JP6506755B2 - 連続油相を含む発泡性パーソナルケア組成物 - Google Patents
連続油相を含む発泡性パーソナルケア組成物 Download PDFInfo
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- JP6506755B2 JP6506755B2 JP2016530428A JP2016530428A JP6506755B2 JP 6506755 B2 JP6506755 B2 JP 6506755B2 JP 2016530428 A JP2016530428 A JP 2016530428A JP 2016530428 A JP2016530428 A JP 2016530428A JP 6506755 B2 JP6506755 B2 JP 6506755B2
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- SFFVATKALSIZGN-UHFFFAOYSA-N hexadecan-7-ol Chemical compound CCCCCCCCCC(O)CCCCCC SFFVATKALSIZGN-UHFFFAOYSA-N 0.000 description 1
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
- DWMMZQMXUWUJME-UHFFFAOYSA-N hexadecyl octanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCC DWMMZQMXUWUJME-UHFFFAOYSA-N 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000000411 inducer Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 1
- 229940093629 isopropyl isostearate Drugs 0.000 description 1
- 229940074928 isopropyl myristate Drugs 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940075495 isopropyl palmitate Drugs 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 229940105132 myristate Drugs 0.000 description 1
- 229940078812 myristyl myristate Drugs 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004533 oil dispersion Substances 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 229940101267 panthenol Drugs 0.000 description 1
- 235000020957 pantothenol Nutrition 0.000 description 1
- 239000011619 pantothenol Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 229940067631 phospholipid Drugs 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229940079988 potassium cocoyl glycinate Drugs 0.000 description 1
- 229940095106 ppg-3 benzyl ether myristate Drugs 0.000 description 1
- 229940116987 ppg-3 myristyl ether Drugs 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 230000035910 sensory benefits Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 1
- YVZQQYAFKGUHJV-UHFFFAOYSA-M sodium;2-(octadecanoylamino)acetate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)NCC([O-])=O YVZQQYAFKGUHJV-UHFFFAOYSA-M 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 229940104261 taurate Drugs 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- BORJONZPSTVSFP-UHFFFAOYSA-N tetradecyl 2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)O BORJONZPSTVSFP-UHFFFAOYSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229920000428 triblock copolymer Polymers 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/0275—Containing agglomerated particulates
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q9/00—Preparations for removing hair or for aiding hair removal
- A61Q9/02—Shaving preparations
Description
Zabottoらの特許文献1は、油相、乳化剤及び微粒子水溶性ポリマー研磨微粒子を含有する、無水皮膚クレンジング組成物について記載している。
i.35から90重量%の、好ましくは40から80重量%のキャリアオイル、
ii.10から65重量%の、好ましくは20から60重量%の固体クレンジング界面活性剤、及び
iii.5重量%までの、好ましくは4重量%までの、より好ましくは3重量%までの水
を含む組成物が提供される。
RO(CH2CH2O)nSO3M
を有するものがあり、式中、Rは、8から22個の炭素、好ましくは8から18個の炭素、より好ましくは12から18個の炭素を有するアルキル又はアルケニルであり;nは、1.0を超える、好ましくは2から3の平均値を有し;及びMは、溶解性カチオン、例えばナトリウム、カリウム、アンモニウム又は置換アンモニウムである。アンモニウムラウレル(laurel)エーテルサルフェート及びナトリウムラウレル(laurel)エーテルサルフェートが好ましい。アニオン性界面活性剤はまた、アルキルスルホスクシネート(モノアルキルスルホスクシネート及びジアルキルスルホスクシネート、例えばC8−C22スルホスクシネートを含む);アルキルタウレート及びアシルタウレート、アルキルサルコシネート及びアシルサルコシネート、スルホアセテート、C8−C22アルキルホスフェート及びホスフェート、アルキルホスフェートエステル及びアルコキシアルキルホスフェートエステル、アシルラクテート、C8−C22モノアルキルスクシネート及びマレエート、スルホアセテート、アシルイセチオネート並びにアシルグリシネートなどでもよい。
R1O2CCH2(SO3M)CO2M
を有するモノアルキルスルホスクシネート;及び式:
R1CONHCH2CH2O2CCH2CH(SO3M)CO2M
のアミド−MEAスルホスクシネート
(このような式中、R1はC8−C22アルキルの範囲に及び、Mは上記のような溶解性カチオンである。);又は式:
RCONH(CH2)CH(CH3)(SO3M)CO2M
のアミド−MIPAスルホスクシネート(式中、R及びMは、上記の通りである。)
であってよい。
R−O−(CH2CH2O)m−C(O)−CH2CH(SO3M)CO2M)
(式中、m=1−20;並びにR及びMは上記の通りである。)
も含まれる。
R2CONR3CH2CH2SO3M
によって識別され、式中、R2は上記の通りであり、R3はC1−C4アルキルの範囲に及び、Mは溶解性カチオンである。
R2(CH2CH2O)pM
式中、R2は上記の通りであり、pは0から20であり、Mは溶解性カチオンである。使用できるまた別のカルボキシレートは、アミドアルキルポリペプチドであり、例えばセピックから商標Monteine(登録商標)で入手可能である。
R2CONHCH2COOM
によって表され、式中、R2及びMは、上記の通りである。好適なアシルグリシネートとしては、例えばナトリウムココイルグリシネート、ナトリウムステアロイルグリシネート、ナトリウムラウロイルグリシネート、ナトリウムラウロイルサルコシネート及びカリウムココイルグリシネートが挙げられる。
[実施例1−6]
この一連の実施例によって、分散した界面活性剤粒子を含有する油連続性組成物の安定性に対する、固体界面活性剤粒子の凝集体の効果を示す。
油連続性クレンジング組成物を、表2に記載した製剤に従って、粒子凝集の誘発剤としての異なる油、各種の水含有成分を使用して調製した。
Claims (12)
- 少なくとも1つのキャリアオイルを含む連続油相と分散した固体クレンジング界面活性剤の凝集粒子とを含む、発泡性流体パーソナルケア組成物であって:
i.前記組成物の総重量に基づいて、35から90重量%のキャリアオイル;
ii.前記組成物の総重量に基づいて、10から65重量%の固体クレンジング界面活性剤;及び
iii.前記組成物の総重量に基づいて、5重量%までの水
を含み、
前記固体クレンジング界面活性剤が0.5から200μmの範囲内の径の粒子の形態で存在し、
前記粒子の少なくとも50%が200μm未満の径であり、前記粒子の少なくとも30%が150μm未満の径である、組成物。 - 水が前記組成物の総重量に基づいて、0.2から4重量%の量で存在する、請求項1に
記載の組成物。 - 前記キャリアオイルが、炭化水素油、エーテル油、エステル油、脂肪アルコール及びシ
リコーン油から選択される1つ以上の油を含む、請求項1に記載の組成物。 - 前記キャリアオイルの90から100重量%が非揮発性炭化水素、トリグリセリド及び
シリコーン油から選択される1つ以上の油である、請求項1に記載の組成物。 - 前記キャリアオイルが少なくとも95重量%の非揮発性油を含む、請求項1に記載の組
成物。 - 前記キャリアオイルが前記組成物の総重量に基づいて、40から80重量%の量で存在
する、請求項1に記載の組成物。 - 前記固体界面活性剤が前記組成物の総重量に基づいて、35から60重量%の量で存在
する、請求項1に記載の組成物。 - 0.01rps及び23℃にて、300から50,000kgm−1秒−1の粘度を有
する、請求項1に記載の組成物。 - 水が前記組成物の総重量に基づいて、0.5から3重量%の量で存在する、請求項1に
記載の組成物。 - 前記固体界面活性剤を前記キャリアオイルによって分散させて、剪断下で混合し、
水を添加して、前記凝集粒子を形成する、請求項1に記載の組成物を調製する方
法。 - 前記固体界面活性剤及びキャリアオイルを20から25℃の範囲の温度にて、剪断下で
混合する、請求項10に記載の方法。 - 界面活性剤水溶液をミクロン径の液滴としてスプレー又は噴霧して、水を蒸発させることによって前記固体クレンジング界面活性剤の凝集粒子を調製し、当該凝集粒子をキャリアオイルによって分散させることを含む、請求項1に記載の組成物を調製する方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US201361861001P | 2013-08-01 | 2013-08-01 | |
US61/861,001 | 2013-08-01 | ||
PCT/EP2014/065707 WO2015014667A1 (en) | 2013-08-01 | 2014-07-22 | Foamable personal care composition comprising a continuous oil phase |
Publications (3)
Publication Number | Publication Date |
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JP2016528222A JP2016528222A (ja) | 2016-09-15 |
JP2016528222A5 JP2016528222A5 (ja) | 2018-10-25 |
JP6506755B2 true JP6506755B2 (ja) | 2019-04-24 |
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EP (1) | EP3027169B1 (ja) |
JP (1) | JP6506755B2 (ja) |
CN (1) | CN105636574B (ja) |
AR (1) | AR097123A1 (ja) |
BR (1) | BR112015032668B1 (ja) |
CA (1) | CA2916340C (ja) |
EA (1) | EA029628B1 (ja) |
ES (1) | ES2627493T3 (ja) |
MX (1) | MX352333B (ja) |
WO (1) | WO2015014667A1 (ja) |
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EP3322399B1 (en) * | 2015-07-16 | 2018-10-31 | Unilever Plc. | In-situ process for making a small particle narrow distribution fatty acyl isethionate in oil composition |
GB2541930A (en) | 2015-09-04 | 2017-03-08 | Cosmetic Warriors Ltd | Composition |
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GB1500719A (en) * | 1974-06-14 | 1978-02-08 | Procter & Gamble Ltd | Foaming and conditioning detergent composition |
US4294855A (en) * | 1975-11-26 | 1981-10-13 | Desoto, Inc. | Emollient and/or dyed prilled urea bath bead composition |
JP2000191510A (ja) * | 1998-12-28 | 2000-07-11 | Kao Corp | 皮膚洗浄剤組成物 |
JP2008214321A (ja) * | 2007-03-07 | 2008-09-18 | Kose Corp | 油性皮膚洗浄料 |
JP5033567B2 (ja) * | 2007-10-01 | 2012-09-26 | 株式会社コーセー | オイルクレンジング料 |
JP2010195694A (ja) * | 2009-02-24 | 2010-09-09 | Miyoshi Kasei Inc | 粉体分散物とこの粉体分散物を含有する化粧料 |
-
2014
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- 2014-07-22 EP EP14747872.1A patent/EP3027169B1/en active Active
- 2014-07-22 CA CA2916340A patent/CA2916340C/en active Active
- 2014-07-22 CN CN201480043465.3A patent/CN105636574B/zh active Active
- 2014-07-22 WO PCT/EP2014/065707 patent/WO2015014667A1/en active Application Filing
- 2014-07-22 EA EA201592197A patent/EA029628B1/ru not_active IP Right Cessation
- 2014-07-22 JP JP2016530428A patent/JP6506755B2/ja active Active
- 2014-07-22 BR BR112015032668-4A patent/BR112015032668B1/pt active IP Right Grant
- 2014-07-22 ES ES14747872.1T patent/ES2627493T3/es active Active
- 2014-07-30 AR ARP140102838A patent/AR097123A1/es unknown
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Publication number | Publication date |
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CN105636574B (zh) | 2019-02-15 |
ES2627493T3 (es) | 2017-07-28 |
EA201592197A1 (ru) | 2016-06-30 |
EA029628B1 (ru) | 2018-04-30 |
EP3027169B1 (en) | 2017-03-22 |
JP2016528222A (ja) | 2016-09-15 |
BR112015032668A8 (pt) | 2020-02-04 |
BR112015032668A2 (pt) | 2017-07-25 |
MX352333B (es) | 2017-11-21 |
BR112015032668B1 (pt) | 2020-07-21 |
MX2016001297A (es) | 2016-04-07 |
CN105636574A (zh) | 2016-06-01 |
CA2916340C (en) | 2021-11-23 |
EP3027169A1 (en) | 2016-06-08 |
CA2916340A1 (en) | 2015-02-05 |
AR097123A1 (es) | 2016-02-17 |
WO2015014667A1 (en) | 2015-02-05 |
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