JP6642624B2 - Chemical injection control method and control device for circulating water treatment chemical in wet coating booth - Google Patents

Chemical injection control method and control device for circulating water treatment chemical in wet coating booth Download PDF

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JP6642624B2
JP6642624B2 JP2018099815A JP2018099815A JP6642624B2 JP 6642624 B2 JP6642624 B2 JP 6642624B2 JP 2018099815 A JP2018099815 A JP 2018099815A JP 2018099815 A JP2018099815 A JP 2018099815A JP 6642624 B2 JP6642624 B2 JP 6642624B2
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circulating water
chemical
paint
turbidity
phenolic resin
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JP2019202280A (en
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恒行 吉田
恒行 吉田
貴大 福田
貴大 福田
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Kurita Water Industries Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/30Control equipment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B14/00Arrangements for collecting, re-using or eliminating excess spraying material
    • B05B14/40Arrangements for collecting, re-using or eliminating excess spraying material for use in spray booths
    • B05B14/46Arrangements for collecting, re-using or eliminating excess spraying material for use in spray booths by washing the air charged with excess material
    • B05B14/462Arrangements for collecting, re-using or eliminating excess spraying material for use in spray booths by washing the air charged with excess material and separating the excess material from the washing liquid, e.g. for recovery
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B16/00Spray booths
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Details Or Accessories Of Spraying Plant Or Apparatus (AREA)

Description

本発明は、湿式塗装ブース循環水処理薬剤を適正に薬注制御する方法および装置に関する。   TECHNICAL FIELD The present invention relates to a method and an apparatus for properly controlling a chemical for treating a circulating water treatment chemical in a wet coating booth.

自動車工業や家庭電器、金属製品製造業等の塗装工程では、様々な塗料がスプレー塗装されている。工業的に使用されている塗料は溶剤型塗料と水性塗料とに大別され、各塗料は単独又は併用で使用されている。   2. Description of the Related Art In a coating process in the automobile industry, home appliances, metal products manufacturing industry, and the like, various paints are spray-painted. Paints used industrially are roughly classified into solvent-based paints and water-based paints, and each paint is used alone or in combination.

水性塗料は、水可溶型、ディスパージョン型、エマルジョン型の3つに大別されるが、いずれも水を溶媒とするため(一部溶剤を併用する場合もある)、引火性がなく、安全かつ衛生的であり、溶剤による公害発生の恐れがないなどの利点を有することから、近年、特にその応用範囲が拡大されつつある。   Aqueous paints are broadly classified into three types: water-soluble, dispersion-type, and emulsion-type. However, since all use water as a solvent (some solvents may be used in combination), there is no flammability. In recent years, in particular, the range of application has been expanding because of its advantages such as safety and hygiene and no risk of pollution caused by solvents.

各種工業等における塗装工程では、一般に被塗装物に噴霧された塗料の歩留りは必ずしも100%ではなく、例えば自動車工業においては、60〜80%程度であり、使用塗料の40〜20%は次工程で除去すべき余剰塗料である。この過剰に噴霧された余剰塗料を捕集するために湿式塗装ブース内での水洗が行われており、水洗水は循環使用される。   In the coating process in various industries, the yield of the paint sprayed on the object to be coated is not necessarily 100%. For example, in the automobile industry, it is about 60 to 80%, and 40 to 20% of the paint used is in the next step. Is the surplus paint to be removed. In order to collect the excess paint sprayed excessively, water is washed in a wet coating booth, and the washing water is circulated.

この場合、水性塗料は水に可溶ないし分散し、固液分離が難しいために、この湿式塗装ブースの循環水に残留して蓄積し、次のような問題を引き起こす。
(a) 循環水は高粘性、高粘稠となり、循環ポンプの負荷を増大させ、著しい場合には循環不可能となり、操業が停止する。
(b) 析出して不溶化した塗料や、塗料以外のゴミ、SS成分が、ノズルや配管系の閉塞障害や、水膜板等への付着障害を引き起こす。
(c) 発泡障害を生じる。
(d) 循環水が高COD、高BODとなるため腐敗し、腐敗臭により、作業環境が悪化する。
(e) 高COD、高BODのため、廃水処理が困難となり、処理装置の負荷が増大する。
In this case, the water-based paint is soluble or dispersed in water, and solid-liquid separation is difficult. Therefore, the water-based paint remains in the circulating water of the wet coating booth and accumulates, causing the following problem.
(A) The circulating water becomes highly viscous and highly viscous, increasing the load of the circulating pump.
(B) Precipitated and insolubilized paint, dust other than paint, and SS components cause blockage failure of nozzles and piping systems and adhesion failure to water film plates and the like.
(C) Foaming disorder occurs.
(D) The circulating water has a high COD and a high BOD, so that it rots, and the working environment is deteriorated due to odor.
(E) Due to high COD and high BOD, wastewater treatment becomes difficult and the load on the treatment equipment increases.

このような問題を解決するために、従来、循環水に処理薬剤を添加して循環水中の余剰塗料を凝集分離することが行われている。
特許文献1には、水性塗料及び/又は溶剤型塗料を含む湿式塗装ブース循環水中の塗料を効率的に凝集処理するための処理薬剤として、フェノール系樹脂とカチオン系ポリマーとを併用することが記載されている。フェノール系樹脂とカチオン系ポリマーとの併用により、次のようなメカニズムで効果的な処理を行える。
In order to solve such a problem, conventionally, a treatment agent has been added to circulating water to coagulate and separate excess paint in the circulating water.
Patent Document 1 describes that a phenolic resin and a cationic polymer are used in combination as a treatment agent for efficiently coagulating a paint in a circulating water of a wet coating booth containing an aqueous paint and / or a solvent-based paint. Have been. By using a phenolic resin and a cationic polymer together, an effective treatment can be performed by the following mechanism.

即ち、フェノール系樹脂をアルカリ水溶液等に溶解させて湿式塗装ブース循環水に注入すると、フェノール系樹脂は、溶解状態又はコロイド状で分散する。このとき、カチオン系ポリマーが存在するとフェノール系樹脂は荷電中和されて凝結、不溶化する。一方、循環水中に溶解又はコロイド状に分散している塗料もカチオン系ポリマーにより、荷電中和されて凝結、不溶化するが、フェノール系樹脂がカチオン系ポリマーで不溶化するとき、この凝結した塗料を巻き込んだ形でフロック化して凝集する。塗料を巻き込んだ形で凝集したフェノール系樹脂のフロックは、ある程度の大きさの粒子となるので、循環水から分離除去され易く、浮上分離、遠心分離、濾過などの方法で容易に分離除去することができる。   That is, when a phenolic resin is dissolved in an alkaline aqueous solution or the like and injected into circulating water of a wet coating booth, the phenolic resin is dispersed in a dissolved state or in a colloidal state. At this time, if a cationic polymer is present, the phenolic resin is charge-neutralized and coagulates and becomes insoluble. On the other hand, the paint dissolved or colloidally dispersed in the circulating water is also charged and neutralized by the cationic polymer to be coagulated and insolubilized, but when the phenolic resin is insolubilized by the cationic polymer, the coagulated paint is involved. It flocks in the form of an ellipse and aggregates. The floc of phenolic resin aggregated in a form involving paint becomes particles of a certain size, so it is easy to separate and remove from circulating water, and it is easy to separate and remove by flotation, centrifugation, filtration, etc. Can be.

湿式塗装ブース循環水の処理においては、循環水中に含まれる塗料量に対して処理薬剤を適正な薬注量で添加することが重要である。そのために、従来は、
(1) 塗装している時間帯として製品を載せたコンベアーが動いている間だけ薬注する
(2) 生産数をカウントしながらその量に合った薬注を行う
(3) 塗料を廃棄する時間が決まっているため、(1)、(2)とは別にこの時間帯は薬注する
といった方法が行われている。これらは事前に予期できる情報をもとに薬注する方法でありフィードフォワード制御といえる。
また、実際に薬剤が吐出されているのか、タンクの残量はあるのかという情報も適正な薬注を確保する上で重要であり、センサーで、薬剤の吐出量や残量を記録することを上記のフィードフォワード制御と合わせて実施するのが望ましいとされている。
In the treatment of the circulating water in the wet coating booth, it is important to add the treatment chemical in an appropriate amount for the paint contained in the circulating water. Therefore, conventionally,
(1) During the painting time, dosing only while the conveyor carrying the product is moving (2) Doing the dosing according to the quantity while counting the number of production (3) Time to discard paint Therefore, in addition to (1) and (2), a method of injecting medicine during this time period is performed. These are methods of injecting medicine based on information that can be predicted in advance, and can be said to be feedforward control.
In addition, information on whether the medicine is actually being ejected and whether there is a remaining amount in the tank is also important for ensuring proper medicine injection.It is important to record the ejection amount and remaining amount of the medicine with a sensor. It is said that it is desirable to carry out the control in combination with the above-described feedforward control.

一方、塗料の種類の変更や塗料やシンナーの廃棄や捨て吹きなど、事前に予測しにくい条件変動もあり、これらの変動に対しては、フィードフォワード制御では適正な薬注制御を行うことができない。
このようなことから、湿式塗装ブース循環水の水質等を常時計測し、その変動に対して循環水処理薬剤の薬注制御(フィードバック制御)も合わせて実施できれば、より安定した薬注制御となり、循環水の安定処理が可能となると考えられる。
On the other hand, there are condition fluctuations that are difficult to predict in advance, such as changing the type of paint and discarding or throwing away paint or thinner, and feed forward control cannot perform appropriate chemical injection control for these changes. .
From such a situation, if the quality of the circulating water in the wet coating booth is constantly measured, and if the fluctuation can be implemented together with the chemical injection control (feedback control) of the circulating water treatment chemical, more stable chemical injection control can be achieved. It is thought that stable treatment of circulating water is possible.

特開2004−337671号公報JP-A-2004-337671

水性塗料や水性塗料と溶剤塗料混合塗料を用いた湿式塗装ブース循環水系では、予期せず循環水中の塗料量が急激に増加する場合があり、この場合、従来のフィードフォワード制御では、この急激な塗料量の増大に対応できず、循環水が発泡したり、循環水を取水してスラッジ回収装置へ送った水の高分子凝集剤による凝集処理が不良となり、スラッジ回収量が減ったりする。
なお、循環水槽からスラッジ回収装置へ送給される水やスラッジ回収装置から循環水槽に戻される水の濁度又は懸濁物質濃度を測定し、この測定値をもとに高分子凝集剤を薬注制御することは従来より行われてきたが、この方法では、湿式塗装ブース循環水の予期せぬ塗料負荷の増大に対応して塗料の適正処理(不粘着、凝集(一次凝集)、ピットでの浮上)を行うことはできず、塗料負荷増大時の循環水処理薬剤量の不足の根本対策にはならない。
一方で、循環水処理薬剤を塗料負荷の上昇を見越して常時過剰に添加することは薬剤コストが高くつき、好ましくない。
In a wet coating booth circulating water system using a water-based paint or a water-based paint and a solvent paint mixed paint, the amount of paint in the circulating water may suddenly increase unexpectedly.In this case, in the conventional feed forward control, this sharp Unable to cope with an increase in the amount of paint, the circulating water foams, or the flocculation treatment with the high-molecular flocculant of the water taken from the circulating water and sent to the sludge collecting device becomes defective, and the sludge recovery amount decreases.
The turbidity or suspended solids concentration of the water fed from the circulating water tank to the sludge collecting device and the water returned from the sludge collecting device to the circulating water tank were measured. Note that control has been performed in the past. However, in this method, appropriate treatment of paint (non-adhesion, aggregation (primary aggregation), Cannot be performed, and this is not a fundamental countermeasure against the shortage of the circulating water treatment chemical when the paint load is increased.
On the other hand, it is not preferable to constantly add a circulating water treatment chemical in anticipation of an increase in paint load, because the chemical cost increases.

本発明は上記従来技術の問題点を解決し、湿式塗装ブース循環水の予期せぬ塗料負荷の増大に的確に対応し、適正な処理薬剤の薬注制御を行うことができる方法及び装置を提供することを目的とする。   The present invention solves the above-mentioned problems of the prior art, and provides a method and an apparatus capable of appropriately coping with an unexpected increase in paint load in the circulating water of a wet-type painting booth and performing appropriate chemical injection control of a treatment chemical. The purpose is to do.

本発明者らは、上記課題を解決すべく鋭意検討を重ねた結果、湿式塗装ブース循環水の塗料負荷の増大を循環水の濁度又は懸濁物質濃度の上昇で検知し、この濁度又は懸濁物質濃度の上昇に応じて循環水処理薬剤の薬注制御を行うことで、塗料の適正処理を行えることを見出した。
即ち、本発明は以下を要旨とする。
The present inventors have conducted intensive studies to solve the above problems, and as a result, detected an increase in paint load in the circulating water of the wet coating booth by detecting an increase in the turbidity or the concentration of suspended solids in the circulating water. It has been found that by controlling the chemical injection of the circulating water treatment chemical in accordance with the increase in the concentration of the suspended solids, it is possible to carry out the proper treatment of the paint.
That is, the present invention provides the following.

[1] 湿式塗装ブース循環水中の塗料の不粘着化、凝集ないしは浮上のための処理薬剤の該循環水への薬注制御方法であって、該循環水の濁度又は懸濁物質濃度に基づいて、該循環水への該処理薬剤の添加を制御することを特徴とする湿式塗装ブース循環水処理薬剤の薬注制御方法。 [1] A wet coating booth is a method for controlling the injection of a treatment agent for preventing tackiness, agglomeration or floating of paint in circulating water into the circulating water, based on the turbidity of the circulating water or the concentration of suspended solids. Controlling the addition of the treatment agent to the circulating water by a wet coating booth.

[2] 前記循環水の濁度又は懸濁物質濃度を測定し、該濁度又は懸濁物質濃度の測定値が予め設定した所定値A以上となったときに前記処理薬剤の添加を開始するか或いは前記処理薬剤の添加量を増量することを特徴とする[1]に記載の湿式塗装ブース循環水処理薬剤の薬注制御方法。 [2] The turbidity or suspended substance concentration of the circulating water is measured, and the addition of the treatment agent is started when the measured value of the turbidity or suspended substance concentration becomes equal to or more than a predetermined value A set in advance. Alternatively, the method according to [1], wherein the amount of the treatment chemical added is increased.

[3] 前記濁度又は懸濁物質濃度の測定値が予め設定した所定値B以下となったときに前記処理薬剤の添加を停止するか或いは前記処理薬剤の添加量を減量することを特徴とする[2]に記載の湿式塗装ブース循環水処理薬剤の薬注制御方法。 [3] When the measured value of the turbidity or the suspended substance concentration becomes equal to or less than a predetermined value B set in advance, the addition of the processing agent is stopped or the amount of the processing agent added is reduced. The method for controlling chemical injection of a chemical for treating circulating water in a wet coating booth according to [2].

[4] 前記処理薬剤が、フェノール系樹脂および有機凝結剤、或いはフェノール系樹脂、有機凝結剤および高分子凝集剤であることを特徴とする[1]ないし[3]のいずれかに記載の湿式塗装ブース循環水処理薬剤の薬注制御方法。 [4] The wet method according to any one of [1] to [3], wherein the treatment agent is a phenolic resin and an organic coagulant, or a phenolic resin, an organic coagulant and a polymer flocculant. Chemical injection control method for paint booth circulating water treatment chemicals.

[5] 湿式塗装ブース循環水中の塗料の不粘着化、凝集ないしは浮上のための処理薬剤の該循環水への薬注制御装置であって、該循環水の濁度を測定する濁度計又は懸濁物質濃度を測定するSS計と、該濁度計又はSS計の測定値が入力され、該測定値に基づいて、該循環水への該処理薬剤の添加を制御する制御手段とを有することを特徴とする湿式塗装ブース循環水処理薬剤の薬注制御装置。 [5] A wet coating booth is a device for controlling the injection of a treatment agent for preventing tackiness, agglomeration or floating of the paint in the circulating water into the circulating water, wherein the turbidity meter measures the turbidity of the circulating water or It has an SS meter for measuring the concentration of suspended solids, and control means for inputting the measured value of the turbidity meter or the SS meter and controlling the addition of the treatment agent to the circulating water based on the measured value. A chemical injection control device for a wet coating booth circulating water treatment chemical, characterized in that:

[6] 前記制御手段は、前記濁度計又はSS計の測定値が予め設定した所定値A以上となったときに、前記処理薬剤の添加を開始するか或いは前記処理薬剤の添加量を増量する信号を出力することを特徴とする[5]に記載の湿式塗装ブース循環水処理薬剤の薬注制御装置。 [6] When the measured value of the turbidity meter or the SS meter becomes equal to or more than a predetermined value A set in advance, the control means starts the addition of the processing agent or increases the amount of the processing agent added. The chemical injection control device for a wet coating booth circulating water treatment chemical according to [5], which outputs a signal indicating that the chemical is to be processed.

[7] 前記制御手段は、前記濁度計又はSS計の測定値が予め設定した所定値B以下となったときに前記処理薬剤の添加を停止するか或いは前記処理薬剤の添加量を減量する信号を出力することを特徴とする[6]に記載の湿式塗装ブース循環水処理薬剤の薬注制御装置。 [7] The control means stops the addition of the processing agent or reduces the amount of the processing agent when the measured value of the turbidity meter or the SS meter becomes equal to or less than a predetermined value B set in advance. The chemical injection control device for a wet coating booth circulating water treatment chemical according to [6], which outputs a signal.

[8] 前記処理薬剤が、フェノール系樹脂および有機凝結剤、或いはフェノール系樹脂、有機凝結剤および高分子凝集剤であることを特徴とする[5]ないし[7]のいずれかに記載の湿式塗装ブース循環水処理薬剤の薬注制御装置。 [8] The wet method according to any one of [5] to [7], wherein the treatment agent is a phenolic resin and an organic coagulant, or a phenolic resin, an organic coagulant and a polymer flocculant. Injection booth circulating water treatment chemical injection control device.

本発明によれば、湿式塗装ブース循環水の予期せぬ塗料負荷の増大に的確に対応して適正な処理薬剤の薬注制御を行えるので、処理の安定化を図ることができる。   ADVANTAGE OF THE INVENTION According to this invention, since it can respond | correspond to the unexpected increase of the paint load of the circulating water of a wet-type coating booth appropriately, and can perform appropriate chemical | medical-agent injection | pouring control of a processing chemical | chemical, stabilization of a process can be achieved.

実施例1で用いた湿式塗装ブース循環水処理薬剤の薬注制御装置を示す系統図である。FIG. 3 is a system diagram showing a chemical injection control device for a wet coating booth circulating water treatment chemical used in Example 1. 実施例1における循環水の懸濁物質濃度の経時変化を示すグラフである。4 is a graph showing the change over time in the concentration of suspended solids in circulating water in Example 1.

以下に本発明の実施の形態を詳細に説明する。   Hereinafter, embodiments of the present invention will be described in detail.

本発明の湿式塗装ブース循環水処理薬剤の薬注制御方法は、湿式塗装ブース循環水中の塗料の不粘着化、凝集ないしは浮上のための処理薬剤の該循環水への薬注制御方法であって、該循環水の濁度又は懸濁物質濃度(以下、単に「濁度等」と記載する場合あり)に基づいて、該循環水への該処理薬剤の添加を制御する。
本発明の湿式塗装ブース循環水処理薬剤の薬注制御装置は、湿式塗装ブース循環水中の塗料の不粘着化、凝集ないしは浮上のための処理薬剤の該循環水への薬注制御装置であって、該循環水の濁度を測定する濁度計又は懸濁物質濃度を測定するSS計(以下、両測定センサを併せて単に「濁度計等」と記載する場合がある)と、該濁度計等の測定値が入力され、該測定値に基づいて、該循環水への該処理薬剤の添加を制御する制御手段とを有することを特徴とする。
The method for controlling chemical injection of a wet coating booth circulating water treatment chemical according to the present invention is a method for controlling the chemical injection into the circulating water of a processing chemical for making the paint in the wet coating booth circulating water non-adhesive, coagulating or floating. The addition of the treatment agent to the circulating water is controlled based on the turbidity of the circulating water or the concentration of suspended substances (hereinafter, may be simply referred to as “turbidity etc.”).
The chemical spraying control device for a wet coating booth circulating water treatment chemical of the present invention is a chemical spraying control device for treating a chemical in a wet coating booth circulating water to prevent the paint from sticking, coagulating or floating into the circulating water. A turbidity meter for measuring the turbidity of the circulating water or an SS meter for measuring the concentration of suspended solids (hereinafter, both measurement sensors may be simply referred to as “turbidity meter or the like” in some cases); And a control means for inputting a measured value from a degree meter or the like and controlling the addition of the treatment agent to the circulating water based on the measured value.

本発明における循環水処理薬剤の薬注制御は、具体的には、循環水の濁度等を測定し、該濁度等の測定値が予め設定した所定値A(以下「上限値A」と称す場合がある。)以上となったときに処理薬剤の添加を開始するか或いは処理薬剤の添加量を増量し、濁度等の測定値が予め設定した所定値B(以下「下限値B」と称す場合がある。)以下となったときに処理薬剤の添加を停止するか或いは処理薬剤の添加量を減量することで行うことが好ましい。   The chemical injection control of the circulating water treatment chemical in the present invention is, specifically, measuring the turbidity of the circulating water, and measuring the turbidity and the like to a predetermined value A (hereinafter referred to as “upper limit A”). When the amount becomes equal to or more than the above, the addition of the treatment agent is started or the amount of the treatment agent is increased, and the measurement value such as turbidity is set to a predetermined value B (hereinafter referred to as “lower limit value B”). It is preferable to stop the addition of the processing chemicals or reduce the amount of the processing chemicals when the following conditions are satisfied.

ここで、所定値A,Bとしては特に制限はなく、循環水の水質や、塗料負荷の変動幅等に応じて適宜決定される。特に制限されるものではないが、例えば、濁度の場合には、所定値Aは100〜1000の範囲で設定され、所定値Bは10〜200の範囲で設定される。そして、懸濁物質濃度の場合には所定値Aは50〜500の範囲で設定され、所定値Bは5〜200の範囲で設定される。
なお、濁度計としては、一般的なレーザー式の濁度センサ等を用いることができる。濁度の単位はNTUである。
また、SS計としては、透過式や散乱子式の光学的SS計等を用いることができる。具体的にはオプテックス社のSSチェッカーを用いることができる。懸濁物質濃度の単位はmg/Lである。
Here, the predetermined values A and B are not particularly limited, and are appropriately determined according to the quality of the circulating water, the fluctuation range of the paint load, and the like. Although not particularly limited, for example, in the case of turbidity, the predetermined value A is set in a range of 100 to 1000, and the predetermined value B is set in a range of 10 to 200. In the case of the suspended substance concentration, the predetermined value A is set in a range of 50 to 500, and the predetermined value B is set in a range of 5 to 200.
As the turbidity meter, a general laser turbidity sensor or the like can be used. The unit of turbidity is NTU.
Further, as the SS meter, a transmission type or scatterer type optical SS meter or the like can be used. Specifically, an SS checker manufactured by Optex can be used. The unit of the suspended substance concentration is mg / L.

濁度計等による循環水の濁度等の測定は、循環水系のいずれの箇所で行ってもよく、例えば、湿式塗装ブースから循環水槽に返送される循環水、或いは循環水槽内の循環水について濁度等を測定することができるが、循環水処理薬剤の薬注効果を迅速に把握することができることから、循環水槽内の循環水の濁度等を測定することが好ましい。この場合、濁度計等のセンサは、循環水槽内の水深の半分程度となるような位置に設けることが、水位変動や、堆積スラッジの影響を少なくする点で好ましい。   The measurement of the turbidity of the circulating water by a turbidity meter or the like may be performed at any point in the circulating water system.For example, the circulating water returned to the circulating water tank from the wet coating booth or the circulating water in the circulating water tank Although the turbidity and the like can be measured, it is preferable to measure the turbidity and the like of the circulating water in the circulating water tank since the effect of injecting the circulating water treatment chemical can be quickly grasped. In this case, it is preferable that the sensor such as the turbidity meter is provided at a position where the water depth is about half of the water depth in the circulating water tank, in order to reduce the influence of water level fluctuation and sediment sludge.

循環水の濁度等は、循環水中の塗料が処理薬剤による処理で浮上又は沈降することで低下するが、塗料が沈降することは好ましくないため、本発明で用いる循環水処理薬剤は、塗料を浮上させる薬剤が好ましく、後述のフェノール系樹脂とカチオン系ポリマー等の有機凝結剤との併用が好ましい。これらに更に高分子凝集剤を併用することにより、より処理の安定性を向上させることができ好ましい。   The turbidity of the circulating water, etc., decreases when the paint in the circulating water rises or sinks due to the treatment with the treatment agent.However, since it is not preferable that the paint sediments, the circulating water treatment agent used in the present invention is used for treating the paint. It is preferable to use a floating agent, and it is preferable to use a phenolic resin described below in combination with an organic coagulant such as a cationic polymer. It is preferable to further use a polymer coagulant in combination with these, because the stability of the treatment can be further improved.

以下に本発明の好適態様について更に詳述する。   Hereinafter, preferred embodiments of the present invention will be described in more detail.

<フェノール系樹脂>
本発明で使用されるフェノール系樹脂としては、フェノール、クレゾール、キシレノール等の一価フェノール等のフェノール類とホルムアルデヒド等のアルデヒドとの縮合物或いはその変性物であって、架橋硬化する前のフェノール系樹脂が挙げられる。具体的には次のようなものが挙げられる。
<Phenolic resin>
The phenolic resin used in the present invention is a condensate of a phenol such as a monohydric phenol such as phenol, cresol or xylenol and an aldehyde such as formaldehyde or a modified product thereof, and the phenolic resin before crosslinking and curing. Resins. Specific examples include the following.

[1] フェノールとホルムアルデヒドとの縮合物
[2] クレゾールとホルムアルデヒドとの縮合物
[3] キシレノールとホルムアルデヒドとの縮合物
[4] 上記[1]〜[3]のフェノール系樹脂をアルキル化して得られるアルキル変性フェノール系樹脂
[5] ポリビニルフェノール
[1] Condensate of phenol and formaldehyde [2] Condensate of cresol and formaldehyde [3] Condensate of xylenol and formaldehyde [4] Obtained by alkylating the phenolic resin of the above [1] to [3]. Alkyl-modified phenolic resin [5] polyvinyl phenol

これらのフェノール系樹脂はノボラック型であってもレゾール型であっても良い。なお、フェノール系樹脂は重量平均分子量が1,000〜10,000程度のものを好適に用いることができる。   These phenolic resins may be of novolak type or resol type. In addition, a phenolic resin having a weight average molecular weight of about 1,000 to 10,000 can be suitably used.

これらのフェノール系樹脂は、1種を単独で用いても良く、2種以上を混合して用いても良い。   One of these phenolic resins may be used alone, or two or more of them may be used in combination.

このようなフェノール系樹脂は水に難溶であるので、水に溶解可能な溶媒に溶解ないし分散させるなどして溶液状又はエマルジョンとして用いるのが好ましい。使用される溶媒としてはアセトン等のケトン、酢酸メチル等のエステル、メタノール等のアルコール等の水溶性有機溶媒、アルカリ水溶液、アミン等が挙げられるが、好ましくは、苛性ソーダ(NaOH)、苛性カリ(KOH)等のアルカリ剤に溶解して用いる。   Since such a phenolic resin is hardly soluble in water, it is preferably used as a solution or an emulsion by dissolving or dispersing in a water-soluble solvent. Examples of the solvent used include ketones such as acetone, esters such as methyl acetate and the like, water-soluble organic solvents such as alcohols such as methanol, alkaline aqueous solutions, amines, etc., and preferably caustic soda (NaOH) and caustic potash (KOH). Dissolved in an alkaline agent such as

フェノール系樹脂をアルカリ性水溶液として用いる場合、このアルカリ性水溶液はアルカリ剤濃度1〜25質量%、フェノール系樹脂濃度1〜50質量%の範囲とすることが好ましい。なお、フェノール系樹脂濃度が高い場合、70〜80℃程度に加温してフェノール系樹脂を溶解させるようにしても良い。   When the phenolic resin is used as an alkaline aqueous solution, the alkaline aqueous solution preferably has an alkaline agent concentration of 1 to 25% by mass and a phenolic resin concentration of 1 to 50% by mass. When the phenolic resin concentration is high, the phenolic resin may be dissolved by heating to about 70 to 80 ° C.

本発明において、フェノール系樹脂を循環水の濁度等に応じて薬注制御する場合、フェノール系樹脂は、循環水の濁度等に応じてON・OFF制御で、濁度等の測定値が上限値A以上となった場合にフェノール系樹脂の添加を開始し、下限値B以下となった場合にフェノール系樹脂の添加を停止するようにしてもよく、フェノール系樹脂を常時添加し、濁度等の測定値が上限値A以上となったときにフェノール系樹脂の添加量を増量し、下限値B以下となったときにフェノール系樹脂の添加量を減量するようにしてもよい。   In the present invention, when the chemical injection control of the phenolic resin is performed according to the turbidity of the circulating water, the measured value of the phenolic resin is controlled by ON / OFF control according to the turbidity of the circulating water. The addition of the phenolic resin may be started when the upper limit A or more is reached, and the addition of the phenolic resin may be stopped when the lower limit B or less is reached. The addition amount of the phenolic resin may be increased when the measured value such as the degree becomes equal to or more than the upper limit value A, and the added amount of the phenolic resin may be decreased when the measured value becomes equal to or less than the lower limit value B.

循環水へのフェノール系樹脂の添加量は、制御方法や循環水の水質(循環水中の塗料の種類や塗料含有量等)によっても異なるが、例えば、ON・OFF制御の場合、濁度等の測定値が上限値A以上となった場合は、有効成分量(フェノール系樹脂の固形分量)として循環水に対して1〜100mg/Lの添加を開始し、下限値B以下となった場合は、フェノール系樹脂の添加を停止することが好ましい。
また、フェノール系樹脂添加量を増減する場合は、有効成分量として循環水に対して1〜100mg/Lの添加量の範囲で濁度等の測定値が上限値A以上となった場合は添加量を増量し、下限値B以下となった場合は添加量を減量することが好ましい。
The amount of the phenolic resin added to the circulating water varies depending on the control method and the quality of the circulating water (the type of paint in the circulating water, the content of the paint, etc.). When the measured value is equal to or higher than the upper limit A, the addition of 1 to 100 mg / L to the circulating water as an active ingredient amount (solid content of the phenolic resin) is started. Preferably, the addition of the phenolic resin is stopped.
When the amount of the phenolic resin to be added is increased or decreased, if the measured value of the turbidity or the like exceeds the upper limit A in the range of 1 to 100 mg / L with respect to the circulating water as the amount of the active ingredient, it is added. It is preferable to increase the amount, and when the amount falls below the lower limit value B, the amount to be added is reduced.

<有機凝結剤>
有機凝結剤としては、カチオン性のものが好ましく、例えば、ジメチルジアリルアンモニウムクロライド、アルキルアミン・エピクロルヒドリン縮合物、ポリエチレンイミン、アルキレンジクロライド・ポリアルキレンポリアミン縮合物、ジシアンジクロライド・ポリアルキレンポリアミン縮合物、DMA(ジメチルアミノエチルメタクリレート)、DADMAC(ジアリルジメチルアンモニウムクロライド)等のカチオン系ポリマーが挙げられるが、何らこれらに限定されるものではない。
<Organic coagulant>
As the organic coagulant, a cationic coagulant is preferable. Examples thereof include cationic polymers such as (dimethylaminoethyl methacrylate) and DADMAC (diallyldimethylammonium chloride), but are not limited thereto.

これらの有機凝結剤は、1種を単独で用いても良く、2種以上を混合して用いても良い。   One of these organic coagulants may be used alone, or two or more thereof may be used in combination.

本発明において、有機凝結剤を循環水の濁度等に応じて薬注制御する場合、有機凝結剤は、循環水の濁度等に応じてON・OFF制御で、濁度等の測定値が上限値A以上となった場合に有機凝結剤の添加を開始し、下限値B以下となった場合に有機凝結剤の添加を停止するようにしてもよく、有機凝結剤を常時添加し、濁度等の測定値が上限値A以上となったときに有機凝結剤の添加量を増量し、下限値B以下となったときに有機凝結剤の添加量を減量するようにしてもよい。   In the present invention, when the chemical control of the organic coagulant is performed in accordance with the turbidity of the circulating water, the measured value of the turbidity and the like of the organic coagulant is controlled by ON / OFF control in accordance with the turbidity of the circulating water. The addition of the organic coagulant may be started when the upper limit value A or more is reached, and the addition of the organic coagulant may be stopped when the lower limit value B or less is reached. The addition amount of the organic coagulant may be increased when the measured value such as the degree becomes equal to or more than the upper limit value A, and may be decreased when the measured value becomes equal to or less than the lower limit value B.

循環水への有機凝結剤の添加量は、制御方法や循環水の水質(循環水中の塗料の種類や塗料含有量等)によっても異なるが、例えば、ON・OFF制御の場合、濁度等の測定値が上限値A以上となった場合は、有機凝結剤は、有効成分量として循環水に対して0.2〜20mg/Lの添加を開始し、下限値B以下となった場合は、有機凝結剤の添加を停止することが好ましい。
また、有機凝結剤添加量を増減する場合は、有効成分量として循環水に対して0.2〜20mg/Lの添加量の範囲で濁度等の測定値が上限値A以上となった場合は添加量を増量し、下限値B以下となった場合は添加量を減量することが好ましい。
The amount of the organic coagulant added to the circulating water varies depending on the control method and the quality of the circulating water (such as the type of paint in the circulating water and the content of the paint). When the measured value is equal to or higher than the upper limit A, the organic coagulant starts adding 0.2 to 20 mg / L to the circulating water as an active ingredient amount, and when the measured value is equal to or lower than the lower limit B, It is preferred to stop adding the organic coagulant.
When the amount of the organic coagulant added is increased or decreased, when the measured value of turbidity or the like exceeds the upper limit A in the range of 0.2 to 20 mg / L with respect to the circulating water as the amount of the active ingredient. It is preferable to increase the amount of addition, and to decrease the amount of addition when the amount becomes equal to or less than the lower limit B.

<高分子凝集剤>
本発明では、上記フェノール系樹脂及び有機凝結剤と共に、重量平均分子量が、通常100万超、好ましくは500万以上の水溶性高分子よりなる高分子凝集剤を併用添加してフェノール系樹脂および有機凝結剤による塗料の凝集フロックを高分子凝集剤で更に粗大化することが好ましい。
この場合、高分子凝集剤としては、公知のアニオン系高分子凝集剤、カチオン系高分子凝集剤、両性高分子凝集剤などの1種又は2種以上を用いることができる。
<Polymer flocculant>
In the present invention, a phenolic resin and an organic coagulant are added together with a polymer coagulant comprising a water-soluble polymer having a weight average molecular weight of usually more than 1,000,000, preferably 5,000,000 or more. It is preferable that the flocculated floc of the paint by the coagulant is further coarsened by the polymer flocculant.
In this case, as the polymer flocculant, one or more known anionic polymer flocculants, cationic polymer flocculants, amphoteric polymer flocculants and the like can be used.

高分子凝集剤を用いる場合、その添加量は、有効成分量として余剰塗料に対して0.1〜10質量%、好ましくは0.5〜2質量%の範囲で、良好な凝集効果が得られるように適宜決定すればよい。
なお、高分子凝集剤についても、フェノール系樹脂および有機凝結剤と同様に、循環水の濁度等に応じて薬注制御してもよいが、通常は高分子凝集剤は定量添加で十分な効果を得ることができる。
When a polymer coagulant is used, a good coagulation effect is obtained in an amount of 0.1 to 10% by mass, preferably 0.5 to 2% by mass, based on the amount of the surplus paint, as an active ingredient. May be determined as appropriate.
In addition, the polymer coagulant may be controlled by chemical injection according to the turbidity of the circulating water, as in the case of the phenolic resin and the organic coagulant. The effect can be obtained.

<薬注箇所>
フェノール系樹脂および有機凝結剤の薬注箇所としては特に制限はなく、循環水系のどのような箇所に添加してもよいが、通常の場合、循環水槽又は湿式塗装ブースから循環水槽への戻り水配管、或いはこれらの双方に添加される。また、フェノール系樹脂と有機凝結剤とは同じ箇所に添加してもよく、別々の箇所に添加してもよい。
<Drug injection point>
There is no particular limitation on the phenolic resin and organic coagulant injection point, and it may be added to any part of the circulating water system, but in the normal case, the return water from the circulating water tank or wet painting booth to the circulating water tank It is added to piping or both. Further, the phenolic resin and the organic coagulant may be added to the same place or may be added to separate places.

高分子凝集剤については、通常、スラッジ回収装置或いは循環水槽からスラッジ回収装置への循環水の送水配管に添加される。後述の実施例の項に示されるように、スラッジ回収装置への取水ポンプに注入してもよい。   The polymer flocculant is usually added to a sludge collecting device or a piping for supplying circulating water from a circulating water tank to the sludge collecting device. As shown in the section of the embodiment described later, it may be injected into a water intake pump to a sludge collecting device.

なお、凝集処理系のpHは、設備の腐食防止の点と、有機凝結剤として添加するカチオン系ポリマーのpHに関する効果特性の点から、6.0〜8.5程度であることが好ましい。従って、pHがこの範囲を外れ低くなる場合には、アルカリ剤を添加してpH調整を行うことが好ましい。通常、実機では高pH側に範囲が外れることはないが、極端に外れる場合はpH調整が必要になることがある。   The pH of the coagulation treatment system is preferably from about 6.0 to 8.5 from the viewpoint of preventing corrosion of the equipment and the effect characteristics relating to the pH of the cationic polymer added as the organic coagulant. Therefore, when the pH falls outside this range and becomes low, it is preferable to adjust the pH by adding an alkali agent. Normally, in actual machines, the range does not deviate to the high pH side, but if it deviates extremely, the pH may need to be adjusted.

<凝集フロックの回収>
フェノール系樹脂と有機凝結剤の添加、更には高分子凝集剤の添加により、循環水中の塗料は速やかに不粘着化、凝集、浮上してフロックを生成する。凝集により生成したフロックの分離回収には、浮上分離、ウェッジワイヤ、ロータリースクリーン、バースクリーン、サイクロン、遠心分離機、濾過装置などによる方法を採用することができる。
<Recovery of flocculated floc>
By the addition of the phenolic resin and the organic coagulant, and further the addition of the polymer flocculant, the paint in the circulating water quickly becomes tack-free, flocculates and floats to generate flocs. For separation and recovery of flocs generated by aggregation, a method using flotation, wedge wire, rotary screen, bar screen, cyclone, centrifugal separator, filtration device, or the like can be employed.

このような方法で分離回収されたスラッジは、重力脱水後、或いは通常の方法で脱水後、焼却、埋立処理される。   The sludge separated and recovered by such a method is subjected to incineration and landfill after gravity dehydration or after dehydration by an ordinary method.

<適用循環水>
本発明は、水性塗料を含む湿式塗装ブース循環水、或いは水性塗料と溶剤型塗料を含む湿式塗装ブース循環水のように、塗料負荷の急激な上昇で濁度等が大きく上昇する循環水の処理に効果的に適用することができる。
<Applicable circulating water>
The present invention is directed to the treatment of circulating water, such as wet coating booth circulating water containing a water-based paint, or wet coating booth circulating water containing a water-based paint and a solvent-based paint, in which turbidity and the like greatly increase due to a sharp increase in paint load. Can be applied effectively.

以下に実施例を挙げて本発明をより具体的に説明するが、本発明はその要旨を超えない限り、以下の実施例に限定されるものではない。   Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited to the following examples unless it exceeds the gist of the present invention.

なお、以下において、循環水の処理薬剤としては、以下のものを用いた。   In the following, the following circulating water treatment chemicals were used.

フェノール系樹脂のアルカリ溶液:フェノール・ホルムアルデヒド重縮合物(重量平均分子量8,000)のNaOH水溶液(フェノール系樹脂濃度:30質量%、NaOH濃度:10質量%、pH:12〜13)(以下「フェノール系樹脂溶液」と記載する。)
カチオン系ポリマー:アルキルアミン・エピクロルヒドリン縮合物(重量平均分子量:10万)の水溶液(カチオン系ポリマー濃度:50質量%)
高分子凝集剤:アクリルアミド・2(アクリロイルオキシ)エチルトリメチルアンモニウムクロライド共重合物(重量平均分子量700万)のW/O型エマルション(有効成分濃度40質量%)
Alkaline solution of phenolic resin: NaOH aqueous solution of phenol / formaldehyde polycondensate (weight average molecular weight 8,000) (phenolic resin concentration: 30% by mass, NaOH concentration: 10% by mass, pH: 12 to 13) (hereinafter referred to as " Phenolic resin solution ").
Cationic polymer: aqueous solution of alkylamine-epichlorohydrin condensate (weight average molecular weight: 100,000) (cationic polymer concentration: 50% by mass)
Polymer flocculant: W / O emulsion of acrylamide / 2 (acryloyloxy) ethyltrimethylammonium chloride copolymer (weight average molecular weight 7,000,000) (active ingredient concentration 40% by mass)

[実施例1]
図1に示す湿式塗装ブース循環水の処理装置において、本発明に従って、循環水の懸濁物質濃度に基づく処理薬剤の薬注制御を行った。
この湿式塗装ブース循環水処理薬剤の薬注制御装置は、水性塗料と溶剤塗料を用いた、循環水量10m/minで、平均的な循環水塗料濃度100mg/Lの湿式塗装ブース循環水の処理装置であり、塗料の捨て吹きや廃棄で不定期的に塗料負荷が急激に上昇することがある。
[Example 1]
In the wet coating booth circulating water treatment apparatus shown in FIG. 1, the chemical injection control of the treatment chemical based on the suspended solid concentration of the circulating water was performed according to the present invention.
This wet coating booth circulating water treatment chemical dispensing control apparatus uses a water-based paint and a solvent paint, and treats the wet-painting booth circulating water with an average circulating water paint concentration of 100 mg / L using a circulating water amount of 10 m 3 / min. It is a device, and the paint load may rise suddenly and irregularly due to the abandoned spraying or disposal of paint.

図1において、1は循環水槽であり、湿式塗装ブースからの余剰塗料を捕集した水が配管11を経て返送される。
循環水槽1内の循環水は、処理薬剤が添加されて不粘着化、凝集、浮上処理され、スクリーン2を透過した凝集処理水がポンプ12Pにより配管12を経て湿式塗装ブースに送水される。
In FIG. 1, reference numeral 1 denotes a circulating water tank in which water that has collected excess paint from a wet coating booth is returned via a pipe 11.
The circulating water in the circulating water tank 1 is treated to be tack-free, coagulated, and floated by adding a processing chemical, and the coagulated water transmitted through the screen 2 is sent to the wet coating booth via the pipe 12 by the pump 12P.

また、循環水槽1内の浮上、凝集フロックを含む水が取水ポンプ3で取水され、配管13を経てスラッジ回収装置4に送給される。スラッジ回収装置4で、凝集フロックのスラッジが固液分離され、回収されたスラッジは、回収スラッジ貯槽5に貯留される。一方、分離された処理水は、配管14を経て循環水槽1に戻される。   Further, water containing floating and flocculated flocs in the circulating water tank 1 is taken in by the water intake pump 3 and sent to the sludge collection device 4 via the pipe 13. The sludge of the flocculated floc is separated into solid and liquid by the sludge collecting device 4, and the collected sludge is stored in the collected sludge storage tank 5. On the other hand, the separated treated water is returned to the circulating water tank 1 via the pipe 14.

この処理装置では、薬注ポンプ15Pを有する配管15よりフェノール系樹脂溶液が、循環水槽1内の循環水に添加される。そして、薬注ポンプ17Pを有する配管17よりカチオン系ポリマーが、循環水槽1内の循環水に添加される。また、高分子凝集剤は、配管16より取水ポンプ3の薬注口より注入される。   In this processing apparatus, a phenolic resin solution is added to the circulating water in the circulating water tank 1 from a pipe 15 having a chemical injection pump 15P. Then, the cationic polymer is added to the circulating water in the circulating water tank 1 from the pipe 17 having the chemical injection pump 17P. The polymer flocculant is injected from the pipe 16 through the chemical inlet of the water intake pump 3.

循環水槽1内には槽内の循環水の懸濁物質濃度を測定するSS計6が水深の中間からやや上方の位置に設けられており、SS計6の測定値は、制御盤7に入力される。この制御盤7は入力されたSS計6の測定値に基づいて、薬注ポンプ15P,17PのON/OFF信号が制御される。   In the circulating water tank 1, an SS meter 6 for measuring the concentration of suspended solids in the circulating water in the tank is provided at a position slightly above the middle of the water depth, and the measured value of the SS meter 6 is input to the control panel 7. Is done. The control panel 7 controls ON / OFF signals of the chemical injection pumps 15P and 17P based on the input measurement values of the SS meter 6.

本実施例では、高分子凝集剤は有効成分量として0.5質量%対余剰塗料で定量添加とし、フェノール系樹脂のアルカリ溶液とカチオン系ポリマーの添加を下記の制御基準でON・OFF制御した。
SS計6の測定値が200mg/L以上の時:ON
SS計6の測定値が100mg/L以下の時:OFF
即ち、循環水槽1内の懸濁物質濃度の上昇で懸濁物質濃度が200mg/L以上になったときに薬注ポンプ15P,17PをONとして薬注を開始し、薬注により循環水の懸濁物質濃度が低下し、100mg/L以下となったときに薬注ポンプ15P,17PをOFFとして薬注を停止する。
薬注ON時は、フェノール系樹脂溶液を有効成分量として10mg/L、カチオン系ポリマーを有効成分量として2.0mg/L添加することとした。
In this example, the polymer coagulant was added in an amount of 0.5% by mass as an active ingredient in a surplus paint, and the addition of the alkaline solution of the phenolic resin and the cationic polymer was ON / OFF controlled according to the following control criteria. .
When the SS total 6 is 200mg / L or more: ON
When the measured value of SS meter 6 is 100 mg / L or less: OFF
That is, when the concentration of the suspended substance in the circulating water tank 1 rises and the concentration of the suspended substance becomes 200 mg / L or more, the chemical injection pumps 15P and 17P are turned ON to start the chemical injection, and the suspension of the circulating water is started by the chemical injection. When the concentration of the suspended solids drops and becomes 100 mg / L or less, the chemical injection pumps 15P and 17P are turned off to stop the chemical injection.
At the time of chemical injection ON, the phenolic resin solution was added as an active ingredient in an amount of 10 mg / L, and the cationic polymer was added as an active ingredient in an amount of 2.0 mg / L.

まず、運転開始時は、フェノール系樹脂溶液とカチオン系ポリマーについて薬注制御を行わず、フェノール系樹脂溶液を有効成分量として5.0mg/L、カチオン系ポリマーを有効成分量として1.0mg/Lで定量注入し、高分子凝集剤を有効成分量として0.5質量%対余剰塗料で定量添加とした。この時、図2の破線に示すように、塗料の捨て吹きや廃棄で不定期的に循環水の塗料負荷が急激に上昇するが、薬注制御を行っていなくても、高分子凝集剤の添加で懸濁物質濃度は徐々に低下してゆく。ただし、この懸濁物質濃度の低下は非常になだらかである。   First, at the start of the operation, the chemical injection control was not performed for the phenol-based resin solution and the cationic polymer, and the phenol-based resin solution was 5.0 mg / L as the active ingredient and the cationic polymer was 1.0 mg / L as the active ingredient. L, and the polymer coagulant was added in an amount of 0.5% by mass as an active ingredient with a surplus paint. At this time, as shown by the broken line in FIG. 2, the paint load of the circulating water suddenly rises irregularly due to the spraying and discarding of the paint. With the addition, the concentration of the suspended substance gradually decreases. However, this drop in suspended solids concentration is very gentle.

薬注制御なしの処理後、高分子凝集剤の薬注はそのままで、フェノール系樹脂溶液とカチオン系ポリマーについて、前述のON・OFFによる薬注制御を開始したところ、図2の実線に示すように、循環水の懸濁物質濃度の上昇で薬注ON、懸濁物質濃度の低下で薬注OFFとすることで、上昇した循環水の懸濁物質濃度は速やかに低下するようになった。
即ち、懸濁物質濃度が200mg/L以上になるとフェノール系樹脂溶液とカチオン系ポリマーの薬注が開始され、これらの薬剤と循環水中の塗料とが反応して浮上するため、循環水槽1内の循環水の懸濁物質濃度は速やかに低下する。懸濁物質濃度が100mg/L以下となった場合には、薬注を停止するため、薬剤の無駄を省くことができる。
このように、本発明によれば、必要最低限の薬注量で効果的な処理を行えることが分かる。なお、単位時間当たりの循環水処理薬剤コストは、ON・OFF制御を行うことで、制御を行わない場合の約0.8倍に削減することができた。
After the treatment without the chemical injection control, the chemical injection of the phenolic resin solution and the cationic polymer was started by the above ON / OFF for the phenolic resin solution and the cationic polymer while the chemical injection of the polymer flocculant was left as shown in the solid line of FIG. In addition, by turning the chemical injection ON when the concentration of the suspended substance in the circulating water is increased, and by turning OFF the chemical injection when the concentration of the suspended substance is decreased, the increased concentration of the suspended substance in the circulated water is immediately reduced.
That is, when the concentration of the suspended substance becomes 200 mg / L or more, chemical injection of the phenolic resin solution and the cationic polymer is started, and these chemicals react with the paint in the circulating water to float up. The concentration of suspended solids in the circulating water drops quickly. When the suspended substance concentration becomes 100 mg / L or less, the chemical injection is stopped, so that waste of the chemical can be omitted.
As described above, according to the present invention, it can be seen that effective processing can be performed with the minimum necessary chemical injection amount. Note that the circulating water treatment chemical cost per unit time could be reduced to about 0.8 times by performing ON / OFF control as compared with the case where control was not performed.

1 循環水槽
2 スクリーン
3 取水ポンプ
4 スラッジ回収装置
5 回収スラッジ貯槽
6 SS計
7 制御盤
DESCRIPTION OF SYMBOLS 1 Circulating water tank 2 Screen 3 Intake pump 4 Sludge collection device 5 Collection tank for collected sludge 6 SS meter 7 Control panel

Claims (2)

湿式塗装ブース循環水中の塗料の不粘着化、凝集ないしは浮上のための処理薬剤の該循環水への薬注制御方法であって、
前記処理薬剤が、フェノール系樹脂および有機凝結剤、或いはフェノール系樹脂、有機凝結剤および高分子凝集剤であり、
前記循環水の濁度を測定し、該濁度の測定値が予め設定した所定値A以上となったときに前記処理薬剤の添加を開始し、前記濁度の測定値が予め設定した所定値B以下となったときに前記処理薬剤の添加を停止することを特徴とする湿式塗装ブース循環水処理薬剤の薬注制御方法。
A wet coating booth is a method for controlling the chemical injection into the circulating water of a treatment agent for preventing tackiness, agglomeration or floating of the paint in the circulating water,
The treatment agent is a phenolic resin and an organic coagulant, or a phenolic resin, an organic coagulant and a polymer flocculant,
The turbidity of the circulating water is measured, and when the measured value of the turbidity is equal to or greater than a predetermined value A, the addition of the treatment agent is started, and the measured value of the turbidity is a predetermined value. B. A method for controlling chemical injection of a treatment agent for circulating water in a wet coating booth , wherein the addition of the treatment agent is stopped when the value becomes B or less .
湿式塗装ブース循環水中の塗料の不粘着化、凝集ないしは浮上のための処理薬剤の該循環水への薬注制御装置であって、該循環水の濁度を測定する濁度計と、該濁度計の測定値が入力され、該測定値に基づいて、該循環水への該処理薬剤の添加を制御する制御手段とを有し、
前記処理薬剤が、フェノール系樹脂および有機凝結剤、或いはフェノール系樹脂、有機凝結剤および高分子凝集剤であり、
前記制御手段は、前記濁度計の測定値が予め設定した所定値A以上となったときに、前記処理薬剤の添加を開始する信号を出力し、前記濁度計の測定値が予め設定した所定値B以下となったときに前記処理薬剤の添加を停止する信号を出力することを特徴とする湿式塗装ブース循環水処理薬剤の薬注制御装置。
A wet coating booth is a device for controlling the injection of a treatment agent for preventing tackiness, agglomeration or floating of paint in circulating water into the circulating water, wherein the turbidity meter measures turbidity of the circulating water; is inputted measured values in degrees meter, have a control means on the basis of the measured value to control the addition of the treatment agent to the circulating water,
The treatment agent is a phenolic resin and an organic coagulant, or a phenolic resin, an organic coagulant and a polymer flocculant,
The control means outputs a signal for starting the addition of the treatment agent when the measured value of the turbidity meter is equal to or more than a predetermined value A set in advance, and the measured value of the turbidity meter is set in advance. A chemical injection control device for a wet coating booth circulating water treatment chemical, which outputs a signal for stopping the addition of the treatment chemical when the value falls below a predetermined value B.
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