JP6220970B2 - 溶融成形3次元物品およびこの製造方法 - Google Patents
溶融成形3次元物品およびこの製造方法 Download PDFInfo
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
- B29C64/118—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/68—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2025/00—Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material
- B29K2025/04—Polymers of styrene
- B29K2025/08—Copolymers of styrene, e.g. AS or SAN, i.e. acrylonitrile styrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2096/00—Use of specified macromolecular materials not provided for in a single one of main groups B29K2001/00 - B29K2095/00, as moulding material
- B29K2096/04—Block polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0085—Copolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2867/00—Use of polyesters or derivatives thereof as mould material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2875/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as mould material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/007—Hardness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/24983—Hardness
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Optics & Photonics (AREA)
- Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Description
本実施例では、以下の配合物を熱溶解積層成形により可撓性フィラメントに成形し、本発明の着色物品の作製に使用した。白色とピンク色のマスターバッチは、所望により物品を多色にすると、物品のある領域を強調できることを示すために用いた。材料は、ゴム100に対する重量部または当量百分率のいずれかを基準とする。両方の配合物は、分布制御水素化スチレン系ブロックコポリマー、スチレン−エチレンブタジエン−スチレン(SEBS)の中間ブロックに無水マレイン酸をグラフト化した官能化水素化スチレン系ブロックコポリマーを使用した。Irganox 101およびIrgafos 168は業界で周知の一次および二次安定剤である。これら各々の配合物のショアA硬度は80であった。
Claims (4)
- 硬度が同一でないまたは異なる領域を有する溶融成形モデリング3次元物品であって、
前記領域の一方は剛性で、かつプラスチック、金属、ガラス、木材、コンクリート、岩石またはこれらの混合物であり、および前記領域の他方は、分布制御水素化スチレン系ブロックコポリマー組成物を含む低剛性領域であり、
前記分布制御水素化スチレン系ブロックコポリマー組成物を含む領域は、一時的な支持材料ではなく、および、前記分布制御水素化スチレン系ブロックコポリマー組成物が、180°粘着性試験で少なくとも60N/25mmの剥離強度を有する、
物品。 - 3次元物品を製造するためのアディティブ法であって、
第1のプラスチック材料である固形供給原料を少なくとも1つの押出ヘッドに提供することと、
前記少なくとも1つの押出ヘッド内で第1のプラスチック材料である前記固形供給原料を溶融することと、
前記第1のプラスチック材料の層を台座に堆積させ、3次元物品の一部分を形成することと、
第2のプラスチック材料である固形の第2の供給原料を前記少なくとも1つの押出ヘッドに提供することであって、該第2のプラスチック材料である前記固形の第2の供給原料が、第1のプラスチック材料である前記固形の供給原料と比較して同一でない硬度を有することと、
第2のプラスチック材料である前記固形の供給原料が前記少なくとも1つの押出ヘッド内で溶融することと、および
前記第2のプラスチック材料の層を前記3次元物品の前記部分に堆積させることとを含み、
これによって、硬度が同一でないまたは異なる層または領域を有する3次元物品を形成し、
前記第1のプラスチック材料または前記第2のプラスチック材料のいずれかに分布制御水素化スチレン系ブロックコポリマー組成物を含み、
前記分布制御水素化スチレン系ブロックコポリマー組成物を含む層または領域は、一時的な支持材料ではなく、および、前記分布制御水素化スチレン系ブロックコポリマー組成物が、180°粘着性試験で少なくとも60N/25mmの剥離強度を有する、
方法。 - 3次元物品を製造するためのアディティブ法であって、
プラスチック、金属、ガラス、木材、コンクリート、岩石またはこれらの混合物の3次元固体物品の一部を提供することと、
分布制御水素化スチレン系ブロックコポリマー組成物を含む固形供給原料を少なくとも1つの押出ヘッドに提供することと、
前記少なくとも1つの押出ヘッド内で前記固形供給原料を溶融することと、
3次元固体物品の前記一部上に前記溶融供給原料の層を堆積させることとを含み、
前記分布制御水素化スチレン系ブロックコポリマー組成物が、3次元物品の前記一部よりも低い硬度を有し、
これによって硬度の異なる領域を有する3次元物品を形成し、
前記分布制御水素化スチレン系ブロックコポリマー組成物を含む領域は、一時的な支持材料ではなく、および、前記分布制御水素化スチレン系ブロックコポリマー組成物が、180°粘着性試験で少なくとも60N/25mmの剥離強度を有する、
方法。 - 3次元物品を製造するためのアディティブ法であって、
分布制御水素化スチレン系ブロックコポリマーを含む3次元固体物品の一部を提供することと、
固形供給原料を少なくとも1つの押出ヘッドに提供することとであって、前記固形プラスチック供給原料が3次元物品の前記一部と比較して同一でない硬度を有することと、
前記少なくとも1つの押出ヘッド内で前記固形供給原料を溶融することと、
3次元固体物品の前記一部上に前記溶融供給原料の層を堆積させることとを含み、
これによって硬度の異なる領域を有する3次元物品を形成し、
前記分布制御水素化スチレン系ブロックコポリマーを含む3次元固体物品の一部は、一時的な支持材料ではなく、および、前記分布制御水素化スチレン系ブロックコポリマーが、180°粘着性試験で少なくとも60N/25mmの剥離強度を有する、
方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US14/070,053 | 2013-11-01 | ||
US14/070,053 US10843401B2 (en) | 2013-11-01 | 2013-11-01 | Fuse molded three dimensional article and a method for making the same |
PCT/US2014/062122 WO2015065826A1 (en) | 2013-11-01 | 2014-10-24 | A fuse molded three dimensional article and a method for making the same |
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JP2016539822A JP2016539822A (ja) | 2016-12-22 |
JP6220970B2 true JP6220970B2 (ja) | 2017-10-25 |
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JP2016527178A Active JP6220970B2 (ja) | 2013-11-01 | 2014-10-24 | 溶融成形3次元物品およびこの製造方法 |
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US (1) | US10843401B2 (ja) |
EP (1) | EP3063187B1 (ja) |
JP (1) | JP6220970B2 (ja) |
KR (1) | KR101819405B1 (ja) |
CN (1) | CN105764939B (ja) |
RU (1) | RU2016121406A (ja) |
TW (1) | TWI547363B (ja) |
WO (1) | WO2015065826A1 (ja) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015091814A1 (de) * | 2013-12-18 | 2015-06-25 | Styrolution Group Gmbh | Verwendung von formmassen basierend auf vinylaromat-dien-blockcopolymeren für den 3d druck |
WO2015195527A1 (en) * | 2014-06-16 | 2015-12-23 | Sabic Global Technologies B.V. | Process for additive manufacturing using thermoplastic materials having selected melt indexes |
US10066100B2 (en) * | 2015-09-08 | 2018-09-04 | Kraton Polymers U.S. Llc | Copolyester/controlled distribution styrenic block copolymer blends and methods of making and using same |
RU2745215C2 (ru) * | 2015-10-23 | 2021-03-22 | Хемсон Полимер-Эддитив Аг | Поливинилхлориды и композиции для технологии послойного синтеза |
CN105694340A (zh) * | 2016-03-14 | 2016-06-22 | 重庆中科智翼科技有限责任公司 | 一种熔融沉积技术用高强度abs基聚合物合金及其制备方法 |
CN105866000A (zh) * | 2016-03-24 | 2016-08-17 | 辽宁工程技术大学 | 一种单一裂缝岩石渗流试验装置及方法 |
JP7075032B2 (ja) * | 2016-04-04 | 2022-05-25 | 有限会社スワニー | 緩衝材の製造方法 |
EP3321002A1 (en) * | 2016-11-15 | 2018-05-16 | Höganäs AB | Feedstock for an additive manufacturing method, additive manufacturing method using the same, and article obtained therefrom |
EP3562648B1 (de) * | 2016-12-28 | 2020-10-07 | Covestro Deutschland AG | Lagenweises fertigungsverfahren für einen gegenstand mit unterschiedlichem lagenmaterial |
US20180290398A1 (en) * | 2017-04-10 | 2018-10-11 | Stratasys, Inc. | Additive manufacturing system with a channeled starter piece and method of printing a 3d part utilizing the starter piece |
EP3395572A1 (de) | 2017-04-24 | 2018-10-31 | Covestro Deutschland AG | Additives fertigungsverfahren mit mehreren thermoplastischen polyurethanen |
CN110607062A (zh) * | 2019-10-14 | 2019-12-24 | 常州铭仁三维科技有限公司 | 一种3d打印聚碳酸酯材料及其制备方法 |
CN114479339B (zh) * | 2022-01-19 | 2023-11-03 | 金发科技股份有限公司 | 一种abs合金材料及其制备方法与应用 |
Family Cites Families (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA716645A (en) | 1965-08-24 | Shell Oil Company | Block polymers and process for preparing them | |
US3595942A (en) | 1968-12-24 | 1971-07-27 | Shell Oil Co | Partially hydrogenated block copolymers |
USRE27145E (en) | 1969-05-20 | 1971-06-22 | Side-chain | |
US3634549A (en) | 1969-08-04 | 1972-01-11 | Shell Oil Co | Conjugated diene block copolymers having a random copolymer elastomeric block and their hydrogenated counterparts |
US3670054A (en) | 1969-10-29 | 1972-06-13 | Shell Oil Co | Block copolymers having reduced solvent sensitivity |
US3700633A (en) | 1971-05-05 | 1972-10-24 | Shell Oil Co | Selectively hydrogenated block copolymers |
US4039593A (en) | 1973-05-18 | 1977-08-02 | Lithium Corporation Of America | Preparation of hydroxy-terminated conjugated diene polymers |
US3985830B1 (en) | 1974-07-15 | 1998-03-03 | Univ Akron | Star polymers and process for the preparation thereof |
US4391949A (en) | 1981-11-12 | 1983-07-05 | Shell Oil Company | Asymmetric block copolymers and corresponding adhesive formulations |
US4444953A (en) | 1981-11-12 | 1984-04-24 | Shell Oil Company | Assymetric block copolymers and corresponding adhesive formulations |
US4578429A (en) * | 1984-08-31 | 1986-03-25 | Shell Oil Company | Selectively hydrogenated block copolymers modified with acid compounds or derivatives |
US4788361A (en) | 1987-10-30 | 1988-11-29 | Shell Oil Company | Polymeric viscosity index improver and oil composition comprising the same |
US5503785A (en) | 1994-06-02 | 1996-04-02 | Stratasys, Inc. | Process of support removal for fused deposition modeling |
JPH09176438A (ja) * | 1995-10-26 | 1997-07-08 | Shell Internatl Res Maatschappij Bv | 少なくとも1つのエンジニアリング熱可塑性プラスチック層と少なくとも1つのソフトタッチ組成層とを含む多層ポリマー系、およびそれに使用する組成物 |
US7314591B2 (en) | 2001-05-11 | 2008-01-01 | Stratasys, Inc. | Method for three-dimensional modeling |
US6645412B2 (en) | 1999-04-20 | 2003-11-11 | Stratasys, Inc. | Process of making a three-dimensional object |
US6391981B1 (en) | 1999-04-23 | 2002-05-21 | Kraton Polymers Us Llc | Increased throughput in the manufacture of anionic polymers by reduction in polymer cement viscosity through the addition of metal alkyls |
US6652256B2 (en) | 2000-10-27 | 2003-11-25 | Dorsey D. Coe | Three-dimensional model colorization during model construction from computer aided design data |
US20020171177A1 (en) | 2001-03-21 | 2002-11-21 | Kritchman Elisha M. | System and method for printing and supporting three dimensional objects |
US20030181584A1 (en) * | 2002-02-07 | 2003-09-25 | Kraton Polymers U.S. Llc | Elastomeric articles prepared from controlled distribution block copolymers |
US6759454B2 (en) | 2002-02-07 | 2004-07-06 | Kraton Polymers U.S. Llc | Polymer modified bitumen compositions |
EP1582563A1 (en) * | 2004-03-31 | 2005-10-05 | KRATON Polymers Research B.V. | Hydrogenated styrenic block copolymer compositions with improved high temperature overmolding properties |
US7365131B2 (en) * | 2004-04-28 | 2008-04-29 | The Goodyear Tire & Rubber Company | Thermoplastic vulcanizate composition |
JP4807005B2 (ja) | 2005-08-19 | 2011-11-02 | テクノポリマー株式会社 | Fdm方式またはsls方式による造形用熱可塑性樹脂組成物および造形物 |
US20070066753A1 (en) * | 2005-09-16 | 2007-03-22 | Ehrlich Martin L | Highly processible compounds of high MW conventional block copolymers and controlled distribution block copolymers |
US7582702B2 (en) * | 2006-03-24 | 2009-09-01 | Kraton Polymers U.S. Llc | Block copolymer compositons |
US7592390B2 (en) | 2006-03-24 | 2009-09-22 | Kraton Polymers U.S. Llc | Hydrogenated block copolymer compositions |
US7585916B2 (en) * | 2006-03-24 | 2009-09-08 | Kraton Polymers Us Llc | Block copolymer compositions |
EP2001656B1 (en) | 2006-04-06 | 2014-10-15 | 3D Systems Incorporated | KiT FOR THE PRODUCTION OF THREE-DIMENSIONAL OBJECTS BY USE OF ELECTROMAGNETIC RADIATION |
US20080006966A1 (en) | 2006-07-07 | 2008-01-10 | Stratasys, Inc. | Method for building three-dimensional objects containing metal parts |
JP5249548B2 (ja) | 2007-10-03 | 2013-07-31 | アロン化成株式会社 | 熱可塑性樹脂配合物、および複合材料、および複合材料の製造方法 |
EP2123430B1 (en) | 2008-05-20 | 2020-07-01 | EOS GmbH Electro Optical Systems | Influencing specific mechanical properties of three-dimensional objects manufactured by a selective sintering by means of electromagnetic radiation from a powder comprising at least one polymer or copolymer |
US20110082225A1 (en) * | 2008-06-17 | 2011-04-07 | Polyone Corporation | Thermoplastic elastomers exhibiting superior abrasion resistance properties |
US8404171B2 (en) | 2009-09-04 | 2013-03-26 | Bolson Materials Intl. | Use and provision of an amorphous vinyl alcohol polymer for forming a structure |
US8236227B2 (en) * | 2009-09-30 | 2012-08-07 | Stratasys, Inc. | Method for building three-dimensional models in extrusion-based digital manufacturing systems using tracked filaments |
KR101463318B1 (ko) * | 2009-11-12 | 2014-11-18 | 크레이튼 폴리머즈 유.에스. 엘엘씨 | 열가소성 폴리우레탄 블록 공중합체 조성물 |
CN102725318B (zh) * | 2010-01-27 | 2014-07-23 | 科腾聚合物美国有限责任公司 | 包含苯乙烯-异丁烯-苯乙烯和苯乙烯-乙烯/丁烯-苯乙烯嵌段共聚物的组合物 |
US20110262686A1 (en) * | 2010-04-22 | 2011-10-27 | Kathryn Wright | High Tensile Strength Article with Elastomeric Layer |
US9227365B2 (en) * | 2010-04-25 | 2016-01-05 | Stratasys Ltd. | Solid freeform fabrication of shelled objects |
WO2012014318A1 (ja) * | 2010-07-30 | 2012-02-02 | Necディスプレイソリューションズ株式会社 | 表示装置 |
KR101446091B1 (ko) | 2010-10-27 | 2014-10-06 | 파일2파트, 인코포레이티드 | 3차원 물체 제작 방법 및 장치 |
EP2514775A1 (en) * | 2011-04-20 | 2012-10-24 | Evonik Röhm GmbH | Maleic anhydride copolymers as soluble support material for fused deposition modelling (FDM) printer |
US20130225020A1 (en) | 2012-02-24 | 2013-08-29 | Kraton Polymers Us Llc | High flow, hydrogenated styrene-butadiene-styrene block copolymer and applications |
US10179853B2 (en) * | 2013-09-11 | 2019-01-15 | Toray Industries, Inc. | Material for fused deposition modeling type three-dimensional modeling, and filament for fused deposition modeling type 3D printing device |
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CN105764939B (zh) | 2018-12-04 |
KR20160079058A (ko) | 2016-07-05 |
CN105764939A (zh) | 2016-07-13 |
WO2015065826A1 (en) | 2015-05-07 |
EP3063187A1 (en) | 2016-09-07 |
EP3063187A4 (en) | 2017-06-14 |
EP3063187B1 (en) | 2022-04-13 |
TWI547363B (zh) | 2016-09-01 |
TW201529285A (zh) | 2015-08-01 |
US20150125682A1 (en) | 2015-05-07 |
KR101819405B1 (ko) | 2018-01-16 |
RU2016121406A (ru) | 2017-12-06 |
JP2016539822A (ja) | 2016-12-22 |
US10843401B2 (en) | 2020-11-24 |
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