in Table 11.
In addition, the speed of viscosity development reaches 90% or more of the peak viscosity at 5 points: 2 minutes, reaches 90% or more of the peak viscosity at 4 points: 5 minutes, and 90% of the peak viscosity at 3 points: 10 minutes. When the above was reached, 2 points: 90% of the peak viscosity was not reached even after 10 minutes had passed, and 1 point: the peak viscosity was clearly low and the viscosity was not developed. Table 12 shows the evaluation results of dispersibility and viscosity development.

Figure 0006766105
Figure 0006766105

Figure 0006766105
Figure 0006766105

表11、12より明らかなように糊料を乳化剤と金属塩で被覆した本発明品22〜25では、糊料含量が格段に多い処方系においても優れた分散性を有し、ダマの発生もなく均一に分散し粘度発現率も2分後にはピーク粘度の90%以上に達し、素早い粘度発現性が実現された。乳化剤のみで被覆した糊料を大量に配合した処方系である本発明品26では分散性がやや劣り、粘度発現速度もやや劣る結果となった。塩化カリウムを糊料の被覆に用いずに使用した本発明品27はダマの発生も良好なレベルに抑制されほぼ均一に分散し、粘度発現率も5分後にはピーク粘度の90%以上に達し、良好な粘度発現性が実現された。
これに比べ比較例7、8は表面改質がされておらず分散性が劣り、ダマが多量に発生した。塩化カリウムのみで糊料表面を改質した比較品9も糊料含量が格段に多い処方系においては良好な分散性を有するには至らず、ダマが多量に発生した。
糊料表面に乳化剤と金属塩をあわせて被覆することにより、特に糊料含量が格段に多い処方系における水への分散性が著しく向上し、分散した糊料組成物は確実に溶解することが確認される結果となった。
As is clear from Tables 11 and 12, the products 22 to 25 of the present invention in which the paste is coated with an emulsifier and a metal salt have excellent dispersibility even in a formulation system having a significantly large paste content, and lumps are also generated. The viscosity was evenly dispersed, and the viscosity development rate reached 90% or more of the peak viscosity after 2 minutes, and quick viscosity development was realized. In the product 26 of the present invention, which is a formulation system containing a large amount of a paste coated only with an emulsifier, the dispersibility was slightly inferior and the viscosity development rate was also slightly inferior. The product 27 of the present invention, which used potassium chloride without using potassium chloride for coating the paste, was suppressed to a good level of lumps and dispersed almost uniformly, and the viscosity development rate reached 90% or more of the peak viscosity after 5 minutes. , Good viscosity development was realized.
Compared with this, Comparative Examples 7 and 8 were not surface-modified and had poor dispersibility, and a large amount of lumps were generated. The comparative product 9 in which the surface of the paste was modified only with potassium chloride did not have good dispersibility in a formulation system having a significantly high paste content, and a large amount of lumps were generated.
By coating the surface of the paste with an emulsifier and a metal salt, the dispersibility in water is remarkably improved, especially in a formulation system having a significantly high paste content, and the dispersed paste composition can be reliably dissolved. The result was confirmed.

本発明により、分散性、溶解性に優れた糊料組成物を提供することができるため、攪拌・溶解装置をもたず強い攪拌が得られない製造工場の作業性の改善や、特に咀嚼・嚥下困難者用補助組成物として高齢の患者や介護者が簡便に咀嚼・嚥下困難者用食品を調製することが可能となり、産業上の貢献度は非常に高いものである。
INDUSTRIAL APPLICABILITY Since the present invention can provide a paste composition having excellent dispersibility and solubility, it is possible to improve workability in a manufacturing factory where strong stirring cannot be obtained without a stirring / dissolving device, and particularly for chewing / dissolving. As an auxiliary composition for people with dysphagia, elderly patients and caregivers can easily prepare foods for people with dysphagia, which makes a great contribution to the industry.

Claims (4)

乳化剤と金属塩を水に添加し、乳化剤が分散したバインダー溶液を糊料に噴霧し乾燥させて糊料を被覆する工程を有することを特徴とする、被覆された糊料を含有する糊料組成物の製造方法であって、前記金属塩が塩化カリウムであり、前記乳化剤が、グリセリン脂肪酸エステル、ジグリセリン脂肪酸エステル、ペンタグリセリン脂肪酸エステル、及び有機酸モノグリセリドからなる群より選ばれる少なくとも1種を含み、糊料100重量部に対して乳化剤0.01〜0.5重量部を噴霧し、糊料100重量部に対して塩化カリウム1〜10重量部を噴霧する、手攪拌で使用可能な糊料組成物の製造方法。 A paste containing a coated paste, which comprises a step of adding an emulsifier and a metal salt to water, spraying a binder solution in which the emulsifier is dispersed onto the paste, drying the paste, and coating the paste. A method for producing a composition, wherein the metal salt is potassium chloride and the emulsifier is at least one selected from the group consisting of glycerin fatty acid ester, diglycerin fatty acid ester, pentaglycerin fatty acid ester, and organic acid monoglyceride. A glue that can be used by hand stirring, which comprises spraying 0.01 to 0.5 parts by weight of an emulsifier on 100 parts by weight of the paste and 1 to 10 parts by weight of potassium chloride on 100 parts by weight of the paste. A method for producing an emulsifier composition. 糊料が、キサンタンガム及び/又はカルボキシメチルセルロースカルシウムを含む、請求項1記載の製造方法。 The production method according to claim 1, wherein the paste comprises xanthan gum and / or calcium carboxymethyl cellulose. 糊料組成物が、さらに賦形剤を含有する、請求項1又は2記載の製造方法。 The production method according to claim 1 or 2, wherein the paste composition further contains an excipient. 賦形剤が、デキストリン、澱粉及び糖類からなる群より選ばれる少なくとも1種である、請求項3記載の製造方法。 The production method according to claim 3, wherein the excipient is at least one selected from the group consisting of dextrin, starch and sugar.
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