JP6557672B2 - 伝熱指向性uhmwpe製品の調製プロセスとこれより取得される製品 - Google Patents

伝熱指向性uhmwpe製品の調製プロセスとこれより取得される製品 Download PDF

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Publication number
JP6557672B2
JP6557672B2 JP2016554444A JP2016554444A JP6557672B2 JP 6557672 B2 JP6557672 B2 JP 6557672B2 JP 2016554444 A JP2016554444 A JP 2016554444A JP 2016554444 A JP2016554444 A JP 2016554444A JP 6557672 B2 JP6557672 B2 JP 6557672B2
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Prior art keywords
uhmwpe
range
thermal conductivity
product
directional
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JP2016554444A
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Japanese (ja)
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JP2017506696A (ja
JP2017506696A5 (enExample
Inventor
ベハリ マツール,アジット
ベハリ マツール,アジット
ヴィジェイ カダム,シヴァジ
ヴィジェイ カダム,シヴァジ
スリニヴァーサ ラオ ガンダム,サチャ
スリニヴァーサ ラオ ガンダム,サチャ
サンカー サトパシー,ウマ
サンカー サトパシー,ウマ
レンガナス サルマ,クリシュナ
レンガナス サルマ,クリシュナ
フルジブハイ パテル,ナヌブハイ
フルジブハイ パテル,ナヌブハイ
マニラル メタ,ガウラン
マニラル メタ,ガウラン
マヘシュブハイ アミン,ヨギーニ
マヘシュブハイ アミン,ヨギーニ
クマル プナムシャンド シャー,アミット
クマル プナムシャンド シャー,アミット
パテル,ヴィラルクマル
ヴィル ジャスラ,ラクシュ
ヴィル ジャスラ,ラクシュ
クマル シュクラ,デヴェッシュ
クマル シュクラ,デヴェッシュ
インドラヴァダン パレク,アシシュクマル
インドラヴァダン パレク,アシシュクマル
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Reliance Industries Ltd
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Reliance Industries Ltd
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Priority claimed from IN701MU2014 external-priority patent/IN2014MU00701A/en
Publication of JP2017506696A publication Critical patent/JP2017506696A/ja
Publication of JP2017506696A5 publication Critical patent/JP2017506696A5/ja
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/003—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/22—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
    • B29C43/24—Calendering
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/005—Shaping by stretching, e.g. drawing through a die; Apparatus therefor characterised by the choice of materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/18—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets by squeezing between surfaces, e.g. rollers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B29C43/14—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles in several steps
    • B29C43/146—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles in several steps for making multilayered articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/04—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique
    • B29C55/06—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique parallel with the direction of feed
    • B29C55/065—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique parallel with the direction of feed in several stretching steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04—Polymers of ethylene
    • B29K2023/06—PE, i.e. polyethylene
    • B29K2023/0658—PE, i.e. polyethylene characterised by its molecular weight
    • B29K2023/0683—UHMWPE, i.e. ultra high molecular weight polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
    • B29K2105/0047—Agents changing thermal characteristics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16—Fillers
    • B29K2105/162—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16—Fillers
    • B29K2105/165—Hollow fillers, e.g. microballoons or expanded particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16—Fillers
    • B29K2105/165—Hollow fillers, e.g. microballoons or expanded particles
    • B29K2105/167—Nanotubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0012—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular thermal properties
    • B29K2995/0013—Conductive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00—Flat articles, e.g. films or sheets
    • B29L2007/008—Wide strips, e.g. films, webs
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/01—High molecular weight, e.g. >800,000 Da.
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18—Bulk density
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/26—Use as polymer for film forming
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/12—Applications used for fibers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/068—Ultra high molecular weight polyethylene

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
JP2016554444A 2014-02-27 2015-02-27 伝熱指向性uhmwpe製品の調製プロセスとこれより取得される製品 Active JP6557672B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
IN701/MUM/2014 2014-02-27
IN3106MU2014 2014-09-29
IN3106/MUM/2014 2014-09-29
IN701MU2014 IN2014MU00701A (enExample) 2014-02-27 2015-02-27
PCT/IB2015/051459 WO2015128843A2 (en) 2014-02-27 2015-02-27 Process for preparing thermally conductive oriented uhmwpe products and products obtained therefrom

Publications (3)

Publication Number Publication Date
JP2017506696A JP2017506696A (ja) 2017-03-09
JP2017506696A5 JP2017506696A5 (enExample) 2019-05-30
JP6557672B2 true JP6557672B2 (ja) 2019-08-07

Family

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Family Applications (1)

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JP2016554444A Active JP6557672B2 (ja) 2014-02-27 2015-02-27 伝熱指向性uhmwpe製品の調製プロセスとこれより取得される製品

Country Status (6)

Country Link
US (1) US10105880B2 (enExample)
EP (1) EP3110856B1 (enExample)
JP (1) JP6557672B2 (enExample)
KR (1) KR20160127033A (enExample)
CN (1) CN106029706A (enExample)
WO (1) WO2015128843A2 (enExample)

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WO2017136196A1 (en) 2016-02-01 2017-08-10 Cabot Corporation Thermally conductive polymer compositions containing carbon black
US10193030B2 (en) * 2016-08-08 2019-01-29 General Electric Company Composite materials having red emitting phosphors
US20190023819A1 (en) * 2017-07-21 2019-01-24 Celanese Sales Germany Gmbh Conductive Ultrahigh Molecular Weight Polyethylene Compositions
US11718730B2 (en) * 2017-12-14 2023-08-08 Temple University—Of the Commonwealth System of Higher Education Polymer nanocomposites and methods of making the same
JP2019131705A (ja) * 2018-01-31 2019-08-08 帝人株式会社 絶縁熱伝導シートおよびその製造方法
CN109206712A (zh) * 2018-08-28 2019-01-15 合肥卓汇新材料科技有限公司 一种超高分子量聚乙烯导电复合材料的加工方法
WO2020201502A1 (en) 2019-04-05 2020-10-08 Technische Universiteit Eindhoven Composite film comprising ultra-drawn uhmwpe and one or more (co-) additives
KR20230093281A (ko) * 2020-10-23 2023-06-27 듀폰 일렉트로닉스, 인크. 다기능 시트 및 라미네이트, 물품, 및 방법
JP2023132843A (ja) * 2022-03-11 2023-09-22 三井化学株式会社 放熱部材複合体
US20240026099A1 (en) * 2022-07-19 2024-01-25 Meta Platforms Technologies, Llc Ultrahigh molecular weight polyethylene thin films formed by gel casting

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JPS60155428A (ja) * 1984-01-25 1985-08-15 Nippon Petrochem Co Ltd 積層シ−トもしくは積層フイルムの製造方法
JPH07673B2 (ja) * 1986-08-07 1995-01-11 日本石油株式会社 高強度・高弾性率ポリエチレン材料の製造方法
JPH11179798A (ja) * 1997-12-19 1999-07-06 Sekisui Chem Co Ltd ポリオレフィン樹脂シートの製造方法
JP2002030212A (ja) * 2000-06-29 2002-01-31 Three M Innovative Properties Co 熱伝導性シート
US7740779B2 (en) * 2007-04-13 2010-06-22 Bae Systems Tensylon H.P.M., Inc Multiple calender process for forming non-fibrous high modulus ultra high molecular weight polyethylene tape
US7854870B2 (en) * 2008-04-01 2010-12-21 BAE Systems Tensy Lon H.P.M., Inc. Method and apparatus for the production of high tenacity polyolefin sheet
US8206810B1 (en) * 2007-06-25 2012-06-26 Bae Systems Tensylon H. P. M., Inc. High modulus ultra high molecular weight polyethylene tape
EP2014445A1 (en) * 2007-07-09 2009-01-14 Teijin Aramid B.V. Polyethylene film with high tensile strength and high tensile energy to break
JP5313747B2 (ja) * 2009-04-09 2013-10-09 帝人株式会社 ポリオレフィン成形体の製造方法
US8697220B2 (en) 2009-08-11 2014-04-15 Honeywell International, Inc. High strength tape articles from ultra-high molecular weight polyethylene
US8299159B2 (en) * 2009-08-17 2012-10-30 Laird Technologies, Inc. Highly thermally-conductive moldable thermoplastic composites and compositions
US8658263B2 (en) * 2010-04-30 2014-02-25 Mitsui Chemicals, Inc. Shape-retaining film, process for producing same, laminate for packaging, packaging material and process for producing same, shape-retaining fiber, and anisotropic heat-conductive film
BR112014008658A2 (pt) 2011-10-10 2017-04-25 Reliance Ind Ltd processo para síntese de polímeros de polietileno
WO2013118140A2 (en) 2012-02-08 2013-08-15 Reliance Industries Ltd Immobilization of single site catalyst on inorganic oxide support for preparation of uhmwpe
US8937139B2 (en) * 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same

Also Published As

Publication number Publication date
JP2017506696A (ja) 2017-03-09
WO2015128843A3 (en) 2015-12-10
CN106029706A (zh) 2016-10-12
EP3110856A4 (en) 2017-11-01
EP3110856A2 (en) 2017-01-04
US10105880B2 (en) 2018-10-23
KR20160127033A (ko) 2016-11-02
WO2015128843A2 (en) 2015-09-03
US20160368182A1 (en) 2016-12-22
EP3110856B1 (en) 2025-08-13

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