JP6109169B2 - 自熱式気相脱水素化を実施するための連続的な方法 - Google Patents
自熱式気相脱水素化を実施するための連続的な方法 Download PDFInfo
- Publication number
- JP6109169B2 JP6109169B2 JP2014523309A JP2014523309A JP6109169B2 JP 6109169 B2 JP6109169 B2 JP 6109169B2 JP 2014523309 A JP2014523309 A JP 2014523309A JP 2014523309 A JP2014523309 A JP 2014523309A JP 6109169 B2 JP6109169 B2 JP 6109169B2
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- Prior art keywords
- reactor
- heat exchanger
- zone
- autothermal
- phase dehydrogenation
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- Expired - Fee Related
Links
- 238000006356 dehydrogenation reaction Methods 0.000 title claims description 64
- 238000010924 continuous production Methods 0.000 title description 4
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- 239000012071 phase Substances 0.000 claims description 45
- 238000006243 chemical reaction Methods 0.000 claims description 43
- 230000003197 catalytic effect Effects 0.000 claims description 42
- 239000012495 reaction gas Substances 0.000 claims description 42
- 230000008929 regeneration Effects 0.000 claims description 36
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- 229930195733 hydrocarbon Natural products 0.000 claims description 34
- 150000002430 hydrocarbons Chemical class 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 33
- 239000004215 Carbon black (E152) Substances 0.000 claims description 31
- 238000004519 manufacturing process Methods 0.000 claims description 30
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 29
- 239000001301 oxygen Substances 0.000 claims description 29
- 229910052760 oxygen Inorganic materials 0.000 claims description 29
- 239000003054 catalyst Substances 0.000 claims description 19
- 238000002156 mixing Methods 0.000 claims description 18
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- 239000002638 heterogeneous catalyst Substances 0.000 claims description 6
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000001273 butane Substances 0.000 claims description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 4
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 4
- 230000004913 activation Effects 0.000 claims description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 2
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- 239000001294 propane Substances 0.000 claims description 2
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- 238000004817 gas chromatography Methods 0.000 description 4
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
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- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
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- 229910052751 metal Inorganic materials 0.000 description 1
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- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
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Images
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- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
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- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/50—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with an organic compound as an acceptor
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Automation & Control Theory (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11176328.0 | 2011-08-02 | ||
| EP11176328 | 2011-08-02 | ||
| PCT/EP2012/064987 WO2013017608A1 (de) | 2011-08-02 | 2012-08-01 | Kontinuierliches verfahren zur durchführung von autothermen gasphasendehydrierungen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014529485A JP2014529485A (ja) | 2014-11-13 |
| JP2014529485A5 JP2014529485A5 (enExample) | 2015-09-10 |
| JP6109169B2 true JP6109169B2 (ja) | 2017-04-05 |
Family
ID=46598538
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014523309A Expired - Fee Related JP6109169B2 (ja) | 2011-08-02 | 2012-08-01 | 自熱式気相脱水素化を実施するための連続的な方法 |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP2739386B1 (enExample) |
| JP (1) | JP6109169B2 (enExample) |
| KR (1) | KR20140068035A (enExample) |
| CN (1) | CN103958048B (enExample) |
| EA (1) | EA201490316A1 (enExample) |
| MY (1) | MY185004A (enExample) |
| WO (1) | WO2013017608A1 (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9611191B2 (en) | 2012-12-12 | 2017-04-04 | Basf Se | Reactor for carrying out an autothermal gas-phase dehydrogenation |
| WO2014202503A1 (de) * | 2013-06-17 | 2014-12-24 | Basf Se | Verfahren und anlage zur durchführung einer exothermen gasphasenreaktion an einem heterogenen partikelförmigen katalysator |
| KR102568103B1 (ko) * | 2018-09-21 | 2023-08-17 | 주식회사 엘지화학 | 1,3-부타디엔의 제조방법 |
| KR102564957B1 (ko) * | 2018-09-21 | 2023-08-07 | 주식회사 엘지화학 | 1,3-부타디엔의 제조방법 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3637524A (en) * | 1968-07-11 | 1972-01-25 | Atlantic Richfield Co | Halide addition and distribution in the reactivation of platinum group catalysts |
| FR2511671A1 (fr) * | 1981-08-18 | 1983-02-25 | Davy Mckee Ag | Procede de deshydrogenation |
| US4560815A (en) * | 1983-04-25 | 1985-12-24 | The Babcock & Wilcox Company | Automated catalyst regeneration in a reactor |
| DE3416672A1 (de) * | 1984-05-05 | 1985-11-07 | Veba Oel AG, 4650 Gelsenkirchen | Verfahren zum dehydrieren von kohlenwasserstoffen |
| US5405814A (en) * | 1990-07-25 | 1995-04-11 | Mobil Oil Corporation | Olefin conversion catalyst regeneration |
| EP0917764A2 (en) | 1997-06-06 | 1999-05-26 | Koninklijke Philips Electronics N.V. | Oscillator frequency-drift compensation |
| DE19743667B4 (de) | 1997-10-02 | 2004-07-01 | Robert Bosch Gmbh | Anordnung zum Regeln des Ladedrucks einer Brennkraftmaschine |
| EP1167282B1 (en) * | 1999-12-28 | 2007-04-04 | Daikin Industries, Ltd. | Shift reactor with heat-exchanger |
| WO2001076731A1 (en) * | 2000-04-05 | 2001-10-18 | Hydrogen Burner Technology, Inc. | Pulsed flow, fuel-processing system |
| DE10047642A1 (de) * | 2000-09-26 | 2002-04-11 | Basf Ag | Verfahren zur Dehydrierung von Kohlenwasserstoffen |
| MY135793A (en) | 2002-07-12 | 2008-06-30 | Basf Ag | Method for the production of butadiene from n-butane |
| DE10246119A1 (de) * | 2002-10-01 | 2004-04-15 | Basf Ag | Verfahren zur Herstellung von wenigstens einem partiellen Oxidations- und/oder Ammoxidationsprodukt des Propylens |
| DE102005061626A1 (de) * | 2005-12-21 | 2007-06-28 | Basf Ag | Verfahren der kontinuierlichen heterogen katalysierten partiellen Dehydrierung wenigstens eines zu dehydrierenden Kohlenwasserstoffs |
| US7842846B2 (en) | 2006-03-30 | 2010-11-30 | Basf Aktiengesellschaft | Process for heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated |
| DE102006060509A1 (de) * | 2006-12-19 | 2008-06-26 | Basf Se | Reaktor zur Durchführung einer kontinuierlichen Oxidehydrierung sowie Verfahren |
| DE102007006647A1 (de) * | 2007-02-06 | 2008-08-07 | Basf Se | Verfahren zur Regenerierung eines im Rahmen einer heterogen katalysierten partiellen Dehydrierung eines Kohlenwasserstoffs deaktivierten Katalysatorbetts |
| DE102007036750A1 (de) * | 2007-08-03 | 2009-02-05 | Uhde Gmbh | Regeneration von Katalysatoren zur Dehydrierung von Alkanen |
| CN201276506Y (zh) * | 2008-07-29 | 2009-07-22 | 徐志刚 | 芳香饱和烃类催化反应脱氢反应器 |
| CA2782417A1 (en) * | 2009-12-01 | 2011-06-09 | Basf Se | Reactor for carrying out autothermal gas-phase dehydrogenations |
| CN103391812B (zh) * | 2010-12-21 | 2015-04-08 | 巴斯夫欧洲公司 | 用于进行自热气相脱氢的反应器 |
-
2012
- 2012-08-01 CN CN201280036091.3A patent/CN103958048B/zh not_active Expired - Fee Related
- 2012-08-01 KR KR1020147005010A patent/KR20140068035A/ko not_active Withdrawn
- 2012-08-01 MY MYPI2014000093A patent/MY185004A/en unknown
- 2012-08-01 JP JP2014523309A patent/JP6109169B2/ja not_active Expired - Fee Related
- 2012-08-01 WO PCT/EP2012/064987 patent/WO2013017608A1/de not_active Ceased
- 2012-08-01 EP EP12740993.6A patent/EP2739386B1/de not_active Not-in-force
- 2012-08-01 EA EA201490316A patent/EA201490316A1/ru unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN103958048A (zh) | 2014-07-30 |
| EP2739386A1 (de) | 2014-06-11 |
| EP2739386B1 (de) | 2015-06-10 |
| JP2014529485A (ja) | 2014-11-13 |
| MY185004A (en) | 2021-04-30 |
| WO2013017608A1 (de) | 2013-02-07 |
| KR20140068035A (ko) | 2014-06-05 |
| EA201490316A1 (ru) | 2014-11-28 |
| CN103958048B (zh) | 2016-11-16 |
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