JP2004350680A - Gelling agent composition and gelatinous composition for food suitable for person with ingestion/swallowing difficulty - Google Patents

Gelling agent composition and gelatinous composition for food suitable for person with ingestion/swallowing difficulty Download PDF

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JP2004350680A
JP2004350680A JP2003400605A JP2003400605A JP2004350680A JP 2004350680 A JP2004350680 A JP 2004350680A JP 2003400605 A JP2003400605 A JP 2003400605A JP 2003400605 A JP2003400605 A JP 2003400605A JP 2004350680 A JP2004350680 A JP 2004350680A
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gum
swallowing
foods
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Takahiro Funemi
孝博 船見
Kazuhiro Kishimoto
一宏 岸本
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San Ei Gen FFI Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide foods having (1) excellent block forming property (cohesiveness of foods in the mouth), (2) slightly adhesive property in the oral cavity and larynx, and (3) excellent water holding property, suitable for a person with reduced ingestion/swallowing function such as a person with ingestion/swallowing difficulties or an aged person. <P>SOLUTION: The foods for persons with ingestion/swallowing difficulties have the optimum properties for ingestion/swallowing by formulating (a) at least one kind selected from guar gum, tara gum or locust bean gum, (b) xanthan gum and/or κ-carrageenan, and (c) gum arabic and/or water-soluble soybean polysaccharides. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、ゲル状組成物、特には、咀嚼・嚥下障害者や高齢者等の、咀嚼又は嚥下機能が低下している者が、安全且つ容易に摂食できるように調製されたゲル食品ならびに既存食品にかかる性質を付与する目的で添加される咀嚼・嚥下補助用のゲル化剤組成物に関する。   The present invention is a gel composition, in particular, a chewing or swallowing disorder or elderly people, such as those with reduced chewing or swallowing function, gel food prepared so that it can be safely and easily eaten, The present invention relates to a gelling agent composition for chewing / swallowing assistance added for the purpose of imparting such properties to existing foods.

詳細には、咀嚼・嚥下障害者や高齢者が食品本来の香味や食感を楽しみ、且つ安全に嚥下でき、更に常温で長時間放置しても、優れた咀嚼・嚥下適性が維持されているゲル食品ならびに既存の食品にかかる性質を付与する目的で添加される咀嚼・嚥下補助用のゲル化剤組成物に関する。   In detail, people with mastication and dysphagia and elderly people can enjoy the original flavor and texture of food and swallow safely, and even if left at room temperature for a long time, excellent chewing and swallowing suitability is maintained. The present invention relates to a gel food composition and a gelling agent composition for assisting chewing and swallowing which is added for imparting such properties to existing foods.

高齢者の増加に伴い、食物を噛み砕き飲み込むという一連の動作に障害をもつ、いわゆる咀嚼・嚥下障害者が増加している。加えて、脳血管障害、腫瘍等の疾病が咀嚼・嚥下障害を引き起こす場合も多く、その増加を一層加速させている。これら咀嚼・嚥下障害者は窒息や誤嚥肺炎を起こしやすいため、栄養摂取の方法を、経口から経管あるいは経静脈へと変えなければならないことが多い。経管あるいは経静脈栄養法の技術的進歩は目覚しく、咀嚼・嚥下障害者の栄養管理のうえでそれらが果たす役割は大きい。反面、経口的に食物を摂取できないという精神的苦痛を伴うため、QOL(Quality of Life)の改善という観点からみると、できるだけ「口から摂取できる食事」を工夫することが重要である。このような状況のもと、経口摂食が可能で食べる楽しみが得られ、かつ、摂食機能を向上させることが出来る嚥下障害者用の食品の開発が盛んに行われている。   As the number of elderly people increases, so-called masticatory and dysphagic persons who have an obstacle in a series of actions of chewing and swallowing food are increasing. In addition, diseases such as cerebrovascular disorders and tumors often cause mastication and dysphagia, and the increase is further accelerated. Since these masticatory and dysphagic persons are susceptible to suffocation and aspiration pneumonia, it is often necessary to change the nutritional intake method from oral to tube or vein. The technical advancement of tube or parenteral nutrition is remarkable and plays a large role in the nutritional management of masticatory and dysphagic patients. On the other hand, since it is accompanied by the mental pain of not being able to ingest food orally, it is important from the viewpoint of improving the quality of life (QOL) to devise a diet that can be consumed by mouth as much as possible. Under such circumstances, development of foods for people with dysphagia that can be orally ingested, can enjoy pleasure of eating, and can improve the eating function has been actively performed.

咀嚼・嚥下障害者に適した食品として、1)食塊形成性(口中での食品のまとまりやすさ)に優れること、2)口腔及び咽頭への付着性が少ないこと、及び3)保水性が高いことなどが挙げられ、このようなテクスチャー条件を満たす食品、あるいは既存食品にかかる性質を付与するためのゲル化剤、増粘剤の開発が種々検討されている。既存食品のテクスチャーを上記のごとく改良するゲル化剤、増粘剤としては、例えば、「キサンタンガム含有流動状食品」(特許文献1)にみられるキサンタンガム、「易嚥下補助組成物並びにこれを用いた食品組成物及び医薬品用組成物」(特許文献2)にみられるタラガムおよび/またはローカストビーンガムとキサンタンガムの併用、「嚥下補助食品」(特許文献3)にみられるローメトキシルペクチン、アルギン酸ナトリウムおよびカラギナンから選択される1種類または2種類以上のゲル化剤溶液とカルシウム溶液の併用、「液状食品粘稠化剤」(特許文献4)にみられるタピオカ澱粉又はバレイショ澱粉の使用、「ゲル状組成物及びその製造方法」(特許文献5)にみられる寒天及び/又はファーセルランとネイティブ型ジェランガムの併用、κ-カラギナンとキサンタンガム及び/又はネイティブ型ジェランガムの併用、およびジェランガムとグァーガム及び/又はローカストビーンガムの併用等が知られている。   As foods suitable for people with mastication and dysphagia, 1) excellent bolus formation (easiness of uniting food in the mouth), 2) low adhesion to the oral cavity and pharynx, and 3) water retention The development of a gelling agent and a thickening agent for imparting such properties to foods satisfying such texture conditions or existing foods has been studied. As a gelling agent and a thickening agent for improving the texture of an existing food as described above, for example, xanthan gum found in “Xanthan gum-containing fluid food” (Patent Document 1), “Easy swallowing auxiliary composition and its use” Combination of cod and / or locust bean gum and xanthan gum found in "food composition and pharmaceutical composition" (Patent Document 2), and low methoxyl pectin, sodium alginate and carrageenan found in "swallowing supplement" (Patent Document 3) A combination of one or more gelling agent solutions selected from the group consisting of a calcium solution and tapioca starch or potato starch found in "Liquid food thickening agent" (Patent Document 4), "gel composition" And / or production method thereof ”(Patent Document 5) and agar and / or furcellulane and native gela Combination of gums, .kappa.-carrageenan and xanthan gum and / or native gellan gum in combination, and combination or the like of gellan gum and guar gum and / or locust bean gum are known.

ゲル化剤や増粘剤を利用して、食品物性を咀嚼・嚥下しやすいものに改良するためには、素材の選択と使用量の設定が重要である。食品工業分野で汎用されているゲル化剤として、例えば脱アシル型ジェランガム、寒天、κ-カラギナンを挙げることができるが(特許文献5を参照)、これらは総じて脆い食感のゲルを形成し、一度破砕したゲルは再結着しにくい。また、脆さを低減するために低濃度で使用すると、離水が多くなるという問題がある。一方、キサンタンガム又はκ-カラギナンと、ローカストビーンガム又はタラガムを併用することにより(特許文献2参照)、低濃度でも保水性の高いゲルを調製することができる。しかし、この場合、ゲルの弾力が非常に強く、咀嚼しにくい食感となる。特許文献1に記載のキサンタンガム、特許文献3に記載のカルシウム反応性ゲル化剤溶液、及び特許文献4に記載のでん粉は、いずれも対象が液状食品であり、固形食品には適用できない。このように、咀嚼・嚥下困難者用食品の基盤となる素材及び素材の組み合わせは必ずしも多くない。   In order to improve the physical properties of foods by using a gelling agent or a thickener so that they can be easily chewed or swallowed, it is important to select the materials and set the amount of use. Examples of gelling agents widely used in the food industry field include deacylated gellan gum, agar, and κ-carrageenan (see Patent Document 5), which generally form a gel having a brittle texture, Once crushed gel is less likely to rebound. In addition, when used at a low concentration to reduce brittleness, there is a problem that water separation increases. On the other hand, by using xanthan gum or κ-carrageenan in combination with locust bean gum or cod gum (see Patent Document 2), a gel having high water retention even at a low concentration can be prepared. However, in this case, the elasticity of the gel is very strong and the texture becomes difficult to chew. The xanthan gum described in Patent Literature 1, the calcium-reactive gelling agent solution described in Patent Literature 3, and the starch described in Patent Literature 4 are all liquid foods and cannot be applied to solid foods. As described above, there are not necessarily many materials and combinations of materials that form the basis of foods for people with difficulty in chewing and swallowing.

特開平11-318356号公報JP-A-11-318356 特開2000-191553号公報JP 2000-191553 A 特開2000-325041号公報JP 2000-325041 A 特開平5-38262号公報JP-A-5-38262 特開2002-300854号公報JP-A-2002-300854

本発明は、上記事情に鑑みなされたもので、ゲル状組成物、特には、咀嚼・嚥下障害者や高齢者等の咀嚼・嚥下機能が低下した者に適したゲル状組成物、即ち、1)食塊形成性(口中での食品のまとまりやすさ)に優れ、2)口腔及び咽頭への付着性が少なく、3)保水性に優れたゲル状組成物を提供することを目的とする。   The present invention has been made in view of the above circumstances, and a gel composition, in particular, a gel composition suitable for those with reduced mastication and swallowing functions such as those with mastication and dysphagia and the elderly, ie, 1 An object of the present invention is to provide a gel composition which is excellent in bolus formation (easiness of uniting food in the mouth), has low adhesion to the oral cavity and pharynx, and has excellent water retention.

本発明者らは、上記課題を解決するために鋭意検討した結果、ゲル状組成物に、(a)グァーガム、タラガム及びローカストビーンガムから選ばれる少なくとも1種以上、(b)キサンタンガム及び/又はκ-カラギナン、及び(c)アラビアガム及び/又は水溶性大豆多糖類を含むことで、調製したゲル状組成物は、弱いゲル構造が構築されて、水のような液状食品の流動性が適度に抑制され、食塊の形成性がよく、且つ口腔及び咽頭への付着性が著しく小さいという、特に、咀嚼・嚥下に最適な特性のゲル状組成物となることを見いだした。   Means for Solving the Problems The present inventors have conducted intensive studies to solve the above-mentioned problems. As a result, the gel composition contains (a) at least one selected from guar gum, cod gum and locust bean gum, (b) xanthan gum and / or κ. -By containing carrageenan, and (c) gum arabic and / or water-soluble soybean polysaccharide, the prepared gel-like composition has a weak gel structure, so that the fluidity of liquid food such as water can be moderately adjusted. It has been found that it is a gel composition that is suppressed, has good bolus formation properties, and has extremely low adherence to the oral cavity and pharynx, and particularly has optimal properties for chewing and swallowing.

また、既存の食品に前記嚥下・咀嚼に適した特性を付与する目的で添加される咀嚼・嚥下補助用のゲル化剤組成物に、(a)グァーガム、タラガム及びローカストビーンガムから選ばれる少なくとも1種以上、(b)キサンタンガム及び/又はκ-カラギナン、及び(c)アラビアガム及び/又は水溶性大豆多糖類を含むことで、既存の食品を簡便な操作で嚥下・咀嚼に適したゲル食品とすることが出来ることを見いだした。   In addition, the gelling agent composition for chewing and swallowing assistance added for the purpose of imparting the above-mentioned properties suitable for swallowing and chewing to existing foods includes (a) at least one selected from guar gum, cod gum and locust bean gum. More than one species, containing (b) xanthan gum and / or κ-carrageenan, and (c) gum arabic and / or water-soluble soy polysaccharide to make existing foods a gel food suitable for swallowing and mastication with a simple operation I found what I could do.

なお、上記(a)〜(c)の3成分の混合比率、および上記3成分からなる組成物の食品への配合量によって、形成されるゲル状構造の硬さを自由に調節し、咀嚼・嚥下に適した物性を調製できることを見いだした。   In addition, the hardness of the gel-like structure formed is freely adjusted by the mixing ratio of the three components (a) to (c) and the amount of the composition comprising the three components in the food, so that chewing and chewing can be performed. It has been found that physical properties suitable for swallowing can be prepared.

本発明は、以下の態様を有するゲル状組成物及びゲル化剤組成物に関する;
項1.次の(a)〜(c)を含むことを特徴とするゲル状組成物;
(a)グァーガム、タラガム及びローカストビーンガムから選ばれる少なくとも1種以上
(b)キサンタンガム及び/又はκ-カラギナン
(c)アラビアガム及び/又は水溶性大豆多糖類
項2.項1記載の(a)、(b)、(c)の含有量について、(a)を0.01〜1重量%、(b)を0.01〜0.5重量%、及び(c)を0.01〜1重量%含有する、項1に記載のゲル状組成物。
項3.咀嚼・嚥下困難者用食品である、項1又は2に記載のゲル状組成物。
項4.次の(a)〜(c)を含むことを特徴とするゲル化剤組成物;
(a)グァーガム、タラガム及びローカストビーンガムから選ばれる少なくとも1種以上
(b)キサンタンガム及び/又はκ-カラギナン
(c)アラビアガム及び/又は水溶性大豆多糖類。
項5.項4記載の(a)、(b)、(c)の含有量について、(a)を0.5〜98重量%、(b)を0.5〜98重量%、及び(c)を0.5〜98重量%含有する、項4に記載のゲル化剤組成物。
項6.咀嚼・嚥下困難者用食品に使用される、項4又は5に記載のゲル化剤組成物。
The present invention relates to a gel composition and a gelling agent composition having the following aspects;
Item 1. A gel composition comprising the following (a) to (c);
(A) at least one selected from guar gum, cod gum and locust bean gum; (b) xanthan gum and / or κ-carrageenan; and (c) gum arabic and / or water-soluble soybean polysaccharide. About the content of (a), (b), and (c) of item 1, (a) is 0.01 to 1% by weight, (b) is 0.01 to 0.5% by weight, and (c) Item 1. The gel composition according to Item 1, comprising 0.01 to 1% by weight.
Item 3. Item 3. The gel composition according to Item 1 or 2, which is a food for people with difficulty in chewing and swallowing.
Item 4. A gelling agent composition comprising the following (a) to (c);
(A) at least one selected from guar gum, cod gum and locust bean gum; (b) xanthan gum and / or κ-carrageenan; and (c) gum arabic and / or a water-soluble soybean polysaccharide.
Item 5. Regarding the contents of (a), (b) and (c) according to item 4, (a) is 0.5 to 98% by weight, (b) is 0.5 to 98% by weight, and (c) is 0 to 0%. Item 5. The gelling agent composition according to Item 4, comprising from 5 to 98% by weight.
Item 6. Item 6. The gelling agent composition according to Item 4 or 5, which is used in foods for people with difficulty in chewing and swallowing.

本発明により、保水性に優れ、食塊形成能(口中での食品のまとまりやすさ)がよく、付着性の少ないゲル状組成物を調製することができるようになった。これらの性質は特に咀嚼・嚥下困難者用食品に要求される食感的および機能的性質を十分に満足するものであり、咀嚼・嚥下困難者用食品に適したゲル状組成物である。   ADVANTAGE OF THE INVENTION According to this invention, it became possible to prepare the gel composition which was excellent in water retention, had good bolus formation ability (easiness of uniting food in the mouth), and had low adhesion. These properties fully satisfy the texture and functional properties required for foods for people with difficult mastication and swallowing, and are gel compositions suitable for foods for people with difficult mastication and swallowing.

本発明のゲル化剤組成物は、食品に適度なゲル構造を付与し、食塊形成能を改良する。また付着性や経時的な物性変化が少ないので高齢者や咀嚼・嚥下困難者用食品を調製する際の補助組成物としては理想的な性状を備えている。更に、食品の外観や味をほとんど損なわないので、嗜好面でも優れている。   The gelling agent composition of the present invention imparts an appropriate gel structure to food and improves bolus forming ability. Further, since it has little adhesion and little change in physical properties over time, it has ideal properties as an auxiliary composition when preparing foods for the elderly and those who have difficulty in chewing and swallowing. Furthermore, since the appearance and taste of the food are hardly impaired, the taste is excellent.

(1)ゲル状組成物
本発明のゲル状組成物は、次の(a)〜(c)を含むことを特徴とする;
(a)グァーガム、タラガム及びローカストビーンガムから選ばれる少なくとも1種以上
(b)キサンタンガム及び/又はκ-カラギナン
(c)アラビアガム及び/又は水溶性大豆多糖類。
(1) Gel composition The gel composition of the present invention comprises the following (a) to (c);
(A) at least one selected from guar gum, cod gum and locust bean gum; (b) xanthan gum and / or κ-carrageenan; and (c) gum arabic and / or a water-soluble soybean polysaccharide.

本発明のゲル状組成物で用いられる(a)グァーガム、タラガム及びローカストビーンガムから選ばれる少なくとも1種以上について説明する。グァーガム、タラガム、ローカストビーンガムは、いずれもマメ科植物の種子を原料とする多糖類であり、β-1,4-D-マンナンの主鎖骨格に側鎖としてD-ガラクトースがα-1,6結合した、いわゆるガラクトマンナン類に属するものである。これら3種類の多糖類は、構成糖であるマンノースとガラクトースのモル比が異なっており、グァーガムでマンノース:ガラクトース=2:1(平均)、タラガムで3:1(平均)、ローカストビーンガムで4:1(平均)である。側鎖の多いグァーガムは常温の水に溶解するが、側鎖の少ないローカストビーンガムでは加熱なしでは水に溶解しない。食品工業の分野において、ガラクトマンナン類はアイスクリームの安定剤、麺類の保水性及び/又は食感改良剤、漬物類に使用する調味液の粘度付け、艶出し、ソース類の粘度付け、油脂代替、冷凍食品では衣の剥離防止や具材の離水防止、畜肉加工品ではピックル液の肉中での分散性の改良等の目的で広く使用されている。   The (a) at least one selected from guar gum, cod gum and locust bean gum used in the gel composition of the present invention will be described. Guar gum, cod gum, and locust bean gum are all polysaccharides made from the seeds of leguminous plants, and α-1,4-D-galactose as a side chain in the main chain skeleton of β-1,4-D-mannan. It belongs to the so-called galactomannans with 6 bonds. These three types of polysaccharides have different molar ratios of the constituent sugars of mannose and galactose. Mannose: galactose = 2: 1 (average) for guar gum, 3: 1 (average) for tara gum, and 4% for locust bean gum. : 1 (average). Guar gum with many side chains dissolves in water at room temperature, but locust bean gum with few side chains does not dissolve in water without heating. In the field of food industry, galactomannans are used as stabilizers for ice cream, water retention and / or texture improver for noodles, thickening of seasoning liquid used for pickles, glazing, thickening of sauces, substitutes for fats and oils. In addition, frozen foods are widely used for the purpose of preventing peeling of clothes and preventing separation of ingredients, and for processed meat products, for improving the dispersibility of pickle liquid in meat.

本発明では、ゲル構造を構築する目的で、上記ガラクトマンナンのうち特にローカストビーンガムを使用するのが好ましく、商業的に入手可能な製品として、例えば三栄源エフ・エフ・アイ株式会社製の「ローカストビンガムF」、「ビストップ[商標]D-171」等を挙げることができる。   In the present invention, for the purpose of constructing a gel structure, it is particularly preferable to use locust bean gum among the above galactomannans, and as a commercially available product, for example, a product of Saneigen FFI Co., Ltd. Locust Bingham F "," Vistop ™ D-171 "and the like.

次に、(b)キサンタンガム及び/又はκ-カラギナンについて説明する。(b)成分のうちキサンタンガムは、微生物Xanthomonas campestrisが産生する発酵多糖類であり、β-1,4-D-グルカンの主鎖骨格に、D-マンノース、D-グルクロン酸、D-マンノースからなる側鎖が結合したアニオン性の多糖類である。主鎖に結合したD-マンノースのC6位はアセチル化され、末端のD-マンノースはピルビン酸とアセタールで結合している。食品工業の分野において、キサンタンガムはドレッシング類の乳化安定性の改良、アイスクリームの安定剤、ホイップクリームの含泡性の改良、漬物類に使用する調味液の粘度付け等の目的で広く用いられており、商業的に入手可能な製品として、三栄源エフ・エフ・アイ株式会社製のサンエース[商標](標準品)、サンエース[商標]S(微粒品)、サンエース[商標]E−S(顆粒品)、サンエース[商標]C(透明品)、及びサンエース[商標]NXG−S(高粘度品)等を挙げることができる。   Next, (b) xanthan gum and / or κ-carrageenan will be described. Among the components (b), xanthan gum is a fermented polysaccharide produced by the microorganism Xanthomonas campestris and comprises D-mannose, D-glucuronic acid, and D-mannose in the main chain skeleton of β-1,4-D-glucan. It is an anionic polysaccharide with a side chain attached. C-position of D-mannose bound to the main chain is acetylated, and terminal D-mannose is linked to pyruvate with acetal. In the field of food industry, xanthan gum is widely used for the purpose of improving the emulsification stability of dressings, the stabilizer of ice cream, the improvement of the foaming property of whipped cream, and the thickening of seasoning liquid used for pickles. As commercially available products, San-Ace TM F (trademark), San-Ace TM (trademark) S (fine-grained product), and San-Ace [TM] ES (granules) Products), SAN ACE [TM] C (transparent product), SAN ACE [TM] NXG-S (high viscosity product) and the like.

(b)成分のうちκ-カラギナンは、β-D-ガラクトースと3,6-アンヒドロ-α-D-ガラクトースの繰り返し構造をモノマーとする紅藻由来の酸性多糖類(カラギナン)の一種である。食品工業の分野において、カラギナンはデザートゼリーおよびプリンの基盤素材、アイスクリーム、食肉加工品、及びソース類等の安定剤、保水性改良剤、食感改良剤として広く使用されている。カラギナンは硫酸基の結合位置およびアンヒドロ糖の有無によって主としてκ型、ι型、及びλ型の3種類に分類されるが、本発明において好適に使用されるのは、α-D-ガラクトースのC4位に硫酸基が結合したκ型のカラギナンである。かかるカラギナンは商業的に入手可能であり、例えば三栄源エフ・エフ・アイ株式会社製の「カラギニンCSK−1」や「カラギニンCS−562」を挙げることができる。   Among components (b), κ-carrageenan is a kind of red polyalga-derived acidic polysaccharide (carrageenan) having a repeating structure of β-D-galactose and 3,6-anhydro-α-D-galactose as monomers. In the food industry, carrageenan is widely used as a base material for dessert jelly and pudding, as a stabilizer such as ice cream, processed meat, and sauces, as a water retention agent, and as a texture modifier. Carrageenans are mainly classified into three types, κ-type, ι-type, and λ-type, depending on the binding position of a sulfate group and the presence or absence of an anhydrosugar. In the present invention, C4 of α-D-galactose is preferably used. It is a κ-type carrageenan with a sulfate group bonded at the position. Such carrageenans are commercially available and include, for example, "Carrageenin CSK-1" and "Carrageenin CS-562" manufactured by Saneigen FFI Co., Ltd.

次に、(c)成分であるが、(c)成分のうちアラビアガムは、マメ科アカシア属植物の樹液に含まれる水溶性のヘテロ多糖である。アラビアガムの分子構造は明らかにされてはいないが、ガラクトース、アラビノース、ラムノース、およびグルクロン酸を構成糖とすることが知られており、少量(<2%)のタンパク質が含まれる。また、平均分子量は200,000〜580,000であると報告されている。食品工業の分野において、アラビアガムは菓子類のコーティング剤、飲料乳化剤、およびベーカリー食品の光沢剤として広く使用されており、例えばAcasia senegal 及び Acasia seyal を起原とするものを挙げることができるが、特にこれらに限定されるものではない。商業的に入手可能な製品として、例えば三栄源エフ・エフ・アイ株式会社製の「ビストップ[商標]D−2041」を挙げることができる。   Next, regarding the component (c), gum arabic among the components (c) is a water-soluble heteropolysaccharide contained in the sap of a plant belonging to the genus Acacia. Although the molecular structure of gum arabic has not been elucidated, it is known that galactose, arabinose, rhamnose and glucuronic acid are constituent sugars, and contains a small amount (<2%) of protein. The average molecular weight is reported to be 200,000 to 580,000. In the field of food industry, gum arabic is widely used as a coating agent for confectionery, a beverage emulsifier, and a brightener for bakery foods, and includes, for example, those derived from Acasia senegal and Acasia seyal, It is not particularly limited to these. Commercially available products include, for example, "Vistop (trademark) D-2041" manufactured by Saneigen FFI Co., Ltd.

(c)成分のうち水溶性大豆多糖類は、大豆タンパク製造の際に生じる不溶性食物繊維(オカラ)から、弱酸性下で抽出、精製、殺菌して調製されたものである。水溶性大豆多糖類の分子構造は必ずしも明らかではないが、ガラクトース、アラビノース、ガラクツロン酸、ラムノース、キシロース、フコース、およびグルコースを構成糖とし、ラムノガラクツロン酸鎖にガラクタンとアラビナンが結合した構造が推定されている。食品工業の分野において、大豆多糖類は酸性乳の安定化剤、ベーカリー食品の食感改良剤として使用されている。かかる水溶性大豆多糖類は商業的に入手可能であり、例えば三栄源エフ・エフ・アイ株式会社製の「SM−640」、「SM−660」、「SM-700」、「SM-900」、「SM-920」を挙げることができる。   Among the components (c), the water-soluble soybean polysaccharide is prepared by extracting, purifying, and sterilizing from insoluble dietary fiber (okara) produced during the production of soybean protein under weak acidity. Although the molecular structure of the water-soluble soybean polysaccharide is not always clear, it is presumed that galactose, arabinose, galacturonic acid, rhamnose, xylose, fucose, and glucose are the constituent sugars, and that the structure of galactan and arabinan is bound to the rhamnogalacturonic acid chain. Have been. In the field of the food industry, soybean polysaccharides are used as stabilizers for acidic milk and as texture improvers for bakery foods. Such water-soluble soy polysaccharides are commercially available, for example, “SM-640”, “SM-660”, “SM-700”, “SM-900” manufactured by Saneigen FFI Co., Ltd. , "SM-920".

本発明において(a)〜(c)の各成分のゲル状組成物中の配合量としては、(a)成分0.01〜1重量%、(b)成分0.01〜0.5重量%、及び(c)成分0.01〜1重量%(いずれも最終食品中)、好ましくは(a)成分0.05〜0.7重量%、(b)成分0.03〜0.3重量%、及び(c)成分0.05〜0.7重量%、更に好ましくは(a)成分0.2〜0.5重量%、(b)成分0.05〜0.2重量%、及び(c)成分0.2〜0.5重量%を挙げることができる。   In the present invention, the amounts of the components (a) to (c) in the gel composition are 0.01 to 1% by weight of the component (a) and 0.01 to 0.5% by weight of the component (b). And (c) component 0.01 to 1% by weight (all in the final food), preferably component (a) 0.05 to 0.7% by weight, component (b) 0.03 to 0.3% by weight And (c) component 0.05 to 0.7% by weight, more preferably component (a) 0.2 to 0.5% by weight, component (b) component 0.05 to 0.2% by weight, and (c) ) Component 0.2 to 0.5% by weight.

本発明のゲル状組成物は、少なくとも上記(a)〜(c)の3成分を含有するものであればよいが、本発明の効果を奏する限りにおいて、他に任意の成分を配合することもできる。   The gel composition of the present invention may contain at least the three components (a) to (c) described above, but any other components may be blended as long as the effects of the present invention are exhibited. it can.

特に、(b)成分としてκ-カラギナンを添加する場合は、カチオン、なかでもカリウム塩を添加するのが好ましい。水中に溶解したカラギナンは冷却により螺旋(二重あるいは一重)構造をとるが、螺旋の外側に配向した硫酸基がカチオンの添加により遮蔽され、分子間会合が促進される結果、ゲルの弾性率が増加する。本発明の咀嚼・嚥下困難者用食品においても、κ-カラギナンが形成するゲル構造を強化する目的でカチオンを添加することが可能であり、カリウム塩、好適には塩化カリウムが用いられる。塩化カリウムを使用する場合、κ-カラギナンの10〜200重量%が添加量の目安となるが、塩濃度が過剰になると弾性率が低下する場合がある。   In particular, when κ-carrageenan is added as the component (b), it is preferable to add a cation, especially a potassium salt. Carrageenan dissolved in water takes a helical (double or single) structure upon cooling, but the sulfate groups oriented to the outside of the helix are shielded by the addition of cations, promoting intermolecular association, resulting in a decrease in the elastic modulus of the gel. To increase. A cation can be added to the food for people with difficulty in chewing and swallowing of the present invention for the purpose of strengthening the gel structure formed by κ-carrageenan, and a potassium salt, preferably potassium chloride, is used. When potassium chloride is used, 10 to 200% by weight of κ-carrageenan is a standard for the amount to be added. However, when the salt concentration is excessive, the elastic modulus may decrease.

本発明のゲル状組成物には、食品原材料は無論のこと、(a)グァーガム、タラガム及びローカストビーンガムから選ばれる少なくとも1種以上、(b)キサンタンガム及び/又はκ-カラギナン、(c)アラビアガム及び/又は水溶性大豆多糖類の効果を妨げない範囲において、他の食品添加物、例えば、L-アスパラギン酸ナトリウム等のアミノ酸またはその塩、5'-イノシン酸二ナトリウム等の核酸またはその塩、クエン酸一カリウム等の有機酸またはその塩、および塩化カリウム等の無機塩類に代表される調味料;カラシ抽出物、ワサビ抽出物、およびコウジ酸等の日持向上剤;シラコたん白抽出物、ポリリジン、およびソルビン酸等の保存料;α、βアミラーゼ、α、βグルコシダ−ゼ、パパイン等の酵素;クエン酸、フマル酸、コハク酸等のpH調整剤;ショ糖脂肪酸エステル、グリセリン脂肪酸エステル、有機酸モノグリセリド、レシチン等の乳化剤;香料;β-カロチン、アナトー色素等の着色料;ι-カラギナン、λ-カラギナン、アルギン酸及びアルギン酸塩、LM及びHMペクチン、タマリンドシードガム、サバクヨモギシードガム、コンニャクグルコマンナン、澱粉、化工及び加工澱粉、澱粉加水分解物、ラムザンガム、ウェランガム、カードラン、プルラン、カラヤガム、トラガントガム、ガッティガム、微結晶セルロース、微小繊維状セルロース、発酵セルロース、カルボキシメチルセルロース塩、メチルセルロース、エチルメチルセルロース、ハイドロキシプロピルセルロース、キチン、キトサン等の増粘剤、ゲル化剤;膨張剤;乳清たん白質、大豆たん白質等のたん白質;ショ糖、果糖、還元デンプン糖化物、エリスリトール、キシリトール等の糖類;スクラロース、ソーマチン、アセスルファムカリウム、アスパルテーム等の甘味料;ビタミンA、ビタミンC、ビタミンE、ビタミンK等のビタミン類;鉄、カルシウム等のミネラル類等を添加することができる。   In the gel composition of the present invention, food ingredients are, of course, (a) at least one selected from guar gum, tara gum and locust bean gum, (b) xanthan gum and / or κ-carrageenan, (c) arabic. Other food additives, for example, an amino acid such as sodium L-aspartate or a salt thereof, a nucleic acid such as disodium 5′-inosinate or a salt thereof, as long as the effects of the gum and / or the water-soluble soybean polysaccharide are not impaired , Seasonings such as organic acids such as monopotassium citrate or salts thereof, and inorganic salts such as potassium chloride; mustard extract, wasabi extract, and shelf life improver such as kojic acid; shirako protein extract , Polylysine, and sorbic acid; preservatives; α, β-amylase, α, β-glucosidase, papain and other enzymes; citric acid, fumaric acid, succinic acid PH adjusters; emulsifiers such as sucrose fatty acid esters, glycerin fatty acid esters, organic acid monoglycerides, lecithin; fragrances; coloring agents such as β-carotene and annatto pigments; And HM pectin, tamarind seed gum, mugwort mugwort seed gum, konjac glucomannan, starch, modified and processed starch, starch hydrolyzate, ramzan gum, welan gum, curdlan, pullulan, karaya gum, tragacanth gum, gutti gum, microcrystalline cellulose, microfiber Thickeners such as cellulose cellulose, fermented cellulose, carboxymethylcellulose salts, methylcellulose, ethylmethylcellulose, hydroxypropylcellulose, chitin, chitosan, gelling agents; swelling agents; whey protein, soybean protein, etc. Protein; sugars such as sucrose, fructose, reduced starch saccharified product, erythritol, xylitol; sweeteners such as sucralose, thaumatin, acesulfame potassium, aspartame; vitamins such as vitamin A, vitamin C, vitamin E, vitamin K; And minerals such as calcium.

本発明のゲル状組成物の具体例態様としては、水分補給ゼリー、栄養補給ゼリー及びプリン、ミキサー加工食品、うらごし野菜、キザミ食、ムース状食品、高栄養流動食品、及びたんぱく質調整食品等のゲル状の食品、特には、咀嚼・嚥下困難者用に供される食品を広く挙げることができるが、特にこれらに限定されるものではない。   Specific embodiments of the gel composition of the present invention include hydrated jelly, nutritional supplemented jelly and pudding, mixed processed food, seaweed vegetable, croaked food, mousse-shaped food, highly nutritive fluid food, protein-modified food, and the like. Gel-type foods, especially foods for those who have difficulty in chewing and swallowing can be widely mentioned, but are not particularly limited thereto.

(2)ゲル化剤組成物
本発明のゲル化剤組成物は、(a)グァーガム、タラガム、及びローカストビーンガムから選ばれる少なくとも1種以上、(b)キサンタンガム及び/又はκ-カラギナン及び(c)アラビアガム及び/又は水溶性大豆多糖類を併用してなることを特徴とする。
(2) Gelling agent composition The gelling agent composition of the present invention comprises (a) at least one selected from guar gum, cod gum and locust bean gum, (b) xanthan gum and / or κ-carrageenan and (c) A) gum arabic and / or water-soluble soybean polysaccharide are used in combination.

上記3成分を併用したゲル化剤組成物を既存の食品に添加すると、保水性に優れ、食塊形成能(口中での食品のまとまりやすさ)がよく、付着性の少ないゲル状組成物を調製することができる。これらの性質は特に咀嚼・嚥下困難者用食品に要求される食感的および機能的性質を十分に満足するものであり、咀嚼・嚥下困難者用食品に適したゲル化剤組成物となる。   When a gelling composition containing the above three components is added to an existing food, a gel composition having excellent water retention, good bolus formation ability (easiness of uniting the food in the mouth), and low adhesion is obtained. Can be prepared. These properties sufficiently satisfy the texture and functional properties required of foods for people with difficulty in chewing and swallowing, and result in gelling compositions suitable for foods for people with difficult mastication and swallowing.

本発明において、上記3成分のゲル化剤組成物中の配合量であるが、(a)成分0.5〜98重量%、(b)成分0.5〜98重量%、及び(c)成分0.5〜98重量%(いずれも該組成物中の配合量)、好ましくは(a)成分4.5〜90重量%、(b)成分2〜80重量%、及び(c)成分4.5〜90重量%、更に好ましくは(a)成分20〜70重量%、(b)成分4.5〜35重量%、及び(c)成分20〜70重量%を挙げることができる。なお、該組成物の食品への添加量は0.03〜2.5重量%、好ましくは0.13〜1.7重量%、更に好ましくは0.45〜1.2重量%である。   In the present invention, the amounts of the three components in the gelling agent composition are 0.5 to 98% by weight of component (a), 0.5 to 98% by weight of component (b), and component (c). 0.5 to 98% by weight (all in the composition), preferably 4.5 to 90% by weight of component (a), 2 to 80% by weight of component (b) and component 4. 5 to 90% by weight, more preferably 20 to 70% by weight of component (a), 4.5 to 35% by weight of component (b) and 20 to 70% by weight of component (c). The amount of the composition added to food is 0.03 to 2.5% by weight, preferably 0.13 to 1.7% by weight, more preferably 0.45 to 1.2% by weight.

本発明のゲル化剤組成物は、任意の既存食品に添加することができるが、そのゲル化特性を発揮させるためには、該組成物を溶媒中で加熱溶解し、冷却させるという熱履歴を経ることが望ましい。このように処理することで、保水性に優れ、食塊形成性がよく、付着性の少ないゲル状食品を調製することができる。   The gelling agent composition of the present invention can be added to any existing food, but in order to exhibit its gelling properties, the composition is heated and dissolved in a solvent and cooled by cooling. It is desirable to go through. By performing such treatment, it is possible to prepare a gel food having excellent water retention, good bolus formation, and low adhesion.

本発明のゲル化剤組成物は、少なくとも上記3成分を含有するものであればよいが、本発明の効果を奏する限りにおいて、他に任意の成分を配合することもでき、例えば前述の塩化カリウムを挙げることができる。   The gelling agent composition of the present invention may contain at least the above three components, but any other components can be blended as long as the effects of the present invention are exhibited. Can be mentioned.

本発明のゲル化剤組成物には、その効果を妨げない範囲において、他の食品添加物、例えば、L-アスパラギン酸ナトリウム等のアミノ酸またはその塩、5'-イノシン酸二ナトリウム等の核酸またはその塩、クエン酸一カリウム等の有機酸またはその塩、および塩化カリウム等の無機塩類に代表される調味料;カラシ抽出物、ワサビ抽出物、およびコウジ酸等の日持向上剤;シラコたん白抽出物、ポリリジン、およびソルビン酸等の保存料;α、βアミラーゼ、α、βグルコシダ−ゼ、パパイン等の酵素;クエン酸、フマル酸、コハク酸等のpH調整剤;ショ糖脂肪酸エステル、グリセリン脂肪酸エステル、有機酸モノグリセリド、レシチン等の乳化剤;香料;β-カロチン、アナトー色素等の着色料;ι-カラギナン、λ-カラギナン、アルギン酸及びアルギン酸塩、LM及びHMペクチン、タマリンドシードガム、サバクヨモギシードガム、コンニャクグルコマンナン、澱粉、化工及び加工澱粉、澱粉加水分解物、ラムザンガム、ウェランガム、カードラン、プルラン、カラヤガム、トラガントガム、ガッティガム、微結晶セルロース、微小繊維状セルロース、発酵セルロース、カルボキシメチルセルロース塩、メチルセルロース、エチルメチルセルロース、ハイドロキシプロピルセルロース、キチン、キトサン等の増粘剤、ゲル化剤;膨張剤;乳清たん白質、大豆たん白質等のたん白質;ショ糖、果糖、還元デンプン糖化物、エリスリトール、キシリトール等の糖類;スクラロース、ソーマチン、アセスルファムカリウム、アスパルテーム等の甘味料;ビタミンA、ビタミンC、ビタミンE、ビタミンK等のビタミン類;鉄、カルシウム等のミネラル類等を添加することができる。   The gelling agent composition of the present invention contains other food additives, for example, an amino acid such as sodium L-aspartate or a salt thereof, a nucleic acid such as 5′-disodium inosinate or the like, as long as the effect is not hindered. Seasonings typified by salts thereof, organic acids such as monopotassium citrate or salts thereof, and inorganic salts such as potassium chloride; retention agents such as mustard extract, wasabi extract, and kojic acid; shirako protein Preservatives such as extract, polylysine and sorbic acid; enzymes such as α, β-amylase, α, β-glucosidase, papain; pH regulators such as citric acid, fumaric acid, succinic acid; sucrose fatty acid ester, glycerin Emulsifiers such as fatty acid esters, organic acid monoglycerides and lecithin; fragrances; coloring agents such as β-carotene and annatto pigments; ι-carrageenan, λ-carrageenan, alginic acid and Luginate, LM and HM pectin, tamarind seed gum, mugwort mugwort seed gum, konjac glucomannan, starch, modified and processed starch, starch hydrolyzate, ramzan gum, welan gum, curdlan, pullulan, karaya gum, tragacanth gum, gutti gum, fine Thickening agents such as crystalline cellulose, microfibrous cellulose, fermented cellulose, carboxymethylcellulose salt, methylcellulose, ethylmethylcellulose, hydroxypropylcellulose, chitin, chitosan, gelling agents; swelling agents; whey protein, soybean protein, etc. Proteins; sugars such as sucrose, fructose, reduced starch saccharified products, erythritol, xylitol; sweeteners such as sucralose, thaumatin, acesulfame potassium, aspartame; vitamins A, vitamin C, vitamins , Vitamins such as vitamin K; can be added to the iron minerals such as calcium, and the like.

本発明のゲル化剤組成物が対象とする食品は、例えばアイスクリーム、アイスミルク、ラクトアイス、シャーベット、氷菓等の冷菓類;牛乳、乳飲料、乳酸菌飲料、果汁入り清涼飲料、炭酸飲料、果汁飲料、菜汁飲料、茶飲料、イオン飲料、スポーツ飲料、機能性飲料、ビタミン補給飲料、栄養補給バランス飲料、粉末飲料等の飲料類;カスタードプリン,ミルクプリン及び果汁入りプリン等のプリン類、ゼリー、ババロア及びヨーグルト等のデザート類;チューインガムや風船ガム等のガム類(板ガム、糖衣状粒ガム);マーブルチョコレート等のコーティングチョコレートの他、イチゴチョコレート、ブルーベリーチョコレート及びメロンチョコレート等の風味を付加したチョコレート等のチョコレート類;ソフトキャンディー(キャラメル、ヌガー、グミキャンディー、マシュマロ等を含む)、タフィ等のキャラメル類;ソフトビスケット、ソフトクッキー等の菓子類;セパレートドレッシングやノンオイルドレッシングなどのドレッシング類、ケチャップ、たれ、ソースなどのソース類;ストロベリージャム、ブルーベリージャム、マーマレード、リンゴジャム、杏ジャム、プレザーブ等のジャム類;赤ワイン等の果実酒;シロップ漬のチェリー、アンズ、リンゴ、イチゴ等の加工用果実;ハム、ソーセージ、焼き豚等の畜肉加工品;魚肉ハム、魚肉ソーセージ、魚肉すり身、蒲鉾、竹輪、はんぺん、薩摩揚げ、伊達巻き、鯨ベーコン等の水産練り製品;うどん、冷麦、そうめん、ソバ、中華そば、スパゲッティ、マカロニ、ビーフン、はるさめ及びワンタン等の麺類;コンソメスープ、ポタージュスープ、クリームスープ、中華スープ等の各種スープ、味噌汁、清汁、シチュウ、カレー、グラタンなどのスープ類;その他、各種総菜及び加工食品等を挙げることができる。また、このような一般食品に加えて、蛋白質・リン・カリウム調整食品、塩分調整食品、油脂調整食品、整腸作用食品、カルシウム・鉄・ビタミン強化食品、低アレルギー食品、濃厚流動食、ミキサー食、及びキザミ食等の特殊食品や治療食を挙げることができる。   Food products targeted by the gelling agent composition of the present invention include, for example, ice cream, ice milk, lacto ice, sherbet, frozen desserts such as ice desserts; milk, milk drinks, lactic acid bacteria drinks, soft drinks containing fruit juice, carbonated drinks, juice drinks , Vegetable drinks, tea drinks, ionic drinks, sports drinks, functional drinks, vitamin supplemented drinks, nutritionally balanced drinks, drinks such as powdered drinks; purines such as custard pudding, milk pudding and fruit juice pudding, jelly, Desserts such as bavarois and yogurt; gums such as chewing gum and balloon gum (plate gum, sugar-coated gum); coated chocolates such as marble chocolates, and chocolates with added flavors such as strawberry chocolate, blueberry chocolate and melon chocolate. Chocolate such as; soft candy (character , Nougat, gummy candy, marshmallow, etc.), caramels such as toffee; confectionery such as soft biscuits and soft cookies; dressings such as separate dressing and non-oil dressing; sauces such as ketchup, sauce and sauce; strawberry Jams such as jams, blueberry jams, marmalades, apple jams, apricot jams, preserves, etc .; fruit wines, such as red wine; fruits for processing, such as cherry, apricot, apple, and strawberry pickled in syrup; meat processing of ham, sausages, grilled pork, etc. Products: Fish ham, fish sausage, fish meat surimi, kamaboko, bamboo ring, hampan, Satsumaage, Date roll, whale bacon, etc. Fishery products such as udon, cold wheat, somen, buckwheat, Chinese buckwheat, spaghetti, macaroni, rice noodles, harunasa and wonton Noodles, etc. Somesupu, potage soup, cream soup, various types of soup such as Chinese soup, miso soup, Sumashijiru, situ, curry, soup such as gratin; Other, mention may be made of a variety of side dishes and processed foods and the like. In addition to such general foods, protein / phosphorous / potassium adjusted foods, salt adjusted foods, oil / fat adjusted foods, intestinal action foods, calcium / iron / vitamin-enriched foods, hypoallergic foods, concentrated liquid foods, mixer foods And special foods and therapeutic foods such as ragged foods.

本発明のゲル化剤組成物の製造方法は、上記の必須3成分を含むものであれば特に制限されず、例えば(1)リボンミキサーやVブレンダーを用いて粉体で混合する方法、(2)水中で加熱することによって溶解、均一分散させ液状とする方法、(3)別々に溶液を調製し、使用時に混合する方法、(4)溶液化したものをスプレードライ等により分散粉末化する方法、(5)粉体で混合し、プレス機で圧縮することにより打錠し、錠剤状にする方法、及び(6)溶液化したものを造粒機により、顆粒化して使用する方法等によって調製することができる。   The method for producing the gelling agent composition of the present invention is not particularly limited as long as it contains the above three essential components. For example, (1) a method of mixing with a powder using a ribbon mixer or a V blender, (2) ) A method of dissolving, dispersing and dispersing by heating in water to make a liquid, (3) A method of separately preparing solutions and mixing at the time of use, and (4) A method of dispersing the solution into powder by spray drying or the like. , (5) tableting by mixing with powder and compressing with a press machine to form tablets, and (6) method of granulating the solution into a granulator and using it. can do.

以下、本発明の内容を以下の実施例、比較例等を用いて具体的に説明するが、本発明はこれらに何ら限定されるものではない。また、特に記載のない限り「部」は「重量部」、「%」は「重量%」を意味するものとする。文中「*」印のものは、三栄源エフ・エフ・アイ株式会社製、文中「※」印は三栄源エフ・エフ・アイ株式会社の登録商標であることを示す。   Hereinafter, the content of the present invention will be specifically described with reference to the following Examples and Comparative Examples, but the present invention is not limited to these. Unless otherwise specified, “parts” means “parts by weight” and “%” means “% by weight”. The symbol with “*” in the text indicates that it is manufactured by San-Ei Gen FFI Co., Ltd., and the symbol with “*” in the text indicates that it is a registered trademark of San-Ei Gen FFI Co., Ltd.

実験例1
(1)ゲル状組成物(水分補給ゼリー)の調製
表1に示す処方に従い、水分補給ゼリーを調製した。具体的には、80℃に加熱した脱イオン水に、予め混合したゲル化剤と中国緑茶エキスパウダーを添加し、10分間攪拌溶解した。脱イオン水を用いて重量を補正した後、カップ(直径6.2cm、高さ5.4cm)に充填し、8℃の恒温水槽中で約1時間冷却した。得られたゲルを121℃ 20分間レトルト加熱して、水分補給ゼリーを調製した。水分補給ゼリーは4℃で一晩保存して、各種評価に供した。
Experimental example 1
(1) Preparation of gel composition (hydration jelly) A hydration jelly was prepared according to the formulation shown in Table 1. Specifically, a premixed gelling agent and Chinese green tea extract powder were added to deionized water heated to 80 ° C., and the mixture was stirred and dissolved for 10 minutes. After correcting the weight with deionized water, the cup was filled into a cup (diameter 6.2 cm, height 5.4 cm) and cooled in a constant temperature water bath at 8 ° C. for about 1 hour. The obtained gel was retorted at 121 ° C. for 20 minutes to prepare a hydrated jelly. The hydrated jelly was stored at 4 ° C. overnight and subjected to various evaluations.

なお、緑茶エキスパウダーとして、「FD中国緑茶エキスパウダーNO.16323*」、アラビアガムとして、「ビストップ※D−2041*」、ローカストビーンガムとして、「ローカストビンガムF*」、ガラクトマンナン共沈物として、「ビストップ※D−1827*」、キサンタンガム「サンエース※C*」、寒天として、「ゲルアップ※J−1630*」を使用した。
(2)水分補給ゼリーの評価
以下の4項目について、保存1日後にゼリーを25℃まで戻して評価した。結果を表1に併せて示す。
1.口中での食塊形成のしやすさを5段階(1: 悪い、2: やや悪い、3: やや良い、4: 良い、5: 非常に良い)で評価した。
2.口腔及び咽頭への付着性を5段階(1: 悪い(多い)、2: やや悪い(多い)、3: やや良い(少ない)、4: 良い(少ない)、5: 非常に良い(少ない)
)で評価した。
3.カップ表面に遊離した水分をペーパータオルでふき取り、重量の減少分から離水量を算出した。
4.ホモジナイザーを用いて、ゼリーを10倍量の脱イオン水中で分散させ、25℃でpHメーターにより測定した。
The green tea extract powder was "FD China Green Tea Extract No. 16323 *", the gum arabic was "Vistop * D-2041 *", the locust bean gum was "Locust Bingham F *", and the coprecipitated galactomannan. "Bistop * D-1827 *", xanthan gum "San Ace * C *", and agar "Gel Up * J-1630 *" were used.
(2) Evaluation of hydration jelly The following four items were evaluated by returning the jelly to 25 ° C. one day after storage. The results are shown in Table 1.
1. The ease of bolus formation in the mouth was evaluated on a five-point scale (1: bad, 2: somewhat poor, 3: fairly good, 4: good, 5: very good).
2. Five levels of adhesion to the oral cavity and pharynx (1: bad (many), 2: somewhat bad (many), 3: somewhat good (less), 4: good (less), 5: very good (less)
).
3. The water released on the cup surface was wiped off with a paper towel, and the amount of water separation was calculated from the weight loss.
4. The jelly was dispersed in a 10-fold amount of deionized water using a homogenizer, and measured at 25 ° C. with a pH meter.

Figure 2004350680
Figure 2004350680

表1より、本発明の3成分、即ち(a)ローカストビーンガム、(b)キサンタンガム、及び(c)アラビアガムを使用した水分補給ゼリー(実施例1)は、保水性に優れ(見た目に離水が殆どない)、食塊形成性がよく、口腔及び咽頭への付着性が殆どなく、みずみずしい食感であり、咀嚼・嚥下に適した特性を示した。   From Table 1, it can be seen that the hydration jelly using the three components of the present invention, namely, (a) locust bean gum, (b) xanthan gum, and (c) gum arabic (Example 1) has excellent water retention (appearance of water separation) Almost no), good bolus formation, little adhesion to the oral cavity and pharynx, fresh texture, and properties suitable for chewing and swallowing.

それに対して、寒天単独使用区(比較例1)は脆く、再結着性がないため、口内でゲルの食塊がばらばらになり、飲み込みにくかった。また、ゼリー内部から水分が容易に滲みだすという現象が認められた。また、ローカストビーンガム及びキサンタンガム使用区(アラビアガム未使用)(比較例2)では、弾力性が非常に強くてさじ切れが悪く、噛み切れないため、咀嚼・嚥下困難者用食品の基材としては不適切であった。更に、キサンタンガム及びアラビアガム使用区(ローカストビーンガム未使用)(比較例3)、ローカストビーンガム及びアラビアガム使用区(キサンタン未使用)(比較例4)ではゲルを形成せず、ゾル状あるいは溶液状のままであり、水分補給ゼリーの調製は困難であった。   On the other hand, the agar-only section (Comparative Example 1) was brittle and had no rebinding properties, so that the bolus of the gel was broken in the mouth and difficult to swallow. In addition, a phenomenon that water easily oozes out of the jelly was observed. In the locust bean gum and xanthan gum use areas (without gum arabic) (Comparative Example 2), the elasticity is very strong, the scoring is poor, and the sponge does not bite. Was inappropriate. Furthermore, in the section using xanthan gum and gum arabic (without locust bean gum) (Comparative Example 3), and in the section using locust bean gum and gum arabic (without xanthan) (Comparative Example 4), no gel was formed, and a sol or solution was not obtained. The preparation of hydrated jelly was difficult.

このように本発明の3成分を併用することで、従来の素材では調製することができない、咀嚼・嚥下困難者に適した水分補給ゼリーを調製できることが分かった。   Thus, it was found that by using the three components of the present invention together, it is possible to prepare a hydration jelly suitable for persons with difficulty in chewing and swallowing, which cannot be prepared with conventional materials.

実験例2
(1)咀嚼・嚥下ゲル化剤組成物の調製
(a)ローカストビーンガムとして「ローカストビンガムF*」、(b)κ-カラギナンとして「カラギニンCSK-1*」、及び(c)水溶性大豆多糖類として「SM−660*」を使用し、下記表2に示す処方に従い、咀嚼・嚥下ゲル化剤組成物を調製した。また、比較例として、ジェランガムとして「ケルコゲル*」を使用したもの(比較例a)、κ−カラギナン及び水溶性大豆多糖類を使用したもの(比較例b)、ローカストビーンガム及び水溶性大豆多糖類を使用したもの(比較例c)、ローカストビーンガム及びκ−カラギナンを使用したもの(比較例d)を調製した。
Experimental example 2
(1) Preparation of a chewing / swallowing gelling agent composition (a) "Locust Bingham F *" as locust bean gum, (b) "Carrageenin CSK-1 *" as κ-carrageenan, and (c) water-soluble soybean Using “SM-660 *” as a saccharide, a chewing / swallowing gelling agent composition was prepared according to the formulation shown in Table 2 below. As comparative examples, those using "Kelcogel *" as gellan gum (Comparative Example a), those using κ-carrageenan and water-soluble soybean polysaccharide (Comparative Example b), locust bean gum and water-soluble soybean polysaccharide (Comparative Example c) and those using locust bean gum and κ-carrageenan (Comparative Example d) were prepared.

Figure 2004350680
Figure 2004350680

(2)水分補給ゼリーの調製
表2に示す咀嚼・嚥下ゲル化剤組成物を、表3に示す添加量で使用して、水分補給ゼリーを調製した。具体的には、80℃に加熱した脱イオン水に表2の組成物、グラニュー糖、クエン酸三ナトリウムを添加し、10分間攪拌溶解した。次に、グレープ果汁、乳酸カルシウム、クエン酸、グレープエッセンスを混合、脱イオン水を用いて重量を補正した後、カップ(直径6.2cm、高さ5.4cm)充填し、8℃の恒温水槽中で約1時間冷却した。得られたゲルを85℃で30分間加熱殺菌して水分補給ゼリーを調製した。水分補給ゼリーは4℃で一晩保存して、各種評価に供した。
(2) Preparation of hydration jelly A hydration jelly was prepared using the chewing / swallowing gelling agent composition shown in Table 2 in the amount shown in Table 3. Specifically, the composition shown in Table 2, granulated sugar and trisodium citrate were added to deionized water heated to 80 ° C., and the mixture was stirred and dissolved for 10 minutes. Next, grape juice, calcium lactate, citric acid, and grape essence are mixed, the weight is corrected using deionized water, and then a cup (6.2 cm in diameter, 5.4 cm in height) is filled, and a constant temperature water bath at 8 ° C. For about 1 hour. The obtained gel was sterilized by heating at 85 ° C. for 30 minutes to prepare a hydrated jelly. The hydrated jelly was stored at 4 ° C. overnight and subjected to various evaluations.

(3)水分補給ゼリーの評価
実験例1と同様の4項目について、保存1日後にゲルを25℃まで戻して評価した。結果を表3に併せて示す。
(3) Evaluation of water replenishment jelly For the same four items as in Experimental Example 1, the gel was returned to 25 ° C. one day after storage and evaluated. The results are shown in Table 3.

Figure 2004350680
Figure 2004350680

表3より、本発明の3成分、即ち(a)ローカストビーンガム、(b)κ-カラギナン、及び(c)水溶性大豆多糖類を使用した水分補給ゼリー(実施例2)は、保水性に優れ(みために離水が殆どない)、食塊形成性がよく、口腔及び咽頭への付着性が殆どなく、みずみずしい食感であり、咀嚼・嚥下に適した特性を示した。ジェランガム単独使用区(比較例5)は脆く、再結着性がないため、口内でゲルの食塊がばらばらになり、飲み込みにくかった。また、ゼリー表面に明らかに離水が認められた。また、κ-カラギナン及び水溶性大豆多糖類使用区(ローカストビーンガム未使用)(比較例6)及びローカストビーンガム及びκ-カラギナン使用区(水溶性大豆多糖類未使用)(比較例8)では、比較例6では付着性が、比較例8では弾力性があり、いずれも食塊形成性が悪く、咀嚼・嚥下困難者用食品の基材としては不適切であった。更に、ローカストビーンガム及び水溶性大豆多糖類使用区(κ-カラギナン未使用)(比較例7)ではゲルを形成せず、ゾル状あるいは溶液状のままであり、水分補給ゼリーの調製は困難であった。   From Table 3, it can be seen that the three components of the present invention, namely (a) locust bean gum, (b) κ-carrageenan, and (c) a hydrated jelly using water-soluble soybean polysaccharide (Example 2), Excellent (with little water separation due to appearance), good bolus formation, little adhesion to the oral cavity and pharynx, had a fresh texture, and exhibited characteristics suitable for chewing and swallowing. Gellan gum alone (Comparative Example 5) was brittle and had no rebinding properties, so the bolus of the gel fell apart in the mouth and was difficult to swallow. Also, water separation was clearly observed on the jelly surface. In the section using κ-carrageenan and water-soluble soybean polysaccharide (without using locust bean gum) (Comparative Example 6), and in the section using locust bean gum and κ-carrageenan (without using water-soluble soybean polysaccharide) (Comparative Example 8) Comparative Example 6 had adhesiveness, and Comparative Example 8 had elasticity, all of which had poor bolus formation, and were unsuitable as base materials for foods for people with difficult mastication and swallowing. Furthermore, in the section using locust bean gum and the water-soluble soybean polysaccharide (without use of κ-carrageenan) (Comparative Example 7), no gel was formed and the gel remained in a sol or solution state, and it was difficult to prepare a hydrated jelly. there were.

このように本発明の3成分を併用することで、従来の素材では調製することができない、咀嚼・嚥下困難者に適した水分補給ゼリーを調製できることが分かった。   Thus, it was found that by using the three components of the present invention together, it is possible to prepare a hydration jelly suitable for persons with difficulty in chewing and swallowing, which cannot be prepared with conventional materials.

本発明により、咀嚼・嚥下障害者や高齢者等の咀嚼・嚥下機能が低下した者に適したゲル状組成物、即ち、1)食塊形成性(口中での食品のまとまりやすさ)に優れ、2)口腔及び咽頭への付着性が少なく、3)保水性に優れたゲル状組成物を提供することができる。   According to the present invention, a gel composition suitable for those with reduced mastication and swallowing functions such as those with mastication and dysphagia and elderly people, that is, 1) excellent bolus formation (easiness of uniting foods in the mouth) 2) Low adhesiveness to the oral cavity and pharynx; 3) A gel composition excellent in water retention can be provided.

Claims (6)

次の(a)〜(c)を含むことを特徴とするゲル状組成物;(a)グァーガム、タラガム及びローカストビーンガムから選ばれる少なくとも1種以上、(b)キサンタンガム及び/又はκ-カラギナン、(c)アラビアガム及び/又は水溶性大豆多糖類。 A gel composition comprising the following (a) to (c); (a) at least one or more selected from guar gum, tara gum and locust bean gum; (b) xanthan gum and / or κ-carrageenan; (C) Gum arabic and / or water-soluble soy polysaccharide. 請求項1記載の(a)、(b)、(c)の含有量について、(a)を0.01〜1重量%、(b)を0.01〜0.5重量%、及び(c)を0.01〜1重量%含有する、請求項1に記載のゲル状組成物。 Regarding the contents of (a), (b) and (c) according to claim 1, (a) is 0.01 to 1% by weight, (b) is 0.01 to 0.5% by weight, and (c) The gel composition according to claim 1, which comprises 0.01 to 1% by weight. 咀嚼・嚥下困難者用食品である、請求項1又は2に記載のゲル状組成物。 The gel composition according to claim 1 or 2, which is a food for people with difficulty in chewing and swallowing. 次の(a)〜(c)を含むことを特徴とするゲル化剤組成物;(a)グァーガム、タラガム及びローカストビーンガムから選ばれる少なくとも1種以上、(b)キサンタンガム及び/又はκ-カラギナン、(c)アラビアガム及び/又は水溶性大豆多糖類。 A gelling agent composition comprising the following (a) to (c); (a) at least one or more selected from guar gum, tara gum and locust bean gum; (b) xanthan gum and / or κ-carrageenan (C) gum arabic and / or water-soluble soy polysaccharide. 請求項4記載の(a)、(b)、(c)の含有量について、(a)を0.5〜98重量%、(b)を0.5〜98重量%、及び(c)を0.5〜98重量%含有する、請求項4に記載のゲル化剤組成物。 Regarding the contents of (a), (b) and (c) according to claim 4, (a) is 0.5 to 98% by weight, (b) is 0.5 to 98% by weight, and (c) is The gelling agent composition according to claim 4, which contains 0.5 to 98% by weight. 咀嚼・嚥下困難者用食品に使用される、請求項4又は5に記載のゲル化剤組成物。
The gelling agent composition according to claim 4 or 5, which is used in foods for people with difficulty in chewing and swallowing.
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