JP6263820B1 - Eating and drinking composition - Google Patents

Eating and drinking composition Download PDF

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JP6263820B1
JP6263820B1 JP2017168923A JP2017168923A JP6263820B1 JP 6263820 B1 JP6263820 B1 JP 6263820B1 JP 2017168923 A JP2017168923 A JP 2017168923A JP 2017168923 A JP2017168923 A JP 2017168923A JP 6263820 B1 JP6263820 B1 JP 6263820B1
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宏哉 高橋
宏哉 高橋
高垣 欣也
欣也 高垣
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Toyo Shinyaku Co Ltd
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Abstract

【課題】イミダゾールジペプチドによる運動能力維持作用や抗疲労作用を有する飲食用組成物を製造する場合に、イミダゾールジペプチドの呈味が改善された嗜好性の高い飲食用組成物を提供することを目的とする。【解決手段】本発明に係る飲食用組成物は、(A)イミダゾールジペプチドと、(B)大麦茎葉を含有する。【選択図】図1An object of the present invention is to provide a highly-preferred eating and drinking composition in which the taste of imidazole dipeptide is improved when producing an eating and drinking composition having an athletic ability maintaining action and an anti-fatigue action by imidazole dipeptide. To do. The composition for eating and drinking according to the present invention contains (A) imidazole dipeptide and (B) barley foliage. [Selection] Figure 1

Description

本発明は、飲食用組成物、及び、イミダゾールジペプチドの呈味改善用組成物、に関する。 The present invention relates to a composition for eating and drinking and a composition for improving the taste of imidazole dipeptide.

イミダゾールジペプチドは、鶏肉や豚肉、牛肉等の畜肉類や、カツオ、マグロ等の魚介類に含まれるペプチド成分であり、アンセリン(β−アラニル−1−メチルヒスチジン)、カルノシン(β−アラニルヒスチジン)、バレニン(β−アラニル−3−メチルヒスチジン)などの総称である。これらのイミダゾールジペプチドは、運動能力の維持、抗疲労効果が確認されているほか、尿酸値抑制作用、活性酸素消去作用、血圧上昇抑制作用、抗炎症作用等の機能を有することが知られている。 Imidazole dipeptide is a peptide component contained in livestock meat such as chicken, pork, and beef, and seafood such as skipjack, tuna, etc., anserine (β-alanyl-1-methylhistidine), carnosine (β-alanylhistidine) , Valenine (β-alanyl-3-methylhistidine). These imidazole dipeptides have been confirmed to maintain exercise ability and have anti-fatigue effects, and also have functions such as uric acid level inhibitory action, active oxygen scavenging action, blood pressure increase inhibitory action, and anti-inflammatory action. .

イミダゾールジペプチドで運動能力の維持や抗疲労効果を得る場合、ある程度の量を摂取する必要があるが(例えば、非特許文献1又は2)、イミダゾールジペプチドは、独特の臭いがあることや後味が悪いという欠点があった(例えば、特許文献1又は2)。しかしながら、イミダゾールジペプチドの独特の臭いや風味を改善する具体的な研究は十分になされていなかった。一方、消費者の自然派志向の高まりを受けて、人工添加物を用いずに、自然由来の素材を用いた飲食用組成物の開発が求められていた。 In order to maintain exercise ability and obtain an anti-fatigue effect with imidazole dipeptide, it is necessary to ingest a certain amount (for example, Non-Patent Document 1 or 2), but imidazole dipeptide has a unique smell and poor aftertaste. (For example, Patent Document 1 or 2). However, specific studies for improving the unique odor and flavor of imidazole dipeptide have not been sufficiently conducted. On the other hand, in response to the increasing consumer orientation of naturalism, there has been a demand for the development of a composition for eating and drinking using materials derived from nature without using artificial additives.

特開2008−120754JP2008-120754 特開2002−173442JP 2002-173442 A

田中雅彰他 「CBEX−DR配合飲料の健常者における抗疲労効果」医薬と治療、vol.36 No.3 2008Masaaki Tanaka et al. “Anti-fatigue effect of CBEX-DR beverages in healthy subjects” Medicine and treatment, vol.36 No.3 2008 清水恵一郎他 「イミダゾールジペプチド配合飲料の日常的な作業のなかで疲労を自覚している健常者に対する継続摂取による有用性」医薬と治療、vol.37 No.3 2009Keiichiro Shimizu et al. “Usefulness of continuous intake of a drink containing imidazole dipeptide for healthy people who are aware of fatigue in daily work” Medicine and treatment, vol.37 No.3 2009

本発明は、イミダゾールジペプチドを含有する飲食用組成物において、その独特の臭いや風味を改善することを目的としてなされたものである。 This invention is made | formed for the purpose of improving the peculiar smell and flavor in the food-drinking composition containing an imidazole dipeptide.

本出願人は、上記課題を鑑みて鋭意検討を行った結果、自然素材である大麦茎葉が優れたイミダゾールジペプチドの呈味改善効果を有することを見出し、本発明に至った。 As a result of intensive studies in view of the above-mentioned problems, the present applicant has found that barley stalks and leaves, which are natural materials, have an excellent taste-improving effect of imidazole dipeptide, leading to the present invention.

本発明の概要は、以下の通りである。
<1>(A)イミダゾールジペプチドと、(B)大麦茎葉を含有する飲食用組成物。
<2>さらに、(C)オリゴ糖を含有する<1>に記載の飲食用組成物。
<3>(B)大麦茎葉を含有する、イミダゾールジペプチドの呈味改善用組成物。
<4>さらに、(C)オリゴ糖を含有する<3>に記載のイミダゾールジペプチドの呈味改善用組成物。
<5>(C)オリゴ糖が消化性オリゴ糖及び難消化性オリゴ糖から選ばれる少なくとも1種である、<2>又は<4>のいずれかに記載の組成物。
The outline of the present invention is as follows.
<1> A edible composition containing (A) imidazole dipeptide and (B) barley stalks and leaves.
<2> The dietary composition according to <1>, further comprising (C) an oligosaccharide.
<3> (B) A composition for improving taste of imidazole dipeptide, comprising barley foliage.
<4> The composition for improving taste of imidazole dipeptide according to <3>, further comprising (C) an oligosaccharide.
<5> (C) The composition according to any one of <2> or <4>, wherein the oligosaccharide is at least one selected from a digestible oligosaccharide and an indigestible oligosaccharide.

本発明のイミダゾールジペプチドを含有する飲食用組成物は、大麦茎葉を配合することにより、その臭い、不快な酸味、不快な塩味、生臭い味、苦味、キレ、舌触り、粉っぽさ、口当たり、のどごし、後味が良好となるため、嗜好性の高い飲食用組成物を得ることができる。また、大麦茎葉に加えてオリゴ糖を配合することにより、さらに嗜好性の高い飲食用組成物を得ることができる。 The composition for food and drink containing the imidazole dipeptide of the present invention contains barley stalks and leaves, so that its odor, unpleasant acidity, unpleasant salty taste, raw odor, bitterness, sharpness, texture, texture, mouthfeel, throat texture Since the aftertaste is good, a highly edible composition for eating and drinking can be obtained. Moreover, the composition for eating and drinking with higher palatability can be obtained by mix | blending an oligosaccharide in addition to a barley foliage.

比較例1、実施例1〜11の官能評価結果を表す図である。It is a figure showing the sensory evaluation result of the comparative example 1 and Examples 1-11.

以下、本発明の組成物について説明する。なお、本発明は、下記の実施の形態に限定されるものではない。 Hereinafter, the composition of the present invention will be described. In addition, this invention is not limited to the following embodiment.

(A)イミダゾールジペプチド
本発明で用いられるイミダゾールジペプチドは、鶏肉や豚肉、牛肉等の畜肉類や、カツオ、マグロ等の魚介類に含まれるペプチド成分であり、アンセリン、カルノシン、バレニンなどの総称である。これらイミダゾールジペプチドは、アンセリン、カルノシン、バレニンのいずれか1種であってもよく、2種以上の混合物であってもよい。本発明で用いられるイミダゾールジペプチドの製造方法は特に限定されず、鳥肉(例えば、ニワトリなど)、畜肉(例えば、ウシ、ブタ等)や魚肉(例えば、カツオ、マグロ等)等から、水抽出、熱水抽出、アルコール抽出、超臨界抽出等の方法で抽出して得られるエキス(抽出物)やその精製物、加工物(例えば、乾燥粉末(以下、エキスの乾燥粉末のことを「エキス末」ともいう))として製造することが可能であり、また、市販のものを利用することも可能である。イミダゾールジペプチドは精製物である必要はなく、チキンエキスや魚介エキスなどの、イミダゾールジペプチド含有量を高めた状態のエキスを使用しても良い。本発明で用いられるイミダゾールジペプチドは、好ましくは鶏肉等から抽出し、必要に応じて酵素処理などを行い、脱塩、脱色、濃縮、乾燥工程等を経て、イミダゾールジペプチドを5%以上、好ましくは10%以上含有するチキンエキスである。
(A) Imidazole dipeptide The imidazole dipeptide used in the present invention is a peptide component contained in livestock meat such as chicken, pork and beef, and seafood such as skipjack and tuna, and is a generic term for anserine, carnosine, and valenin. . These imidazole dipeptides may be any one of anserine, carnosine, and valenin, or may be a mixture of two or more. The method for producing the imidazole dipeptide used in the present invention is not particularly limited, and water extraction from chicken (for example, chicken), livestock (for example, cow, pig), fish (for example, skipjack, tuna, etc.), Extracts (extracts) obtained by extraction by hot water extraction, alcohol extraction, supercritical extraction, and the like, as well as purified products and processed products thereof (for example, dry powders (hereinafter referred to as “extract powder”) Also, it is possible to manufacture a commercially available product. The imidazole dipeptide does not need to be a purified product, and an extract with an increased imidazole dipeptide content, such as a chicken extract or a seafood extract, may be used. The imidazole dipeptide used in the present invention is preferably extracted from chicken and the like, subjected to enzyme treatment as necessary, and subjected to desalting, decolorization, concentration, drying steps, etc., and the imidazole dipeptide is 5% or more, preferably 10 % Chicken extract.

イミダゾールジペプチドのエキスを得る場合、その抽出溶媒は特に限定はされないが、例えば、水、アルコール(例えば、メタノール、エタノール、n−プロパノール、n−ブタノールなど)、アセトン、酢酸エチルなどが挙げられる。また、その乾燥粉末を得る場合は、例えば減圧乾燥や噴霧乾燥等、当業者が通常用いる方法によりエキスの溶媒を除去することで得ることができる。 When obtaining an extract of imidazole dipeptide, the extraction solvent is not particularly limited, and examples thereof include water, alcohol (for example, methanol, ethanol, n-propanol, n-butanol, etc.), acetone, ethyl acetate and the like. Moreover, when obtaining the dry powder, it can obtain by removing the solvent of an extract by the method normally used by those skilled in the art, such as reduced pressure drying and spray drying.

本発明においては、イミダゾールジペプチドのエキス、エキス末を用いることが好ましく、加工性や安定性の観点から、エキス末を用いることがより好ましい。 In the present invention, it is preferable to use an extract of imidazole dipeptide and extract powder, and it is more preferable to use extract powder from the viewpoint of processability and stability.

本発明の組成物に配合されるイミダゾールジペプチドの含有量としては、特に制限はなく、目的や形状、使用対象等の様々な条件に応じて、広範囲でその含有量を適宜設定できる。例えば、0.0001〜20質量%、好ましくは0.001〜10質量%、より好ましくは0.01〜5質量%の範囲で選択される。 There is no restriction | limiting in particular as content of the imidazole dipeptide mix | blended with the composition of this invention, According to various conditions, such as an objective, a shape, and a use object, the content can be suitably set in a wide range. For example, it is selected in the range of 0.0001 to 20% by mass, preferably 0.001 to 10% by mass, more preferably 0.01 to 5% by mass.

(B)大麦茎葉
本発明で用いられる大麦茎葉とは、大麦(学名 Hordeum vulgare)から得られる茎及び/又は葉のことを言う。使用できる大麦としては、二条大麦、六条大麦、裸大麦などが挙げられ、これらは1種又は2種以上を組み合わせて用いることができる。大麦の茎葉は、成熟期前、すなわち、分けつ開始期から出穂前に収穫されたもの(大麦若葉)であることが好ましい。
(B) Barley Stover The barley stover used in the present invention refers to a stem and / or leaf obtained from barley (scientific name: Hordeum vulgare). Examples of barley that can be used include two-row barley, six-row barley, and bare barley. These can be used alone or in combination of two or more. The barley stalks and leaves are preferably harvested before the maturity period, that is, before the heading from the start of the splitting (barley young leaves).

本発明で用いられる大麦茎葉としては、粉砕物及びその粉末(粉砕末)、細片化物及びその粉末(細片化末)、搾汁及びその粉末(搾汁末)、エキス(抽出物)及びその粉末(エキス末)などが挙げられる。なお、本願明細書で「粉末」と言う場合は、乾燥粉末、粉砕末、細片化末、搾汁末、エキス末を含むものである。本発明に用いられる大麦茎葉の粉砕末の製造方法としては特に限定されないが、例えば、大麦の茎葉を切断した後、ブランチング処理を行い、次いで乾燥し、その後粉砕する方法が挙げられる。また、大麦茎葉の搾汁末の製造方法としては、特に限定されないが、例えば、大麦の茎葉又はその細片化物を圧搾、遠心又はろ過によって搾汁し、粗固形分を除去することにより搾汁を得る方法があげられる。搾汁は、必要に応じて濃縮してもよいし、凍結乾燥や熱風乾燥、噴霧乾燥などの処理を行い、乾燥粉末(搾汁末)とすることもできる。大麦茎葉のエキス(抽出物)を得る場合、その抽出溶媒は特に限定はされないが、例えば、水、アルコール(例えば、メタノール、エタノール、n−プロパノール、n−ブタノールなど)、アセトンなどの溶媒が挙げられ、好ましくは、水および/またはエタノールなどを使用することができる。また、その乾燥粉末を得る場合は、例えば減圧乾燥や噴霧乾燥等、当業者が通常用いる方法によりエキスの溶媒を除去することで得ることができる。 As barley stalks and leaves used in the present invention, a pulverized product and its powder (pulverized powder), a fragmented product and its powder (milled powder), squeezed and its powder (squeezed powder), an extract (extract) and The powder (extract powder) etc. are mentioned. In the present specification, the term “powder” includes dry powder, pulverized powder, fragmented powder, squeezed powder, and extract powder. Although it does not specifically limit as a manufacturing method of the pulverized powder of barley foliage used for this invention, For example, after cutting barley foliage, a blanching process is performed, Then, the method of drying and crushing after that is mentioned. Moreover, it is not specifically limited as a manufacturing method of the squeezed powder of barley stalks and leaves. The method of obtaining is mentioned. The squeezed juice may be concentrated as necessary, or may be processed into freeze-dried powder (squeezed powder) by subjecting it to freeze-drying, hot-air drying, spray drying or the like. When obtaining an extract (extract) of barley stalks and leaves, the extraction solvent is not particularly limited, and examples thereof include solvents such as water, alcohol (eg, methanol, ethanol, n-propanol, n-butanol, etc.), acetone and the like. Preferably, water and / or ethanol can be used. Moreover, when obtaining the dry powder, it can obtain by removing the solvent of an extract by the method normally used by those skilled in the art, such as reduced pressure drying and spray drying.

本発明においては、加工性や安定性の点から、大麦茎葉の粉末が好ましく使用され、特に、粉砕末又は搾汁末を用いることが好ましい。本発明においては、市販品を使用してもよく、また当該分野で公知の方法で製造したものを使用することもできる。 In the present invention, barley foliage powder is preferably used from the viewpoint of processability and stability, and it is particularly preferable to use crushed powder or squeezed powder. In the present invention, commercially available products may be used, and those manufactured by methods known in the art can also be used.

本発明の組成物に配合される大麦茎葉の含有量としては、特に制限はなく、目的や形状、使用対象等の様々な条件に応じて、広範囲でその含有量を適宜設定できる。例えば、0.0001〜30質量%、好ましくは0.001〜20質量%、より好ましくは0.01〜10質量%の範囲で選択される。 There is no restriction | limiting in particular as content of the barley foliage mix | blended with the composition of this invention, According to various conditions, such as an objective, a shape, and a usage object, the content can be suitably set in a wide range. For example, it is selected in the range of 0.0001 to 30% by mass, preferably 0.001 to 20% by mass, more preferably 0.01 to 10% by mass.

(C)オリゴ糖
本発明で用いられるオリゴ糖は、少糖類を指し、2〜20個の糖がグリコシド結合してなる化合物を言う。本発明で使用できるオリゴ糖としては、例えば、乳果オリゴ糖、フラクトオリゴ糖、ガラクトオリゴ糖、キシロオリゴ糖、大豆オリゴ糖などの難消化性オリゴ糖、マルトオリゴ糖、イソマルトオリゴ糖、ラクツロース、ラクチトール、ラフィノースなどの消化性オリゴ糖を挙げることができるが、これらに限定されない。なお、本発明の効果を高める観点から、2種以上のオリゴ糖を組み合わせることが好ましく、難消化性オリゴ糖と消化性オリゴ糖とを組み合わせることがより好ましく、特に、フラクトオリゴ糖とイソマルトオリゴ糖とを組み合わせることが好ましい。難消化性オリゴ糖の生理機能として、ヒトの消化酵素で分解されずに、大腸に到達し、腸内ビフィズス菌の活性化や増殖に寄与し、腸内環境を改善する効果などがあり、消化性オリゴ糖の生理機能として、ヒトの消化酵素で分解され、胃や小腸で吸収されてエネルギー源となる効果がある。
(C) Oligosaccharide The oligosaccharide used in the present invention refers to a oligosaccharide, which is a compound formed by glycosidic bonding of 2 to 20 sugars. Examples of oligosaccharides that can be used in the present invention include indigestible oligosaccharides such as dairy oligosaccharides, fructooligosaccharides, galactooligosaccharides, xylo-oligosaccharides and soybean oligosaccharides, malto-oligosaccharides, isomalt-oligosaccharides, lactulose, lactitol, raffinose and the like. However, it is not limited to these digestible oligosaccharides. In addition, from the viewpoint of enhancing the effect of the present invention, it is preferable to combine two or more oligosaccharides, more preferably a combination of an indigestible oligosaccharide and a digestible oligosaccharide, and particularly a fructooligosaccharide and an isomaltoligosaccharide. Are preferably combined. Physiological functions of indigestible oligosaccharides have the effect of improving the intestinal environment by reaching the large intestine without being degraded by human digestive enzymes, contributing to the activation and growth of intestinal bifidobacteria, As a physiological function of the functional oligosaccharide, it is decomposed by human digestive enzymes and absorbed in the stomach and small intestine to serve as an energy source.

本発明においては、加工性や安定性の点から、粉末状のオリゴ糖が好ましく使用され、市販品を使用してもよく、また当該分野で公知の方法で製造したものを使用することもできる。 In the present invention, powdered oligosaccharides are preferably used from the viewpoint of processability and stability, and commercially available products may be used, or those produced by methods known in the art can also be used. .

本発明の組成物に配合されるオリゴ糖の含有量としては、特に制限はなく、目的や形状、使用対象等の様々な条件に応じて、広範囲でその含有量を適宜設定できる。例えば、0.0001〜30質量%、好ましくは0.001〜20質量%、より好ましくは0.01〜10質量%の範囲で選択される。本発明においてオリゴ糖を使用する場合は、1種のみを使用しても良いし、2種以上を用いることもできる。但し、オリゴ糖を2種以上含有する場合は、その総量である。 There is no restriction | limiting in particular as content of the oligosaccharide mix | blended with the composition of this invention, According to various conditions, such as an objective, a shape, and a use object, the content can be set suitably in a wide range. For example, it is selected in the range of 0.0001 to 30% by mass, preferably 0.001 to 20% by mass, more preferably 0.01 to 10% by mass. In the present invention, when an oligosaccharide is used, only one type may be used, or two or more types may be used. However, when it contains 2 or more types of oligosaccharides, it is the total amount.

本発明の組成物における、(A)イミダゾールジペプチドと(B)大麦茎葉の配合比(質量比)は特に限定されず、目的や使用対象等の条件に応じて適宜設定できるが、例えば、本発明の効果を高める観点から、(A):(B)=1:0.0001〜500、好ましくは1:0.0005〜100、より好ましくは1:0.01〜10の範囲で選択される。 The mixing ratio (mass ratio) of (A) imidazole dipeptide and (B) barley stalks and leaves in the composition of the present invention is not particularly limited and can be appropriately set according to the conditions such as the purpose and intended use. From the viewpoint of enhancing the effect of (A): (B) = 1: 0.0001 to 500, preferably 1: 0.0005 to 100, more preferably 1: 0.01 to 10.

本発明の組成物における、(A)イミダゾールジペプチド、(B)大麦茎葉、(C)オリゴ糖の配合比(質量比)は特に限定されず、目的や使用対象等の条件に応じて適宜設定できるが、例えば、本発明の効果を高める観点から、(A):(B)+(C)=1:0.001〜1000、好ましくは1:0.01〜100、より好ましくは1:0.1〜10の範囲で選択される。 The mixing ratio (mass ratio) of (A) imidazole dipeptide, (B) barley foliage, and (C) oligosaccharide in the composition of the present invention is not particularly limited, and can be set as appropriate according to the conditions such as the purpose and use target. However, from the viewpoint of enhancing the effects of the present invention, for example, (A) :( B) + (C) = 1: 0.001-1000, preferably 1: 0.01-100, more preferably 1: 0. It is selected in the range of 1-10.

本発明の組成物における、(B)大麦茎葉と(C)オリゴ糖の配合比(質量比)は特に限定されず、目的や使用対象等の条件に応じて適宜設定できるが、例えば、本発明の効果を高める観点から、(B):(C)=1:0.0001〜100、好ましくは1:0.001〜50、より好ましくは1:0.01〜10の範囲で選択される。 The blending ratio (mass ratio) of (B) barley foliage and (C) oligosaccharide in the composition of the present invention is not particularly limited and can be appropriately set according to the conditions such as the purpose and use object. For example, the present invention (B) :( C) = 1: 0.0001-100, preferably 1: 0.001-50, more preferably 1: 0.01-10.

本発明の組成物には、(A)イミダゾールジペプチド、(B)大麦茎葉、(C)オリゴ糖以外に、その他の成分を含有しても良い。前記のその他の成分としては、例えば、タンパク質、食物繊維、ミネラル類、植物又は植物加工品、藻類、乳酸菌等の微生物等を配合することができる。更に必要に応じて通常食品分野で用いられる、デキストリン、でんぷん等の糖類、甘味料、酸味料、天然着色料、ゲル化剤(増粘剤)、賦形剤、ビタミン類、栄養補助剤、結合剤、安定剤、乳化剤、食品添加物、調味料等を挙げることができる。これらその他の成分の含有量は、本発明の組成物の形態等に応じて適宜選択することができる。 The composition of the present invention may contain other components in addition to (A) imidazole dipeptide, (B) barley foliage, and (C) oligosaccharide. Examples of the other components include protein, dietary fiber, minerals, plants or processed plant products, algae, microorganisms such as lactic acid bacteria, and the like. In addition, sugars such as dextrin and starch, sweeteners, acidulants, natural coloring agents, gelling agents (thickening agents), excipients, vitamins, nutritional supplements, binding Agents, stabilizers, emulsifiers, food additives, seasonings and the like. The content of these other components can be appropriately selected according to the form of the composition of the present invention.

本発明の組成物の形態は特に限定されず、任意の形態とすることができる。具体的な形態としては、例えば、粉や顆粒、細粒等の粉末状、タブレット(チュアブル)状、球状、カプセル状、カプレット状、液状、ゼリー状等の形状が挙げられる。尚、カプセル状の組成物は、ソフトカプセル及びハードカプセルが含まれる。本発明の組成物は、液状やゼリー状が好ましく、特に、液体飲料(粉末状の飲料を水や牛乳などに溶かして飲用するものも含む)やゼリー飲料であることが、運動時などに摂取しやすく、また、吸収性にも優れる点からも好ましい。 The form of the composition of this invention is not specifically limited, It can be set as arbitrary forms. Specific forms include, for example, powders such as powders, granules, and fine particles, tablets (chewable), spheres, capsules, caplets, liquids, jelly, and the like. The capsule composition includes soft capsules and hard capsules. The composition of the present invention is preferably in a liquid or jelly form, and in particular, it is a liquid drink (including a drink in which a powdered drink is dissolved in water or milk) or a jelly drink. It is preferable also from the point which is easy to do and is excellent also in absorptivity.

本発明の組成物は、従来公知の方法により製造することができる。本発明の組成物を製造する際、使用する原料の形態は特に限定されず、組成物の形態に合わせて適宜選択し、使用することができる。例えば、粉や顆粒、細粒等の粉末状の組成物を得る場合、(A)イミダゾールジペプチド、(B)大麦茎葉及び(C)オリゴ糖は、これらをそのまま使用しても良いし、賦形剤等との混合物を使用しても良い。また、液状やゼリー状の組成物を得る場合は、水や果汁等の溶媒にあらかじめ溶解又は分散させたものを使用しても良い。 The composition of the present invention can be produced by a conventionally known method. When manufacturing the composition of this invention, the form of the raw material to be used is not specifically limited, According to the form of a composition, it can select suitably and can be used. For example, when obtaining a powdery composition such as powder, granule or fine granule, (A) imidazole dipeptide, (B) barley foliage and (C) oligosaccharide may be used as they are, or shaped. You may use the mixture with an agent etc. Moreover, when obtaining a liquid or jelly-like composition, you may use what was previously melt | dissolved or disperse | distributed to solvents, such as water and fruit juice.

以下、本発明を実施例により具体的に説明する。なお、本発明はこれらの実施例に限定されるものではない。 Hereinafter, the present invention will be specifically described by way of examples. The present invention is not limited to these examples.

[飲食用組成物の官能評価]
1.飲食用組成物の製造
以下の表1に示す配合を有する飲食用組成物を調製した。表1のうち、数値は質量(g)を表わす。イミダゾールジペプチドとしては、市販のチキン由来イミダゾールジペプチドのエキス末(アンセリン・カルノシン複合体、イミダゾールジペプチド規格値10±1%)を用い、大麦茎葉は粉砕末(大麦若葉末、株式会社東洋新薬製)を用い、オリゴ糖としてはいずれも市販のイソマルトオリゴ糖(粉末状)とフラクトオリゴ糖(粉末状)を用い、デキストリンは市販の粉末状のものを用いた。尚、デキストリンは賦形剤として用いたものであり、本評価に関与しない成分である。
[Sensory evaluation of the composition for eating and drinking]
1. Manufacture of the composition for eating and drinking The composition for eating and drinking which has the mixing | blending shown in Table 1 below was prepared. In Table 1, the numerical value represents mass (g). As imidazole dipeptide, commercially available chicken-derived imidazole dipeptide extract powder (anserine / carnosine complex, imidazole dipeptide standard value 10 ± 1%) is used, and barley foliage is crushed powder (barley young leaf powder, manufactured by Toyo Shinyaku Co., Ltd.) As the oligosaccharide, commercially available isomalto-oligosaccharide (powder) and fructo-oligosaccharide (powder) were used, and dextrin was used as a commercially available powder. Note that dextrin is used as an excipient and is not a component involved in this evaluation.

2.官能評価
(1)サンプルの調製
上記表1に記載の比較例1及び実施例1〜11のサンプルについて、各サンプル8gを、水100mLと混合して各試験サンプルを得た。
2. Sensory evaluation (1) Preparation of samples For the samples of Comparative Example 1 and Examples 1 to 11 described in Table 1 above, 8 g of each sample was mixed with 100 mL of water to obtain each test sample.

(2)サンプルの評価
被験者として、健常な成人4名を無作為に選出した。これらの被験者4名に対し、下記表2の評価項目について、アンケートを実施し、官能評価を行った。具体的には、例えば、実施例1〜11の評価は比較例1を基準(5点)として他のサンプルを比較し、それぞれ1〜9点の点数をつけた。
(2) Four healthy adults were randomly selected as sample subjects. For these four test subjects, a questionnaire was conducted on the evaluation items in Table 2 below, and sensory evaluation was performed. Specifically, for example, in the evaluation of Examples 1 to 11, other samples were compared using Comparative Example 1 as a reference (5 points), and scored 1 to 9 points, respectively.

各サンプルについて、被験者の点数の平均点を算出し、基準としたサンプル(比較例
1)との差を算出した。結果を図1のグラフに示す。
For each sample, the average score of the subjects was calculated, and the difference from the reference sample (Comparative Example 1) was calculated. The results are shown in the graph of FIG.

(3)考察
賦形剤であるデキストリンを除く成分(イミダゾールジペプチドのエキス末、大麦茎葉の粉砕末、オリゴ糖)について、嗜好性の評価結果を考察した。
(3) Discussion Regarding the components (extract powder of imidazole dipeptide, pulverized powder of barley foliage, oligosaccharide) excluding dextrin which is an excipient, the evaluation results of palatability were considered.

図1は、官能試験の結果を示すものである。図1に示すように、イミダゾールジペプチドのエキス末と大麦茎葉の粉砕末とを含有する実施例1〜5は、大麦茎葉の粉砕末を高用量にするほど、いずれの項目も高い値となった。しかし、大麦茎葉の粉砕末が低用量(0.2g、実施例2)であっても、そこにイソマルトオリゴ糖(消化性オリゴ糖)を配合した実施例6は、大麦茎葉の粉砕末を実施例2の10倍配合した実施例3や、実施例2の20倍の大麦茎葉の粉砕末を配合した実施例4と、同程度の高い評価となった。一方、イソマルトオリゴ糖(消化性オリゴ糖)に替えてフラクトオリゴ糖(難消化性オリゴ糖)を配合した実施例8は、実施例6よりも低い評価となった。このことから、どのオリゴ糖であっても同程度の呈味改善効果が得られるわけではなく、フラクトオリゴ糖(難消化性オリゴ糖)よりもイソマルトオリゴ糖(消化性オリゴ糖)の方が、呈味改善効果が優れることがわかった。さらに、2種のオリゴ糖を配合した実施例10や11は、1種のオリゴ糖をオリゴ糖の総量が同じになるように配合した実施例6、8や実施例7、9よりもそれぞれ高い評価となり、非常に優れた呈味改善効果が得られた。その要因は不明ではあるが、消化性オリゴ糖と難消化性オリゴ糖の組み合わせにより、効果が奏された可能性が推測できる。 FIG. 1 shows the results of the sensory test. As shown in FIG. 1, Examples 1 to 5 containing the extract powder of imidazole dipeptide and the pulverized powder of barley foliage had higher values for all items as the pulverized powder of barley foliage was made higher. . However, even when the barley stalks and powders were pulverized at a low dose (0.2 g, Example 2), Example 6 in which isomaltoligosaccharides (digestible oligosaccharides) were blended therewith conducted barley stalks and powders. The evaluation was as high as Example 3 in which Example 2 was blended 10 times in Example 2 and Example 4 in which 20 times of barley stalks and pulverized powders were blended in Example 2. On the other hand, Example 8 which mix | blended fructooligosaccharide (hard-digestible oligosaccharide) instead of isomalt-oligosaccharide (digestible oligosaccharide) evaluated lower than Example 6. FIG. Therefore, not all oligosaccharides provide the same level of taste improvement effect, and isomalt-oligosaccharides (digestible oligosaccharides) are more effective than fructooligosaccharides (hard-digestible oligosaccharides). It was found that the taste improving effect was excellent. Further, Examples 10 and 11 in which two kinds of oligosaccharides are blended are higher than Examples 6, 8 and Examples 7 and 9 in which one kind of oligosaccharide is blended so that the total amount of oligosaccharides is the same. It became evaluation and the very excellent taste improvement effect was acquired. Although the cause is unknown, it can be estimated that the effect was achieved by the combination of digestible oligosaccharide and indigestible oligosaccharide.

以上の結果より、(A)イミダゾールジペプチドを単独で用いた組成物(組成物I)は、イミダゾールジペプチド独特の臭いや味を有し、単独では嗜好性が悪いものであったが、組成物Iに(B)大麦茎葉を添加した組成物(組成物II)は、組成物Iと比較して、イミダゾールジペプチド独特の臭いや味を効果的に改善することができた。組成物IIにさらに(C)オリゴ糖を添加した組成物(組成物III)は、組成物IIと比較して、イミダゾールジペプチド独特の臭いや味をより一層改善することができた。また、(C)オリゴ糖として、イソマルトオリゴ糖(消化性オリゴ糖)のみを含有する組成物(組成物III-1)は、フラクトオリゴ糖(難消化性オリゴ糖)のみを含有する組成物(組成物III-2)よりも呈味改善効果に優れることがわかった。特に、(C)イソマルトオリゴ糖(消化性オリゴ糖)とフラクトオリゴ糖(難消化性オリゴ糖)の2種のオリゴ糖を含有する本発明の組成物(組成物IV)は、オリゴ糖の総量は同じでも、組成物III-1と比べても非常に高い呈味改善効果を有し、嗜好性に優れた組成物となることがわかった。 From the above results, (A) the composition (composition I) using imidazole dipeptide alone had a smell and taste peculiar to imidazole dipeptide, and it was poor in palatability alone. Compared with the composition I, the composition (composition II) to which (B) barley stover was added could effectively improve the odor and taste peculiar to imidazole dipeptide. The composition (composition III) obtained by further adding (C) the oligosaccharide to the composition II was able to further improve the odor and taste unique to the imidazole dipeptide compared to the composition II. Further, (C) a composition (composition III-1) containing only isomaltoligosaccharide (digestible oligosaccharide) as an oligosaccharide is a composition containing only fructooligosaccharide (hardly digestible oligosaccharide) (composition) It was found that the taste-improving effect was superior to the product III-2). In particular, the composition (Composition IV) of the present invention containing two types of oligosaccharides (C) isomalt-oligosaccharide (digestible oligosaccharide) and fructooligosaccharide (hard-digestible oligosaccharide) Even in the same case, it was found that the composition had a very high taste improving effect as compared with the composition III-1, and was excellent in palatability.

実施例12及び13(粉末飲料の製造)
下記処方例に記載の配合比に従って原料を調製したのち、常法に従って、本発明の効果を奏する粉末飲料8gを製造した。
Examples 12 and 13 (Production of powdered beverages)
After preparing the raw materials according to the blending ratios described in the following formulation examples, 8 g of a powdered beverage having the effects of the present invention was produced according to a conventional method.

実施例14及び15(ゼリー状飲料の製造)
下記処方例に記載の配合比に従って原料を調製したのち、常法に従って、本発明の効果を奏するゼリー状飲料150gを製造した。
Examples 14 and 15 (production of jelly-like beverage)
After preparing the raw materials according to the blending ratio described in the following prescription examples, 150 g of a jelly-like beverage having the effects of the present invention was produced according to a conventional method.

本発明によれば、人工添加物を用いずにイミダゾールジペプチドの呈味を改善することができるため、イミダゾールの機能性を有し、かつ嗜好性の高い、自然派志向の飲食用組成物を提供することができる。 According to the present invention, since the taste of imidazole dipeptide can be improved without using an artificial additive, a natural-oriented eating and drinking composition having imidazole functionality and high palatability is provided. can do.

Claims (2)

(A)イミダゾールジペプチドと、(B)大麦茎葉を含有する飲食用組成物であって、前記(B)大麦茎葉が粉砕末であることを特徴とする飲食用組成物(A) An edible composition containing imidazole dipeptide and (B) barley foliage , wherein the (B) barley foliage is a pulverized powder . さらに、(C)オリゴ糖を含有する請求項1に記載の飲食用組成物。 Furthermore, the composition for eating and drinking of Claim 1 containing (C) oligosaccharide.
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