JP6481998B2 - Supported catalyst - Google Patents
Supported catalyst Download PDFInfo
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- JP6481998B2 JP6481998B2 JP2015039663A JP2015039663A JP6481998B2 JP 6481998 B2 JP6481998 B2 JP 6481998B2 JP 2015039663 A JP2015039663 A JP 2015039663A JP 2015039663 A JP2015039663 A JP 2015039663A JP 6481998 B2 JP6481998 B2 JP 6481998B2
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- Prior art keywords
- supported catalyst
- protective material
- polymer protective
- carbon
- nanoparticles
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims description 54
- 239000002245 particle Substances 0.000 claims description 37
- 239000000463 material Substances 0.000 claims description 33
- 230000001681 protective effect Effects 0.000 claims description 32
- 229920000642 polymer Polymers 0.000 claims description 31
- OYJSZRRJQJAOFK-UHFFFAOYSA-N palladium ruthenium Chemical compound [Ru].[Pd] OYJSZRRJQJAOFK-UHFFFAOYSA-N 0.000 claims description 30
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 29
- 239000002105 nanoparticle Substances 0.000 claims description 29
- 229910000929 Ru alloy Inorganic materials 0.000 claims description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 10
- 239000006104 solid solution Substances 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000919 ceramic Substances 0.000 claims description 7
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 7
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 241000003832 Lantana Species 0.000 claims description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 3
- 239000006230 acetylene black Substances 0.000 claims description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 3
- 239000000292 calcium oxide Substances 0.000 claims description 3
- 235000012255 calcium oxide Nutrition 0.000 claims description 3
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims description 3
- 239000002041 carbon nanotube Substances 0.000 claims description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 3
- 229910052878 cordierite Inorganic materials 0.000 claims description 3
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 3
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 3
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 3
- 229960001545 hydrotalcite Drugs 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- 229910052863 mullite Inorganic materials 0.000 claims description 3
- 239000002116 nanohorn Substances 0.000 claims description 3
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 3
- -1 perovskite Chemical compound 0.000 claims description 3
- IYDGMDWEHDFVQI-UHFFFAOYSA-N phosphoric acid;trioxotungsten Chemical compound O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.OP(O)(O)=O IYDGMDWEHDFVQI-UHFFFAOYSA-N 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 3
- 229910001887 tin oxide Inorganic materials 0.000 claims description 3
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 3
- 229910052586 apatite Inorganic materials 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 description 24
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 19
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- 238000002441 X-ray diffraction Methods 0.000 description 7
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- 101150003085 Pdcl gene Proteins 0.000 description 3
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- 238000009835 boiling Methods 0.000 description 3
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- 239000003595 mist Substances 0.000 description 3
- 229910052763 palladium Inorganic materials 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- 238000001350 scanning transmission electron microscopy Methods 0.000 description 3
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- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
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- 238000003321 atomic absorption spectrophotometry Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000004993 emission spectroscopy Methods 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N ethylene glycol monomethyl ether acetate Natural products COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229910002093 potassium tetrachloropalladate(II) Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- BIXNGBXQRRXPLM-UHFFFAOYSA-K ruthenium(3+);trichloride;hydrate Chemical compound O.Cl[Ru](Cl)Cl BIXNGBXQRRXPLM-UHFFFAOYSA-K 0.000 description 2
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- 239000007809 chemical reaction catalyst Substances 0.000 description 1
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- 229940117389 dichlorobenzene Drugs 0.000 description 1
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- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
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- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
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- 238000011068 loading method Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
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- 239000003921 oil Substances 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- MUJIDPITZJWBSW-UHFFFAOYSA-N palladium(2+) Chemical compound [Pd+2] MUJIDPITZJWBSW-UHFFFAOYSA-N 0.000 description 1
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- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Catalysts (AREA)
- Inert Electrodes (AREA)
Description
本発明は、高分子保護材フリーの担持触媒に関する。 The present invention relates to a supported catalyst free of a polymer protective material.
従来、化学反応触媒又は燃料電池などでは、カーボン系の担体にナノ粒子を担持した不均一系触媒が用いられている。また、ボイラー又は排ガスの浄化などでは、セラミックス系の担体にナノ粒子を担持した不均一系触媒が用いられている。不均一系触媒に用いるナノ粒子としてPd−Ru合金ナノ粒子が開示されている(例えば、特許文献1、非特許文献1を参照。)。非特許文献1では、Pd−Ru合金ナノ粒子を担体に担持して不均一系触媒として使用する場合、ポリビニルピロリドンなどの高分子保護材を用いてナノ粒子を合成・精製した後に、得られたナノ粒子を担体に担持している。 Conventionally, in a chemical reaction catalyst or a fuel cell, a heterogeneous catalyst in which nanoparticles are supported on a carbon-based carrier has been used. In addition, in the purification of boilers or exhaust gases, heterogeneous catalysts in which nanoparticles are supported on a ceramic carrier are used. Pd—Ru alloy nanoparticles are disclosed as nanoparticles used for heterogeneous catalysts (see, for example, Patent Document 1 and Non-Patent Document 1). In Non-Patent Document 1, when Pd—Ru alloy nanoparticles were supported on a carrier and used as a heterogeneous catalyst, the nanoparticles were synthesized and purified using a polymer protective material such as polyvinylpyrrolidone. Nanoparticles are supported on a carrier.
しかし、ナノ粒子の合成時に用いた高分子保護材が触媒中に残っていると、触媒の効果が十分に発揮されない場合がある。高分子保護材の除去を目的としてナノ粒子の精製を繰り返すと、精製回数が増加するにつれて得られるナノ粒子の収量が少なくなるという問題である。 However, if the polymer protective material used in the synthesis of the nanoparticles remains in the catalyst, the effect of the catalyst may not be sufficiently exhibited. If the purification of the nanoparticles is repeated for the purpose of removing the polymer protective material, the yield of nanoparticles obtained decreases as the number of purification increases.
本発明の目的は、触媒の性能を低下させる高分子保護材を用いず、触媒の効果を十分に発揮できる担持触媒を提供することである。 An object of the present invention is to provide a supported catalyst that can sufficiently exhibit the effect of the catalyst without using a polymer protective material that lowers the performance of the catalyst.
本発明に係る担持触媒は、ナノ粒子としてPd−Ru合金粒子が担持体に担持された担持触媒において、前記Pd−Ru合金粒子は、固溶体を形成しており、前記担持触媒の外表面に高分子保護材が存在しないことを特徴とする。Pd−Ru合金粒子が固溶体を形成していることで触媒活性をより高めることができる。 The supported catalyst according to the present invention is a supported catalyst in which Pd—Ru alloy particles are supported as a nanoparticle on a support. The Pd—Ru alloy particles form a solid solution, and a high concentration is formed on the outer surface of the supported catalyst. It is characterized by the absence of molecular protective material. Since the Pd—Ru alloy particles form a solid solution, the catalytic activity can be further increased.
本発明に係る担持触媒は、高分子保護材を含有しないことが好ましい。触媒活性をより高めることができる。 The supported catalyst according to the present invention preferably contains no polymer protective material. The catalytic activity can be further increased.
本発明に係る担持触媒では、前記ナノ粒子と前記担持体との間に前記高分子保護材が介在しないことが好ましい。触媒活性をより高めることができる。 In the supported catalyst according to the present invention, it is preferable that the polymer protective material is not interposed between the nanoparticles and the support. The catalytic activity can be further increased.
本発明に係る担持触媒では、前記担持体は、カーボン若しくはセラミックスのいずれか一方又は両方である形態を包含する。 In the supported catalyst according to the present invention, the support includes one or both of carbon and ceramics.
本発明に係る担持触媒では、前記担持体は、アルミナ、シリカ、シリカアルミナ、カルシア、マグネシア、チタニア、セリア、ジルコニア、セリアジルコニア、ランタナ、ランタナアルミナ、酸化スズ、酸化タングステン、アルミノシリケート、アルミノホスフェート、ボロシリケート、リンタングステン酸、ヒドロキシアパタイト、ハイドロタルサイト、ペロブスカイト、コージェライト、ムライト、シリコンカーバイド、活性炭、カーボンブラック、アセチレンブラック、カーボンナノチューブ及びカーボンナノホーンの中から選ばれる1種以上である形態を包含する。 In the supported catalyst according to the present invention, the support is alumina, silica, silica alumina, calcia, magnesia, titania, ceria, zirconia, ceria zirconia, lantana, lantana alumina, tin oxide, tungsten oxide, aluminosilicate, aluminophosphate, Includes one or more forms selected from borosilicate, phosphotungstic acid, hydroxyapatite, hydrotalcite, perovskite, cordierite, mullite, silicon carbide, activated carbon, carbon black, acetylene black, carbon nanotube and carbon nanohorn To do.
本発明は、触媒の性能を低下させる高分子保護材を用いず、触媒の効果を十分に発揮できる担持触媒を提供することができる。 The present invention can provide a supported catalyst that can sufficiently exhibit the effect of the catalyst without using a polymer protective material that lowers the performance of the catalyst.
次に本発明について実施形態を示して詳細に説明するが本発明はこれらの記載に限定して解釈されない。本発明の効果を奏する限り、実施形態は種々の変形をしてもよい。 Next, although an embodiment is shown and explained in detail about the present invention, the present invention is limited to these descriptions and is not interpreted. As long as the effect of the present invention is exhibited, the embodiment may be variously modified.
本実施形態に係る担持触媒は、ナノ粒子としてPd−Ru合金粒子が担持体に担持された担持触媒において、担持触媒の外表面に高分子保護材が存在しない。高分子保護材が担持触媒の外表面に存在しないことで、触媒の作用を十分の発揮させることができる。高分子保護材は、例えば、ポリビニルピロリドン(PVP)である。本実施形態に係る担持触媒では、高分子保護材がナノ粒子の外表面に付着していないことが好ましく、高分子保護材がナノ粒子の外表面及び担持体の外表面に付着していないことがより好ましい。 In the supported catalyst according to the present embodiment, in the supported catalyst in which Pd—Ru alloy particles are supported on the support as nanoparticles, the polymer protective material does not exist on the outer surface of the supported catalyst. Since the polymer protective material is not present on the outer surface of the supported catalyst, the function of the catalyst can be sufficiently exerted. The polymer protective material is, for example, polyvinyl pyrrolidone (PVP). In the supported catalyst according to this embodiment, the polymer protective material is preferably not attached to the outer surface of the nanoparticle, and the polymer protective material is not attached to the outer surface of the nanoparticle and the outer surface of the support. Is more preferable.
本実施形態に係る担持触媒では、ナノ粒子と担持体との間に高分子保護材が介在しないことが好ましい。 In the supported catalyst according to the present embodiment, it is preferable that no polymer protective material is interposed between the nanoparticles and the support.
本実施形態に係る担持触媒は、高分子保護材を含有しないことが好ましい。担持触媒が高分子保護材を含有するか否かは、例えば、X線回折パターン(XRDパターン)によって確認できる。例えば高分子保護材がPVPであるとき、室温でλ=CuKαの測定条件で測定したXRDパターンにおいて、10°付近にPVP由来のパターンが確認されないことで、担持触媒が高分子保護材を含有しないことを確認することができる。 The supported catalyst according to this embodiment preferably does not contain a polymer protective material. Whether or not the supported catalyst contains a polymer protective material can be confirmed by, for example, an X-ray diffraction pattern (XRD pattern). For example, when the polymer protective material is PVP, the supported catalyst does not contain the polymer protective material because the PVP-derived pattern is not confirmed at around 10 ° in the XRD pattern measured at room temperature under the measurement condition of λ = CuKα. I can confirm that.
本実施形態に係る担持触媒は、従来の担持触媒の製造方法のように予め合成したナノ粒子を担持体に担持させる方法ではなく、ナノ粒子の合成とナノ粒子の担持体への担持とを同時に行う方法で製造することが好ましい。ナノ粒子の合成とナノ粒子の担持体への担持とを同時に行うことで、従来の製造方法と比較して製造工程を少なくすることができる。本明細書において、ナノ粒子とは、平均粒子径が100nm以下の微細粒子をいう。ナノ粒子の平均粒子径は、透過型電子顕微鏡(TEM)によって得られた粒子像から少なくとも100個以上の粒子の粒子径を計測し、その平均を求めることによって算出した値である。TEMの観察倍率は、例えば、120000倍又は150000倍であることが好ましい。ナノ粒子の平均粒子径の下限は、特に限定されないが、1nm以上であることが好ましい。 The supported catalyst according to the present embodiment is not a method in which nanoparticles synthesized in advance are supported on a support as in the conventional method for producing a supported catalyst, but the synthesis of nanoparticles and the support of nanoparticles on the support are simultaneously performed. It is preferable to manufacture by the method to perform. By simultaneously performing the synthesis of the nanoparticles and the loading of the nanoparticles on the carrier, the number of manufacturing steps can be reduced as compared with the conventional manufacturing method. In this specification, a nanoparticle means the fine particle whose average particle diameter is 100 nm or less. The average particle diameter of the nanoparticles is a value calculated by measuring the particle diameter of at least 100 particles from a particle image obtained by a transmission electron microscope (TEM) and obtaining the average. The observation magnification of TEM is preferably 120,000 times or 150,000 times, for example. Although the minimum of the average particle diameter of a nanoparticle is not specifically limited, It is preferable that it is 1 nm or more.
本実施形態に係る担持触媒の製造方法は、Pd−Ru合金粒子を合成するとともに、Pd−Ru合金粒子を担持体に担持させる工程1を有し、工程1は、担持体と有機溶媒とを含有し、かつ、高分子保護材を含有しない混合物を加熱する工程1aと、Pd化合物、Ru化合物及び純水を含有し、かつ、高分子保護材を含有しない混合物を作製する工程1bと、工程1aの混合物と工程1bの混合物とを混合する工程1cとを有することが好ましい。 The method for producing a supported catalyst according to the present embodiment includes the step 1 of synthesizing Pd—Ru alloy particles and supporting the Pd—Ru alloy particles on the support, and the step 1 includes the support and the organic solvent. Step 1a for heating a mixture containing and not containing a polymer protective material, Step 1b for producing a mixture containing Pd compound, Ru compound and pure water and containing no polymer protective material, and step It is preferable to have the process 1c which mixes the mixture of 1a, and the mixture of the process 1b.
次に、工程1で用いる各物質について説明する。 Next, each substance used in step 1 will be described.
(ナノ粒子の合成原料となる化合物)
Pd−Ru合金粒子の合成原料となる化合物はRu化合物及びPd化合物である。Ru化合物は、例えば、Ru塩化物、Ru窒化物である。Pd化合物は、例えば、Pd塩化物、Pd窒化物である。このうち、Ru化合物及びPd化合物はRu塩化物及びPd塩化物であることが好ましい。担持触媒をより効率的に得ることができる。Ru塩化物は、例えば、塩化ルテニウム(III)n水和物、塩化ルテニウム(IV)n水和物、ルテニウム酸ナトリウムである。Pd塩化物は、例えば、テトラクロロパラジウム酸カリウム(II)、ジニトロジアンミンパラジウム(II)である。
(Compound that is a raw material for the synthesis of nanoparticles)
The compound that is a raw material for synthesizing Pd—Ru alloy particles is a Ru compound and a Pd compound. The Ru compound is, for example, Ru chloride or Ru nitride. The Pd compound is, for example, Pd chloride or Pd nitride. Of these, the Ru compound and the Pd compound are preferably Ru chloride and Pd chloride. A supported catalyst can be obtained more efficiently. Ru chloride is, for example, ruthenium (III) chloride n hydrate, ruthenium (IV) chloride n hydrate, or sodium ruthenate. Pd chloride is, for example, potassium tetrachloropalladate (II) or dinitrodiammine palladium (II).
(担持体)
担持体は、カーボン若しくはセラミックスのいずれか一方又は両方である形態を包含する。セラミックスは、例えば、アルミナ、シリカ、シリカアルミナ、カルシア、マグネシア、チタニア、セリア、ジルコニア、セリアジルコニア、ランタナ、ランタナアルミナ、酸化スズ、酸化タングステン、アルミノシリケート、アルミノホスフェート、ボロシリケート、リンタングステン酸、ヒドロキシアパタイト、ハイドロタルサイト、ペロブスカイト、コージェライト、ムライト又はシリコンカーバイドである。カーボンは、例えば、活性炭、カーボンブラック、アセチレンブラック、カーボンナノチューブ又はカーボンナノホーンである。本実施形態では、これらの担持体の中から1種だけを使用するか、又は2種以上を併用してもよい。2種以上を併用する場合は、セラミックスから2種以上を組合せて用いるか、カーボンから2種以上を組合せて用いるか、又はセラミックスから1種以上及びカーボンから1種以上を組合せて用いてもよい。より好ましくは、アルミナ、シリカ、チタニア、セリア、ジルコニア、活性炭及びカーボンブラックの中から選ばれる1種以上を用いる。
(Carrier)
The support includes a form that is one or both of carbon and ceramics. Ceramics include, for example, alumina, silica, silica alumina, calcia, magnesia, titania, ceria, zirconia, ceria zirconia, lantana, lantana alumina, tin oxide, tungsten oxide, aluminosilicate, aluminophosphate, borosilicate, phosphotungstic acid, hydroxy Apatite, hydrotalcite, perovskite, cordierite, mullite or silicon carbide. The carbon is, for example, activated carbon, carbon black, acetylene black, carbon nanotube, or carbon nanohorn. In this embodiment, only 1 type may be used from these support bodies, or 2 or more types may be used together. When two or more types are used in combination, two or more types from ceramics may be used in combination, two or more types from carbon may be used in combination, or one or more types from ceramics and one or more types from carbon may be used in combination. . More preferably, at least one selected from alumina, silica, titania, ceria, zirconia, activated carbon and carbon black is used.
(有機溶媒)
有機溶媒は、炭素数が2以上であり、還元性をもつことが好ましい。有機溶媒の炭素数は、4以上であることがより好ましい。有機溶媒の炭素数の上限は、特に限定されないが、常温において液体であることが好ましい。
(Organic solvent)
The organic solvent preferably has 2 or more carbon atoms and has reducibility. More preferably, the organic solvent has 4 or more carbon atoms. The upper limit of the carbon number of the organic solvent is not particularly limited, but is preferably liquid at normal temperature.
有機溶媒の沸点は100℃以上であることが好ましい。取り扱い性に優れる。また、担持触媒をより安全に得ることができる。有機溶媒の沸点は、160℃以上であることがより好ましい。有機溶媒の沸点の上限は、特に限定されないが、担持触媒から溶媒をより容易に除去できる点で、300℃以下であることが好ましく、290℃以下であることがより好ましい。 The boiling point of the organic solvent is preferably 100 ° C. or higher. Excellent handleability. In addition, the supported catalyst can be obtained more safely. The boiling point of the organic solvent is more preferably 160 ° C. or higher. Although the upper limit of the boiling point of the organic solvent is not particularly limited, it is preferably 300 ° C. or lower, more preferably 290 ° C. or lower, from the viewpoint that the solvent can be more easily removed from the supported catalyst.
有機溶媒は、多価アルコール、ブタノール、イソブタノール、エトキシエタノール、ジメチルホルムアミド、キシレン、N−メチルピロリジノン、ジクロロベンゼン、トルエン、プロピレングリコールモノメチルエーテル、エチレングリコールモノメチルエーテル、エチレングリコールモノメチルエーテルアセテート、エチルラクテート、ジエチレングリコールジメチルエーテル、ジプロピレングリコールジメチルエーテル、ジエチレングリコールエチルメチルエーテル、ジエチレングリコールイソプロピルメチルエーテル、ジプロピレングリコールモノメチルエーテル、ジエチレングリコールジエチルエーテル、ジエチレングリコールモノメチルエーテル、ジエチレングリコールブチルメチルエーテル、トリプロピレングリコールジメチルエーテル、トリエチレングリコールジメチルエーテル、ジエチレングリコールモノブチルエーテル、エチレングリコールモノフェニルエーテル、リエチレングリコールモノメチルエーテル、ジエチレングリコールジブチルエーテル、トリエチレングリコールブチルメチルエーテル、ポリエチレングリコールジメチルエーテル、テトラエチレングリコールジメチルエーテル及びポリエチレングリコールモノメチルエーテルの中から選ばれる1種以上であることが好ましい。担持触媒をより安全、かつ、より効率的に得ることができる。このうち、多価アルコールがより好ましい。 Organic solvents are polyhydric alcohol, butanol, isobutanol, ethoxyethanol, dimethylformamide, xylene, N-methylpyrrolidinone, dichlorobenzene, toluene, propylene glycol monomethyl ether, ethylene glycol monomethyl ether, ethylene glycol monomethyl ether acetate, ethyl lactate, Diethylene glycol dimethyl ether, dipropylene glycol dimethyl ether, diethylene glycol ethyl methyl ether, diethylene glycol isopropyl methyl ether, dipropylene glycol monomethyl ether, diethylene glycol diethyl ether, diethylene glycol monomethyl ether, diethylene glycol butyl methyl ether, tripropylene glycol dimethyl Ether, triethylene glycol dimethyl ether, diethylene glycol monobutyl ether, ethylene glycol monophenyl ether, reethylene glycol monomethyl ether, diethylene glycol dibutyl ether, triethylene glycol butyl methyl ether, polyethylene glycol dimethyl ether, tetraethylene glycol dimethyl ether and polyethylene glycol monomethyl ether It is preferable that it is 1 or more types. The supported catalyst can be obtained more safely and more efficiently. Of these, polyhydric alcohols are more preferred.
多価アルコールは、エチレングリコール、ジエチレングリコール、トリエチレングリコール、プロピレングリコール及びブチレングリコールの中から選ばれる1種以上であることが好ましい。このうち、トリエチレングリコールがより好ましい。担持触媒をより安全、かつ、より効率的に得ることができる。 The polyhydric alcohol is preferably at least one selected from ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol and butylene glycol. Of these, triethylene glycol is more preferable. The supported catalyst can be obtained more safely and more efficiently.
次に、工程1について説明する。 Next, step 1 will be described.
工程1aでは、まず、担持体と有機溶媒とを含有し、かつ、高分子保護材を含有しない混合物を作製する。混合物の作製にあたり、担持体を有機溶媒中に懸濁させた後、例えば超音波などの分散機を用いて分散させることが好ましい。 In step 1a, first, a mixture containing a carrier and an organic solvent and not containing a polymer protective material is prepared. In preparing the mixture, it is preferable that the support is suspended in an organic solvent and then dispersed using, for example, an ultrasonic disperser.
次いで、混合物を加熱する。加熱方法は、特に限定されず、例えば、オイルバス、マントルヒーター、ブロックヒーター若しくは熱媒循環式ジャケットなどの外部加熱方式、又はマイクロ波照射方式である。加熱温度は、100〜300℃であることが好ましく、180〜230℃であることがより好ましい。 The mixture is then heated. The heating method is not particularly limited, and is, for example, an external heating method such as an oil bath, a mantle heater, a block heater or a heat medium circulation jacket, or a microwave irradiation method. The heating temperature is preferably 100 to 300 ° C, and more preferably 180 to 230 ° C.
工程1bでは、Pd化合物、Ru化合物及び純水を含有し、かつ、高分子保護材を含有しない混合物を作製する。混合物は、Pd化合物及びRu化合物が純水に溶解した溶液であるか、又はPd化合物及びRu化合物が純水に分散した分散液であってもよい。このうち、混合物は、Pd化合物及びRu化合物が純水に溶解した溶液であることがより好ましい。Pd化合物とRu化合物との割合は、得られるPd−Ru合金粒子においてRuとPdとの原子比が所定の範囲となるように調整する。Ru:Pdが原子比で0.1:0.9〜0.9:0.1の範囲であることが特に好ましい。合金の原子比は、例えば高周波誘導結合プラズマ発光分光分析、原子吸光分光光度法で測定することができる。 In step 1b, a mixture containing a Pd compound, a Ru compound and pure water and containing no polymer protective material is prepared. The mixture may be a solution in which the Pd compound and the Ru compound are dissolved in pure water, or a dispersion in which the Pd compound and the Ru compound are dispersed in pure water. Among these, the mixture is more preferably a solution in which a Pd compound and a Ru compound are dissolved in pure water. The ratio of the Pd compound and the Ru compound is adjusted so that the atomic ratio of Ru and Pd is within a predetermined range in the obtained Pd—Ru alloy particles. It is particularly preferable that Ru: Pd is in the range of 0.1: 0.9 to 0.9: 0.1 in atomic ratio. The atomic ratio of the alloy can be measured by, for example, high frequency inductively coupled plasma emission spectrometry or atomic absorption spectrophotometry.
工程1cでは、工程1aの混合物を前記した加熱温度に保ちながら、工程1aの混合物と工程1bの混合物とを混合する。混合方法は、特に限定されないが、工程1aの混合物に、工程1bの混合物を噴霧する方法であることが好ましい。工程1cでは、工程1aの混合物と工程1bの混合物とを混合後、加熱状態を保持することが好ましい。混合液の全量を混合後加熱状態を保持する時間は、5〜60分であることが好ましく、10〜30分であることがより好ましい。 In step 1c, the mixture of step 1a and the mixture of step 1b are mixed while maintaining the mixture of step 1a at the heating temperature described above. The mixing method is not particularly limited, but is preferably a method in which the mixture of step 1b is sprayed onto the mixture of step 1a. In step 1c, it is preferable to maintain the heated state after mixing the mixture of step 1a and the mixture of step 1b. The time for maintaining the heated state after mixing the entire amount of the mixed solution is preferably 5 to 60 minutes, and more preferably 10 to 30 minutes.
Ru化合物及びPd化合物の合計量と担持体の量との割合は、担持触媒中のPd−Ru合金粒子の担持量が所定の範囲となるように調整する。担持触媒中のPd−Ru合金粒子の担持量は、0.001〜60質量%であることが好ましい。ここで、担持量は、乾燥状態の担持触媒の質量に対するナノ粒子の質量の割合であり、例えば高周波誘導結合プラズマ発光分光分析、原子吸光分光光度分析で測定することができる。 The ratio between the total amount of the Ru compound and Pd compound and the amount of the support is adjusted so that the supported amount of the Pd—Ru alloy particles in the supported catalyst falls within a predetermined range. The supported amount of Pd—Ru alloy particles in the supported catalyst is preferably 0.001 to 60% by mass. Here, the supported amount is the ratio of the mass of the nanoparticles to the mass of the supported catalyst in the dry state, and can be measured by, for example, high frequency inductively coupled plasma emission spectrometry or atomic absorption spectrophotometry.
工程1では、Ru化合物及びPd化合物が有機溶媒によって還元され、担持体の表面でPd−Ru合金粒子の核生成及び粒成長が起こる。そして、Pd−Ru合金粒子が担持体に担持された担持触媒が得られる。溶解法ではPd−Ru合金粒子中のRu含有量が10〜90原子%ではPd−Ru合金の固溶体を形成しないが、本実施形態ではPd−Ru合金の固溶体を形成することができる。Pd−Ru合金粒子が固溶体を形成していることで、触媒活性がより高まる。より好ましくは、Pd−Ru合金粒子が固溶体の単相を形成している。Pd−Ru合金粒子の状態は、例えば、走査透過電子顕微鏡法(STEM)を用いたエネルギー分散型蛍光X線分析法(EDS)の元素マッピングによって確認できる。Pd−Ru合金粒子の平均粒子径は、30nm以下であることが好ましく、20nm以下であることがより好ましい。Pd−Ru合金粒子の平均粒子径の下限は、特に限定されないが、1nm以上であることが好ましい。 In step 1, the Ru compound and the Pd compound are reduced by an organic solvent, and nucleation and grain growth of Pd—Ru alloy particles occur on the surface of the support. And the supported catalyst by which the Pd-Ru alloy particle was carry | supported by the support body is obtained. In the melting method, when the Ru content in the Pd—Ru alloy particles is 10 to 90 atomic%, a solid solution of the Pd—Ru alloy is not formed, but in this embodiment, a solid solution of the Pd—Ru alloy can be formed. Since the Pd—Ru alloy particles form a solid solution, the catalytic activity is further increased. More preferably, the Pd—Ru alloy particles form a solid solution single phase. The state of the Pd—Ru alloy particles can be confirmed by elemental mapping of energy dispersive X-ray fluorescence analysis (EDS) using scanning transmission electron microscopy (STEM), for example. The average particle diameter of the Pd—Ru alloy particles is preferably 30 nm or less, and more preferably 20 nm or less. The lower limit of the average particle diameter of the Pd—Ru alloy particles is not particularly limited, but is preferably 1 nm or more.
工程1cの後、担持触媒を溶媒から分離精製することが好ましい。担持触媒を分離精製する方法は、特に限定されないが、例えば、温度が下がった混合物をろ過し、洗浄・乾燥する方法である。 After step 1c, the supported catalyst is preferably separated and purified from the solvent. The method for separating and purifying the supported catalyst is not particularly limited. For example, the method is a method of filtering, washing and drying a mixture having a lowered temperature.
以降、実施例を示しながら本発明についてさらに詳細に説明するが、本発明は実施例に限定して解釈されない。 Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not construed as being limited to the examples.
(実施例1B)
フラスコに純水を50mL投入した。塩化ルテニウム(III)n水和物(以下、RuCl3・nH2O)を0.1177gとテトラクロロパラジウム酸カリウム(II)(以下、K2PdCl4)を0.1635gとを秤とり前記純水に添加して溶解した水溶液を作製した。水溶液に高分子保護材は添加しなかった。また、活性炭(FAM−50、日本エンバイロケミカルズ社製)を1.15g秤とりトリエチレングリコール(以下、TEG)100mL中に添加し、超音波で分散して混合液を作製した。混合液に高分子保護材は添加しなかった。この混合液を205℃に加熱し、混合液の温度が200℃以上を保持した条件で前記水溶液を霧状に添加した。水溶液の全量を添加終了後15min加熱保持し、その後冷却した。冷却後の混合液を減圧濾過し、固体成分(濾物)をH2O及びエタノールを用いて十分に洗浄した後減圧乾燥を実施し、担持触媒を得た。
(Example 1B)
50 mL of pure water was charged into the flask. Ruthenium (III) chloride n hydrate (hereinafter RuCl 3 · nH 2 O) 0.1177 g and potassium tetrachloropalladate (II) (hereinafter K 2 PdCl 4 ) 0.1635 g were weighed and the pure An aqueous solution dissolved in water was prepared. No polymer protective material was added to the aqueous solution. Further, 1.15 g of activated carbon (FAM-50, manufactured by Nippon Enviro Chemicals) was weighed and added to 100 mL of triethylene glycol (hereinafter, TEG), and dispersed with ultrasonic waves to prepare a mixed solution. The polymer protective material was not added to the mixed solution. This mixed solution was heated to 205 ° C., and the aqueous solution was added in the form of a mist under the condition that the temperature of the mixed solution was maintained at 200 ° C. or higher. The whole amount of the aqueous solution was kept heated for 15 minutes after the addition was completed, and then cooled. The mixed liquid after cooling was filtered under reduced pressure, and the solid component (filtered material) was sufficiently washed with H 2 O and ethanol and then dried under reduced pressure to obtain a supported catalyst.
(実施例2B)
フラスコに純水を50mL投入した。RuCl3・nH2Oを0.0582gとK2PdCl4を0.0779gとを秤とり前記純水に添加して溶解した水溶液を作製した。水溶液に高分子保護材は添加しなかった。また、活性炭(FAM−50)を0.959g秤とりTEG100mL中に添加し、超音波で分散して混合液を作製した。混合液に高分子保護材は添加しなかった。この混合液を205℃に加熱し、混合液の温度が200℃以上を保持した条件で前記水溶液を霧状に添加した。水溶液の全量を添加終了後15min加熱保持し、その後冷却した。遠心分離を用いて冷却後の混合液から固体成分を沈降させ上澄みを除去し、固体成分をH2O及びエタノールを用いて十分に洗浄した後減圧乾燥を実施し、目的のPd−Ru担持触媒を得た。
(Example 2B)
50 mL of pure water was charged into the flask. An aqueous solution in which 0.0582 g of RuCl 3 · nH 2 O and 0.0779 g of K 2 PdCl 4 were weighed and dissolved in the pure water was prepared. No polymer protective material was added to the aqueous solution. Further, 0.959 g of activated carbon (FAM-50) was weighed and added to 100 mL of TEG, and dispersed by ultrasonic waves to prepare a mixed solution. The polymer protective material was not added to the mixed solution. This mixed solution was heated to 205 ° C., and the aqueous solution was added in the form of a mist under the condition that the temperature of the mixed solution was maintained at 200 ° C. or higher. The whole amount of the aqueous solution was kept heated for 15 minutes after the addition was completed, and then cooled. The solid component is settled from the cooled mixed solution using centrifugal separation, the supernatant is removed, the solid component is thoroughly washed with H 2 O and ethanol, and then dried under reduced pressure, and the target Pd-Ru supported catalyst is obtained. Got.
(実施例3B)
フラスコに純水を50mL投入した。RuCl3・nH2Oを0.3535gとK2PdCl4を0.4917gとを秤とり前記純水に添加して溶解した水溶液を作製した。水溶液に高分子保護材は添加しなかった。また、ケッチェンブラック(EC300J、ライオン社製)を0.7023g秤とりTEG100mL中に添加し、超音波で分散して混合液を作製した。混合液に高分子保護材は添加しなかった。この混合液を205℃に加熱し、混合液の温度が200℃以上を保持した条件で前記水溶液を霧状に添加した。水溶液の全量を添加終了後15min加熱保持し、その後冷却した。遠心分離を用いて冷却後の混合液から固体成分を沈降させ上澄みを除去し、固体成分をH2O及びエタノールを用いて十分に洗浄した後減圧乾燥を実施し、目的のPd−Ru担持触媒を得た。
(Example 3B)
50 mL of pure water was charged into the flask. An aqueous solution in which 0.3535 g of RuCl 3 .nH 2 O and 0.4917 g of K 2 PdCl 4 were weighed and dissolved in the pure water was prepared. No polymer protective material was added to the aqueous solution. In addition, 0.7023 g of Ketjen Black (EC300J, manufactured by Lion Corporation) was weighed and added to 100 mL of TEG, and dispersed with ultrasonic waves to prepare a mixed solution. The polymer protective material was not added to the mixed solution. This mixed solution was heated to 205 ° C., and the aqueous solution was added in the form of a mist under the condition that the temperature of the mixed solution was maintained at 200 ° C. or higher. The whole amount of the aqueous solution was kept heated for 15 minutes after the addition was completed, and then cooled. The solid component is settled from the cooled mixed solution using centrifugal separation, the supernatant is removed, the solid component is thoroughly washed with H 2 O and ethanol, and then dried under reduced pressure, and the target Pd-Ru supported catalyst is obtained. Got.
(Pd−Ru合金粒子の平均粒子径)
実施例1Bの担持触媒をTEMで倍率150000倍で観察し、得られた粒子像から100個の粒子の粒子径を計測し、その平均を求め、図1に実施例1BのTEM像を示す。実施例1Bの平均粒子径は、6.71nmであった。また、図1から、凝集した粒子の存在は確認されなかった。
(Average particle diameter of Pd—Ru alloy particles)
The supported catalyst of Example 1B was observed with a TEM at a magnification of 150,000 times, the particle diameter of 100 particles was measured from the obtained particle image, the average was obtained, and the TEM image of Example 1B is shown in FIG. The average particle size of Example 1B was 6.71 nm. Further, from FIG. 1, the presence of aggregated particles was not confirmed.
(合金の状態)
実施例1Bの担持触媒について、XRD測定及び昇温XRD測定を行った。XRD測定条件は、室温でλ=CuKαである。昇温XRD測定条件は、室温、100℃、200℃、300℃、400℃、500℃で、λ=0.58Åである。図2に実施例1BのXRDパターンを示す。図3に実施例1Bの昇温XRDパターンを示す。図2及び図3からPd−Ru合金ナノ粒子が合成されたことが確認できた。また、実施例1Bの担持触媒について、STEM測定を行った。図4に実施例1BのSTEM像を、図5に実施例1BのEDSマッピングを示す。図4からPd−Ru合金粒子が担持体上に形成されていることが確認できた。また、図5はPdとRuとの固溶限界を超えた混合比でPdとRuとが混合した粒子を形成していることを示しており、Pd−Ru合金が固溶体を形成していることが確認できた。図5では、元素マッピングをグレー階調に処理した画像を示したが、元素マッピングはグレー調に処理する前のカラー画像によって、より正確に表現される。
(Alloy state)
The supported catalyst of Example 1B was subjected to XRD measurement and elevated temperature XRD measurement. The XRD measurement condition is λ = CuKα at room temperature. The temperature rise XRD measurement conditions are room temperature, 100 ° C., 200 ° C., 300 ° C., 400 ° C., 500 ° C., and λ = 0.58Å. FIG. 2 shows the XRD pattern of Example 1B. FIG. 3 shows the temperature rise XRD pattern of Example 1B. It was confirmed from FIGS. 2 and 3 that Pd—Ru alloy nanoparticles were synthesized. Further, STEM measurement was performed on the supported catalyst of Example 1B. FIG. 4 shows an STEM image of Example 1B, and FIG. 5 shows an EDS mapping of Example 1B. From FIG. 4, it was confirmed that Pd—Ru alloy particles were formed on the support. Further, FIG. 5 shows that particles in which Pd and Ru are mixed at a mixing ratio exceeding the solid solution limit of Pd and Ru are formed, and that the Pd—Ru alloy forms a solid solution. Was confirmed. FIG. 5 shows an image in which element mapping is processed to gray gradation, but element mapping is more accurately expressed by a color image before processing in gray tone.
Claims (5)
前記Pd−Ru合金粒子は、固溶体を形成しており、
前記担持触媒の外表面に高分子保護材が存在しないことを特徴とする担持触媒。 In a supported catalyst in which Pd—Ru alloy particles are supported on a support as nanoparticles,
The Pd—Ru alloy particles form a solid solution,
A supported catalyst characterized in that no polymer protective material is present on the outer surface of the supported catalyst.
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