JP6645421B2 - Polyester hollow fiber sphere - Google Patents

Polyester hollow fiber sphere Download PDF

Info

Publication number
JP6645421B2
JP6645421B2 JP2016505635A JP2016505635A JP6645421B2 JP 6645421 B2 JP6645421 B2 JP 6645421B2 JP 2016505635 A JP2016505635 A JP 2016505635A JP 2016505635 A JP2016505635 A JP 2016505635A JP 6645421 B2 JP6645421 B2 JP 6645421B2
Authority
JP
Japan
Prior art keywords
fiber
hollow fiber
polyester
polyester hollow
spherical body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2016505635A
Other languages
Japanese (ja)
Other versions
JPWO2016121643A1 (en
Inventor
吉田 哲弘
哲弘 吉田
俊馬 宮内
俊馬 宮内
皓太 安達
皓太 安達
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Publication of JPWO2016121643A1 publication Critical patent/JPWO2016121643A1/en
Application granted granted Critical
Publication of JP6645421B2 publication Critical patent/JP6645421B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4391Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece characterised by the shape of the fibres
    • D04H1/43918Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece characterised by the shape of the fibres nonlinear fibres, e.g. crimped or coiled fibres
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326Condensation or reaction polymers
    • D04H1/435Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4391Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece characterised by the shape of the fibres
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4391Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece characterised by the shape of the fibres
    • D04H1/43914Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece characterised by the shape of the fibres hollow fibres
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • D04H1/76Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres otherwise than in a plane, e.g. in a tubular way

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Artificial Filaments (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Nonwoven Fabrics (AREA)

Description

本発明は、ポリエステル中空繊維球状体に関するものである。さらに詳しくは、本発明は、軽量でかつ優れたかさ高性を有するだけでなく、柔らかくかつ羽毛に近似した風合いに富み保温性に優れ、クッションやダウンジャケット等の中綿素材として好適に用いられるポリエステル中空繊維を用いてなる繊維球状体に関するものである。   TECHNICAL FIELD The present invention relates to a polyester hollow fiber spherical body. More specifically, the present invention is a polyester which is not only lightweight and has excellent bulkiness, but also has a soft and rich texture close to feathers and excellent heat retention, and is preferably used as a batting material such as a cushion or a down jacket. The present invention relates to a fibrous spherical body using hollow fibers.

従来、ダウンジャケットおよびシュラフの中綿素材やクッション材として、羽毛やポリエステル系短繊維が広く用いられている。   Conventionally, feathers and polyester-based short fibers have been widely used as batting materials and cushioning materials for down jackets and shuffles.

羽毛は、一般的に水鳥の羽毛が使用され、風合いに富み軽量で保温性に優れ、体に沿いやすくかさ高に優れており回復率の高いことが知られている。しかしながら、天然の羽毛を得ようとした場合、その供給量には限度がある上、自然条件や疫病の影響によって供給量が変動するという課題がある。   It is known that feathers of waterfowl are generally used, and are rich in texture, lightweight, excellent in heat retention, easy to follow the body, excellent in bulkiness, and high in recovery rate. However, when trying to obtain natural feathers, there is a problem in that the supply amount is limited, and the supply amount fluctuates due to natural conditions and the effects of plague.

さらには、自然保護の観点から、野生の鳥を捕捉することには限度があり、水鳥を飼育して羽毛を得ようとした場合、多くの水鳥を飼育しなければならず、その結果、多量の飼料を必要とするだけでなく、水鳥の排泄物による水質汚染や感染症の発生とその拡散という課題が生じている。   Furthermore, from the viewpoint of nature conservation, catching wild birds is limited, and when raising waterfowl to obtain feathers, many waterfowl must be bred. In addition to the need for feed, the problem of water pollution and the spread of infectious diseases due to the excrement of water birds has arisen.

また、羽毛を詰め綿として使用できるようにするためには、採毛、選別、消毒、脱脂および布団詰めなどの多くの工程を経る必要があり、かつ、羽毛が舞い上がるという点でも作業が繁雑になり、その結果、羽毛を使った製品具の価格は高くなるという傾向がある。   Also, in order to be able to use feathers as wadding, it is necessary to go through many steps such as hair collection, sorting, disinfection, degreasing and packing with futons, and work is complicated in that feathers fly up. As a result, the price of products using feathers tends to be higher.

さらには、採毛時に羽毛の末端に肉が残り腐敗臭の原因になったり、欧州等では動物愛護の観点から羽毛を排除する動きも出ている。   Further, meat is left at the ends of feathers during hair sampling, causing a rotten smell. In Europe and the like, there is a movement to remove feathers from the viewpoint of animal welfare.

一方、ポリエステル系短繊維は、安価でかさ高性に優れており、繊維製造時の製糸性や不織布等の製品に加工する際の加工性が良好である。そのため、ポリエステル短繊維をカードなどで開繊し繊維ウェッブを層状に積層したシートを、側地で覆う方法がよく知られている。しかしながら、この方法では、層状の繊維ウェッブ積層体を側地で覆うために手間がかかるという課題がある。   On the other hand, polyester-based short fibers are inexpensive and excellent in bulkiness, and have good thread formability during fiber production and good workability when processed into products such as nonwoven fabrics. For this reason, a method of spreading polyester short fibers with a card or the like and laminating a fiber web in a layered form and covering the sheet with a side material is well known. However, this method has a problem that it takes time and effort to cover the layered fiber web laminate with the side ground.

このような課題に対し、風合いがソフトで弾力性に優れ、圧縮耐久性に優れた形態安定性を有する高弾性繊維球状体(ファイバーボール)からなる中綿が提案されている(特許文献1および特許文献2参照。)。   In order to solve such a problem, batting comprising a high elastic fiber spherical body (fiber ball) having soft texture, excellent elasticity, and excellent morphological stability with excellent compression durability has been proposed (Patent Document 1 and Patent Document 1). Reference 2).

さらに、球状綿の主体素材として、ポリエステル繊維、ポリアミド繊維、ポリオレフィン繊維およびアクリル繊維が提案されている(特許文献3および特許文献4参照。)。   Furthermore, polyester fibers, polyamide fibers, polyolefin fibers, and acrylic fibers have been proposed as main materials of spherical cotton (see Patent Documents 3 and 4).

しかしながら、前記の特許文献1、特許文献2、特許文献3および特許文献4の提案では、使用される繊維素材が例えば、ポリエステル繊維とバインダー繊維からなる繊維球状体であり、球状体形成時に熱風等によりバインダー繊維を熱融着させるため、熱形成時に繊維が収縮して密度の高い繊維球状体になることにより球状体としてのソフト性が劣ったり、熱接着部があるために球状体のソフト性が劣るという課題がある。   However, in the proposals of Patent Literature 1, Patent Literature 2, Patent Literature 3, and Patent Literature 4, the fiber material to be used is, for example, a fiber sphere made of polyester fiber and binder fiber. Due to the thermal fusion of the binder fibers, the fibers shrink during heat formation and become high-density fiber spheres, resulting in poor softness of the spheres, or the softness of the spheres due to the presence of the heat bonding part Is inferior.

さらに別に、球状綿の表面にバインダー液を噴霧し型成形し、球状綿の表面と他の球状綿の表面間が接着されてなるクッション材が提案されている(特許文献5参照。)。しかしながら、この提案では、球状綿にバインダー液を噴霧し型形成するため、球状体同士を接着させることにより、最終製品への加工性、すなわち、吹き込み性が劣ったり球状体の流動性が劣ったり、かさ高が低下するという課題がある。   Further, a cushioning material has been proposed in which a binder liquid is sprayed on a surface of a spherical cotton and molded, and the surface of the spherical cotton and the surface of another spherical cotton are bonded to each other (see Patent Document 5). However, in this proposal, the binder liquid is sprayed onto the spherical cotton to form a mold. By adhering the spherical bodies to each other, the workability into a final product, that is, the blowing property is poor or the flowability of the spherical body is poor. However, there is a problem that the bulk is reduced.

また、トウを延伸後、熱処理し、表面に付与したシリコーン平滑剤を熱硬化させ、切断後に再度熱処理させた繊維を形成した繊維球状体が提案されている(特許文献6参照。)。しかしながら、トウを延伸後、熱処理し、シリコーン平滑剤を硬化させ、切断後に再度熱処理させており、トウを切断前に熱硬化しているために、けん縮形態は、三次元のらせん状となり、かつ、S方向、Z方向のものがランダムなものとなり、得られる繊維球状体は絡まりすぎ、風合いが硬く、さらには、嵩高性が劣るという課題がある。   Further, there has been proposed a fibrous spherical body in which a tow is stretched, heat-treated, a silicone smoothing agent applied to the surface is heat-cured, and after cutting, the fiber is heat-treated again (see Patent Document 6). However, after the tow is stretched and heat-treated, the silicone smoothing agent is cured, and the heat treatment is performed again after the cutting.The crimped form becomes a three-dimensional spiral because the tow is heat-cured before the cutting. In addition, there is a problem that the fibers in the S and Z directions are random, and the resulting fiber spheres are too entangled, the texture is hard, and the bulkiness is poor.

特開2002−212868号公報JP 2002-212868 A 特開2007−169846号公報JP 2007-169846 A 特開H10−259559号公報JP H10-259559 A 特開S61−125377号公報JP-A-S61-125377 特開2003−169978号公報JP-A-2003-169978 特開昭62−033856号公報JP-A-62-033856

そこで本発明の目的は、上述した従来技術における課題を解決し、軽量でかつ優れたかさ高性を有するだけでなく、柔らかくかつ羽毛に近似した風合いに富み、クッションやダウンジャケット等の中綿素材として好適に用いられるポリエステル中空繊維球状体を提供することにある。   Therefore, an object of the present invention is to solve the above-mentioned problems in the prior art, and not only to have a light weight and excellent bulkiness, but also to be soft and rich in texture close to feathers, as a batting material such as a cushion or a down jacket. An object of the present invention is to provide a polyester hollow fiber spherical body which is suitably used.

本発明者らは、軽量性とかさ高を兼ね備えた繊維球状体を得るためには、ポリエステル中空繊維を用いることが好適であると考えた。また、ポリエステル中空繊維のけん縮形態と得られた繊維球状体のかさ高との関係に着目し、適正なけん縮形態を得るための検討を重ねた。さらに、ポリエステル中空繊維の単繊維繊度と中空率の検討も重ね、本発明に想到したものである。   The present inventors considered that it is preferable to use a polyester hollow fiber in order to obtain a fiber spherical body having both lightness and bulkiness. In addition, attention was paid to the relationship between the crimped form of the polyester hollow fiber and the bulk of the obtained fiber sphere, and studies were repeated to obtain an appropriate crimped form. Furthermore, the inventors have studied the single fiber fineness and hollow ratio of the polyester hollow fiber, and have arrived at the present invention.

すなわち、本発明は、上記目的を達成せんとするものであって、本発明のポリエステル中空繊維球状体は、単繊維繊度が2.0〜6.6dtex、中空率が15〜35%、けん縮数が2〜8山/25mm、けん縮率が6〜14%、繊維長が20〜50mmである繊維球状体であり、かさ高が8,200以上〜11,500cm/50g以下であることを特徴とするポリエステル中空繊維球状体である。
本発明のポリエステル中空繊維球状体の好ましい態様によれば、前記のポリエステル中空繊維の固有粘度は0.60〜0.75である。
本発明のポリエステル中空繊維球状体の好ましい態様によれば、前記のポリエステル中空繊維の質量に対してポリシロキサンを含む油剤が0.3〜1.0質量%の割合で付着されている。
本発明のポリエステル中空繊維球状体の好ましい態様によれば、前記のポリエステル中空繊維の繊維摩擦係数μsが0.06〜0.14である。
That is, the present invention is intended to achieve the above object, and the polyester hollow fiber spherical body of the present invention has a single fiber fineness of 2.0 to 6.6 dtex, a hollow ratio of 15 to 35%, and a crimp. number 2-8 peaks / 25 mm, crimp ratio 6 to 14%, a fiber spheres fiber length of 20 to 50 mm, it bulky is 8,200 or more ~11,500cm 3 / 50g or less And a polyester hollow fiber sphere.
According to a preferred embodiment of the polyester hollow fiber spherical body of the present invention, the intrinsic viscosity of the polyester hollow fiber is 0.60 to 0.75.
According to a preferred embodiment of the polyester hollow fiber spherical body of the present invention, an oil agent containing polysiloxane is attached at a ratio of 0.3 to 1.0% by mass based on the mass of the polyester hollow fiber.
According to a preferred embodiment of the polyester hollow fiber spherical body of the present invention, the polyester hollow fiber has a fiber friction coefficient μs of 0.06 to 0.14.

本発明のポリエステル中空繊維球状体の好ましい態様によれば、前記のポリエステル中空繊維の次式(1)に示されるけん縮率数比は、1.5〜3.0である。
・けん縮率数比=けん縮率/けん縮数・・・・(1)。
According to a preferred embodiment of the polyester hollow fiber spherical body of the present invention, the crimp ratio ratio of the polyester hollow fiber represented by the following formula (1) is 1.5 to 3.0.
-Ratio of crimp ratio = crimp ratio / number of crimps ... (1).

本発明の前記のポリエステル中空繊維球状体の製造方法は、ポリエステルを中空糸用紡糸口金から紡出し、紡出糸の片側から冷却風を吹き付けて非対称冷却した後に引き取り、熱延伸後、けん縮付与工程を介さずにポリシロキサンを含む油剤を付与し、所定の繊維長に切断後、加熱スチーム処理によりスパイラル状にけん縮発現させた後に熱セットして、ポリエステル中空繊維を得、得られたポリエステル中空繊維を開繊して繊維球状体に加工することを特徴とするポリエステル中空繊維球状体の製造方法である。   The method for producing a spherical polyester hollow fiber spherical body of the present invention comprises spinning polyester from a spinneret for a hollow fiber, blowing a cooling air from one side of the spun yarn, asymmetrically cooling the yarn, taking it up, applying heat, and crimping. Applying an oil agent containing polysiloxane without going through a process, cutting to a predetermined fiber length, crimping in a spiral shape by heating steam treatment, and then heat setting to obtain a polyester hollow fiber, the obtained polyester This is a method for producing a polyester hollow fiber sphere, characterized in that the hollow fiber is opened and processed into a fiber sphere.

本発明によれば、軽量でかつ優れたかさ高性を有するだけでなく、柔らかくかつ羽毛に近似した風合いに富み保温性に優れ、クッションやダウンジャケット等の中綿素材として好適に用いられるポリエステル中空繊維を用いてなる繊維球状体が得られる。   According to the present invention, polyester hollow fibers that are not only lightweight and have excellent bulkiness, but also have a soft and rich texture close to feathers and have excellent heat retention, and are preferably used as a batting material such as a cushion or a down jacket. Is obtained.

図1は、本発明のポリエステル中空繊維球状体を例示する図面代用写真である。FIG. 1 is a photograph as a substitute of a drawing, which illustrates the polyester hollow fiber spherical body of the present invention.

次に、本発明のポリエステル中空繊維球状体とその製造方法の実施態様について、具体的に説明する。   Next, embodiments of the polyester hollow fiber spherical body and the method for producing the same according to the present invention will be specifically described.

本発明のポリエステル中空繊維球状体は、固有粘度が0.60〜0.75のポリエステルからなるポリエステル中空繊維であって、単繊維繊度が2.0〜6.6dtex、中空率が15〜35%、けん縮数が2〜8山/25mm、けん縮率が6〜14%、繊維長が20〜50mmであり、ポリエステル繊維質量に対してポリシロキサンを含む油剤が0.3〜1.0%の割合で付着されている、繊維摩擦係数μsが0.06〜0.14のポリエステル中空繊維を用いてなる繊維球状体であり、かつ、かさ高が8,200以上〜11,500cm/50g以下のポリエステル中空繊維からなる球状体である。The polyester hollow fiber spherical body of the present invention is a polyester hollow fiber composed of polyester having an intrinsic viscosity of 0.60 to 0.75, and has a single fiber fineness of 2.0 to 6.6 dtex and a hollow ratio of 15 to 35%. The number of crimps is 2 to 8 peaks / 25 mm, the crimp ratio is 6 to 14%, the fiber length is 20 to 50 mm, and the oil containing polysiloxane is 0.3 to 1.0% based on the mass of the polyester fiber. is attached at the rate of a fiber spheroids fiber friction coefficient μs is obtained by using the polyester hollow fibers of 0.06 to 0.14, and a bulk height 8,200 or more ~11,500cm 3 / 50g It is a spherical body composed of the following polyester hollow fibers.

本発明で用いられるポリエステル中空繊維を構成するポリエステルとしては、ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリトリメチレンテレフタレート、ポリエチレンナフタレートおよびポリブチレンナフタレートなどが挙げられるが、中でもポリエチレンテレフタレートが好ましく用いられる。   Examples of the polyester constituting the polyester hollow fiber used in the present invention include polyethylene terephthalate, polybutylene terephthalate, polytrimethylene terephthalate, polyethylene naphthalate, and polybutylene naphthalate. Of these, polyethylene terephthalate is preferably used.

本発明で用いられるポリエステルの固有粘度は、0.60〜0.75とするであることが好ましい。固有粘度は、さらに好ましくは、0.62〜0.72である。固有粘度が0.6未満では、けん縮の発現力が低下して捲縮が低くなることにより、繊維球状体への加工において繊維が球状に丸まり難くなり、繊維球状体の形成が難しくなる。さらには、繊維の剛性も低くなることにより、十分なかさ高を有する繊維球状体が得られない場合がある。一方、固有粘度が0.75を超えると、溶融粘度が高くなり繊維の製造が困難となる場合がある。   The intrinsic viscosity of the polyester used in the present invention is preferably 0.60 to 0.75. The intrinsic viscosity is more preferably 0.62 to 0.72. When the intrinsic viscosity is less than 0.6, crimping power is reduced and crimping is reduced, so that it becomes difficult for the fiber to be rounded into a spherical shape in processing into a fibrous spherical body, and it is difficult to form a fibrous spherical body. Further, due to the low rigidity of the fiber, a fibrous body having a sufficient bulk may not be obtained in some cases. On the other hand, when the intrinsic viscosity exceeds 0.75, the melt viscosity becomes high, and it may be difficult to produce fibers.

本発明で用いられるポリエステル中空繊維の単繊維繊度は、2.0〜6.6dtexであることが重要である。単繊維繊度は、好ましくは2.2〜4.4dtexである。正量単繊維繊度が2.0dtex未満になると、正量単繊維繊度が細くなるため、けん縮の発現力が低下して捲縮が低くなることにより、繊維球状体への加工において繊維が球状に丸まり難くなり、繊維球状体の形成が難しくなる。さらには、繊維の剛性が低くなることにより、かさ高に欠ける繊維球状体となる。一方、単繊維繊度が6.6dtexを超えると、繊維とした際の剛性が高くなることにより、柔らかくかつ羽毛に近似した繊維球状体が得られない。   It is important that the single fiber fineness of the polyester hollow fiber used in the present invention is 2.0 to 6.6 dtex. The single fiber fineness is preferably 2.2 to 4.4 dtex. When the single fiber fineness of the positive quantity is less than 2.0 dtex, the fineness of the single weight fiber becomes thin, so that the crimp expression power is reduced and the crimp is reduced, so that the fibers are spherical in the processing into the fiber spherical body. And it is difficult to form a fiber spherical body. Furthermore, the rigidity of the fiber is reduced, resulting in a fiber spherical body lacking in bulk. On the other hand, if the single-fiber fineness exceeds 6.6 dtex, the rigidity of the fiber becomes high, so that a fiber spherical body that is soft and approximates to feathers cannot be obtained.

本発明で用いられるポリエステル中空繊維の中空率は、15〜35%であることが重要である。中空率は、より好ましくは20〜30%である。中空率が15%未満になると、非対称冷却不足となり、けん縮の発現力が低下し捲縮が低くなることにより、繊維球状体への加工において繊維が球状に丸まり難くなり、繊維球状体の形成が難しくなる。一方、中空率が35%を超えると、製糸での糸切れが多く安定した繊維製造が困難となることがある。   It is important that the hollow ratio of the polyester hollow fiber used in the present invention is 15 to 35%. The hollow ratio is more preferably 20 to 30%. When the hollow ratio is less than 15%, the asymmetric cooling is insufficient, the crimping power is reduced, and the crimp is reduced. Becomes difficult. On the other hand, if the hollow ratio exceeds 35%, it may be difficult to produce a stable fiber with many yarn breaks in the yarn production.

このポリエステル中空繊維の中空率は、繊維横断面拡大写真によって、中空部分を含めた繊維断面の全面積に対する中空部分面積の割合を算出し、%で表示することができる。   The hollow ratio of this polyester hollow fiber can be expressed by% by calculating the ratio of the area of the hollow portion to the entire area of the fiber cross section including the hollow portion by using an enlarged photograph of the fiber cross section.

本発明において、中空とは、繊維横断面において、繊維外形内部に空洞部を有することをいう。空洞部は、好ましくは繊維中心部に位置するものであるが、繊維中心部からずれて偏心で位置するものもあるが、空洞部は、好ましくは繊維中心に位置するものである。   In the present invention, the term “hollow” means having a hollow portion inside the outer shape of the fiber in the cross section of the fiber. The hollow portion is preferably located at the center of the fiber. However, although there are some which are located eccentrically off the center of the fiber, the hollow portion is preferably located at the center of the fiber.

中空率は、口金設計、ポリエステル固有粘度および冷却条件に依存し、当業者がおのおのの特定の設定によって制御することができる。   The porosity depends on the die design, polyester intrinsic viscosity and cooling conditions, and can be controlled by one of ordinary skill in the art through each specific setting.

本発明で用いられるポリエステル中空繊維のけん縮数は、2〜8山/25mmであることが重要である。けん縮数は、好ましくは3〜7山/25mmである。けん縮数が2山/25mm未満になると、繊維球状体への加工において繊維が球状に丸まり難くなり、繊維球状体の形成が難しくなる。一方、けん縮数が8山/25mmを超えると、得られた繊維球状体の直径が小さく、その密度が高くなることで、かさ高に欠ける繊維球状体となる。   It is important that the number of crimps of the polyester hollow fiber used in the present invention is 2 to 8 peaks / 25 mm. The number of crimps is preferably 3 to 7 peaks / 25 mm. When the number of crimps is less than 2 peaks / 25 mm, it becomes difficult for the fiber to be rounded into a spherical shape in processing into a fibrous spherical body, and it is difficult to form a fibrous spherical body. On the other hand, when the number of crimps exceeds 8 peaks / 25 mm, the diameter of the obtained fibrous spherical body is small, and the density is increased, whereby the fibrous spherical body lacks bulk.

本発明で用いられるポリエステル中空繊維のけん縮率は、6〜14%であることが好ましい。けん縮率は、6より好ましくは8〜12%である。けん縮率が6%未満になると、繊維球状体への加工において繊維が球状に丸まり難くなり、繊維球状体の形成が難しくなる。一方、けん縮率が14%を超えると、得られた繊維球状体の直径が小さくなり密度が高くなるため、かさ高に欠ける繊維球状体となる。   The crimping ratio of the polyester hollow fiber used in the present invention is preferably 6 to 14%. The crimp ratio is more preferably 6 to 8 to 12%. When the crimping ratio is less than 6%, the fibers are hard to be rounded into a spherical shape in processing into a fibrous spherical body, and it is difficult to form the fibrous spherical body. On the other hand, when the crimp ratio exceeds 14%, the diameter of the obtained fiber sphere becomes small and the density becomes high, so that the fiber sphere lacks bulk.

本発明で用いられるポリエステル中空繊維の繊維長は、20〜50mmであることが重要である。繊維長は、好ましくは25〜40mmである。繊維長が20mm未満になると、繊維球状体への加工において繊維同士の絡みが弱くなり、繊維の絡みが解除されることにより、球状体の形状維持が難しくなる。一方、繊維長が50mmを超えると、繊維球状体への加工において繊維が球状に丸まり難くなり、繊維球状体の形成が難しくなり、さらには繊維球状体同士が絡み易くなることにより、流動性に欠け製品品位が悪化する。   It is important that the fiber length of the polyester hollow fiber used in the present invention is 20 to 50 mm. The fiber length is preferably 25 to 40 mm. If the fiber length is less than 20 mm, the entanglement of the fibers becomes weaker in the processing into the fiber sphere, and the entanglement of the fiber is released, making it difficult to maintain the shape of the sphere. On the other hand, when the fiber length exceeds 50 mm, the fibers are hard to be rounded into a spherical shape in processing into a fibrous spherical body, forming a fibrous spherical body becomes difficult, and furthermore, the fibrous spherical bodies are easily entangled with each other, so that the fluidity is reduced. Chipped product quality deteriorates.

本発明で用いられるポリエステル中空繊維の質量に対して、ポリシロキサンを含む油剤は、0.3〜1.0質量%の範囲(割合)で付与され付着していることが好ましい。油剤付着量は、さらに好ましくは0.4〜0.8質量%である。ポリシロキサンを含む油剤が0.3質量%未満では、繊維の平滑性が低くなり繊維球状体同士が絡み易くなることにより、繊維球状体の流動性に欠け製品品位が悪化する場合がある。一方、油剤付着量が1.0質量%を超えても、それ以上の繊維平滑性の向上は認められず、原単位の悪化に繋がる場合がある。   It is preferable that the oil agent containing the polysiloxane is provided and adhered in a range (ratio) of 0.3 to 1.0% by mass with respect to the mass of the polyester hollow fiber used in the present invention. The amount of the oil agent attached is more preferably 0.4 to 0.8% by mass. When the amount of the oil agent containing polysiloxane is less than 0.3% by mass, the smoothness of the fibers is reduced, and the fiber spheres are easily entangled with each other. On the other hand, even if the amount of the oil agent attached exceeds 1.0% by mass, no further improvement in the fiber smoothness is observed, which may lead to deterioration of the basic unit.

本発明で用いられるポリシロキサンとしては、例えば、アミノ変性シリコーンなどを使用することができる。ポリエステル中空繊維にポリシロキサンを付与し付着させるためには、ポリシロキサン含む油剤を付与することにより実施することができる。この油剤には、ポリシロキサン他に、リン酸系化合物、脂肪族化合物およびハロゲン系化合物を含むことが好ましく、さらには、酸化防止剤、防燃剤および静電防止剤を含んでいることが好ましい態様である。   As the polysiloxane used in the present invention, for example, amino-modified silicone can be used. The application and attachment of the polysiloxane to the polyester hollow fiber can be carried out by applying an oil agent containing the polysiloxane. The oil preferably contains a phosphoric acid compound, an aliphatic compound and a halogen compound in addition to the polysiloxane, and further preferably contains an antioxidant, a flame retardant and an antistatic agent. It is.

このポリシロキサンを含む油剤の付与は、本発明で用いられるポリエステル中空繊維の短繊維を製造する工程においては、トウをカットする直前において付与されることが好ましい。油剤付与の際には、ポリシロキサンの濃度を好ましくは3〜10質量%、さらに好ましくは4〜8質量%である油剤水溶液にしてポリエステル中空繊維に付与し、その後任意の温度で乾燥することが好ましい。   In the step of producing the polyester hollow fiber short fibers used in the present invention, the oil agent containing the polysiloxane is preferably applied immediately before cutting the tow. At the time of applying the oil agent, it is possible to apply an oil solution having a polysiloxane concentration of preferably 3 to 10% by mass, more preferably 4 to 8% by mass, apply it to the polyester hollow fiber, and then dry it at an arbitrary temperature. preferable.

本発明で用いられるポリエステル中空繊維の繊維摩擦係数μsは、0.06〜0.14であることが好ましい。繊維摩擦係数μsは、さらに好ましくは0.07〜0.12である。繊維摩擦係数μsが0.07未満では、繊維の平滑性が低くなり繊維球状体同士が絡み易くなることにより、繊維球状体の流動性に欠け製品品位が悪化する場合がある。一方、繊維摩擦係数μsが0.12を超えても、それ以上の繊維平滑性の向上は認められない。   The fiber friction coefficient μs of the polyester hollow fiber used in the present invention is preferably 0.06 to 0.14. The fiber friction coefficient μs is more preferably 0.07 to 0.12. When the fiber friction coefficient μs is less than 0.07, the smoothness of the fibers is reduced and the fiber spheres are easily entangled with each other. On the other hand, even if the fiber friction coefficient μs exceeds 0.12, no further improvement in fiber smoothness is observed.

ポリエステル中空繊維球状体のかさ高は、8,200以上〜11,500cm/50g以下であることが重要である。かさ高は、好ましくは9,000以上〜10,700cm/50g以下である。かさ高が8,200cm/50g未満になると、かさ高が得られず、軽量感やボリューム感に劣る繊維球状体となる。一方、かさ高が11,500cm/50gを超える繊維球状体を得る製造条件を得ることは困難である。Bulky polyester hollow fibers spheroids, it is important that at most 8,200 or more ~11,500cm 3 / 50g. Bulky is preferably 9,000 or more ~10,700cm 3 / 50g or less. If the bulk height less than 8,200cm 3 / 50g, not bulky is obtained, and fiber spheroids inferior lightness and voluminous feeling. On the other hand, it is difficult to obtain a production conditions bulky obtain a fibrous spheroids exceeding 11,500cm 3 / 50g.

本発明で用いられるポリエステル中空繊維のけん縮率数比は、1.5〜3.0であることが好ましい。けん縮率数比は、より好ましくは8〜12%である。けん縮率数比が1.5未満になると、繊維球状体への加工において繊維が球状に丸まり難くなることにより、繊維球状体の形成が難しくなる。一方、けん縮率数比が3.0を超えると、高いけん縮発現性を得るための安定した繊維製造が困難となる。   The crimp ratio ratio of the polyester hollow fibers used in the present invention is preferably 1.5 to 3.0. The number ratio of the crimp ratio is more preferably 8 to 12%. When the crimp ratio is less than 1.5, it is difficult for the fibers to be spherically rounded during processing into a fibrous spherical body, so that it is difficult to form the fibrous spherical body. On the other hand, when the crimp ratio ratio exceeds 3.0, stable fiber production for obtaining high crimp development becomes difficult.

けん縮率数比は、次式(1)で示される。
けん縮率数比=けん捲率/けん縮数・・・・(1)
次に、本発明で用いられるポリエステル中空繊維とポリエステル中空繊維球状体の製造方法について、具体的に一態様を例示して説明する。
The crimp ratio ratio is expressed by the following equation (1).
Crimp ratio ratio = Crimp ratio / Crimp number ... (1)
Next, the method for producing the polyester hollow fiber and the polyester hollow fiber spherical body used in the present invention will be specifically described by exemplifying one embodiment.

まず、ポリエステルを溶融し、中空繊維用吐出孔を好ましくは90〜400孔有する紡糸口金を通して、融点よりも15〜30℃程度高い紡糸温度で、中空部が形成されるように溶融紡出し、紡出直後に好ましくは10〜25℃の温度の空気を好ましくは80〜130m/分の風量で非対称冷却させた後、さらに、好ましくは10〜25℃の温度の空気を好ましくは140〜170m/分の風量で冷却させ、紡糸油剤を付与し、好ましくは引き取り速度1000〜1700m/分で一旦、缶に納めることにより未延伸糸トウを得る。   First, the polyester is melted and melt-spun through a spinneret having discharge holes for hollow fibers preferably having 90 to 400 holes at a spinning temperature higher than the melting point by about 15 to 30 ° C. so that a hollow portion is formed. Immediately after being discharged, air having a temperature of preferably 10 to 25 ° C. is preferably asymmetrically cooled at an air volume of preferably 80 to 130 m / min, and further air having a temperature of preferably 10 to 25 ° C. is preferably 140 to 170 m / min. And the spinning oil agent is applied, and the undrawn yarn tow is obtained by temporarily putting it in a can at a take-off speed of preferably 1000 to 1700 m / min.

次いで、得られた未延伸糸トウを好ましくは2.3〜3.0倍の延伸倍率で、好ましくは温度75〜100℃の液浴を用いて1段延伸を施し、けん縮付与工程を介さずに、ポリシロキサンを含む油剤を好ましくは濃度3〜10質量%で含まれた油剤水溶液を、繊維質量に対して好ましくは0.3〜1.0質量%の範囲となるようにシャワーで付与し、所定の繊維長に切断し、好ましくは100〜250℃の加熱スチーム処理によりスパイラル状にけん縮発現させ、好ましくは145〜165℃の温度で好ましくは5〜20分熱セットすることにより、ポリエステル中空繊維を製造することができる。   Next, the obtained undrawn yarn tow is subjected to one-stage drawing preferably at a draw ratio of 2.3 to 3.0 times, preferably using a liquid bath at a temperature of 75 to 100 ° C, and subjected to a crimp applying step. Instead, an oil solution containing a polysiloxane-containing oil solution, preferably at a concentration of 3 to 10% by mass, is applied by shower so as to be preferably in a range of 0.3 to 1.0% by mass with respect to the fiber mass. Then, cut to a predetermined fiber length, preferably crimped in a spiral shape by heating steam treatment at 100 to 250 ° C, and heat-set at a temperature of preferably 145 to 165 ° C, preferably for 5 to 20 minutes, Polyester hollow fibers can be produced.

上記のスパイラル捲縮とは、コイル状に繊維が発現したけん縮のことである。   The above-mentioned spiral crimping is crimping in which fibers are expressed in a coil shape.

本発明のポリエステル中空繊維球状体の形成方法は、前記のようにして得られたポリエステル中空繊維を、ガーネットワイヤーが表面に設けられた複数のローラが設けられたカードなどを用いて開繊を十分に行い、空気の乱流の起きやすい円筒状の空間の中で複数のフィンが着いて回転する回転体が設けられた部屋の中に、開繊を十分に行った繊維を吹き込み所定時間乱流撹拌後に取り出せるようにした装置などで球状体化したり、開繊を十分に行った繊維をある程度大きな部屋に空気の渦流を起こさせながら滞留させて球状体化したりして、剛体(フィン)や空気から力学的な力を受けることにより、ループ状の捲縮がさらに進行し、繊維球状体を形成することができる。   In the method for forming a spherical polyester hollow fiber body of the present invention, the polyester hollow fiber obtained as described above is sufficiently opened using a card provided with a plurality of rollers provided with a garnet wire on the surface. In a room where a plurality of fins are attached and rotate in a cylindrical space where turbulence of air is likely to occur, a sufficiently opened fiber is blown into the room, and turbulence for a predetermined time is blown. A spheroid is formed by a device that can be taken out after agitation, or a fiber that has been sufficiently opened is spheroidized by accumulating in a somewhat large room while creating a vortex of air. , A loop-shaped crimp further proceeds, and a fibrous spherical body can be formed.

また、ポリエステル中空繊維球状体の大きさは、好ましくは平均直径が3〜8mmであり、より好ましくは4〜6mmである。平均直径が3mm未満の繊維球状体の加工は難しく、平均直径が8mmを超えると繊維球状体は吹き込みなどの製品加工性に欠けた製品となる。   Further, the size of the polyester hollow fiber sphere is preferably such that the average diameter is 3 to 8 mm, more preferably 4 to 6 mm. It is difficult to process a fiber spheroid having an average diameter of less than 3 mm. If the average diameter exceeds 8 mm, the fiber spheroid becomes a product lacking in processability such as blowing.

図1は、本発明のポリエステル中空繊維球状体を例示する図面代用写真である。図1のポリエステル中空繊維球状体は、サイズのバラツキが小さく、嵩高性が良く、未成型繊維がほとんどない。   FIG. 1 is a photograph as a substitute of a drawing, which illustrates the polyester hollow fiber spherical body of the present invention. The polyester hollow fiber sphere of FIG. 1 has small size variation, good bulkiness, and almost no unmolded fiber.

本発明のポリエステル中空繊維球状体は、軽量でかつ優れたかさ高性を有するだけでなく、柔らかくかつ羽毛に近似した風合いに富み、クッションやダウンジャケット等の中綿素材として好適に用いられる。   The polyester hollow fiber spherical body of the present invention is not only lightweight and has excellent bulkiness, but also is soft and has a texture close to feathers, and is suitably used as a batting material such as a cushion or a down jacket.

次に、本発明のポリエステル中空繊維球状体とその製造方法について、実施例を用いて詳細に説明する。物性等の測定方法は、次のとおりである。   Next, the polyester hollow fiber spherical body of the present invention and a method for producing the same will be described in detail with reference to examples. Methods for measuring physical properties and the like are as follows.

(固有粘度)
試料をオルソクロロフェノールに溶解して、ウベローデ粘度計を用いて自然落下時間を測定し、標準試料との相対値で固有粘度をN=3の平均値で求めた。
(Intrinsic viscosity)
The sample was dissolved in orthochlorophenol, the spontaneous fall time was measured using an Ubbelohde viscometer, and the intrinsic viscosity was determined as an average value of N = 3 relative to a standard sample.

(単繊維繊度、けん縮数、けん縮率、繊維長および繊維摩擦係数μs)
JIS L1015(2010年)に準じて測定した。
(Single fiber fineness, crimp number, crimp rate, fiber length and fiber friction coefficient μs)
It was measured according to JIS L1015 (2010).

(けん縮率数比)
捲縮数と捲縮率をJIS L1015(2010年)に準じて測定し、式1に示す方法でけん縮率数比を算出した。
(式1)けん縮率数比=けん縮率/けん縮数
(繊維質量に対するポリシロキサンを含む油剤の付着量)
試料を発煙硫酸と発煙硝酸で分解し、電気炉で炭化した後、アルカリで溶解する。その後、モリウデン酸アンモニウムで発色させ分光高度計で吸光度を測定し、検量線から無機シリコーン(Si)量を算出し、N=3の平均値を油分量に換算した。
(中空率)
得られたポリエステル中空繊維の断面を、顕微鏡を用いて400倍の倍率で撮影し、さらに断面写真を拡大コピーする。コピーした用紙について、繊維部断面を切り取り、電子天秤でN=20質量を測定する。次に中空部を切り取り、電子天秤でN=20質量を測定し、次式(2)で示す質量比率で算出した。
中空率(%)=(中空部質量/繊維部断面質量)×100・・・(2)
(繊維球状体のかさ高)
繊維球状体サンプル50g±0.1gを計量し、内径が28.8cmで高さが50cmの測定シリンダーに投入し、94.3gの荷重をかけて5分後のかさ高を測定する。測定結果は5回の平均値とし、次式(3)により算出した。
かさ高=V=πdH/4(単位:cm/50g)・・・(3)
(式中、dは、次の測定シリンダー内径d=28.8cmである。Hは、試料のかさ高(平均値)であり、単位はcmである。)
(繊維球状体の直径)
任意に選択した繊維球状体の直径をノギスにより測定し、N=100の平均値を求めた。
(Crimp ratio ratio)
The number of crimps and the rate of crimp were measured according to JIS L1015 (2010), and the ratio of the number of crimps was calculated by the method shown in Equation 1.
(Formula 1) Ratio of crimping ratio = crimping ratio / crimping number (Amount of oil agent containing polysiloxane to fiber mass)
The sample is decomposed with fuming sulfuric acid and fuming nitric acid, carbonized in an electric furnace, and then dissolved with alkali. Thereafter, the color was developed with ammonium molybdate, the absorbance was measured with a spectrophotometer, the amount of inorganic silicone (Si) was calculated from the calibration curve, and the average value of N = 3 was converted to the oil content.
(Hollow ratio)
A cross section of the obtained polyester hollow fiber is photographed at a magnification of 400 times using a microscope, and a photograph of the cross section is further enlarged and copied. A section of the fiber portion is cut out from the copied paper, and N = 20 mass is measured with an electronic balance. Next, the hollow portion was cut out, N = 20 mass was measured by an electronic balance, and the mass ratio was calculated by the following formula (2).
Hollow ratio (%) = (mass of hollow portion / cross-sectional mass of fiber portion) × 100 (2)
(Bulk height of fiber sphere)
A fibrous sphere sample of 50 g ± 0.1 g is weighed, put into a measuring cylinder having an inner diameter of 28.8 cm and a height of 50 cm, and applying a load of 94.3 g to measure the bulk after 5 minutes. The measurement result was an average value of five times, and was calculated by the following equation (3).
Bulky = V = πd 2 H / 4 ( unit: cm 3 / 50g) ··· ( 3)
(Where d is the next measurement cylinder inner diameter d = 28.8 cm. H is the height (average value) of the sample, and the unit is cm.)
(Diameter of fiber sphere)
The diameter of the arbitrarily selected fibrous body was measured with a caliper, and the average value of N = 100 was determined.

(繊維球状体の風合い/柔らかさ)
10人のパネラーが手で触れた時の触感(風合い;ソフト性/柔らかさ)をランク付けで、良好〜不良を5〜0点として評価した。その平均点が4点を超えると風合い良好(○)とし、4点未満を風合い不良(×)として評価した。
(Texture / softness of fiber sphere)
The tactile sensation (feel; softness / softness) when ten panelists touched with their hands was ranked, and good to poor were evaluated as 5 to 0 points. When the average score exceeded 4 points, the texture was evaluated as good (O), and when the average score was less than 4 points, the texture was evaluated as poor (X).

[実施例1]
ポリエステル中空繊維を、次の方法で製造した。固有粘度が0.650のポリエチレンテレフタレート(融点260℃)を溶融し、吐出孔を300孔有する中空口金を通して紡糸温度280℃で溶融紡糸し、口金から紡糸直後、20℃の温度の空気を100m/分の風量で非対称冷却させた後、引き取り速度1500m/分で未延伸糸トウを得た。
[Example 1]
Polyester hollow fibers were produced in the following manner. Polyethylene terephthalate having an intrinsic viscosity of 0.650 (melting point: 260 ° C.) is melted and melt-spun at a spinning temperature of 280 ° C. through a hollow die having 300 discharge holes. After asymmetric cooling with an air flow rate of 1 minute, an undrawn yarn tow was obtained at a take-off speed of 1500 m / min.

次いで、得られた未延伸糸トウを、80℃の温度の液浴を用いて、2.6倍の延伸倍率で1段延伸を施し、けん縮付与工程を介さずに、ポリシロキサンを含む油剤をシャワーで付与し、表1に記載の規定の繊維長に切断し、200℃の温度の加熱スチーム処理によりスパイラル状にけん縮発現させ、165℃の温度で10分熱セットすることにより、表1に示す諸特性のポリエステル中空繊維を製造した。   Next, the obtained undrawn yarn tow is subjected to single-stage drawing at a draw ratio of 2.6 times using a liquid bath at a temperature of 80 ° C., and an oil agent containing a polysiloxane without a crimping step. Is applied in a shower, cut into the specified fiber lengths shown in Table 1, crimped in a spiral shape by heating and steaming at a temperature of 200 ° C., and heat-set at a temperature of 165 ° C. for 10 minutes. Polyester hollow fibers having the properties shown in No. 1 were produced.

次いで、得られたポリエステル中空繊維を、ガーネットワイヤーが表面に設けられた複数のローラが設けられたカードで、開繊を十分に行い、空気の乱流の起きやすい円筒状の空間の中で複数のフィンが着いて回転する回転体が設けられた部屋の中に、繊維を吹き込み所定時間乱流撹拌後に取り出せるようにした装置で、ポリエステル中空繊維球状体を得た。得られた繊維構造体は優れたかさ高を有し、かつ、柔らかい風合いのポリエステル中空繊維球状体であることを確認した。結果を表1に示す。   Next, the obtained polyester hollow fiber is sufficiently opened with a card provided with a plurality of rollers provided with a garnet wire on the surface, and a plurality of the hollow fibers are formed in a cylindrical space where air turbulence easily occurs. The polyester hollow fiber sphere was obtained by using a device in which the fiber was blown into a room provided with a rotating body provided with a fin and rotated so that the fiber could be taken out after turbulent stirring for a predetermined time. It was confirmed that the obtained fiber structure was a polyester hollow fiber sphere having an excellent bulkiness and a soft texture. Table 1 shows the results.

[比較例1]
繊維長が64mmのポリエステル中空繊維としたこと以外は、実施例1と同じ条件でポリエステル中空繊維を製造し、ポリエステル中空繊維球状体を得た。得られたポリエステル中空繊維球状体を構成するポリエステル中空繊維は、繊維長が長いため、繊維球状体への加工において繊維が球状に丸まり難くなることにより、繊維球状体形状不良部分や繊維球状体同士が絡まった部分が認められた。結果を表1に示す。
[Comparative Example 1]
A polyester hollow fiber was manufactured under the same conditions as in Example 1 except that the polyester hollow fiber had a fiber length of 64 mm, and a polyester hollow fiber spherical body was obtained. The polyester hollow fiber constituting the obtained polyester hollow fiber sphere has a long fiber length, so that it is difficult for the fiber to be rounded into a sphere in the processing into the fiber sphere, and thus the defective portion of the fiber sphere and the shape of the fiber sphere are formed. Was found. Table 1 shows the results.

[比較例2]
単繊維繊度が1.7dtexのポリエステル中空繊維としたこと以外は、実施例1と同じ条件でポリエステル中空繊維を製造し、繊維球状体を得た。単繊維繊度と捲縮率が低いため、繊維球状体への加工において繊維が球状に丸まり難くなることにより、ポリエステル中空繊維球状体の形成ができなかった。結果を表1に示す。
[Comparative Example 2]
A polyester hollow fiber was produced under the same conditions as in Example 1 except that the polyester hollow fiber had a single fiber fineness of 1.7 dtex, and a fiber spherical body was obtained. Since the single fiber fineness and the crimp rate are low, the fibers are hardly rounded in a spherical shape during processing into a fiber spherical body, so that a polyester hollow fiber spherical body cannot be formed. Table 1 shows the results.

[比較例3]
単繊維繊度が7.5dtexのポリエステル中空繊維としたこと以外は、実施例1と同じ条件でポリエステル中空繊維を製造し、繊維球状体を得た。単繊維繊度が大きく繊維の剛性が高いため、柔らかさに欠ける繊維球状体が得られた。結果を表1に示す。
[比較例4]
実施例1においてポリシロキサンを含む油剤をシャワーで付与する工程までは同様とし、その後、160℃の温度で10分間熱セット後、規定の繊維長に切断し、160℃の温度で10分熱セットすることにより、表1に示す諸特性のポリエステル中空繊維を製造し、繊維球状体を得た。けん縮形態が、三次元のらせん状となり、かつ、S方向、Z方向のものがランダムなものとなるため、得られる繊維球状体は絡まりすぎ、風合いが硬く、さらには、嵩高性が劣る繊維球状体となった。結果を表1に示す。
[Comparative Example 3]
A polyester hollow fiber was produced under the same conditions as in Example 1 except that the polyester hollow fiber had a single fiber fineness of 7.5 dtex, and a fiber spherical body was obtained. Since the single fiber fineness was large and the rigidity of the fiber was high, a fiber spherical body lacking in softness was obtained. Table 1 shows the results.
[Comparative Example 4]
The same procedure as in Example 1 was performed up to the step of applying an oil agent containing polysiloxane by showering. After that, the fiber was heat-set at a temperature of 160 ° C. for 10 minutes, cut into a specified fiber length, and heat-set at a temperature of 160 ° C. for 10 minutes. As a result, polyester hollow fibers having various properties shown in Table 1 were produced, and fibrous spherical bodies were obtained. Since the crimped form is a three-dimensional helical shape, and the one in the S and Z directions is random, the fiber sphere obtained is too entangled, the texture is hard, and further, the fiber with poor bulkiness It became spherical. Table 1 shows the results.

Claims (7)

単繊維繊度が2.0〜6.6dtex、中空率が15〜35%、けん縮数が2〜8山/25mm、けん縮率が6〜14%、繊維長が20〜50mmとするポリエステル中空繊維を用いてなる繊維球状体であり、かさ高が8,200以上〜11,500cm3/50g以下であることを特徴とするポリエステル中空繊維球状体。 Polyester hollow having a single fiber fineness of 2.0 to 6.6 dtex, a hollow ratio of 15 to 35%, a crimp number of 2 to 8 ridges / 25 mm, a crimp ratio of 6 to 14%, and a fiber length of 20 to 50 mm A polyester hollow fiber sphere, which is a fiber sphere made of fibers and has a bulk of 8,200 or more to 11,500 cm3 / 50 g or less. 該ポリエステル中空繊維の固有粘度が0.60〜0.75であることを特徴とする請求項1記載のポリエステル中空繊維球状体。 2. The polyester hollow fiber spherical body according to claim 1, wherein the intrinsic viscosity of the polyester hollow fiber is 0.60 to 0.75. 該ポリエステル中空繊維に、ポリエステル繊維質量に対してポリシロキサンを含む油剤が0.3〜1.0質量%の割合で付着されていることを特徴とする請求項2記載のポリエステル中空繊維球状体。 The polyester hollow fiber sphere according to claim 2, wherein an oil agent containing polysiloxane is attached to the polyester hollow fiber at a ratio of 0.3 to 1.0% by mass based on the mass of the polyester fiber. 該ポリエステル中空繊維の繊維摩擦係数μsが0.06〜0.14であることを特徴とする請求項3記載のポリエステル中空繊維球状体。 The polyester hollow fiber spherical body according to claim 3, wherein the polyester hollow fiber has a fiber friction coefficient μs of 0.06 to 0.14. 次式(1)で示されるポリエステル中空繊維のけん縮率数比が、1.5〜3.0であることを特徴とする請求項1記載のポリエステル中空繊維球状体。
けん縮率数比=けん縮率/けん縮数・・・・(1)
The polyester hollow fiber sphere according to claim 1, wherein the crimp ratio of the polyester hollow fiber represented by the following formula (1) is 1.5 to 3.0.
Ratio of number of crimping ratios = number of crimping ratios / number of crimping factors (1)
請求項1に記載の中空繊維球状体を中綿としたことを特徴とするダウンジャケット。 A down jacket, wherein the hollow fiber spherical body according to claim 1 is a batting. 請求項1〜5のいずれかに記載のポリエステル中空繊維球状体の製造方法であって、ポリエステルを中空糸用紡糸口金から紡出し、紡出糸の片側から冷却風を吹き付けて非対称冷却した後に引き取り、熱延伸後、けん縮付与工程を介さずにポリシロキサンを含む油剤を付与し、所定の繊維長に切断後、加熱スチーム処理によりスパイラル状にけん縮発現させた後に熱セットして、ポリエステル中空繊維を得、得られたポリエステル中空繊維を開繊し繊維球状体に加工することを特徴とするポリエステル中空繊維球状体の製造方法。
The method for producing a polyester hollow fiber spherical body according to any one of claims 1 to 5, wherein the polyester is spun from a spinneret for a hollow fiber, and a cooling air is blown from one side of the spun yarn to asymmetrically cool and then taken off. After hot stretching, apply an oil agent containing polysiloxane without going through a crimping step, cut to a predetermined fiber length, heat-steam to express crimp in a spiral shape, heat-set, and heat the polyester hollow A method for producing a polyester hollow fiber spherical body, comprising obtaining a fiber, opening the obtained polyester hollow fiber, and processing the fiber into a fiber spherical body.
JP2016505635A 2015-01-26 2016-01-22 Polyester hollow fiber sphere Active JP6645421B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2015012171 2015-01-26
JP2015012171 2015-01-26
PCT/JP2016/051838 WO2016121643A1 (en) 2015-01-26 2016-01-22 Polyester hollow fiber spherical material

Publications (2)

Publication Number Publication Date
JPWO2016121643A1 JPWO2016121643A1 (en) 2017-11-02
JP6645421B2 true JP6645421B2 (en) 2020-02-14

Family

ID=56543256

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2016505635A Active JP6645421B2 (en) 2015-01-26 2016-01-22 Polyester hollow fiber sphere

Country Status (4)

Country Link
JP (1) JP6645421B2 (en)
KR (1) KR102416737B1 (en)
CN (1) CN107208321B (en)
WO (1) WO2016121643A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108239794A (en) * 2016-12-23 2018-07-03 东丽纤维研究所(中国)有限公司 A kind of hollow long fibre of polyester
KR102487609B1 (en) * 2020-10-14 2023-01-11 주식회사 나프 Method for manufacturing fiber aggregate having excellent elasticity
CN112323252A (en) * 2020-10-28 2021-02-05 青岛热源纤维科技有限公司 Machine-washable high-filling-power heat-insulation filling material
CN112695404A (en) * 2020-12-24 2021-04-23 上海德福伦化纤有限公司 Fine denier three-dimensional curled hollow silicon-added PTT fiber and preparation method thereof
CN116575182B (en) * 2023-07-14 2023-09-19 江苏富之岛美安纺织品科技有限公司 PLA (polylactic acid) bi-component super-expansion super-elastic pearl cotton ball processing equipment and manufacturing method thereof

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52103263A (en) * 1976-02-25 1977-08-30 Mitsubishi Rayon Co Method of producing feather quiltt like bedding
JPS56169813A (en) * 1980-05-29 1981-12-26 Toyobo Co Ltd Synthetic fiber for wadding
JPS5789649A (en) * 1980-11-25 1982-06-04 Teijin Ltd Production of padding material
US4618531A (en) 1985-05-15 1986-10-21 E. I. Du Pont De Nemours And Company Polyester fiberfill and process
US4794038A (en) * 1985-05-15 1988-12-27 E. I. Du Pont De Nemours And Company Polyester fiberfill
JPS5836031A (en) * 1981-08-28 1983-03-02 Hitachi Ltd Noise reducing device
JPS6040088A (en) * 1983-08-12 1985-03-02 東レ株式会社 Polyester fiber for padding
JPS6055989A (en) * 1983-09-08 1985-04-01 東レ株式会社 Polyester fiber for padding
JPS61125377A (en) 1984-11-21 1986-06-13 日本エステル株式会社 Production of paddings
JP3322045B2 (en) * 1995-01-06 2002-09-09 東レ株式会社 Fiber mixture, fiber molded body, and method for producing fiber molded body
JP3701765B2 (en) 1997-03-13 2005-10-05 帝人ファイバー株式会社 Molded article with improved stress diffusivity made of highly elastic spheres
KR100270437B1 (en) * 1998-08-25 2001-03-02 김윤 Spinnerets for spontaneous high-strength hollow fiber manufacturing
KR100698003B1 (en) * 2000-01-07 2007-03-23 데이진 가부시키가이샤 Crimped polyester fiber and fibrous structure comprising the same
JP4522592B2 (en) 2001-01-05 2010-08-11 株式会社クラレ Spherical fiber structure and manufacturing method thereof
JP3936861B2 (en) 2001-12-07 2007-06-27 寛範 石井 Cushion material manufacturing method and manufacturing apparatus
CN100404732C (en) * 2005-09-19 2008-07-23 上海联吉合纤有限公司 Dacron thin-denier high-hollow short fiber and its production method
JP4791175B2 (en) 2005-12-26 2011-10-12 帝人ファイバー株式会社 Molded product made of highly elastic fiber spheres
CN201074257Y (en) * 2007-01-19 2008-06-18 东华大学 Three-dimensional crimp hollow synthetic fiber
CN102851805B (en) * 2011-06-30 2016-03-30 东丽纤维研究所(中国)有限公司 A kind of false-twisted fiber
JP2014167185A (en) * 2013-02-28 2014-09-11 Toray Ind Inc Spun yarn containing polymethylpentene hollow fiber, and fiber structure comprising the same
CN105002579B (en) * 2015-05-18 2017-07-18 浙江恒逸高新材料有限公司 A kind of high hollow fine-denier polyester long filament and preparation method thereof

Also Published As

Publication number Publication date
KR102416737B1 (en) 2022-07-05
CN107208321A (en) 2017-09-26
KR20170104442A (en) 2017-09-15
JPWO2016121643A1 (en) 2017-11-02
WO2016121643A1 (en) 2016-08-04
CN107208321B (en) 2020-02-28

Similar Documents

Publication Publication Date Title
JP6645421B2 (en) Polyester hollow fiber sphere
JP3664585B2 (en) Fiber with excellent heat radiation
TWI353820B (en) Artificial hair, wig using the same, and method of
JP5700048B2 (en) Manufacturing method of polyvinyl chloride resin fiber
JP6414228B2 (en) Stuffed cotton
US20190233983A1 (en) Fiber-filled material and fiber product obtained by using same
TW200934897A (en) Conjugate fiber having low-temperature processability, nonwoven fabric and formed article using the conjugate fiber
EP3450598B1 (en) Bulky yarn
JP2017089092A (en) Wadding
WO2014054777A1 (en) Bristle for antibacterial cosmetic brush, and antibacterial cosmetic brush obtained using said bristle and process for producing same
TWI793092B (en) A kind of polyester hollow long fiber and preparation method thereof
CN110832123A (en) Synthetic fiber with reduced density using hollow microcapsules
JP2017166103A (en) Sea-island-type hollow composite fiber and fiber spherical body
JP2012214951A (en) Blended wadding
JP2015175074A (en) Eccentric sheath-core type composite fiber and fiber spheroid using the same
JP2015052178A (en) Polyester fiber structure and wadding
JP2015188487A (en) wadding
JP2022144473A (en) Polyester fiber and fiber spheroid thereof
JP2019157296A (en) Bulky-structure yarn, padding, and fiber-filled material and fiber product each using the same
JP7205196B2 (en) Bulky yarn
JP6268575B2 (en) Antibacterial cosmetic brush hair material, antibacterial cosmetic brush using the hair material, and method for producing the same
JP2020070529A (en) Short fiber aggregate
CN104250881B (en) Production method of aromatic polyester flocculus
JP6492584B2 (en) Short fiber assembly
WO2018074544A1 (en) Fiber and wadding

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20181116

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20190903

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20191002

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20191210

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20191223

R151 Written notification of patent or utility model registration

Ref document number: 6645421

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R151