JP6108044B2 - Steel plate for can lid and manufacturing method thereof - Google Patents

Steel plate for can lid and manufacturing method thereof Download PDF

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JP6108044B2
JP6108044B2 JP2016550297A JP2016550297A JP6108044B2 JP 6108044 B2 JP6108044 B2 JP 6108044B2 JP 2016550297 A JP2016550297 A JP 2016550297A JP 2016550297 A JP2016550297 A JP 2016550297A JP 6108044 B2 JP6108044 B2 JP 6108044B2
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克己 小島
克己 小島
智也 平口
智也 平口
田中 匠
田中  匠
裕樹 中丸
裕樹 中丸
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
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    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0236Cold rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0273Final recrystallisation annealing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
    • C21D8/0447Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the heat treatment
    • C21D8/0473Final recrystallisation annealing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C21D9/48Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals deep-drawing sheets
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D51/00Making hollow objects
    • B21D51/16Making hollow objects characterised by the use of the objects
    • B21D51/26Making hollow objects characterised by the use of the objects cans or tins; Closing same in a permanent manner
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D51/00Making hollow objects
    • B21D51/16Making hollow objects characterised by the use of the objects
    • B21D51/38Making inlet or outlet arrangements of cans, tins, baths, bottles, or other vessels; Making can ends; Making closures
    • B21D51/44Making closures, e.g. caps
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/004Dispersions; Precipitations

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Description

本発明は、食品缶詰や飲料缶詰等の缶蓋用鋼板およびその製造方法に関するものである。   The present invention relates to a steel plate for can lids such as canned foods and canned beverages, and a method for producing the same.

食品缶詰や飲料缶詰は、その製造段階で内容物の加熱殺菌処理が行われる。この際、缶の内外で圧力差が生じ、缶体に圧力が作用する。缶体は、缶胴と缶蓋とから主に構成される。このうち、缶胴はその形状が応力を分散させやすい円筒形であるため、圧力が作用しても変形が少ない。一方、缶蓋は平面で構成される部分が多く、圧力を平面で受けるため変形しやすい。缶蓋の過剰な変形は好ましくなく、圧力を受けても変形し難い缶蓋の提供が求められている。   In food cans and beverage cans, the contents are heat sterilized at the manufacturing stage. At this time, a pressure difference is generated between the inside and outside of the can, and pressure acts on the can body. The can body is mainly composed of a can body and a can lid. Among these, the can body has a cylindrical shape that is easy to disperse stress, so that deformation is small even when pressure is applied. On the other hand, the can lid is often formed of a flat surface, and is easily deformed because it receives pressure on the flat surface. Excessive deformation of the can lid is undesirable, and there is a need to provide a can lid that is difficult to deform even under pressure.

缶蓋の圧力に対する変形を抑制する方法としては、缶蓋用鋼板の耐圧強度を高くすることが挙げられる。耐圧強度を高くした缶蓋用の鋼板に関する技術として、以下の特許文献1〜3に記載の技術がある。   As a method for suppressing the deformation of the can lid with respect to the pressure, increasing the pressure resistance of the steel plate for can lid may be mentioned. As technologies related to steel plates for can lids with increased pressure resistance, there are technologies described in Patent Documents 1 to 3 below.

特許文献1に記載の技術は、下降伏強度と板厚の積を規定することで加工性を確保し、かつ、時効後の上降伏強度と板厚の二乗の積を規定することで耐圧強度を確保したエアゾールボトム缶用鋼板に関するものである。この特許文献1には、質量%で、C:0.020%以上0.090%以下、Si:0.01%以上0.05%以下、Mn:0.05%以上0.60以下%、P:0.001%以上0.100%以下、S:0.001%以上0.025%以下、N:0.0010%以上0.0070%未満、Al:0.010%以上{−4.2×Nの含有量(%)+0.11}%以下を含有し、残部がFeおよび不可避的不純物からなる成分組成を有し、板厚を0.350mm以下とし、下降伏強度(N/mm)と前記板厚(mm)との積が195(N/mm)以下、圧延率10%の圧延予歪を施した後、25℃において10日間の室温時効を行った際の上降伏強度(N/mm2)と、板厚(mm)の二乗との積が52.0N以上である、耐圧強度が高く加工性に優れたエアゾール缶ボトム用鋼板およびその製造方法が開示されている。The technology described in Patent Document 1 secures workability by defining the product of the yield strength and the plate thickness, and the pressure strength by defining the product of the upper yield strength after aging and the square of the plate thickness. This relates to a steel plate for aerosol bottom cans. In Patent Document 1, C: 0.020% to 0.090%, Si: 0.01% to 0.05%, Mn: 0.05% to 0.60% by mass, P: 0.001% or more and 0.100% or less, S: 0.001% or more and 0.025% or less, N: 0.0010% or more and less than 0.0070%, Al: 0.010% or more {-4. 2 × N content (%) + 0.11}% or less, the balance is composed of Fe and inevitable impurities, the plate thickness is 0.350 mm or less, and the yield strength (N / mm 2 ) The yield strength when the product of the plate thickness (mm) is 195 (N / mm) or less and the rolling pre-strain is performed at a rolling rate of 10% and then subjected to room temperature aging at 25 ° C. for 10 days. The product of (N / mm 2 ) and the square of the plate thickness (mm) is 52.0 N or more, high pressure strength and processing A steel plate for an aerosol can bottom having excellent properties and a method for producing the same are disclosed.

また、特許文献2に記載の技術は、固溶強化のために0.0075〜0.013質量%のNを積極的に添加して耐圧強度を高める技術である。この特許文献2には、質量%で、C:0.025〜0.065%、Mn:0.10〜0.28%、P:0.005〜0.03%、Al:0.01〜0.04%、N:0.0075〜0.013%を含有し、Si:0.05%以下、S:0.009%以下に制限し、残部がFe及び不可避的不純物からなる化学組成を有し、時効処理後の圧延方向の降伏強度YPが460〜540MPaの範囲であり、時効処理後の圧延方向の全伸びが15%以上であり、時効処理後の圧延方向の降伏点伸びELYPが6%以下であり、mm単位での板厚tと、MPa単位での時効処理後の圧延方向の降伏強度TPと、%単位での時効処理後の圧延方向の降伏点伸びELYPとが130≦t×YP×(1−ELYP/100)を満たす、エアゾール缶蓋用鋼板およびその製造方法が開示されている。The technique described in Patent Document 2 is a technique for increasing the pressure strength by positively adding 0.0075 to 0.013 mass% N for solid solution strengthening. In this patent document 2, by mass%, C: 0.025 to 0.065%, Mn: 0.10 to 0.28%, P: 0.005 to 0.03%, Al: 0.01 to A chemical composition containing 0.04%, N: 0.0075 to 0.013%, Si: 0.05% or less, S: 0.009% or less, the balance being Fe and inevitable impurities The yield strength YP in the rolling direction after the aging treatment is in the range of 460 to 540 MPa, the total elongation in the rolling direction after the aging treatment is 15% or more, and the yield point elongation EL YP in the rolling direction after the aging treatment. Is the thickness t in mm, the yield strength TP in the rolling direction after aging in MPa, and the yield point elongation EL YP in the rolling direction after aging in%. 130 ≦ t × meet YP × (1-EL YP / 100), a steel sheet for an aerosol can lid Its production process and are disclosed.

また、特許文献3に記載の技術は、特許文献1、特許文献2が比較的高い伸張率で高い強度を得ていたことに対し、特許文献2の技術よりも更に多い0.007〜0.025%のNを添加し、歪時効硬化を利用して耐圧強度を高める技術である。この特許文献3には、質量%で、C:0.02〜0.10%、Si:0.01〜0.5%、P:0.001〜0.100%、S:0.001〜0.020%、N:0.007〜0.025%、Al:0.01〜{−4.2×N(%)+0.11}%を含有し、Mnf=Mn−1.71×S(ただし、式中Mn量、S量は鋼中のMn含有量(質量%)、S含有量(質量%))とした時、Mnf:0.10%以上0.30%未満であり、残部がFeおよび不可避的不純物からなる。そして、この鋼板は、板厚が0.35(mm)以下であり、鋼板の下降伏強度(N/mm)と板厚(mm)との積が160(N/mm)以下であり、10%の引張予歪後、25℃において10日間の室温時効を行った際の上降伏強度(N/mm)と板厚(mm)の二乗との積が52.0(N)以上である、耐圧強度が高く加工性に優れたエアゾール缶ボトム用鋼板およびその製造方法が開示されている。In addition, the technique described in Patent Document 3 has a high strength at a relatively high elongation rate in Patent Document 1 and Patent Document 2, whereas 0.007-0. This is a technique in which 025% N is added and the pressure strength is increased by utilizing strain age hardening. In this Patent Document 3, in mass%, C: 0.02 to 0.10%, Si: 0.01 to 0.5%, P: 0.001 to 0.100%, S: 0.001 to 0.020%, N: 0.007 to 0.025%, Al: 0.01 to {-4.2 × N (%) + 0.11}%, Mnf = Mn−1.71 × S (However, when Mn content and S content in the formula are Mn content (mass%) and S content (mass%) in steel), Mnf: 0.10% or more and less than 0.30%, the balance Consists of Fe and inevitable impurities. And this steel plate has a plate thickness of 0.35 (mm) or less, and the product of the steel sheet's yield strength (N / mm 2 ) and the plate thickness (mm) is 160 (N / mm) or less, The product of the upper yield strength (N / mm 2 ) and the square of the plate thickness (mm) when the room temperature aging is performed at 25 ° C. for 10 days after 10% tensile pre-strain is 52.0 (N) or more. A steel plate for an aerosol can bottom having a high pressure strength and excellent workability and a method for producing the same are disclosed.

特開2013−147744号公報JP 2013-147744 A 国際公開第2012/077628号International Publication No. 2012/077628 特開2012−207305号公報JP 2012-207305 A

しかしながら、これらの特許文献1〜3に記載の技術はいずれもエアゾール缶に用いられる鋼板に関するものである。このエアゾール缶の底蓋やボトムは、高い耐圧強度を達成するために缶内面側に膨らんだドーム形状をしており、特許文献1〜3に記載の技術では、前述した食品缶詰等の缶体の平板形状の缶蓋で発生しやすい缶内外の圧力差による変形については、考慮されていなかった。   However, all of the techniques described in Patent Documents 1 to 3 relate to a steel plate used for an aerosol can. The bottom lid and bottom of this aerosol can have a dome shape that swells toward the inner surface of the can in order to achieve high pressure resistance, and in the techniques described in Patent Documents 1 to 3, the cans such as food cans described above The deformation due to the pressure difference between the inside and outside of the can, which is likely to occur in the flat plate-shaped can lid, was not considered.

このように、食品缶詰等の缶体に用いられる、平面で構成される部分が多い平板形状の缶蓋で発生しやすい缶内外の圧力差による変形を抑制する技術はまだ確立されていなかった。そこで、本発明は、かかる事情に鑑みてなされたもので、缶内外の圧力差による変形を抑制することができる缶蓋用鋼板およびその製造方法を提供することを目的とする。   As described above, a technique for suppressing deformation due to a pressure difference between the inside and outside of the can, which is likely to occur in a flat can lid used for cans such as food cans, which has many flat portions, has not yet been established. Then, this invention was made | formed in view of this situation, and it aims at providing the steel plate for can lids which can suppress the deformation | transformation by the pressure difference inside and outside a can, and its manufacturing method.

本発明者らは、鋼板の機械特性の缶蓋の耐圧特性に及ぼす影響について検討した。その結果、下降伏強度YP、降伏点伸びYPElを適切に制御することで、平面で構成される部分が多い平板形状の缶蓋の場合であっても、良好な耐圧特性を得られることを見いだした。   The present inventors examined the influence of the mechanical properties of the steel sheet on the pressure resistance characteristics of the can lid. As a result, it has been found that by properly controlling the yield strength YP and the yield point elongation YPEL, good pressure resistance characteristics can be obtained even in the case of a flat plate-shaped can lid having many flat portions. It was.

また、N含有量を多くし、Al、Mn、Sを特定の含有量とし、また、製造条件として、スラブ加熱温度、熱間圧延の巻取り温度、調質圧延の伸長率を所定の範囲に調整することで、上記の特定の条件を満たす機械特性が得られることも見いだした。   In addition, the N content is increased, Al, Mn, and S are specified contents, and the slab heating temperature, the hot rolling coiling temperature, and the temper rolling elongation rate are within a predetermined range as manufacturing conditions. It has also been found that mechanical characteristics satisfying the above specific conditions can be obtained by adjustment.

本発明はかかる知見に基づくものであって、その要旨とするところは以下の通りである。   The present invention is based on such knowledge, and the gist thereof is as follows.

[1]質量%で、
C:0.020〜0.060%、
Si:0.01〜0.05%、
Mn:0.20〜0.60%
P:0.001〜0.100%、
S:0.008〜0.020%、
N:0.0130〜0.0190%、
Al:0.005〜{−4.20×N+0.110}%(ただし、式中、Nは鋼中のN含有量(質量%))を含有し、
Mnf=Mn−1.7×S(ただし、式中Mn、Sは鋼中のMn含有量(質量%)、S含有量(質量%))とした時、Mnf:0.30%以上0.58%以下であり、
残部がFeおよび不可避的不純物からなり、
210℃×10分の時効処理の後、下降伏強度YP(N/mm)および降伏点伸びYPEl(%)が、YP≧355、YPEl≧2、かつYPEl≧(60/(YP−355))+2およびYP≦4.09×YPEl+476を満たす、缶蓋用鋼板。
[2]前記[1]に記載の缶蓋用鋼板の製造方法であり、
1150℃以上の温度に鋼スラブを再加熱し、
巻取り温度を680℃以下として再加熱した鋼スラブを熱間圧延し、熱延鋼板を製造し、
該熱延鋼板を冷間圧延し、冷延鋼板を製造し、
該冷延鋼板を再結晶焼鈍し、
伸張率3%以下で調質圧延する、缶蓋用鋼板の製造方法。
[1] By mass%
C: 0.020 to 0.060%,
Si: 0.01 to 0.05%,
Mn: 0.20 to 0.60%
P: 0.001 to 0.100%,
S: 0.008 to 0.020%,
N: 0.0130 to 0.0190%
Al: 0.005 to {-4.20 × N + 0.110}% (where N is the N content (mass%) in the steel),
Mnf = Mn-1.7 × S (where Mn and S are Mn content (mass%) and S content (mass%) in steel), Mnf: 0.30% or more and 0.00. 58% or less,
The balance consists of Fe and inevitable impurities,
After aging treatment at 210 ° C. × 10 minutes, the yield strength YP (N / mm 2 ) and the yield point elongation YPEl (%) are YP ≧ 355, YPEl ≧ 2, and YPEl ≧ (60 / (YP-355). ) Steel plate for can lid satisfying +2 and YP ≦ 4.09 × YPEL + 476.
[2] A method for producing a steel plate for can lids according to [1],
Reheat the steel slab to a temperature of 1150 ° C or higher,
A steel slab reheated at a coiling temperature of 680 ° C. or lower is hot-rolled to produce a hot-rolled steel sheet,
Cold rolling the hot rolled steel sheet to produce a cold rolled steel sheet,
Recrystallizing the cold-rolled steel sheet,
A method for producing a steel plate for can lid, which is temper-rolled at an elongation of 3% or less.

本発明によれば、缶内外の圧力差による変形を抑制することができる缶蓋用鋼板を得ることができる。   ADVANTAGE OF THE INVENTION According to this invention, the steel plate for can lids which can suppress the deformation | transformation by the pressure difference inside and outside a can can be obtained.

缶胴、缶蓋からなる缶体の外観を示す図である。It is a figure which shows the external appearance of the can body which consists of a can body and a can lid. (a)は缶蓋の形状を示す平面図であり、(b)は(a)中のA−A断面図である。(A) is a top view which shows the shape of a can lid, (b) is AA sectional drawing in (a). 缶蓋の内外の圧力差による変形についての缶蓋用鋼板の下降伏強度YPと降伏点伸びYPElの影響を評価した結果を示すグラフである。It is a graph which shows the result of having evaluated the influence of the yield strength YP and the yield point elongation YPEl of the steel plate for can lids about the deformation | transformation by the pressure difference inside and outside of a can lid.

本発明の缶蓋用鋼板は、C:0.020〜0.060%、Si:0.01〜0.05%、Mn:0.20〜0.60%、P:0.001〜0.100%、S:0.008〜0.020%、N:0.0130〜0.0190%、Al:0.005〜{−4.20×N+0.110}%(ただし、式中、Nは鋼中のN含有量(質量%))を含有し、Mnf=Mn−1.7×S(ただし、式中Mn、Sは鋼中のMn含有量(質量%)、S含有量(質量%))とした時、Mnf:0.30%以上0.58%以下であり、残部がFeおよび不可避的不純物からなる成分組成を有し、210℃×10分の時効処理の後、下降伏強度YP(N/mm)および降伏点伸びYPEl(%)が、YP≧355、YPEl≧2、かつYPEl≧(60/(YP−355))+2およびYP≦4.09×YPEl+476を満たす。以下に本発明の缶蓋用鋼板およびその製造方法について詳細に説明する。The steel plate for can lids of this invention is C: 0.020-0.060%, Si: 0.01-0.05%, Mn: 0.20-0.60%, P: 0.001-0. 100%, S: 0.008 to 0.020%, N: 0.0130 to 0.0190%, Al: 0.005 to {-4.20 × N + 0.110}% (where N is N content in steel (% by mass)), Mnf = Mn-1.7 × S (wherein Mn and S are Mn content in steel (% by mass), S content (% by mass) )), Mnf: not less than 0.30% and not more than 0.58%, the remainder has a component composition consisting of Fe and inevitable impurities, and after aging treatment at 210 ° C. for 10 minutes, the yield strength is lowered YP (N / mm 2) and yield point elongation YPEl (%) is, YP ≧ 355, YPEl ≧ 2 , and YPEl ≧ (60 / (YP- 3 5)) + 2 and satisfy YP ≦ 4.09 × YPEl + 476. Below, the steel plate for can lids of this invention and its manufacturing method are demonstrated in detail.

まず、本発明の缶蓋用鋼板の成分組成について説明する。成分はすべて質量%である。   First, the component composition of the steel plate for can lids of this invention is demonstrated. All components are in weight percent.

C:0.020〜0.060%
本発明の鋼板は、熱間圧延、冷間圧延、再結晶焼鈍、調質圧延の各工程を経て製造される鋼板であり、上記の機械特性を備える必要がある。このような特性を満たすために、本発明の鋼板では、固溶強化元素としてCを含有することが重要であり、C含有量の下限は0.020%とする。Cの含有量が0.020%未満では、本発明で規定する機械特性が得られない。また、好ましくは、C含有量は0.030%以上である。一方、Cの含有量が0.060%を超えると、過剰に硬質となることで蓋加工の際に鋼板と加工金型との間の接触面圧が高くなり、鋼板の表面に被覆された有機皮膜が損傷する。よって、C含有量の上限は、0.060%とする。また、好ましくは、C含有量は0.050%以下である。
C: 0.020 to 0.060%
The steel plate of the present invention is a steel plate manufactured through each process of hot rolling, cold rolling, recrystallization annealing, and temper rolling, and needs to have the above mechanical characteristics. In order to satisfy such characteristics, in the steel sheet of the present invention, it is important to contain C as a solid solution strengthening element, and the lower limit of the C content is 0.020%. If the C content is less than 0.020%, the mechanical properties defined in the present invention cannot be obtained. Preferably, the C content is 0.030% or more. On the other hand, when the content of C exceeds 0.060%, the contact surface pressure between the steel plate and the processing mold is increased during the lid processing due to being excessively hard, and the surface of the steel plate is coated. The organic film is damaged. Therefore, the upper limit of the C content is 0.060%. Preferably, the C content is 0.050% or less.

Si:0.01〜0.05%
Siは、固溶強化に有効な作用をもたらす一方、多量に含有すると鋼板の耐食性を劣化させる。Siは、鋼板の原料である鉄鉱石に多量に含有されるため、精錬段階で除去しつつその含有量を調整する。本発明の場合、Siの固溶強化に対する寄与よりも耐食性を劣化させる影響を排除することが望ましい。そのため、Si含有量は、耐食性の影響が顕在化しない0.05%以下とする。好ましくは、Si含有量は0.03%以下である。耐食性の観点ではSi含有量は極力低減することが望ましいが、過剰な低減操作は精錬での作業負荷を増加させるため、下限は0.01%とする。
Si: 0.01-0.05%
Si provides an effective action for solid solution strengthening, but if contained in a large amount, the corrosion resistance of the steel sheet is deteriorated. Since Si is contained in a large amount in iron ore, which is a raw material for steel plates, the content is adjusted while removing it in the refining stage. In the case of the present invention, it is desirable to eliminate the influence of deteriorating the corrosion resistance rather than the contribution to the solid solution strengthening of Si. Therefore, the Si content is set to 0.05% or less where the influence of corrosion resistance is not apparent. Preferably, the Si content is 0.03% or less. From the viewpoint of corrosion resistance, it is desirable to reduce the Si content as much as possible. However, excessive reduction increases the work load in refining, so the lower limit is made 0.01%.

Mn:0.20〜0.60%
Mnは、鋼板の強度を調整することに有効な元素であるが、Mn含有量が0.20%未満では、その効果を得られない。一方、Mn含有量が0.60%を超えると、鋼板の強度が過度に高くなる。よって、Mn含有量は、0.20%以上0.60%以下とする。Mn含有量について、下限側は0.25%以上が好ましい。上限側は0.55%以下が好ましい。
Mn: 0.20 to 0.60%
Mn is an element effective for adjusting the strength of the steel sheet, but if the Mn content is less than 0.20%, the effect cannot be obtained. On the other hand, if the Mn content exceeds 0.60%, the strength of the steel sheet becomes excessively high. Therefore, the Mn content is set to 0.20% or more and 0.60% or less. Regarding the Mn content, the lower limit side is preferably 0.25% or more. The upper limit is preferably 0.55% or less.

P:0.001〜0.100%
Pは、固溶強化能が大きい元素であるが、0.100%を超えて含有させると耐食性を著しく損う。よって、P含有量の上限は0.100%とする。好ましくは、P含有量は0.020%以下である。一方、Pを0.001%未満にするには脱リンコストが過大となる。よって、P含有量の下限は0.001%とする。
P: 0.001 to 0.100%
P is an element having a large solid solution strengthening ability, but if it exceeds 0.100%, corrosion resistance is significantly impaired. Therefore, the upper limit of the P content is 0.100%. Preferably, the P content is 0.020% or less. On the other hand, dephosphorization cost becomes excessive to make P less than 0.001%. Therefore, the lower limit of the P content is 0.001%.

S:0.008〜0.020%
Sは、鋼中のMnと結合してMnSを生成する。S含有量が0.020%を超えると、高温において粒界にMnSが析出し、脆化の原因となる。そのため、S含有量の上限は0.020%とする。一方、S含有量を0.008%未満にするには脱硫コストが過大となる。よって、S含有量の下限は0.008%とする。
S: 0.008 to 0.020%
S combines with Mn in steel to generate MnS. If the S content exceeds 0.020%, MnS precipitates at the grain boundaries at high temperatures, causing embrittlement. Therefore, the upper limit of the S content is 0.020%. On the other hand, desulfurization cost becomes excessive to make the S content less than 0.008%. Therefore, the lower limit for the S content is 0.008%.

N:0.0130〜0.0190%
Nは固溶強化、および後述する降伏点伸びYPElの確保に寄与する元素である。これらの効果を発現させるためには、Nを0.0130%以上含有させる必要がある。一方、Nを0.0190%を超えて含有させると、歪時効硬化への効果が飽和し有効に作用しないばかりか、熱間延性の劣化を招く。よって、N含有量の上限は0.0190%とする。N含有量について、下限側は0.0135%以上が好ましい。上限側は0.0175%以下が好ましい。
N: 0.0130 to 0.0190%
N is an element that contributes to solid solution strengthening and securing the yield point elongation YPEL described later. In order to express these effects, it is necessary to contain 0.0130% or more of N. On the other hand, if N is contained in an amount exceeding 0.0190%, the effect on strain age hardening is saturated and not effective, and hot ductility is deteriorated. Therefore, the upper limit of the N content is 0.0190%. For the N content, the lower limit is preferably 0.0135% or more. The upper limit is preferably 0.0175% or less.

Al:0.005〜{−4.20×N+0.110}%(ただし、式中、Nは鋼中のN含有量(質量%))
Alは、脱酸剤として作用し、鋼板の清浄度を高めるために必要な元素である。また、本発明においては、機械特性を確保するために固溶Nを利用する。一方、Alは鋼中のNと結合してAlNを形成する。以上より、AlNの過剰な析出を抑制する必要があり、Al量の上限を規定する必要がある。Al含有量が{−4.20×Nの含有量(%)+0.110}%を超えると、AlNの析出が過剰になり、固溶N量が不足するという不具合がある。一方で、Al含有量が0.005%未満となるような鋼では、脱酸不足となって鋼板の清浄度が劣化するため、下限は0.005%とする。なお、本発明におけるAlは酸可溶Alである。
Al: 0.005 to {-4.20 × N + 0.110}% (where N is the N content (mass%) in the steel)
Al acts as a deoxidizer and is an element necessary for increasing the cleanliness of the steel sheet. In the present invention, solid solution N is used to ensure mechanical properties. On the other hand, Al combines with N in steel to form AlN. From the above, it is necessary to suppress excessive precipitation of AlN, and it is necessary to define the upper limit of the Al amount. When the Al content exceeds {−4.20 × N content (%) + 0.110}%, there is a problem that the precipitation of AlN becomes excessive and the amount of dissolved N is insufficient. On the other hand, in steel with an Al content of less than 0.005%, deoxidation is insufficient and the cleanliness of the steel sheet deteriorates, so the lower limit is made 0.005%. In the present invention, Al is acid-soluble Al.

Mnf=Mn−1.7×S(ただし、式中Mn、Sは鋼中のMn含有量(質量%)、S含有量(質量%))とした時、Mnf:0.30%以上0.58%以下
Mnは、固溶強化、結晶粒の細粒化により鋼板の強度を増加させる。しかし、MnはSと結合してMnSを形成するので、固溶強化に寄与するMn量は、Mn含有量からMnSを形成しうるMn量を差し引いた量と見なされる。MnとSの原子量比を考慮すると、固溶強化に寄与するMn量はMnf=Mn−1.7×Sと表すことができる。Mnfが0.58%超では、結晶粒径を小さくする効果が顕著に生じ、過剰に硬化する。よって、Mnfは0.58%以下とする。好ましくは、Mnfは0.53%以下である。一方、Mnfが0.30%未満になると軟化して必要な耐圧強度が得られなくなる。よって、Mnfは0.30%以上とする。好ましくは、Mnfは0.33%以上である。
Mnf = Mn-1.7 × S (where Mn and S are Mn content (mass%) and S content (mass%) in steel), Mnf: 0.30% or more and 0.00. Mn of 58% or less increases the strength of the steel sheet by solid solution strengthening and crystal grain refinement. However, since Mn combines with S to form MnS, the amount of Mn contributing to solid solution strengthening is considered to be the amount obtained by subtracting the amount of Mn capable of forming MnS from the Mn content. Considering the atomic weight ratio of Mn and S, the amount of Mn contributing to solid solution strengthening can be expressed as Mnf = Mn−1.7 × S. When Mnf is more than 0.58%, the effect of reducing the crystal grain size is remarkably produced, and it is hardened excessively. Therefore, Mnf is 0.58% or less. Preferably, Mnf is 0.53% or less. On the other hand, when Mnf is less than 0.30%, it softens and the required pressure strength cannot be obtained. Therefore, Mnf is set to 0.30% or more. Preferably, Mnf is 0.33% or more.

残部はFeおよび不可避的不純物とする。   The balance is Fe and inevitable impurities.

なお、本発明の鋼板はパーライト組織を含まない組織であることが望ましい。パーライト組織とはフェライト相とセメンタイト相が層状に析出した組織である。粗大なパーライト組織が存在すると、変形時に応力集中によるクラックの発生起点となる場合がある。缶蓋が缶胴に巻き締めによって装着される際、このようなクラックの発生起点が存在すると巻き締め部の割れに至る可能性があるため、本発明の鋼板はパーライト組織を含まない組織であることが望ましい。このパーライト組織を含まない組織は、冷間圧延時の圧延率を80%以上とすること、冷間圧延の後の再結晶焼鈍における焼鈍温度をAc変態点未満とすることにより得ることができる。The steel sheet of the present invention preferably has a structure that does not contain a pearlite structure. The pearlite structure is a structure in which a ferrite phase and a cementite phase are deposited in a layered manner. If a coarse pearlite structure is present, cracks may be generated from stress concentration during deformation. When the can lid is attached to the can body by tightening, there is a possibility that cracking of the tightening portion will occur if there is such a crack starting point, so the steel sheet of the present invention does not include a pearlite structure. It is desirable. This structure not including the pearlite structure can be obtained by setting the rolling rate during cold rolling to 80% or more, and by setting the annealing temperature in recrystallization annealing after cold rolling to less than the Ac 1 transformation point. .

次に、本発明の鋼板が備えるべき機械特性について説明する。本発明者らは、鋼板の機械特性が缶蓋の耐圧特性に及ぼす影響について検討した。その結果、下降伏強度YP、降伏点伸びYPElを適切に制御することで、平面で構成される部分が多い平板形状の蓋であっても、良好な耐圧特性を備えた缶蓋が得られることを見いだした。   Next, the mechanical properties that the steel sheet of the present invention should have will be described. The present inventors examined the influence of the mechanical characteristics of the steel sheet on the pressure resistance characteristics of the can lid. As a result, by properly controlling the yield strength YP and the yield point elongation YPEL, a can lid having good pressure resistance characteristics can be obtained even with a flat lid having many flat parts. I found.

具体的には、本発明の鋼板では、210℃×10分の時効処理の後、下降伏強度YP(N/mm)および降伏点伸びYPEl(%)が、YP≧355、YPEl≧2、かつYPEl≧60/(YP−355)+2およびYP≦4.09×YPEl+476を満たす。Specifically, in the steel sheet of the present invention, after aging treatment at 210 ° C. × 10 minutes, the yield strength YP (N / mm 2 ) and the yield point elongation YPEl (%) are YP ≧ 355, YPEl ≧ 2, And YPEl ≧ 60 / (YP-355) +2 and YP ≦ 4.09 × YPEL + 476 are satisfied.

一般的には、圧力に対する缶蓋の変形を抑制するためには、鋼板自体の剛性向上等により、缶蓋の剛性を高めることが有効である。これに対し、本発明では缶蓋の残留応力に着目した。   Generally, in order to suppress deformation of the can lid with respect to pressure, it is effective to increase the rigidity of the can lid by improving the rigidity of the steel plate itself. In contrast, the present invention focuses on the residual stress of the can lid.

図1は、本発明の鋼板が用いられる缶蓋を有する缶体10の外観を示す図である。図1に示すように、缶体10は缶胴1と缶蓋2とから主に構成される。また、図2は、(a)が缶蓋2の形状を示す平面図であり、(b)が(a)中のA−A断面図である。本発明の対象とする食品缶詰や飲料缶詰等の缶蓋2は、図2に示すように、外周部近傍にエキスパンドリングを備えている(図2(b)の符号x参照)。このエキスパンドリングに、加工によるスプリングバックを生じさせることで缶蓋2内部に残留応力を発生させることができる。   FIG. 1 is a view showing an appearance of a can body 10 having a can lid in which the steel plate of the present invention is used. As shown in FIG. 1, the can body 10 is mainly composed of a can body 1 and a can lid 2. 2A is a plan view showing the shape of the can lid 2, and FIG. 2B is a cross-sectional view taken along line AA in FIG. As shown in FIG. 2, the can lid 2 for food canned foods, beverage canned foods, and the like, which is an object of the present invention, includes an expanding ring in the vicinity of the outer peripheral portion (see reference numeral x in FIG. 2B). Residual stress can be generated inside the can lid 2 by generating a spring back by processing in the expanding ring.

スプリングバックを大きくするためには、鋼板の下降伏強度YPを高めることが有効である。一方、本発明の対象とする食品缶詰、飲料缶詰の缶蓋2は、図2に示すように、中央部におおむね平坦な領域を有する。この部分で残留応力を発生させるためには、降伏点伸びYPElを向上させることが有効である。つまり、降伏点伸びYPElを向上させることで缶蓋2の平坦部分に不連続変形を生じさせ、変形部と未変形部とを混在させた状態にすることで缶蓋2内部に残留応力を生じさせることができる。   In order to increase the springback, it is effective to increase the yield strength YP of the steel sheet. On the other hand, as shown in FIG. 2, the can lid 2 for food cans and beverage cans targeted by the present invention has a generally flat region at the center. In order to generate a residual stress in this portion, it is effective to improve the yield point elongation YPEL. In other words, discontinuous deformation occurs in the flat portion of the can lid 2 by improving the yield point elongation YPEL, and residual stress is generated in the can lid 2 by mixing the deformed portion and the undeformed portion. Can be made.

このような残留応力を生じさせるためには、下降伏強度YPと降伏点伸びYPElとを適切に調整する必要がある。図3は、缶蓋の内外の圧力差による変形についての缶蓋用鋼板の下降伏強度YPと降伏点伸びYPElの影響を評価した結果を示すグラフである。図3に示す評価では、板厚0.251mm〜0.277mm、呼び径603(直径が約6インチと3/16インチ)の缶蓋を成形し、この缶蓋の内外の圧力差による蓋の変形を耐圧強度試験機を用いて調べた。具体的には、成形した缶蓋を大気圧下で缶胴に巻き締めた後、缶内部に加圧空気を注入することで缶内外圧差を50kPaとし、その際の缶蓋中央部の高さと巻き締め部頂点の高さの差を測定した。その結果について、その値が4mm以下のものを合格とし、4mm超のものを不合格とし、合格を○、不合格を×で示した。   In order to generate such residual stress, it is necessary to appropriately adjust the yield strength YP and the yield point elongation YPEL. FIG. 3 is a graph showing the results of evaluating the influence of the lower yield strength YP and the yield point elongation YPEL of the steel plate for can lids on the deformation due to the pressure difference between the inside and outside of the can lid. In the evaluation shown in FIG. 3, a can lid having a plate thickness of 0.251 mm to 0.277 mm and a nominal diameter of 603 (diameters of about 6 inches and 3/16 inches) was formed, and the lid of the lid due to a pressure difference between the inside and outside of the can lid was formed. The deformation was examined using a pressure strength tester. Specifically, after the molded can lid is wound around the can body at atmospheric pressure, the pressure difference between the inside and outside of the can is set to 50 kPa by injecting pressurized air into the inside of the can. The difference in height of the tightening portion apex was measured. About the result, the value was 4 mm or less, the thing over 4 mm was made unsuccessful, the acceptance was indicated by ○, and the failure was indicated by ×.

缶蓋内に残留応力を生じさせるためには、下降伏強度YP、降伏点伸びYPElは大きいほど有利と考えられ、YPEl≧60/(YP−355)+2となる領域で蓋変形は合格となる。一方で下降伏強度YPが高すぎると、蓋変形は不合格となり、YP≦4.09×YPEl+476である必要がある。このメカニズムは現状では明確ではないが、下降伏強度YPが高すぎるとスプリングバックが大きくなることでエキスパンドリングの形状が不均一となり、蓋の形状が不安定になることなどが理由として考えられる。   In order to generate residual stress in the can lid, it is considered that the lower the yield strength YP and the yield point elongation YPEl, the more advantageous, and the lid deformation passes in the region where YPEl ≧ 60 / (YP-355) +2. . On the other hand, when the falling yield strength YP is too high, the lid deformation is rejected, and it is necessary that YP ≦ 4.09 × YPEL + 476. Although this mechanism is not clear at present, the reason is that if the yield strength YP is too high, the spring back becomes large, the shape of the expanding ring becomes non-uniform, and the shape of the lid becomes unstable.

なお、本発明の引張試験は、JIS Z 2201「金属材料引張り試験片」に規定された5号試験片を用い、JIS Z 2241「金属材料引張り試験方法」に準じて行うことができる。   The tensile test of the present invention can be performed according to JIS Z 2241 “Metal material tensile test method” using No. 5 test piece defined in JIS Z 2201 “Metal material tensile test piece”.

降伏点伸びYPElは、ゲージ長50mmを基準とした際の伸びを採用する。また、引張試験における引張方向は、鋼板の圧延方向とする。一般に、鋼板の下降伏強度YPは圧延方向で最も低く、缶蓋に圧力が作用して変形する際は、下降伏強度YPが最も低い圧延方向から変形が始まり、缶蓋の耐圧挙動を考慮する場合は最も下降伏強度YPが低い方向を考慮することが耐圧強度の下限値を与えるため、鋼板の圧延方向を引張方向とする。   As the yield point elongation YPEL, an elongation based on a gauge length of 50 mm is adopted. The tensile direction in the tensile test is the rolling direction of the steel sheet. In general, the lower yield strength YP of the steel sheet is the lowest in the rolling direction, and when the can lid is deformed by pressure, the deformation starts from the rolling direction with the lowest lower yield strength YP, and the pressure resistance behavior of the can lid is taken into consideration. In this case, considering the direction in which the lower yield strength YP is the lowest gives the lower limit value of the pressure strength, the rolling direction of the steel sheet is taken as the tensile direction.

この下降伏強度YPは、成分、製造条件を適正な範囲で制御することにより調整することができるが、特に、Mn含有量とS含有量の制御、調質圧延率の制御が重要である。また、この降伏点伸びYPElは、成分、製造条件を適正な範囲で制御することにより調整することができるが、特に、Al含有量とN含有量の制御、スラブ加熱温度、熱間圧延の巻取り温度の制御が重要である。   The yield strength YP can be adjusted by controlling the components and production conditions within an appropriate range. In particular, it is important to control the Mn content and S content and the temper rolling rate. Further, the yield point elongation YPEL can be adjusted by controlling the components and production conditions within an appropriate range. In particular, the control of the Al content and the N content, the slab heating temperature, the hot rolling coil The control of the temperature is important.

なお、本発明において、下降伏強度YP(N/mm)および降伏点伸びYPEl(%)の規定は、呼び径603の缶蓋に関する実験結果から定めたものであるが、缶蓋の直径が小さいほど缶蓋の圧力に対する変形も小さくなるため、上記の評価指標は直径が呼び径603の缶蓋よりも小さい直径の缶蓋にも適用することができる。In the present invention, the specifications of the lower yield strength YP (N / mm 2 ) and the yield point elongation YPEL (%) are determined from the experimental results on the can lid having a nominal diameter of 603. Since the smaller the deformation of the can lid, the smaller the deformation of the can lid, the above evaluation index can be applied to a can lid having a diameter smaller than that of a can lid having a nominal diameter of 603.

次に、本発明の缶蓋用鋼板の製造方法の一例について説明する。   Next, an example of the manufacturing method of the steel plate for can lids of this invention is demonstrated.

本発明の鋼板は、熱間圧延、冷間圧延、再結晶焼鈍、調質圧延、必要に応じて表面処理の各工程を経て製造される。詳細を以下に説明する。   The steel sheet of the present invention is manufactured through each step of hot rolling, cold rolling, recrystallization annealing, temper rolling, and surface treatment as necessary. Details will be described below.

まず、上述した成分組成を有する鋼スラブは、溶製し、連続鋳造によって得ることができる。連続鋳造では、垂直曲げ型または湾曲型の連続鋳造機によりスラブを作製し、スラブに曲げあるいは曲げ戻し変形が加えられる領域における角部の表面温度を800℃以下または900℃以上とすることが好ましい。これにより、スラブ横断面における長辺および短辺の角部での割れを回避することができる。   First, a steel slab having the component composition described above can be melted and obtained by continuous casting. In continuous casting, it is preferable that a slab is produced by a vertical bending type or a curved type continuous casting machine, and the surface temperature of the corner in a region where bending or unbending deformation is applied to the slab is 800 ° C. or lower or 900 ° C. or higher. . Thereby, the crack in the corner | angular part of the long side and short side in a slab cross section can be avoided.

そして、鋼スラブを1150℃以上で再加熱を行う。1150℃以上の温度でスラブを再加熱することにより、スラブ冷却の過程で析出したAlNを溶解させることができる。一方、加熱に伴う過度の酸化を防止するため、スラブ加熱温度は1300℃以下が好ましい。なお、本発明においてスラブ温度はスラブの表面温度とする。   And steel slab is reheated at 1150 degreeC or more. By reheating the slab at a temperature of 1150 ° C. or higher, the AlN deposited during the slab cooling process can be dissolved. On the other hand, in order to prevent excessive oxidation accompanying heating, the slab heating temperature is preferably 1300 ° C. or lower. In the present invention, the slab temperature is the surface temperature of the slab.

次いで、スラブを熱間圧延する。この際、熱間圧延における仕上げ温度はAr点以上の温度とすることが望ましい。また、巻取り温度は680℃以下とし、好ましくは680℃未満、より好ましくは600℃以下とする。仕上げ圧延後の巻取り温度が680℃超では、AlNが析出し、本発明におけるNの効果が得られない。なお、鋼板の過剰な硬質化を避けるために、巻取り温度は540℃以上であることが望ましい。なお、巻取り温度は鋼板表面温度である。The slab is then hot rolled. At this time, it is desirable that the finishing temperature in the hot rolling is a temperature of Ar 3 points or more. The coiling temperature is 680 ° C. or less, preferably less than 680 ° C., more preferably 600 ° C. or less. When the coiling temperature after finish rolling exceeds 680 ° C., AlN precipitates, and the effect of N in the present invention cannot be obtained. In order to avoid excessive hardening of the steel sheet, the winding temperature is preferably 540 ° C. or higher. The winding temperature is the steel sheet surface temperature.

熱間圧延後、冷却した熱延鋼板(熱延鋼帯)に対し、スケールを除去することが好ましい。スケールの除去方法は各種の方法が適用でき、例えば、酸洗のような化学的な除去や、物理的な除去等、種々の方法が適用できる。酸洗の場合は、硫酸法、塩酸法などの常法にしたがって行うことができる。   After hot rolling, it is preferable to remove the scale from the cooled hot-rolled steel sheet (hot-rolled steel strip). Various methods can be applied to the scale removal method, and various methods such as chemical removal such as pickling and physical removal can be applied. In the case of pickling, it can be carried out according to conventional methods such as sulfuric acid method and hydrochloric acid method.

次いで、冷間圧延を行う。冷間圧延は80%以上の圧延率で行うことが好ましい。冷間圧延時の圧延率を80%以上とすることで、熱間圧延後に生成するパーライト組織を破砕することができる。冷間圧延時の圧延率が80%未満であるとパーライト組織が残存する可能性がある。一方で、冷間圧延時の圧延率の上限は、過大な圧延率による圧延機の負荷の増大とそれに伴う圧延不良の発生を避けるため、95%とすることが好ましい。   Next, cold rolling is performed. Cold rolling is preferably performed at a rolling rate of 80% or more. By setting the rolling rate during cold rolling to 80% or more, the pearlite structure produced after hot rolling can be crushed. If the rolling rate during cold rolling is less than 80%, a pearlite structure may remain. On the other hand, the upper limit of the rolling rate during cold rolling is preferably 95% in order to avoid an increase in the load on the rolling mill due to an excessive rolling rate and the occurrence of rolling defects accompanying it.

次いで、冷間圧延の後に再結晶焼鈍を施す。再結晶焼鈍は連続焼鈍が好ましい。箱焼鈍では、固溶NがAlNとして析出し、室温歪時効硬化が得られない場合がある。また、焼鈍温度はAc変態点未満とすることが好ましい。焼鈍温度をAc変態点以上とすると、焼鈍中にオーステナイト相が生成し、缶蓋の加工時に割れの起点となりうるパーライト組織が形成される場合がある。本発明において、Ac変態点(℃)は示差熱分析により求めることができる。また、焼鈍温度は鋼板表面温度である。Next, after cold rolling, recrystallization annealing is performed. The recrystallization annealing is preferably continuous annealing. In box annealing, solid solution N may precipitate as AlN, and room temperature strain age hardening may not be obtained. The annealing temperature is preferably less than the Ac 1 transformation point. When the annealing temperature is set to the Ac 1 transformation point or higher, an austenite phase is generated during annealing, and a pearlite structure that can be a starting point of cracking during the processing of the can lid may be formed. In the present invention, the Ac 1 transformation point (° C.) can be determined by differential thermal analysis. The annealing temperature is the steel sheet surface temperature.

焼鈍後、鋼板を所定の機械特性、表面粗さにするために調質圧延を行う。調質圧延時の伸張率が高いほど、下降伏強度YPは高くなる一方で、降伏点伸びYPElは減少する。本発明で必要な下降伏強度および降伏点伸びバランスを得るため、伸長率は3%以下とする。一方、所定の表面粗さを得るため、伸長率は0.8%以上が望ましい。   After annealing, temper rolling is performed to make the steel sheet have predetermined mechanical properties and surface roughness. The higher the elongation during temper rolling, the higher the yield strength YP, while the yield point elongation YPEL decreases. In order to obtain the yield strength and yield point elongation balance required in the present invention, the elongation rate is 3% or less. On the other hand, in order to obtain a predetermined surface roughness, the elongation rate is desirably 0.8% or more.

以上により、本発明の缶蓋用鋼板が製造される。   Thus, the steel plate for can lid of the present invention is manufactured.

上記により製造された鋼板は、表面処理鋼板用の原板として使用される。本発明の効果は表面処理の種類によっては影響を受けないため、表面処理の種類は問わない。代表的な缶用表面処理の例としては、錫めっき(ぶりき)、クロムめっき(ティンフリースチール)などの金属、金属酸化物、金属水酸化物、無機塩等の被覆処理、さらにそれらの処理の上層に有機樹脂皮膜の被覆、例えばラミネート処理などがある。これらの表面処理において、鋼板に対して加熱処理が施される場合があり、鋼板はそれによる時効を受ける。また、鋼板が缶蓋に加工される前に保管される際にも、保管温度および保管期間に応じた時効を受ける。さらに、鋼板に対して塗装を行う場合にも時効を受ける。しかし、これらの原板状態での時効は本発明の効果には影響を及ぼさないことは確認されている。   The steel plate manufactured by the above is used as an original plate for a surface-treated steel plate. Since the effect of the present invention is not affected by the type of surface treatment, the type of surface treatment is not limited. Typical examples of surface treatment for cans are coating treatments for metals such as tin plating (blink) and chrome plating (tin-free steel), metal oxides, metal hydroxides, inorganic salts, and the like. The upper layer is coated with an organic resin film, for example, a laminate process. In these surface treatments, the steel sheet may be subjected to heat treatment, and the steel sheet is subjected to aging. Also, when the steel sheet is stored before being processed into a can lid, it is subjected to aging according to the storage temperature and the storage period. Furthermore, it is also subjected to aging when painting on steel sheets. However, it has been confirmed that aging in these original plate states does not affect the effect of the present invention.

以下、本発明の実施例について説明する。まず、表1に示す成分組成からなる鋼を溶製し、表2〜4に示すスラブ加熱温度でスラブ加熱し、表2〜4に示す巻取り温度で熱間圧延を行い、冷間圧延した後、再結晶焼鈍し、表2〜4に示す伸張率で調質圧延を行い製造した。
なお、表1において鋼Kは欠番である。表2〜4において、番号34〜37は欠番である。
Examples of the present invention will be described below. First, steel having the composition shown in Table 1 was melted, slab heated at the slab heating temperatures shown in Tables 2 to 4, hot rolled at the coiling temperatures shown in Tables 2 to 4, and cold rolled. Thereafter, recrystallization annealing was performed, and temper rolling was performed at the elongation shown in Tables 2 to 4.
In Table 1, steel K is a missing number. In Tables 2 to 4, numbers 34 to 37 are missing numbers.

Figure 0006108044
Figure 0006108044

Figure 0006108044
Figure 0006108044

Figure 0006108044
Figure 0006108044

Figure 0006108044
Figure 0006108044

その後、210℃×10分の人工時効処理を行った。以上により得られた鋼板に対し、JIS Z 2201「金属材料引張り試験片」に規定された5号試験片を用い、JIS Z 2241「金属材料引張り試験方法」に準じた引張試験により、下降伏強度(YP)、降伏点伸び(YPEl)を測定した。それらの結果に対して以下の判定条件1、判定条件2で合否を判定した。ここでは判定条件に合致するものを○、合致しないものを×とした。   Thereafter, an artificial aging treatment was performed at 210 ° C. for 10 minutes. The steel sheet obtained as described above was subjected to a tensile test in accordance with JIS Z 2241 “Metal material tensile test method” using a No. 5 test piece defined in JIS Z 2201 “Metal material tensile test piece”. (YP), yield point elongation (YPEl) was measured. With respect to those results, pass / fail was determined under the following determination conditions 1 and 2. In this example, a case that matches the determination condition is indicated by ◯, and a case that does not match the determination condition is indicated by ×.

更に、得られた鋼板を603径蓋に成形したのち、缶胴に巻き締め、缶内部の圧力を50kPaに加圧し、巻き締め部を基準とした缶蓋中央部の高さを測定した。この測定値が4mm以下であれば合格(○)と判断し、耐圧特性を評価した。   Furthermore, after the obtained steel plate was formed into a 603 diameter lid, it was wound around the can body, the pressure inside the can was increased to 50 kPa, and the height of the central portion of the can lid with respect to the wound portion was measured. If this measured value was 4 mm or less, it was judged as acceptable (◯), and the pressure resistance characteristics were evaluated.

表2〜4に示すように本発明例、つまり判定条件1、判定条件2が合格するものであれば、耐圧特性も合格であった。このように、本発明例では圧力に対する変形を抑制可能な缶蓋用鋼板を得ることができた。   As shown in Tables 2 to 4, if the present invention example, that is, the determination condition 1 and the determination condition 2 pass, the pressure resistance characteristics also passed. Thus, in the example of this invention, the steel plate for can lids which can suppress the deformation | transformation with respect to a pressure was able to be obtained.

判定条件1
210℃×10分の人工時効処理の後、下降伏強度YP(N/mm)および降伏点伸びYPEl(%)が、YP≧355、YPEl≧2、かつYPEl≧(60/(YP−355))+2を満たす。
Judgment condition 1
After artificial aging treatment at 210 ° C. × 10 minutes, the yield strength YP (N / mm 2 ) and the yield point elongation YPEl (%) are YP ≧ 355, YPEl ≧ 2, and YPEl ≧ (60 / (YP-355). )) + 2 is satisfied.

判定条件2
210℃×10分の人工時効処理の後、下降伏強度YP(N/mm)および降伏点伸びYPEl(%)が、YP≦4.09×YPEl+476を満たす。
Judgment condition 2
After the artificial aging treatment at 210 ° C. × 10 minutes, the yield strength YP (N / mm 2 ) and the yield point elongation YPEl (%) satisfy YP ≦ 4.09 × YPEL + 476.

1 缶胴
2 缶蓋
10 缶体
1 Can body 2 Can lid 10 Can body

Claims (2)

質量%で、
C:0.020〜0.060%、
Si:0.01〜0.05%、
Mn:0.20〜0.60%、
P:0.001〜0.100%、
S:0.008〜0.020%、
N:0.0130〜0.0190%、
Al:0.005〜{−4.20×N+0.110}%(ただし、式中、Nは鋼中のN含有量(質量%))を含有し、
Mnf=Mn−1.7×S(ただし、式中Mn、Sは鋼中のMn含有量(質量%)、S含有量(質量%))とした時、Mnf:0.30%以上0.58%以下であり、
残部がFeおよび不可避的不純物からなり、
210℃×10分の時効処理の後、下降伏強度YP(N/mm)および降伏点伸びYPEl(%)が、YP≧355、YPEl≧2、かつYPEl≧(60/(YP−355))+2、およびYP≦4.09×YPEl+476を満たす、缶蓋用鋼板。
% By mass
C: 0.020 to 0.060%,
Si: 0.01 to 0.05%,
Mn: 0.20 to 0.60%,
P: 0.001 to 0.100%,
S: 0.008 to 0.020%,
N: 0.0130 to 0.0190%
Al: 0.005 to {-4.20 × N + 0.110}% (where N is the N content (mass%) in the steel),
Mnf = Mn-1.7 × S (where Mn and S are Mn content (mass%) and S content (mass%) in steel), Mnf: 0.30% or more and 0.00. 58% or less,
The balance consists of Fe and inevitable impurities,
After aging treatment at 210 ° C. × 10 minutes, the yield strength YP (N / mm 2 ) and the yield point elongation YPEl (%) are YP ≧ 355, YPEl ≧ 2, and YPEl ≧ (60 / (YP-355). ) +2, and YP ≦ 4.09 × YPEL + 476.
請求項1に記載の缶蓋用鋼板の製造方法であり、
1150℃以上の温度に鋼スラブを再加熱し、
巻取り温度を680℃以下として再加熱した鋼スラブを熱間圧延し、熱延鋼板を製造し、
該熱延鋼板を冷間圧延し、冷延鋼板を製造し、
該冷延鋼板を再結晶焼鈍し、
伸張率3%以下で調質圧延する、缶蓋用鋼板の製造方法。
It is a manufacturing method of the steel plate for can lids of Claim 1,
Reheat the steel slab to a temperature of 1150 ° C or higher,
A steel slab reheated at a coiling temperature of 680 ° C. or lower is hot-rolled to produce a hot-rolled steel sheet,
Cold rolling the hot rolled steel sheet to produce a cold rolled steel sheet,
Recrystallizing the cold-rolled steel sheet,
A method for producing a steel plate for can lid, which is temper-rolled at an elongation of 3% or less.
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