JP6685726B2 - Hair treatment composition - Google Patents

Hair treatment composition Download PDF

Info

Publication number
JP6685726B2
JP6685726B2 JP2015522762A JP2015522762A JP6685726B2 JP 6685726 B2 JP6685726 B2 JP 6685726B2 JP 2015522762 A JP2015522762 A JP 2015522762A JP 2015522762 A JP2015522762 A JP 2015522762A JP 6685726 B2 JP6685726 B2 JP 6685726B2
Authority
JP
Japan
Prior art keywords
hair
amodimethicone
treatment composition
present
microemulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2015522762A
Other languages
Japanese (ja)
Other versions
JPWO2014199936A1 (en
Inventor
堅 林
堅 林
賢二 野田
賢二 野田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shiseido Co Ltd
Original Assignee
Shiseido Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shiseido Co Ltd filed Critical Shiseido Co Ltd
Publication of JPWO2014199936A1 publication Critical patent/JPWO2014199936A1/en
Application granted granted Critical
Publication of JP6685726B2 publication Critical patent/JP6685726B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/068—Microemulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Description

本発明は毛髪処理剤組成物に関する。より詳細には、毛髪に蓄積されたカルシウムイオンを効率的に除去することのできる毛髪処理剤組成物に関する。   The present invention relates to a hair treatment composition. More particularly, it relates to a hair treatment composition capable of efficiently removing calcium ions accumulated in hair.

毛髪は、紫外線などの自然環境からの刺激や、パーマネントウェーブ処理、カラーリング処理、脱色処理などの化学処理を受けることにより損傷して「きしみ」や「ぱさつき」を生じる。さらに、損傷により親水化した毛髪に金属イオンが吸着することによって滑らかさが失われ、ごわごわした感触を生ずるとも言われている。即ち、損傷した毛髪をケアする目的でシャンプーやトリートメント処理を施しても、それを洗い流す水中に含まれる金属イオンの影響によって「ごわつき」が助長されてしまうという問題がある。   Hair is damaged by being stimulated by a natural environment such as ultraviolet rays or subjected to chemical treatments such as permanent wave treatment, coloring treatment, and decolorization treatment to cause "creaks" and "smoothness". Further, it is said that the metal ions are adsorbed on the hair which has been hydrophilized due to the damage, resulting in a loss of smoothness and a rough feeling. That is, even if shampooing or treatment treatment is performed for the purpose of caring for damaged hair, there is a problem that "stiffness" is promoted due to the influence of metal ions contained in the water for washing the hair.

特許文献１には、金属イオンの中でも銅イオンに着目し、銅イオンを選択的にキレートするキレート剤、例えばジアミン−Ｎ，Ｎ‘−ジポリ酸又はモノアミンモノアミド−Ｎ，Ｎ’−ジポリ酸を配合した毛髪処理剤が損傷を低減するのに有用であると記載されている。   In Patent Document 1, paying attention to copper ions among metal ions, a chelating agent that selectively chelates copper ions, for example, diamine-N, N'-dipolyacid or monoaminemonoamide-N, N'-dipolyacid is blended. Said hair treatment composition is said to be useful in reducing damage.

一方、特許文献２には、損傷した毛髪からカルシウム等のアルカリ土類金属を除去し、毛髪の柔らかさを改善するとともに、毛髪の痛みを改善して滑らかな感触を付与する毛髪化粧料が開示され、当該化粧料は、α−ヒドロキシ酸化合物と、没食子酸化合物とを含有し、ｐＨが２〜４であることを特徴としている。   On the other hand, Patent Document 2 discloses a hair cosmetic composition that removes alkaline earth metals such as calcium from damaged hair to improve the softness of the hair and also to improve the pain of the hair and impart a smooth feel. The cosmetic is characterized by containing an α-hydroxy acid compound and a gallic acid compound and having a pH of 2 to 4.

特許文献３には、前記α−ヒドロキシ酸化合物をカルシウムキレート剤として配合するとともに（例えば、段落００１９）、特定の油剤及び窒素含有変性シリコーンを配合した毛髪化粧料で処理することにより、処理後の毛髪の強度を高め、表面を疎水化して毛髪の摩擦抵抗を低減できると記載されている。   In Patent Document 3, the α-hydroxy acid compound is added as a calcium chelating agent (for example, paragraph 0019), and a hair cosmetic composition containing a specific oil agent and a nitrogen-containing modified silicone is used to treat the hair. It is described that the strength of hair can be increased and the surface can be made hydrophobic to reduce the frictional resistance of hair.

しかしながら、上記特許文献１、２に記載された従来技術では、毛髪表面あるいは内部に蓄積された銅イオンやカルシウムイオンがキレート剤を用いて除去されるものの、毛髪に滑らかさを付与するトリートメント効果が得られない。特許文献３では、特定の油剤及び窒素含有変性シリコーンを共配合することにより毛髪に強さと滑らかさを付与しているが、カルシウムイオンを除去するためにはキレート剤（α−ヒドロキシ酸）が必須である。   However, in the conventional techniques described in Patent Documents 1 and 2, although the copper ions and calcium ions accumulated on the surface of the hair or inside are removed by using a chelating agent, the treatment effect that imparts smoothness to the hair is obtained. I can't get it. In Patent Document 3, the hair is given strength and smoothness by co-blending a specific oil agent and a nitrogen-containing modified silicone, but a chelating agent (α-hydroxy acid) is essential for removing calcium ions. Is.

特表２００４−５２５１９１号公報Special table 2004-525191 gazette 特開２００５−１７９１９８号公報JP, 2005-179198, A 特開２０１１−８４５８４号公報JP, 2011-84584, A

上記した従来技術の現状に鑑み、本発明は、キレート剤を含まなくてもカルシウムイオン等の多価金属イオンを有効に除去することができ、なおかつ毛髪に対するトリートメント効果も発揮する毛髪処理剤組成物を提供することを目的とする。   In view of the above-mentioned conventional state of the art, the present invention is a hair treatment composition capable of effectively removing polyvalent metal ions such as calcium ions without containing a chelating agent, and exhibiting a treatment effect on hair. The purpose is to provide.

上記の課題を解決すべく、本発明者等は鋭意研究を行った結果、アモジメチコンのマイクロエマルジョンを含む組成物で処理することにより、キレート剤を配合しなくてもカルシウムイオンを有効に除去できることを見出し、本発明を完成するに至った。   In order to solve the above-mentioned problems, the present inventors have conducted diligent research and as a result, by treating with a composition containing a microemulsion of amodimethicone, calcium ions can be effectively removed without adding a chelating agent. The present invention has been completed and the present invention has been completed.

即ち本発明は、アモジメチコンのマイクロエマルジョンを含む、毛髪からカルシウムを除去するための毛髪処理剤組成物を提供する。   That is, the present invention provides a hair treatment composition for removing calcium from hair, which comprises a microemulsion of amodimethicone.

本発明の毛髪処理剤組成物は、キレート剤を含まなくても、損傷した毛髪に蓄積されたカルシウムイオン等の多価金属イオンを有効に除去することができ、なおかつ毛髪に対するトリートメント効果も発揮する。本発明の毛髪処理剤組成物で処理した毛髪は、シャンプー処理を施した後であっても毛髪表面が疎水性のまま維持されており、滑らかで柔らかな感触が持続する。   The hair treatment composition of the present invention can effectively remove polyvalent metal ions such as calcium ions accumulated in damaged hair without containing a chelating agent, and also exhibits a treatment effect on hair. . The hair treated with the hair treatment composition of the present invention keeps its hair surface hydrophobic even after being shampooed, and has a smooth and soft feeling.

実施例１において毛髪処理剤組成物を適用する前（未処理）及び適用した後（処理）の毛髪中のカルシウム濃度を示すグラフである。5 is a graph showing calcium concentration in hair before (untreated) and after (treated) application of the hair treatment composition in Example 1.

以下、本発明について詳細に説明する。
本発明の毛髪処理剤組成物は、アモジメチコンのマイクロエマルジョンを含むことを特徴とする。
本明細書におけるアモジメチコンのマイクロエマルジョンとは、アモジメチコンを水性媒体中に分散させた水中油型の乳化物であり、その平均乳化粒子径が約１〜約５０ｎｍのものをいう。Hereinafter, the present invention will be described in detail.
The hair treatment composition of the present invention is characterized by containing a microemulsion of amodimethicone.
In the present specification, the microemulsion of amodimethicone is an oil-in-water type emulsion in which amodimethicone is dispersed in an aqueous medium, and has an average emulsion particle size of about 1 to about 50 nm.

本発明で使用されるアモジメチコンは、表示名称（ＩＮＣＩ名）がアモジメチコンであるアミノ基含有シリコーン化合物であり、例えば、下記式（Ｉ）：
（式中、Ｒ１はメチル基又は水酸基を表し、Ｒ２は-(ＣＨ２)ａ-ＮＨ-(ＣＨ２)ｂＮＨ２を表し、ｐ＝５０〜３００の整数、ｑ＝１〜１０の整数、ａ及びｂは同一でも異なっていてもよく、１〜１０の整数である）
で表される化合物が好ましく用いられる。The amodimethicone used in the present invention is an amino group-containing silicone compound whose display name (INCI name) is amodimethicone, and includes, for example, the following formula (I):
(In the formula, R 1 represents a methyl group or a hydroxyl group, R 2 represents — (CH 2 ) a —NH— (CH 2 ) b NH 2 , an integer of p = 50 to 300, and q = 1 to 10 The integers, a and b may be the same or different and are integers of 1 to 10).
The compound represented by is preferably used.

上記式（Ｉ）で表されるアモジメチコンの中でも、Ｒ１が全てメチル基であり、Ｒ２基におけるａが３、ｂが２である化合物が特に好ましい。Among the amodimethicones represented by the above formula (I), a compound in which all R 1 groups are methyl groups and a in the R 2 group is 3 and b is 2 is particularly preferable.

本発明におけるアモジメチコンのマイクロエマルジョンは、上記のようなアモジメチコンを分散相、水性媒体を連続相とするマイクロエマルジョンである。当該マイクロエマルジョンは、イオン性（アニオン性、カチオン性又は両性）あるいはノニオン性の界面活性剤、グリセリン等の多価アルコールや増粘剤といった乳化安定剤、ｐＨ調整剤などの成分を含んでいてもよい。   The microemulsion of amodimethicone in the present invention is a microemulsion having the above-mentioned amodimethicone as a dispersed phase and an aqueous medium as a continuous phase. The microemulsion may contain components such as an ionic (anionic, cationic or amphoteric) or nonionic surfactant, an emulsion stabilizer such as a polyhydric alcohol such as glycerin or a thickener, and a pH adjuster. Good.

マイクロエマルジョンに含まれるアモジメチコンの量は、安定なマイクロエマルジョンが形成される量であれば特に限定されるものではないが、例えば１〜３０質量％、好ましくは５〜２５質量％、より好ましくは１０〜２０質量％程度である。
例えば、ＢＹ２２−０７９（東レダウコーニング社製）は、１４質量％のアモジメチコン、９．４質量％の非イオン界面活性剤（ポリオキシエチレン分岐アルキル（Ｃ１２〜１４）エーテルを含む水中油型マイクロエマルジョンであり、本発明において特に好ましく使用できる。The amount of amodimethicone contained in the microemulsion is not particularly limited as long as it forms a stable microemulsion, but for example, 1 to 30% by mass, preferably 5 to 25% by mass, and more preferably It is about 10 to 20 mass%.
For example, BY22-079 (manufactured by Toray Dow Corning Incorporated) is an oil-in-water micro-type containing 14% by mass of amodimethicone and 9.4% by mass of a nonionic surfactant (polyoxyethylene branched alkyl (C12-14) ether. It is an emulsion and can be particularly preferably used in the present invention.

本発明の毛髪処理剤組成物は、前記アモジメチコンのマイクロエマルジョンを含んでいれば、毛髪からカルシウムイオンを有効に除去することができる。
毛髪処理剤組成物におけるアモジメチコンのマイクロエマルジョンの配合量は、特に限定されるものではないが、アモジメチコンの実分として、通常は、組成物全体に対して０．０１〜５質量％、好ましくは０．０５〜３質量％、より好ましくは０．１〜２質量％程度とする。アモジメチコンの配合量が０．０１質量％未満であると、実用的な時間内にカルシウムイオン除去効果が十分に得られない場合があり、５質量％を超えて配合すると、毛髪に重い感触やべたつきを生ずる場合がある。The hair treatment composition of the present invention can effectively remove calcium ions from hair if it contains the microemulsion of amodimethicone.
The amount of the microemulsion of amodimethicone in the hair treatment composition is not particularly limited, but it is usually 0.01 to 5% by mass, preferably 0.01 to 5% by mass, based on the total amount of amodimethicone as the actual content of amodimethicone. Is 0.05 to 3% by mass, more preferably about 0.1 to 2% by mass. If the amount of amodimethicone is less than 0.01% by mass, the effect of removing calcium ions may not be sufficiently obtained within a practical time. It may cause stickiness.

本発明の毛髪処理剤組成物は、アモジメチコンのマイクロエマルジョンに加えて、他の任意成分を本発明の効果を阻害しない範囲で配合することができる。
配合され得る任意成分としては、特に限定されないが、例えば、高級アルコール、炭化水素油、エステル油、シリコーン油等の油分、保湿剤、イオン性の高分子、非イオン性の高分子、イオン性の界面活性剤、非イオン性の界面活性剤、ｐＨ調整剤、防腐剤、色剤等を挙げることができる。The hair treatment composition of the present invention can contain other optional components in addition to the amodimethicone microemulsion within a range that does not impair the effects of the present invention.
The optional components that can be blended are not particularly limited, and examples thereof include oils such as higher alcohols, hydrocarbon oils, ester oils, silicone oils, humectants, ionic polymers, nonionic polymers, and ionic polymers. Examples thereof include surfactants, nonionic surfactants, pH adjustors, preservatives, coloring agents and the like.

本発明の毛髪処理剤組成物においては、マイクロエマルジョン形態のアモジメチコンが単独で毛髪からのカルシウムイオン除去効果を発揮するので、特許文献１〜３に記載されているようなキレート剤を含んでいなくてもよい。しかしながら、特許文献２、３でキレート剤として使用されているα−ヒドロキシ酸は、クエン酸等の化粧料で汎用されているｐＨ調整剤を含んでいる。従って、本発明の組成物は、クエン酸等のα−ヒドロキシ酸をｐＨ調整剤として含有する場合もある。なお、本発明の組成物のｐＨは弱酸性又は中性から弱アルカリ性とするのが好ましく、ｐＨ値で表すと４〜８、好ましくは６〜８程度である。   The hair treatment composition of the present invention does not contain a chelating agent as described in Patent Documents 1 to 3 because amodimethicone in the form of a microemulsion exerts an effect of removing calcium ions from hair by itself. You don't have to. However, the α-hydroxy acid used as a chelating agent in Patent Documents 2 and 3 contains a pH adjusting agent that is commonly used in cosmetics such as citric acid. Therefore, the composition of the present invention may contain an α-hydroxy acid such as citric acid as a pH adjuster. The pH of the composition of the present invention is preferably weakly acidic or neutral to weakly alkaline, and expressed in pH value is 4 to 8, preferably 6 to 8.

本発明の毛髪処理剤組成物は、パーマネントウェーブ処理やカラーリング処理によって損傷した毛髪に蓄積されたカルシウムイオンを効率的に除去することができる。従って、本発明の毛髪処理剤組成物は、前記のような化学処理等によって損傷を受けた毛髪に適用されるコンディショナーやトリートメントといった形態で提供するのが好ましい。   The hair treatment composition of the present invention can effectively remove calcium ions accumulated in hair damaged by permanent wave treatment or coloring treatment. Therefore, the hair treatment composition of the present invention is preferably provided in the form of a conditioner or treatment that is applied to hair damaged by the chemical treatment as described above.

本発明の毛髪処理剤組成物は、パーマネントウェーブ処理のような化学処理が施される美容室、美容院、ヘアサロン等において使用するのに特に適している。
即ち、本発明は、サロン等において、シャンプー処理及びタオルドライさせた毛髪に、アモジメチコンを含む毛髪処理剤組成物を適用して所定時間放置することを含む、毛髪からカルシウムを除去する毛髪処理方法も提供する。放置した後、当該毛髪処理剤組成物は洗い流しても流さなくてもよい。The hair treatment composition of the present invention is particularly suitable for use in a beauty salon, a beauty salon, a hair salon or the like, which is subjected to a chemical treatment such as permanent wave treatment.
That is, the present invention provides a hair treatment method for removing calcium from hair, which comprises applying a hair treatment composition containing amodimethicone to hair that has been shampooed and towel-dried in a salon or the like, and leaving it for a predetermined time. Also provide. After standing, the hair treatment composition may or may not be washed off.

前記毛髪処理方法において、毛髪処理剤組成物を適用した毛髪を放置する時間は、少なくとも３０分、好ましくは１時間程度である。しかしながら、毛髪処理剤組成物を適用した毛髪を加温することにより、放置する時間を短縮することが可能である。加温する温度は、少なくとも５０℃、好ましくは６０℃以上とする。加温することにより放置時間が約１/３に短縮される。   In the hair treatment method, the time for leaving the hair to which the hair treatment composition has been applied is at least 30 minutes, preferably about 1 hour. However, by heating the hair to which the hair treatment composition is applied, it is possible to shorten the time for leaving it. The heating temperature is at least 50 ° C, preferably 60 ° C or higher. By heating, the standing time is reduced to about 1/3.

以下、具体例を挙げて本発明を更に詳細に説明するが、これらは本発明の技術的範囲を何ら限定するものではない。
なお、以下の実施例等における配合量は特記しない限り質量％である。Hereinafter, the present invention will be described in more detail with reference to specific examples, but these do not limit the technical scope of the present invention.
In addition, the compounding amount in the following examples and the like is mass% unless otherwise specified.

（実施例１）
アモジメチコン（実分）を０．１質量％含む水中油型マイクロエマルジョンからなる毛髪処理剤組成物を調製し、当該組成物を脱色及びパーマネントウェーブ処理してシャンプー洗浄した毛髪に適用した。
所定時間経過後、毛髪に含まれるカルシウム濃度を測定した。具体的には、毛髪を５０％塩酸で９０℃、１時間処理してカルシウムを抽出し、ＩＣＰ発光分析法（Simultaneous Mode）にてカルシウム濃度を測定した。(Example 1)
A hair treatment composition consisting of an oil-in-water microemulsion containing 0.1% by weight of amodimethicone (actual content) was prepared, and the composition was applied to shampoo-washed hair that was decolorized and permanent wave treated.
After a predetermined time, the calcium concentration contained in the hair was measured. Specifically, hair was treated with 50% hydrochloric acid at 90 ° C. for 1 hour to extract calcium, and the calcium concentration was measured by ICP emission spectrometry (Simultaneous Mode).

本発明の毛髪処理剤組成物を適用する前及び適用して放置した後の毛髪中のカルシウム濃度の変化を図１のグラフに示す。
図１から明らかなように、本発明の毛髪処理剤組成物を適用することにより、毛髪中のカルシウムが除去された。なお、放置している間に毛髪を６０℃に加温することにより、カルシウム低下効速度が３倍に促進された。The graph of FIG. 1 shows changes in calcium concentration in the hair before and after the application of the hair treatment composition of the present invention and the application of the composition.
As is clear from FIG. 1, calcium in hair was removed by applying the hair treatment composition of the present invention. In addition, by heating the hair to 60 ° C. while standing, the calcium lowering effect rate was accelerated three times.

（実施例２）
下記表１に示す組成の試料（残部は水）を調製した。脱色及びパーマネント処理を施して損傷を与え感触の悪化した毛髪の束に各試料を適用し、ドライヤーで乾燥させた後の感触を評価した。
評価は専門パネルにより実施し、以下の基準に基づいて評価した。
［評価基準]
×（１）：ざらついた悪い感触
△（２）：ややざらついているが感触は改善された
○（３）：感触が良好
△（４）：やや重いが感触は改善された
×（５）：べたつきがあり感触が悪い(Example 2)
A sample having the composition shown in Table 1 below (the balance being water) was prepared. Each sample was applied to a bundle of hair that had been bleached and had been permanently treated to cause damage and worsen the feel, and the feel after being dried with a dryer was evaluated.
The evaluation was carried out by a specialized panel and evaluated based on the following criteria.
[Evaluation criteria]
× (1): Rough and bad feeling △ (2): Slightly rough but improved feeling ○ (3): Good feeling △ (4): Slightly heavy but improved feeling × (5): Sticky and uncomfortable

図１及び表１に示した結果から、アモジメチコンのマイクロエマルジョンを含む組成物で処理することにより、毛髪中のカルシウムを除去できるのみならず、毛髪の感触を改善することができることが確認された。このような感触改善効果は一般的な金属イオンキレート剤であるＥＤＴＡや特許文献２及び３で使用されている乳酸では得られない効果である。   From the results shown in FIG. 1 and Table 1, it was confirmed that treatment with the composition containing the microemulsion of amodimethicone can not only remove calcium in the hair but also improve the feel of the hair. . Such a touch-improving effect is an effect that cannot be obtained with EDTA which is a general metal ion chelating agent and lactic acid used in Patent Documents 2 and 3.

（実施例３）
シリコーンの種類又は乳化粒子径による効果の相違を確認した。
下記表２に示すジメチコン又はアモジメチコンを同量（１質量％）の実分で含有するエマルジョン又はマイクロエマルジョンの試料を調製した。
脱色及びパーマネント処理を施して損傷を与えた毛髪の束に各試料を適用し、適用前及び適用後における毛髪中のカルシウム濃度を実施例１の要領で測定した。(Example 3)
The difference in the effect depending on the type of silicone or the emulsion particle size was confirmed.
Samples of emulsions or microemulsions containing dimethicone or amodimethicone shown in Table 2 below in the same amount (1% by mass) of actual components were prepared.
Each sample was applied to a bleached and permanent-treated damaged hair bundle, and the calcium concentration in the hair before and after the application was measured in the same manner as in Example 1.

その結果、シリコーンとしてジメチコンを配合したエマルジョン及びマイクロエマルジョン（試料Ａ〜Ｃ）及びアモジメチコンを配合したエマルジョン（試料Ｄ、Ｅ）に比較して、アモジメチコンを配合したマイクロエマルジョン（試料Ｆ）は、毛髪からのカルシウム除去効果が格段に優れていた。
また、各試料で処理した後の毛髪表面の接触角を測定したところ、いずれも表面が疎水化されていたが、更にシャンプー処理を施した後に測定した結果、アモジメチコンを配合したマイクロエマルジョン（試料Ｆ）で処理した毛髪以外は、接触角が小さくなり親水化されたのに対し、試料Ｆで処理した毛髪はシャンプー処理後でも疎水化された表面が保持されており、滑らかで柔らかい感触が得られることが確認された。As a result, compared to the emulsions and microemulsions (Samples A to C) containing dimethicone as silicone and the emulsions (Samples D and E) containing amodimethicone, the microemulsion containing Amodimethicone (Sample F) The effect of removing calcium from hair was remarkably excellent.
In addition, when the contact angle of the hair surface after treatment with each sample was measured, it was found that the surface was hydrophobized in both cases, but after the shampoo treatment was further performed, the measurement result showed that the microemulsion containing amodimethicone (sample Other than the hair treated with F), the contact angle was reduced and the hair was hydrophilized, whereas the hair treated with Sample F retained the hydrophobic surface even after shampoo treatment, and a smooth and soft feel was obtained. It was confirmed that

Claims (1)

アモジメチコンのマイクロエマルジョンからなり、前記マイクロエマルジョンが５０ｎｍ以下の平均乳化粒子径を有する毛髪カルシウム除去剤であって、
前記アモジメチコンが、下記式（Ｉ）：
（式中、Ｒ １ はメチル基を表し、Ｒ ２ は-(ＣＨ ２ ) ａ −ＮＨ−(ＣＨ ２ ) ｂ ＮＨ ２ を表し、ｐ＝５０〜３００の整数、ｑ＝１〜１０の整数、ａ＝３及びｂ＝２である）
で表される、毛髪カルシウム除去剤。 A hair calcium remover comprising an amodimethicone microemulsion, the microemulsion having an average emulsified particle size of 50 nm or less ,
The amodimethicone has the following formula (I):
(Wherein, R 1 represents a methyl group, R 2 is - (CH 2) a -NH- ( CH 2) represents a b NH 2, integers p = 50~300, q = 1~10 integer, a = 3 and b = 2)
A hair calcium remover represented by .
JP2015522762A 2013-06-13 2014-06-09 Hair treatment composition Active JP6685726B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2013124332 2013-06-13
JP2013124332 2013-06-13
PCT/JP2014/065189 WO2014199936A1 (en) 2013-06-13 2014-06-09 Hair treatment composition

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2018236316A Division JP2019069975A (en) 2013-06-13 2018-12-18 Hair treatment agent composition

Publications (2)

Publication Number Publication Date
JPWO2014199936A1 JPWO2014199936A1 (en) 2017-02-23
JP6685726B2 true JP6685726B2 (en) 2020-04-22

Family

ID=52022232

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2015522762A Active JP6685726B2 (en) 2013-06-13 2014-06-09 Hair treatment composition
JP2018236316A Pending JP2019069975A (en) 2013-06-13 2018-12-18 Hair treatment agent composition

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2018236316A Pending JP2019069975A (en) 2013-06-13 2018-12-18 Hair treatment agent composition

Country Status (5)

Country Link
JP (2) JP6685726B2 (en)
KR (1) KR102241232B1 (en)
CN (1) CN105377231B (en)
HK (1) HK1215684A1 (en)
WO (1) WO2014199936A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3311794A1 (en) * 2016-10-19 2018-04-25 Kao Germany GmbH Cosmetic composition comprising two optical brighteners, method, use, and kit-of-parts thereof
EP3329904A1 (en) * 2016-12-05 2018-06-06 Kao Germany GmbH Cosmetic composition for enhancing properties of pre-colored keratin fibers
WO2020090951A1 (en) * 2018-11-02 2020-05-07 株式会社 資生堂 Hair treatment method
CN115317407B (en) * 2022-09-13 2023-08-22 广州品尚生物科技发展有限公司 Liquid hair conditioner and preparation method thereof

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2002303139B2 (en) 2001-03-20 2005-06-30 Noxell Corporation Compositions suitable for the treatment of hair comprising chelants and methods for reducing oxidative hair damage
JP2005179198A (en) 2003-12-16 2005-07-07 Lion Corp Hair cosmetic
JP4129645B2 (en) * 2004-08-30 2008-08-06 ライオン株式会社 Shampoo composition
KR20070078569A (en) * 2006-01-27 2007-08-01 주식회사 엘지생활건강 Transparent shampoo composition
JP2008297246A (en) * 2007-05-31 2008-12-11 Lion Corp Cosmetic composition and method for preserving and stabilizing cosmetic composition
JP5207697B2 (en) * 2007-09-25 2013-06-12 株式会社 資生堂 Hair cosmetics
JP2010150175A (en) * 2008-12-25 2010-07-08 Milbon Co Ltd Shampoo composition
CN102596166B (en) * 2009-11-12 2014-12-03 花王株式会社 Hair cosmetic
JP5688947B2 (en) * 2010-10-27 2015-03-25 株式会社ミルボン Hair treatment agent
JP5111628B2 (en) 2011-01-28 2013-01-09 ライオン株式会社 Hair cosmetics
JP2012176996A (en) 2012-06-22 2012-09-13 Momentive Performance Materials Inc Hair cosmetic composition

Also Published As

Publication number Publication date
WO2014199936A1 (en) 2014-12-18
KR20160018453A (en) 2016-02-17
CN105377231B (en) 2018-06-22
HK1215684A1 (en) 2016-09-09
JP2019069975A (en) 2019-05-09
JPWO2014199936A1 (en) 2017-02-23
CN105377231A (en) 2016-03-02
KR102241232B1 (en) 2021-04-16

Similar Documents

Publication Publication Date Title
JP2019069975A (en) Hair treatment agent composition
JP6440835B2 (en) Method for reducing crimp using a composition containing crosslinkable silicone
JP6591557B2 (en) Hair beauty treatment method
WO2014073711A1 (en) Hair treatment agent composition
JP2004018509A (en) Composition for hair treatment
JP4756249B2 (en) Multi-agent hair cosmetic
JP2006306823A (en) Method for treating hair
JP2010077092A (en) Second agent for hair deformation, hair deforming agent and method for hair deformation
JP2009269879A (en) Hair cosmetic composition and method for using the same
JP2012082169A (en) Hair treating agent
JP4866600B2 (en) How to increase the saturation of hair
JP5594608B2 (en) Modified silicone-containing multi-agent hair rinse or hair treatment
JP5714233B2 (en) Hair deformation agent
JP2004018414A (en) Hair-treating agent
JP2011073991A (en) Hair treating agent
JP2013095696A (en) First agent and second agent for permanent wave and hair treatment method
JP6599851B2 (en) In bath treatment composition
JP2004059559A (en) Keratinous fiber f-layer damage-repairing agent and hair cosmetic containing the same
JP2003081774A (en) Two bottle-type hair treatment agent
KR20120049122A (en) Emulsified hair cosmetics
JP5295520B2 (en) Curl forming cosmetic
JP5774263B2 (en) Emulsifying hair cosmetics
JP5124381B2 (en) Hair cosmetic and hair treatment method
EP3290019A1 (en) Hair treatment method
JP6856237B2 (en) Hair treatment agent

Legal Events

Date Code Title Description
A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20170525

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20170525

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20180713

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20180906

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20180921

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20181218

A911 Transfer of reconsideration by examiner before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20190128

A912 Removal of reconsideration by examiner before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A912

Effective date: 20190315

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20191219

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20191219

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20200401

R150 Certificate of patent or registration of utility model

Ref document number: 6685726

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150