JP6425064B2 - Water discharge when the toilet excrete - Google Patents
Water discharge when the toilet excrete Download PDFInfo
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- JP6425064B2 JP6425064B2 JP2014165576A JP2014165576A JP6425064B2 JP 6425064 B2 JP6425064 B2 JP 6425064B2 JP 2014165576 A JP2014165576 A JP 2014165576A JP 2014165576 A JP2014165576 A JP 2014165576A JP 6425064 B2 JP6425064 B2 JP 6425064B2
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/16—Disinfection, sterilisation or deodorisation of air using physical phenomena
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
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- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
Description
この発明は、トイレ排泄時前に、便器内のため水に本発明品を投入して泡の層を作りだし、排泄時における水はね防止、消臭、防音、洗浄、トイレ室内の汚れ抑制に関する発明である。The present invention relates to the present invention is added to water in the toilet bowl to create a foam layer before toilet discharge, and relates to water splash prevention, deodorant, soundproofing, washing, dirt control in the toilet room at the time of discharge It is an invention.
従来、人がトイレで排泄を行うには、便器のため水に向けて排泄を行う形になっていた。Conventionally, in order to excrete in the toilet, it has been a form to excrete water for the toilet bowl.
これは次のような欠点があった。
(イ)便器のため水に排泄物を落下させるため、水はねが必然的に起こり、便器外に飛び 散り、身体、衣服、床、壁などに付着し不衛生であった。
(ロ)男性が洋式便器に立って行う一回の放尿時には、目に見えない微量の水滴も含めて 多くて約2000滴もの水滴が便器外に飛び散っているといわれている。また、そ れが和式便器である場合には、身体とため水の水面との距離が洋式便器よりも遠く なるものがほとんどのため、排泄物の落下する勢いがさらに増し、さらに多くの水 はねが起こっている。
(ハ)女性が洋式または和式便器で排泄を行う際にも、臀部、性器などの身体と便器のた め水との距離が近いため、ため水の水はねを受けやすく、汚れ、感染症引き起こす おそれもあった。
(二)また、ため水に向けて排泄を行うため、排泄物の着水音、臭いが無防備に発生し、 羞恥心を起こさせていた。
本発明は以上のような欠点なくすためになされたものである。This has the following drawbacks.
(A) In order to drop excrement into water for the toilet bowl, water splashing inevitably occurs and spatters out of the toilet bowl and adheres to the body, clothes, floor, wall, etc., resulting in poor hygiene.
(B) It is said that, at the time of a single urination performed by a man standing in a Western-style toilet bowl, as many as about 2000 drops of water, including small traces of invisible water, are splashing out of the toilet bowl. Also, if it is a Japanese-style urinal, most of the distance between the body and the water surface is longer than that of the Western-style urinal, further increasing the falling impact of excrement, and more water A splash is happening.
(C) Even when women excrete in a Western-style or Japanese-style toilet bowl, the body is close to the body, such as the buttocks and genitals, and the water is close to the toilet bowl, so it is susceptible to water splashing, dirt and infection. There was also a risk of causing illness.
(2) In addition, in order to excrete toward water, the sound of water coming in from the excrement and odor occur unprotectedly, causing shame.
The present invention has been made to eliminate the above-mentioned drawbacks.
排泄直前に、携帯可能でおよそ掌に乗るサイズの本発明品をトイレため水にそのまま直接手で放り込む。本発明品は水に触れると先ず包装物である水溶紙やフィルムが水に溶けだす。そして内容物のアルカリ性物質と酸性物質と界面活性剤が水に触れると化学反応を起こし、泡の層を発生させるものである。水面から上に約1〜10cmのほどの泡の層をため水の水面上に作る。人はその泡の層に向けて排泄を行う。泡の層がクッションとなり排泄物の落下によるトイレため水の飛沫等を防ぐものである。Just before excretion, the portable product of the present invention, which is about the size of a palm, is directly thrown into the water for the toilet as it is. When the product of the present invention comes in contact with water, first the water-soluble paper or film as a package dissolves in the water. When the alkaline substance, the acidic substance and the surfactant in the contents come into contact with water, they cause a chemical reaction to generate a bubble layer. A layer of foam about 1 to 10 cm above the water surface is made on the water surface. People excrete towards the layer of foam. A layer of foam acts as a cushion to prevent water splashes and the like due to the toilet falling off of excrement.
便器のため水の水面上に、厚さ約1〜10cmほどの泡の層を張るため、排泄物の着水時のはね返り水が、泡の層によって便器外への飛び散りを防ぐことができる。
よって、汚水の飛沫が防止されるため、身体、衣服、床、壁等への汚れが防げ、衛生的になる。便器、トイレ室内の掃除の頻度も減る。また排泄物の着水音を泡の層によって抑えることができる。A layer of foam with a thickness of about 1 to 10 cm is placed on the surface of the water for the toilet bowl, so that the splashing water when the waste comes in water can prevent splashing out of the toilet bowl by the foam layer.
Therefore, since the splash of sewage is prevented, the fouling on the body, clothes, floor, wall, etc. is prevented and it becomes hygienic. The frequency of cleaning the toilet bowl and toilet room also decreases. Also, the sound of water coming from the excrement can be suppressed by the foam layer.
以下、本発明を実施するための形態について説明する。
(イ)アルカリ性の重曹等と酸性のクエン酸等を混ぜたものに水を加えると化学反応を起 こし炭酸ガスつまり二酸化炭素を出すという性質を利用し、トイレ便器内のため水 の水面上に泡の層を作る。
(ロ)その泡をすぐに消えないように界面活性剤を含有させることで発生した泡を持続可 能にし、一つひとつの気泡を強化する。
(ハ)消毒液や石鹸などで利用されるカチオン性界面活性剤や両性界面活性剤を本発明品に含有させることにより、細菌を吸着し洗い流す効果も有する。
これを使用するときは、本発明品を排泄時前に直接便器内のため水に一度投入するだけでよい。本発明品は、水に触れると自動的に化学反応を起こし、泡の層が形成される。Hereinafter, modes for carrying out the present invention will be described.
(B) When water is added to a mixture of alkaline sodium bicarbonate etc. and acidic citric acid etc., a chemical reaction occurs and carbon dioxide, that is, carbon dioxide is emitted, and it is on the water surface of the water because it is in the toilet bowl. Make a layer of foam.
(B) Make the generated bubbles persistent by containing a surfactant so that the bubbles do not disappear immediately, and strengthen each single bubble.
(C) By containing a cationic surfactant or an amphoteric surfactant used in a disinfectant solution or soap in the product of the present invention, it also has an effect of adsorbing and washing out bacteria.
When this is used, it is only necessary to put the product of the present invention into water directly for urinal discharge prior to excretion. The product of the present invention causes a chemical reaction automatically when it is in contact with water to form a foam layer.
本発明品には、アルカリ性物質と酸性物質と界面活性剤、三つの物質を必要とする。排泄前に直接手に取って簡単にワンアクションでトイレため水に投入することが肝である。よってアルカリ性物質と酸性物質と界面活性剤だけを使って簡単に投入できるなら水溶紙、水に溶けるフィルムを使用しないことも考えられる。
例えば、アルカリ性物質と酸性物質だけが粉状またはジェル状または液体状またはフレーク状または板状にし、その周りをチューイングガムの糖衣がけのように界面活性剤でコーティングすることも考えられる。このことは上記三つの物質それぞれ入れ替えて作成することも考えられる。The product of the present invention requires an alkaline substance, an acidic substance, a surfactant and three substances. It is the liver to take it directly into the water for toilets with one action easily. Therefore, it is also conceivable not to use a water-soluble paper or a water-soluble film if it can be easily introduced using only alkaline substances, acidic substances and surfactants.
For example, it is also conceivable that only the alkaline substance and the acidic substance are powdered or gelled or liquid or flaked or plate-like, and coated with surfactant like sugar coating of chewing gum. It can be considered that this is made by replacing the above three substances respectively.
アルカリ性物質と酸性物質と界面活性剤は、粉末状だけではなくジェル状または液体状にすることも考えられる。それらを水溶紙または水に溶けるフィルムで包装、パッケージングする。The alkaline substance, the acidic substance and the surfactant can be considered not only in powder form but also in gel form or liquid form. Pack and package them in water-soluble paper or water-soluble film.
アルカリ性とは、正式には塩基性といい。アルカリ性とは塩基性の物質のうち、特に水に溶ける物質のことをいう。アルカリ性物質としては、例えば、水酸化ナトリウム、水酸化カリウム、水酸化カルシウム、水酸化バリウム、水酸化銅、水酸化アルミニウム、水酸化鉄、水酸化アンモニウム、炭酸アンモニウム、炭酸マグネシウム、炭酸塩、セスキ炭酸ソーダ、ベーキングパウダー、炭酸水素ナトリウムつまり重曹などである。重曹は、水質汚染で問題とされるBOD・COD値がなく、環境ホルモンも含まれていないため環境にやさしいとされる。また食品添加物としても使用できるくらい人体に対しても安全であると考えられている。Alkalinity is formally good as basicity. Among the basic substances, alkaline refers to a substance that is particularly soluble in water. As an alkaline substance, for example, sodium hydroxide, potassium hydroxide, calcium hydroxide, barium hydroxide, copper hydroxide, aluminum hydroxide, iron hydroxide, ammonium hydroxide, ammonium carbonate, magnesium carbonate, carbonate, sesquicarbonate Soda, baking powder, sodium bicarbonate or baking soda. Baking soda is considered environmentally friendly as it has no BOD and COD values that are considered to be a problem in water pollution, and does not contain environmental hormones. It is also considered safe for the human body as it can be used as a food additive.
酸性とは、化学において塩基と対になって働く物質のことで単純に言えば酢、梅干し、レモン、胃液のようなスッパイものが酸性であるといえる。有機酸または無機酸がある。酸性物質としては、例えば、ハロゲン化水素、ハロゲンオキソ酸、硫酸ナトリウム、フルオロスルホン酸、硝酸、リン酸、ヘキサフルオロアンチモン酸、クロム酸、ホウ酸、メタンスルホン酸、エタンスルホン酸、ベンゼンスルホン酸、ポリスチレンスルホン酸ナトリウム、カルボン酸、酢酸、クエン酸、ギ酸、グルコン酸、乳酸、シュウ酸、酒石酸カリウム、ビニル性カルボン酸、核酸、デオキシリボ核酸、リボ核酸、コハク酸、リンゴ酸、サリチル酸、グルコール酸、安息香酸、塩酸などが挙げられる。Acidic is a substance that works in tandem with a base in chemistry. Simply speaking, it can be said that a spice, like vinegar, pickled plum, lemon, and gastric juice-like suppai is acidic. There is an organic or inorganic acid. Examples of the acidic substance include hydrogen halide, halogen oxo acid, sodium sulfate, fluorosulfonic acid, nitric acid, phosphoric acid, hexafluoroantimonic acid, chromic acid, boric acid, methanesulfonic acid, ethanesulfonic acid, benzenesulfonic acid, Polystyrene sulfonate sodium, carboxylic acid, acetic acid, citric acid, formic acid, gluconic acid, lactic acid, oxalic acid, potassium tartrate, vinylic carboxylic acid, nucleic acid, deoxyribonucleic acid, ribonucleic acid, succinic acid, malic acid, salicylic acid, glucose acid, Examples include benzoic acid and hydrochloric acid.
界面活性剤は界面に作用して界面の性質を変化させる物質として定められている。界面活性剤としての物質は、アニオン系、非イオン系、カチオン系、両性系、サポニンやたんぱく質の天然の界面活性能を有する物質などに分類される。例えば、脂肪酸塩つまり石鹸、スルホ脂肪酸エステル塩、アルキルベンゼンスルホン酸塩、直鎖アルキルベンゼンスルホン酸塩、アルキル硫酸塩、ラウレス‐4、ラウレス‐3硫酸アンモニウム、石鹸素地、グリセリン、アルキルエーテル硫酸エステル塩、ホホバ種子油、アルキル硫酸トリエタノールアミン、脂肪酸ジエタノールアミド、ポリオキシエチレンアルキルエーテル、ジアルキルジメチルアンモニウムクロリド、卵白、サボニン、アルキルカルボキシベタイン、ラウリン酸ナトリウム、ステアリン酸ナトリウム、ラウレス硫酸ナトリウム、ラウリル硫酸ナトリウム、パイン油、ユーカリ油、オレイン酸ナトリウム、ラウリルベタイン、ミリスチン酸ナトリウム、ショ糖エステルなどである。Surfactants are defined as substances that act on the interface to change the properties of the interface. Substances as surfactants are classified into anionic type, nonionic type, cationic type, amphoteric type, substances having natural surface activity of saponin and protein, and the like. For example, fatty acid salt ie soap, sulfo fatty acid ester salt, alkyl benzene sulfonate, linear alkyl benzene sulfonate, alkyl sulfate, laureth-4, laureth-3 ammonium sulfate, soap base, glycerin, alkyl ether sulfate, jojoba seed Oil, alkyl sulfate triethanolamine, fatty acid diethanolamide, polyoxyethylene alkyl ether, dialkyl dimethyl ammonium chloride, egg white, savonine, alkyl carboxy betaine, sodium laurate, sodium stearate, sodium laureth sulfate, sodium lauryl sulfate, pine oil, Eucalyptus oil, sodium oleate, lauryl betaine, sodium myristate, sucrose esters and the like.
水に溶けるフィルムは、ゼラチンなどで形成したカプセルを使うことが考えられる。フィルムの素材としては、プロビレングリコール、グリセリン、塩化マグネシウム、亜硫酸カリウム、エタノール、プロパンジオール、ホウ酸などが考えられる。It is conceivable that a water-soluble film uses a capsule formed of gelatin or the like. As materials of the film, there may be considered propylene glycol, glycerin, magnesium chloride, potassium sulfite, ethanol, propanediol, boric acid and the like.
水溶紙はシークレットペーパーともいう。アルカリ性物質と酸性物質と界面活性剤を水溶紙で包装する。水溶紙はトイレットペーパーよりも水によく溶ける。接着素材は下水トラブルを起こさないものや環境にやさしいものを使うのが望ましい。例えば、でんぷん糊や米ぬかを使った接着剤が考えられる。Water soluble paper is also called secret paper. Pack the alkaline substance, acidic substance and surfactant in water-soluble paper. Water-soluble paper dissolves in water better than toilet paper. It is desirable to use adhesive materials that do not cause sewage troubles and those that are environmentally friendly. For example, an adhesive using starch paste or rice bran can be considered.
アルカリ性物質は重曹を使い、酸性物質はクエン酸を使い、界面活性剤はラウリル硫酸ナトリウムを使うことが望ましい。これらの物質は人体や環境にやさしいとされている。この場合は、アルカリ性物質と酸性物質と界面活性剤の混合割合は、およそ3対4対1が最適である。It is preferable to use sodium bicarbonate as the alkaline substance, citric acid as the acidic substance, and sodium lauryl sulfate as the surfactant. These substances are considered to be friendly to humans and the environment. In this case, the optimum mixing ratio of the alkaline substance, the acidic substance and the surfactant is approximately 3 to 4 to 1.
本発明品のサイズは指でつまめる大きさ、手のひらに簡単に乗るくらいの大きさである。1回使い切り、破らずそのままトイレため水に投入する。The size of the product of the present invention is a size that can be pinched with a finger, and a size that can easily get on the palm. Do not use it once and put it into the water for the toilet as it is.
本発明品はトイレため水に投入すると水溶紙が数秒で水に溶けだし、内容物のアルカリ性物質と酸性物質と界面活性剤が水に触れると化学反応を起こし泡の層が形成される。In the product of the present invention, when it is put into water for toilet, the water-soluble paper dissolves in water in a few seconds, and when the alkaline substance, acidic substance and surfactant in the contents come in contact with water, a chemical reaction occurs to form a foam layer.
泡の層は、小便の勢いとともに、ブクブクとさらに発達していく。小用時の水圧とともに気泡が大きくなったり、気泡が増加する。The layer of foam develops further with bukubuku with the force of urination. With the water pressure at the time of small use, bubbles increase or bubbles increase.
アルカリ性物質と酸性物質と界面活性剤は水に触れるだけで自動的に化学反応が起きてしまうので、携帯可能で投入しやすいように上記3つの物質だけで、例えばアルコールなどを使って圧力を加えてプレスし、固めることも考えられる。つまり、簡単に指でつまめるくらいため水に投入するのが容易になるなら、水溶紙または水に溶けるフィルムを使用しないことも考えられる。Alkaline substance, acid substance and surfactant cause chemical reaction to occur automatically only by touching water, so pressure is applied using only alcohol, for example, with the above three substances so that it is portable and easy to add. It is also conceivable to press and harden. In other words, it is conceivable not to use water-soluble paper or water-soluble film if it is easy to put in water because it is easy to clog with fingers.
本発明の目的、効果を阻害しない程度であれば、気泡剤、起泡剤、増粘安定剤、防腐剤、抗菌剤、殺菌剤、香料、消剤、酵素、色素、増粘多糖類、ゲル化剤、アルコール、PH調整剤、泡調整剤、水軟化剤、分散剤、安定化剤、凍結防止剤等を含有することも考えられる。また防臭剤、洗浄剤なども本発明品に含有させて、におい、よごれを抑えることも考えられる。The object of the present invention is a foaming agent, a foaming agent, a thickening stabilizer, an antiseptic agent, an antibacterial agent, a bactericide, a fragrance, a extinguishing agent, an enzyme, a pigment, a polysaccharide, a gel, as long as the effect of the invention is not impaired It is also conceivable to contain a plasticizer, alcohol, pH regulator, foam regulator, water softener, dispersant, stabilizer, antifreezing agent and the like. Further, it is also conceivable to contain a deodorant, a detergent and the like in the product of the present invention to suppress odor and dirt.
本発明品はトイレため水の水面上に泡の層を形成し、水面を覆うものである。泡の層がクッションとなり、排せつ時の水はね等を抑える効果がある。この観点からすると界面活性剤のみを携帯可能で直接手に触れて投入しやすいように加工して使用することも考えられる。この場合自動的に泡の層は形成されないが、小用時の水面にあたる水圧でブクブクと泡が発達していくことで、水はね等防止の効果が増していくのである。The product according to the present invention forms a foam layer on the surface of water for the toilet and covers the surface of the water. The foam layer acts as a cushion, which has the effect of suppressing water splashing and the like during drainage. From this point of view, it may be considered to process and use only the surfactant so as to be portable and easy to handle by hand. In this case, although a foam layer is not automatically formed, the development of bubbling and bubbles by the water pressure corresponding to the water surface at the time of small use increases the effect of preventing water splashing and the like.
トイレの便器の大きさは様々なので、トイレため水の量や水面の大きさも様々である。約2リットルが平均的な水の量だと言われている。節水型の便器の場合の水の量は1リットル前後である。その場合は本発明品を一つだけ投入する、旧式で大きな便器の場合は水の量が多いこともあり、その場合は本発明品を1〜3つくらいを投入する、という様に適宜調節することが望ましい。Because the size of the toilet bowl varies, the amount of water and the size of the water surface also vary. About 2 liters is said to be the average amount of water. The amount of water in the case of a water-saving toilet bowl is around 1 liter. In this case, only one product of the present invention may be added, and in the case of an old large toilet bowl, the amount of water may be large, and in such a case, one to three components of the present invention may be added. It is desirable to do.
本発明品はトイレ便器に付属させた装置またはトイレ便器に内蔵させた装置ではなく、携帯可能なので自宅だけでなく外出先のトイレにおいても使用できる。手でつまめるサイズ、重さで、ワンアクションで直接手でポンと放り込むだけである。
本発明は以上のような構造である。The present invention is not a device attached to the toilet bowl or a device built in the toilet bowl, and can be used not only at home but also at the toilet outside the house because it is portable. Hand-clogged size and weight, you just need to pong directly with one action.
The present invention has the above structure.
1 本発明品を投入する手
2 本発明品
3 化学反応を起こし泡の層を形成し始める泡
4 トイレため水
5 便器の断面図
6 泡の層
7 尿
8 泡の層によって抑制される飛沫
9 便器外に飛び散る飛沫1 Hand to put in the present invention 2 Present invention 3 foam to cause chemical reaction to start forming foam layer Water for
Claims (1)
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JP2014165576A JP6425064B2 (en) | 2014-07-29 | 2014-07-29 | Water discharge when the toilet excrete |
PCT/JP2015/072978 WO2016017829A1 (en) | 2014-07-29 | 2015-07-30 | Toilet foam for prevention of splashes during excretion |
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JP2014165576A JP6425064B2 (en) | 2014-07-29 | 2014-07-29 | Water discharge when the toilet excrete |
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JP2015120882A5 JP2015120882A5 (en) | 2018-05-31 |
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JP6425064B2 (en) * | 2014-07-29 | 2018-11-21 | とべる工房株式会社 | Water discharge when the toilet excrete |
JP6765034B2 (en) * | 2016-03-29 | 2020-10-07 | パナソニックIpマネジメント株式会社 | Sanitary cleaning equipment |
WO2019138450A1 (en) * | 2018-01-15 | 2019-07-18 | 広康 渡邊 | Urine splash preventing device, and fixture for transporting liquid to toilet bowl |
JP2023514934A (en) | 2019-12-18 | 2023-04-12 | クレアネオル | Effervescent composition for masking excrement and preventing splashes and falling sounds |
IT202000006820A1 (en) | 2020-04-01 | 2021-10-01 | Univ Degli Studi Di Foggia | Aqueous foaming composition and its use for the prevention and / or inhibition of aerosol formation from the rebound of a liquid on a surface |
CN113214671A (en) * | 2021-05-10 | 2021-08-06 | 彭鑫 | Sanitary defensive substance, preparation and application |
WO2023089605A1 (en) * | 2021-11-17 | 2023-05-25 | Azouri Loren | Composition to prevent or reduce splashing on use of a toilet |
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JPH0372124A (en) * | 1989-08-11 | 1991-03-27 | Hiroaki Hino | Water splash preventive agent for use in water closet |
JP2624549B2 (en) * | 1989-12-21 | 1997-06-25 | 三菱マテリアル株式会社 | Circulating toilet waste treatment agent |
JPH06105893A (en) * | 1992-09-24 | 1994-04-19 | Saburou Takebe | Foamable deodorant |
JPH07278598A (en) * | 1994-04-05 | 1995-10-24 | Pias Arise Kk | Deodorizing and washing agent for water closet |
JP2005516112A (en) * | 2002-01-31 | 2005-06-02 | ジボダン エス エー | Effervescent granule composition |
JP2004188235A (en) * | 2002-12-06 | 2004-07-08 | Tsurumi Soda Co Ltd | Deodorant and method for using the deodorant |
US20070039089A1 (en) * | 2005-08-19 | 2007-02-22 | Worrel Keith A | Noise and splash attenuation agent and device |
US7638475B2 (en) * | 2006-03-24 | 2009-12-29 | Georgia-Pacific Consumer Products Lp | Space saving toilet cleaning system |
WO2008020246A2 (en) * | 2006-08-18 | 2008-02-21 | Lavitec Corporation Limited | Sanitary composition |
JP2010063503A (en) * | 2008-09-08 | 2010-03-25 | Ishizaka Tsutomu | Foam composition for toilet, foaming agent for toilet, and spray filled with foaming agent for toilet |
CN102367399A (en) * | 2011-05-25 | 2012-03-07 | 王国松 | Sanitation bubbles |
JP2015052257A (en) * | 2013-09-06 | 2015-03-19 | 正太郎 外村 | Bubble for preventing water splash and the like during evacuation in toilet |
JP6425064B2 (en) * | 2014-07-29 | 2018-11-21 | とべる工房株式会社 | Water discharge when the toilet excrete |
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