JP2015188487A - wadding - Google Patents

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JP2015188487A
JP2015188487A JP2014065852A JP2014065852A JP2015188487A JP 2015188487 A JP2015188487 A JP 2015188487A JP 2014065852 A JP2014065852 A JP 2014065852A JP 2014065852 A JP2014065852 A JP 2014065852A JP 2015188487 A JP2015188487 A JP 2015188487A
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fiber
cotton
cross
hollow
fibers
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紀孝 伴
Noritaka Ban
紀孝 伴
合田 裕憲
Hironori Aida
裕憲 合田
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Teijin Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide wadding that has excellent bulkiness and heat-retaining properties and allows functions of agents attached to the wadding to be expressed easily, and provide a fiber product using the wadding.SOLUTION: Wadding includes 20 to 100 wt.% of hollow fiber and has 0.1 to 11.0 dtex of weighted average fineness of all fibers constituting the wadding. The hollow fiber includes: a core part of which a cross section perpendicular to a fiber axis has a round shape; and 6 to 12 fin parts that protrude radially from an outer periphery of the core part. On the cross section perpendicular to the fiber axis of the hollow fiber, a percentage of hollowness expressed by the following formula is 5 to 25%. The wadding can solve the above problem.

Description

本発明は、優れた嵩性および保温性を有する詰綿、ならびに該詰綿を用いてなる繊維製品を提供する。   The present invention provides a cotton wool having excellent bulkiness and heat retention, and a fiber product using the cotton wool.

従来、ふとん、まくら、衣料用中綿などの分野で詰綿として、風合いが優れ、軽量で保温性の高い羽毛が好適に用いられている。しかしながら、羽毛は、気候や疫病等の影響で供給量が変動し、価格が高騰する問題がある。また、動物愛護の観点からも、欧米を中心に、その使用を排除する動きがある。これらの状況に対応するため、羽毛を、合成繊維によって代替することが試みられている。例えば、繊度、断面形状、捲縮形態等の異なる繊維を複数組み合わせることで、羽毛に近似した詰綿を提案している(例えば、特許文献1、特許文献2参照。)。これらは嵩高性および嵩ヘタリによる保温性の低下を防ぐための中空太短繊維と、保温性を高めるための細繊度繊維とを混用することにより、嵩高性と保温性の高い詰綿を提案しているが、嵩高性と保温性が、異なる構成繊維によって分担して担われているために、これらの内の一方を高めるようとすると、他方を犠牲にするトレードオフが発生する問題があった。   Conventionally, feathers having excellent texture, light weight and high heat retention properties are suitably used as stuffing cotton in the fields of futons, pillows, clothing padding and the like. However, feathers have a problem that the supply amount fluctuates due to the influence of the climate and the plague and the price increases. Also, from the viewpoint of animal welfare, there is a movement to eliminate its use, mainly in the West. In order to cope with these situations, attempts have been made to substitute feathers with synthetic fibers. For example, a cotton pad that approximates feathers has been proposed by combining a plurality of fibers having different fineness, cross-sectional shape, crimped shape, and the like (see, for example, Patent Document 1 and Patent Document 2). They propose a cotton padding with high bulkiness and heat retention by mixing hollow thick and short fibers to prevent deterioration of heat retention due to bulkiness and bulkiness, and fine fibers for enhancing heat retention. However, since bulkiness and heat retention are shared and carried by different constituent fibers, there is a problem that when one of these is increased, a trade-off occurs at the expense of the other. .

特開2006−115987号公報JP 2006-115987 A 特開2012−214951号公報JP 2012-214951 A

本発明は上記の背景に鑑みなされたものであり、その目的は、優れた嵩回復性と保温性を両立した詰綿、および該詰綿を用いてなる繊維製品を提供することにある。   The present invention has been made in view of the above background, and an object of the present invention is to provide a cotton wool that has both excellent bulk recovery and heat retention, and a fiber product using the cotton wool.

本発明者らは上記の課題を達成するため鋭意検討した結果、放射状に突出するフィン部を有する中空繊維で詰綿を構成すると、単糸繊維の剛性により高い嵩高性および嵩回復性を有するとともに、単糸繊維中の中空部だけでなく、放射状に突出したフィンによって単糸繊維間に形成される微細な空隙によって保温性を向上させることができることを見出し、さらに鋭意検討を重ねることにより本発明を完成するに至った。   As a result of intensive investigations to achieve the above-mentioned problems, the inventors of the present invention have high bulkiness and bulk recoverability due to the rigidity of the single yarn fiber when the stuffed cotton is constituted by hollow fibers having fin portions protruding radially. The present invention is based on the finding that heat retention can be improved not only by the hollow portion in the single yarn fiber but also by the fine voids formed between the single yarn fibers by the radially projecting fins, and by further earnest study It came to complete.

かくして、本発明によれば「中空繊維を20〜100重量%含む詰綿であって、前記詰綿を構成する全繊維の加重平均繊度が0.1〜11.0dtexからなる詰綿であり、前記中空繊維は繊維軸に対して直交する断面が丸型もしくは多角形型であるコアー部と、該コアー部の外周表面から放射状に突出する6〜12個のフィン部とを有し、前記中空繊維の繊維軸に対して直交する断面において、下記式で示す中空率が5〜25%であることを特徴とする、詰綿
中空率(%)=[1−(A/B)]×100
A:単糸繊維軸に直交する断面面積
B:単糸繊維横断面最外周面積」
が提供される。また、前記中空繊維がポリエステル系ポリマーからなるトウ、または、短繊維であることが好ましい。また、本発明によれば、前記の詰綿を含む、ふとん、まくら、ぬいぐるみ、衣料、およびクッション構造体からなる群より選択されるいずれかの繊維製品が提供される。
Thus, according to the present invention, “a stuffed cotton containing 20 to 100% by weight of hollow fibers, wherein the weighted average fineness of all the fibers constituting the stuffed cotton is 0.1 to 11.0 dtex, The hollow fiber has a core part having a round or polygonal cross section perpendicular to the fiber axis, and 6 to 12 fin parts projecting radially from the outer peripheral surface of the core part. In the cross section perpendicular to the fiber axis of the fiber, the hollowness shown by the following formula is 5 to 25%, and the filling cotton hollowness (%) = [1− (A / B)] × 100
A: Cross-sectional area perpendicular to single yarn fiber axis B: Single-fiber cross-sectional outermost circumference area ”
Is provided. The hollow fiber is preferably a tow made of a polyester polymer or a short fiber. In addition, according to the present invention, there is provided any textile product selected from the group consisting of a futon, a pillow, a stuffed toy, a garment, and a cushion structure, including the above-described cotton stuffing.

本発明によれば、優れた嵩性および保温性を同時に有する詰綿を提供することができる。更に、該詰綿を用いてなる繊維製品を提供することができ、繊維製品の消費者に対して快適な生活資材を提供することができる。   ADVANTAGE OF THE INVENTION According to this invention, the cotton stuffing which has the outstanding bulkiness and heat retention property can be provided. Furthermore, a textile product using the stuffed cotton can be provided, and comfortable living materials can be provided to consumers of the textile product.

本発明で用いることのできる中空繊維(単糸繊維)の、繊維軸に直交する断面の模式図であり、R,rはそれぞれこの断面の模式図における最外周の長径、コアー部の長径を表す。It is a schematic diagram of the cross section orthogonal to the fiber axis of the hollow fiber (single yarn fiber) that can be used in the present invention, and R and r represent the major axis of the outermost periphery and the major axis of the core part in the schematic diagram of the cross section, respectively. . 本発明で用いることのできる中空繊維を製造する紡糸口金での吐出孔の模式図である。It is a schematic diagram of the discharge hole in the spinneret which manufactures the hollow fiber which can be used by this invention.

以下、本発明の実施の形態について詳細に説明する。
まず、本発明の詰綿に含まれる中空繊維において、繊維軸に対して直交する断面が、中空であるコアー部と該コアー部の外表面から放射状に突出するフィン部とを有することが肝要である。前記中空繊維において、繊維軸に対して直交する断面が、中空であるコアー部と、該コアー部の外表面から放射状に突出するフィン部とを有するので、詰綿を形成した際に、単繊維内および単繊維間に形成される空隙により、優れた嵩性および保温性を有する詰綿が得られる。ここでフィン部がコアー部の外周表面から放射線状に突出していない場合、例えば「井」型のような形状である場合には、繊維軸から直角方向のあらゆる方向から荷重がかかった場合に、フィン部が特に変形しやすい特定の方向が存在し、詰綿にしたに嵩性、保温性を発揮できない場合がある。
Hereinafter, embodiments of the present invention will be described in detail.
First, in the hollow fiber contained in the stuffed cotton of the present invention, it is important that the cross section perpendicular to the fiber axis has a hollow core portion and fin portions that protrude radially from the outer surface of the core portion. is there. In the hollow fiber, the cross section orthogonal to the fiber axis has a hollow core portion and fin portions protruding radially from the outer surface of the core portion. Due to the gaps formed between the inner fibers and the single fibers, it is possible to obtain stuffed cotton having excellent bulkiness and heat retention. Here, when the fin part does not protrude radially from the outer peripheral surface of the core part, for example, in the case of a shape like a “well” type, when a load is applied from all directions perpendicular to the fiber axis, There is a specific direction in which the fin portion is particularly likely to be deformed, and there are cases where bulkiness and heat retention cannot be exhibited even if it is packed.

また、前記コアー部は中空であることが肝要であり、中空部を有しない中実繊維の場合には、中空部の存在により発現する優れた嵩性および保温性が得られず好ましくない。また、かかるコアー部の形状としては、繊維軸に対して直交する断面におけるあらゆる圧縮方向に対して等方的な反発またはコアー部形状の変形破壊に対する抵抗を示すよう、図1に示すような中空部を有する丸型断面形状またはもしくは辺の数が6以上の多角形状の断面であることが好ましい。特開2011−200295のような中空部を有するが、矩形状の断面の形状の場合は、矩形の対角方向に圧縮された際につぶれやすくなるため、好ましくない。コアー部の形状は丸型断面または、辺の数が6以上の多角形状の断面であることが好ましく、より好ましくは、丸型断面または辺の数が6〜12角形状であること、更により好ましくは8〜10角形状であることである。   Further, it is important that the core part is hollow, and in the case of a solid fiber that does not have a hollow part, the excellent bulkiness and heat retaining properties that are manifested by the presence of the hollow part cannot be obtained. In addition, the shape of the core portion is hollow as shown in FIG. 1 so as to show resistance to isotropic repulsion or deformation of the core portion shape in any compression direction in a cross section orthogonal to the fiber axis. It is preferably a round cross-sectional shape having a portion or a polygonal cross-section having 6 or more sides. Although it has a hollow part like Unexamined-Japanese-Patent No. 2011-200295, in the case of the shape of a rectangular cross section, since it becomes easy to collapse when compressed in the diagonal direction of a rectangle, it is not preferable. The shape of the core part is preferably a round cross section or a polygonal cross section having 6 or more sides, more preferably a round cross section or 6 to 12 squares, Preferably it is an 8-10 square shape.

単糸繊維の繊維軸に直交する断面の最外周の長径をR、コアー部の長径をrとするとき、下記式で定義する異型度が、1.2〜3.0であることが望ましい。異型度が1.2よりも小さいと繊維間の空隙が十分に得られず保温性を得ることができない。3.0より大きいと、圧縮された際にフィン部の折れや曲がりが発生し、繊維や詰綿としての性能が損なわれる可能性があるため、好ましくない。より好ましい異型度の範囲は1.4〜2.9であり、更により好ましい異型度の範囲は1.5〜2.8であり、更にもっとより好ましい異型度の範囲は1.8〜2.7であり、最も好ましい異型度の範囲は1.9〜2.1である。
異型度=R/r
R:単糸繊維軸に直交する断面の最外周の長径
r:単糸繊維軸に直交する断面のコアー部の長径
When the major axis of the outermost circumference of the cross section orthogonal to the fiber axis of the single yarn fiber is R and the major axis of the core part is r, the degree of variation defined by the following formula is preferably 1.2 to 3.0. If the degree of profile is less than 1.2, sufficient gaps between fibers cannot be obtained, and heat retention cannot be obtained. If the ratio is larger than 3.0, the fins may be bent or bent when compressed, and the performance as a fiber or stuffed cotton may be impaired. A more preferable range of the degree of modification is 1.4 to 2.9, an even more preferable range of the degree of modification is 1.5 to 2.8, and an even more preferable range of the degree of modification is 1.8 to 2. 7, and the most preferable range of the degree of variation is 1.9 to 2.1.
Atypical degree = R / r
R: major axis of outermost circumference of cross section perpendicular to single yarn fiber axis r: major axis of core portion of cross section perpendicular to single yarn fiber axis

次に、かかるコアー部の外表面から放射状に突出するフィン部の個数は、6〜12個、好ましくは8〜10個である。フィンが6個より少ないと、デッドエアー(移動しない空気層)を形成する効果が小さくなり、保温性が低下する。12個より多いと、フィン間の空間が小さくなり、繊維間に十分なデッドエアーを形成できなくなり、フィンを有さない断面と同様になるため、好ましくない。また、かかるフィン部は、繊維の長さ方向(繊維軸方向)に延在していると、優れた嵩性および保温性が得られやすく好ましい。上述した該辺の数が6以上の多角形はフィン部のフィンの数と同数の辺の数を有する多角形である場合には、繊維軸断面と直角方向からの荷重がかかってもコアー部がつぶれにくいので好ましい。   Next, the number of fin portions projecting radially from the outer surface of the core portion is 6 to 12, preferably 8 to 10. When the number of fins is less than 6, the effect of forming dead air (an air layer that does not move) is reduced, and the heat retention is reduced. When the number is more than 12, it is not preferable because the space between the fins becomes small and sufficient dead air cannot be formed between the fibers, and the cross section does not have the fins. Moreover, it is preferable that such fin portions extend in the fiber length direction (fiber axis direction) because excellent bulkiness and heat retention are easily obtained. In the case where the above-mentioned polygon having 6 or more sides is a polygon having the same number of sides as the number of fins of the fin portion, the core portion even if a load from a direction perpendicular to the fiber axis cross section is applied Is preferable because it is difficult to collapse.

前記中空繊維において、繊維軸に対して直交する断面の外周部分を線(図1の破線部分)で結びその内面積(単糸繊維横断面最外周面積)を面積B、単糸繊維軸に直交する断面面積(ポリマー樹脂等で占められている部分の面積)をAとするとき、下記式で定義する中空率(%)が5〜25%であることが好ましい。より好ましくは6〜23%であり、更により好ましくは7〜19%である。
中空率(%)=[1−(A/B)]×100
A;単糸繊維軸に直交する断面面積(繊維を構成するポリマー樹脂等で占められている部分の面積)
B;単糸繊維横断面最外周面積
In the hollow fiber, the outer peripheral portion of the cross section orthogonal to the fiber axis is connected by a line (the broken line portion in FIG. 1), and the inner area (single fiber cross section outermost peripheral area) is the area B, orthogonal to the single fiber axis When the cross-sectional area (area occupied by the polymer resin or the like) is A, the hollow ratio (%) defined by the following formula is preferably 5 to 25%. More preferably, it is 6-23%, and still more preferably 7-19%.
Hollow ratio (%) = [1- (A / B)] × 100
A: Cross-sectional area orthogonal to the single fiber axis (area of the portion occupied by the polymer resin constituting the fiber)
B: Outer peripheral area of cross section of single yarn fiber

中空率が5%より小さいと、十分な空気層を保持することができないため、高い保温性を得ることができない。また、中空率が25%を超えると、荷重がかかった際に、一の中空繊維に形成されているフィンが、隣接する他の中空繊維のフィンの間に嵌入したり、コアー部の中空がつぶれたりすることで、嵩性が損なわれるため好ましくない。また、中空率が25%を超えると、後述するような常法により機械捲縮を付与する場合、捲縮が掛かり難くなって、高い嵩性を得ることが困難となる。以上のような、コアー部の形状、中空率、フィン部の個数の組合せにより、詰綿としたときの本発明の目的、優れた嵩性および保温性を同時に奏することができるのである。また、詰綿全体としての加重平均繊度を後述の値とする為には、上述したような形状を有する繊維において、単糸繊度を0.5〜10.0dtex、好ましくは0.8〜9.5dtex、より好ましくは1.0〜8.0dtexの範囲とすることが好ましい。なお、上記の本発明の詰綿を構成する繊維のコアー部の形状、異型度、中空率、フィン数、単糸繊度を所定の形状ないし、数値範囲にするには、紡糸口金の形状の設計、繊維を構成するポリマー種の吐出量、引き取り速度、見延伸糸または部分延伸糸を延伸する倍率等の延伸条件の組み合わせによって適宜調整し、達成することができる。   When the hollow ratio is less than 5%, a sufficient air layer cannot be maintained, so that high heat retention cannot be obtained. If the hollowness exceeds 25%, when a load is applied, the fins formed in one hollow fiber are inserted between the fins of other adjacent hollow fibers, or the hollow of the core part is It is not preferable that the material is crushed because the bulkiness is impaired. On the other hand, when the hollowness exceeds 25%, when mechanical crimping is applied by a conventional method as described later, it becomes difficult to apply crimping, and it becomes difficult to obtain high bulkiness. By the combination of the shape of the core part, the hollowness, and the number of fin parts as described above, the object of the present invention, excellent bulkiness and heat retention can be achieved at the same time. Moreover, in order to make the weighted average fineness as the whole stuffing cotton into the value mentioned later, in the fiber having the shape as described above, the single yarn fineness is 0.5 to 10.0 dtex, preferably 0.8 to 9. 5 dtex, more preferably in the range of 1.0 to 8.0 dtex. In addition, in order to make the shape, atypical degree, hollowness, number of fins, and single yarn fineness of the core part of the fiber constituting the above-described stuffed cotton of the present invention within a predetermined shape or numerical range, design of the shape of the spinneret It can be appropriately adjusted and achieved by a combination of drawing conditions such as the discharge amount of the polymer species constituting the fiber, the take-up speed, the magnification for drawing the apparently drawn yarn or the partially drawn yarn.

また、前記中空繊維において、繊維の形態としては、長繊維でもよいが、繊維長3〜100mmの短繊維であると優れた嵩性および保温性が得られ好ましい。より好ましい繊維長は5〜90mmであり、更により好ましい繊維長は10〜80mmである。また、前記中空繊維に捲縮が付与されていると、詰綿の嵩性および保温性がさらに向上することが期待され、好ましい。その際、捲縮付与方法としては、単糸繊維を異方的に冷却することによりスパイラル状捲縮を付与する方法、捲縮数が3〜40個/2.54cm(好ましくは7〜18個/2.54cm、より好ましくは10〜17個/2.54cm)となるように通常の押し込みクリンパー方式により機械捲縮を付与する方法など、種々の方法を用いればよいが、嵩高性、製造コスト等の面から機械捲縮を付与するのが好ましい。   In the hollow fiber, the fiber may be a long fiber, but a short fiber having a fiber length of 3 to 100 mm is preferable because excellent bulkiness and heat retention are obtained. A more preferable fiber length is 5 to 90 mm, and an even more preferable fiber length is 10 to 80 mm. In addition, it is preferable that crimps are imparted to the hollow fibers because it is expected that the bulkiness and heat retention of the stuffed cotton are further improved. At that time, as a method of imparting crimps, a method of imparting spiral crimps by anisotropically cooling single yarn fibers, the number of crimps is 3 to 40 / 2.54 cm (preferably 7 to 18) /2.54 cm, more preferably 10 to 17 pieces / 2.54 cm), and various methods such as a method of imparting mechanical crimping by an ordinary indentation crimper method may be used. It is preferable to provide mechanical crimping from the viewpoint of the above.

前記中空繊維を形成するポリマーの種類としては特に限定されず、ポリエステル、ポリアミド、またはポリエチレン、ポリプロピレン、ポリアクリロニトリル、ポリスチレンその他のポリオレフィンなどの通常の繊維形成性ポリマーなどでよい。なかでも、ポリエチレンテレフタレート、ポリトリメチレンテレフタレート、ポリブチレンテレフタレート、ポリエチレンナフタレート、ポリトリメチレンナフタレート、ポリブチレンナフタレート、ポリ乳酸、またはステレオコンプレックスポリ乳酸などのポリエステルや、第3成分を共重合させた共重合ポリエステルなどが好ましく例示される。かかるポリエステルとしては、マテリアルリサイクルまたはケミカルリサイクルされたポリエステルや、特開2009−01694号公報に記載された、バイオマス由来すなわち生物由来の物質を原材料として得られたモノマー成分を使用してなるポリエチレンテレフタレート、ポリトリメチレンテレフタレート、ポリエチレンナフタレート、ポリトリメチレンナフタレートであってもよい。なかでも、ポリエチレンテレフタレート、ポリブチレンテレフタレートは荷重がある場合であっても繊維断面形状の変形が起こりにくい程度の剛性を有している点で特に好ましい。ポリトリメチレンテレフタレートがソフトな特性を有する点で特に好ましい。さらには、特開2004−270097号公報や特開2004−211268号公報に記載されているような、特定のリン化合物およびチタン化合物を含む触媒を用いて得られたポリエステルでもよい。該ポリエステル中には、本発明の目的を損なわない範囲内で必要に応じて、微細孔形成剤、カチオン染料可染剤、着色防止剤、熱安定剤、蛍光増白剤、艶消し剤、着色剤、吸湿剤、無機微粒子が1種または2種以上含まれていてもよい。ポリオレフィンについては、上記の単一成分のポリオレフィンに限定されず、上記のポリオレフィンの共重合体や、酢酸ビニル、マレイン酸、無水マレイン酸等のカルボキシル基、ヒドロキシル基、エステル基、アミノ基、アミド基、シアノ基、ハロゲン基を有するアルケンを共重合したポリオレフィンであっても良い。   The type of polymer that forms the hollow fiber is not particularly limited, and may be polyester, polyamide, or ordinary fiber-forming polymer such as polyethylene, polypropylene, polyacrylonitrile, polystyrene, or other polyolefins. Among them, polyesters such as polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polytrimethylene naphthalate, polybutylene naphthalate, polylactic acid, or stereocomplex polylactic acid, and the third component are copolymerized. Preferred examples include copolymer polyesters. Examples of such polyester include material-recycled or chemical-recycled polyester, and polyethylene terephthalate, which is described in JP-A-2009-01694, using a monomer component obtained from a biomass-derived material, that is, a biological material, Polytrimethylene terephthalate, polyethylene naphthalate, and polytrimethylene naphthalate may be used. Among these, polyethylene terephthalate and polybutylene terephthalate are particularly preferable in that they have rigidity enough to prevent deformation of the fiber cross-sectional shape even when there is a load. Polytrimethylene terephthalate is particularly preferable in that it has soft characteristics. Furthermore, the polyester obtained using the catalyst containing the specific phosphorus compound and titanium compound which are described in Unexamined-Japanese-Patent No. 2004-270097 and 2004-2111268 may be sufficient. In the polyester, a fine pore forming agent, a cationic dye dyeing agent, an anti-coloring agent, a thermal stabilizer, a fluorescent whitening agent, a matting agent, a coloring agent may be added as necessary within the range not impairing the object of the present invention. 1 type (s) or 2 or more types of an agent, a hygroscopic agent, and inorganic fine particles may be contained. The polyolefin is not limited to the above single-component polyolefin, but may be a copolymer of the above polyolefin, a carboxyl group such as vinyl acetate, maleic acid, maleic anhydride, a hydroxyl group, an ester group, an amino group, an amide group. Further, a polyolefin obtained by copolymerizing an alkene having a cyano group or a halogen group may be used.

また、前記中空繊維において、前記油剤には、脂肪酸エステル、多価アルコールエステル、エーテルエステル、ポリエーテル、ポリシロキサン、鉱物油などの平滑剤や帯電防止剤、界面活性剤、集束剤、防錆剤、防腐剤、酸化防止剤を加えてもよい。特にポリシロキサンを含有する油剤は、繊維に平滑性を与え、ソフトな風合いを与えるため、好ましい。
前記中空繊維は、例えば、固有粘度(オルソクロロフェノールを溶媒として使用し35℃で測定)0.55〜0.80dL/gのポリエステルポリマーを用いて、例えば図3に模式的に示す吐出形状を有する口金を用いて常法により紡糸、延伸した後、必要に応じて油剤を付与し、次いで、必要に応じて押し込みクリンパーで機械捲縮を付与し、必要に応じて上述したような所定の繊維長に切断することにより製造することができる。
In the hollow fiber, the oil agent includes a smoothing agent such as fatty acid ester, polyhydric alcohol ester, ether ester, polyether, polysiloxane, mineral oil, antistatic agent, surfactant, bundling agent, and rust inhibitor. Further, an antiseptic and an antioxidant may be added. In particular, an oil containing polysiloxane is preferable because it provides smoothness and soft texture to the fiber.
The hollow fiber has, for example, a discharge shape schematically shown in FIG. 3 using a polyester polymer having an intrinsic viscosity (measured at 35 ° C. using orthochlorophenol as a solvent) of 0.55 to 0.80 dL / g. After spinning and drawing by a conventional method using a base having, an oil agent is applied if necessary, then a mechanical crimp is applied by an indentation crimper if necessary, and a predetermined fiber as described above if necessary It can be manufactured by cutting into long pieces.

本発明の詰綿は、前記のような特徴を有し、前記の方法により製造された中空繊維を20〜100重量%含み、全体の加重平均繊度が、0.1〜11.0dtexである必要がある。ここで、加重平均繊度は、詰綿を構成する中空繊維の繊度と、詰綿中に含まれる該中空繊維の重量分率を掛けて、加算したものである。詰め綿を構成する繊維(上述したようなフィンを有する中空繊維ではない繊維を含む。)が複数種類ある場合には、それらの繊維成分ごとに繊度と重量分率を掛け合わせた数値を加算する。該中空繊維の混率が、20重量%より小さいと、上述した中空繊維の効果を得ることができない。より好ましくは該中空繊維の混率の範囲は30〜100重量%、更により好ましくは40〜100重量%である。また上述した中空繊維を20重量%以上含む、詰綿を構成する繊維の加重平均繊度が0.1dtexより小さいと、中空率が充分な値であり、フィン数が上記の個数を有する繊維であってもデッドエアー(移動しない空気層)を形成する効果が小さくなる。その結果、詰綿の嵩性および嵩回復性が不足するため、好ましくない。加重平均繊度が11.0dtexを超えると保温性が不足するため、好ましくない。より好ましくは該繊維の加重平均繊度の範囲は0.5〜10dtex、更により好ましくは1.0〜8.0dtexである。ここで、詰綿を構成する繊維の加重平均繊度とは、構成する繊維の種類毎に単糸繊度(dtex単位)と詰綿の混率(0〜100%)を掛け、その値を構成する全繊維についての和により算出することができる。加重平均繊度は詰め綿を構成する繊維の繊度の選択、繊維の紡糸・延伸条件(紡糸口金の吐出孔の大きさ、延伸倍率等)により適宜調整することができる。   The stuffed cotton of the present invention has the characteristics as described above, contains 20 to 100% by weight of hollow fibers produced by the above method, and the total weighted average fineness needs to be 0.1 to 11.0 dtex. There is. Here, the weighted average fineness is obtained by multiplying the fineness of the hollow fibers constituting the filling cotton by the weight fraction of the hollow fibers contained in the filling cotton. When there are a plurality of types of fibers (including fibers that are not hollow fibers having fins as described above) constituting the stuffed cotton, a numerical value obtained by multiplying the fineness and the weight fraction is added for each fiber component. . When the mixing ratio of the hollow fibers is less than 20% by weight, the above-described effects of the hollow fibers cannot be obtained. More preferably, the range of the mixing ratio of the hollow fibers is 30 to 100% by weight, and still more preferably 40 to 100% by weight. In addition, when the weighted average fineness of the fibers constituting the cotton filling containing 20% by weight or more of the hollow fibers is smaller than 0.1 dtex, the hollowness is a sufficient value and the number of fins is a fiber having the above number. However, the effect of forming dead air (an air layer that does not move) is reduced. As a result, the stuffed cotton is not preferred because it lacks bulkiness and bulk recovery. When the weighted average fineness exceeds 11.0 dtex, the heat retaining property is insufficient, which is not preferable. More preferably, the range of the weighted average fineness of the fiber is 0.5 to 10 dtex, and even more preferably 1.0 to 8.0 dtex. Here, the weighted average fineness of the fibers constituting the stuffed cotton is obtained by multiplying the single yarn fineness (in units of dtex) and the blending ratio (0 to 100%) of the stuffed cotton for each type of the constituent fibers. It can be calculated by the sum of the fibers. The weighted average fineness can be appropriately adjusted according to the selection of the fineness of the fibers constituting the stuffed cotton and the spinning / drawing conditions of the fibers (size of the discharge hole of the spinneret, draw ratio, etc.).

本発明の詰綿は、前記の中空繊維を含んでおり、該中空繊維は、その断面形状、特にコアー部の形状、中空率、フィン数が所定の個数に規定されているために、単糸の剛性、反発性が高いため、嵩性および嵩回復性に優れる。また、中空部に加え、放射状に突出したフィンを有することによって、単糸繊維中だけでなく単糸繊維間にも空隙ができるため、嵩性がさらに向上するのと同時に、保温性をも向上させることができる。すなわち、本発明の効果は、中空部と、適切な個数のフィン部を同一繊維内に有することにより、はじめて得られる効果であり、中空部のみ、もしくは、フィン部のみを有する繊維(丸中空断面繊維やY字断面や十字断面のような多葉断面繊維)では、十全な効果が得難いものである。また本発明の詰め綿においては、前記の方法により製造された中空繊維を多く含む場合が好ましいが、詰綿を構成する繊維として、0.01〜1.1dtexの極細中実繊維を10〜80質量%含む構成の詰綿も好ましい一態様である。特に細繊度の中実繊維を含むことで、詰綿全体としては十分な反発性を有しつつ、表面の触感がソフトにできる点で好ましい。   The stuffed cotton of the present invention includes the hollow fiber, and the hollow fiber has a cross-sectional shape, in particular, a core portion shape, a hollow ratio, and a number of fins. Because of its high rigidity and resilience, it is excellent in bulkiness and bulk recovery. In addition to the hollow part, by having radially protruding fins, voids are created not only in the single yarn fiber but also between the single yarn fibers, so that the bulk is further improved and the heat retention is also improved. Can be made. That is, the effect of the present invention is an effect obtained for the first time by having a hollow part and an appropriate number of fin parts in the same fiber, and is a fiber having only a hollow part or only a fin part (round hollow cross section). With fibers, multi-leaf cross-section fibers such as Y-shaped cross-sections and cross-sections, it is difficult to obtain a sufficient effect. Further, in the stuffed cotton of the present invention, it is preferable to contain a lot of hollow fibers produced by the above method, but as the fiber constituting the stuffed cotton, 0.01 to 1.1 dtex ultrafine solid fibers of 10 to 80 are used. Cotton filling with a composition containing mass% is also a preferred embodiment. In particular, the inclusion of solid fibers with a fineness is preferable in that the entire stuffed cotton has sufficient resilience and the surface feel can be softened.

上記詰綿の形態は、特に限定されるものではなく、カード機や開繊機で開繊された綿、ウェブ、ファイバーボール、樹脂綿、未捲縮トウ、捲縮を付与したトウ、繊維構造体等、いずれの形態であってもよい。また、保温性を向上させるために、極細繊維を混綿、メルトブロー不織布を積層する等を実施してよい。   The form of the stuffed cotton is not particularly limited. Cotton, web, fiber ball, resin cotton, uncrimped tow, crimped tow, and fiber structure opened by a card machine or a spreader Any form may be used. Moreover, in order to improve heat retention, you may implement blending of an ultrafine fiber, a melt blown nonwoven fabric, etc.

次に、本発明の繊維製品は、前記の詰綿を含む、ふとん、まくら、ぬいぐるみ、衣料、およびクッション構造体からなる群より選択されるいずれかの繊維製品である。通常、これらの繊維製品は前記詰綿と側地とで構成される。その際、側地を構成する布帛としては、ポリエステルや綿などからなる繊維で構成された通常の織編物でよい。本発明の繊維製品は、前記の詰綿を含むため、優れた嵩性、嵩回復性および保温性を有する。   Next, the textile product of the present invention is any textile product selected from the group consisting of a futon, a pillow, a stuffed toy, a garment, and a cushion structure, including the above-described cotton filling. Usually, these textile products are composed of the padding and the side fabric. In that case, as a fabric which comprises a side fabric, the normal woven / knitted fabric comprised by the fiber which consists of polyester, cotton, etc. may be sufficient. Since the fiber product of the present invention contains the above-mentioned cotton wool, it has excellent bulkiness, bulk recovery properties, and heat retention.

次に本発明の実施例及び比較例を詳述するが、本発明はこれらによって限定されるものではない。なお、実施例中の各測定項目は下記の方法で測定した。   Next, although the Example and comparative example of this invention are explained in full detail, this invention is not limited by these. In addition, each measurement item in an Example was measured with the following method.

<固有粘度(IV)>
ポリマー試料を一定量計量し、35℃のo−クロロフェノールに0.012g/mlの濃度に溶解してから、常法に従って求めた。
<Intrinsic viscosity (IV)>
A predetermined amount of the polymer sample was weighed and dissolved in o-chlorophenol at 35 ° C. to a concentration of 0.012 g / ml, and then determined according to a conventional method.

<繊度>
JIS L 1015:2005 8.5.1 A法に記載の方法により測定した。
<Fineness>
Measured by the method described in JIS L 1015: 2005 8.5.1 Method A.

<強度・伸度>
JIS L 1015:2005 8.7.1法に記載の方法により測定した。
<Strength / Elongation>
It was measured by the method described in JIS L 1015: 2005 8.7.1 method.

<捲縮数、捲縮率>
JIS L 1015:2005 8.12.1〜8.12.2法に記載の方法により測定した。
<Number of crimps, crimp ratio>
It was measured by the method described in JIS L 1015: 2005 8.12.1 to 8.12.2.

<中空率>
中空率(%)=[1−(A/B)]×100
A;単糸繊維軸に直交する断面面積
B;単糸繊維横断面最外周面積
<Hollow rate>
Hollow ratio (%) = [1- (A / B)] × 100
A: Cross-sectional area perpendicular to the single yarn fiber axis B: Single-fiber cross-sectional outermost area

<異型度>
異型度=R/r
R:単糸繊維軸に直交する断面の最外周の長径
r:単糸繊維軸に直交する断面のコアー部の長径
<Atypical degree>
Atypical degree = R / r
R: major axis of outermost circumference of cross section perpendicular to single yarn fiber axis r: major axis of core portion of cross section perpendicular to single yarn fiber axis

<嵩性>
積層カードウェブ等から作成した詰綿を14.1cm×14.1cmの大きさでカットし、重量が20gとなるように試験サンプルを作製した。次いで、該サンプルに0.5g/cmの荷重板を載せ、おもり2kgを30秒間載せ、次にこのおもり2kgを除き30秒間放置した。この操作を3回繰返しおもり2kgを除いて30秒間放置後、4隅の高さを測定して平均値を求め下記式により嵩性(cm/g)を算出した。嵩性が85cm/g以上であれば良好とする。
嵩性(cm/g)=(14.1×14.1×h/10)/W
h:サンプルの4隅の高さの平均値(mm)
W:サンプルの質量(g)
<Bulkness>
The test sample was produced so that the filling cotton produced from the lamination | stacking card | curd web etc. was cut by the magnitude | size of 14.1cm x 14.1cm, and a weight might be set to 20g. Next, a load plate of 0.5 g / cm 2 was placed on the sample, 2 kg of weight was placed for 30 seconds, and then 2 kg of this weight was removed and left for 30 seconds. This operation was repeated 3 times, the weight was removed for 2 seconds except 2 kg of weight, the height of the four corners was measured, the average value was obtained, and the bulk (cm 3 / g) was calculated by the following formula. A bulkiness of 85 cm 3 / g or more is considered good.
Bulkiness (cm 3 /g)=(14.1×14.1×h/10)/W
h: Average height of four corners of sample (mm)
W: Mass of sample (g)

<保温性>
ASTM D−1518−57Tにより放熱量を測定し、下記式により保温性(%)を算出した。保温性が75%以上であれば良好とする。
保温性(%)=[1−((発熱体に試験片を取り付けたときの放熱量(W/h))/(発熱体の空試験の放熱量(W/h))]×100
<Heat retention>
The amount of heat release was measured by ASTM D-1518-57T, and the heat retention (%) was calculated by the following formula. If the heat retention is 75% or more, it is considered good.
Thermal insulation (%) = [1 − ((Heat release amount when a test piece is attached to a heating element (W / h)) / (Heat release amount of a heating element in a blank test (W / h))] × 100

[実施例1]
80℃で1時間、170℃で4時間乾燥した固有粘度が0.64dL/g、融点256℃のポリエチレンテレフタレートを溶融し、図2に示す吐出孔を534孔有する紡糸口金より600g/min吐出した。吐出された糸条を吐出面から31mmの位置で、冷却風で空冷し、750m/minの速度で捲き取り、未延伸糸を得た。この未延伸糸を、70℃の温水中で2.41倍、90℃の温水中で、1.10倍で延伸し、ステアリン酸カリウムを0.3重量%付与した後、45℃に加熱した後、押し込みクリンパーで、捲縮を付与し、136℃で60分間乾燥した後、64mmの繊維長にカットし、繊度6.6dtex、中空率が8%、異型度1.90、引張り強度が2.66cN/dtex、伸度が58.4%、捲縮数13.3個/2.54cm、捲縮率15.5%の短繊維を得た。
得られた短繊維をローラーカードにかけてカーディングし、成型機でカードウェブを積層し詰綿を作製し、嵩性を評価した。得られた結果を表1に示した。
[Example 1]
Polyethylene terephthalate having an intrinsic viscosity of 0.64 dL / g and a melting point of 256 ° C. dried at 80 ° C. for 1 hour and 170 ° C. for 4 hours was melted, and discharged at 600 g / min from a spinneret having 534 holes as shown in FIG. . The discharged yarn was air-cooled with cooling air at a position 31 mm from the discharge surface and wound at a speed of 750 m / min to obtain an undrawn yarn. This undrawn yarn was drawn 2.41 times in warm water at 70 ° C., 1.10 times in warm water at 90 ° C., 0.3 wt% potassium stearate was added, and then heated to 45 ° C. Thereafter, crimping was performed with an indentation crimper, and after drying at 136 ° C. for 60 minutes, the fiber was cut into a fiber length of 64 mm, a fineness of 6.6 dtex, a hollowness ratio of 8%, a degree of profile 1.90, and a tensile strength of 2 A short fiber having a .66 cN / dtex, an elongation of 58.4%, a number of crimps of 13.3 pieces / 2.54 cm, and a crimp rate of 15.5% was obtained.
The obtained short fibers were carded on a roller card, and card webs were laminated with a molding machine to produce stuffed cotton, and the bulkiness was evaluated. The obtained results are shown in Table 1.

[実施例2]
吐出された糸条を吐出面から27mmの位置で、冷却風で空冷すること以外は、実施例1と同様にし、繊度6.6dtex、中空率が12%、異型度1.95、引張り強度が2.66cN/dtex、伸度が58.4%、捲縮数13.3個/2.54cm、捲縮率12.5%の短繊維を得た。得られた短繊維を実施例1と同様に嵩性、保温性を評価した。得られた結果を表1に示した。
[Example 2]
Except that the discharged yarn is air-cooled with cooling air at a position 27 mm from the discharge surface, the same as in Example 1, fineness 6.6 dtex, hollowness 12%, profile degree 1.95, tensile strength A short fiber having 2.66 cN / dtex, elongation of 58.4%, number of crimps of 13.3 pieces / 2.54 cm, and crimp rate of 12.5% was obtained. The obtained short fibers were evaluated for bulkiness and heat retention in the same manner as in Example 1. The obtained results are shown in Table 1.

[実施例3]
80℃で1時間、170℃で4時間乾燥した固有粘度が0.64dL/g、融点256℃のポリエチレンテレフタレートを溶融し、図2に示す吐出孔を534孔有する紡糸口金より580g/min吐出した。吐出された糸条を吐出面から31mmの位置で、冷却風で空冷し、500m/minの速度で捲き取り、未延伸糸を得た。この未延伸糸を90℃の温水中で8.4倍、90℃の温水中で、2.50倍で延伸し、ステアリン酸カリウムを0.3重量%付与した後、捲縮を付与し、136℃で60分間乾燥した後、38mmの繊維長にカットし、繊度1.1dtex、中空率が18%、異型度1.50、引張り強度が2.3cN/dtex、伸度が51%、捲縮数13.9個/2.54cm、捲縮率10.5%の短繊維を得た。得られた短繊維を実施例1と同様に嵩性、保温性を評価した。得られた結果を表1に示した。
[Example 3]
Polyethylene terephthalate having an intrinsic viscosity of 0.64 dL / g and a melting point of 256 ° C., dried at 80 ° C. for 1 hour and 170 ° C. for 4 hours, was melted and discharged from a spinneret having 534 holes as shown in FIG. . The discharged yarn was air-cooled with cooling air at a position 31 mm from the discharge surface, and wound at a speed of 500 m / min to obtain an undrawn yarn. This unstretched yarn was stretched 8.4 times in warm water at 90 ° C. and 2.50 times in warm water at 90 ° C., and after 0.3% by weight of potassium stearate was imparted, crimps were imparted, After drying at 136 ° C. for 60 minutes, it was cut into a fiber length of 38 mm, the fineness was 1.1 dtex, the hollowness was 18%, the profile was 1.50, the tensile strength was 2.3 cN / dtex, the elongation was 51%, A short fiber having a number of crimps of 13.9 pieces / 2.54 cm and a crimping ratio of 10.5% was obtained. The obtained short fibers were evaluated for bulkiness and heat retention in the same manner as in Example 1. The obtained results are shown in Table 1.

[実施例4]
実施例1と実施例3で得られた短繊維(中空繊維)を、重量比(前者:後者)50:50となるように混綿した後、ローラーカードにかけてカーディングし、成型機でカードウェブを積層し詰綿を作製し、実施例1と同様に嵩性、保温性を評価した。得られた結果を表1に示した。
[Example 4]
After the short fibers (hollow fibers) obtained in Example 1 and Example 3 were blended so that the weight ratio (the former: the latter) was 50:50, they were carded over a roller card, and the card web was formed with a molding machine. Laminated cotton was produced, and the bulkiness and heat retention were evaluated in the same manner as in Example 1. The obtained results are shown in Table 1.

[実施例5]
実施例1と実施例3で得られた短繊維(中空繊維)を、重量比(前者:後者)80:20となるように混綿した後、ローラーカードにかけてカーディングし、成型機でカードウェブを積層し詰綿を作製し、実施例1と動揺に嵩性、保温性を評価した。得られた結果を表1に示した。
[Example 5]
After blending the short fibers (hollow fibers) obtained in Example 1 and Example 3 so that the weight ratio (the former: the latter) is 80:20, carding is performed on a roller card, and the card web is formed with a molding machine. Laminated cotton was produced, and bulkiness and heat retention were evaluated for shaking as in Example 1. The obtained results are shown in Table 1.

[実施例6]
80℃で1時間、170℃で4時間乾燥した固有粘度が0.47dL/g、融点256℃のポリエチレンテレフタレートを溶融し、孔径0.18mmの丸断面の吐出孔を2504孔有する紡糸口金より400g/min吐出した。吐出された糸条を吐出面から27mmの位置で、冷却風で空冷し、1300m/minの速度で捲き取り、未延伸糸を得た。この未延伸糸を70℃の温水中で2.7倍、90℃の温水中で、1.19倍で延伸し、ステアリン酸カリウムを0.3重量%付与した後、捲縮を付与し、136℃で60分間乾燥した後、38mmの繊維長にカットし、繊度0.5dtex、引張り強度が3.6cN/dtex、伸度が25%、捲縮数16.2個/2.54cm、捲縮率13.0%の中実丸型断面短繊維を得た。
このようにして得られた繊維と実施例1で得られた短繊維(中空繊維)を、重量比(前者:後者)50:50となるように混綿した後、ローラーカードにかけてカーディングし、成型機でカードウェブを積層し詰綿を作製し、実施例1と同様に嵩性、保温性を評価した。得られた結果を表1に示した。
[Example 6]
400 g from a spinneret having a polyethylene terephthalate having an intrinsic viscosity of 0.47 dL / g and a melting point of 256 ° C. dried at 80 ° C. for 1 hour and 170 ° C. for 4 hours, and 2504 holes having a round cross section with a hole diameter of 0.18 mm. / Min was discharged. The discharged yarn was air-cooled with cooling air at a position 27 mm from the discharge surface, and was wound off at a speed of 1300 m / min to obtain an undrawn yarn. This unstretched yarn was stretched 2.7 times in warm water at 70 ° C. and 1.19 times in warm water at 90 ° C., and after 0.3% by weight of potassium stearate was imparted, crimps were imparted, After drying at 136 ° C. for 60 minutes, it is cut into a fiber length of 38 mm, the fineness is 0.5 dtex, the tensile strength is 3.6 cN / dtex, the elongation is 25%, the number of crimps is 16.2 pieces / 2.54 cm, A solid round cross-section short fiber having a reduction ratio of 13.0% was obtained.
The fibers thus obtained and the short fibers (hollow fibers) obtained in Example 1 were blended so that the weight ratio (the former: the latter) was 50:50, and then carded over a roller card and molded. The card webs were laminated with a machine to produce stuffed cotton, and the bulkiness and heat retention were evaluated in the same manner as in Example 1. The obtained results are shown in Table 1.

[実施例7]
実施例1で得られた短繊維(中空繊維)と実施例6で得られた繊維(中実丸型断面短繊維)を、重量比(前者:後者)30:70となるように混綿した後、ローラーカードに掛けてカーディングし、成型機でカードウェブを積層し詰綿を作製し、実施例1と同様に嵩性、保温性を評価した。得られた結果を表1に示した。
[Example 7]
After blending the short fiber (hollow fiber) obtained in Example 1 and the fiber (solid round section short fiber) obtained in Example 6 so that the weight ratio (the former: the latter) is 30:70 Then, carding was carried out on a roller card, and card webs were laminated with a molding machine to produce stuffed cotton, and the bulkiness and heat retention were evaluated in the same manner as in Example 1. The obtained results are shown in Table 1.

[実施例8]
実施例1において、カットする前の長繊維トウを採取し、これをシート状に開繊した後、100g/m2となるよう積層し、実施例1と同様に嵩性、保温性を評価した。得られた結果を表2に示した。
[Example 8]
In Example 1, long fiber tows before being cut were collected, opened in a sheet shape, laminated to 100 g / m 2, and bulkiness and heat retention were evaluated in the same manner as in Example 1. . The obtained results are shown in Table 2.

[実施例9]
実施例1において、繊維長を32mmとし、ファイバーボール製造装置にて、ファイバーボール状に加工した後、詰綿を作製し、実施例1と同様に嵩性、保温性を評価した。得られた結果を表2に示した。
[Example 9]
In Example 1, the fiber length was set to 32 mm, and after processing into a fiber ball shape with a fiber ball manufacturing apparatus, padding was produced, and the bulkiness and heat retention were evaluated in the same manner as in Example 1. The obtained results are shown in Table 2.

[比較例1]
実施例1において、断面形状を中空率28%の8フィン四角中空断面形状、繊度6.6dtex、中空率が18%、異型度2.1、引張り強度が2.89cN/dtex、伸度が49%、捲縮数11.2個/2.54cm、捲縮率5.9%の短繊維を得た。実施例1と同様に嵩性、保温性を評価した。得られた結果を表2に示した。
[Comparative Example 1]
In Example 1, the cross-sectional shape is an 8-fin square hollow cross-sectional shape with a hollow rate of 28%, fineness of 6.6 dtex, hollow rate of 18%, variant degree 2.1, tensile strength of 2.89 cN / dtex, and elongation of 49. %, A short fiber having a number of crimps of 11.2 pieces / 2.54 cm and a crimping rate of 5.9% was obtained. The bulkiness and heat retention were evaluated in the same manner as in Example 1. The obtained results are shown in Table 2.

[比較例2]
実施例1において、断面形状が丸中空となる口金を使用し、繊度6.6dtex、中空率25%、引張り強度が3.4cN/dtex、伸度が51%、捲縮数13.1個/2.54cm、捲縮率9.4%の短繊維を得た。実施例1と同様に詰綿および詰綿構造体を作製し、評価を行った。得られた結果を表2に示した。
[Comparative Example 2]
In Example 1, a die whose cross-sectional shape is round and hollow is used, and the fineness is 6.6 dtex, the hollowness is 25%, the tensile strength is 3.4 cN / dtex, the elongation is 51%, and the number of crimps is 13.1 / A short fiber of 2.54 cm and a crimp rate of 9.4% was obtained. In the same manner as in Example 1, stuffed cotton and stuffed cotton structures were produced and evaluated. The obtained results are shown in Table 2.

[比較例3]
実施例1において、断面形状が三角中空となる口金を使用し、繊度6.6dtex、中空率21%、引張り強度が2.9cN/dtex、伸度が43%、捲縮数12.8個/2.54cm、捲縮率8.5%の短繊維を得た。実施例1と同様に詰綿および詰綿構造体を作製し、実施例1と同様に嵩性、保温性を評価した。得られた結果を表2に示した。
[Comparative Example 3]
In Example 1, a die having a triangular hollow cross section is used, the fineness is 6.6 dtex, the hollowness is 21%, the tensile strength is 2.9 cN / dtex, the elongation is 43%, the number of crimps is 12.8 / A short fiber of 2.54 cm and a crimp rate of 8.5% was obtained. Cotton stuffing and cotton stuffing structures were produced in the same manner as in Example 1, and the bulkiness and heat retention were evaluated in the same manner as in Example 1. The obtained results are shown in Table 2.

[比較例4]
実施例1で得られた短繊維(中空繊維)と実施例6で得られた繊維(中実丸型断面短繊維)を、重量比(前者:後者)15:85となるように混綿した後、ローラーカードに掛けてカーディングし、成型機でカードウェブを積層し詰綿を作製し、実施例1と同様に嵩性、保温性を評価した。得られた結果を表2に示した。
[Comparative Example 4]
After blending the short fibers (hollow fibers) obtained in Example 1 and the fibers (solid round cross-section short fibers) obtained in Example 6 so that the weight ratio (the former: the latter) is 15:85. Then, carding was carried out on a roller card, and card webs were laminated with a molding machine to produce stuffed cotton, and the bulkiness and heat retention were evaluated in the same manner as in Example 1. The obtained results are shown in Table 2.

Figure 2015188487
Figure 2015188487

Figure 2015188487
Figure 2015188487

本発明によれば、優れた嵩性および保温性を同時に有する詰綿を提供することができる。更に、該詰綿を用いてなる繊維製品を提供することができ、繊維製品の消費者に対して快適な生活資材を提供することができる。   ADVANTAGE OF THE INVENTION According to this invention, the cotton stuffing which has the outstanding bulkiness and heat retention property can be provided. Furthermore, a textile product using the stuffed cotton can be provided, and comfortable living materials can be provided to consumers of the textile product.

A:黒色着色部が単糸繊維横断面(繊維を構成するポリマー樹脂等で占められている部分の面積)を表す領域である。
B:点線で表した領域内が単糸繊維横断面最外周面積である。
R:単糸繊維軸に直交する断面の最外周の長径を表す。
r:単糸繊維軸に直交する断面のコアー部の長径を表す。
A: This is a region where the black colored portion represents a single fiber cross section (area of the portion occupied by the polymer resin or the like constituting the fiber).
B: The area represented by the dotted line is the outermost peripheral area of the single yarn fiber cross section.
R: The major axis of the outermost circumference of the cross section perpendicular to the single yarn fiber axis.
r: represents the major axis of the core part of the cross section perpendicular to the single fiber axis.

Claims (6)

中空繊維を20〜100重量%含む詰綿であって、前記詰綿を構成する全繊維の加重平均繊度が0.1〜11.0dtexからなる詰綿であり、前記中空繊維は繊維軸に対して直交する断面が丸型もしくは辺の数が6以上の多角形型であるコアー部と、該コアー部の外周表面から放射状に突出する6〜12個のフィン部とを有し、前記中空繊維の繊維軸に対して直交する断面において、下記式で示す中空率が5〜25%であることを特徴とする、詰綿。
中空率(%)=(1−(A/B))×100
A:単糸繊維軸に直交する断面面積
B:単糸繊維横断面最外周面積
It is a stuffing cotton containing 20 to 100% by weight of hollow fibers, wherein the weighted average fineness of all the fibers constituting the stuffing cotton is 0.1 to 11.0 dtex, and the hollow fibers are in relation to the fiber axis. The hollow fiber has a core portion that is a round shape or a polygonal shape having six or more sides and a fin portion that protrudes radially from the outer peripheral surface of the core portion, In the cross section orthogonal to the fiber axis, the hollowness shown by the following formula is 5 to 25%,
Hollow ratio (%) = (1− (A / B)) × 100
A: Cross-sectional area perpendicular to single yarn fiber axis B: Single-fiber cross-sectional outermost area
前記中空繊維の繊維軸に対して直交する断面において、下記式で示す異型度が1.2〜3.0であることを特徴とする、請求項1に記載の詰綿。
異型度=R/r
R:単糸繊維軸に直交する断面の最外周の長径
r:単糸繊維軸に直交する断面のコアー部の長径
The stuffed cotton according to claim 1, wherein the cross-section perpendicular to the fiber axis of the hollow fiber has a degree of irregularity represented by the following formula of 1.2 to 3.0.
Atypical degree = R / r
R: major axis of outermost circumference of cross section perpendicular to single yarn fiber axis r: major axis of core portion of cross section perpendicular to single yarn fiber axis
詰綿を形成するのが、捲縮トウであることを特徴とする、請求項1または2に記載の詰綿。   The cotton stuffing according to claim 1 or 2, wherein the stuffing cotton is formed by crimped tow. 前記中空繊維を構成するポリマーが、ポリエチレンテレフタレートであることを特徴とする、請求項1〜3のいずれか1項に記載の詰綿。   The filling cotton according to any one of claims 1 to 3, wherein the polymer constituting the hollow fiber is polyethylene terephthalate. 詰綿を構成する繊維として、0.01〜1.1dtexの中実繊維を10〜80質量%含むことを特徴とする、請求項1〜4のいずれか1項に記載の詰綿。   The cotton stuffing according to any one of claims 1 to 4, comprising 10 to 80 mass% of solid fibers of 0.01 to 1.1 dtex as fibers constituting the stuffing cotton. 前記辺の数が6以上の多角形が前記フィンの数と同数の辺の数を有する多角形である請求項1〜5のいずれか1項に記載の詰綿。   The filling cotton according to any one of claims 1 to 5, wherein the polygon having 6 or more sides is a polygon having the same number of sides as the number of fins.
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Publication number Priority date Publication date Assignee Title
KR20190138521A (en) * 2018-06-05 2019-12-13 주식회사 휴비스 Hollow Conjugate Yarn with Natural Fiber-like Characteristics
CN111329758A (en) * 2020-03-03 2020-06-26 江苏省肿瘤防治研究所(江苏省肿瘤医院) Mixed dispensing device of oncology intravenous route

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JPS56101966A (en) * 1980-01-14 1981-08-14 Toray Industries Filament pile rich in flexibility * high bulkiness and warmth preservation
JPS56107892U (en) * 1980-10-02 1981-08-21
JPH09310240A (en) * 1996-05-23 1997-12-02 Unitika Ltd Multilobar shrinking yarn
JP2002061025A (en) * 2000-08-10 2002-02-28 Teijin Ltd Polyester fiber
JP2006115987A (en) * 2004-10-20 2006-05-11 Toray Ind Inc Wadding
JP2008297648A (en) * 2007-05-30 2008-12-11 Solotex Corp Polytrimethylene terephthalate staple fiber
JP2011200295A (en) * 2010-03-24 2011-10-13 Teijin Fibers Ltd Cotton filler and fiber product
JP2012214951A (en) * 2011-03-28 2012-11-08 Toray Ind Inc Blended wadding

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20190138521A (en) * 2018-06-05 2019-12-13 주식회사 휴비스 Hollow Conjugate Yarn with Natural Fiber-like Characteristics
KR102586539B1 (en) * 2018-06-05 2023-10-11 주식회사 휴비스 Hollow Conjugate Yarn with Natural Fiber-like Characteristics
CN111329758A (en) * 2020-03-03 2020-06-26 江苏省肿瘤防治研究所(江苏省肿瘤医院) Mixed dispensing device of oncology intravenous route
CN111329758B (en) * 2020-03-03 2023-03-24 江苏省肿瘤防治研究所(江苏省肿瘤医院) Mixed dispensing device of oncology intravenous route

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