JP6256018B2 - Diffraction structure and anti-counterfeit medium using the same - Google Patents

Description

  The present invention relates to a diffractive structure having an optical change and an anti-counterfeit medium using the same.

  Conventionally, as a means for preventing counterfeiting, a fine structure or color tone change that cannot be easily imitated, or an optical phenomenon that is only in combination with another optical functional film as a discriminator is observed. Various aspects have been put into practical use with the advancement of technology, such as such a configuration, and a specific pattern or the like can be read only by a dedicated reading device.

Among these, for practical use, the most used anti-counterfeit display is a hologram or diffractive structure that is an OVD (Optical (ly) Variable Device) that causes an optical change. Examples include the body. The hologram is produced by providing a fine uneven pattern and a refractive index distribution by an optical photographing method such as two-beam interference. As for the diffractive structure, a diffraction grating image is produced using a pixel in which a diffraction grating is arranged in a minute area.
Both of the above holograms and diffraction structures are difficult to counterfeit, difficult to copy with color copiers, etc., and are excellent in design, so they are widely used for credit cards, ID cards, various securities, certificates, etc. ing.
However, in actual operation, the authenticity of holograms and diffractive structures is left to the human eye, so even if it is a microscopically fake product, all people are uniformly accurate with the naked eye. It is not easy to perform authenticity determination.

Further, as the holograms and diffractive structures as described above are distributed and popularized, forgery technology also advances, so that a display body that is more difficult to forge is required.
For example, a hologram or diffractive structure having a surface relief structure may be duplicated by contact exposure.
In order to prevent forgery, for example, Patent Document 1 describes that a fine pattern having a diffraction effect is devised. This display body makes it difficult to know the presence or absence of security information so that the information cannot be read visually. Therefore, since it is difficult to determine whether or not the product is genuine, a reading machine is used for the determination.
In addition, holograms and diffractive structures replicated by the contact exposure method can be confirmed to have reduced accuracy compared to the original, but usually replicas are distributed only as replicas, so for ordinary people who are not experts There is a problem that it is difficult to determine whether the product is genuine.

It is known that a substrate provided with fine irregularities suppresses reflection of incident light. For example, some types of anti-reflection films have a distribution in the refractive index of the film by embossing fine irregularities on the surface of the film base material, or by mixing a filler into the film forming resin itself. Unevenness is formed on the surface. In recent years, it has been disclosed that incident light can be controlled by making the unevenness finer and setting the period of the protrusions to be equal to or less than the wavelength of light to prevent reflection of light (for example, see Patent Document 2). In this technique, the period of the convex portion is set to be equal to or less than the wavelength of light, particularly about 50 to 250 nm (paragraph 0014 of Patent Document 2), so that reflection of light is suppressed and applied to the light control sheet. (Hereinafter, such a concave-convex structure having a convex period equal to or less than the wavelength of light is referred to as a fine concave-convex structure).
In addition, it is disclosed that a reflective body is provided in a fine concavo-convex structure to control a diffracted light so that a diffracted light can be observed (see, for example, Patent Document 3).

  However, a display body with a reflective layer on such a fine concavo-convex structure has a high anti-counterfeiting effect because it is difficult to counterfeit because it requires a more accurate manufacturing technology than conventional diffractive structures, Since diffracted light is not generated unless observed from an angle close to the horizontal direction of the body, there is a problem that it is difficult to observe the diffracted light with the conventional observation method of the diffractive structure.

JP-T-2002-505774 JP 2007-48688 A JP 2008-275740 A

  An object of the present invention is to provide a diffractive structure that can easily determine the authenticity by grasping the features of the diffractive structure without changing the advanced visual effect of the diffractive structure, and forgery prevention using the diffractive structure. To provide a medium.

  In order to solve the above problems, a diffractive structure according to one embodiment of the present invention is configured as follows. First, the vertical cross-sectional shape is a saw blade shape. Long side portions and short side portions forming the saw blade shape are alternately arranged regularly at a constant angle. The long side portion has a fine uneven structure in which fine unevenness is regularly arranged on the surface. This diffractive structure is a diffractive structure having a long side portion as a light incident surface. This diffractive structure has a fine concavo-convex structure, which is a diffractive structure that expresses an optical change, arranged on a long side portion of a saw blade shape simulating a blazed diffraction grating, thereby allowing incident light incident on the fine concavo-convex structure, The reflected light and diffracted light that appear in the fine concavo-convex structure are changed by the angle of the saw blade shape inclined from the horizontal.

  According to the present invention, a diffractive structure that can be used for an anti-counterfeit medium used to prevent counterfeiting of securities and vouchers, such as banknotes, bonds, gift certificates, lotteries, credit cards, gift cards, etc. Can be realized.

It is sectional drawing which shows the saw blade shape of the diffraction structure which concerns on 1st-8th embodiment of this invention. It is an enlarged view of the 1X section of Drawing 1 showing the saw blade shape of the diffraction structure concerning the 1st-the 8th embodiment of the present invention. It is an enlarged view (cross-sectional enlarged view of a fine concavo-convex structure) of FIG. 2Y showing the saw blade shape of the diffractive structure according to the first to eighth embodiments of the present invention. It is a perspective view which shows the Example of the fine concavo-convex structure which concerns on 1st-8th embodiment of this invention. It is sectional drawing of the forgery prevention adhesive label which concerns on 6th Embodiment of this invention. It is sectional drawing of the forgery prevention thread | sled which concerns on 7th Embodiment of this invention. It is sectional drawing of the forgery prevention transfer foil which concerns on 8th Embodiment of this invention.

Embodiments of the present invention will be described below in detail with reference to the accompanying drawings.
(First embodiment)
With reference to FIG. 1, a cross-sectional view of the diffractive structure according to the first embodiment of the present invention will be described. As shown in FIG. 1, the cross section of the diffractive structure has a saw blade shape with a short side portion S and a long side portion L. When the bottom of the sectional view is the horizontal line F, the inclination of the long side portion L is an angle θ1 formed by the horizontal line F and the long side portion L. The inclination of the short side S is an angle θ2 formed by the horizontal line F and the short side S. The long side portions L and the short side portions S forming the saw blade shape in the present embodiment are alternately arranged regularly at a constant angle.

  FIG. 2 is an enlarged cross-sectional view of the X portion of the saw blade shape shown in FIG. The surface of the long side portion L shows that a fine concavo-convex structure arranged at an inclination of the angle θ1 is formed. Here, the distance between adjacent vertex portions of the saw blade shape is A (hereinafter, vertex distance A), and the vertex height is B (hereinafter vertex height B).

  FIG. 3 is an enlarged view of the Y portion of the fine concavo-convex structure formed in the long side portion L of the saw blade shape shown in FIG. The Y portion of the fine concavo-convex structure has a convex portion center distance D (hereinafter, convex portion center distance D), a height difference H between the convex portion and the concave portion (hereinafter, convex concave portion height difference H), and an inclination of an angle θ1. It can be seen that they are regularly formed. The distance between the centers of the convex portions may be read as the distance between the centers of the concave portions. This is because when the convex portions are arranged at regular intervals, the concave portions are also arranged at regular intervals, and therefore the distance between the concave portion centers is equal to the central distance between the convex portions. Moreover, you may read the convex-concave height difference as the convex-part height. This is because the difference in height between the convex portion and the concave portion indicates the height of the convex portion when the bottom (lowermost point) of the concave portion is used as a reference.

(Second Embodiment)
In the second embodiment of the present invention, the convex center distance D in FIG. 3 is 200 nm or more and 500 nm or less, and the convex / concave height difference H is 100 nm or more.
Here, when the convex-center distance D is less than 200 nm, even if the convex-concave height difference H is 100 nm or more, even if light having a wavelength of visible light of about 400 nm to 700 nm is incident, the visible light region. The diffracted light cannot be observed because it is not expressed. On the other hand, even if the convex center distance D is 200 nm or more and 500 nm or less, if the convex / concave height difference H is less than 100 nm, light scattering occurs, so that it is not easy to observe the diffracted light. .

(Third embodiment)
In the third embodiment of the present invention, the value (aspect ratio) indicated by H / D in the cross-sectional view of the fine concavo-convex structure shown in FIG. Here, if the convex portion center distance D, which is within the numerical range of the second embodiment of the present invention, is set to the maximum of 500 nm and the convex / concave height difference H is set to the minimum of 100 nm, the aspect ratio becomes 0.2. If it is a combination, the convex-concave height difference H is insufficient and light scattering occurs, making it difficult to observe the diffracted light.
If the aspect ratio is 0.5 or more, the actual fine concavo-convex structure is rounded with the convex part not sharp, as shown in the perspective view of FIG. 4, and a flat surface is formed in a part of the concave part. It may be a semi-conical shape, a tapered cone or a pyramid.

(Fourth embodiment)
In the cross-sectional views shown in FIG. 1 and FIG. 2, the cross section of the diffractive structure has a saw blade shape in which short side portions S and long side portions L are alternately and regularly formed. The angle θ1 and the angle θ2 are determined by the combination of the parts L.
However, in the fourth embodiment of the present invention, as the optimum condition for expressing the diffracted light by the diffractive structure, the length of the short side portion S connecting adjacent long side portions L in the cross-sectional view in FIG. The length of the long side portion L on which the fine concavo-convex structure is formed is specified to be 2 μm or more and 20 μm or less, the inclination of the long side portion L is specified to be 5 ° or more and 60 ° or less, and the short side The inclination of the part S was defined as 45 ° or more and 90 ° or less.
Considering the case where the angles θ1 and θ2 are small, when the angle θ1 = 5 ° and the angle θ2 = 30 °, if the angle θ1 is small, the angle shift effect when diffracted light is observed is reduced. End up. Further, when the angle θ2 is small, the reflected light and diffracted light expressed in the short side portion S are relatively larger than the reflected light and diffracted light expressed in the long side portion L, and as a result, the long side portion It becomes difficult to observe only L diffracted light.
On the other hand, when the angle θ1 exceeds 60 °, the inclination angle is too large, and it becomes difficult to form a fine uneven structure. Further, when the angle θ2 exceeds 90 °, the angle becomes a reverse taper structure, which makes it difficult to manufacture.

(Fifth embodiment)
In the fifth embodiment of the present invention, in the saw blade shape shown in FIGS. 1 and 2, when the long side portion L does not have a fine uneven structure, the saw blade shape satisfies the condition of the blazed diffraction grating. By forming a fine concavo-convex structure on a part of the long side portion L and making the long side portion L of the other portion flat, both a blazed diffraction grating and a fine concavo-convex structure are formed in one diffractive structure. To do.
As a typical example of the blazed diffraction grating, the distance A between the vertices of the saw blade shape is about 0.5 to 1 μm, and the vertex height B is about 0.1 to 1 μm.

(Sixth embodiment)
FIG. 5 is a cross-sectional view of an anti-counterfeit adhesive label 11 that is an anti-counterfeit medium having a diffractive structure showing an example of the sixth embodiment of the present invention. Here, the substrate 1 is a label substrate. A transparent resin film is used for the substrate 1. For the diffractive structure forming layer 2, a highly transparent resin is used for optical performance. After the diffractive structure 3 is formed on the diffractive structure forming layer 2, the reflective layer 4 for reflecting incident light on the end face of the diffractive structure 3 is laminated and formed. Then, the forgery-preventing pressure-sensitive adhesive label 11 having a diffractive structure is formed by laminating the pressure-sensitive adhesive layer 5 formed of a pressure-sensitive adhesive used for general labels.
This configuration is a typical example of the anti-counterfeit pressure-sensitive adhesive label of the present embodiment, and a printing layer for adding design properties, a protective layer for improving surface durability, and the like as necessary. Another layer may be added.

(Seventh embodiment)
FIG. 6 is a cross-sectional view of an anti-counterfeit thread (Security Thread) 12 which is an anti-counterfeit medium having a diffractive structure showing an example of the seventh embodiment of the present invention. Here, the base material 1 is a thread base material. A transparent resin film is used for the substrate 1. For the diffractive structure forming layer 2, a highly transparent resin is used for optical performance. After the diffractive structure 3 is formed on the diffractive structure forming layer 2, the reflective layer 4 for reflecting incident light on the end face of the diffractive structure 3 is laminated and formed. Thereafter, the thread adhesive layer 6 for bringing the thread and the paper into close contact with each other when being rolled into the paper is laminated, thereby forming the forgery prevention thread 12 having the diffractive structure. This configuration shows a typical example of the anti-counterfeit thread according to the present embodiment. When a printing layer is added to impart designability, or when the sheet is inserted into a paper base, the adhesiveness to the paper In order to further improve the above, another layer may be added as necessary, such as adding an adhesive layer to the surface of the substrate 1.

(Eighth embodiment)
FIG. 7 is a cross-sectional view of an anti-counterfeit transfer foil 13 that is an anti-counterfeit medium having a diffractive structure showing an example of the eighth embodiment of the present invention. For the support 7, a resin film having transparency and heat-resistant paper is used. The diffractive structure is peeled off from the support 7 by transfer by thermal thickness. A peeling protective layer 8 for protecting the diffractive structure is laminated after peeling. The diffraction structure forming layer 2 is laminated on the peeling protective layer 8. For the diffractive structure forming layer 2, a highly transparent resin is used for optical performance. After the diffractive structure 3 is formed on the diffractive structure forming layer 2, the reflective layer 4 for reflecting incident light on the end face of the diffractive structure 3 is laminated and formed. Thereafter, an adhesive layer 9 for transfer foil for adhering to the substrate to be transferred is laminated. This configuration shows a typical example of the anti-counterfeit transfer foil of this embodiment, and a printing layer for adding design properties, a functional layer for giving another function, and the like as necessary. Another layer may be added.

(Configuration of anti-counterfeit media)
Hereinafter, the configuration of the forgery prevention medium using the diffractive structure according to the sixth to eighth embodiments will be described in more detail.
(Base material)
A transparent resin film is used for the base material 1 and the support body 7 used for the forgery prevention medium of each embodiment. As the resin film, a polyethylene terephthalate resin film, a polyethylene naphthalate resin film, a polyimide resin film, a polyethylene resin film, a polypropylene resin film, a heat-resistant vinyl chloride film, or the like can be used. Among these resins, since the heat resistance is high and the thickness is stable, a polyethylene terephthalate resin film can be preferably used.

(Peeling protection layer)
In the anti-counterfeit transfer foil 13 according to the eighth embodiment of the present invention, a peeling protective layer 8 is laminated on one side of the support 7. As the peeling protection layer 8, a resin added with a lubricant can be used. As the resin, a thermoplastic resin, a thermosetting resin, a moisture curable resin, an ultraviolet curable resin, an electron beam curable resin, or the like can be used. For example, acrylic resin, polyester resin, and polyamideimide resin. As the lubricant, polyethylene powder or wax such as carnauba wax can be used. These are formed by a known coating method such as a gravure printing method or a micro gravure method.

(Diffraction structure forming layer)
The diffractive structure forming layer 2 is formed by laminating a resin on one surface of the substrate 1 or the peeling protection layer 8. As the resin, a thermoplastic resin, a thermosetting resin, an ultraviolet ray, an electron beam curable resin, or the like can be used. For example, acrylic resin, epoxy resin, cellulose resin, vinyl resin, etc. can be used as the thermoplastic resin. Further, as the thermosetting resin, urethane resin, melamine resin, phenol resin and the like obtained by adding polyisocyanate as a crosslinking agent to acrylic polyol or polyester polyol having a reactive hydroxyl group and crosslinking can be used. Moreover, epoxy (meth) acryl, urethane (meth) acrylate, etc. can be used as ultraviolet ray or electron beam curable resin. These are formed by a known coating method such as a gravure printing method or a micro gravure method.

The fine concavo-convex structure formed in the diffraction structure forming layer 2 can be formed by irradiating the surface of the electron beam curable resin with an electron beam, exposing it in a desired pattern, and then developing it. Then, by forming a metal film on the surface of the formed relief type master plate having a fine uneven structure by electroplating, the uneven pattern of the relief type master plate is duplicated and used as a press plate. Then, the diffractive structure including the fine concavo-convex structure is formed on the surface of the diffractive structure forming layer 2 by thermocompression bonding the press plate to the diffractive structure forming layer 2 or curing the press plate in close contact with the uncured curable resin. A body 3 is formed.
In addition, about the formation method of the resin material in the diffraction structure formation layer 2 of each embodiment, or a fine uneven structure, it is not limited to said method.

(Reflective layer)
Next, as the reflective layer 4, it is preferable to form a metal thin film by using a vacuum film forming method in order to form a thin film on the surface layer of the diffraction structure forming layer 2 without filling the unevenness of the fine uneven structure. Examples of the metal used for the reflective layer 4 include aluminum (Al), tin (Sn), chromium (Cr), nickel (Ni), copper (Cu), gold (Au), and brass. And as a vacuum film-forming method, a vacuum evaporation method, sputtering method, etc. are applicable. Actually, it is only necessary to control the thickness of the metal thin film between 5 nm and 100 nm. Here, a thickness of 10 nm or more and 80 nm or less is preferable in terms of visible light transmittance.

The thickness of the reflective layer 4 may vary between the flat portion and the portion where the fine uneven structure is formed. However, the change in this case is obtained in advance after grasping in advance.
For example, when the reflective layer 4 is formed using the above vacuum film forming method, the film thickness of the metal thin film changes depending on the surface shape of the film forming object even if the processing conditions are constant. However, in each embodiment, since the surface shape is precisely controlled and molded, it is possible to predict in advance the thickness of the metal thin film in various shapes of unevenness from the stage of designing the uneven shape. It is. Therefore, even if the concavo-convex structure changes within the fine concavo-convex structure, it is possible to obtain desired transmittance and reflectance utilizing this change.

The reflective layer 4 can be removed to partially form an arbitrary pattern by at least one of the following first to seventh methods.
The first method is a method that uses the printing method described above.
The second method is a method in which the reflective layer 4 is formed into an image pattern by stacking a mask having openings having a fine concavo-convex structure image pattern in a vacuum.

  In the third method, a solvent-soluble resin layer is provided in a negative pattern, and the reflective layer 4 is uniformly formed on the entire surface by coating the solvent-soluble resin layer. Is dissolved and removed, and at the same time, the remaining reflective layer 4 is formed into an image pattern by removing the reflective layer 4 superimposed on the solvent-soluble resin layer.

  In the fourth method, a resin layer that can be easily peeled off is provided in a fine pattern on the fine concavo-convex structure, and the reflective layer 4 is uniformly formed on the entire surface by covering the resin layer, and then pressed against an adhesive roll or adhesive paper. Is transferred to an adhesive roll or adhesive paper in a negative pattern and removed, and as a result, the reflective layer 4 remains in an image pattern.

  In the fifth method, the reflective layer 4 is uniformly formed on the entire surface, a chemical-resistant resin layer is provided on the reflective layer 4 in an image pattern, and the reflective layer exposed by applying an alkaline or acidic etching solution. In this method, the layer 4 is dissolved and removed. In the case of this method, after the reflective layer 4 is processed into an image pattern, the chemical-resistant resin layer may be removed, but it is left as it is and used as a protective layer for imparting chemical resistance. You can also

  In the sixth method, a photosensitive resin layer is formed on the reflective layer 4 uniformly formed on the entire surface, exposed and developed in an image pattern, and then exposed by applying an alkaline or acidic etching solution. In this method, 4 is dissolved and removed. Also in this method, the remaining photosensitive resin layer can be left as it is, and can be used as a protective layer having chemical resistance.

  The seventh method is a method in which the remaining reflective layer 4 is formed into an image pattern by directly removing the reflective layer 4 formed uniformly on the entire surface by irradiating the laser beam.

  In each embodiment, the method of forming the reflective layer 4 in a pattern or changing the thickness thereof is not limited to the above method. In addition, these patterns may be random patterns having no clear meaning, but information that can be recognized by the observer may be given as patterns such as pictures, figures, patterns, letters, numbers, symbols, etc. .

(Adhesive layer, adhesive layer)
The pressure-sensitive adhesive layer 5 and the contact bonding 9 may be any material that adheres to the surface of the transfer object by pressure or heat and pressure. Further, the thread adhesive layer 6 may be any layer that adheres to the paper base material when it is dried in the paper production process when it is rolled into the paper base material. In any case, a known pressure-sensitive adhesive material, heat-sensitive adhesive material, or the like can be used.

(Other layers)
Although not shown, in order to make the adhesion between each layer stronger as other layers, to provide an adhesion auxiliary layer, to provide a colored layer that colors the entire surface or part, to print characters and designs Printing layers can be added. As these inks, known adhesion improvers and adhesives, colorants using dyes and pigments, printing inks, and the like can be used.

Next, examples produced based on the above-described first to eighth embodiments of the present invention will be described.
Example 1
As Example 1, an anti-counterfeit adhesive label 11 according to a sixth embodiment of the present invention having a diffractive structure according to the third embodiment of the present invention will be described.
First, as the substrate 1, a transparent polyethylene terephthalate (commonly known as PET) film having a thickness of 50 μm was used. On one side of the substrate 1, about 2 μm of ink composed of the following composition is applied. A press plate on which the diffractive structure 3 was formed was brought into close contact with one side of the substrate 1 so that no bubbles would enter the ink. Here, the cross section of the diffractive structure 3 has a saw blade shape with a short side portion and a long side portion. A conical fine concavo-convex structure having an aspect ratio of 1.0 with a convex center distance of 400 nm and a convex / concave height difference H of 400 nm is formed on the long side portion of the sawtooth shape of the diffractive structure 3. Therefore, a fine concavo-convex structure is transferred and formed in the ink application part to which the press plate is adhered. Then, after the ink is completely cured by irradiating the ink application part with ultraviolet light including a wavelength of 300 nm or more and 400 nm or less from the mercury lamp through the substrate 1, the press plate is peeled from the cured ink, A diffraction structure forming layer 2 was formed.

Next, on the surface of the diffractive structure forming layer 2, an aluminum vapor deposition film was formed at 50 nm by a vacuum vapor deposition method on the entire surface where the diffractive structure 3 was formed, thereby forming a reflective layer 4. In addition, since the film thickness of this aluminum vapor deposition film changes according to the size and depth of the unevenness of the fine uneven structure, strictly, the flat part on which the diffractive structure 3 is not formed is produced at the same time. The film thickness of the aluminum vapor deposition film was measured and used as a representative value.
When illumination light is incident on the substrate 1 with the reflective layer 4 formed in this manner, the desired diffracted light can be observed, so that the reflective layer 4 in contact with the diffractive structure 3 has a sufficient reflective function. It was confirmed to have.

  Next, an ink composed of the following composition was applied and dried on the reflective layer 4 to form a pressure-sensitive adhesive layer 5 having a thickness of 20 μm, and a release paper 10 was bonded to the pressure-sensitive adhesive layer 5. Finally, it was punched into a desired shape to produce a desired anti-counterfeit adhesive label 11.

[Diffraction structure forming layer ink composition]
UV curable acrylic resin 19.4 parts by weight Initiator 0.6 parts by weight Methyl ethyl ketone 40.0 parts by weight Methyl isobutyl ketone 40.0 parts by weight

[Adhesive layer ink composition]
Acrylic adhesive 40.0 parts by mass Ethyl acetate 45.0 parts by mass Toluene 15.0 parts by mass

  The anti-counterfeit pressure-sensitive adhesive label 11 produced in this way has an angle at which the reflected light and diffracted light can be observed according to the inclination of the long side portion of the saw blade shape. Diffracted light can be easily observed. Moreover, it proved that it was a genuine product, and it turned out that authenticity determination can be performed easily.

(Example 2)
As Example 2, a forgery prevention thread 12 according to a seventh embodiment of the present invention having a diffraction structure according to the fourth embodiment of the present invention will be described.

  First, a transparent polyethylene terephthalate (commonly known as PET) film having a thickness of 12 μm was used as the substrate 1.

  On one side of the substrate 1, about 2 μm of ink composed of the following composition is applied. A press plate on which the diffractive structure 3 was formed was brought into close contact with one side of the substrate 1 so that no bubbles would enter the ink. Here, the cross section of the diffractive structure 3 has a saw blade shape with a short side portion and a long side portion. The saw blade shape of the diffractive structure 3 has a long side portion length of 5 μm, an inclination of about 23.6 °, a short side portion length of 2 μm, and an inclination of 90 °. On the surface of the long side portion of the saw blade shape, a conical fine concavo-convex structure having an aspect ratio of 1.0 with a convex center distance of 400 nm and a convex / concave height difference H of 400 nm is formed. Therefore, a fine concavo-convex structure is transferred and formed in the ink application part to which the press plate is adhered. Then, after the ink is completely cured by irradiating the ink application part with ultraviolet light including a wavelength of 300 nm or more and 400 nm or less from the mercury lamp through the substrate 1, the press plate is peeled from the cured ink, A diffraction structure forming layer 2 was formed.

  Next, an aluminum vapor deposition film was formed at 50 nm on the entire surface where the diffraction structure 3 was formed by a vacuum vapor deposition method to form a reflective layer 4. The film thickness of this aluminum vapor deposition film was measured with the aluminum vapor deposition film on a flat surface where the fine uneven structure was not formed, as in Example 1 above, and this was taken as the representative value of the film thickness. did.

An ink composed of the following composition is applied onto the reflective layer 4 and dried to form a 7 μm thick thread adhesive layer 6, and finally slitted with a width of 5 mm to prevent forgery with a width of 5 mm. Was made.
In addition, two copy papers are prepared simply for verification, and windows with 1 cm square holes are provided in one row at intervals of 2 cm on one copy paper, and then commercially available on one side of the copy paper. Apply an appropriate amount of adhesive with a paper adhesive spray. Next, the anti-counterfeit thread 12 prepared on the other copy paper without a window is placed and bonded using a roll transfer device having a roll heated to a temperature of 120 ° C. Finally, place the copy paper with the window open so that the anti-counterfeit thread with a width of 5 mm is exposed from the row of 1 cm square windows, bond it, and cut it to the desired size. Produced.

[Diffraction structure forming layer ink composition]
UV curable acrylic resin 19.4 parts by weight Initiator 0.6 parts by weight Methyl ethyl ketone 40.0 parts by weight Methyl isobutyl ketone 40.0 parts by weight

[Adhesive layer ink composition]
Ethylene vinyl acetate resin 15.0 parts by mass Toluene 70.0 parts by mass Ethyl acetate 15.0 parts by mass

  The anti-counterfeit thread paper produced in this way has an angle at which the reflected light and diffracted light can be observed according to the inclination of the long side of the saw blade shape. Could be observed easily. Further, it was found that by forging the anti-counterfeit thread 12 into the paper base material, it is proved that it is a genuine product, and an anti-counterfeit thread paper that can easily determine authenticity can be produced.

(Example 3)
As Example 3, an anti-counterfeit transfer foil 13 according to an eighth embodiment of the present invention having a diffractive structure according to the fifth embodiment of the present invention will be described.
First, a transparent polyethylene terephthalate (commonly known as PET) film having a thickness of 25 μm was used as the support 7. On one surface of the support 7, an ink composed of the following composition was applied and dried to form a peel protection layer 8 having a thickness of 1 μm.

  Next, about 2 μm of ink composed of the following composition is applied on the release protective layer 8. In addition, not all of the saw blade shape having a long side length of 5 μm, an inclination of about 23.6 °, a short side length of 2 μm, and an inclination of 90 °, but a convex portion on the surface of a part of the long side portion A conical fine concavo-convex structure having an aspect ratio of 1.0 with a center-to-center distance of 400 nm and a convex-concave height difference of H 400 nm is formed. The long side portion and the short side portion where the fine uneven structure is not formed form a blazed diffraction grating. As a result, the press plate on which two types of diffractive structures, a blazed diffraction grating and a diffractive structure with a fine concavo-convex structure are formed, are brought into close contact with each other so that bubbles do not enter the ink. After irradiating ultraviolet rays including the following wavelengths toward the ink application part to completely cure the ink, the press plate was peeled from the cured ink to form the diffraction structure forming layer 2.

  Next, an aluminum vapor deposition film was formed at 50 nm on the entire surface where the diffraction structure 3 was formed by a vacuum vapor deposition method to form a reflective layer 4. The film thickness of this aluminum vapor deposition film was measured with the aluminum vapor deposition film on a flat surface where the fine uneven structure was not formed, as in Examples 1 and 2, and this was used as a representative value of the film thickness. .

  Finally, an ink composed of the following composition was applied and dried to form a transfer foil adhesive layer 9 having a thickness of 3 μm, thereby producing a forgery-preventing transfer foil 13 according to the eighth embodiment.

[Peeling protective layer ink composition]
Polyamideimide resin (Tg. 250 ° C.) 19.2 parts by mass Polyethylene powder 0.8 parts by mass Dimethylacetamide 45.0 parts by mass Toluene 35.0 parts by mass

[Diffraction structure forming layer ink composition]
UV curable acrylic resin 19.4 parts by weight Initiator 0.6 parts by weight Methyl ethyl ketone 40.0 parts by weight Methyl isobutyl ketone 40.0 parts by weight

[Adhesive layer ink composition]
Vinyl chloride / vinyl acetate copolymer resin 15.0 parts by mass Acrylic resin (Tg. 20 ° C.) 10.0 parts by mass Silica 1.0 part by mass Methyl ethyl ketone 44.0 parts by mass Toluene 30.0 parts by mass

  The anti-counterfeit transfer foil 13 produced in this way was able to observe diffracted light by a fine uneven structure and diffracted light by a blazed diffraction grating without tilting the anti-counterfeit transfer foil 13 greatly. Furthermore, the anti-counterfeit transfer foil 13 can be easily transferred to paper or a plastic material using a conventional transfer machine, so that an anti-counterfeit medium that proves authenticity and can easily determine authenticity is produced. I understood that I could do it.

(Effect of each embodiment)
Each of the above embodiments has the following effects.
The diffractive structure according to the first embodiment is arranged so that the fine concavo-convex structure, which is a diffractive structure that causes optical changes, is arranged on the long side of a saw blade shape simulating a blazed diffraction grating, and is incident on the fine concavo-convex structure. The incident light to be reflected and the reflected light or diffracted light expressed by the fine concavo-convex structure are changed by an angle of a saw blade shape inclined from the horizontal.
According to this diffractive structure, it is possible to change the incident angle incident on the diffractive structure and the reflection angle expressed by the diffracted light expressed in the diffractive structure by an arbitrary constant angle.

In the diffractive structure according to the second embodiment, the distance between the centers of adjacent convex portions or concave portions of the fine concavo-convex structure is 200 nm or more and 500 nm or less, and the height difference between the convex portions and the concave portions is 100 nm or more. .
According to this diffractive structure, when light enters the diffractive structure, it becomes possible to strengthen the diffracted light that appears at an angle different from the reflected light while weakening the reflected light.

Further, the diffraction structure according to the third embodiment has a distance H / D (where D is the distance between the centers of adjacent convex portions or concave portions of the fine concavo-convex structure and H is the height difference between the convex portions and the concave portions. (Aspect ratio: aspect ratio) is set to 0.5 or more.
According to this diffractive structure, since the reflected light is further weakened and the diffracted light is strengthened, the visibility of the diffracted light can be improved.

In the diffractive structure according to the fourth embodiment, the length of the short side portion connecting the adjacent long side portions in the fine concavo-convex structure is 0.5 μm or more and 2 μm or less, and the fine concavo-convex structure is formed. The long side portion has a length of 2 μm to 20 μm, the long side portion has an inclination of 5 ° to 60 °, and the short side portion has an inclination of 45 ° to 90 °.
According to this diffractive structure, the length of the long side and the short side of the saw blade shape, and the inclination angle of the long side and the short side are specified, and the expression of the diffracted light expressed by the fine concavo-convex structure An angle can be set arbitrarily. As a result, it becomes possible to easily observe the diffracted light.

Further, in the diffractive structure according to the fifth embodiment, the above-described fine concavo-convex structure is formed not only on all long sides but only on some long sides. The long side portion and the short side portion where the fine concavo-convex structure is not formed become a blazed diffraction grating due to the saw blade shape. As described above, one diffractive structure has both a fine concavo-convex structure and a blazed diffraction grating.
According to this diffractive structure, since the saw blade shape satisfies the conditions of the blazed diffraction grating, two optical changes, that is, an optical change due to the fine concavo-convex structure and an optical change due to the blazed diffraction grating, depending on the presence or absence of the fine concavo-convex structure on the long side Can be realized with one diffractive structure.

In the anti-counterfeit medium according to the sixth embodiment, the above-described diffractive structure is formed in the diffractive structure forming layer. From the surface, the base material, the diffractive structure forming layer, the reflective layer, and the adhesive layer are stacked in this order. Adhesive label.
According to the anti-counterfeit medium, the anti-counterfeit adhesive label can be obtained by forming the diffraction structure having the above-described effect as an adhesive label.

In the anti-counterfeit medium according to the seventh embodiment, the above-described diffractive structure is formed on the diffractive structure forming layer. From the surface, the base material, the diffractive structure forming layer, the reflective layer, and the adhesive layer are stacked in this order. Threaded.
According to the anti-counterfeit medium, the anti-counterfeit paper can be obtained by inserting the anti-counterfeit thread formed by threading the diffraction structure into the paper base material.

Further, in the anti-counterfeit medium according to the eighth embodiment, the above-described diffractive structure is formed on the diffractive structure forming layer, and from the surface, the base material, the peeling protective layer, the diffractive structure forming layer, the reflective layer, and the adhesive layer They are laminated in order to make a transfer foil.
According to this anti-counterfeit medium, it becomes possible to obtain a forgery-preventing transfer foil by forming the above-mentioned diffractive structure into a transfer foil as a diffractive structure forming layer.

As described above, the diffractive structure according to each embodiment can be used as various types of anti-counterfeit media using a complicated structure and optical changes. In particular, when observing diffracted light used for authenticity determination, it is possible to easily observe a plurality of types of reflected light and diffracted light without tilting the anti-counterfeit medium to various angles or tilting to a deep angle. In addition, counterfeiting is more difficult due to the complicated and fine structure and special optical changes.
The diffractive structure according to each of the above embodiments should be used as a forgery prevention medium used for preventing forgery of securities and vouchers such as banknotes, bonds, gift certificates, lotteries, credit cards, gift cards, etc. Can do. Note that the above embodiments can be implemented in combination.

  As mentioned above, although embodiment of this invention was explained in full detail, actually, it is not restricted to said embodiment, Even if there is a change of the range which does not deviate from the summary of this invention, it is included in this invention.

DESCRIPTION OF SYMBOLS 1 ... Base material 2 ... Diffraction structure formation layer 3 ... Diffraction structure 4 ... Reflective layer 5 ... Adhesive layer 6 ... Adhesive layer for thread | sled 7 ... Support body 8 ... Peeling protective layer 9 ... Adhesive layer 10 for transfer foils ... Release paper 11 ... Anti-counterfeit adhesive label 12 ... Anti-counterfeit thread 13 ... Anti-counterfeit transfer foil A ... Distance between vertices in saw blade shape B ... Height of vertices in saw blade shape D ... Distance between centers of protrusions in fine uneven structure H ... Fine Difference in height between convex and concave portions of the concavo-convex structure S ... Saw blade-shaped short side L ... Saw blade-shaped long side F ... Saw blade-shaped horizontal line θ1 ... Saw blade-shaped long side tilt angle θ2 ... Slope angle of the short side of the saw blade shape

Claims (7)

The vertical cross-sectional shape is a saw blade,
The long side portion and the short side portion forming the saw blade shape are alternately arranged regularly at a constant angle,
The long side portion has a fine uneven structure in which fine unevenness is regularly arranged on the surface ,
The fine concavo-convex structure is formed on a part of the long side part,
The flat long side portion and the short side portion where the fine concavo-convex structure is not formed form a blazed diffraction grating by the saw blade shape,
A diffraction structure characterized in that both diffraction structures of the fine concavo-convex structure and the blazed diffraction grating are formed in one diffraction structure. The distance between the centers of adjacent convex portions or concave portions of the fine concavo-convex structure is 200 nm or more and 500 nm or less,
2. The diffractive structure according to claim 1, wherein a height difference between the convex portion and the concave portion of the fine concavo-convex structure is 100 nm or more.   H / D (aspect ratio: aspect ratio) is 0.5 or more, where D is the distance between the centers of adjacent convex portions or concave portions of the fine concavo-convex structure and H is the height difference between the convex portions and the concave portions. The diffractive structure according to claim 1 or 2, characterized in that: The length of the short side portion connecting the adjacent long side portions is 0.5 μm or more and 2 μm or less,
The length of the long side portion where the fine concavo-convex structure is formed is 2 μm or more and 20 μm or less,
The long side portion has an inclination of 5 ° or more and 60 ° or less,
4. The diffractive structure according to claim 1, wherein an inclination of the short side portion is not less than 45 ° and not more than 90 °. 5. The diffractive structure according to any one of claims 1 to 4 is formed in a diffractive structure forming layer,
An anti-counterfeit medium characterized in that a substrate, the diffraction structure forming layer, the reflective layer, and the adhesive layer are laminated in this order from the surface to form an adhesive label. The diffractive structure according to any one of claims 1 to 4 is formed in a diffractive structure forming layer,
An anti-counterfeit medium characterized in that a base material, the diffractive structure forming layer, a reflective layer, and a back surface adhesive layer are laminated in order from the front surface and threaded. The diffractive structure according to any one of claims 1 to 4 is formed in a diffractive structure forming layer,
An anti-counterfeit medium characterized in that, from the surface, a support, a peeling protective layer, the diffraction structure forming layer, a reflective layer, and an adhesive layer are laminated in this order to form a transfer foil.

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