JP6275397B2 - Porous laminate, adsorption buffer material, and adsorption method - Google Patents

Description

  The present invention relates to a porous laminate, an adsorption buffer material including the porous laminate, and an adsorption method using the adsorption buffer material.

  One of the means for fixing or transporting thin-film, plate- or film-like objects such as liquid crystal glass plates and multilayer ceramic capacitor green sheets. Alternatively, there is a method of sucking and conveying. The adsorption stage is provided with a porous resin body having air permeability as an adsorption buffer material on the adsorption surface. Thereby, it can prevent that a damage | wound and a contact trace arise in a to-be-adsorbed member. As such a resin porous body, a sintered molded body obtained by sintering and molding polyethylene powder may be used from the viewpoints of rigidity and cushioning properties.

  In recent years, liquid crystal and multilayer ceramic capacitors have been rapidly reduced in size and performance, and glass plates and ceramic green sheets, which are raw materials, have been reduced in thickness. For this reason, it is necessary to perform very precise adsorption fixation or adsorption conveyance. Therefore, excellent surface smoothness, strength rigidity, and the like are also demanded as an adsorption buffer material to be attached to the adsorption stage by vacuum suction.

  As such a porous sheet having excellent surface smoothness, a porous sheet provided with a particle layer including plastic fine particles on at least one surface has been proposed (for example, see Patent Document 1). In addition, as a suction fixing plate that has excellent strength and rigidity and prevents the deformation of the sucked material, a suction fixing plate in which a mesh screen is attached to a metal plate or a resin plate having suction holes has been proposed (for example, see Patent Document 2). .)

JP 2006-26981 A Japanese Patent Laid-Open No. 9-57561

  In precision parts such as liquid crystals and ceramic capacitors, the entry of foreign substances is extremely limited. Therefore, it is required not to generate foreign matter in various parts used in the manufacturing process. There is also a demand for a sintered body of resin powder used as an adsorption buffer material used during adsorption fixation and adsorption conveyance so that raw material resin powder does not fall off.

  However, the porous sheet disclosed in Patent Document 1 has not been studied for dropping off the resin powder. In addition, the film suction holding jig disclosed in Patent Document 2 has not been studied for surface smoothness.

  Furthermore, the adsorption buffer material is also required to have no partial unevenness in surface smoothness, and a technique for solving all of these is required.

  The present invention has been made in view of the above problems, and has a porous smooth body having excellent surface smoothness, little variation in the surface smoothness, and no dropping of raw material particles, An object of the present invention is to provide an adsorption buffer material including a porous laminate and an adsorption method using the adsorption buffer material.

  As a result of intensive studies to solve the above-mentioned problems, the inventors of the present invention have a porous laminate in which a sheet having air permeability and excellent surface smoothness is laminated on at least one surface of the resin porous body. The present inventors have found that the above problems can be solved, and have completed the present invention.

That is, the present invention is as follows.
[1]
Having a porous resin body (a),
A sheet (b) having air permeability and a surface roughness (Ra) of 0.1 to 20 μm is laminated on at least one surface of the resin porous body (a),
The sheet (b) is either a woven fabric, a nonwoven fabric, or a pore sheet,
The surface roughness (Ra) of the sheet (b) is 2.0 to 12.9 μm.
Porous laminate.
[2]
The porous product according to [1], wherein the resin porous body (a) contains a polyolefin resin.
Layered body.
[3]
The porous laminate according to [2], wherein the polyolefin-based resin contains polyethylene.
[4]
The porous laminate according to [3] above, wherein the polyethylene has a density of 890 to 970 kg / m ³ .
[5]
The porous laminate according to any one of [1] to [4], wherein the porous resin body (a) includes a sintered compact of resin powder.
[6]
The porous laminate according to any one of [1] to [5], wherein the sheet (b) has a surface roughness (Ra) of 2.0 to 10 μm.
[7]
The porous laminate according to any one of [1] to [6] above, having a thickness of 0.06 to 15 mm.
[8]
The flexural modulus is 30 to 3000 MPa,
The porous laminate according to any one of [1] to [7] above, wherein the air flow rate is 0.3 to ³⁰ cm ³ / cm ² / s.
[9]
An adsorption buffer material comprising the porous laminate according to any one of [1] to [8] above.
[10]
An adsorption method for adsorbing a thin film using the adsorption buffer material according to the item [9].
[11]
The adsorption method according to [10], wherein the thin film is a ceramic green sheet.

  According to the present invention, a porous laminate having excellent surface smoothness, little variation in the surface smoothness, and no dropping of raw material particles, an adsorption buffer material comprising the porous laminate, And an adsorption method using the adsorption buffer material can be provided.

  Hereinafter, a mode for carrying out the present invention (hereinafter referred to as “the present embodiment”) will be described in detail. The present invention is not limited to the following embodiment, and can be implemented with various modifications within the scope of the gist.

[Porous laminate]
The porous laminate according to this embodiment is
Having a porous resin body (a),
A sheet (b) having air permeability and having a surface roughness (Ra) of 0.1 to 20 μm is laminated on at least one surface of the porous resin body (a).

[Resin porous body (a)]
Although it does not specifically limit as resin which comprises the resin porous body (a), For example, a thermoplastic resin or a thermosetting resin is mentioned. The thermoplastic resin is not particularly limited. Specifically, polyolefin resin, polyester resin, polyarylate, liquid crystal polyester, polyvinyl chloride, polyvinyl alcohol, ethylene vinyl acetate, polystyrene, acrylonitrile-butadiene-styrene copolymer Examples include coalesced resin, acrylonitrile-styrene copolymer resin, polymethyl methacrylate, polyamide resin, polyacetal, polycarbonate, fluorine resin, polyether ether ketone, polyether sulfone, polyphenylene sulfide, and the like.

  In addition, the thermosetting resin is not particularly limited, and specific examples include phenol resin, urea resin, melamine resin, allyl resin, and epoxy resin.

  Among these, a thermoplastic resin is preferable from the viewpoints of formability and secondary processability. Furthermore, among thermoplastic resins, polyolefin resins represented by polyethylene and polypropylene are more preferable. When the resin porous body (a) contains a polyolefin-based resin, it becomes cheaper, has better chemical resistance and processability, and tends to have lower moisture absorption and water absorption. Such a polyolefin resin is not particularly limited, and specifically, an ethylene homopolymer such as polyethylene, or one or more of ethylene and propylene, butene-1, hexene-1, octene-1, etc. Copolymer of α-olefin, ethylene, vinyl acetate, acrylic acid, methacrylic acid, acrylic ester, methacrylic ester, etc., propylene homopolymer, and propylene, Examples thereof include copolymers with one or more α-olefins such as ethylene and butene-1.

  Among polyolefin resins, polyethylene is preferable. By using polyethylene, the cost becomes lower, the sintering molding becomes easier, the workability and chemical resistance after molding are excellent, and the hygroscopicity and water absorption of the material itself tend to be lower.

The density of polyethylene is preferably 890 to 970 kg / m ³ . From the viewpoint of imparting sufficient rigidity to the porous resin body (a), the lower limit of the density is preferably 890 kg / m ^3, more preferably 920 kg / m ^3, more preferably ^{930kg / m 3, 940kg / m} 3 Gayori Further preferred. From the viewpoint of handling ease, the upper limit of the density is preferably 970 kg / m ^3, more preferably 960 kg / m ^3. Here, the density of polyethylene can be obtained by measuring by the density gradient tube method (23 ° C.) in accordance with JIS K 7112: 1999.

The viscosity average molecular weight of polyethylene is preferably from 1,000 to 10,000,000, more preferably from 10,000 to 10,000,000, and even more preferably from 100,000 to 10,000,000. When the viscosity average molecular weight is within the above range, the flow of the resin, which is a factor that hinders the formation of pores during sintering molding, is reduced, and the fusing property between adjacent resin particles tends to be superior. A viscosity average molecular weight can be calculated | required by the method shown below, for example. First, polyethylene is dissolved in decalin (decahydronaphthalene) to prepare a plurality of solutions having different concentrations. The respective reduced viscosities (ηsp / C) of these solutions are determined in a thermostatic bath at 135 ° C. using an Ubbelohde viscometer. A linear expression of the concentration (C) and the reduced viscosity (ηsp / C) of the polymer is derived, and the intrinsic viscosity ([η]) extrapolated to the concentration 0 is obtained. From this intrinsic viscosity ([η]), the viscosity average molecular weight (Mv) can be determined according to the following formula.
Mv = 5.34 × 10 ⁴ × [η] ^1.49

  The porous resin body (a) may be a mixed raw material of polyethylene having different density and / or viscosity average molecular weight, or a mixed raw material of polyethylene and a raw material resin other than polyethylene.

  The resin porous body (a) preferably includes a sintered compact of resin powder. By including a sintered compact of the resin powder as described above, the rigidity and cushioning properties tend to be superior.

  A method for forming the resin porous body (a) is not particularly limited, and a known method can be used, and examples thereof include foam molding and sintering molding. In addition, for example, after forming a molded body with a resin melted together with extractable components, the extractable components can be extracted to form a porous body having continuous pores. Among these, sintering molding is performed by filling a mold with raw materials, putting it in a heating furnace maintained at a temperature above the melting point in a pressurized or non-pressurized state, and then cooling and molding from the mold. It is more preferable because a porous body having continuous pores can be formed by removing the body. When obtaining a sheet-like porous body, sintering molding in a mold, extrusion molding, a molding method in which raw material resin is deposited on an endless belt and then heated by heating, or a pore molded using the above molding method Means such as slicing or skiving the material are preferably used. In addition, the continuous pores referred to in the present embodiment refers to a product in which pores are continuous from one surface of the molded body to another surface. The pores may be straight or curved. Note that the pores may have uniform dimensions as a whole, or may be, for example, a surface layer and an inside, or a material in which the pore size is changed between one surface layer and another surface layer.

  When the porous resin body (a) is obtained by sintering, a raw material resin is used in a powder form. In this case, in the porous resin body (a), a sheet having sufficient air permeability but having (b) air permeability and a surface roughness (Ra) of 0.1 to 20 μm at the time of suction under reduced pressure is a resin. From the viewpoint of making the pore diameter so as not to be sucked and bent inside the porous body (a), the average particle diameter of the raw material resin is preferably 30 μm to 1000 μm, more preferably 30 μm to 300 μm. 100 μm to 300 μm is more preferable, and 120 μm to 250 μm is even more preferable. The average particle diameter of the raw material resin is a particle diameter with a cumulative weight of 50%, that is, a median diameter. Using a laser diffraction particle size distribution measuring device (“SALD-2100” manufactured by Shimadzu Corporation), methanol is used. It can be measured as a dispersion medium.

  From the viewpoint that the resin porous body (a) is excellent in handleability, the thickness is preferably 0.05 to 10 mm, more preferably 0.05 to 3 mm, and further preferably 0.1 mm to 3 mm. 0.2 to 3 mm is even more preferable. The thickness (a) of the porous resin body here may be the thickness before the sheet (b) is laminated, or the thickness of the resin porous body (a) only after the sheet (b) is laminated. It may be measured. The thickness of only the resin porous body (a) after laminating the sheet (b) is obtained by cutting the porous laminated body along the thickness direction, and cutting the cut surface with an optical microscope (manufactured by Keyence Corporation, “Microscope”). VH-Z100UR ") can be used for observation.

[Bleeding sheet (b)]
In the porous laminate according to this embodiment, a sheet (b) having air permeability and a surface roughness (Ra) of 0.1 to 20 μm is laminated on at least one surface of the resin porous body (a). It is a thing. By using such a sheet (b), there is little partial variation in surface smoothness, it has excellent surface smoothness, and it is possible to further suppress the dropping of raw material particles from the resin porous body (a). it can.

  Here, “breathability” refers to the property that air passes from the high pressure surface side to the low pressure surface side (the property of allowing air to pass through) when there is a difference in air pressure between one side of the sheet and the opposite side. ).

  Although it does not specifically limit as a sheet | seat (b), A woven fabric, a nonwoven fabric, a pore sheet | seat, sponge, a porous membrane is mentioned. Among these, any of a woven fabric, a nonwoven fabric, or a pore sheet is preferable. In general, it is known that a woven fabric, a non-woven fabric, or a pore sheet has a uniform thickness and a uniform opening. By using these as a sheet (b), a certain quality is maintained and surface smoothness is maintained. It is possible to obtain a porous laminate with less partial variation.

  “Woven fabric” refers to a woven fabric made by combining fibers with a background, or a knitted fabric in which fibers are knitted. The woven fabric can be obtained by a conventionally known method.

  “Nonwoven fabric” refers to a sheet obtained by laminating and superposing fibers without being woven together and bonding them by various methods. The method for producing the nonwoven fabric is not particularly limited, and examples thereof include a wet method, a spunlace method, a melt blow method, and an electrospinning method. Among non-woven fabrics, a long-fiber non-woven fabric having excellent wear resistance and high strength is preferred because there are no falling fibers.

  The “pore sheet” refers to a sheet produced by punching holes using a punch or the like in a thin film, plate, or film sheet. The pores of the pore sheet are not particularly limited, and may be various shapes such as a polygon as well as a circle. The arrangement may also be various arrangements such as a lattice shape and a staggered shape.

  Among these, woven fabrics and pore sheets are widely used as sieve screens. Furthermore, it is widely known that fabrics made by combining fibers among woven fabrics are also used for screen printing plates.

  The material used for the sheet (b) in the case of a woven fabric or a non-woven fabric is not particularly limited. For example, polyamide-based fibers such as nylon 6, nylon 66, copolymer polyamide; polyethylene terephthalate, polybutylene terephthalate, polytrimethylene Polyester fibers such as terephthalate and copolyester; Polyolefin fibers such as polyethylene, polypropylene, and copolypropylene; Fluorine fibers such as polytetrafluoroethylene, polyvinylidin fluoride, and perfluoropolymer; Polyurethane fibers such as polyether urethane Vinylon fiber, polyvinyl chloride fiber, polyvinylidene chloride fiber, acrylic fiber, polyimide fiber, polyetherimide fiber, polyarylate fiber, polyphenylene sulfide fiber, polyvinyl Synthetic fibers typified by lucor fiber, polycarbonate fiber, polylactic acid fiber, polyoxide fiber, polyethylene oxide fiber, polystyrene fiber, polyethylene glycol derivative fiber, polyphosphazene fiber, etc .; cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, Semi-synthetic fibers represented by promixes, etc .; inorganic fibers represented by glass fibers, carbon fibers, etc .; recycled fibers represented by rayon, cupra, etc .; represented by cotton, cotton, asbestos, wool, hemp, silk, etc. Natural fibers; or metal fibers. These may be used alone or in combination of two or more. Moreover, the sheath part may be made of polyethylene, polypropylene, copolyester or the like, and the core part may be a composite fiber made of polypropylene, polyester or the like. Furthermore, the crossing portions of the fibers may be joined by melting or may be joined by an adhesive substance.

  In addition, the material used for the sheet (b) in the case of the pore sheet is not particularly limited, but for example, polyethylene, polypropylene, ethylene vinyl acetate copolymer, ethylene-vinyl alcohol copolymer, ethylene-methacrylic acid copolymer. Polyolefin resin represented by polymer, cyclic olefin copolymer, polymethylpentene, etc .; ethylene-tetrafluoroethylene copolymer, tetrafluoroethylene-hexafluoropropylene copolymer, ethylene-chlorotrifluoroethylene copolymer Fluorine resins typified by coalescence, perfluoroalkoxy fluorine, polytetrafluoroethylene, polychlorotrifluoroethylene, polyvinylidene fluoride, polyvinyl fluoride, etc .; polyamide resins such as nylon 6, nylon 66, copolymer polyamide; Sauce Polyester resins such as polyester, polybutylene terephthalate, polytrimethylene terephthalate, and copolyester; ionomer, polyurethane, cellophane, polylactic acid, triacetyl cellulose, polyether ether ketone, polyimide, polyether imide, polyarylate, polyacetal, modified Examples include polyphenylene ether, polyvinyl chloride, polyvinylidene chloride, polyphenylene sulfide, polyvinyl alcohol, polyvinyl butyral, polycarbonate, polystyrene, polyacrylonitrile and the like. These may be used alone or in combination of two or more.

  The surface roughness (Ra) of the sheet (b) according to this embodiment is 0.1 to 20 μm, preferably 0.1 to 10 μm, more preferably 0.1 to 5 μm, and further 0.1 to 3 μm. preferable. When the surface roughness (Ra) is within the above range, the surface smoothness is less likely to be partially varied, and the surface smoothness is more excellent. Surface roughness (Ra) was measured using a stylus type surface roughness meter (“Handy Surf E-35B” manufactured by Tokyo Seimitsu Co., Ltd.), tip diameter R: 5 μm, speed: 0.6 mm / s, measurement length: It can be obtained by measurement under the conditions of 12.5 mm, cut-off value λc: 2.5 mm, number of measurements: n = 5. More specifically, the surface roughness (Ra) can be measured by the method described in the examples.

  The surface roughness (Ra) of the sheet can be adjusted by the fiber diameter and the number of meshes of fibers used in the case of a woven fabric, the pore diameter in the case of a nonwoven fabric, and the shape and size of the pores in the case of a pore sheet. it can. Although it depends on the material used, Ra can be made 20 μm or less by setting the number of meshes to 150 mesh or more in the case of plain woven fabric. Moreover, if it is a nonwoven fabric, surface roughness (Ra) can be 20 micrometers or less by making the average pore diameter which can be measured with a palm porometer into 100 micrometers or less. In the case of a woven fabric made by combining fibers with the background, the number of meshes is preferably 150 mesh or more, more preferably 250 mesh or more, and further preferably 420 mesh or more. When the number of meshes is 150 mesh or more, the surface smoothness tends to be superior. Furthermore, the sheet | seat (b) which performed the calendar process which improves surface smoothness, and the shrink process which makes an opening part small for the textile fabric of 420 mesh or more is also preferable. By using the sheet (b) subjected to such processing, the surface smoothness tends to be further improved. Here, the “number of meshes” is the number of yarns per inch.

  On the other hand, if the sheet is a pore sheet, the surface roughness (Ra) can be reduced to 20 μm or less by setting the opening diameter to 100 μm or less, for example, if the thickness is 0.05 mm, depending on the thickness of the sheet.

  The thickness of the sheet (b) is preferably 0.001 to 5 mm, more preferably 0.01 to 2 mm, further preferably 0.01 to 0.2 mm, and still more preferably 0.02 to 0.1 mm. When the thickness is within the above range, it tends to be easier to handle and more cost effective. When measuring the thickness of the sheet (b) in the porous laminate, the porous laminate is cut along the thickness direction, and the cut surface is optical microscope ("Microscope VH-Z100UR" manufactured by Keyence Corporation). It can measure by observing using ").

  The sheet (b) is very effective in the industry from the viewpoint of the stability of the area and thickness of the opening, since it is easy to produce a sheet having different porosity even in the same opening area.

[Method for producing porous laminate]
In order to laminate the resin porous body (a) and the sheet (b), they may be bonded using an adhesive or the like, or may be fused by heat.

  In order to ensure air permeability, it is preferable that the two materials are partially bonded and / or fused by heat. Such a laminating method is not particularly limited, but includes, for example, a spray-type pressure-sensitive adhesive, a method of forming an adhesive surface such as a dot or fiber using an adhesive, a gravure coater, a roll coater, a screen printing machine, or the like. Method of forming adhesive surfaces in the form of dots, meshes, streaks, etc., method of pressurizing and fusing through a thermoplastic resin of particle shape or net shape, ultrasonic welder machine, ultrasonic sewing machine Or the like, or a method of fusing the surface of the porous resin body (a) in contact with the sheet (b) by slightly melting it. Among these, a method of forming a dotted or fibrous adhesive surface using a spray adhesive is preferable because it is simple.

  Although it does not specifically limit as a spray-type adhesive and an adhesive agent, For example, polyester-type resin, acrylic resin, polyamide-type resin, polyimide-type resin, alpha-olefin resin, polyolefin-type resin, urethane type resin, ether-type cellulose, for example , Nitrocellulose, polyvinyl acetate resin, polystyrene resin, polyvinyl alcohol resin, polyvinyl pyrrolidone resin, polyvinyl butyral resin, polybenzimidazole resin, polymethacrylate resin, melamine resin, urea resin, Resorcinol resin, ethylene vinyl acetate resin, vinyl acetate resin, epoxy resin, vinyl chloride resin, chloroprene rubber resin, styrene butadiene rubber resin, nitrile rubber resin, cyanoacrylate resin, aqueous polymer, Nate resin, silicone resin, modified silicone resin, phenol resin, fluorine resin, or ethylene vinyl acetate resin hot melt, reactive hot melt, polyamide resin hot melt, polyurethane hot melt, polyolefin hot melt, etc. Can be adopted.

  In order to laminate the porous resin body (a) and the sheet (b), a woven fabric with an adhesive can also be used. A known method (for example, described in JP-A No. 2009-167275) can be used as a production method in which the adhesive layer is provided only on the linear portion of the woven fabric.

  The thickness of the porous laminate according to this embodiment is preferably 0.06 to 15 mm, more preferably 0.06 to 5 mm, still more preferably 0.1 to 3 mm, and still more preferably 0.2 to 3 mm. When the thickness is within the above range, it tends to be superior in terms of ease of handling and cost. Here, the “thickness” is measured using a micrometer having a reading of 1/1000 mm (“MDC-SB” manufactured by Mitutoyo Corporation).

  The bending elastic modulus of the porous laminate according to this embodiment is preferably 30 to 3000 MPa, more preferably 200 to 3000 MPa, further preferably 200 to 1000 MPa, and still more preferably 200 to 800 MPa. When the bending elastic modulus is within the above range, the rigidity as an adsorption buffer material and an appropriate cushioning property tend to be excellent. Here, the “flexural modulus” is measured according to JIS K 7171: 1994 under the conditions of a test speed of 5 mm / min and a support point distance of 30 mm.

Aeration rate of the porous laminate according to the present embodiment is preferably 0.3~30cm ³ / cm ² / s, more preferably ^{0.3~10cm 3 / cm 2 / s,} 1~10cm 3 / cm 2 / S is more preferable. When the air flow rate is within the above range, the air permeability as an adsorption buffer material tends to be superior. Here, the “aeration amount” is measured using a permeability measuring device (“FX3360PORTAIR” manufactured by TEXTEST) under the conditions of a measurement range of 20 cm ² and a measurement differential pressure of 125 Pa.

[Adsorption buffer material]
The adsorption buffer material according to the present embodiment includes the porous laminate. The porous laminate according to the present embodiment can be suitably used as an adsorption buffer material because it has excellent surface smoothness, there is little partial variation in the surface smoothness, and there is no loss of raw material particles. Adsorption buffer is one of the means for fixing or transporting thin-film, plate- or film-like objects such as liquid crystal glass plates and multilayer ceramic capacitor sheets, and is a suction stage using vacuum suction. There is a method of suction fixation or suction conveyance, which is attached to the suction surface of the suction stage.

  As the adsorption buffer material, the porous laminate may be used as it is. In addition, the method of processing as an adsorption buffer material is not particularly limited, but for example, when attached to the adsorption stage, if necessary, the adsorption stage may be subjected to adhesive processing, or the porous laminate may be set to a predetermined size. The method of cutting is mentioned.

[Adsorption method]
The adsorption method according to the present embodiment includes a step of adsorbing a thin film using an adsorption buffer material. More specifically, an adsorption buffer material is attached to the adsorption surface of the adsorption stage, and a thin film, plate, or film object can be fixed on the adsorption buffer material and conveyed. The adsorption buffer material can be attached by vacuum suction or the like.

  Here, the thin film to be fixed or conveyed is not particularly limited, and examples thereof include a ceramic green sheet. Ceramic green sheets are usually ceramic powder, binders (acrylic resin, butyral resin, etc.), plasticizers (phthalates, glycols, adipic acid, phosphates) and organic solvents (toluene, MEK, acetone). Etc.) is prepared, and this ceramic paint is applied onto a carrier sheet by the doctor blade method or the like and dried by heating.

  Next, the present embodiment will be described more specifically with reference to examples and comparative examples. However, the present embodiment is not limited to the following examples unless it exceeds the gist.

Each physical property of each material was measured as follows.
[Measurement method of surface roughness (Ra) average and surface roughness (Ra) variation]
Surface roughness (Ra) was measured using a stylus type surface roughness meter (“Handy Surf E-35B” manufactured by Tokyo Seimitsu Co., Ltd.), tip diameter R: 5 μm, speed: 0.6 mm / s, measurement. Measurement was performed under the conditions of length: 12.5 mm and cut-off value λc: 2.5 mm. The measurement position was measured at a total of five locations, one at the center of the surface of the object to be measured and one at the center of the four equally divided surfaces when the surface was equally divided into four as much as possible.
The average surface roughness (Ra) was determined as the average value of the above five measurements.
The surface roughness (Ra) variation is a difference between the maximum value and the minimum value of the above five measurements, and was evaluated based on the following criteria.
○: The difference between the maximum value and the minimum value is 10% or less of the average value.
X: The difference between the maximum value and the minimum value exceeds 10% of the average value.

[Powder removal]
The measurement of powder fall-off property is performed using a vibrator (“Vibrated Repacker VP-15D” manufactured by Shinko Electric Co., Ltd.) on a sheet of 200 mm × 200 mm size on paper of the color opposite to the color of the raw material particles. After applying vibration for a minute, it was visually confirmed whether or not there were raw material particles on the opposite color paper, and evaluated based on the following criteria.
A: There was almost no dropout of the raw material resin.
○: Dropping of the raw material resin was extremely small.
X: There were many dropouts of the raw material resin.

[Bending elastic modulus]
The flexural modulus was measured according to JIS K 7171: 1994 under the conditions of a test speed of 5 mm / min and a support point distance of 30 mm.

[Air flow rate]
The air flow rate was measured using an air permeability measuring device (“FX3360PORTAIR” manufactured by TEXTEST) under the conditions of a measurement range of 20 cm ² and a measurement differential pressure of 125 Pa.

[thickness]
The thickness of the porous laminate in the present embodiment was measured using a micrometer having a reading of 1/1000 mm (“MDC-SB” manufactured by Mitutoyo Corporation). In addition, the measured numerical value was measured to the third decimal place, and the value of the third decimal place was rounded off.

  The thickness of the laminated resin porous body (a) and sheet (b) is determined by cutting the laminated porous laminate along the thickness direction, and cutting the cut surface with an optical microscope (Keyence Corporation). It was measured by observing using “Microscope VH-Z100UR”. In addition, the measured numerical value was measured to the third decimal place, and the value of the third decimal place was rounded off.

[Example 1]
High-density polyethylene powder Sun Fine (trademark) SH801 (made by Asahi Kasei Chemicals Corporation, density 955 kg / m ³ ) is deposited on a metal flat plate with a thickness of 2.1 mm or more to provide a clearance of 2.1 mm from the metal flat plate. By passing through the scraped portion, the material uniformly deposited with a thickness of 2.1 mm was put into a heating furnace set at 180 ° C., allowed to stand for 10 minutes, then removed from the heating furnace, and at room temperature. By cooling, a sintered compact having a thickness of 2.0 mm was obtained as a porous resin body (a). A polyolefin hot melt adhesive was spray-coated on the porous resin body in a fibrous form at 20 g / m ² using a hot melt applicator set at 160 ° C. As the sheet (b), a woven fabric (warp / weft: polyethylene terephthalate monofilament) L-screen165-027 / 420PW (manufactured by NBC Meshtec Co., Ltd.) is used, and porous by laminating this on the resin porous body (a). A layered product was obtained. Table 1 shows the characteristics of the porous laminate.

[Example 2]
As a sheet (b), instead of L-screen165-027 / 420PW (manufactured by NBC Meshtec Co., Ltd.), a fabric obtained by calendering L-screen165-027 / 420PW (manufactured by NBC Meshtec Co., Ltd.) is used. A porous laminate was obtained in the same manner as in Example 1 except that it was used. Evaluation similar to Example 1 was performed, and the measurement results are shown in Table 1.

[Example 3]
A sheet (b) is made of woven fabric (warp / weft: polyamide monofilament) NY10-HC (manufactured by Sefar) instead of L-screen165-027 / 420PW (manufactured by NBC Meshtec Co., Ltd.). A porous laminate was obtained in the same manner as in Example 1. Evaluation similar to Example 1 was performed, and the measurement results are shown in Table 1.

[Example 4]
As the sheet (b), a woven fabric (warp / weft: stainless steel) BS-400 / 25 (manufactured by Asada Mesh Co., Ltd.) was used instead of L-screen165-027 / 420PW (manufactured by NBC Meshtec Co., Ltd.). Except for this, a porous laminate was obtained in the same manner as in Example 1. Evaluation similar to Example 1 was performed, and the measurement results are shown in Table 1.

[Example 5]
As the sheet (b), a woven fabric (warp / weft: stainless steel) BS-200 / 40 (manufactured by Asada Mesh Co., Ltd.) was used instead of L-screen165-027 / 420PW (manufactured by NBC Meshtec Co., Ltd.). Except for this, a porous laminate was obtained in the same manner as in Example 1. Evaluation similar to Example 1 was performed, and the measurement results are shown in Table 1.

[Comparative Example 1]
Using a high-density polyethylene powder Sun Fine (trademark) SH801 (manufactured by Asahi Kasei Chemicals Corporation), a sintered molded body having a thickness of 2 mm was obtained as a porous resin body in the same manner as in Example 1. The same characteristics as in Example 1 were evaluated using the resin porous material as it was without laminating the sheet (b). The results are shown in Table 1.

[Comparative Example 2]
The same operation and evaluation as in Comparative Example 1 were performed except that ultra high molecular weight polyethylene powder XM-220 (Mitsui Chemicals, Inc.) was used as the porous resin body (a). The results are shown in Table 1.

[Comparative Example 3]
Example 1 using a woven fabric (warp / weft: polyethylene terephthalate monofilament) L-screen165-027 / 420PW (manufactured by NBC Meshtec Co., Ltd.) as the sheet (b) without laminating the porous resin body (a). The same characteristics were evaluated. The results are shown in Table 1.

  From the results shown in Table 1, in the porous resin body having air permeability, the porous laminate formed by substantially integrating a sheet having air permeability and excellent surface smoothness on at least one side has excellent surface smoothness, It has been found that it has rigidity and air permeability, there is little partial variation in the surface smoothness, and there is little dropout of raw material particles.

  The porous laminate of the present invention has industrial applicability in a method for fixing or transporting thin-film, plate-like, or film-like objects such as glass plates for liquid crystals and green sheets for multilayer ceramic capacitors. Have.

Claims (11)

Having a porous resin body (a),
A sheet (b) having air permeability and a surface roughness (Ra) of 0.1 to 20 μm is laminated on at least one surface of the resin porous body (a),
Said sheet (b) is a woven, nonwoven, or Der either pores sheet is,
The surface roughness (Ra) of the sheet (b) is 2.0 to 12.9 μm .
Porous laminate.   The porous laminate according to claim 1, wherein the resin porous body (a) contains a polyolefin-based resin.   The porous laminate according to claim 2, wherein the polyolefin-based resin contains polyethylene. The porous laminate according to claim ³ , wherein the polyethylene has a density of 890 to 970 kg / m ³ .   The porous laminated body of any one of Claims 1-4 in which the said resin porous body (a) contains the sintered compact of a resin powder. The porous laminate according to any one of claims 1 to 5, wherein the sheet (b) has a surface roughness (Ra) of 2.0 to 10 µm. The porous laminate according to any one of claims 1 to 6 , wherein the thickness is 0.06 to 15 mm. The flexural modulus is 30 to 3000 MPa,
Aeration is 0.3~30cm ³ / cm ² / s, the porous laminate according to any one of claims 1-7. The adsorption buffer material containing the porous laminated body of any one of Claims 1-8 . An adsorption method for adsorbing a thin film using the adsorption buffer material according to claim 9 . Thin film is a ceramic green sheet, the adsorption process of claim 1 0.