JP6363372B2 - Adhesive adhesive - Google Patents

Description

  TECHNICAL FIELD The present invention relates to an adhesive wrinkle adhesive, and more specifically, an adhesive adhesive that has excellent adhesiveness of the adhesive wrinkle and does not peel off even if the eyelid moves, and further contains a coloring agent. The present invention also relates to an eyeliner-attached tack adhesive capable of coloring the coated portion.

  In recent years, in the makeup of the eyes, there have been many opportunities to use a false eyelash, and it is often performed to attach the false eyelash to the eyelid.

  In a conventional makeup method, an adhesive adhesive as disclosed in Patent Document 1 is used as an adhesive for adhering the eyelid to the eyelid. This adhesive adhesive uses the high adhesive strength, durability of adhesive strength, water resistance, etc. possessed by the alkyl acrylate copolymer, can be re-applied, and easily peels off the adhesive. Is possible.

  However, in the study by the present inventors, a film formed of a water-insoluble film-forming polymer such as the above-mentioned alkyl acrylate-based polymer is often hard, and when this is added in a lot to the adhesive, I learned that the cosmetic film could not follow the movement of the eyelids, causing problems such as peeling off the eyelids and feeling the burden on the eyelids.

  On the other hand, in order to attach an eyelid to the eyelid, it is common to draw an eyeliner, apply an adhesive to the eyelid, and attach the adhesive eyelash to the eyelid on which the eyeliner is applied. It was the target. However, such a cosmetic method has a problem that it takes time and labor to apply an adhesive after drawing and drying an eyeliner, and also requires advanced techniques. In addition, there were some that were poorly adhered to the eyeliner and easy to remove.

  By the way, in the conventional eyeliner, it is a matter of course that the film formed by coating does not have adhesiveness, and there has been no idea of attaching and attaching a flaw to the coated film.

  In such a situation, the present inventors, as a new idea that was not found in the conventional eyeliner, was conceived of blending a colorant such as black in the composition of the adhesive adhesive, and also used this as an eyeliner, When a colorant is blended in a conventional adhesive adhesive having tackiness and used as an eyeliner, it is a matter of course that the adhesiveness can be lowered. In addition, if black iron oxide blended in a conventional eyeliner is blended in an adhesive agent in an amount that provides sufficient blackness as an eyeliner, the formed film is strong and the eye strain is felt. Is large, unable to follow the movement of the eyelid, causing the spear to move. Moreover, when the amount of black iron oxide as described above is blended in the conventional adhesive iron adhesive, there is a problem that the film becomes non-uniform and the adhesive effect required for the original adhesive iron adhesive is impaired. .

  Therefore, it is conceivable to change the black iron oxide to another pigment, but it is difficult to sufficiently disperse the adhesive component contained in the adhesive adhesive and the film-forming component even with other pigments. In addition, there is a problem that it is difficult to form a uniform adhesive layer.

JP2009-40718 JP2008-273934 JP2011-37742A

  The present invention has been made in view of the above circumstances, and the problem is that the film formed after application can sufficiently follow the movement of the eyelid, and the eyelids peel off or feel a burden on the eyelid. By providing an adhesive agent that does not cause a problem, and further adding a colorant to this, the coated part can be colored, and a fast-drying adhesive layer is added to the coated part, It is to provide an adhesive glue that can be used in combination.

In order to solve the above problems, the present inventor firstly
(1) The application part dries relatively quickly and does not become sticky while having sufficient adhesive strength to bond the spear.
(2) Even after blinking, the spear fluctuates or has adhesive strength and followability that cannot be removed,
(3) The application part is easy to be detached by simple means such as face washing,
Research has been conducted to find a glue adhesive that satisfies the above conditions, and it has been found that a glue adhesive satisfying these conditions can be obtained by combining a water-insoluble film-forming polymer and glycosyl trehalose. It was.

(4) The colorant can be sufficiently mixed to color the coated part.
(5) In consideration of satisfying the condition that it is easy to draw as an eyeliner, the composition of an adhesive adhesive that can also be used as an eyeliner has been studied. The present invention was completed by finding that an adhesive agent that can also be used as an eyeliner that satisfies these conditions can be obtained by blending with the adhesive agent in the adhesive agent.

That is, the present invention comprises the following components (A) and (B):
(A) Water-insoluble film-forming polymer (B) An adhesive glue containing glycosyl trehalose.

The present invention also includes the following components (A) to (C):
(A) Water-insoluble film-forming polymer (B) Glycosyl trehalose (C) An eyeliner-attached eyelid adhesive characterized by containing a colorant.

  Further, the present invention is an eyeliner-attached tack adhesive containing a nonionic surfactant having an HLB of 10 or more as the component (D).

  The adhesive wrinkle adhesive of the present invention has a sufficient adhesive force for holding the adhesive wrinkle and the ability to form a flexible film. The problem of feeling does not occur.

  In addition, the eyeliner-adhesive agent in which a colorant and, if necessary, a specific nonionic surfactant are further added to the adhesive agent, provides a color sufficient as an eyeliner due to the contained colorant. Therefore, the application of the adhesive for attaching the tackle simultaneously draws an eyeliner, which simplifies the makeup method and eliminates the need for conventional advanced techniques.

  The adhesive glue which is the first aspect of the present invention contains a water-insoluble film-forming polymer as component (A) and glycosyl trehalose as component (B).

  The component (A), a water-insoluble film-forming polymer (hereinafter referred to as “component (A)”) mainly has a function of adhering a tackle and a function of forming a film after drying. This component (A) is not particularly limited as long as it is a resin or a polymer that forms a film when a cosmetic is applied, and it can be any natural, semi-synthetic, synthetic or water-insoluble. Can also be used, and preferably can be used as an aqueous dispersion thereof. However, a more preferable component (A) is preferably a component having a high flexibility of the film formed on the skin. Whether or not this flexibility is high is determined by, for example, forming a sample film on a stainless steel plate (SUS304, plate thickness 0.1 mm) with an applicator having a film thickness of 32 mil (about 0.8 mm), and then bending the stainless plate 30 times. It is preferable that the surface of the film does not crack. It is not preferable that the film breaks when touching the surface.

  In addition, the component (A) of the present invention is preferably one that can shorten the drying time in the adhesive agent of the present invention. For example, it is dried in about 1 to 3 minutes after application and adheres the adhesive agent It is preferable that

  Preferred examples of such component (A) include, for example, alkyl acrylate polymers, alkyl acrylate copolymers, alkyl methacrylate polymers, alkyl methacrylate copolymers, styrene / alkyl acrylate copolymers, Styrene / alkyl methacrylate copolymer, vinyl acetate polymer, vinyl pyrrolidone / styrene copolymer, vinyl acetate / alkyl acrylate copolymer, alkyl methacrylate / vinyl acetate copolymer, acrylic acid / alkyl acrylate copolymer Examples thereof include acrylic acid / alkyl methacrylate copolymer, methacrylic acid / alkyl acrylate copolymer, methacrylic acid / alkyl methacrylate copolymer, alkyl dimethicone acrylate copolymer, and organopolysiloxane polymer. it can. In this specification, an alkyl (meth) acrylate (co) polymer refers to a polymer or copolymer containing an alkyl acrylate or alkyl methacrylate as a monomer constituent unit, and a vinyl acetate (co) polymer. The term “polymer” or “copolymer” includes vinyl acetate as a monomer constituent unit.

  These water-insoluble polymers are preferably used as an aqueous dispersion (polymer emulsion) because dispersibility is improved and a uniform film can be formed. Here, an aqueous dispersion of a water-insoluble polymer is a system in which polymer fine particles are stably dispersed in an aqueous solvent, and exists in a liquid or a natural world obtained by polymerizing a monomer emulsified with a surfactant. Contains milky sap. Moreover, a polymer can be obtained by a general polymerization method such as an emulsion polymerization method, a core-shell polymerization method, or a radical polymerization method. In addition, an aqueous solvent means the solvent which has water as a main component and may contain hydrophilic components, such as a lower alcohol and a polyhydric alcohol.

  Examples of polymer emulsions in which one or more of the above polymers or copolymers are dispersed in an aqueous solvent include, for example, alkyl acrylate copolymer emulsions, alkyl acrylate polymer emulsions, alkyl methacrylate copolymer Combined emulsion, alkyl methacrylate polymer emulsion, acrylic acid / alkyl acrylate copolymer emulsion, acrylic acid / alkyl methacrylate copolymer emulsion, methacrylic acid / alkyl acrylate copolymer emulsion, methacrylic acid / alkyl methacrylate copolymer Polymer emulsion, alkyl acrylate / styrene copolymer emulsion, alkyl methacrylate / styrene copolymer emulsion, vinyl acetate polymer emulsion, vinyl acetate-containing copolymer emulsion, vinyl pyrrole Down-styrene copolymer emulsion, an organopolysiloxane polymer emulsion and the like, can be used one or two or more of these. Among these water-insoluble polymers, alkyl (meth) acrylate (co) polymers and vinyl acetate (co) polymers are preferable in terms of adhesion and a flexible film.

  As a commercial item of the component (A) used in the present invention, as an alkyl acrylate copolymer emulsion, ACURYN33A (made by Rohm and Haas), Yodosol GH800, Yodosol GH810, Yodosol GH41F (made by NSC Japan), acetic acid As vinyl / alkyl acrylate copolymer, Vinizole 2140L (Daido Kasei Kogyo Co., Ltd.) and as vinyl acetate polymer emulsion, Vinibran GV-5651 (Nisshin Chemical Co., Ltd.), vinyl pyrrolidone / vinyl acetate copolymer As PVP / VAE-735 (manufactured by ISP), Daitosol 5000SJ (manufactured by Daito Kasei Kogyo Co., Ltd.) as an acrylic acid / methacrylic acid / ethyl hexyl acrylate copolymer, and ANTARA430 (ISP) as a vinylpyrrolidone / styrene copolymer. Ltd.) and the like.

  The component (B) glycosyl trehalose (hereinafter referred to as “component (B)”) of the present invention is a saccharide derivative of trehalose having a trehalose structure at the end of the saccharide. Glucosyl trehalose, maltosyl trehalose, maltotriosyl Examples include trehalose.

  This component (B) is disclosed in Patent Documents 2 and 3. Moreover, this thing can also be mix | blended as a commercially available aqueous solution, and as an example of a commercial item, the mixture of glycosyl trehalose (47 mass%), hydrolyzed hydrogenated starch (27 mass%), and water (26 mass%). Examples include TORNALE (registered trademark, manufactured by Hayashibara), which is an aqueous solution.

  The adhesive adhesive of the present invention is prepared by mixing the component (A) and the component (B) according to a conventional method and blending a solvent or the like as necessary. The contents of component (A) and component (B) at this time are not particularly limited, but component (A) is contained in the entire composition in terms of adhesiveness of the tack, speed of drying, and non-stickiness. ~ 60% by mass (hereinafter referred to as "%"), component (B) is 5 to 70%, more preferably component (A) is 2 to 50%, and component (B) is 10 to 60%. is there.

  Moreover, you may add coloring agents, such as a component (C) mentioned later, in order to color this sticking adhesive. In this case, the content of the colorant such as component (C) is not particularly limited, but is preferably 0.01 to 50%, more preferably 0.05 to 25%. Furthermore, in order to improve the dispersibility of the component, a nonionic surfactant having a component (D) of HLB 10 or higher may be added to the adhesive adhesive. In this case, the content of the component (D) is not particularly limited, but is preferably about 0.01 to 15%, more preferably 0.05 to 10%.

  As an example of a preferable method for preparing the adhesive agent of the present invention, a component such as a container that can block air after the components (A) and (B) and other components are mixed uniformly, if necessary, such as a sealed container, is used. Can be used.

  Water can be blended in the adhesive adhesive of the present invention, and the content thereof is not particularly limited, but is preferably 20 to 75%, more preferably 25 to 65% in terms of usability and expression of effects. .

  Furthermore, the cosmetic adhesive of the present invention can be blended with any cosmetic ingredient as long as the adhesive strength and drying performance are not hindered. Examples of such cosmetic components include powder components other than colorants, oily components, aqueous components, surfactants, ultraviolet absorbers, humectants, polyvinyl alcohol, polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymers, and the like. Water-soluble film-forming resins, anti-fading agents, antioxidants, antifoaming agents, cosmetic ingredients, preservatives, and fragrances.

  The eyeliner-attached tack adhesive that is the second embodiment of the present invention contains a colorant as the component (C) in addition to the component (A) and the component (B).

  If the colorant of the component (C) used in the eyeliner-attached tack adhesive of the present invention is a colorant usually used in cosmetics, the shape such as a spherical shape, a plate shape, a spindle shape, a needle shape, There are no particular limitations on the particle size of fumes, fine particles, pigment grades, or the like, or the particle structure of a variety of materials, such as a variety of materials, and the like, and inorganic pigments, organic pigments, glitter pigments, metals and the like can be used. . The color tone of the colorant is preferably a dark color system based on black, such as black, dark blue, dark red, dark purple, dark brown, and dark green, which is common as an eyeliner.

  Specific colorants include colored inorganic pigments such as carbon black, iron oxide, chromium oxide, chromium hydroxide, bitumen, ultramarine blue, and bengara, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, and barium sulfate, mica Titanium, bismuth oxychloride, organic pigment-treated mica titanium, titanium dioxide-coated mica, titanium dioxide-coated synthetic phlogopite, titanium dioxide-coated bismuth oxychloride, iron oxide mica titanium, bituminized mica titanium, carmine-treated mica titanium, fish scale foil, dioxide Luminous pigments such as titanium coated glass powder, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder, etc., red 201, red 202, Red 20 No., Red No. 226, Red No. 228, Orange No. 203, Orange No. 204, Blue No. 404, Yellow No. 401 and other organic pigment powders, Red No. 3, Red No. 104, Red No. 106, Orange No. 205, Yellow No. 4 No. 5, Yellow No. 5, Green No. 3, Blue No. 1, etc., organic pigment powder such as zirconium, barium or aluminum lake, or metal powder such as aluminum powder, gold powder, silver powder, etc., fine titanium oxide coated mica titanium, fine particles Examples include zinc oxide-coated mica titanium, barium sulfate-coated mica titanium, titanium oxide-containing silicon dioxide, zinc oxide-containing silicon dioxide, and other composite powders. One or two or more types may be used as necessary. Can do.

  These use one or more of fluorine compounds, silicone compounds, metal soap, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, waxes, surfactants, etc. And may be surface-treated.

  Among the above-mentioned colorants having a dark color tone, carbon black, bitumen, ultramarine, black iron oxide, bengara, organic pigment-treated mica titanium, iron oxide mica titanium, bituminized mica titanium, carmine-treated mica titanium , Red 201, red 202, red 205, red 226, red 228, blue 404, red 3, red 104, red 106, green 3, blue 1, etc. zirconium, barium As an example of a more preferable one, carbon black can be mentioned, and it is possible to efficiently impart black to a film formed after applying the eyeliner / attachment adhesive to the skin. it can.

  The carbon black used as a more preferred colorant in the present invention is not particularly limited, but those that can be obtained by incomplete combustion or thermal decomposition of natural gas or liquid hydrocarbon can be preferably used. From the viewpoint of black color development and smooth use feeling during coating, those having a particle size of 0.01 to 15 μm are preferable, and those of 0.02 to 10 μm are more preferable. As a commercially available product of this carbon black, midnight black (manufactured by Geotech Co., Ltd.) and the like are known, and these can be used, and one or more can be used.

  In the eyeliner-attaching tack adhesive that is the second aspect of the present invention, a nonionic surfactant of HLB 10 or higher can be further contained as the component (D).

  Component (D) HLB10 or higher nonionic surfactant (hereinafter sometimes referred to as “nonionic active agent”) is mainly dispersed uniformly in eyeliner-attached tack adhesive. It is something to be made.

  The component (D) may be any nonionic active agent that has an HLB value of 10 or more and is usually used in cosmetics. Preferred examples thereof include polyglycerin fatty acid esters and sucrose fatty acids. Ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbit fatty acid ester, polyethylene glycol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene Examples include hydrogenated castor oil, polyoxyethylene fatty acid ethanolamide, polyoxyalkylene-modified silicone, and polyoxyalkylene alkyl co-modified silicone.

  Specific examples of the component (D) include polyoxyethylene glyceryl fatty acid esters such as polyoxyethylene (15) glyceryl monostearate and polyoxyethylene (15) glyceryl monooleate; hexaglyceryl monomyristate, monolauric acid Polyglycerin fatty acid esters such as decaglyceryl and decaglyceryl monostearate; poly such as polyoxyethylene (20) sorbitan monooleate, polyoxyethylene (20) sorbitan monostearate, polyoxyethylene (20) sorbitan trioleate Oxyethylene sorbitan fatty acid ester; polyoxyethylene (20) hydrogenated castor oil, polyoxyethylene (60) hydrogenated castor oil, and other polyoxyethylene hydrogenated castor oil; polyoxyethylene (15 Polyoxyethylene cholesteryl ethers such as cholesteryl ether and polyoxyethylene (30) cholesteryl ether; polyoxyethylene phytosteryl ethers such as polyoxyethylene (10) phytosteryl ether and polyoxyethylene (20) phytosteryl ether; polyethylene monolaurate Polyethylene glycol fatty acid esters such as glycol (10), polyethylene glycol monostearate (25), polyethylene glycol monostearate (40), polyethylene glycol monostearate (55); polyoxyethylene (9) lauryl ether, polyoxyethylene (30) behenyl ether, polyoxyethylene (7) cetyl ether, polyoxyethylene (20) stearyl ether, etc. Polyoxyethylene alkyl ethers of polyoxyethylene (20) polyoxypropylene (4) cetyl ether, polyoxyethylene (30) polyoxypropylene (6) polyoxyethylene polyoxypropylene alkyl ethers such as tetradecyl ether Can do.

  In the present invention, the component (D) HLB 10 or more nonionic surfactant can be used singly or in combination of two or more. Among these, polyoxyethylene alkyl ether, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene hydrogenated castor oil, polyethylene glycol fatty acid ester and the like are preferable from the viewpoint of dispersibility. The HLB value is preferably 10 or more and 20 or less, and more preferably 15 or more and 18 or less from the viewpoint of dispersibility.

  The eyeliner-attached tack adhesive of the present invention is prepared by mixing and homogenizing the above components (A) to (C) and, if necessary, the component (D) according to a conventional method. The content of each component is not particularly limited, but the range in which the effect can be sufficiently exhibited is 1 to 60% for component (A), 5 to 70% for component (B), and more preferably component (A). Is 2 to 50%, and component (B) is 10 to 60%. Moreover, the compounding quantity of a component (C) is although it does not specifically limit, 1-50% is preferable and 5-25% is more preferable. Within this range, satisfactory results can be obtained in terms of color development and no bleeding with water such as tears or sebum.

  Further, the content when the component (D) is blended is not particularly limited, but is preferably about 0.01 to 15%, more preferably 0.05 from the viewpoint of dispersibility and stability over time. -10%.

  As described above, the eyeliner-attached tack adhesive of the present invention may be mixed by homogenizing the components (A) to (C) and the component (D) as necessary. For example, the following method is mentioned. That is, first, the component (D) is added to the component (C) and sufficiently dispersed and mixed, and then the mixture is added to the components (A) and (B) and mixed uniformly. According to this method, the colorant component (C) is preferable because it can be uniformly dispersed in the eyeliner-attaching tack adhesive and can be applied neatly.

  The eyeliner-attaching tack adhesive of the present invention can be blended with known components as long as the effects and effects thereof are not impaired. Examples of such known components include water components such as powder components, oil components, aqueous components, surfactants, UV absorbers, humectants, polyvinyl alcohol, polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymers, and the like. Examples thereof include an adhesive film-forming resin, an anti-fading agent, an antioxidant, an antifoaming agent, a cosmetic ingredient, an antiseptic, and a fragrance.

  Of these, as a powder, other than the component (C), as long as it is usually used as a raw material for cosmetics, a plate shape, a spindle shape, a needle shape, a fume shape, a particle size such as a fine particle class, a porous shape, etc. There is no particular limitation on the particle structure such as quality and non-porous, inorganic powders, aluminum oxide, cerium oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, aluminum silicate, magnesium silicate, aluminum silicate Inorganic powders such as magnesium, mica, synthetic mica, synthetic sericite, sericite, talc, kaolin, silica, silicon carbide and boron nitride, organic powders such as magnesium stearate, zinc stearate, N-acyl lysine and nylon 1 type or 2 or more types can be used. These powders may be used singly or in combination of two or more, and the surface treatment may be performed with an oil agent treatment, a silicone compound treatment, a water-soluble polymer treatment or the like.

  In addition, the oil component acts as a base material and an emollient component, and is a hydrocarbon regardless of the origin of animal oil, vegetable oil, synthetic oil, etc., or the properties of solid oil, semi-solid oil, liquid oil, volatile oil, etc. , Oils and fats, waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine-based oils, lanolin derivatives, oily gelling agents and the like can be used. Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, polyisobutylene, polybutene, paraffin wax, ceresin wax, microcrystalline wax, ethylene propylene copolymer, molasses, montan wax, Fischer-Trops wax, olive oil, castor oil Oils such as jojoba oil, mink oil, macadamian nut oil, beeswax, carnauba wax, candelilla wax, wax such as gay wax, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, Glyceryl trioctanoate, polyglyceryl diisostearate, diglyceryl triisostearate, glyceryl tribehenate, pentaerythritol ester of rosin acid, dioctane Neopentyl glycol, cholesrelol fatty acid ester, esters such as N-lauroyl-L-glutamic acid di (cholesteryl, behenyl, octyldodecyl), stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid, 12 -Fatty acids such as hydroxystearic acid, higher alcohols such as stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol, low polymerization dimethylpolysiloxane, high polymerization dimethylpolysiloxane, methylphenylpolysiloxane , Decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, polyether-modified polysiloxane, polyoxyalkylene alkylmethylpolysiloxane Silicones such as methylpolysiloxane copolymer, alkoxy-modified polysiloxane, cross-linked organopolysiloxane, and fluorine-modified polysiloxane, fluorine-based oils such as perfluorodecane, perfluorooctane, and perfluoropolyether, lanolin, lanolin acetate Lanolin derivatives such as lanolin fatty acid isopropyl, lanolin alcohol, dextrin fatty acid ester, sucrose fatty acid ester, starch fatty acid ester, 12-hydroxyaluminum stearate, calcium stearate and other oily gelling agents.

  Further, the aqueous component acts as a moisturizing and powder dispersing agent. In addition to water, any component that is soluble in water may be used. For example, alcohols such as ethyl alcohol and isopropyl alcohol, propylene Glycols such as glycol, 1,3-butylene glycol, dipropylene glycol, polyethylene glycol, glycerols such as glycerin, diglycerin, polyglycerin, saccharides such as sorbitol, maltitol, sucrose, starch sugar, lactitol, guar gum, Sodium chondroitin sulfate, sodium hyaluronate, gum arabic, sodium alginate, carrageenan, methylcellulose, hydroxyethylcellulose, carboxymethylcellulose, carboxyvinyl polymer, polyvinyl alcohol, polyvinyl Pyrrolidone, water-soluble polymers such as sodium polyacrylate, sodium chloride, magnesium chloride, salts such as sodium lactate, aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender, plant extracts such as rose, and the like.

  Furthermore, the surfactant is used for the purpose of improving the dispersibility of the powder and adjusting the feel, and is generally used for cosmetics and is any surfactant that is safe for the human body. Nonionic surfactants other than the component (D), anionic surfactants, cationic surfactants, amphoteric surfactants and the like can be used. Among these, examples of the anionic surfactant include inorganic and organic salts of fatty acids such as stearic acid and lauric acid, alkylbenzene sulfate, alkyl sulfonate, α-olefin sulfonate, dialkyl sulfosuccinate, α- Sulfonated fatty acid salt, acylmethyl taurine salt, N-methyl-N-alkyl taurine salt, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkylphenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, poly Examples thereof include oxyethylene alkylphenyl ether phosphate, N-acyl amino acid salt, N-acyl-N-alkyl amino acid salt, o-alkyl substituted malate, alkyl sulfosuccinate and the like. Examples of the cationic surfactant include alkylamine salts, polyamines and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, and cyclic quaternary ammonium salts. Furthermore, as the amphoteric surfactant, amino acid type or betaine type carboxylic acid type, sulfate ester type, sulfonic acid type, phosphate ester type can be used, for example, N, N-dimethyl-N-alkyl-N. -Carboxymethyl ammonium betaine, N, N-dialkylaminoalkylene carboxylic acid, N, N, N-trialkyl-N-sulfoalkylene ammonium betaine, N, N-dialkyl-N, N-bis (polyoxyethylene sulfate) Examples include ammonium betaine, 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine, and lecithin.

  Still further, examples of the ultraviolet absorber include benzophenone-based, PABA-based, cinnamic acid-based, salicylic acid-based, 4-tert-butyl-4′-methoxydibenzoylmethane, oxybenzone, and the like. Mucopolysaccharide, collagen, elastin, keratin, etc., as antioxidants, for example α-tocopherol, ascorbic acid, etc., as beauty ingredients, for example vitamins, anti-inflammatory agents, herbal medicines, etc., as preservatives, for example, paraoxy Benzoic acid ester, phenoxyethanol and the like can be mentioned.

  There are no particular limitations on the dosage form of the tacking adhesive or eyeliner tacking adhesive of the present invention described above, but water-based, solubilized or oil-in-water systems in which water constitutes the outer phase are usable and drying properties. Is preferable. The liquid is preferably in the form of a liquid or gel, and a brush, pen, chip, or the like is preferably used as the coating means. However, if the discharge port is narrow, it can be applied directly.

  Furthermore, what is filled in a tube-type container, an adhesive is filled inside the application body, the adhesive is guided to the tip of a brush, pen, tip, etc., and applied by an application part, so-called brush pen type or Alternatively, it may be filled in a container with an application body, and applied by applying an adhesive to the application body such as a brush, pen, or chip.

  The method of using the adhesive eyelid adhesive or eyeliner adhesive adhesive of the present invention is not particularly limited. For example, it can be applied directly to the eyelid and then attached to the eyelid. It is possible to apply directly and attach a spear, or to apply to both.

  EXAMPLES Next, although an Example is given and this invention is demonstrated in more detail, this invention is not restrict | limited at all by these Examples.

Example 1
Adhesive adhesive:
According to the composition shown in Table 1 below and the following production method, the adhesive articles of the inventive products 1 to 6 and the comparative products 1 and 2 were prepared. With respect to these adhesive adhesives, the following four evaluation items were tested. The results are also shown in Table 1.

注１：ＹＯＤＯＳＯＬ ＧＨ８００Ｆ（アクゾノーベル社製；
固形分４５％）
注２：ビニゾール２１４０Ｌ（大同化成工業社製；固形分４３％）
注３：ビニブランＧＶ−５６５１（日信化学工業社製；固形分３６％）
注４：ＴＯＲＮＡＬＥ（林原社製；グリコシルトレハロース含量
４７％）

Note 1: YODOSOL GH800F (manufactured by Akzo Nobel;
(45% solids)
Note 2: Vinizole 2140L (Daido Kasei Kogyo Co., Ltd .; solid content 43%)
Note 3: Vinibrand GV-5651 (manufactured by Nissin Chemical Industry Co., Ltd .; solid content 36%)
Note 4: TORNALE (produced by Hayashibara; glycosyl trehalose content)
47%)

<Production method>
(1) Mix 1-5 and disperse uniformly.

<Evaluation test>
(Evaluation item)
A. Adhesiveness of spears b. Drying speed c. Adhesiveness of sputum over time d. No sticky makeup film

(Evaluation method)
About each sample, the use test by 20 expert panels was done by each item of said i-ni. The use test is performed by applying each sample to the spear and attaching the spear to the eyelid near the base of the spear. The attachment of the spear (item a) is 30 seconds after attaching the spear. Whether the wrinkle is attached when the is released, the speed of drying (item b) is whether it dries after 1 minute of application to form a film, the adhesion of the wrinkle over time (item c) is It was evaluated whether or not the wrinkles had adhered after 10 hours of application, and the absence of stickiness of the decorative film (item d) whether or not the film was sticky after 3 minutes of application.

  About each item, each panel person evaluated in seven grades by the following absolute evaluation criteria, gave a score, the average value was calculated from the total score of all the panels, and judged by the following four-step judgment criteria.

(Evaluation criteria)
Absolute Evaluation Criteria (Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad
1: Bad 0: Very bad

4-step criteria (judgment): (average score)
AA: Exceeding 5 points / very good A: Exceeding 3.5 points and 5 points or less / good B: Exceeding 1 point and 3.5 points or less / slightly defective C: 1 point or less / defect

<Evaluation results>
Inventive products 1 to 3 were evaluated as AA in all items, and were good results. Inventive product 4 was a little inferior in adhesion to the spear due to its low amount of glycosyl trehalose, but it was rated as A and was a good result. Inventive product 5 had a low water-insoluble film-forming high molecular weight, so the speed of drying and the non-stickiness of the decorative film were slightly inferior, but the evaluation was A, which was a good result. Invention 6 was evaluated as AA in all items, and was a good result.

  On the other hand, Comparative Product 1 does not contain a water-insoluble film-forming polymer and does not form a film. Therefore, the C product is evaluated as having a quick drying time and the stickiness of the decorative film is not satisfactory. It was. Since Comparative Product 2 was not formulated with glycosyl trehalose, it was evaluated as “C” based on the adhesiveness of the tack and the adhesiveness of the tack over time, and satisfactory quality was not obtained.

Example 2
Eyeliner combination adhesive:
According to the composition shown in Table 2 below and the following production method, the eyeliner combination adhesives for inventive products 7 to 12 and comparative products 3 and 4 were prepared. About these eyeliner combined use adhesive adhesives, the test of 4 items of Example 1 and 3 newly added items were tested. In the test, each sample was applied on the eyelid near the base of the eyelids so that the eyeliner was applied, and the eyelids were attached to the portions. The results are also shown in Table 2.

注１〜４：前と同じ
注５：ＨＬＢ値 １７

Note 1-4: Same as before Note 5: HLB value 17

<Production method>
(1) Disperse 1-4.
(2) Mix 5-9, add (1) and disperse uniformly.

<Evaluation test>
(Additional evaluation items)
E. Persistence of cosmetic film f. Smudge. Ease of writing eyelines

(Additional item evaluation method)
Whether the makeup film persists (item e) after 10 hours of application, whether the makeup film persists after 10 hours of application, whether the blurring (item f) does not bleed after 10 hours of application, eyeline writing ease (item g) Evaluated whether it was easy to draw as an eyeliner. The evaluation criteria and determination are the same as in Example 1.

<Evaluation results>
Inventive products 7 to 9 were evaluated as AA in all items and were good results. Inventive product 10 has a little glycosyl trehalose, so the adhesion of the spices is slightly inferior, but it is A evaluation and is a good result. Inventive product 11 has a low water-insoluble film-forming high molecular weight, so it dries quickly, has no stickiness of the decorative film, and is slightly inferior in blurring, but it was A and was a good result. Inventive product 12 was evaluated as AA in all items, and was a good result.

  On the other hand, Comparative Product 3 does not contain a water-insoluble film-forming polymer and does not form a film. Therefore, it has a satisfactory quality as it has a C rating for speed of drying, non-stickiness of the decorative film, and difficulty of bleeding. Was not obtained. Since Comparative Product 4 was not formulated with glycosyl trehalose, it was evaluated as C based on the adhesiveness of the sputum and the adhesiveness of the sputum over time, and satisfactory quality could not be obtained.

Example 3
By using the following components and production method, an eyeliner-attached eyelid adhesive with a coating color of wrinkle was prepared.

(Component) (%)
1. Polyoxyethylene (20) hardened castor oil ^{Note 6} 2
2. 1,3-butylene glycol 10
3. Ultramarine 1
4). Conger 0.5
5. Black iron oxide 0.8
6). Alkyl acrylate / vinyl acetate copolymer emulsion ^{Note 1} 60
7). Glycosyl trehalose / hydrogenated starch decomposition product aqueous solution ^{Note 4} 20
8). Residual amount of water 9. Titanium oxide coated synthetic phlogopite ^{* 7} 1
Note 1: Same as before Note 4: Same as before Note 6: HLB value 10.5
Note 7: HELIOS R100S (S) (Topy Industries, Ltd.)
Average particle size 105μm

( Production method )
A. Components (1) to (5) are dispersed uniformly.
B. A and components (6) to (9) are mixed uniformly.

  Apply the eyeliner-attached eyelid adhesive obtained in this example to the eyelid and the eyelid. Adhesion of the eyelash, speed of drying, persistence of the cosmetic film, adhesion of the eyelash over time, blurring Evaluation of the hardness, the non-stickiness of the decorative film, and the ease of writing of the eyeline were all excellent.

Example 4
By using the following components and production method, an eyeliner combined use adhesive with a brown coating color was prepared.

(Component) (%)
1. Polyethylene glycol monostearate (40) ^{Note 8} 2
2. 1,3-butylene glycol 10
3. Red 202 0.5
4). Yellow 4 0.5
5. Yellow iron oxide 0.8
6). Red iron oxide 0.5
7). Vinyl acetate polymer emulsion ^{Note 3} 40
8). Glycosyl trehalose / hydrogenated starch degradation product aqueous solution ^{Note 4} 40
9. Residual amount of water 10. Titanium oxide coated mica ^{Note 9} 1
Note 3: Same as before Note 4: Same as before Note 8: HLB value 17.5
Note 9: FLAMENCO ULTRA SPARKLE 4500 (BASF
(Made by company) Average particle size 50μm

( Production method )
A. Components (1) to (6) are uniformly dispersed.
B. A and components (7) to (10) are mixed uniformly.

  Applying the eyeliner adhesive adhesive obtained in this example to the eyelid, the adhesiveness of the eyelashes, the speed of drying, the persistence of the cosmetic film, the adhesiveness of the eyelashes over time, the blurring resistance, the makeup As a result of evaluating the non-stickiness of the film and the ease of writing the eyeline, all of them were excellent.

Example 5
A transparent eyeliner-attaching tack adhesive capable of providing glitter after coating was prepared by the following components and production method.

(Component) (%)
1. Polyethylene glycol monostearate (55) ^{Note 10} 2
2. 1,3-butylene glycol 10
3. Alkyl acrylate polymer emulsion ^{Note 1} 20
4). Glycosyl trehalose / hydrogenated starch degradation product aqueous solution ^{Note 4} 60
5. Residual amount of water (PET / AL) Laminate ^{Note 11} 2
7). Titanium oxide-coated glass powder ^{* 12} 1
Note 1: Same as before Note 4: Same as before
Note 10: HLB value 18
Note 11: KFS Glitter Silver 0.15mm (made by Katani Sangyo Co., Ltd.)
Average particle size of 150μm
Note 12: Microglass Metashine MT1080RS (Nippon Sheet Glass Co., Ltd.)
Average particle size 80μm

( Production method )
A. Ingredients (1) to (7) are mixed uniformly.

  Applying the eyeliner adhesive adhesive obtained in this example to the eyelid, the adhesiveness of the adhesive, the speed of drying, the persistence of the cosmetic film, the adhesiveness of the adhesive film over time, the stickiness of the cosmetic film Evaluation of the absence and ease of writing of the eyeline was excellent in all cases.

Example 6
An eyeliner combined use adhesive with a green coating color was prepared by the following components and production method.

(Component) (%)
1. Polyoxyethylene (20) sorbitan monooleate ^{Note 13} 1
2. Polyoxyethylene cetyl ether ^{Note 5} 1
3. 1,3-butylene glycol 10
4). Yellow iron oxide 2
5. Conger 1
6). Alkyl acrylate / vinyl acetate copolymer emulsion ^{Note 1} 30
7). Glycosyl trehalose / hydrogenated starch degradation product aqueous solution ^{Note 4} 40
8). Residual amount of water 9. Titanium oxide coated synthetic phlogopite ^{* 7} 1
Note 1: Same as before Note 4: Same as before Note 5: Same as before Note 7: Same as before Note 13: HLB value 15

( Production method )
A. Components (1) to (5) are dispersed uniformly.
B. A and components (6) to (9) are mixed uniformly.

  Apply the eyeliner-attached eyelid adhesive obtained in this example to the eyelid and the eyelid. Adhesion of the eyelash, speed of drying, persistence of the cosmetic film, adhesion of the eyelash over time, blurring Evaluation of the hardness, the non-stickiness of the decorative film, and the ease of writing of the eyeline were all excellent.

  The adhesive wrinkle adhesive of the present invention obtained as described above has a high adhesiveness of the adhesive wrinkle and can provide a flexible decorative film, and has a low feeling of burden that the eyelid does not peel off even if the eyelid moves. It is.

In addition, the eyeliner combined adhesive agent of the present invention, in which a coloring agent is blended with the adhesive agent, is fast drying and can be colored on the application part, so that the application part has the same cosmetic effect as the eyeliner. Can make the makeup of the eyes easier.

Claims (9)

The following components (A) and (B);
(A) 1-60% by mass of water-insoluble film-forming polymer (B) 5 to 70% by mass of glycosyl trehalose The adhesive adhesive according to claim 1, wherein the water-insoluble film-forming polymer of component (A) is a polymer or copolymer containing alkyl (meth) acrylate as a monomer constituent unit. The adhesive adhesive according to claim 1, wherein the water-insoluble film-forming polymer of component (A) is a polymer or copolymer containing vinyl acetate as a monomer constituent unit. The following components (A) to (C);
(A) 5 to 60% by mass of water-insoluble film-forming polymer (B) 20 to 70% by mass of glycosyl trehalose (C) 1 to 50% by mass of coloring agent睫 Adhesive. The eyeliner-attaching tack adhesive according to claim 4, wherein the water-insoluble film-forming polymer of component (A) is a polymer or copolymer containing alkyl (meth) acrylate as a monomer constituent unit. The eyeliner-attaching tack adhesive according to claim 4, wherein the water-insoluble film-forming polymer of the component (A) is a polymer or copolymer containing vinyl acetate as a monomer constituent unit. The eyeliner-attaching tack adhesive according to any one of claims 4 to 6 , wherein the colorant of component (C) contains carbon black. The eyeliner-attaching tack adhesive according to any one of claims 4 to 7 , further comprising 0.1 to 10% by mass of a nonionic surfactant having an HLB of 10 or more as component (D). The eyeliner-attaching tack adhesive according to claim 8 , wherein the nonionic surfactant having an HLB of 10 or more as the component (D) is polyoxyethylene alkyl ether.